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CN116079606A - A kind of utensil stain cleaning product and using method thereof - Google Patents

A kind of utensil stain cleaning product and using method thereof Download PDF

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CN116079606A
CN116079606A CN202211336730.XA CN202211336730A CN116079606A CN 116079606 A CN116079606 A CN 116079606A CN 202211336730 A CN202211336730 A CN 202211336730A CN 116079606 A CN116079606 A CN 116079606A
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parts
powder
cleaning product
stain cleaning
utensil
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CN116079606B (en
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周寿柱
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Shanghai Yisu New Material Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0009Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B27/00Other grinding machines or devices
    • B24B27/033Other grinding machines or devices for grinding a surface for cleaning purposes, e.g. for descaling or for grinding off flaws in the surface
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/02Polishing compositions containing abrasives or grinding agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0034Fixed on a solid conventional detergent ingredient
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/14Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/16Phosphates including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/20Water-insoluble oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/268Carbohydrates or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Health & Medical Sciences (AREA)
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Abstract

The invention relates to the technical field of appliance cleaning, in particular to an appliance stain cleaning product and a use method thereof, wherein the preparation raw materials at least comprise 50-150 parts of abrasive and 5-50 parts of adhesive in parts by weight, the decontamination and reduction effects are good, and especially for metal products and porcelain products, all stains, oil stains and Jiao Zi on the metal surfaces can be effectively removed, the use is convenient, and meanwhile, the stain particles can be effectively adsorbed by utilizing small fine powder generated by the product, and the product can be washed clean by water or other liquids without causing repeated pollution.

Description

一种器具污渍清洗产品及其使用方法A kind of utensil stain cleaning product and using method thereof

技术领域technical field

本发明涉及器具清洁技术领域,具体为一种器具污渍清洗产品及其使用方法。The invention relates to the technical field of appliance cleaning, in particular to an appliance stain cleaning product and a use method thereof.

背景技术Background technique

当前对器具(设备)的清洗去污方式分为三大类,1、使用化学方法清洗,如用酸、碱、酶和表面活性剂等方式清洗去污;2、使用刮擦方式去污清洗,如用钢丝球、丝瓜纤维(天然)、百洁布、竹条束等;3、使用研磨的方式去污清洗,如研磨粉、研磨膏等。但每一类都有相应的局限性,使用化学方法,不环保,对于去除强污渍效果差,而且缺少通用性,要针对选择,特别是酸/碱类的清洁剂对器具(设备)会造成损伤。使用刮擦方式,要么去强污渍效果差,(如天然丝瓜纤维,不加金钢砂的百洁布等),要么对器具(设备)损伤严重(如钢丝球和加了金钢砂的百洁布等),清洗后容易产生锈渍。而且,纤维类的百洁布和钢丝球很容易纳污(特别是油渍),又不易清洗干净,会对器具(设备)造成重复的污染。用研磨类的粉或膏,使用不方便,需要另配一个研磨器具(一般会用百洁布),研磨下来的污渍粿粒会污染研磨器具,而且用量上面也不好把控,此外研磨粉或研磨膏的重复使用,又极易污染而产生霉菌。The current cleaning and decontamination methods for utensils (equipment) are divided into three categories. 1. Use chemical methods for cleaning, such as cleaning and decontamination with acids, alkalis, enzymes and surfactants; 2. Use scraping methods for decontamination and cleaning , such as steel balls, loofah fibers (natural), scouring pads, bamboo bundles, etc.; 3. Use grinding methods for decontamination and cleaning, such as grinding powder, grinding paste, etc. However, each category has corresponding limitations. Using chemical methods is not environmentally friendly. It has poor effect on removing strong stains and lacks versatility. It must be selected accordingly, especially acid/alkaline cleaners will cause damage to appliances (equipment). damage. Using the scraping method, either the effect of removing strong stains is poor (such as natural loofah fiber, scouring pads without emery, etc.), or the appliance (equipment) is severely damaged (such as steel wool and scouring pads with emery) Cleaning cloth, etc.), easy to produce rust stains after cleaning. Moreover, fibrous scouring pads and steel wool balls are easy to hold dirt (especially oil stains), and are not easy to clean, which will cause repeated pollution to utensils (equipment). It is inconvenient to use grinding powder or paste, and you need to prepare another grinding tool (usually use a scouring pad). The stained grains will contaminate the grinding tool, and the amount is not easy to control. In addition, the grinding powder Or the repeated use of abrasive paste is very easy to pollute and produce mold.

中国申请专利CN107434953A公开了一种一种汽车漆面清洁磨泥配方,具体采用黏土、二氧化硅研磨粉、三氧化二铝抛光粉、润滑剂、光亮剂和粘合剂制备,目的在于清楚车漆上的黑点锈点氧化层、铁粉、飞溅油漆、虫尸鸟粪等,但是在去除强污渍,尤其是器具(设备)表面的油渍、污渍和焦渍的去除效果有待提高,效率也不高。中国专利申请CN103060832A公开了一种金属油污去除剂及其制备方法,同时引入有机溶剂油、氨水、草酸、苯酚制备得到金属油污去除剂,但是一方面煤油、溶剂汽油及松节油的使用易对器具造成重复的污染,另一方面酸性和碱性原料的引入会对器具(设备)造成损伤,而且不利于使用者的健康。Chinese patent application CN107434953A discloses a formula for cleaning and grinding mud for automobile paint surfaces. Black spots, rust spots, oxide layers, iron powder, splashed paint, insect corpses, bird droppings, etc. on the paint, but the removal effect of strong stains, especially oil stains, stains and burnt stains on the surface of appliances (equipment) needs to be improved, and the efficiency is also low. not tall. Chinese patent application CN103060832A discloses a metal oil stain remover and a preparation method thereof, and simultaneously introduces organic solvent oil, ammonia water, oxalic acid, and phenol to prepare a metal oil stain remover. Repeated pollution, on the other hand, the introduction of acidic and alkaline raw materials will cause damage to utensils (equipment), and is not conducive to the health of users.

发明内容Contents of the invention

为了解决上述问题,本发明提供了一种器具污渍清洗产品及其使用方法,去污还原效果好,特别是针对金属制品和瓷器制品等硬质材质制品,能有效的去除金属表面的一切污渍、油渍、焦渍和锈渍,且使用方便,效率高,同时利用自身产生的小细末能有效地吸附污渍颗粒,用水或其他液体即可冲洗干净,清洗后能有效地防止金属生锈,不会造成重复的污染。In order to solve the above problems, the present invention provides a stain cleaning product for utensils and its use method, which has a good decontamination and reduction effect, especially for hard material products such as metal products and porcelain products, and can effectively remove all stains on the metal surface, Oil stains, burnt stains and rust stains, easy to use, high efficiency, at the same time, the small fines produced by itself can effectively absorb stain particles, and can be rinsed with water or other liquids. After cleaning, it can effectively prevent metal from rusting, without Will cause repeated pollution.

本发明一方面提供了一种器具污渍清洗产品,按照重量份计,其制备原料至少包括研磨剂50-150份、粘合剂5-50份。One aspect of the present invention provides a stain cleaning product for utensils. The raw materials for its preparation include at least 50-150 parts of grinding agent and 5-50 parts of adhesive in parts by weight.

作为一种优选的技术方案,所述研磨剂、粘合剂的质量比为10:(1-10),优选为10:(1-2)。As a preferred technical solution, the mass ratio of the abrasive to the binder is 10:(1-10), preferably 10:(1-2).

作为一种优选的技术方案,所述研磨剂为沸石粉、滑石粉、石膏粉、碳酸钙、氧化硅、氧化钛、石英粉、活性炭粉、植物粉末中的至少一种。优选的,所述研磨剂为石膏粉、碳酸钙、沸石粉和活性炭粉的组合;优选的,所述石膏粉、碳酸钙、沸石粉和活性炭粉的质量比为(3-5):(2-4):(1-3):1。基于本发明体系,通过采用质量比为(3-5):(2-4):(1-3):1的石膏粉、碳酸钙、沸石粉和活性炭粉组合作为研磨剂,使制备得到的产品不损伤基材的同时有效去除污渍。发明人分析原因可能为,在特定粘合剂的粘合作用下,石膏粉、碳酸钙、沸石粉和活性炭粉被润湿分散结合为方便使用的具有合适硬度的固体,在与器具或设备进行刮擦使用时,掉落的粉末颗粒大小适中,且具有多孔的结构,吸附掉落的污渍颗粒,实现不使用化学表面活性剂的条件下达到较好的清洁效果。As a preferred technical solution, the abrasive is at least one of zeolite powder, talc powder, gypsum powder, calcium carbonate, silicon oxide, titanium oxide, quartz powder, activated carbon powder, and plant powder. Preferably, the grinding agent is a combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder; preferably, the mass ratio of the gypsum powder, calcium carbonate, zeolite powder and activated carbon powder is (3-5): (2 -4):(1-3):1. Based on the system of the present invention, by using the combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder with a mass ratio of (3-5): (2-4): (1-3): 1 as abrasive, the prepared The product effectively removes stains without damaging the substrate. The contriver's analysis reason may be, under the binding effect of specific binder, gypsum powder, calcium carbonate, zeolite powder and activated carbon powder are wetted and dispersed and combined into a solid with suitable hardness for convenient use. When using by scraping, the particle size of the fallen powder particles is moderate, and has a porous structure, which can absorb the fallen stain particles, so as to achieve a better cleaning effect without using chemical surfactants.

作为一种优选的技术方案,所述粘合剂为有机树脂、松香、石膏、硅酸盐、粘土、石灰、植物胶中一种或几种的组合。优选的,所述粘合剂为有机树脂、石膏、硅酸盐的组合,所述有机树脂、石膏、硅酸盐的质量比为(3-5):(0.1-0.5):1。优选的,所述有机树脂为液体酚醛树脂,所述液体酚醛树脂的固含量为30-55%,所述液体酚醛树脂的粘度(25℃)为5-55mpa.s。优选的,所述液体酚醛树脂为液体酚醛树脂A和液体酚醛树脂B的组合;所述液体酚醛树脂A的固含量为33-41%,粘度(25℃)为5-20mpa.s;所述液体酚醛树脂B的固含量为50-54%,粘度(25℃)为25-40mpa.s。优选的,所述液体酚醛树脂A和液体酚醛树脂B的质量比为(1-3):1。所述液体酚醛树脂A(PF9171)和液体酚醛树脂B(PF9501-1)均来源于济南圣泉基团股份有限公司。As a preferred technical solution, the binder is one or a combination of organic resins, rosin, gypsum, silicate, clay, lime, and vegetable glue. Preferably, the binder is a combination of organic resin, gypsum, and silicate, and the mass ratio of the organic resin, gypsum, and silicate is (3-5):(0.1-0.5):1. Preferably, the organic resin is a liquid phenolic resin, the solid content of the liquid phenolic resin is 30-55%, and the viscosity (25°C) of the liquid phenolic resin is 5-55mpa.s. Preferably, the liquid phenolic resin is a combination of liquid phenolic resin A and liquid phenolic resin B; the solid content of the liquid phenolic resin A is 33-41%, and the viscosity (25°C) is 5-20mpa.s; The solid content of the liquid phenolic resin B is 50-54%, and the viscosity (25°C) is 25-40mpa.s. Preferably, the mass ratio of the liquid phenolic resin A to the liquid phenolic resin B is (1-3):1. Both the liquid phenolic resin A (PF9171) and the liquid phenolic resin B (PF9501-1) come from Jinan Shengquan Group Co., Ltd.

基于本发明体系,通过控制研磨剂、粘合剂的质量比为10:(1-2)以保证器具或设备的污渍清洁效果同时,将研磨剂粘合为方便使用的块状固体物,有助于实现大规模工业化生产使用。但是,研磨剂和粘合剂的选择对产品的硬度和使用效果的影响较高,发明人在探究过程中发现,通过采用质量比为(3-5):(0.1-0.5):1的有机树脂、石膏、硅酸盐的组合为粘合剂,尤其是采用质量比为(1-3):1的两种不同固含量和粘度的液体酚醛树脂A和液体酚醛树脂B,实现体系中石膏粉、碳酸钙、沸石粉和碳粉之间的有效结合,同时使制备得到的产品具有合适的硬度,采用制备得到的产品去刮擦器具表面的污渍时,进行刮擦的部位也开始掉落研磨粉末颗粒,掉落的研磨粉末颗粒一方面在刮擦的过程中起到辅助研磨的作用,另一方面起到吸附掉落的污渍颗粒的作用,整体实现优异的清洁效果,同时避免重复污染。Based on the system of the present invention, by controlling the mass ratio of abrasives and binders to be 10: (1-2) to ensure the stain cleaning effect of utensils or equipment, the abrasives are bonded into blocky solids that are convenient to use. Contribute to the realization of large-scale industrial production and use. However, the selection of abrasives and binders has a high impact on the hardness and use effect of the product. The inventor found in the process of exploration that by using an organic compound with a mass ratio of (3-5):(0.1-0.5):1 The combination of resin, gypsum, and silicate is used as the binder, especially the liquid phenolic resin A and liquid phenolic resin B with a mass ratio of (1-3):1, which have different solid contents and viscosities, to realize the gypsum in the system. The effective combination between powder, calcium carbonate, zeolite powder and carbon powder makes the prepared product have a suitable hardness. When the prepared product is used to scrape the stains on the surface of the appliance, the scraped part also begins to fall off Grinding powder particles, the falling grinding powder particles play the role of auxiliary grinding during the scraping process on the one hand, and on the other hand play the role of absorbing the falling stain particles, achieving excellent cleaning effect as a whole and avoiding repeated pollution .

作为一种优选的技术方案,按重量份计,所述器具污渍清洗产品还包括5-15份磷酸盐类化合物、4-8份聚合物水溶液、0.5-2份碱式盐水溶液。As a preferred technical solution, in parts by weight, the appliance stain cleaning product further includes 5-15 parts of phosphate compounds, 4-8 parts of polymer aqueous solution, and 0.5-2 parts of alkaline saline solution.

作为一种优选的技术方案,所述磷酸盐类化合物为六偏磷酸钠、焦磷酸钠、焦磷酸四钾、三聚磷酸钠中的至少一种。优选的,所述磷酸盐类化合物为焦磷酸四钾和六偏磷酸钠的组合;所述焦磷酸四钾和六偏磷酸钠的质量比为(3-5):1。发明人在实际探究过程中发现,基于本发明体系,引入5-15重量份的磷酸盐类化合物,尤其是引入质量比为(3-5):1的焦磷酸四钾和六偏磷酸钠的组合,一方面提高产品对器具或设备顽强物质的去除效果,另一方面提高研磨剂在粘合剂中的分散效果和结合能力,便于产品后续赋形。发明人分析原因可能为:在该质量比下,焦磷酸四钾和六偏磷酸钠有助于改善研磨剂在粘合剂中的分散作用效果,与研磨剂之间产生鳌合作用,形成稳定的结合物,生产出方便使用的块状固体物,在产品与器具或设备研磨去污的同时,焦磷酸四钾和六偏磷酸钠能够与物质形成溶于水的复合盐,在研磨清洁的过程中使顽强污渍更容易去除,同时易于用清水冲洗除去,进一步提高清洁效果。As a preferred technical solution, the phosphate compound is at least one of sodium hexametaphosphate, sodium pyrophosphate, tetrapotassium pyrophosphate, and sodium tripolyphosphate. Preferably, the phosphate compound is a combination of tetrapotassium pyrophosphate and sodium hexametaphosphate; the mass ratio of tetrapotassium pyrophosphate and sodium hexametaphosphate is (3-5):1. The inventor found in the actual research process that based on the system of the present invention, the introduction of 5-15 parts by weight of phosphate compounds, especially the introduction of tetrapotassium pyrophosphate and sodium hexametaphosphate with a mass ratio of (3-5): 1 The combination, on the one hand, improves the removal effect of the product on the tenacious substances of the appliance or equipment, and on the other hand, improves the dispersion effect and binding ability of the abrasive in the binder, which facilitates the subsequent shaping of the product. The inventor analyzes that the reason may be: under this mass ratio, tetrapotassium pyrophosphate and sodium hexametaphosphate help to improve the dispersion effect of the abrasive in the binder, and produce chelation with the abrasive to form a stable Combination of materials to produce blocky solids that are convenient to use. When the product and utensils or equipment are ground and decontaminated, tetrapotassium pyrophosphate and sodium hexametaphosphate can form a water-soluble compound salt with the substance. In the process, it makes it easier to remove stubborn stains, and at the same time, it is easy to rinse with water to further improve the cleaning effect.

作为一种优选的技术方案,所述聚合物水溶液为藻酸丙二醇酯水溶液、羧甲基纤维素钠水溶液中的至少一种。优选的,所述聚合物水溶液为藻酸丙二醇酯水溶液。优选的,所述藻酸丙二醇酯水溶液中藻酸丙二醇酯的质量浓度为0.5-2%;As a preferred technical solution, the aqueous polymer solution is at least one of an aqueous solution of propylene glycol alginate and an aqueous solution of sodium carboxymethylcellulose. Preferably, the aqueous polymer solution is an aqueous solution of propylene glycol alginate. Preferably, the mass concentration of propylene glycol alginate in the aqueous solution of propylene glycol alginate is 0.5-2%;

作为一种优选的技术方案,所述碱式盐水溶液为乙酸铝水溶液、硬脂酸铝水溶液中的至少一种。优选的,所述碱式盐水溶液为乙酸铝水溶液;优选的,所述乙酸铝水溶液中乙酸铝的质量浓度为8-12%。As a preferred technical solution, the basic saline solution is at least one of aluminum acetate aqueous solution and aluminum stearate aqueous solution. Preferably, the basic salt solution is an aqueous aluminum acetate solution; preferably, the mass concentration of aluminum acetate in the aqueous aluminum acetate solution is 8-12%.

基于本发明体系,引入50-150份研磨剂,保证产品与器具或设备之间通过研磨及相互作用实现优异的清洁效果,但是在与金属表面摩擦过程中会产生噪声,发明人在探究过程中发现,引入4-8重量份聚合物水溶液和0.5-2重量份碱式盐水溶液,尤其是引入的聚合物水溶液为质量浓度为0.5-2%的藻酸丙二醇酯水溶液和质量浓度为8-12%的乙酸铝水溶液,有效抑制由于大量研磨剂的引入导致的噪音,提升使用体验感。发明人分析原因可能为,配方量的质量浓度为0.5-2%的藻酸丙二醇酯水溶液和质量浓度为8-12%的乙酸铝水溶液能够发生特异性相互作用形成凝胶状物质,改善了研磨剂的振动吸收特性、提高了研磨材料的衰减特性,有效抑制研磨过程中产生的噪音。Based on the system of the present invention, 50-150 parts of abrasives are introduced to ensure an excellent cleaning effect through grinding and interaction between products and utensils or equipment, but noise will be generated during friction with metal surfaces. Find, introduce 4-8 weight part polymer aqueous solution and 0.5-2 weight part basic saline solution, especially the polymer aqueous solution that introduces is the propylene glycol alginate aqueous solution that mass concentration is 0.5-2% and mass concentration is 8-12% % aluminum acetate aqueous solution, which can effectively suppress the noise caused by the introduction of a large amount of abrasives and improve the user experience. The inventor's analysis may be that the mass concentration of the formulation amount is that the propylene glycol alginate aqueous solution of 0.5-2% and the aluminum acetate aqueous solution of 8-12% can have specific interactions to form a gel-like substance, which improves the grinding process. The vibration absorption characteristics of the agent improve the attenuation characteristics of the abrasive material and effectively suppress the noise generated during the grinding process.

作为一种优选的技术方案,所述器具污渍清洗产品的制备方法为,将研磨剂混合研磨后得到粒度为1000-1500目研磨剂混合料;将研磨剂混合料与粘合剂混合均匀后加入磷酸盐类化合物、聚合物水溶液、碱式盐水溶液搅拌混合30-40min后得到混合料,将混合料置于一定形状的模具中,在100-150℃的条件下放置2-3h后即得。As a preferred technical solution, the preparation method of the appliance stain cleaning product is: mixing and grinding the abrasive to obtain an abrasive mixture with a particle size of 1000-1500 mesh; mixing the abrasive mixture and the binder evenly and then adding The phosphate compound, the polymer aqueous solution, and the basic saline solution are stirred and mixed for 30-40 minutes to obtain a mixture, which is placed in a mold of a certain shape and placed at 100-150° C. for 2-3 hours.

本发明另一方面提供了一种器具污渍清洗产品的使用方法,采用器具污渍清洗产品去刮擦器具表面的污渍,进行刮擦的部位掉落研磨粉末,之后用水冲洗干净即可。Another aspect of the present invention provides a method for using the appliance stain cleaning product. The appliance stain cleaning product is used to scrape the stains on the surface of the appliance, and the scraping part drops abrasive powder, and then rinses with water.

有益效果Beneficial effect

1、本发明提供了一种器具污渍清洗产品及其使用方法,去污还原效果好,特别是针对金属制品和瓷器制品等硬质材质制品,能有效的去除金属表面的一切污渍、油渍、焦渍和锈渍,且使用方便,效率高,同时利用自身产生的小细末能有效地吸附污渍颗粒,用水或其他液体即可冲洗干净,清洗后能有效地防止金属生锈,不会造成重复的污染。1. The present invention provides a stain cleaning product for utensils and its use method, which has a good decontamination and reduction effect, especially for hard material products such as metal products and porcelain products, and can effectively remove all stains, oil stains, and burnt stains on the metal surface. It is easy to use and has high efficiency. At the same time, the small powder produced by itself can effectively absorb stain particles, and it can be rinsed with water or other liquids. After cleaning, it can effectively prevent metal from rusting and will not cause repeated pollution.

2、基于本发明体系,通过采用质量比为(3-5):(2-4):(1-3):1的石膏粉、碳酸钙、沸石粉和活性炭粉组合作为研磨剂,使制备得到的产品不损伤基材的同时有效去除污渍。2. Based on the system of the present invention, the combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder with a mass ratio of (3-5): (2-4): (1-3): 1 is used as an abrasive to prepare The resulting product effectively removes stains without damaging the substrate.

3、基于本发明体系,通过控制研磨剂、粘合剂的质量比为10:(1-2)以保证器具或设备的污渍清洁效果同时,将研磨剂粘合为方便使用的块状固体物,有助于实现大规模工业化生产使用。3. Based on the system of the present invention, by controlling the mass ratio of the abrasive to the binder to be 10: (1-2) to ensure the stain cleaning effect of the utensil or equipment, the abrasive is bonded into a convenient block solid , contribute to the realization of large-scale industrial production and use.

4、本发明通过采用质量比为(3-5):(0.1-0.5):1的有机树脂、石膏、硅酸盐的组合为粘合剂,尤其是采用质量比为(1-3):1的两种不同固含量和粘度的液体酚醛树脂A和液体酚醛树脂B,实现体系中石膏粉、碳酸钙、沸石粉和碳粉之间的有效结合,同时使制备得到的产品具有合适的硬度,采用制备得到的产品去刮擦器具表面的污渍时,进行刮擦的部位也开始掉落研磨粉末颗粒,掉落的研磨粉末颗粒一方面在刮擦的过程中起到辅助研磨的作用,另一方面起到吸附掉落的污渍颗粒的作用,整体实现优异的清洁效果,同时避免重复污染。4. The present invention adopts the combination of organic resin, gypsum and silicate as the adhesive by adopting the mass ratio of (3-5): (0.1-0.5): 1, especially adopting the mass ratio of (1-3): 1. Two kinds of liquid phenolic resin A and liquid phenolic resin B with different solid content and viscosity, realize the effective combination of gypsum powder, calcium carbonate, zeolite powder and carbon powder in the system, and at the same time make the prepared product have suitable hardness When the prepared product is used to scrape the stains on the surface of the utensil, the scraped part also begins to drop abrasive powder particles. The dropped abrasive powder particles play an auxiliary grinding role in the scraping process on the one hand. On the one hand, it plays the role of absorbing the fallen dirt particles, and achieves excellent cleaning effect as a whole, while avoiding repeated pollution.

5、基于本发明体系,引入5-15重量份的磷酸盐类化合物,尤其是引入质量比为(3-5):1的焦磷酸四钾和六偏磷酸钠的组合,一方面提高产品对器具或设备顽强物质的去除效果,另一方面提高研磨剂在粘合剂中的分散效果和结合能力,便于产品后续赋形。5. Based on the system of the present invention, the introduction of 5-15 parts by weight of phosphate compounds, especially the introduction of a combination of tetrapotassium pyrophosphate and sodium hexametaphosphate with a mass ratio of (3-5): 1, improves the product on the one hand. The removal effect of tenacious substances in appliances or equipment, on the other hand, improves the dispersion effect and binding ability of abrasives in binders, and facilitates the subsequent shaping of products.

6、本发明通过引入4-8重量份聚合物水溶液和0.5-2重量份碱式盐水溶液,尤其是引入的聚合物水溶液为质量浓度为0.5-2%的藻酸丙二醇酯水溶液和质量浓度为8-12%的乙酸铝水溶液,有效抑制由于大量研磨剂的引入导致的噪音,提升使用体验感。6. The present invention introduces 4-8 parts by weight of polymer aqueous solution and 0.5-2 parts by weight of basic saline solution, especially the introduced polymer solution is a propylene glycol alginate aqueous solution with a mass concentration of 0.5-2% and a mass concentration of 8-12% aluminum acetate aqueous solution can effectively suppress the noise caused by the introduction of a large amount of abrasives and improve the user experience.

附图说明Description of drawings

图1为瓷器使用本发明实施例1提供的产品去除污渍前、使用产品研磨30s后用清水冲洗后的对比图,图中(a)使用前,(b)使用后。Fig. 1 is a comparison diagram of porcelain before using the product provided by Example 1 of the present invention to remove stains, and after using the product for 30 seconds and rinsing with water, in which (a) before use and (b) after use.

图2为本发明实施例1提供的器具污渍清洗产品实际产品图。Fig. 2 is an actual product diagram of the appliance stain cleaning product provided in Example 1 of the present invention.

具体实施方式Detailed ways

实施例1Example 1

参见图2,本发明的实施例1一方面提供了一种器具污渍清洗产品,按照重量份计,其制备原料包括研磨剂100份、粘合剂10份。Referring to FIG. 2 , Example 1 of the present invention provides, on the one hand, a stain cleaning product for utensils. The raw materials for its preparation include 100 parts of abrasive and 10 parts of adhesive in parts by weight.

所述研磨剂为石膏粉、碳酸钙、沸石粉和活性炭粉的组合;所述石膏粉、碳酸钙、沸石粉和活性炭粉的质量比为4:3:2:1。The grinding agent is a combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder; the mass ratio of the gypsum powder, calcium carbonate, zeolite powder and activated carbon powder is 4:3:2:1.

所述粘合剂为有机树脂、石膏、硅酸盐的组合,所述有机树脂、石膏、硅酸盐的质量比为4:0.3:1。所述石膏为1000目的石膏粉,所述硅酸盐为硅酸钠。所述有机树脂为液体酚醛树脂。所述液体酚醛树脂为液体酚醛树脂A和液体酚醛树脂B的组合;所述液体酚醛树脂A的固含量为33-41%,粘度(25℃)为5-20mpa.s;所述液体酚醛树脂B的固含量为50-54%,粘度(25℃)为25-40mpa.s。所述液体酚醛树脂A和液体酚醛树脂B的质量比为2:1。所述液体酚醛树脂A(PF9171)和液体酚醛树脂B(PF9501-1)均来源于济南圣泉基团股份有限公司。The binder is a combination of organic resin, gypsum, and silicate, and the mass ratio of the organic resin, gypsum, and silicate is 4:0.3:1. The gypsum is 1000 mesh gypsum powder, and the silicate is sodium silicate. The organic resin is liquid phenolic resin. The liquid phenolic resin is a combination of liquid phenolic resin A and liquid phenolic resin B; the solid content of the liquid phenolic resin A is 33-41%, and the viscosity (25°C) is 5-20mpa.s; the liquid phenolic resin The solid content of B is 50-54%, and the viscosity (25°C) is 25-40mpa.s. The mass ratio of the liquid phenolic resin A to the liquid phenolic resin B is 2:1. Both the liquid phenolic resin A (PF9171) and the liquid phenolic resin B (PF9501-1) come from Jinan Shengquan Group Co., Ltd.

按重量份计,所述器具污渍清洗产品还包括10份磷酸盐类化合物、5份聚合物水溶液、1份碱式盐水溶液。In parts by weight, the appliance stain cleaning product further includes 10 parts of phosphate compounds, 5 parts of polymer aqueous solution, and 1 part of alkaline saline solution.

所述聚合物水溶液为藻酸丙二醇酯水溶液。所述藻酸丙二醇酯水溶液中藻酸丙二醇酯的质量浓度为1%;The polymer aqueous solution is an aqueous solution of propylene glycol alginate. The mass concentration of propylene glycol alginate in the described propylene glycol alginate aqueous solution is 1%;

所述碱式盐水溶液为乙酸铝水溶液;所述乙酸铝水溶液中乙酸铝的质量浓度为10%。The basic salt solution is an aluminum acetate aqueous solution; the mass concentration of aluminum acetate in the aluminum acetate aqueous solution is 10%.

所述器具污渍清洗产品的制备方法为,将研磨剂混合研磨后得到粒度为1200目研磨剂混合料;将研磨剂混合料与粘合剂混合均匀后加入磷酸盐类化合物、聚合物水溶液、碱式盐水溶液搅拌混合30min后得到混合料,将混合料置于一定形状的模具中,在120℃的条件下放置2.5h后即得。The preparation method of the appliance stain cleaning product is as follows: mixing and grinding the abrasive to obtain an abrasive mixture with a particle size of 1200 mesh; mixing the abrasive mixture and the binder evenly, adding phosphate compounds, polymer aqueous solution, alkali Formula saline solution was stirred and mixed for 30 minutes to obtain a mixture, which was placed in a mold of a certain shape and placed at 120°C for 2.5 hours.

本发明的实施例1另一方面提供了一种器具污渍清洗产品的使用方法,采用器具污渍清洗产品去刮擦器具表面的污渍,进行刮擦的部位掉落研磨粉末,之后用水冲洗干净即可。On the other hand, Embodiment 1 of the present invention provides a method of using an appliance stain cleaning product. The appliance stain cleaning product is used to scrape the stains on the surface of the appliance, and the scraping part drops abrasive powder, and then rinses with water. .

实施例2Example 2

本发明的实施例2一方面提供了一种器具污渍清洗产品,按照重量份计,其制备原料包括研磨剂100份、粘合剂15份。Embodiment 2 of the present invention provides, on the one hand, a stain cleaning product for utensils. The raw materials for its preparation include 100 parts of grinding agent and 15 parts of adhesive in parts by weight.

所述研磨剂为石膏粉、碳酸钙、沸石粉和活性炭粉的组合;所述石膏粉、碳酸钙、沸石粉和活性炭粉的质量比为4:3:2:1。The grinding agent is a combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder; the mass ratio of the gypsum powder, calcium carbonate, zeolite powder and activated carbon powder is 4:3:2:1.

所述粘合剂为有机树脂、石膏、硅酸盐的组合,所述有机树脂、石膏、硅酸盐的质量比为4:0.3:1。所述石膏为1000目的石膏粉,所述硅酸盐为硅酸钠。所述有机树脂为液体酚醛树脂,所述液体酚醛树脂为液体酚醛树脂A和液体酚醛树脂B的组合;所述液体酚醛树脂A的固含量为33-41%,粘度(25℃)为5-20mpa.s;所述液体酚醛树脂B的固含量为50-54%,粘度(25℃)为25-40mpa.s。所述液体酚醛树脂A和液体酚醛树脂B的质量比为3:1。所述液体酚醛树脂A(PF9171)和液体酚醛树脂B(PF9501-1)均来源于济南圣泉基团股份有限公司。The binder is a combination of organic resin, gypsum, and silicate, and the mass ratio of the organic resin, gypsum, and silicate is 4:0.3:1. The gypsum is 1000 mesh gypsum powder, and the silicate is sodium silicate. Described organic resin is liquid phenolic resin, and described liquid phenolic resin is the combination of liquid phenolic resin A and liquid phenolic resin B; The solid content of described liquid phenolic resin A is 33-41%, and viscosity (25 ℃) is 5- 20mpa.s; the solid content of the liquid phenolic resin B is 50-54%, and the viscosity (25°C) is 25-40mpa.s. The mass ratio of the liquid phenolic resin A to the liquid phenolic resin B is 3:1. Both the liquid phenolic resin A (PF9171) and the liquid phenolic resin B (PF9501-1) come from Jinan Shengquan Group Co., Ltd.

按重量份计,所述器具污渍清洗产品还包括10份磷酸盐类化合物、5份聚合物水溶液、1份碱式盐水溶液。In parts by weight, the appliance stain cleaning product further includes 10 parts of phosphate compounds, 5 parts of polymer aqueous solution, and 1 part of alkaline saline solution.

所述聚合物水溶液为藻酸丙二醇酯水溶液。所述藻酸丙二醇酯水溶液中藻酸丙二醇酯的质量浓度为1%;The polymer aqueous solution is an aqueous solution of propylene glycol alginate. The mass concentration of propylene glycol alginate in the described propylene glycol alginate aqueous solution is 1%;

所述碱式盐水溶液为乙酸铝水溶液;所述乙酸铝水溶液中乙酸铝的质量浓度为10%。The basic salt solution is an aluminum acetate aqueous solution; the mass concentration of aluminum acetate in the aluminum acetate aqueous solution is 10%.

所述器具污渍清洗产品的制备方法为,将研磨剂混合研磨后得到粒度为1200目研磨剂混合料;将研磨剂混合料与粘合剂混合均匀后加入磷酸盐类化合物、聚合物水溶液、碱式盐水溶液搅拌混合30min后得到混合料,将混合料置于一定形状的模具中,在120℃的条件下放置2.5h后即得。The preparation method of the appliance stain cleaning product is as follows: mixing and grinding the abrasive to obtain an abrasive mixture with a particle size of 1200 mesh; mixing the abrasive mixture and the binder evenly, adding phosphate compounds, polymer aqueous solution, alkali Formula saline solution was stirred and mixed for 30 minutes to obtain a mixture, which was placed in a mold of a certain shape and placed at 120°C for 2.5 hours.

本发明的实施例2另一方面提供了一种器具污渍清洗产品的使用方法,采用器具污渍清洗产品去刮擦器具表面的污渍,进行刮擦的部位掉落研磨粉末,之后用水冲洗干净即可。On the other hand, Embodiment 2 of the present invention provides a method of using an appliance stain cleaning product. The appliance stain cleaning product is used to scrape the stains on the surface of the appliance, and the scraping part drops abrasive powder, and then rinses it with water. .

实施例3Example 3

本发明的实施例3一方面提供了一种器具污渍清洗产品,按照重量份计,其制备原料包括研磨剂100份、粘合剂8份。Embodiment 3 of the present invention provides, on the one hand, a stain cleaning product for utensils. The raw materials for its preparation include 100 parts of grinding agent and 8 parts of adhesive in parts by weight.

所述研磨剂为石膏粉、碳酸钙、沸石粉和活性炭粉的组合;所述石膏粉、碳酸钙、沸石粉和活性炭粉的质量比为4:3:2:1。The grinding agent is a combination of gypsum powder, calcium carbonate, zeolite powder and activated carbon powder; the mass ratio of the gypsum powder, calcium carbonate, zeolite powder and activated carbon powder is 4:3:2:1.

所述粘合剂为有机树脂、石膏、硅酸盐的组合,所述有机树脂、石膏、硅酸盐的质量比为4:0.3:1。所述石膏为1000目的石膏粉,所述硅酸盐为硅酸钠。所述有机树脂为液体酚醛树脂,所述液体酚醛树脂为液体酚醛树脂A和液体酚醛树脂B的组合;所述液体酚醛树脂A的固含量为33-41%,粘度(25℃)为5-20mpa.s;所述液体酚醛树脂B的固含量为50-54%,粘度(25℃)为25-40mpa.s。所述液体酚醛树脂A和液体酚醛树脂B的质量比为1:1。所述液体酚醛树脂A(PF9171)和液体酚醛树脂B(PF9501-1)均来源于济南圣泉基团股份有限公司。The binder is a combination of organic resin, gypsum, and silicate, and the mass ratio of the organic resin, gypsum, and silicate is 4:0.3:1. The gypsum is 1000 mesh gypsum powder, and the silicate is sodium silicate. Described organic resin is liquid phenolic resin, and described liquid phenolic resin is the combination of liquid phenolic resin A and liquid phenolic resin B; The solid content of described liquid phenolic resin A is 33-41%, and viscosity (25 ℃) is 5- 20mpa.s; the solid content of the liquid phenolic resin B is 50-54%, and the viscosity (25°C) is 25-40mpa.s. The mass ratio of the liquid phenolic resin A to the liquid phenolic resin B is 1:1. Both the liquid phenolic resin A (PF9171) and the liquid phenolic resin B (PF9501-1) come from Jinan Shengquan Group Co., Ltd.

按重量份计,所述器具污渍清洗产品还包括10份磷酸盐类化合物、5份聚合物水溶液、1份碱式盐水溶液。In parts by weight, the appliance stain cleaning product further includes 10 parts of phosphate compounds, 5 parts of polymer aqueous solution, and 1 part of alkaline saline solution.

所述聚合物水溶液为藻酸丙二醇酯水溶液。所述藻酸丙二醇酯水溶液中藻酸丙二醇酯的质量浓度为1%;The polymer aqueous solution is an aqueous solution of propylene glycol alginate. The mass concentration of propylene glycol alginate in the described propylene glycol alginate aqueous solution is 1%;

所述碱式盐水溶液为乙酸铝水溶液;所述乙酸铝水溶液中乙酸铝的质量浓度为10%。The basic salt solution is an aluminum acetate aqueous solution; the mass concentration of aluminum acetate in the aluminum acetate aqueous solution is 10%.

所述器具污渍清洗产品的制备方法为,将研磨剂混合研磨后得到粒度为1200目研磨剂混合料;将研磨剂混合料与粘合剂混合均匀后加入磷酸盐类化合物、聚合物水溶液、碱式盐水溶液搅拌混合30min后得到混合料,将混合料置于一定形状的模具中,在120℃的条件下放置2.5h后即得。The preparation method of the appliance stain cleaning product is as follows: mixing and grinding the abrasive to obtain an abrasive mixture with a particle size of 1200 mesh; mixing the abrasive mixture and the binder evenly, adding phosphate compounds, polymer aqueous solution, alkali Formula saline solution was stirred and mixed for 30 minutes to obtain a mixture, which was placed in a mold of a certain shape and placed at 120°C for 2.5 hours.

本发明的实施例3另一方面提供了一种器具污渍清洗产品的使用方法,采用器具污渍清洗产品去刮擦器具表面的污渍,进行刮擦的部位掉落研磨粉末,之后用水冲洗干净即可。Embodiment 3 of the present invention, on the other hand, provides a method of using an appliance stain cleaning product. The appliance stain cleaning product is used to scrape the stains on the surface of the appliance, and the scraped part drops abrasive powder, and then rinses with water. .

对比例1Comparative example 1

本发明的对比例1提供了一种器具污渍清洗产品及其使用方法,其具体实施方式同实施例1,不同之处在于,按照重量份计,其制备原料包括研磨剂150份、粘合剂10份、磷酸盐类化合物10份、聚合物水溶液5份、碱式盐水溶液1份。Comparative Example 1 of the present invention provides a product for cleaning utensil stains and its use method, its specific implementation is the same as that of Example 1, the difference is that, in parts by weight, its preparation raw materials include 150 parts of grinding agent, adhesive 10 parts, 10 parts of phosphate compound, 5 parts of polymer aqueous solution, 1 part of alkaline saline solution.

对比例2Comparative example 2

本发明的对比例2提供了一种器具污渍清洗产品,其具体实施方式同实施例1,不同之处在于,按照重量份计,其制备原料包括研磨剂100份、粘合剂10份、磷酸盐类化合物10份。Comparative Example 2 of the present invention provides a product for cleaning utensil stains, its specific implementation is the same as that of Example 1, the difference is that, in parts by weight, its preparation raw materials include 100 parts of abrasive, 10 parts of binder, phosphoric acid 10 parts of salt compound.

对比例3Comparative example 3

本发明的对比例3提供了一种器具污渍清洗产品,其具体实施方式同实施例1,不同之处在于,所述液体酚醛树脂的固含量为55-59%,粘度(25℃)为50-150mpa.s,所述液体酚醛树脂(PF9400)来源于济南圣泉基团股份有限公司。Comparative example 3 of the present invention provides a kind of utensil stain cleaning product, and its specific embodiment is the same as embodiment 1, and difference is that, the solid content of described liquid phenolic resin is 55-59%, and viscosity (25 ℃) is 50 -150mpa.s, the liquid phenolic resin (PF9400) comes from Jinan Shengquan Group Co., Ltd.

对比例4Comparative example 4

本发明的对比例4提供了一种器具污渍清洗产品,其具体实施方式同实施例1,不同之处在于,所述聚合物水溶液为羧甲基纤维素钠水溶液。所羧甲基纤维素钠水溶液的质量浓度为1%。Comparative Example 4 of the present invention provides a product for cleaning utensil stains, and its specific implementation method is the same as that of Example 1, except that the polymer aqueous solution is an aqueous solution of sodium carboxymethylcellulose. The mass concentration of the sodium carboxymethylcellulose aqueous solution is 1%.

对比例5Comparative example 5

本发明的对比例5提供了一种器具污渍清洗产品,其具体实施方式同实施例1,不同之处在于,其制备原料包括研磨剂100份、粘合剂10份、磷酸盐类化合物10份、聚合物水溶液5份。Comparative Example 5 of the present invention provides a product for cleaning utensil stains. Its specific implementation method is the same as that of Example 1, except that its preparation raw materials include 100 parts of abrasives, 10 parts of binders, and 10 parts of phosphate compounds. , 5 parts of polymer aqueous solution.

性能测试方法performance test method

1、按照实施例和对比例提供的使用方法对器具进行研磨清洁,采用声级计测定研磨过程中产生的摩擦噪声强度,记录研磨过程中的最大频率,结果参见表1。1. Grind and clean the utensils according to the usage methods provided in the examples and comparative examples, use a sound level meter to measure the intensity of friction noise generated during the grinding process, and record the maximum frequency during the grinding process. The results are shown in Table 1.

2、粗糙度变化率,取一洁净干燥的不锈钢器具,采用实施例及对比例提供的产品对器具内壁不同位置研磨刮擦相同时间,记录摩擦前后器具表面粗糙度,采用公式计算粗糙度变化率=(研磨后粗糙度-研磨前粗糙度)×100%/研磨前粗糙度,结果参见表1。2. Roughness change rate, take a clean and dry stainless steel appliance, use the products provided in the examples and comparative examples to grind and scrape different positions on the inner wall of the appliance for the same time, record the surface roughness of the appliance before and after friction, and use the formula to calculate the roughness change rate =(roughness after grinding-roughness before grinding)×100%/roughness before grinding, see Table 1 for the results.

3、清洁效果,采用实施例1提供的使用方法采用器具污渍清洗产品用于瓷器内壁污渍的去除,瓷器使用产品去除污渍前、使用产品研磨30s后用清水冲洗后的对比图参见图1,证明在实施例1提供的使用方法下,实施例1提供的产品具有快速去除污渍的效果。3. Cleaning effect, using the method provided in Example 1, using the stain cleaning product for utensils to remove stains on the inner wall of porcelain, before using the product to remove stains on porcelain, and after using the product to grind for 30 seconds and rinsing with clean water, see Figure 1 for a comparison chart, which proves Under the use method provided in Example 1, the product provided in Example 1 has the effect of quickly removing stains.

表1、Table 1,

最大频率(Hz)Maximum frequency (Hz) 粗糙度变化率(%)Roughness change rate (%) 实施例1Example 1 200200 0.10.1 实施例2Example 2 220220 0.20.2 实施例3Example 3 230230 0.30.3 对比例1Comparative example 1 380380 33 对比例2Comparative example 2 350350 2.52.5 对比例3Comparative example 3 320320 22 对比例4Comparative example 4 280280 1.51.5 对比例5Comparative example 5 300300 1.81.8

Claims (10)

1.一种器具污渍清洗产品,其特征在于,按照重量份计,其制备原料至少包括研磨剂50-150份、粘合剂5-50份。1. A product for cleaning utensil stains, characterized in that, in parts by weight, its preparation raw materials include at least 50-150 parts of abrasive and 5-50 parts of adhesive. 2.根据权利要求1所述的一种器具污渍清洗产品,其特征在于,所述研磨剂、粘合剂的质量比为10:(1-10),优选为10:(1-2)。2. A product for cleaning utensils and stains according to claim 1, characterized in that the mass ratio of the abrasive to the binder is 10:(1-10), preferably 10:(1-2). 3.根据权利要求1或2所述的一种器具污渍清洗产品,其特征在于,所述研磨剂为沸石粉、滑石粉、石膏粉、碳酸钙、氧化硅、氧化钛、石英粉、活性炭粉、碳化硅、氧化铝、植物粉末中的至少一种。3. A kind of utensil stain cleaning product according to claim 1 or 2, characterized in that, the abrasive is zeolite powder, talcum powder, gypsum powder, calcium carbonate, silicon oxide, titanium oxide, quartz powder, activated carbon powder , silicon carbide, aluminum oxide, plant powder at least one. 4.根据权利要求3所述的一种器具污渍清洗产品,其特征在于,所述粘合剂为有机树脂、松香、石膏、硅酸盐、粘土、石灰、植物胶中一种或几种的组合。4. A kind of utensil stain cleaning product according to claim 3, characterized in that, the adhesive is one or more of organic resin, rosin, gypsum, silicate, clay, lime, vegetable glue combination. 5.根据权利要求4所述的一种器具污渍清洗产品,其特征在于,所述粘合剂为有机树脂、石膏、硅酸盐的组合,所述有机树脂、石膏、硅酸盐的质量比为(3-5):(0.1-0.5):1。5. A kind of appliance stain cleaning product according to claim 4, is characterized in that, described binding agent is the combination of organic resin, gypsum, silicate, and the mass ratio of described organic resin, gypsum, silicate is (3-5):(0.1-0.5):1. 6.根据权利要求5所述的一种器具污渍清洗产品,其特征在于,所述有机树脂为液体酚醛树脂,所述液体酚醛树脂的固含量为30-55%,所述液体酚醛树脂的粘度为5-55mpa.s。6. a kind of utensil stain cleaning product according to claim 5, is characterized in that, described organic resin is liquid phenolic resin, and the solid content of described liquid phenolic resin is 30-55%, the viscosity of described liquid phenolic resin 5-55mpa.s. 7.根据权利要求3所述的一种器具污渍清洗产品,其特征在于,按重量份计,所述器具污渍清洗产品还包括5-15份磷酸盐类化合物、4-8份聚合物水溶液、0.5-2份碱式盐水溶液。7. A kind of utensil stain cleaning product according to claim 3, characterized in that, in parts by weight, the utensil stain cleaning product further comprises 5-15 parts of phosphate compounds, 4-8 parts of polymer aqueous solution, 0.5-2 parts of basic saline solution. 8.根据权利要求7所述的一种器具污渍清洗产品,其特征在于,所述磷酸盐类化合物为六偏磷酸钠、焦磷酸钠、焦磷酸四钾、三聚磷酸钠中的至少一种。8. A kind of utensil stain cleaning product according to claim 7, characterized in that, the phosphate compound is at least one of sodium hexametaphosphate, sodium pyrophosphate, tetrapotassium pyrophosphate, and sodium tripolyphosphate . 9.根据权利要求7所述的一种器具污渍清洗产品,其特征在于,所述聚合物水溶液为藻酸丙二醇酯水溶液、羧甲基纤维素钠水溶液中的至少一种。9. A kind of utensil stain cleaning product according to claim 7, characterized in that, the aqueous polymer solution is at least one of an aqueous solution of propylene glycol alginate and an aqueous solution of sodium carboxymethylcellulose. 10.一种根据权利要求1-9任一项所述的器具污渍清洗产品的使用方法,其特征在于,采用器具污渍清洗产品去刮擦器具表面的污渍,进行刮擦的部位掉落研磨粉末,之后用水冲洗干净即可。10. A method for using the appliance stain cleaning product according to any one of claims 1-9, characterized in that, the appliance stain cleaning product is used to scrape the stains on the surface of the appliance, and the scraped part drops abrasive powder , then rinse with water.
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CN101767318A (en) * 2010-02-11 2010-07-07 北京国瑞升科技有限公司 Granulation polishing film, preparing method thereof and application thereof
CN103770018A (en) * 2014-01-10 2014-05-07 当涂县南方红月磨具磨料有限公司 Ceramic zirconia-corundum grinding wheel for high-speed grinding

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1284904A (en) * 1997-11-03 2001-02-21 美国3M公司 Abrasive article containing grinding aid and method of making the same
CN101115429A (en) * 2005-02-04 2008-01-30 3M创新有限公司 Abrasive articles and methods for their preparation
CN101219530A (en) * 2008-02-03 2008-07-16 北京国瑞升科技有限公司 Granulated abrasive paper and its preparation method and application
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