CN116606576A - High-temperature anti-corrosion coating and preparation method thereof - Google Patents
High-temperature anti-corrosion coating and preparation method thereof Download PDFInfo
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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Abstract
Description
技术领域technical field
本发明涉及防腐材料技术领域,具体涉及一种高温防腐涂层及其制备方法。The invention relates to the technical field of anti-corrosion materials, in particular to a high-temperature anti-corrosion coating and a preparation method thereof.
背景技术Background technique
随着技术的革新,特殊工况也越来越多,在石油化工、航空航天、冶金电力等领域,一些设备的部件在腐蚀和高温的共同作用下会发生加速腐蚀。涂覆防腐涂层是目前解决腐蚀问题最有效的办法之一。With the innovation of technology, there are more and more special working conditions. In petrochemical, aerospace, metallurgical power and other fields, some parts of equipment will undergo accelerated corrosion under the combined action of corrosion and high temperature. Coating anti-corrosion coating is one of the most effective ways to solve corrosion problems at present.
然而,在高温条件下,需要采用耐高温防腐涂层,其中运用较为广泛的陶瓷涂层和有机硅涂层,但是附着力差、机械强度低、易破裂且耐H2S性能差。However, under high temperature conditions, high temperature resistant anti-corrosion coatings are required, among which ceramic coatings and silicone coatings are widely used, but they have poor adhesion, low mechanical strength, easy cracking and poor H 2 S resistance.
发明内容Contents of the invention
为了解决上述问题,本发明提供了一种高温防腐涂层及其制备方法,以提高涂层的耐高温和防腐性能。In order to solve the above problems, the present invention provides a high-temperature anti-corrosion coating and a preparation method thereof, so as to improve the high-temperature resistance and anti-corrosion performance of the coating.
本发明的第一个目的是提供一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺3-5份、三聚氰胺12-16份、海泡石10-15份、石墨鳞片16-20份、导电剂5-8份、聚酰胺蜡粉12-16份、苯并三氮唑14-20份、三苯基膦15-22份、肌醇六磷酸酯12-18份、液体石蜡4-8份、四氟硼酸四乙基铵6-12份、触变剂4-8份、聚己内酯5-10份、聚乙烯吡咯烷酮14-22份、丁二醇缩水甘油醚18-26份、N-甲基吡咯烷酮10-14份、聚氨酯分散剂4-6份、颜填料5-8份、助溶剂4-6份、消泡剂2-6份。The first object of the present invention is to provide a high-temperature anti-corrosion coating, which is made of the following raw material components in parts by weight: 3-5 parts of sulfur polyimide, 12-16 parts of melamine, and 10-15 parts of sepiolite , 16-20 parts of graphite flakes, 5-8 parts of conductive agent, 12-16 parts of polyamide wax powder, 14-20 parts of benzotriazole, 15-22 parts of triphenylphosphine, 12- 18 parts, 4-8 parts of liquid paraffin, 6-12 parts of tetraethylammonium tetrafluoroborate, 4-8 parts of thixotropic agent, 5-10 parts of polycaprolactone, 14-22 parts of polyvinylpyrrolidone, butanediol 18-26 parts of glycidyl ether, 10-14 parts of N-methylpyrrolidone, 4-6 parts of polyurethane dispersant, 5-8 parts of pigment and filler, 4-6 parts of co-solvent, 2-6 parts of defoamer.
优选的,所述高温防腐涂层由以下重量份的原料组分制成:硫聚酰亚胺4份、三聚氰胺14份、海泡石12.5份、石墨鳞片18份、导电剂6.5份、聚酰胺蜡粉14份、苯并三氮唑17份、三苯基膦18.5份、肌醇六磷酸酯15份、液体石蜡6份、四氟硼酸四乙基铵9份、触变剂6份、聚己内酯7.5份、聚乙烯吡咯烷酮18份、丁二醇缩水甘油醚22份、N-甲基吡咯烷酮12份、聚氨酯分散剂5份、颜填料6.5份、助溶剂5份、消泡剂4份。Preferably, the high-temperature anti-corrosion coating is made of the following raw material components in parts by weight: 4 parts of sulfur polyimide, 14 parts of melamine, 12.5 parts of sepiolite, 18 parts of graphite flakes, 6.5 parts of conductive agent, polyamide 14 parts of wax powder, 17 parts of benzotriazole, 18.5 parts of triphenylphosphine, 15 parts of phytic acid ester, 6 parts of liquid paraffin, 9 parts of tetraethylammonium tetrafluoroborate, 6 parts of thixotropic agent, poly 7.5 parts of caprolactone, 18 parts of polyvinylpyrrolidone, 22 parts of butanediol glycidyl ether, 12 parts of N-methylpyrrolidone, 5 parts of polyurethane dispersant, 6.5 parts of pigment and filler, 5 parts of cosolvent, 4 parts of defoamer .
优选的,所述颜填料为钛白粉、氧化铝、亲水性二氧化硅、碳纳米管中的任意一种或多种。Preferably, the pigment and filler are any one or more of titanium dioxide, alumina, hydrophilic silica, and carbon nanotubes.
优选的,所述助溶剂为乙醇、乙二醇、乙二醇乙醚中的任意一种或多种。Preferably, the co-solvent is any one or more of ethanol, ethylene glycol, and ethylene glycol ether.
优选的,所述消泡剂为聚氧丙烯氧化乙烯甘油醚、聚二甲基硅氧烷、高碳醇和磷酸三丁酯中的一种或几种混合。Preferably, the defoamer is one or more of polyoxypropylene oxide ethylene glyceryl ether, polydimethylsiloxane, higher alcohol and tributyl phosphate.
优选的,所述硫聚酰亚胺的粒径为10-50μm。Preferably, the particle size of the sulfur polyimide is 10-50 μm.
优选的,还包括环氧树脂,所述环氧树脂为酚醛树脂、磷酚醛环氧树脂、多酚型缩水甘油醚环氧树脂中的一种或者多种混合。Preferably, epoxy resin is also included, and the epoxy resin is one or more mixtures of phenolic resin, phosphorous novolac epoxy resin and polyphenol glycidyl ether epoxy resin.
本发明的第二个目的是提供一种高温防腐涂层的制备方法,包括以下步骤:Second object of the present invention is to provide a kind of preparation method of high temperature anticorrosion coating, comprises the following steps:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为800-1500r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 800-1500r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为300-500r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into the dispersion tank, stir and disperse evenly under the stirring condition of the rotating speed of 300-500r/min, and obtain the mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
优选的,在步骤2中,所述在转速为800-1500r/min的条件下搅拌分散均匀包括:在转速为800-1500r/min、环境温度为25-30℃的条件下搅拌30-45min。Preferably, in step 2, said stirring and dispersing uniformly at a rotation speed of 800-1500r/min comprises: stirring for 30-45min at a rotation speed of 800-1500r/min and an ambient temperature of 25-30°C.
优选的,在步骤4中,所述在转速为300-500r/min的搅拌条件下搅拌分散均匀包括:在转速为300-500r/min的搅拌条件下搅拌分散均匀,再研磨至细度≤60μm,得到混合物B。Preferably, in step 4, said stirring and dispersing uniformly under the stirring condition of rotating speed of 300-500r/min includes: stirring and dispersing uniformly under the stirring condition of rotating speed of 300-500r/min, and then grinding to a fineness≤60μm , to obtain mixture B.
与现有技术相比,本发明提供的高温防腐涂层,具有以下有益效果:Compared with the prior art, the high-temperature anti-corrosion coating provided by the present invention has the following beneficial effects:
本发明制备的高温防腐涂层具有自润滑、耐高温、耐腐蚀的性能,且制备方法简单,易操作,成本低,耐磨材料的组分简单、易于加工、利于推广。其中,硫聚酰亚胺和三聚氰胺的混合大大提高了防腐性能;采用海泡石作为耐高温无机填料,显著提高了涂料的耐火极限;采用石墨鳞片作为防腐蚀填料,能够阻挡和减缓腐蚀性介质向涂层中的渗透,显著提高了涂料的防腐蚀性能;采用聚己内酯可以用来改善丙烯酸、聚脂、环氧等树脂的柔韧性、低温耐冲击性、流动性和成型性等其耐热性(400℃以上)可达100h以上,同时防腐性(耐盐雾性≥2000h)不受影响。本发明的配方组成与制备工艺简单,减少了传统涂料所需的添加剂的使用以及复杂的工艺,降低了成本,保护了环境。The high-temperature anti-corrosion coating prepared by the invention has the properties of self-lubrication, high temperature resistance and corrosion resistance, and the preparation method is simple, easy to operate, low in cost, and the components of the wear-resistant material are simple, easy to process and beneficial to popularization. Among them, the mixture of sulfur polyimide and melamine greatly improves the anti-corrosion performance; the use of sepiolite as a high-temperature resistant inorganic filler significantly improves the fire resistance limit of the coating; the use of graphite flakes as an anti-corrosion filler can block and slow down corrosive media The penetration into the coating significantly improves the anti-corrosion performance of the coating; the use of polycaprolactone can be used to improve the flexibility, low-temperature impact resistance, fluidity and formability of acrylic, polyester, epoxy and other resins. The heat resistance (above 400°C) can reach more than 100h, while the corrosion resistance (salt spray resistance ≥ 2000h) is not affected. The formula composition and preparation process of the invention are simple, reduce the use of additives and complex processes required by traditional coatings, reduce costs and protect the environment.
具体实施方式Detailed ways
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明,但不以任何形式限制本发明。应当指出的是,对本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进。这些都属于本发明的保护范围。The present invention will be described in detail below in conjunction with specific embodiments. The following examples will help those skilled in the art to further understand the present invention, but do not limit the present invention in any form. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention. These all belong to the protection scope of the present invention.
为了使本申请的目的、技术方案及优点更加清楚明白,以下结合实施例,对本申请进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本申请,并不用于限定本申请。In order to make the purpose, technical solution and advantages of the present application clearer, the present application will be further described in detail below in conjunction with the embodiments. It should be understood that the specific embodiments described here are only used to explain the present application, not to limit the present application.
需要说明的是,如果不冲突,本发明实施例中的各个特征可以相互结合,均在本申请的保护范围之内。除非另有定义,本说明书所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本说明书中在本发明的说明书中所使用的术语只是为了描述具体的实施方式的目的,不是用于限制本发明。本说明书所使用的术语“和/或”包括一个或多个相关的所列项目的任意的和所有的组合。It should be noted that, if there is no conflict, various features in the embodiments of the present invention may be combined with each other, and all of them are within the protection scope of the present application. Unless otherwise defined, all technical and scientific terms used in this specification have the same meaning as commonly understood by one of ordinary skill in the technical field of the invention. The terminology used in the description of the present invention in this specification is only for the purpose of describing specific embodiments, and is not used to limit the present invention. The term "and/or" used in this specification includes any and all combinations of one or more of the associated listed items.
此外,下面所描述的本发明各个实施方式中所涉及到的技术特征只要彼此之间未构成冲突就可以相互组合。本发明中所述各原料除特殊说明外,均为现有公开已售产品。In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not constitute a conflict with each other. Each raw material described in the present invention is all existing publicly sold products unless otherwise specified.
实施例1Example 1
一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺3份、三聚氰胺12份、海泡石10份、石墨鳞片16份、导电剂5份、聚酰胺蜡粉12份、苯并三氮唑14份、三苯基膦15份、肌醇六磷酸酯12份、液体石蜡4份、四氟硼酸四乙基铵6份、触变剂4份、聚己内酯5份、聚乙烯吡咯烷酮14份、丁二醇缩水甘油醚18份、N-甲基吡咯烷酮10份、聚氨酯分散剂4份、颜填料5份、助溶剂4份、消泡剂2份。A high-temperature anti-corrosion coating, made of the following raw material components in parts by weight: 3 parts of sulfur polyimide, 12 parts of melamine, 10 parts of sepiolite, 16 parts of graphite flakes, 5 parts of conductive agent, polyamide wax powder 12 parts, 14 parts of benzotriazole, 15 parts of triphenylphosphine, 12 parts of phytic acid ester, 4 parts of liquid paraffin, 6 parts of tetraethylammonium tetrafluoroborate, 4 parts of thixotropic agent, polycaprolactone 5 parts of ester, 14 parts of polyvinylpyrrolidone, 18 parts of butanediol glycidyl ether, 10 parts of N-methylpyrrolidone, 4 parts of polyurethane dispersant, 5 parts of pigment and filler, 4 parts of co-solvent, 2 parts of defoamer.
实施步骤如下:The implementation steps are as follows:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为800r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 800r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为300r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into the dispersion tank, stir and disperse evenly under the stirring condition of the rotating speed of 300r/min, and obtain the mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
实施例2Example 2
一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺4份、三聚氰胺14份、海泡石12.5份、石墨鳞片18份、导电剂6.5份、聚酰胺蜡粉14份、苯并三氮唑17份、三苯基膦18.5份、肌醇六磷酸酯15份、液体石蜡6份、四氟硼酸四乙基铵9份、触变剂6份、聚己内酯7.5份、聚乙烯吡咯烷酮18份、丁二醇缩水甘油醚22份、N-甲基吡咯烷酮12份、聚氨酯分散剂5份、颜填料6.5份、助溶剂5份、消泡剂4份。A high-temperature anti-corrosion coating, made of the following raw material components in parts by weight: 4 parts of sulfur polyimide, 14 parts of melamine, 12.5 parts of sepiolite, 18 parts of graphite flakes, 6.5 parts of conductive agent, polyamide wax powder 14 parts, 17 parts of benzotriazole, 18.5 parts of triphenylphosphine, 15 parts of phytic acid ester, 6 parts of liquid paraffin, 9 parts of tetraethylammonium tetrafluoroborate, 6 parts of thixotropic agent, polycaprolactone 7.5 parts of ester, 18 parts of polyvinylpyrrolidone, 22 parts of butanediol glycidyl ether, 12 parts of N-methylpyrrolidone, 5 parts of polyurethane dispersant, 6.5 parts of pigment and filler, 5 parts of cosolvent, 4 parts of defoamer.
实施步骤如下:The implementation steps are as follows:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为1150r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 1150r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为400r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into the dispersion tank, stir and disperse evenly under the stirring condition of the rotating speed of 400r/min, and obtain the mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
实施例3Example 3
一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺5份、三聚氰胺16份、海泡石15份、石墨鳞片20份、导电剂8份、聚酰胺蜡粉16份、苯并三氮唑20份、三苯基膦22份、肌醇六磷酸酯18份、液体石蜡8份、四氟硼酸四乙基铵12份、触变剂8份、聚己内酯10份、聚乙烯吡咯烷酮22份、丁二醇缩水甘油醚26份、N-甲基吡咯烷酮14份、聚氨酯分散剂6份、颜填料8份、助溶剂6份、消泡剂6份。A high-temperature anti-corrosion coating, made of the following raw material components in parts by weight: 5 parts of sulfur polyimide, 16 parts of melamine, 15 parts of sepiolite, 20 parts of graphite flakes, 8 parts of conductive agent, polyamide wax powder 16 parts, 20 parts of benzotriazole, 22 parts of triphenylphosphine, 18 parts of phytic acid ester, 8 parts of liquid paraffin, 12 parts of tetraethylammonium tetrafluoroborate, 8 parts of thixotropic agent, polycaprolactone 10 parts of ester, 22 parts of polyvinylpyrrolidone, 26 parts of butanediol glycidyl ether, 14 parts of N-methylpyrrolidone, 6 parts of polyurethane dispersant, 8 parts of pigment and filler, 6 parts of cosolvent, and 6 parts of defoamer.
实施步骤如下:The implementation steps are as follows:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为1500r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 1500r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为500r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into a dispersion tank, stir and disperse evenly under the stirring condition of a rotating speed of 500r/min, and obtain a mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
实施例4Example 4
一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺3.5份、三聚氰胺13份、海泡石11份、石墨鳞片17份、导电剂6份、聚酰胺蜡粉13份、苯并三氮唑15份、三苯基膦16份、肌醇六磷酸酯13份、液体石蜡5份、四氟硼酸四乙基铵7份、触变剂5份、聚己内酯6份、聚乙烯吡咯烷酮15份、丁二醇缩水甘油醚19份、N-甲基吡咯烷酮11份、聚氨酯分散剂4.5份、颜填料6份、助溶剂4.5份、消泡剂3份。A high-temperature anti-corrosion coating, made of the following raw material components in parts by weight: 3.5 parts of sulfur polyimide, 13 parts of melamine, 11 parts of sepiolite, 17 parts of graphite flakes, 6 parts of conductive agent, polyamide wax powder 13 parts, 15 parts of benzotriazole, 16 parts of triphenylphosphine, 13 parts of phytic acid ester, 5 parts of liquid paraffin, 7 parts of tetraethylammonium tetrafluoroborate, 5 parts of thixotropic agent, polycaprolactone 6 parts of ester, 15 parts of polyvinylpyrrolidone, 19 parts of butanediol glycidyl ether, 11 parts of N-methylpyrrolidone, 4.5 parts of polyurethane dispersant, 6 parts of pigment and filler, 4.5 parts of co-solvent, 3 parts of defoamer.
实施步骤如下:The implementation steps are as follows:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为900r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 900r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为350r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into the dispersion tank, stir and disperse evenly under the stirring condition of the rotating speed of 350r/min, and obtain the mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
实施例5Example 5
一种高温防腐涂层,由以下重量份的原料组分制成:硫聚酰亚胺4.5份、三聚氰胺15份、海泡石14.5份、石墨鳞片19份、导电剂7份、聚酰胺蜡粉15份、苯并三氮唑19份、三苯基膦20份、肌醇六磷酸酯17份、液体石蜡7份、四氟硼酸四乙基铵11份、触变剂7份、聚己内酯9份、聚乙烯吡咯烷酮20份、丁二醇缩水甘油醚25份、N-甲基吡咯烷酮13份、聚氨酯分散剂5.5份、颜填料7份、助溶剂5.5份、消泡剂5份。A high-temperature anti-corrosion coating, made of the following raw material components by weight: 4.5 parts of sulfur polyimide, 15 parts of melamine, 14.5 parts of sepiolite, 19 parts of graphite flakes, 7 parts of conductive agent, polyamide wax powder 15 parts, 19 parts of benzotriazole, 20 parts of triphenylphosphine, 17 parts of phytic acid ester, 7 parts of liquid paraffin, 11 parts of tetraethylammonium tetrafluoroborate, 7 parts of thixotropic agent, polycaprolactone 9 parts of ester, 20 parts of polyvinylpyrrolidone, 25 parts of butanediol glycidyl ether, 13 parts of N-methylpyrrolidone, 5.5 parts of polyurethane dispersant, 7 parts of pigment and filler, 5.5 parts of cosolvent, and 5 parts of defoamer.
实施步骤如下:The implementation steps are as follows:
步骤1:按配方称取硫聚酰亚胺、三聚氰胺、海泡石、石墨鳞片、导电剂、聚酰胺蜡粉、苯并三氮唑、三苯基膦、肌醇六磷酸酯、液体石蜡、四氟硼酸四乙基铵、触变剂、聚己内酯、聚乙烯吡咯烷酮、丁二醇缩水甘油醚、N-甲基吡咯烷酮;Step 1: Weigh sulfur polyimide, melamine, sepiolite, graphite flakes, conductive agent, polyamide wax powder, benzotriazole, triphenylphosphine, phytate, liquid paraffin, Tetraethylammonium tetrafluoroborate, thixotropic agent, polycaprolactone, polyvinylpyrrolidone, butanediol glycidyl ether, N-methylpyrrolidone;
步骤2:将步骤1称取的原料加入分散罐中,在转速为1400r/min的条件下搅拌分散均匀,得到混合物A;Step 2: Add the raw materials weighed in step 1 into a dispersion tank, stir and disperse evenly under the condition of a rotating speed of 1400r/min, and obtain a mixture A;
步骤3:按配方称取聚氨酯分散剂、颜填料、助溶剂、消泡剂;Step 3: Weigh polyurethane dispersants, pigments and fillers, cosolvents, and defoamers according to the formula;
步骤4:将步骤3中的原料加入分散罐中,在转速为400r/min的搅拌条件下搅拌分散均匀,得到混合物B;Step 4: Add the raw materials in step 3 into the dispersion tank, stir and disperse evenly under the stirring condition of the rotating speed of 400r/min, and obtain the mixture B;
步骤5:将混合物B加入到混合物A中,混合均匀,即得高温防腐涂层。Step 5: Add mixture B to mixture A and mix evenly to obtain a high temperature anti-corrosion coating.
涂抹试验:取样品1-5,分别进行涂抹试验,试验过程为取一样的金属板进行涂抹,将金属板6面涂抹完全,每个试验中,五个样品分别粉刷相近的厚度,其中,第一种试验,底漆厚度300-350微米和面漆厚度400-450微米;第二种试验,底漆厚度350-400微米和面漆厚度450-500微米;第三种试验,底漆厚度300-350微米和面漆厚度500-550微米;第四种试验,底漆厚度350-400微米和面漆厚度550-600微米;第五种试验,底漆厚度380-420微米和面漆厚度580-600微米;Smearing test: Take samples 1-5 and carry out smearing tests respectively. The test process is to take the same metal plate for smearing, and 6 sides of the metal plate are completely smeared. In each test, five samples are painted with similar thicknesses. Among them, the first One test, primer thickness 300-350 microns and top coat thickness 400-450 microns; second test, primer thickness 350-400 microns and top coat thickness 450-500 microns; third test, primer thickness 300 -350 microns and topcoat thickness 500-550 microns; fourth test, primer thickness 350-400 microns and top coat thickness 550-600 microns; fifth test, primer thickness 380-420 microns and top coat thickness 580 -600 microns;
耐盐雾测试:涂抹试验得到多个金属板,按照GB/T1771-2007进行耐盐雾测试,持续时间为5000h,检测金属板上,所有采用现有涂层的金属板上都有起泡和裂缝。所有样品采用实施例1-5职工的涂层的金属板,都无开裂和起泡。再继续试验,持续时间达到6000h后,实施例1和实施例5中的金属板上面涂层已出现裂缝,但底涂层已然完好,而其他的金属板都无开裂和起泡;当持续时间达到8000h后,实施例1、实施例3-5中的金属板的面涂层都已出现起泡和开裂,但所有样品的底涂层完好;当持续时间达到10000h后,实施例1-5中的金属板的底涂层依然完好。Salt spray resistance test: multiple metal plates were obtained from the smear test, and the salt spray test was carried out in accordance with GB/T1771-2007. The duration was 5000h. The metal plates were tested, and all the metal plates with existing coatings had blisters and crack. All samples were free from cracking and blistering using the coated metal panels of Examples 1-5. Continue the test again, after the duration reaches 6000h, cracks have occurred in the coating on the metal plate in embodiment 1 and embodiment 5, but the undercoat is intact, and other metal plates are all without cracking and foaming; when the duration After reaching 8000h, foaming and cracking all occurred in the top coat of metal plate in embodiment 1, embodiment 3-5, but the undercoat of all samples is intact; When the duration reaches 10000h, embodiment 1-5 The base coat of the metal plate is still intact.
耐盐酸、硫酸性能,再取涂抹试验中得到的多个金属板,按照SY/T0319-2012标准进行,温度为60°,时间持续1000h,检测金属板上,所有采用现有涂层的金属板上都有起泡和脱落。所有样品采用实施例1-5职工的涂层的金属板,都无开裂和起泡。当持续时间达到2000h后,所有样品采用实施例1-5职工的涂层的金属板都已出现起泡和开裂,但底涂层完好;当持续时间达到5000h后,所有实施例中的底涂层依然完好。Resistance to hydrochloric acid and sulfuric acid, take a number of metal plates obtained in the smearing test, according to the SY/T0319-2012 standard, the temperature is 60°, the time lasts 1000h, and the metal plates are tested. All metal plates with existing coatings Blisters and flakes all over. All samples were free from cracking and blistering using the coated metal panels of Examples 1-5. After the duration reaches 2000h, all samples adopt the metal plate of embodiment 1-5 worker's coating to all appear foaming and cracking, but the primer is intact; When the duration reaches 5000h, the primer in all embodiments Layers are still intact.
耐碱性能,再取涂抹试验中得到的多个金属板,按照SY/T0319-2012标准进行,温度为60°,时间持续1000h,检测金属板上,所有采用现有涂层的金属板上都有起泡和脱落。所有样品采用实施例1-5职工的涂层的金属板,都无开裂和起泡。Alkali resistance, and then take a number of metal plates obtained in the smearing test, according to the SY/T0319-2012 standard, the temperature is 60°, the time lasts 1000h, and the metal plates are tested. All metal plates with existing coatings are tested. There is blistering and peeling. All samples were free from cracking and blistering using the coated metal panels of Examples 1-5.
当持续时间达到2000h后,所有样品采用实施例1-5职工的涂层的金属板都已出现起泡和开裂,但所有样品的底涂层完好;当持续时间达到5000h后,所有实施例中的金属板的底涂层依然完好。After the duration reaches 2000h, all samples adopt the metal plate of the coating of embodiment 1-5 worker to all appear blistering and cracking, but the undercoating of all samples is intact; After the duration reaches 5000h, in all embodiments The base coat of the metal plate is still intact.
具体地,参考下表,下表为本发明高温防腐涂层与现有的涂料的比较Specifically, with reference to the following table, the following table is a comparison between the high-temperature anti-corrosion coating of the present invention and existing coatings
从上表可以看出,本发明实施例1-5中得到的高温防腐涂层的性能明显优于现有的涂料。It can be seen from the above table that the performance of the high-temperature anti-corrosion coating obtained in Examples 1-5 of the present invention is obviously better than that of the existing coating.
下表为本发明高温防腐涂层与现有的涂料的比较Following table is the comparison of high temperature anticorrosion coating of the present invention and existing coating
从上表可以看出,本发明实施例1-5中得到的高温防腐涂层的硬度、耐冲击性、摩擦系数以及磨损量的性能均优于现有的涂料。It can be seen from the above table that the hardness, impact resistance, friction coefficient and abrasion performance of the high-temperature anti-corrosion coating obtained in Examples 1-5 of the present invention are all better than the existing coatings.
综上所述,本发明制备的高温防腐涂层具有自润滑、耐高温、耐腐蚀的性能,且制备方法简单,易操作,成本低,耐磨材料的组分简单、易于加工、利于推广。其中,硫聚酰亚胺和三聚氰胺的混合大大提高了防腐性能;采用海泡石作为耐高温无机填料,显著提高了涂料的耐火极限;采用石墨鳞片作为防腐蚀填料,能够阻挡和减缓腐蚀性介质向涂层中的渗透,显著提高了涂料的防腐蚀性能;采用聚己内酯可以用来改善丙烯酸、聚脂、环氧等树脂的柔韧性、低温耐冲击性、流动性和成型性等其耐热性(400℃以上)可达100h以上,同时防腐性(耐盐雾性≥2000h)不受影响。本发明的配方组成与制备工艺简单,减少了传统涂料所需的添加剂的使用以及复杂的工艺,降低了成本,保护了环境。In summary, the high-temperature anti-corrosion coating prepared by the present invention has the properties of self-lubrication, high temperature resistance, and corrosion resistance, and the preparation method is simple, easy to operate, and low in cost. The components of the wear-resistant material are simple, easy to process, and conducive to popularization. Among them, the mixture of sulfur polyimide and melamine greatly improves the anti-corrosion performance; the use of sepiolite as a high-temperature resistant inorganic filler significantly improves the fire resistance limit of the coating; the use of graphite flakes as an anti-corrosion filler can block and slow down corrosive media The penetration into the coating significantly improves the anti-corrosion performance of the coating; the use of polycaprolactone can be used to improve the flexibility, low-temperature impact resistance, fluidity and formability of acrylic, polyester, epoxy and other resins. The heat resistance (above 400°C) can reach more than 100h, while the corrosion resistance (salt spray resistance ≥ 2000h) is not affected. The formula composition and preparation process of the invention are simple, reduce the use of additives and complex processes required by traditional coatings, reduce costs and protect the environment.
需要说明的是,当本发明给出数值范围时,应理解,除非本发明另有说明,每个数值范围的两个端点以及两个端点之间任何一个数值均可选用。为了防止赘述,本发明的描述了优选的实施例及效果,尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例做出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。It should be noted that when the present invention gives a numerical range, it should be understood that, unless otherwise stated in the present invention, the two endpoints of each numerical range and any value between the two endpoints can be selected. In order to avoid redundant description, the present invention describes preferred embodiments and effects. Although the preferred embodiments of the present invention have been described, those skilled in the art can make these embodiments once they know the basic inventive concepts. Additional changes and modifications. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention.
以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-mentioned embodiments can be combined arbitrarily. To make the description concise, all possible combinations of the technical features in the above-mentioned embodiments are not described. However, as long as there is no contradiction in the combination of these technical features, should be considered as within the scope of this specification.
以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only express several implementation modes of the present invention, and the descriptions thereof are relatively specific and detailed, but should not be construed as limiting the patent scope of the invention. It should be noted that, for those skilled in the art, several modifications and improvements can be made without departing from the concept of the present invention, and these all belong to the protection scope of the present invention. Therefore, the protection scope of the patent for the present invention should be based on the appended claims.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.
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| CN102220085A (en) * | 2011-05-09 | 2011-10-19 | 东华大学 | Polyimide coating with high-temperature resistance and preparation method thereof |
| CN102838907A (en) * | 2012-08-24 | 2012-12-26 | 华南理工大学 | Waterborne ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN103509429A (en) * | 2013-09-17 | 2014-01-15 | 浙江天蓝环保技术股份有限公司 | Anticorrosive paint with good oxidation resistance and acid-base corrosion resistance as well as preparation method thereof |
| CN105131792A (en) * | 2015-09-30 | 2015-12-09 | 高碑店市安普特种防火材料制造有限公司 | Intumescent type multifunctional fire retardant coating containing nano-graphite sheets |
| CN110540788A (en) * | 2019-08-29 | 2019-12-06 | 洛阳双瑞防腐工程技术有限公司 | Heat-resistant epoxy anticorrosive paint and preparation method thereof |
| CN113278340A (en) * | 2021-05-12 | 2021-08-20 | 中环海化(厦门)船舶智能涂料有限公司 | Anti-aging long-acting anticorrosive paint for charging piles in coastal areas and preparation method thereof |
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2023
- 2023-05-30 CN CN202310623756.0A patent/CN116606576A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102220085A (en) * | 2011-05-09 | 2011-10-19 | 东华大学 | Polyimide coating with high-temperature resistance and preparation method thereof |
| CN102838907A (en) * | 2012-08-24 | 2012-12-26 | 华南理工大学 | Waterborne ultra-thin steel structure fire retardant coating and preparation method thereof |
| CN103509429A (en) * | 2013-09-17 | 2014-01-15 | 浙江天蓝环保技术股份有限公司 | Anticorrosive paint with good oxidation resistance and acid-base corrosion resistance as well as preparation method thereof |
| CN105131792A (en) * | 2015-09-30 | 2015-12-09 | 高碑店市安普特种防火材料制造有限公司 | Intumescent type multifunctional fire retardant coating containing nano-graphite sheets |
| CN110540788A (en) * | 2019-08-29 | 2019-12-06 | 洛阳双瑞防腐工程技术有限公司 | Heat-resistant epoxy anticorrosive paint and preparation method thereof |
| CN113278340A (en) * | 2021-05-12 | 2021-08-20 | 中环海化(厦门)船舶智能涂料有限公司 | Anti-aging long-acting anticorrosive paint for charging piles in coastal areas and preparation method thereof |
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