CN116159665A - Gangue quartz raw material screening method for preparing low-gas-liquid inclusion high-purity quartz sand - Google Patents
Gangue quartz raw material screening method for preparing low-gas-liquid inclusion high-purity quartz sand Download PDFInfo
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Abstract
本发明提出了一种制备低气液包裹体高纯石英砂的脉石英原料筛选方法,所述筛选方法包括以下步骤:选择性破碎解离—擦洗水洗—脱水分级—雾化施药—表面改性—抛光均化—基于机器视觉分拣粗粒预选抛尾—基于透明度差异低气液包体颗粒筛选—不同品级原料颗粒分级利用。本发明通过石英原料颗粒粒径调控、表面改性及透明度优化,根据颗粒透明度差异分拣实现低气液包裹体含量高纯石英原料的筛选及不同透明度高纯石英原料分级利用,有效降低高气液包裹体杂质颗粒制砂后对高品质石英砂产品的污染。
The present invention proposes a method for screening vein quartz raw materials for preparing high-purity quartz sand with low gas-liquid inclusions. The screening method includes the following steps: selective crushing and dissociation—scrubbing and washing—dehydration and classification—atomization and application—surface modification - Polishing homogenization - Sorting coarse particles based on machine vision pre-selection Throwing tail - Screening of low gas-liquid inclusion particles based on transparency difference - Grading and utilization of different grades of raw material particles. The invention realizes the screening of high-purity quartz raw materials with low gas-liquid inclusion content and the graded utilization of high-purity quartz raw materials with different transparency through the particle size control, surface modification and transparency optimization of quartz raw materials, sorting according to the difference in particle transparency, and effectively reduces high-gas The contamination of high-quality quartz sand products by liquid inclusion impurity particles after sand making.
Description
技术领域technical field
本发明涉及高纯石英选矿技术领域,特别是指一种制备低气液包裹体高纯石英砂的脉石英原料筛选方法。The invention relates to the technical field of high-purity quartz beneficiation, in particular to a method for screening vein quartz raw materials for preparing high-purity quartz sand with low gas-liquid inclusions.
背景技术Background technique
石英玻璃是单一组分SiO2的特种高档玻璃,具有极好的化学稳定性、红外光谱透过率高、抗冲击性强、耐高温(摄氏1800度以上)不变形、耐X-射线辐射、电绝缘特优等物理、化学性能,广泛应用于电子工业、光通讯、医学仪器、SiO2薄膜材料、大规模集成电路、激光、航空航天、军事行业等提供尖端材料。Quartz glass is a special high-grade glass with a single component SiO2 , which has excellent chemical stability, high infrared spectrum transmittance, strong impact resistance, high temperature resistance (above 1800 degrees Celsius) without deformation, resistance to X-ray radiation, Excellent physical and chemical properties such as electrical insulation, widely used in electronic industry, optical communication, medical equipment, SiO 2 thin film materials, large-scale integrated circuits, lasers, aerospace, military industries, etc. to provide cutting-edge materials.
高纯石英原料是世界稀缺、我国短缺,并与芯片、光纤、光伏和高端装备制造业安全攸关的战略矿物资源。我国现行产业高纯石英原料主要依赖于国外进口,主要原因在于国内高纯石英原料富含固体矿物杂质、气液包裹体杂质等。对于石英伴生的云母、金红石、绿帘石等固体矿物杂质,通过高温煅烧、水淬、制砂、磁选、超导选、浮选、电选、酸浸、高温氯化、超声波处理、掺杂提纯等手段可以完全去除粒外矿物杂质,部分去除晶界杂质,但是无法去除微小晶体内的气液包裹体杂质。High-purity quartz raw material is a strategic mineral resource that is scarce in the world and in short supply in my country, and is critical to the safety of chip, optical fiber, photovoltaic and high-end equipment manufacturing industries. my country's current industrial high-purity quartz raw materials mainly rely on foreign imports. The main reason is that domestic high-purity quartz raw materials are rich in solid mineral impurities and gas-liquid inclusion impurities. For solid mineral impurities such as mica, rutile, and epidote associated with quartz, through high-temperature calcination, water quenching, sand making, magnetic separation, superconducting separation, flotation, electric separation, acid leaching, high-temperature chlorination, ultrasonic treatment, doping Miscellaneous purification and other means can completely remove extragranular mineral impurities and partially remove grain boundary impurities, but cannot remove gas-liquid inclusion impurities in tiny crystals.
气液包裹体杂质是指在石英矿晶体生长时形成的杂质,主要由液相和一个小气泡组成的二相包裹体,这是伴随着矿物生长时将H2、O2、N2、CO、CH4、CO2、H2O等包裹在石英晶体中形成的结构性杂质,现有工艺技术难以根本消除此类缺陷,尤其对于5μm以下气液包裹体。气液包裹体杂质对高纯石英制品的危害一是包裹体内元素杂质影响石英玻璃纯度,二是气液包裹体在石英玻璃制备过程中形成大量气泡、气线,严重影响石英玻璃制品的透光性、高温稳定性,导致高品质石英矿无法有效利用。The gas-liquid inclusion impurity refers to the impurity formed when the quartz ore crystal grows . It is mainly composed of a liquid phase and a small bubble. , CH 4 , CO 2 , H 2 O and other structural impurities wrapped in the quartz crystal, the existing technology is difficult to eliminate such defects, especially for gas-liquid inclusions below 5 μm. The harm of gas-liquid inclusion impurities to high-purity quartz products is that the element impurities in the inclusions affect the purity of quartz glass, and the second is that gas-liquid inclusions form a large number of bubbles and gas lines during the preparation of quartz glass, which seriously affects the light transmission of quartz glass products Sexuality and high temperature stability lead to the ineffective utilization of high-quality quartz ore.
现有的石英砂中气液包裹体杂质的去除方法主要有:酸碱差异腐蚀法、冷/热爆裂法、氯化脱气法、微波辐射-酸浸法等,其去除气液包裹体的效果或不甚理想,原因在于爆裂法可打开部分直径较大的包裹体,而无法打开5μm以下气液包裹体。采用氯化法、酸浸法等方法可去除部分已打开大直径包腔内杂质,但由于空穴效应,在此类石英砂熔融石英玻璃过程中依然会出现气泡、气线影响产品质量,且由于工艺复杂操作过程存在安全隐患,生产工艺不环保。因此选取包裹体杂质较少的原料是后续能否有效提纯高纯石英的基础。The existing removal methods of gas-liquid inclusion impurities in quartz sand mainly include: acid-base differential corrosion method, cold/heat burst method, chlorination degassing method, microwave radiation-acid leaching method, etc., which remove gas-liquid inclusions. The effect may be unsatisfactory, because the bursting method can open some inclusions with larger diameters, but cannot open gas-liquid inclusions below 5 μm. Chlorination, acid leaching and other methods can remove some impurities in the opened large-diameter cavity, but due to the cavitation effect, bubbles and gas lines will still appear in the process of fused silica glass with such quartz sand and affect product quality, and Due to the hidden safety hazards in the complex operation process of the process, the production process is not environmentally friendly. Therefore, the selection of raw materials with less inclusion impurities is the basis for the subsequent effective purification of high-purity quartz.
发明内容Contents of the invention
本发明提出一种制备低气液包裹体高纯石英砂的脉石英原料筛选方法,通过脉石英原料颗粒粒径调控、表面改性及透明度优化,根据颗粒透明度差异分拣实现低气液包裹体含量高纯石英原料的筛选及不同透明度高纯石英原料分级利用,有效降低高气液包裹体杂质颗粒制砂后对高品质石英砂产品的污染。The present invention proposes a method for screening vein quartz raw materials for preparing high-purity quartz sand with low gas-liquid inclusions. Through particle size control, surface modification and transparency optimization of vein quartz raw materials, low gas-liquid inclusion content can be achieved by sorting according to the difference in particle transparency. The screening of high-purity quartz raw materials and the graded utilization of high-purity quartz raw materials with different transparency can effectively reduce the pollution of high-quality quartz sand products after sand making by impurity particles with high gas-liquid inclusions.
本发明的技术方案是这样实现的:一种制备低气液包裹体高纯石英砂的脉石英原料筛选方法,包括以下步骤:The technical solution of the present invention is achieved in the following way: a method for screening raw material of vein quartz for preparing high-purity quartz sand with low gas-liquid inclusions, comprising the following steps:
(1)脉石英原矿经两段一闭路破碎分级,得到-20+2mm颗粒物料及-2mm粒级物料;(1) Vein quartz raw ore is crushed and classified in two stages and one closed circuit to obtain -20+2mm granular materials and -2mm granular materials;
(2)将-20+2mm颗粒物料进行擦洗水洗,擦洗过程添加为50-200g/t水玻璃作为分散剂及清洗剂;(2) Scrub and wash the -20+2mm granular material with water, and add 50-200g/t water glass as a dispersant and cleaning agent during the scrubbing process;
(3)步骤(2)擦洗后的颗粒物料经过筛分分级、脱水、沥干,获得-20+10mm、-10+5mm和-5+2mm不同粒级的颗粒产品,颗粒产品的表面保持湿润,含水量小于5wt%;(3) The granular material after scrubbing in step (2) is screened, classified, dehydrated, and drained to obtain granular products of different particle sizes of -20+10mm, -10+5mm and -5+2mm, and the surface of the granular product is kept moist , the water content is less than 5wt%;
(4)将步骤(3)不同粒级的颗粒产品分别采用低粘无色药剂进行表面改性,抛光均化;(4) The particle products of different particle sizes in step (3) are respectively surface-modified with low-viscosity colorless agents, polished and homogenized;
(5)将步骤(4)改性后的不同粒级的颗粒产品分别进行色选作业,剔除深色颗粒和被含铁矿物浸染的黄皮颗粒,得到不同粒级的色选石英颗粒;(5) Carry out the color sorting operation to the particle products of different particle sizes modified in step (4) respectively, remove dark particles and yellow-skin particles impregnated with iron-containing minerals, and obtain color-sorted quartz particles of different particle sizes;
(6)将步骤(5)的色选石英颗粒进行透明度分选作业,得到全白及瓷白颗粒、透明石英颗粒产品及半透明石英颗粒产品,透明石英颗粒产品及半透明石英颗粒产品为低气液包裹体杂质的高纯石英原料。(6) The color-selected quartz particles of step (5) are carried out the transparency sorting operation to obtain all white and porcelain white particles, transparent quartz particle products and translucent quartz particle products, transparent quartz particle products and translucent quartz particle products are low High-purity quartz raw material with gas-liquid inclusion impurities.
进一步地,步骤(4)中,低粘无色药剂的用量为颗粒产品干基重量的1-6%;低粘无色药剂为水、乙醇、乙酸乙酯、变压器油、低粘硅油及油性分散剂中的一种或多种。Further, in step (4), the dosage of the low-viscosity colorless medicament is 1-6% of the dry basis weight of the granular product; the low-viscosity colorless medicament is water, ethanol, ethyl acetate, transformer oil, low-viscosity silicone oil and oily One or more of dispersants.
进一步地,步骤(4)中,低粘无色药剂采用雾化加药,加药后采用捏合机进行颗粒产品的表面抛光和均化,控制表面改性药剂覆膜厚度,提高原料表面药剂的均一性及稳定性。Further, in step (4), the low-viscosity and colorless medicament is added by atomization, and after the dosing, a kneader is used to polish and homogenize the surface of the granule product, so as to control the film thickness of the surface modifying medicament and improve the concentration of the medicament on the surface of the raw material. Uniformity and stability.
进一步地,步骤(5)中,色选作业包括一段色选和二段色选,一段色选剔除深色颗粒,得到不同粒级的一段色选颗粒,不同粒级的一段色选颗粒分别进行二段色选,剔除被含铁矿物浸染的黄皮颗粒,得到不同粒级的色选石英颗粒。Further, in step (5), the color sorting operation includes one-stage color sorting and two-stage color sorting. The first-stage color sorting removes dark particles to obtain the first-stage color-sorting particles of different particle sizes, and the first-stage color-sorting particles of different particle sizes are respectively The second-stage color separation removes the yellow skin particles impregnated with iron-containing minerals to obtain color-selected quartz particles of different particle sizes.
进一步地,步骤(6)中,透明度分选作业包括一段透明度分选和二段透明度分选,色选石英颗粒进行一段透明度分选,得到一段透明颗粒和全白及瓷白颗粒,一段透明颗粒进行二段透明度分选,得到透明石英颗粒产品及半透明石英颗粒产品。Further, in step (6), the transparency sorting operation includes one stage of transparency sorting and two stages of transparency sorting, and the color sorted quartz particles are subjected to one stage of transparency sorting to obtain one section of transparent particles and all white and porcelain white particles, one section of transparent particles Carry out two-stage transparency sorting to obtain transparent quartz granule products and translucent quartz granule products.
进一步地,一段色选的具体方法如下:采用双镜头履带式色选机进行色选,上下两侧背景光、前景光全开,在可见光照射条件下,采用CCD面阵光电传感器识别进行感度斑点值在线分析,给料速度为2.8-3.2m/s,分拣气压0.7-0.8MPa,通过识别分拣感度阈值180,斑点阈值30的深色颗粒并剔除,得到二段色选石英颗粒。Further, the specific method of one-stage color sorting is as follows: use a dual-lens crawler-type color sorter for color sorting, with the background light and foreground light on the upper and lower sides fully turned on, and under the condition of visible light, use CCD area array photoelectric sensor to identify sensitive spots On-line value analysis, the feeding speed is 2.8-3.2m/s, the sorting air pressure is 0.7-0.8MPa, by identifying and removing dark particles with a sorting sensitivity threshold of 180 and a spot threshold of 30, the second-stage color sorting quartz particles are obtained.
进一步地,二段色选的具体方法如下:采用双镜头履带式色选机进行色选,上下两侧背景光、前景光全开,在可见光照射条件下,采用CCD面阵光电传感器识别进行感度斑点值在线分析,给料速度为2.8-3.2m/s,分拣气压0.7-0.8MPa,通过识别分拣感度阈值105,斑点阈值25的黄皮颗粒并剔除,得到二段色选石英颗粒。Further, the specific method of the second-stage color sorting is as follows: use a dual-lens crawler-type color sorter for color sorting, the background light and foreground light on both sides of the upper and lower sides are fully turned on, and under the condition of visible light, use CCD area array photoelectric sensor to identify the sensitivity On-line analysis of speckle value, the feeding speed is 2.8-3.2m/s, the sorting air pressure is 0.7-0.8MPa, and the yellow leather particles with a sorting sensitivity threshold of 105 and a speckle threshold of 25 are identified and eliminated, and the second-stage color-sorted quartz particles are obtained.
进一步地,一段透明度分选的具体方法如下:采用双镜头履带式色选机进行分选,上侧照明灯及上下两测背景光全部关闭,只开下侧照明灯,给料速度为2.8-3.0m/s,分拣气压0.7-0.8MPa,识别感度阈值180-210,斑点阈值5-15,获得一段透明颗粒和全白及瓷白颗粒。Further, the specific method of one-stage transparency sorting is as follows: use a dual-lens crawler-type color sorter for sorting, turn off the upper side lighting and the upper and lower background lights, and only turn on the lower side lighting, and the feeding speed is 2.8- 3.0m/s, sorting air pressure 0.7-0.8MPa, recognition sensitivity threshold 180-210, speckle threshold 5-15, obtain a section of transparent particles and all white and porcelain white particles.
进一步地,二段透明度分选的具体方法如下:采用双镜头履带式色选机进行分选,上侧照明灯及上侧背景光全部关闭,下侧照明灯及下侧背景光全部打开,使用下侧CCD面阵光电传感器识别抛物线下落过程中的石英颗粒,给料速度为2.8-3.0m/s,分拣气压0.7-0.8MPa,识别感度阈值120-180,斑点阈值0-5,得到透明石英颗粒产品及半透明石英颗粒产品。Further, the specific method of the second-stage transparency sorting is as follows: use a dual-lens crawler-type color sorter for sorting, turn off the upper side lighting and the upper side background light, turn on the lower side lighting and the lower side background light, use The CCD area array photoelectric sensor on the lower side identifies the quartz particles in the process of parabolic falling, the feeding speed is 2.8-3.0m/s, the sorting air pressure is 0.7-0.8MPa, the recognition sensitivity threshold is 120-180, the spot threshold is 0-5, and the transparent Quartz granule products and translucent quartz granule products.
进一步地,步骤(1)中的-2mm粒级物料和步骤(7)的全白及瓷白颗粒合并为粉料产品,可用于制备3N光伏石英砂或熔融石英。Further, the -2mm particle size material in step (1) and the all-white and porcelain white particles in step (7) are combined into a powder product, which can be used to prepare 3N photovoltaic quartz sand or fused silica.
进一步地,步骤(5)的深色颗粒与步骤(6)的黄皮颗粒合并作为综合尾矿,可用于制造铸造砂或机制砂。Further, the dark granules in step (5) are combined with the yellow granules in step (6) as comprehensive tailings, which can be used to manufacture foundry sand or machine-made sand.
本发明的有益效果:Beneficial effects of the present invention:
本发明提出了“选择性破碎解离—擦洗水洗—脱水分级—雾化加药—表面改性—抛光均化—基于机器视觉分拣粗粒预选抛尾—基于透明度差异低气液包体颗粒筛选—不同品级原料颗粒分级利用”的工艺方法。对于5μm以下气液包裹体,直接进行色选和透明度选矿,则小粒径富气液包体颗粒筛选效果较差,本发明采用雾化施药利于精准控制药剂用量,提高加药的均匀性;表面改性采用低粘无色药剂,药剂性质粘度150±10%,折光率为1.5150±0.05,药剂折光率与石英晶体颗粒折光率相近似,能抵消空气引起的散光现象,采用低粘无色溶剂在颗粒表面形成不同增透效果的光学膜层,放大颗粒透明度特征差异,提高低气液包裹体石英原料识别精度。The invention proposes "selective crushing and dissociation-scrubbing and washing-dehydration and classification-atomization and dosing-surface modification-polishing and homogenization-based on machine vision sorting of coarse particles and pre-selection of tailings-based on transparency difference and low gas-liquid inclusion particles Screening—gradual utilization of different grades of raw material particles” process method. For the gas-liquid inclusions below 5 μm, if the color separation and transparency beneficiation are carried out directly, the screening effect of the small particle size gas-rich liquid inclusion particles is poor. The atomization application of the present invention is beneficial to accurately control the dosage of the drug and improve the uniformity of the drug addition. The surface modification adopts low-viscosity colorless agent, the viscosity of the agent is 150±10%, and the refractive index is 1.5150±0.05. The refractive index of the agent is similar to that of quartz crystal particles, which can offset the astigmatism caused by air. The color solvent forms optical films with different anti-reflection effects on the surface of the particles, amplifies the differences in particle transparency characteristics, and improves the identification accuracy of quartz materials with low gas-liquid inclusions.
本发明基于透明度差异颗粒分拣实现低气液包裹体含量高纯石英原料的筛选及不同透度高纯石英原料分级利用,有效降低高气液包裹体杂质颗粒制砂后对高品质石英砂产品的污染。The invention realizes the screening of high-purity quartz raw materials with low gas-liquid inclusion content and the graded utilization of high-purity quartz raw materials with different permeability based on the particle sorting of transparency difference, effectively reducing the impact on high-quality quartz sand products after sand making by impurity particles with high gas-liquid inclusions pollution.
本发明基于CCD机器视觉颜色及透明度差异分拣实现粗粒矿物杂质颗粒预选分离,通过识别环境前景光源、背景光源、识别感度及斑点的设计,有利于实现深色、全白、瓷白、半透、透明颗粒识别及自动分拣,剔除难选冶富气液包裹体杂质颗粒,实现不同品级原料的分级,最大程度保护和利用优质资源;解决传统人工手分拣粒度范围窄、识别精度低、劳动强度大、效率低、难以工业化规模生产技术难题,提高了资源利用率;本发明对建立高纯石英可利用性定量评价体系、指导高纯石英原料分质分选分级利用有重要参考价值。The present invention is based on CCD machine vision color and transparency difference sorting to realize the pre-selection and separation of coarse-grained mineral impurity particles. Transparent and transparent particle identification and automatic sorting, remove impurity particles of refractory gas-rich liquid inclusions, realize the classification of different grades of raw materials, protect and utilize high-quality resources to the greatest extent; solve the problem of narrow particle size range and low recognition accuracy of traditional manual sorting , high labor intensity, low efficiency, difficult industrial scale production technical problems, and improved resource utilization; the invention has important reference value for establishing a quantitative evaluation system for the availability of high-purity quartz and guiding the quality, sorting and grading utilization of high-purity quartz raw materials .
本发明可部分取代效率低而成本高的选择性开采方法,提高采矿效率;对脉幅窄、贫化率高的矿脉,不均匀成矿矿脉、均匀成矿矿脉的边界与围岩进行处理,提高资源利用率。对不均匀成矿脉石英矿体中不同透明度石英颗粒获得部分高纯石英原料,同时实现不同品级资源分级利用,在我国江苏东海、湖北大悟、蕲春、广东河源、陕西商洛等大型地脉石英资源基地具有推广应用前景。The present invention can partly replace the low-efficiency and high-cost selective mining method, and improve the mining efficiency; it can process the ore veins with narrow width and high dilution rate, uneven ore-forming ore-forming veins, boundaries and surrounding rocks of uniform ore-forming ore-forming veins, Improve resource utilization. Obtain some high-purity quartz raw materials for different transparency quartz particles in uneven ore-forming vein quartz ore bodies, and at the same time realize the graded utilization of resources of different grades. In my country's large-scale vein quartz resource bases such as Donghai in Jiangsu, Dawu in Hubei, Qichun, Heyuan in Guangdong, and Shangluo in Shaanxi It has a prospect of popularization and application.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments of the present invention. Those skilled in the art can also obtain other drawings based on these drawings without creative work.
图1为本发明所述的筛选方法的工艺流程图;Fig. 1 is the process flow diagram of screening method of the present invention;
图2为脉石英原矿的图片;Fig. 2 is the picture of vein quartz raw ore;
图3为透明石英颗粒产品的图片;Fig. 3 is the picture of transparent quartz particle product;
图4为半透明石英颗粒产品的图片;Figure 4 is a picture of a translucent quartz particle product;
图5为综合尾矿的图片。Figure 5 is a picture of integrated tailings.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有付出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
如图1所示,一种制备低气液包裹体高纯石英砂的脉石英原料筛选方法,包括以下步骤:As shown in Figure 1, a method for screening raw material of vein quartz for preparing high-purity quartz sand with low gas-liquid inclusions comprises the following steps:
(1)脉石英原矿经两段一闭路破碎分级,得到-20+2mm颗粒物料及-2mm粒级物料;(1) Vein quartz raw ore is crushed and classified in two stages and one closed circuit to obtain -20+2mm granular materials and -2mm granular materials;
(2)-20+2mm颗粒物料经过擦洗水洗,去除颗粒表皮矿泥及易碎裂隙多的颗粒物,擦洗过程添加为50-200g/t水玻璃作为分散剂及清洗剂;(2) -20+2mm granular materials are scrubbed and washed with water to remove granule skin slime and particles with many brittle cracks. During the scrubbing process, 50-200g/t water glass is added as a dispersant and cleaning agent;
(3)步骤(2)擦洗后的颗粒物料经过筛分分级、脱水、沥干,获得-20+10mm、-10+5mm和-5+2mm不同窄级别粒级的颗粒产品,调控颗粒表面保持湿润,含水量小于5wt%;(3) The scrubbed granular materials in step (2) are screened, classified, dehydrated, and drained to obtain granular products with different narrow grades of -20+10mm, -10+5mm and -5+2mm, and the particle surface is controlled to maintain Wet, with a water content of less than 5wt%;
(4)步骤(3)不同粒级的颗粒产品分别采用低粘无色溶剂进行表面改性捏合均化,在颗粒表面形成不同增透效果的光学膜层,放大颗粒透明度特征差异,提高低气液包裹体石英原料识别精度;所述低粘无色溶剂为水、乙醇、乙酸乙酯、变压器油、低粘硅油中的一种或几种配伍符合溶剂,主要特征为温粘系数小、耐高低温、抗氧化、闪点高、挥发性小、绝缘性好、表面张力小、对金属无腐蚀、无毒等,低粘无色溶剂的用量为颗粒产品干基重量的1-6%,根据颗粒粒级大小调整用量,以颗粒产品离散不黏连为准。(4) Step (3) Particle products of different particle sizes are surface-modified, kneaded and homogenized with low-viscosity colorless solvents, and optical films with different anti-reflection effects are formed on the surface of the particles to amplify the difference in particle transparency characteristics and improve low-gas The identification accuracy of liquid inclusion quartz raw materials; the low-viscosity colorless solvent is one or more compatible solvents among water, ethanol, ethyl acetate, transformer oil, and low-viscosity silicone oil. High and low temperature, anti-oxidation, high flash point, low volatility, good insulation, low surface tension, no corrosion to metal, non-toxic, etc. The amount of low-viscosity and colorless solvent is 1-6% of the dry weight of the granular product. Adjust the dosage according to the size of the particle size, and the particle product is discrete and non-cohesive.
(5)将步骤(4)改性后不同粒级产品分别采用双镜头履带式色选机进行一段色选,具体方法如下:上下两侧背景光、前景光全开,在可见光照射条件下,采用CCD面阵光电传感器识别进行感度斑点值在线分析,给料速度为2.8-3.2m/s,分拣气压0.7-0.8MPa,通过识别分拣感度阈值180,斑点阈值30的深色颗粒废料,分选剔除黑云母、绿泥石等暗色矿物杂质颗粒,得到不同粒级一段色选颗粒;(5) After the step (4) is modified, the products of different grain grades are respectively selected by a double-lens crawler-type color sorter. The specific method is as follows: the upper and lower sides of the background light and the foreground light are fully turned on. Under the condition of visible light, CCD area array photoelectric sensor is used to identify and analyze the sensitivity spot value online. The feeding speed is 2.8-3.2m/s, and the sorting air pressure is 0.7-0.8MPa. By identifying and sorting the dark particle waste with a sensitivity threshold of 180 and a spot threshold of 30, Sorting and removing dark mineral impurity particles such as biotite and chlorite to obtain color-selected particles of different particle sizes;
将不同粒级的一段色选颗粒采用双镜头履带式色选机进行二段色选,具体方法如下:上下两侧背景光、前景光全开,在可见光照射条件下,采用CCD面阵光电传感器识别进行感度斑点值在线分析,给料速度为2.8-3.2m/s,分拣气压0.7-0.8MPa,通过识别分拣感度阈值105,斑点阈值25的黄色颗粒废料,分选剔除被含铁矿物浸染的黄皮颗粒,分别得到不同粒级的二段色选石英颗粒;黄皮颗粒与深色颗粒废料合并,得到综合尾矿,可用于制造铸造砂或机制砂;The first-stage color sorting particles of different particle sizes are selected by a dual-lens crawler-type color sorter for the second-stage color sorting. The specific method is as follows: the background light on both sides and the foreground light are fully turned on. Under the condition of visible light, the CCD area array photoelectric sensor is used. Identify and conduct online analysis of the sensitivity spot value, the feeding speed is 2.8-3.2m/s, and the sorting air pressure is 0.7-0.8MPa. By identifying the yellow particle waste with a sorting sensitivity threshold of 105 and a spot threshold of 25, the iron-containing ore is sorted and eliminated. The yellow skin granules impregnated with materials can be used to obtain second-stage color-selected quartz particles of different particle sizes; the yellow skin granules are combined with dark granule waste to obtain comprehensive tailings, which can be used to manufacture foundry sand or machine-made sand;
(6)将不同粒级的二段色选石英颗粒进行透明度颗粒分级拣选,具体包括一段透明度分选和二段透明度分选;一段透明度分选的具体方法如下:采用双镜头履带式色选机,上侧照明灯及上下两测背景光全部关闭,只开下侧照明灯给料速度为2.8-3.0m/s,分拣气压0.7-0.8MPa,识别感度阈值180-210,斑点阈值5-15,分别获得一段透明颗粒和全白及瓷白颗粒,一段透明颗粒为透明度较好的高亮颗粒;(6) The second-stage color sorting quartz particles of different particle sizes are classified and sorted for transparency particles, specifically including one-stage transparency sorting and two-stage transparency sorting; the specific method of one-stage transparency sorting is as follows: a double-lens crawler type color sorter is used , the upper lighting and the upper and lower measurement background lights are all turned off, only the lower lighting is turned on. The feeding speed is 2.8-3.0m/s, the sorting air pressure is 0.7-0.8MPa, the recognition sensitivity threshold is 180-210, and the spot threshold is 5- 15. Obtain a section of transparent granules, full white and porcelain white granules respectively, and a section of transparent granules are high-brightness granules with good transparency;
一段透明颗粒进行二段透明度分选,具体方法如下:采用双镜头履带式色选机,上侧照明灯及上侧背景光全部关闭,下侧照明灯及下侧背景光全部打开,使用下侧CCD面阵光电传感器识别抛物线下落过程中的石英颗粒,光线会穿透透明的颗粒,部分穿透半透明的矿石颗粒,颗粒不透明部分在背景板上产生信号,传感器就会接收到信号做出反应,实现半透明及透明颗粒分拣,给料速度为2.8-3.0m/s,分拣气压0.7-0.8MPa,识别感度阈值120-180,斑点阈值0-5,分别获得透明石英颗粒产品及半透明石英颗粒产品。One-stage transparent particles are sorted by two-stage transparency, the specific method is as follows: use a dual-lens crawler-type color sorter, turn off the upper side lighting and the upper side background light, turn on the lower side lighting and the lower side background light, use the lower side The CCD area array photoelectric sensor identifies the quartz particles in the process of parabolic fall, the light will penetrate the transparent particles, partly penetrate the translucent ore particles, the opaque part of the particles will generate a signal on the background plate, and the sensor will receive the signal and respond , to achieve sorting of translucent and transparent particles, the feeding speed is 2.8-3.0m/s, the sorting air pressure is 0.7-0.8MPa, the recognition sensitivity threshold is 120-180, and the spot threshold is 0-5. Transparent quartz grain products.
透明石英颗粒产品经煅烧、水淬、制砂、重选、磁选、浮选、酸浸、焙烧提纯后,获得4N75高纯石英砂,SiO2品位为99.9975%;半透明石英颗粒产品经煅烧、水淬、制砂、重选、磁选、浮选、酸浸、焙烧提纯后,获得4N级高纯石英砂。After calcination, water quenching, sand making, gravity separation, magnetic separation, flotation, acid leaching and roasting, transparent quartz granule products are purified to obtain 4N75 high-purity quartz sand with a SiO2 grade of 99.9975%; translucent quartz granule products are calcined , water quenching, sand making, gravity separation, magnetic separation, flotation, acid leaching, roasting and purification to obtain 4N grade high-purity quartz sand.
具体实施例如下:Specific examples are as follows:
某地脉石英原矿SiO2品位为96.69%,如图2所示,伴生大块绿帘石等矿物杂质,部分裂隙受铁质矿物浸染成黄色,原矿不均匀成矿透明度差异显著。采用本发明的制备低气液包裹体高纯石英砂的脉石英原料筛选方法,先对脉石英原矿进行粗碎、中碎和筛分,得到-20+2mm粒级矿物,+20mm粒级矿物返回中碎作业。The grade of SiO2 in a vein quartz raw ore is 96.69%. As shown in Figure 2, it is accompanied by mineral impurities such as large epidote, and some cracks are dyed yellow by iron minerals. Using the vein quartz raw material screening method for preparing high-purity quartz sand with low gas-liquid inclusions of the present invention, the vein quartz raw ore is firstly crushed, medium crushed and screened to obtain -20+2mm grain size minerals, and +20mm grain size minerals are returned Medium crushing work.
-20+2mm粒级矿物擦洗水洗、筛分分级、脱水、沥干,分成-20+10mm、-10+5mm、-5+2mm三个粒级产品,并分别进行表面改性、一段色选、二段色选、一段透明度分选和二段透明度分选,得到透明石英颗粒产品、半透明石英颗粒产品、综合尾矿和全白及瓷白颗粒,-2mm粒级矿物和全白及瓷白颗粒作为粉料产品。透明石英颗粒产品如图3所示,半透明石英颗粒产品如4所示,综合尾矿如图5所示,脉石英原矿制备高纯石英原料,预先抛尾的选矿技术指标如表1所示。-20+2mm grain grade minerals are scrubbed and washed, screened and graded, dehydrated, drained, divided into three grades of -20+10mm, -10+5mm, -5+2mm, and surface modification, one-stage color sorting , two-stage color sorting, one-stage transparency sorting and two-stage transparency sorting to obtain transparent quartz granule products, translucent quartz granule products, comprehensive tailings and all-white and porcelain white granules, -2mm grain size minerals and all-white and porcelain White granules are used as powder products. The transparent quartz granule product is shown in Figure 3, the translucent quartz granule product is shown in Figure 4, and the comprehensive tailings are shown in Figure 5. The raw quartz ore is used to prepare high-purity quartz raw materials, and the beneficiation technical indicators of pre-throwing tailings are shown in Table 1. .
表1脉石英原矿预选抛尾的选矿技术指标Table 1 Mineral processing technical indicators of vein quartz raw ore pre-selection and discarding tailings
从表1中可知,综合尾矿的产率为3.90%,Fe2O3、Al2O3等有害矿物杂质去除率(回收率)分别为55.22%、61.23%,预选抛尾效果显著。透明石英颗粒产品的产率为63.73%,SiO2的品位99.77%,经制砂、重选、磁选、浮选、酸浸提纯后SiO2品位为99.9985%,获得4N85级高纯石英砂产品。半透明石英颗粒精矿与粉料产品合并产率为32.37%,SiO2的品位94.32%,作为二级原料实现全资源分级利用。It can be seen from Table 1 that the yield of comprehensive tailings is 3.90%, the removal rate (recovery rate) of harmful mineral impurities such as Fe 2 O 3 and Al 2 O 3 is 55.22% and 61.23%, respectively, and the effect of pre-selection tailings is remarkable. The yield of transparent quartz granules is 63.73%, and the grade of SiO2 is 99.77%. After sand making, gravity separation, magnetic separation, flotation, and acid leaching, the grade of SiO2 is 99.9985%. The product of 4N85 high-purity quartz sand is obtained . The combined yield of translucent quartz particle concentrate and powder products is 32.37%, and the grade of SiO 2 is 94.32%. It can be used as a secondary raw material to realize the graded utilization of all resources.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the scope of the present invention. within the scope of protection.
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| CN120463210A (en) * | 2025-07-09 | 2025-08-12 | 昆明理工大学 | A method for microwave activation and pressure leaching of quartz sand |
| CN120463210B (en) * | 2025-07-09 | 2025-09-12 | 昆明理工大学 | Quartz sand microwave activation pressure leaching method |
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