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CN116559685A - Method, detection device and readable storage medium for characterizing reactivity of chemical system - Google Patents

Method, detection device and readable storage medium for characterizing reactivity of chemical system Download PDF

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Publication number
CN116559685A
CN116559685A CN202310445359.9A CN202310445359A CN116559685A CN 116559685 A CN116559685 A CN 116559685A CN 202310445359 A CN202310445359 A CN 202310445359A CN 116559685 A CN116559685 A CN 116559685A
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charge
discharge
reactivity
energy efficiency
multiplying power
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CN116559685B (en
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李勇君
蒋治亿
魏思伟
汪泉
万海成
曹剑蓉
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Trina Energy Storage Solutions Jiangsu Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/385Arrangements for measuring battery or accumulator variables
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The invention provides a method for characterizing the reactivity of a chemical system, a detection device and a readable storage medium. Wherein the method for characterizing the reactivity of the chemical system comprises the following steps: charging batteries of various chemical systems at different temperatures and with different charge and discharge multiplying powers; acquiring energy efficiency and a charging and discharging window; and judging the reactivity of the chemical system according to the relation between the charge-discharge multiplying power and the energy efficiency and the relation between the temperature and the charge-discharge window, and obtaining the optimal charge-discharge multiplying power. The reaction activity of the chemical system is judged through the relation between the multiplying power and the energy efficiency by carrying out experimental exploration on the energy efficiency change rules of batteries with various capacities under different temperature conditions and different charge and discharge multiplying powers. Through the exploration of the charge-discharge rule, the battery cell is in the optimal temperature in the subsequent practical use condition, the charge-discharge multiplying power is lower than that of a charge window, the lithium precipitation condition is reduced, the battery cell is in a good running state, the working efficiency is improved, and the service life is prolonged.

Description

表征化学体系反应活性的方法、检测装置及可读存储介质Method, detection device and readable storage medium for characterizing reactivity of chemical system

技术领域technical field

本发明涉及锂电池领域,具体涉及一种表征化学体系反应活性的方法、检测装置及可读存储介质。The invention relates to the field of lithium batteries, in particular to a method for characterizing the reaction activity of a chemical system, a detection device and a readable storage medium.

背景技术Background technique

锂离子电池具有良好的安全性能和卓越的循环性能,并且使用性能稳定,已经在动力电池和储能电池市场中大规模应用,随着应用场景的变化,对其性能要求也有所不同。不同的充放电倍率会对电池的循环性能和能量效率产生重大的影响。一方面需要有足够高的充放电速度,另一方面也需要考虑电池的寿命和成本。Lithium-ion batteries have good safety performance, excellent cycle performance, and stable performance. They have been widely used in the power battery and energy storage battery markets. As the application scenarios change, their performance requirements are also different. Different charge and discharge rates will have a significant impact on the cycle performance and energy efficiency of the battery. On the one hand, it needs to have a sufficiently high charging and discharging speed, on the other hand, it also needs to consider the battery life and cost.

为了提高充电速度,现有的充电方案主要分为两种,一是通过提高初始充放倍率,二是提高截止充电电压。这两种方案在提高充电速度的同时,也对电芯的使用寿命造成一定影响,提高了使用成本。因此,探究充放电倍率与能效的关系也就变得至关重要。In order to increase the charging speed, the existing charging schemes are mainly divided into two types, one is to increase the initial charge-discharge rate, and the other is to increase the cut-off charging voltage. While these two solutions increase the charging speed, they also have a certain impact on the service life of the battery cell, which increases the cost of use. Therefore, it is very important to explore the relationship between the charge-discharge rate and energy efficiency.

上述问题是目前亟待解决的。The above-mentioned problems are urgently to be solved at present.

发明内容Contents of the invention

本发明的目的是提供表征化学体系反应活性的方法、检测装置及可读存储介质。The purpose of the present invention is to provide a method for characterizing the reactivity of a chemical system, a detection device and a readable storage medium.

为了解决上述技术问题,本发明提供了一种表征化学体系反应活性的方法,包括:In order to solve the above technical problems, the invention provides a method for characterizing the reactivity of a chemical system, comprising:

对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电;Charge batteries with various chemical systems at different temperatures and at different charge and discharge rates;

获取能量效率及充放电窗口;Obtain energy efficiency and charge and discharge window;

依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。According to the relationship between charge and discharge rate and energy efficiency, temperature and charge and discharge window, the reactivity of the chemical system is judged to obtain the best charge and discharge rate.

进一步的,所述对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电的步骤包括:Further, the step of charging batteries of various chemical systems at different temperatures with different charge-discharge rates includes:

对多种化学体系在恒温条件下,由高到低调节充放电倍率,测试其能量效率;For a variety of chemical systems under constant temperature conditions, adjust the charge and discharge rate from high to low, and test their energy efficiency;

对三电极电池在不同温度下,由低到高调节充放电倍率,获取充放电窗口。For the three-electrode battery at different temperatures, adjust the charge and discharge rate from low to high to obtain the charge and discharge window.

进一步的,所述充放电倍率与能量效率的关系的获取步骤包括:Further, the step of obtaining the relationship between the charge-discharge rate and energy efficiency includes:

依据充放电倍率和能量效率进行作图;Draw the graph according to the charge and discharge rate and energy efficiency;

获取不同化学体系的能量效率变化曲线;Obtain energy efficiency curves of different chemical systems;

依据斜率的绝对值大小对反应活性进行判断。The reactivity was judged according to the absolute value of the slope.

进一步的,所述依据斜率的绝对值大小对反应活性进行判断的步骤,即:Further, the step of judging the reactivity according to the absolute value of the slope is:

斜率绝对值越大,表明电流密度对能量效率影响越大,放映活性越差。The larger the absolute value of the slope, the greater the influence of the current density on the energy efficiency and the worse the projection activity.

进一步的,所述温度与充放电窗口的关系的获取步骤包括:Further, the step of obtaining the relationship between the temperature and the charge and discharge window includes:

以电池剩余容量和充放电窗口作图;Draw a graph based on the remaining capacity of the battery and the charging and discharging window;

获取不同温度的充放电窗口的变化曲线;Obtain the change curve of the charging and discharging window at different temperatures;

依据充放电窗口的变化曲线,确定不同温度下的充放电倍率。According to the change curve of the charge and discharge window, determine the charge and discharge rate at different temperatures.

进一步的,所述依据充放电窗口的变化曲线,确定不同温度下的充放电倍率的步骤包括:Further, the step of determining the charge-discharge rate at different temperatures according to the change curve of the charge-discharge window includes:

使充放电倍率始终低于充放电窗口。Make the charge and discharge rate always lower than the charge and discharge window.

进一步的,所述依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率的步骤包括:Further, the reactivity of the chemical system is judged based on the relationship between charge and discharge rate and energy efficiency, temperature and charge and discharge window, and the step of obtaining the best charge and discharge rate includes:

根据电池剩余容量,获取低于充放电窗口的充放电倍率的范围;According to the remaining capacity of the battery, obtain the range of the charge-discharge rate lower than the charge-discharge window;

在充放电倍率的范围内,选取最佳充放电倍率;In the range of charge and discharge rate, select the best charge and discharge rate;

跟随电池剩余容量的变化,选取对应的最佳充放电倍率,从而时电池在充电时,化学体系反应活性最高。Following the change of the remaining capacity of the battery, select the corresponding optimal charge and discharge rate, so that when the battery is charging, the chemical system has the highest reactivity.

本发明还提供了一种表征化学体系反应活性的检测装置,包括:The present invention also provides a detection device for characterizing the reactivity of a chemical system, comprising:

充电模块,适于对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电;The charging module is suitable for charging batteries of various chemical systems at different temperatures and at different charge and discharge rates;

获取模块,适于能量效率及充放电窗口。Acquisition module, suitable for energy efficiency and charge and discharge window.

分析模块,适于依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。The analysis module is suitable for judging the reactivity of the chemical system based on the relationship between charge and discharge rate and energy efficiency, temperature and charge and discharge window, and obtaining the best charge and discharge rate.

本发明还提供了一种计算机可读存储介质,所述计算机可读存储介质中存储至少一条指令,所述指令由处理器执行时实现上述的表征化学体系反应活性的方法。The present invention also provides a computer-readable storage medium, wherein at least one instruction is stored in the computer-readable storage medium, and the above-mentioned method for characterizing the reactivity of a chemical system is realized when the instruction is executed by a processor.

本发明还提供了一种电子设备,包括存储器和处理器;所述存储器中存储有至少一条指令;所述处理器,通过加载并执行所述至少一条指令以实现上述的表征化学体系反应活性的方法。The present invention also provides an electronic device, including a memory and a processor; at least one instruction is stored in the memory; and the processor, by loading and executing the at least one instruction, realizes the above-mentioned method of characterizing the reactivity of a chemical system method.

本发明的有益效果是,本发明提供了一种表征化学体系反应活性的方法、检测装置及可读存储介质。其中,表征化学体系反应活性的方法包括:对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电;获取能量效率及充放电窗口;依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。通过对多种容量的电池在不同温度条件下,不同充放电倍率的能效变化规律进行实验探究,通过倍率与能效的关系来判断出化学体系的反应活性。随着电流密度的增大,倍率增加,其能量效率逐渐降低。通过对充放电规律的探索,使得电芯在后续的实际使用条件中,处于最佳的温度,充放电倍率低于充电窗口,减少析锂情况,电芯处在良好的运行状态,提高工作效率,增加使用寿命。The beneficial effect of the present invention is that the present invention provides a method for characterizing the reactivity of a chemical system, a detection device and a readable storage medium. Among them, the methods for characterizing the reactivity of chemical systems include: charging batteries of various chemical systems at different temperatures and at different charge-discharge rates; obtaining energy efficiency and charge-discharge window; The relationship between the discharge window is used to judge the reactivity of the chemical system to obtain the best charge and discharge rate. Through the experimental exploration of the energy efficiency change law of different charge and discharge rates of batteries with various capacities under different temperature conditions, the reactivity of the chemical system can be judged through the relationship between the rate and energy efficiency. As the current density increases, the rate increases and its energy efficiency decreases gradually. Through the exploration of the law of charge and discharge, the battery core is at the best temperature in the subsequent actual use conditions, the charge and discharge rate is lower than the charging window, and the situation of lithium precipitation is reduced, the battery core is in a good operating state, and the work efficiency is improved. , increase the service life.

附图说明Description of drawings

下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1是本发明实施例所提供的表征化学体系反应活性的方法的流程图。Fig. 1 is a flowchart of a method for characterizing the reactivity of a chemical system provided by an embodiment of the present invention.

图2是本发明实施例所提供的充放电倍率与能量效率的关系图。Fig. 2 is a graph showing the relationship between charge and discharge rate and energy efficiency provided by the embodiment of the present invention.

图3是本发明实施例所提供的温度与充放电窗口的关系图。Fig. 3 is a graph showing the relationship between temperature and charging and discharging window provided by the embodiment of the present invention.

图4是本发明实施例所提供的表征化学体系反应活性的检测装置的原理框图。Fig. 4 is a schematic block diagram of a detection device for characterizing the reactivity of a chemical system provided by an embodiment of the present invention.

图5是本发明实施例所提供的电子设备的部分原理框图。Fig. 5 is a partial functional block diagram of an electronic device provided by an embodiment of the present invention.

具体实施方式Detailed ways

现在结合附图对本发明作进一步详细的说明。这些附图均为简化的示意图,仅以示意方式说明本发明的基本结构,因此其仅显示与本发明有关的构成。The present invention is described in further detail now in conjunction with accompanying drawing. These drawings are all simplified schematic diagrams, which only illustrate the basic structure of the present invention in a schematic manner, so they only show the configurations related to the present invention.

实施例1Example 1

请参阅图1,本实施例提供了一种表征化学体系反应活性的方法,随着电流密度的增大,倍率增加,其能量效率逐渐降低。通过对充放电规律的探索,使得电芯在后续的实际使用条件中,处于最佳的温度,充放电倍率低于充电窗口,减少析锂情况,电芯处在良好的运行状态,提高工作效率,增加使用寿命。Please refer to Figure 1. This example provides a method for characterizing the reactivity of a chemical system. As the current density increases, the rate increases and its energy efficiency decreases gradually. Through the exploration of the law of charge and discharge, the battery core is at the best temperature in the subsequent actual use conditions, the charge and discharge rate is lower than the charging window, and the situation of lithium precipitation is reduced, the battery core is in a good operating state, and the work efficiency is improved. , increase the service life.

在本实施例中,表征化学体系反应活性的方法包括:In this embodiment, the methods for characterizing the reactivity of chemical systems include:

S110:对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电。S110: Charge batteries of various chemical systems at different temperatures and at different charge and discharge rates.

具体来说,步骤S110包括以下步骤:Specifically, step S110 includes the following steps:

S111:对多种化学体系在恒温条件下,由高到低调节充放电倍率,测试其能量效率。S111: Under constant temperature conditions, adjust the charge and discharge rate from high to low for various chemical systems, and test their energy efficiency.

以几种化学体系进行多倍率充放电,以巴伏公式为基础,在强极化作用下符合塔菲尔公式η=a+blgic,呈对数关系,弱极化作用下符合η=RT/iF×ic,呈线性关系,探究充放电倍率与能效之间的关系,能够判断出不同化学体系的反应活性高低,但其能效极值均在98%左右,随着充放电倍率的增加,能效逐渐较小。Several chemical systems are used for multi-rate charge and discharge, based on Bavot's formula, under strong polarization, it conforms to Tafel's formula η=a+blgic, which is logarithmic, and under weak polarization, it conforms to η=RT/ If the relationship between iF × ic is linear, exploring the relationship between charge and discharge rate and energy efficiency can determine the reactivity of different chemical systems, but the extreme value of energy efficiency is around 98%. With the increase of charge and discharge rate, the energy efficiency Gradually smaller.

S112:对三电极电池在不同温度下,由低到高调节充放电倍率,获取充放电窗口。S112: For the three-electrode battery at different temperatures, adjust the charge and discharge rate from low to high to obtain a charge and discharge window.

S120:获取能量效率及充放电窗口。S120: Obtain energy efficiency and a charging and discharging window.

具体来说,将能量效率、及对应的充放电倍率、化学体系输入到作图工具中,将充放电窗口对应的充放电倍率,温度条件以及电池剩余容量输入到作图工具中,该工具,可以是但不仅限于PC,移动端。Specifically, input the energy efficiency, the corresponding charge-discharge rate, and chemical system into the drawing tool, and input the charge-discharge rate corresponding to the charge-discharge window, temperature conditions, and remaining capacity of the battery into the drawing tool. The tool, Can be but not limited to PC, mobile terminal.

S130:依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。S130: Judging the reactivity of the chemical system according to the relationship between charge and discharge rate and energy efficiency, temperature and charge and discharge window, and obtaining an optimal charge and discharge rate.

其中,所述充放电倍率与能量效率的关系的获取步骤包括:依据充放电倍率和能量效率进行作图;获取不同化学体系的能量效率变化曲线;依据斜率的绝对值大小对反应活性进行判断。其中,斜率绝对值越大,表明电流密度对能量效率影响越大,放映活性越差。Wherein, the obtaining step of the relationship between the charge-discharge rate and energy efficiency includes: drawing a graph according to the charge-discharge rate and energy efficiency; obtaining energy efficiency change curves of different chemical systems; judging the reactivity according to the absolute value of the slope. Among them, the greater the absolute value of the slope, the greater the impact of the current density on the energy efficiency and the worse the projection activity.

具体来说,借助2Ah 50Ah 100Ah 150Ah 280Ah 300Ah的化学体系(如图2所示),在高低温箱中,25℃恒温条件下,由高到低调节充放电倍率,测试其能量效率,然后对其充放电倍率和能效进行作图,根据斜率的绝对值大小来判断反应活性的高低,斜率绝对值越大,表明电流密度对能效影响越大,反应活性越差,随着充放电倍率的增加,其能效也逐渐减小,并且几种不同化学体系的能效极值均在98%左右。Specifically, with the help of the chemical system of 2Ah 50Ah 100Ah 150Ah 280Ah 300Ah (as shown in Figure 2), in a high-low temperature box, under a constant temperature of 25°C, adjust the charge-discharge rate from high to low, test its energy efficiency, and then test the The charge-discharge rate and energy efficiency are plotted, and the reactivity is judged according to the absolute value of the slope. The larger the absolute value of the slope, the greater the impact of the current density on the energy efficiency and the worse the reactivity. With the increase of the charge-discharge rate , its energy efficiency also decreases gradually, and the extreme values of energy efficiency of several different chemical systems are all around 98%.

其中,所述温度与充放电窗口的关系的获取步骤包括:以电池剩余容量和充放电窗口作图;获取不同温度的充放电窗口的变化曲线;依据充放电窗口的变化曲线,确定不同温度下的充放电倍率,即,使充放电倍率始终低于充放电窗口。Wherein, the step of obtaining the relationship between the temperature and the charge-discharge window includes: plotting the remaining capacity of the battery and the charge-discharge window; obtaining the change curve of the charge-discharge window at different temperatures; according to the change curve of the charge-discharge window, determine The charge and discharge rate, that is, the charge and discharge rate is always lower than the charge and discharge window.

具体来说,借助三电极电池在不同温度下(30℃,25℃,15℃,5℃,0℃,-5℃,-10℃,-20℃),由低到高低调节充放电倍率,探究不同温度不同充放电倍率时其充放电窗口,得到最佳的充放电条件,避免析锂现象,从而使得电芯的能量保持率处在较高水平,增加使用寿命。Specifically, with the help of a three-electrode battery at different temperatures (30°C, 25°C, 15°C, 5°C, 0°C, -5°C, -10°C, -20°C), the charge-discharge rate is adjusted from low to high, Explore the charge-discharge window at different temperatures and different charge-discharge rates to obtain the best charge-discharge conditions and avoid lithium precipitation, so that the energy retention rate of the battery cell is at a high level and the service life is increased.

如图3所示,随着电池剩余容量的增加,充电窗口逐渐缩小,不同主材的充电窗口也出现一定的差异。As shown in Figure 3, as the remaining capacity of the battery increases, the charging window gradually shrinks, and there are also certain differences in the charging window of different main materials.

其中,获取最佳充放电倍率的步骤包括:根据电池剩余容量,获取低于充放电窗口的充放电倍率的范围;在充放电倍率的范围内,选取最佳充放电倍率;跟随电池剩余容量的变化,选取对应的最佳充放电倍率,从而时电池在充电时,化学体系反应活性最高。Wherein, the step of obtaining the best charge and discharge rate includes: according to the remaining capacity of the battery, obtain the range of the charge and discharge rate lower than the charge and discharge window; within the range of the charge and discharge rate, select the best charge and discharge rate; follow the remaining capacity of the battery Change, select the corresponding optimal charge and discharge rate, so that when the battery is charging, the chemical system has the highest reactivity.

由于电池的直流内阻在前期由于活化作用发生下降,后期固体电解质相界面发生分解,阻抗逐渐增加,导致析锂窗口随着使用时间延长不断的收窄,当窗口低于实际使用的充放电倍率时,负极界面将会出现析锂,活性锂的损失速率将会不断的加快,电池的容量和能量保持率将迅速下降达到截止SOH。SOH是指电池的健康状态。它包括两部分:安时容量和功率的变化。一般认为:当安时容量衰减20%或者输出功率衰减25%时,电池的寿命就到了。Since the DC internal resistance of the battery decreases due to activation in the early stage, the phase interface of the solid electrolyte decomposes in the later stage, and the impedance gradually increases, resulting in the continuous narrowing of the lithium analysis window with the prolongation of use time. When the window is lower than the actual charge and discharge rate When the negative electrode interface will appear lithium precipitation, the loss rate of active lithium will continue to accelerate, the capacity and energy retention rate of the battery will drop rapidly to reach the cut-off SOH. SOH refers to the state of health of the battery. It includes two parts: ampere-hour capacity and power changes. It is generally believed that when the ampere-hour capacity decays by 20% or the output power decays by 25%, the battery life is over.

因此,本实施例通过对高低温及充放电规律的探究,可以选择更加良好的充放电制度,使得实际的充放电倍率始终低于充放电窗口,在不同的电池剩余容量时可以采用不同的充电倍率,提高充电倍率的同时又能避免析锂,也可以使得最大充电倍率始终低于100%SOC时对应的倍率,从而电芯的容量和能量保持率保持在较高水平,从而增加电芯的使用寿命,降低使用成本。Therefore, in this embodiment, by exploring the high and low temperature and the law of charging and discharging, a better charging and discharging system can be selected, so that the actual charging and discharging rate is always lower than the charging and discharging window, and different charging and discharging methods can be used when the remaining capacity of the battery is different. The rate can increase the charge rate while avoiding lithium deposition, and can also make the maximum charge rate always lower than the rate corresponding to 100% SOC, so that the capacity and energy retention rate of the battery cell remain at a high level, thereby increasing the battery life. Long service life, reduce the cost of use.

实施例2Example 2

请参阅图4,本实施例提供了一种表征化学体系反应活性的检测装置,包括:充电模块,获取模块以及分析模块。Please refer to FIG. 4 , this embodiment provides a detection device for characterizing the reactivity of a chemical system, including: a charging module, an acquisition module and an analysis module.

其中,充电模块,适于对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电。具体来说,充电模块用于执行步骤S110:对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电。Among them, the charging module is suitable for charging batteries of various chemical systems at different temperatures and at different charge and discharge rates. Specifically, the charging module is used to perform step S110: charging batteries of various chemical systems at different temperatures and at different charge and discharge rates.

具体来说,步骤S110包括以下步骤:Specifically, step S110 includes the following steps:

S111:对多种化学体系在恒温条件下,由高到低调节充放电倍率,测试其能量效率。S111: Under constant temperature conditions, adjust the charge and discharge rate from high to low for various chemical systems, and test their energy efficiency.

以几种化学体系进行多倍率充放电,以巴伏公式为基础,在强极化作用下符合塔菲尔公式η=a+blgic,呈对数关系,弱极化作用下符合η=RT/iF×ic,呈线性关系,探究充放电倍率与能效之间的关系,能够判断出不同化学体系的反应活性高低,但其能效极值均在98%左右,随着充放电倍率的增加,能效逐渐较小。Several chemical systems are used for multi-rate charge and discharge, based on Bavot's formula, under strong polarization, it conforms to Tafel's formula η=a+blgic, which is logarithmic, and under weak polarization, it conforms to η=RT/ If the relationship between iF × ic is linear, exploring the relationship between charge and discharge rate and energy efficiency can determine the reactivity of different chemical systems, but the extreme value of energy efficiency is around 98%. With the increase of charge and discharge rate, the energy efficiency Gradually smaller.

S112:对三电极电池在不同温度下,由低到高调节充放电倍率,获取充放电窗口。S112: For the three-electrode battery at different temperatures, adjust the charge and discharge rate from low to high to obtain a charge and discharge window.

获取模块,适于能量效率及充放电窗口。在本实施例中,获取模块适于执行步骤S120:获取能量效率及充放电窗口。Acquisition module, suitable for energy efficiency and charge and discharge window. In this embodiment, the obtaining module is adapted to perform step S120: obtaining the energy efficiency and the charging and discharging window.

具体来说,将能量效率、及对应的充放电倍率、化学体系输入到作图工具中,将充放电窗口对应的充放电倍率,温度条件以及电池剩余容量输入到作图工具中,该工具,可以是但不仅限于PC,移动端。Specifically, input the energy efficiency, the corresponding charge-discharge rate, and chemical system into the drawing tool, and input the charge-discharge rate corresponding to the charge-discharge window, temperature conditions, and remaining capacity of the battery into the drawing tool. The tool, Can be but not limited to PC, mobile terminal.

分析模块,适于依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。具体来说,分析模块适于执行步骤S130:依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。The analysis module is suitable for judging the reactivity of the chemical system based on the relationship between charge and discharge rate and energy efficiency, temperature and charge and discharge window, and obtaining the best charge and discharge rate. Specifically, the analysis module is suitable for performing step S130: judging the reactivity of the chemical system according to the relationship between the charge-discharge rate and the energy efficiency, temperature and the charge-discharge window, and obtaining the optimal charge-discharge rate.

其中,所述充放电倍率与能量效率的关系的获取步骤包括:依据充放电倍率和能量效率进行作图;获取不同化学体系的能量效率变化曲线;依据斜率的绝对值大小对反应活性进行判断。其中,斜率绝对值越大,表明电流密度对能量效率影响越大,放映活性越差。Wherein, the obtaining step of the relationship between the charge-discharge rate and energy efficiency includes: drawing a graph according to the charge-discharge rate and energy efficiency; obtaining energy efficiency change curves of different chemical systems; judging the reactivity according to the absolute value of the slope. Among them, the greater the absolute value of the slope, the greater the impact of the current density on the energy efficiency and the worse the projection activity.

具体来说,借助2Ah 50Ah 100Ah 150Ah 280Ah 300Ah的化学体系(如图2所示),在高低温箱中,25℃恒温条件下,由高到低调节充放电倍率,测试其能量效率,然后对其充放电倍率和能效进行作图,根据斜率的绝对值大小来判断反应活性的高低,斜率绝对值越大,表明电流密度对能效影响越大,反应活性越差,随着充放电倍率的增加,其能效也逐渐减小,并且几种不同化学体系的能效极值均在98%左右。Specifically, with the help of the chemical system of 2Ah 50Ah 100Ah 150Ah 280Ah 300Ah (as shown in Figure 2), in a high-low temperature box, under a constant temperature of 25°C, adjust the charge-discharge rate from high to low, test its energy efficiency, and then test the The charge-discharge rate and energy efficiency are plotted, and the reactivity is judged according to the absolute value of the slope. The larger the absolute value of the slope, the greater the impact of the current density on the energy efficiency and the worse the reactivity. With the increase of the charge-discharge rate , its energy efficiency also decreases gradually, and the extreme values of energy efficiency of several different chemical systems are all around 98%.

其中,所述温度与充放电窗口的关系的获取步骤包括:以电池剩余容量和充放电窗口作图;获取不同温度的充放电窗口的变化曲线;依据充放电窗口的变化曲线,确定不同温度下的充放电倍率,即,使充放电倍率始终低于充放电窗口。Wherein, the step of obtaining the relationship between the temperature and the charge-discharge window includes: plotting the remaining capacity of the battery and the charge-discharge window; obtaining the change curve of the charge-discharge window at different temperatures; according to the change curve of the charge-discharge window, determine The charge and discharge rate, that is, the charge and discharge rate is always lower than the charge and discharge window.

具体来说,借助三电极电池在不同温度下(30℃,25℃,15℃,5℃,0℃,-5℃,-10℃,-20℃),由低到高低调节充放电倍率,探究不同温度不同充放电倍率时其充放电窗口,得到最佳的充放电条件,避免析锂现象,从而使得电芯的能量保持率处在较高水平,增加使用寿命。Specifically, with the help of a three-electrode battery at different temperatures (30°C, 25°C, 15°C, 5°C, 0°C, -5°C, -10°C, -20°C), the charge-discharge rate is adjusted from low to high, Explore the charge-discharge window at different temperatures and different charge-discharge rates to obtain the best charge-discharge conditions and avoid lithium precipitation, so that the energy retention rate of the battery cell is at a high level and the service life is increased.

如图3所示,随着电池剩余容量的增加,充电窗口逐渐缩小,不同主材的充电窗口也出现一定的差异。As shown in Figure 3, as the remaining capacity of the battery increases, the charging window gradually shrinks, and there are also certain differences in the charging window of different main materials.

其中,获取最佳充放电倍率的步骤包括:根据电池剩余容量,获取低于充放电窗口的充放电倍率的范围;在充放电倍率的范围内,选取最佳充放电倍率;跟随电池剩余容量的变化,选取对应的最佳充放电倍率,从而时电池在充电时,化学体系反应活性最高。Wherein, the step of obtaining the best charge and discharge rate includes: according to the remaining capacity of the battery, obtain the range of the charge and discharge rate lower than the charge and discharge window; within the range of the charge and discharge rate, select the best charge and discharge rate; follow the remaining capacity of the battery Change, select the corresponding optimal charge and discharge rate, so that when the battery is charging, the chemical system has the highest reactivity.

由于电池的直流内阻在前期由于活化作用发生下降,后期固体电解质相界面发生分解,阻抗逐渐增加,导致析锂窗口随着使用时间延长不断的收窄,当窗口低于实际使用的充放电倍率时,负极界面将会出现析锂,活性锂的损失速率将会不断的加快,电池的容量和能量保持率将迅速下降达到截止SOH。SOH是指电池的健康状态。它包括两部分:安时容量和功率的变化。一般认为:当安时容量衰减20%或者输出功率衰减25%时,电池的寿命就到了。Since the DC internal resistance of the battery decreases due to activation in the early stage, the phase interface of the solid electrolyte decomposes in the later stage, and the impedance gradually increases, resulting in the continuous narrowing of the lithium analysis window with the prolongation of use time. When the window is lower than the actual charge and discharge rate When the negative electrode interface will appear lithium precipitation, the loss rate of active lithium will continue to accelerate, the capacity and energy retention rate of the battery will drop rapidly to reach the cut-off SOH. SOH refers to the state of health of the battery. It includes two parts: ampere-hour capacity and power changes. It is generally believed that when the ampere-hour capacity decays by 20% or the output power decays by 25%, the battery life is over.

因此,本实施例通过对高低温及充放电规律的探究,可以选择更加良好的充放电制度,使得实际的充放电倍率始终低于充放电窗口,在不同的电池剩余容量时可以采用不同的充电倍率,提高充电倍率的同时又能避免析锂,也可以使得最大充电倍率始终低于100%SOC时对应的倍率,从而电芯的容量和能量保持率保持在较高水平,从而增加电芯的使用寿命,降低使用成本。Therefore, in this embodiment, by exploring the high and low temperature and the law of charging and discharging, a better charging and discharging system can be selected, so that the actual charging and discharging rate is always lower than the charging and discharging window, and different charging and discharging methods can be used when the remaining capacity of the battery is different. The rate can increase the charge rate while avoiding lithium deposition, and can also make the maximum charge rate always lower than the rate corresponding to 100% SOC, so that the capacity and energy retention rate of the battery cell remain at a high level, thereby increasing the battery life. Longer service life, lower usage cost.

实施例3Example 3

本实施例提供了一种计算机可读存储介质,所述计算机可读存储介质中存储至少一条指令,所述指令由处理器执行时实现实施例1所提供的表征化学体系反应活性的方法。This embodiment provides a computer-readable storage medium, where at least one instruction is stored in the computer-readable storage medium, and when the instruction is executed by a processor, the method for characterizing the reactivity of a chemical system provided in Embodiment 1 is implemented.

表征化学体系反应活性的方法包括:对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电;获取能量效率及充放电窗口;依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。通过对多种容量的电池在不同温度条件下,不同充放电倍率的能效变化规律进行实验探究,通过倍率与能效的关系来判断出化学体系的反应活性。随着电流密度的增大,倍率增加,其能量效率逐渐降低。通过对充放电规律的探索,使得电芯在后续的实际使用条件中,处于最佳的温度,充放电倍率低于充电窗口,减少析锂情况,电芯处在良好的运行状态,提高工作效率,增加使用寿命。The methods for characterizing the reactivity of chemical systems include: charging batteries of various chemical systems at different temperatures and at different charge-discharge rates; obtaining energy efficiency and charge-discharge window; based on charge-discharge rate and energy efficiency, temperature and charge-discharge window To judge the reactivity of the chemical system and obtain the best charge and discharge rate. Through the experimental exploration of the energy efficiency change law of different charge and discharge rates of batteries with various capacities under different temperature conditions, the reactivity of the chemical system can be judged through the relationship between the rate and energy efficiency. As the current density increases, the rate increases and its energy efficiency decreases gradually. Through the exploration of the law of charge and discharge, the battery core is at the best temperature in the subsequent actual use conditions, the charge and discharge rate is lower than the charging window, and the situation of lithium precipitation is reduced, the battery core is in a good operating state, and the work efficiency is improved. , increase the service life.

实施例4Example 4

请参阅图5,本实施例提供了一种电子设备,包括:存储器502和处理器501;所述存储器502中存储有至少一条程序指令;所述处理器501,通过加载并执行所述至少一条程序指令以实现如实施例1所提供的多传感器融合车窗识别方法。Referring to FIG. 5 , this embodiment provides an electronic device, including: a memory 502 and a processor 501; at least one program instruction is stored in the memory 502; and the processor 501 loads and executes the at least one program instruction The program instructions are used to realize the multi-sensor fusion vehicle window recognition method provided in Embodiment 1.

存储器502和处理器501采用总线方式连接,总线可以包括任意数量的互联的总线和桥,总线将一个或多个处理器501和存储器502的各种电路连接在一起。总线还可以将诸如外围设备、稳压器和功率管理电路等之类的各种其他电路连接在一起,这些都是本领域所公知的,因此,本文不再对其进行进一步描述。总线接口在总线和收发机之间提供接口。收发机可以是一个元件,也可以是多个元件,比如多个接收器和发送器,提供用于在传输介质上与各种其他装置通信的单元。经处理器501处理的数据通过天线在无线介质上进行传输,进一步,天线还接收数据并将数据传送给处理器501。The memory 502 and the processor 501 are connected by a bus. The bus may include any number of interconnected buses and bridges. The bus connects one or more processors 501 and various circuits of the memory 502 together. The bus may also connect together various other circuits such as peripherals, voltage regulators, and power management circuits, all of which are well known in the art and therefore will not be further described herein. The bus interface provides an interface between the bus and the transceivers. A transceiver may be a single element or multiple elements, such as multiple receivers and transmitters, providing means for communicating with various other devices over a transmission medium. The data processed by the processor 501 is transmitted on the wireless medium through the antenna, and further, the antenna also receives the data and transmits the data to the processor 501 .

处理器501负责管理总线和通常的处理,还可以提供各种功能,包括定时,外围接口,电压调节、电源管理以及其他控制功能。而存储器502可以被用于存储处理器501在执行操作时所使用的数据。Processor 501 is responsible for managing the bus and general processing, and may also provide various functions including timing, peripheral interface, voltage regulation, power management and other control functions. And the memory 502 may be used to store data used by the processor 501 when performing operations.

综上所述,本发明提供了一种表征化学体系反应活性的方法、检测装置及可读存储介质。其中,表征化学体系反应活性的方法包括:对多种化学体系的电池在不同温度下,以不同充放电倍率进行充电;获取能量效率及充放电窗口;依据充放电倍率与能量效率、温度与充放电窗口的关系对化学体系的反应活性进行判断,获取最佳充放电倍率。通过对多种容量的电池在不同温度条件下,不同充放电倍率的能效变化规律进行实验探究,通过倍率与能效的关系来判断出化学体系的反应活性。随着电流密度的增大,倍率增加,其能量效率逐渐降低。通过对充放电规律的探索,使得电芯在后续的实际使用条件中,处于最佳的温度,充放电倍率低于充电窗口,减少析锂情况,电芯处在良好的运行状态,提高工作效率,增加使用寿命。In summary, the present invention provides a method for characterizing the reactivity of a chemical system, a detection device and a readable storage medium. Among them, the methods for characterizing the reactivity of chemical systems include: charging batteries of various chemical systems at different temperatures and at different charge-discharge rates; obtaining energy efficiency and charge-discharge window; The relationship between the discharge window is used to judge the reactivity of the chemical system to obtain the best charge and discharge rate. Through the experimental exploration of the energy efficiency change law of different charge and discharge rates of batteries with various capacities under different temperature conditions, the reactivity of the chemical system can be judged through the relationship between the rate and energy efficiency. As the current density increases, the rate increases and its energy efficiency decreases gradually. Through the exploration of the law of charge and discharge, the battery core is at the best temperature in the subsequent actual use conditions, the charge and discharge rate is lower than the charging window, and the situation of lithium precipitation is reduced, the battery core is in a good operating state, and the work efficiency is improved. , increase the service life.

本申请中选用的各个器件(未说明具体结构的部件)均为通用标准件或本领域技术人员知晓的部件,其结构和原理都为本技术人员均可通过技术手册得知或通过常规实验方法获知。并且,本申请所涉及的软件程序均为现有技术,本申请不涉及对软件程序作出任何改进。Each device selected in the application (not specifying the parts of the specific structure) is a general standard part or a part known to those skilled in the art, and its structure and principle are known to those skilled in the art through technical manuals or through conventional experimental methods informed. Moreover, the software programs involved in this application are all prior art, and this application does not involve making any improvements to the software programs.

在本发明实施例的描述中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the embodiments of the present invention, unless otherwise specified and limited, the terms "installation", "connection" and "connection" should be interpreted in a broad sense, for example, it can be a fixed connection or a detachable connection, or Integral connection; it can be mechanical connection or electrical connection; it can be direct connection or indirect connection through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention in specific situations.

在本发明的描述中,需要说明的是,术语“中心”、“上”、“下”、“左”、“右”、“竖直”、“水平”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”、“第三”仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer" etc. The indicated orientation or positional relationship is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred device or element must have a specific orientation, or in a specific orientation. construction and operation, therefore, should not be construed as limiting the invention. In addition, the terms "first", "second", and "third" are used for descriptive purposes only, and should not be construed as indicating or implying relative importance.

在本申请所提供的几个实施例中,应该理解到,所揭露的系统、装置和方法,可以通过其它的方式实现。以上所描述的装置实施例仅仅是示意性的,例如,所述单元的划分,仅仅为一种逻辑功能划分,实际实现时可以有另外的划分方式,又例如,多个单元或组件可以结合或者可以集成到另一个系统,或一些特征可以忽略,或不执行。另一点,所显示或讨论的相互之间的耦合或直接耦合或通信连接可以是通过一些通信接口,装置或单元的间接耦合或通信连接,可以是电性,机械或其它的形式。In the several embodiments provided in this application, it should be understood that the disclosed systems, devices and methods may be implemented in other ways. The device embodiments described above are only illustrative. For example, the division of the units is only a logical function division. In actual implementation, there may be other division methods. For example, multiple units or components can be combined or May be integrated into another system, or some features may be ignored, or not implemented. In another point, the mutual coupling or direct coupling or communication connection shown or discussed may be through some communication interfaces, and the indirect coupling or communication connection of devices or units may be in electrical, mechanical or other forms.

所述作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个地方,或者也可以分布到多个网络单元上。可以根据实际的需要选择其中的部分或者全部单元来实现本实施例方案的目的。The units described as separate components may or may not be physically separated, and the components shown as units may or may not be physical units, that is, they may be located in one place, or may be distributed to multiple network units. Part or all of the units can be selected according to actual needs to achieve the purpose of the solution of this embodiment.

另外,在本发明各个实施例中的各功能单元可以集成在一个处理单元中,也可以是各个单元单独物理存在,也可以两个或两个以上单元集成在一个单元中。In addition, each functional unit in each embodiment of the present invention may be integrated into one processing unit, each unit may exist separately physically, or two or more units may be integrated into one unit.

以上述依据本发明的理想实施例为启示,通过上述的说明内容,相关工作人员完全可以在不偏离本项发明技术思想的范围内,进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。Inspired by the above-mentioned ideal embodiment according to the present invention, through the above-mentioned description content, relevant workers can make various changes and modifications within the scope of not departing from the technical idea of the present invention. The technical scope of the present invention is not limited to the content in the specification, but must be determined according to the scope of the claims.

Claims (11)

1. A method of characterizing the reactivity of a chemical system, comprising:
charging batteries of various chemical systems at different temperatures and with different charge and discharge multiplying powers;
acquiring energy efficiency and a charging and discharging window;
and judging the reactivity of the chemical system according to the relation between the charge-discharge multiplying power and the energy efficiency and the relation between the temperature and the charge-discharge window, and obtaining the optimal charge-discharge multiplying power.
2. A method of characterizing the reactivity of a chemical system according to claim 1,
the step of charging the batteries of the multiple chemical systems at different temperatures and with different charge and discharge multiplying powers comprises the following steps:
under the constant temperature condition, the charge-discharge multiplying power is adjusted from high to low for various chemical systems, and the energy efficiency is tested;
and (3) regulating the charge and discharge multiplying power of the three-electrode battery from low to high at different temperatures to obtain a charge and discharge window.
3. A method of characterizing the reactivity of a chemical system according to claim 2,
the step of obtaining the relationship between the charge-discharge multiplying power and the energy efficiency comprises the following steps:
plotting according to charge-discharge multiplying power and energy efficiency;
acquiring energy efficiency change curves of different chemical systems;
and judging the reactivity according to the absolute value of the slope.
4. A method of characterizing the reactivity of a chemical system according to claim 3,
the step of judging the reactivity according to the absolute value of the slope, namely:
the larger absolute value of the slope indicates that the greater the impact of current density on energy efficiency, the worse the projection activity.
5. A method of characterizing the reactivity of a chemical system according to claim 2,
the step of obtaining the relation between the temperature and the charge and discharge window comprises the following steps:
plotting the residual capacity of the battery and a charge-discharge window;
acquiring change curves of charge and discharge windows at different temperatures;
and determining the charge-discharge multiplying power at different temperatures according to the change curve of the charge-discharge window.
6. A method of characterizing the reactivity of a chemical system according to claim 5,
the step of determining the charge-discharge multiplying power at different temperatures according to the change curve of the charge-discharge window comprises the following steps:
the charge-discharge multiplying power is always lower than the charge-discharge window.
7. A method of characterizing the reactivity of a chemical system according to claim 6,
the step of obtaining the optimal charge-discharge multiplying power comprises the following steps:
acquiring a range of charge-discharge multiplying power lower than a charge-discharge window according to the residual capacity of the battery;
selecting the optimal charge-discharge multiplying power within the range of the charge-discharge multiplying power;
and selecting the corresponding optimal charge-discharge multiplying power along with the change of the residual capacity of the battery, so that the chemical system has highest reactivity when the battery is charged.
8. A test device for characterizing the reactivity of a chemical system, comprising:
the charging module is suitable for charging batteries of various chemical systems at different temperatures and with different charge and discharge multiplying powers;
and the acquisition module is suitable for energy efficiency and a charging and discharging window.
9. The analysis module is suitable for judging the reactivity of the chemical system according to the relation between the charge-discharge multiplying power, the energy efficiency and the temperature and the charge-discharge window, and obtaining the optimal charge-discharge multiplying power.
10. A computer readable storage medium having stored therein at least one instruction, wherein the instructions when executed by a processor implement the method of characterizing chemical system reactivity of any one of claims 1 to 7.
11. An electronic device comprising a memory and a processor; at least one instruction is stored in the memory; the processor, upon loading and executing the at least one instruction, implements the method of characterizing chemical system reactivity of any one of claims 1-7.
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