CN115863183B - Manufacturing method of micro-flow channel with measurable flow for heat dissipation of three-dimensional integrated wafer system - Google Patents
Manufacturing method of micro-flow channel with measurable flow for heat dissipation of three-dimensional integrated wafer system Download PDFInfo
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- Y02D10/00—Energy efficient computing, e.g. low power processors, power management or thermal management
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Abstract
Description
技术领域technical field
本申请涉及电子技术领域,尤其涉及用于三维集成晶圆系统散热的流量可测的微流道制造方法。The present application relates to the field of electronic technology, in particular to a method for manufacturing a flow-measureable microfluidic channel for heat dissipation of a three-dimensional integrated wafer system.
背景技术Background technique
在“后摩尔时代”随着先进封装技术的发展,不同的芯片可以通过高密度三维堆叠集成起来,从而大幅度提升了系统的性能。但是高密度集成系统会产生大量的热量,严重影响芯片的正常工作。近年来,人们开始使用载有冷却液的微流道对三维集成的芯片内部进行散热。一种传统的做法是在芯片的背面刻蚀出微流道的槽体结构,再与另一片同样刻蚀有微流道槽体结构的硅片或玻璃片进行对准键合形成微流道闭合管路;另一种常见的做法是在芯片的背面涂覆有机聚合并刻蚀出微流道的槽体结构,再与其他衬片贴合形成微流道闭合管路。传统的做法均需要额外引入其他衬片和键合工艺,不仅增加工艺复杂程度而且也增加了芯片的厚度。In the "post-Moore era", with the development of advanced packaging technology, different chips can be integrated through high-density three-dimensional stacking, which greatly improves the performance of the system. However, a high-density integrated system will generate a lot of heat, which seriously affects the normal operation of the chip. In recent years, people have begun to use microfluidic channels loaded with cooling fluid to dissipate heat inside three-dimensionally integrated chips. A traditional method is to etch the groove structure of the microchannel on the back of the chip, and then align and bond with another silicon wafer or glass sheet with the groove structure of the microchannel etched to form the microchannel. Closed pipeline; Another common practice is to coat the back of the chip with organic polymer and etch the groove structure of the microfluidic channel, and then bond it with other linings to form a closed microfluidic pipeline. Traditional methods require the introduction of additional substrates and bonding processes, which not only increases the complexity of the process but also increases the thickness of the chip.
发明内容Contents of the invention
针对现有技术存在的问题,本申请实施例的目的是提供含有压阻式流量检测功能的晶圆散热微流道的制备方法,基于绝缘体上硅(SOI, Silicon-On-Insulator)晶圆开发了埋氧层二氧化硅牺牲释放工艺,不需要填充有机聚合物,而只依靠SOI晶圆的器件层硅、埋氧层二氧化硅和衬底层硅就能构成微流道闭合管路;开发了电镀铜封闭工艺和内壁选择性化学镀铜工艺,形成的铜柱热沉和内壁金属化铜层大幅度提升了微流道的散热能力;同时,本发明还在微流道中集成了压阻式流量计,可以对冷却液微流体的流速和温度进行实时的检测。In view of the problems existing in the prior art, the purpose of the embodiment of this application is to provide a method for preparing a wafer cooling microfluidic channel with a piezoresistive flow detection function, which is developed based on a silicon-on-insulator (SOI, Silicon-On-Insulator) wafer The silicon dioxide buried oxide layer sacrificial release process has been implemented, which does not need to be filled with organic polymers, and only relies on the device layer silicon, buried oxide layer silicon dioxide, and substrate layer silicon of the SOI wafer to form a closed microfluidic channel; the development The electroplating copper sealing process and the selective electroless copper plating process on the inner wall are adopted, and the formed copper column heat sink and metallized copper layer on the inner wall greatly improve the heat dissipation capacity of the micro-channel; at the same time, the invention also integrates piezoresistive in the micro-channel The flowmeter can detect the flow rate and temperature of the coolant microfluid in real time.
根据本申请实施例的第一方面,提供一种用于三维集成晶圆系统散热的流量可测的微流道制造方法,包括:According to the first aspect of the embodiment of the present application, there is provided a method for manufacturing a microfluidic channel with measurable flow rate for heat dissipation of a three-dimensional integrated wafer system, including:
压阻式流量计制造步骤:在绝缘体上硅晶圆的上表面构造第一力敏应变结构并构造力敏电阻和测温电阻;Manufacturing steps of the piezoresistive flowmeter: constructing a first force-sensitive strain structure on the upper surface of the silicon-on-insulator wafer and constructing a force-sensitive resistor and a temperature-measuring resistor;
埋氧层二氧化硅释放步骤:在所述绝缘体上硅晶圆的上表面刻蚀释放孔,并用湿法腐蚀所述释放孔下方的埋氧层二氧化硅,形成微流道;The silicon dioxide buried oxide layer release step: etching a release hole on the upper surface of the silicon-on-insulator wafer, and etching the silicon dioxide buried oxide layer below the release hole by a wet method to form a microfluidic channel;
释放孔电镀铜封闭步骤:在所述绝缘体上硅晶圆的上表面和所述释放孔的侧壁沉积种子层金属,基于所述种子层电镀铜形成铜柱封闭所述微流道的上表面;Release hole electroplating copper sealing step: deposit seed layer metal on the upper surface of the silicon-on-insulator wafer and the sidewall of the release hole, and form copper pillars to seal the upper surface of the microchannel based on the seed layer copper plating ;
微流道内壁无机镀铜步骤:使用化学法在所述微流道的内壁上下表面镀上铜散热层。The step of inorganic copper plating on the inner wall of the micro-channel: using a chemical method to plate a copper heat dissipation layer on the upper and lower surfaces of the inner wall of the micro-channel.
进一步地,所述绝缘体上硅晶圆为带有有源集成电路的背面或已完成硅垂直通孔和重布线层的硅晶圆转接板的背面。Further, the silicon-on-insulator wafer is the backside of an active integrated circuit or a backside of a silicon wafer interposer with completed silicon vertical vias and a rewiring layer.
进一步地,所述压阻式流量计制造步骤包括:Further, the manufacturing steps of the piezoresistive flowmeter include:
在所述绝缘体上硅晶圆的上表面光刻刻蚀形成第一力敏应变结构,所述第一力敏应变结构为悬臂梁、折叠梁-平板或带孔薄膜;Forming a first force-sensitive strain structure by photolithography etching on the upper surface of the silicon-on-insulator wafer, and the first force-sensitive strain structure is a cantilever beam, a folded beam-plate or a film with holes;
在所述第一力敏应变结构上通过离子注入形成半导体力敏电阻;forming a semiconductor force sensitive resistor on the first force sensitive strain structure by ion implantation;
在所述力敏电阻的附近通过沉积金属形成测温电阻;forming a temperature measuring resistor by depositing metal near the force sensitive resistor;
溅射铬/金形成所述力敏电阻的欧姆接触电极及所述测温电阻的互连线,等离子增强化学气相淀积沉积第一钝化层二氧化硅。Chromium/gold is sputtered to form the ohmic contact electrode of the force sensitive resistor and the interconnection line of the temperature measuring resistor, and the first passivation layer silicon dioxide is deposited by plasma enhanced chemical vapor deposition.
进一步地,所述埋氧层二氧化硅释放步骤包括:Further, the step of releasing silicon dioxide from the buried oxide layer includes:
在所述绝缘体上硅晶圆的上表面光刻刻蚀释放孔和冷却液进出孔;Photoetching release holes and coolant inlet and outlet holes on the upper surface of the silicon-on-insulator wafer;
在所述冷却液进出孔的外侧侧壁和所述绝缘体上硅上表面的第一钝化层二氧化硅上涂布厚光刻胶,其中所述厚光刻胶的厚度≥10微米;Coating a thick photoresist on the outer sidewall of the cooling liquid inlet and outlet hole and the first passivation layer silicon dioxide on the upper surface of the silicon-on-insulator, wherein the thickness of the thick photoresist is ≥ 10 microns;
通过所述释放孔和冷却液进出孔将所述释放孔下方的埋氧层二氧化硅湿法腐蚀,形成供冷却液水平方向流动的微流道。The silicon dioxide buried oxide layer under the release hole is wet-etched through the release hole and the cooling liquid inlet and outlet holes to form a micro flow channel for the cooling liquid to flow in the horizontal direction.
进一步地,所述释放孔电镀铜封闭步骤包括:Further, the release hole electroplating copper sealing step includes:
在所述绝缘体上硅晶圆的上表面和所述释放孔的侧壁沉积铬/铜种子层;Depositing a chromium/copper seed layer on the upper surface of the silicon-on-insulator wafer and the sidewalls of the release holes;
通过电镀的方法在所述释放孔中生长铜形成铜柱热沉;growing copper in the release hole by electroplating to form a copper pillar heat sink;
剥离表面的厚光刻胶,其中所述厚光刻胶的厚度≥10微米;peeling off the thick photoresist on the surface, wherein the thickness of the thick photoresist is ≥ 10 microns;
在所述绝缘体上硅晶圆的下表面沉积第二钝化层二氧化硅。A second passivation layer silicon dioxide is deposited on the lower surface of the silicon-on-insulator wafer.
进一步地,所述微流道内壁无机镀铜步骤包括:Further, the step of inorganic copper plating on the inner wall of the microchannel comprises:
将所述绝缘体上硅晶圆浸入化学镀铜溶液中,则在所述微流道的内壁的上下表面形成上表面铜沉积层和下表面铜沉积层。Immersing the silicon-on-insulator wafer into the electroless copper plating solution forms an upper surface copper deposition layer and a lower surface copper deposition layer on the upper and lower surfaces of the inner wall of the micro flow channel.
进一步地于,所述化学镀铜溶液包括激活液和反应溶液,所述绝缘体上硅晶圆先浸入所述激活液中激活,再浸入所述反应溶液中镀铜,其中所述激活液的成分包括去离子水、氢氟酸和氯化钯,所述反应溶液的成分包括硫酸铜和甲醛。Further, the electroless copper plating solution includes an activation solution and a reaction solution, the silicon-on-insulator wafer is first immersed in the activation solution for activation, and then immersed in the reaction solution for copper plating, wherein the composition of the activation solution Comprising deionized water, hydrofluoric acid and palladium chloride, the components of the reaction solution include copper sulfate and formaldehyde.
进一步地,还包括震动补偿步骤,所述震动补偿步骤设置在所述埋氧层二氧化硅释放步骤之前,该步骤包括:Further, a vibration compensation step is also included, the vibration compensation step is arranged before the buried oxide layer silicon dioxide release step, and this step includes:
在所述微流道外侧,在所述绝缘体上硅晶圆的上表面构造第二力敏应变结构,以消除震动对流体压力测量产生的误差。On the outside of the micro-flow channel, a second force-sensitive strain structure is constructed on the upper surface of the silicon-on-insulator wafer, so as to eliminate errors caused by vibrations in fluid pressure measurement.
进一步地,在所述微流道内壁无机镀铜步骤之后,去除所述第二钝化层二氧化硅。Further, after the step of inorganic copper plating on the inner wall of the micro-channel, the silicon dioxide of the second passivation layer is removed.
根据本申请实施例的第二方面,提供一种根据第一方面所述的方法制造得到的用于三维集成晶圆系统散热的流量可测的微流道的应用,用于制备带有硅垂直通孔或重布线层的硅晶圆转接板,以用于多层集成电路芯片或晶圆的三维垂直堆叠集成。According to the second aspect of the embodiment of the present application, there is provided an application of the microfluidic channel with measurable flow rate for the heat dissipation of the three-dimensional integrated wafer system manufactured according to the method described in the first aspect, which is used to prepare a silicon vertical Silicon wafer interposer with via or redistribution layers for 3D vertical stack integration of multilayer integrated circuit chips or wafers.
本申请的实施例提供的技术方案可以包括以下有益效果:The technical solutions provided by the embodiments of the present application may include the following beneficial effects:
第一,本申请基于SOI晶圆直接在晶圆背部制作微流体通路,无需与其他带有微流道的硅片或玻璃片键合形成微流道,降低了工艺复杂度;First, this application directly manufactures microfluidic channels on the back of the wafer based on SOI wafers, without bonding with other silicon wafers or glass sheets with microchannels to form microchannels, which reduces the complexity of the process;
第二,本申请巧妙地开发了基于SOI晶圆的埋氧层二氧化硅牺牲释放工艺,不需要填充有机聚合物,而只依靠SOI晶圆的器件层硅、埋氧层二氧化硅和衬底层硅就能构成微流道闭合管路;Second, the present application skillfully developed a sacrificial release process based on SOI wafer buried oxide layer silicon dioxide, which does not need to be filled with organic polymers, but only relies on the device layer silicon, buried oxide layer silicon dioxide and liner of SOI wafer. The underlying silicon can form a microfluidic closed circuit;
第三,本申请巧妙地开发了电镀铜封闭工艺和内壁选择性化学镀铜工艺,其中电镀铜柱结构不仅可以封闭微流道侧壁,而且可以形成热沉结构提升散热能力;内壁选择性化学镀铜工艺可以在微流道内壁的上下表面沉积铜层,进一步提升微流道内壁的散热能力;Thirdly, this application has skillfully developed the copper electroplating sealing process and the selective electroless copper plating process on the inner wall. The copper plating process can deposit a copper layer on the upper and lower surfaces of the inner wall of the microchannel to further improve the heat dissipation capacity of the inner wall of the microchannel;
第四,本申请开发了与微流道晶上集成的压阻式流量计,并且具有温度补偿和震动补偿的功能,可以实时监测冷却液的流速和温度。Fourth, the present application has developed a piezoresistive flowmeter integrated with the microchannel crystal, and has the functions of temperature compensation and vibration compensation, and can monitor the flow rate and temperature of the cooling liquid in real time.
应当理解的是,以上的一般描述和后文的细节描述仅是示例性和解释性的,并不能限制本申请。It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the application.
附图说明Description of drawings
此处的附图被并入说明书中并构成本说明书的一部分,示出了符合本申请的实施例,并与说明书一起用于解释本申请的原理。The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the application and together with the description serve to explain the principles of the application.
图1是根据一示例性实施例示出的用于三维集成晶圆系统散热的流量可测的微流道制造方法的流程图,其中图1中的(a)-图1中的(h)是用于三维集成晶圆系统散热的流量可测的微流道制造方法中各流程的结构示意图。Fig. 1 is a flow chart of a method for manufacturing a microfluidic channel with measurable flow rate for heat dissipation in a three-dimensional integrated wafer system according to an exemplary embodiment, wherein (a) in Fig. 1 - (h) in Fig. 1 are Schematic diagram of the structure of each process in the flow-measurable microfluidic channel manufacturing method for the heat dissipation of the three-dimensional integrated wafer system.
图2是根据一示例性实施例示出的震动补偿结构的示意图。Fig. 2 is a schematic diagram of a vibration compensation structure according to an exemplary embodiment.
图3是根据一示例性实施例示出的一种用于三维集成晶圆系统散热的流量可测的微流道的俯视示意图。Fig. 3 is a schematic top view of a flow-measurable microfluidic channel used for heat dissipation in a three-dimensional integrated wafer system according to an exemplary embodiment.
图4是根据一示例性实施例示出的一种用于三维集成晶圆系统散热的流量可测的微流道在三维集成应用领域的一个实施例示意图。Fig. 4 is a schematic diagram of an embodiment of a flow-measurable microfluidic channel used for heat dissipation of a three-dimensional integrated wafer system in the field of three-dimensional integration application according to an exemplary embodiment.
图中:1、SOI晶圆;2、第一力敏应变结构;3、力敏电阻;4、测温电阻;5、第一钝化层二氧化硅;6、释放孔;7、埋氧层二氧化硅;8、冷却液进出孔;9、厚光刻胶;10、微流道;11、闭合柱体;12、第二钝化层二氧化硅;13、上表面铜沉积层;14、下表面铜沉积层;15、第二力敏应变结构;16、集成电路芯片;17、微凸点;18、重布线层;19、硅垂直通孔。In the figure: 1. SOI wafer; 2. The first force-sensitive strain structure; 3. Force-sensitive resistor; 4. Temperature measuring resistor; 5. The first passivation layer silicon dioxide; 6. Release hole; 7. Buried oxygen layer of silicon dioxide; 8. Coolant inlet and outlet holes; 9. Thick photoresist; 10. Micro flow channel; 11. Closed cylinder; 12. Second passivation layer of silicon dioxide; 13. Copper deposition layer on the upper surface; 14. Copper deposition layer on the lower surface; 15. Second force-sensitive strain structure; 16. Integrated circuit chip; 17. Micro-bump; 18. Rewiring layer; 19. Silicon vertical via.
具体实施方式Detailed ways
这里将详细地对示例性实施例进行说明,其示例表示在附图中。下面的描述涉及附图时,除非另有表示,不同附图中的相同数字表示相同或相似的要素。以下示例性实施例中所描述的实施方式并不代表与本申请相一致的所有实施方式。Reference will now be made in detail to the exemplary embodiments, examples of which are illustrated in the accompanying drawings. When the following description refers to the accompanying drawings, the same numerals in different drawings refer to the same or similar elements unless otherwise indicated. The implementations described in the following exemplary embodiments do not represent all implementations consistent with this application.
在本申请使用的术语是仅仅出于描述特定实施例的目的,而非旨在限制本申请。在本申请和所附权利要求书中所使用的单数形式的“一种”、“所述”和“该”也旨在包括多数形式,除非上下文清楚地表示其他含义。还应当理解,本文中使用的术语“和/或”是指并包含一个或多个相关联的列出项目的任何或所有可能组合。The terminology used in this application is for the purpose of describing particular embodiments only, and is not intended to limit the application. As used in this application and the appended claims, the singular forms "a", "the", and "the" are intended to include the plural forms as well, unless the context clearly dictates otherwise. It should also be understood that the term "and/or" as used herein refers to and includes any and all possible combinations of one or more of the associated listed items.
应当理解,尽管在本申请可能采用术语第一、第二、第三等来描述各种信息,但这些信息不应限于这些术语。这些术语仅用来将同一类型的信息彼此区分开。例如,在不脱离本申请范围的情况下,第一信息也可以被称为第二信息,类似地,第二信息也可以被称为第一信息。取决于语境,如在此所使用的词语“如果”可以被解释成为“在……时”或“当……时”或“响应于确定”。It should be understood that although the terms first, second, third, etc. may be used in this application to describe various information, the information should not be limited to these terms. These terms are only used to distinguish information of the same type from one another. For example, without departing from the scope of the present application, first information may also be called second information, and similarly, second information may also be called first information. Depending on the context, the word "if" as used herein may be interpreted as "at" or "when" or "in response to a determination."
图1是根据一示例性实施例示出的用于三维集成晶圆系统散热的流量可测的微流道制造方法的流程图,如图1所示,该方法可以包括以下步骤:Fig. 1 is a flow chart of a method for manufacturing a microfluidic channel with measurable flow rate for heat dissipation in a three-dimensional integrated wafer system according to an exemplary embodiment. As shown in Fig. 1 , the method may include the following steps:
压阻式流量计制造步骤:在绝缘体上硅晶圆的上表面构造第一力敏应变结构2并构造力敏电阻3和测温电阻4;Manufacturing steps of the piezoresistive flowmeter: constructing a first force-
埋氧层二氧化硅7释放步骤:在所述绝缘体上硅晶圆的上表面刻蚀释放孔6,并用湿法腐蚀所述释放孔6下方的埋氧层二氧化硅7,形成微流道10;Buried oxide layer silicon dioxide 7 release step: etching the release hole 6 on the upper surface of the silicon-on-insulator wafer, and wet etching the buried oxide layer silicon dioxide 7 below the release hole 6 to form a
释放孔6电镀铜封闭步骤:在所述绝缘体上硅晶圆的上表面和所述释放孔6的侧壁沉积种子层金属,基于所述种子层电镀铜形成铜柱封闭所述微流道10的上表面;Release hole 6 electroplating copper sealing step: deposit a seed layer metal on the upper surface of the silicon-on-insulator wafer and the sidewall of the release hole 6, and form copper pillars to seal the
微流道10内壁无机镀铜步骤:使用化学法在所述微流道10的内壁上下表面镀上铜散热层。Inorganic copper plating step on the inner wall of the micro-channel 10 : plating a copper heat dissipation layer on the upper and lower surfaces of the inner wall of the micro-channel 10 by chemical method.
由上述实施例,可知本申请基于SOI晶圆1直接在晶圆背部制作微流体通路,无需与其他带有微流道10的硅片或玻璃片键合形成微流道10,降低了工艺复杂度;巧妙地开发了基于SOI晶圆1的埋氧层二氧化硅7牺牲释放工艺,不需要填充有机聚合物,而只依靠SOI晶圆1的器件层硅、埋氧层二氧化硅7和衬底层硅就能构成微流道10闭合管路;巧妙地开发了电镀铜封闭工艺和内壁选择性化学镀铜工艺,其中电镀铜柱结构不仅可以封闭微流道10侧壁,而且可以形成热沉结构提升散热能力;内壁选择性化学镀铜工艺可以在微流道10内壁的上下表面沉积铜层,进一步提升微流道10内壁的散热能力;开发了与微流道10晶上集成的压阻式流量计,并且具有温度补偿和震动补偿的功能,可以实时监测冷却液的流速和温度。From the above embodiments, it can be seen that the present application directly manufactures microfluidic passages on the back of the wafer based on the SOI wafer 1, and does not need to be bonded with other silicon wafers or glass sheets with
在压阻式流量计制造步骤的具体实施中,在绝缘体上硅(SOI)晶圆的上表面构造第一力敏应变结构2并构造力敏电阻3和测温电阻4;In the specific implementation of the piezoresistive flowmeter manufacturing steps, the first force-
如图1所示,以绝缘体上硅(SOI)晶圆为基片(图1中的(a))开始制作微流道10,所述SOI硅晶圆既可以是已经带有有源集成电路的背面,也可以是已经做完硅垂直通孔19(TSV)和重布线层18(RDL)的硅晶圆转接板的背面。此步骤具体可以包括以下过程:As shown in FIG. 1 ,
在所述绝缘体上硅晶圆的上表面光刻刻蚀形成第一力敏应变结构2,所述第一力敏应变结构2为悬臂梁、折叠梁-平板或带孔薄膜;在所述第一力敏应变结构2上通过离子注入形成半导体力敏电阻3;在所述力敏电阻3的附近通过沉积金属形成测温电阻4;溅射铬/金形成所述力敏电阻3的欧姆接触电极及互连线,等离子增强化学气相淀积沉积第一钝化层二氧化硅5。在具体实施中,优选溅射铬/铂形成测温电阻4,优选溅射铬/金形成所述力敏电阻3的欧姆接触电极及互连线,优选等离子增强化学气相淀积(PECVD)沉积第一钝化层二氧化硅5(图1中的(b))。Form the first force-
在所述埋氧层二氧化硅17释放步骤之前,该方法还可以包括震动补偿步骤,可以包括:Before the
在所述微流道10外侧,在所述绝缘体上硅晶圆的上表面构造第二力敏应变结构15,以消除震动对流体压力测量产生的误差。On the outside of the micro-channel 10, a second force-
图2所示为本发明所述可测流速压力温度的微流道10的微流道10的震动补偿结构。由于所述第一力敏应变结构2具有一定的震动敏感性,为了消除震动对流体压力测量产生的误差,可以在所述微流道10之外的附近位置制造与所述第一力敏应变结构2带有相同力学敏感结构的第二力敏应变结构15,所述第二力敏应变结构15上同样有力敏电阻3和测温电阻4,具体形成过程与所述压阻式流量计制造步骤相同,此处不作赘述。所述第二力敏应变结构15上的力敏电阻3只感受震动造成的压阻电阻值变化而不受微流体影响,从而可以利用两个力敏电阻3测得的压阻电阻值通过计算消除震动影响。FIG. 2 shows the vibration compensation structure of the micro-channel 10 of the micro-channel 10 capable of measuring flow velocity, pressure and temperature according to the present invention. Since the first force-
在埋氧层二氧化硅7释放步骤的具体实施中,在所述绝缘体上硅晶圆的上表面刻蚀释放孔6,并用湿法腐蚀所述释放孔6下方的埋氧层二氧化硅7,形成微流道10;In the specific implementation of the step of releasing the buried oxide layer silicon dioxide 7, the release hole 6 is etched on the upper surface of the silicon-on-insulator wafer, and the buried oxide layer silicon dioxide 7 below the release hole 6 is etched by a wet method , forming a
具体地,在所述绝缘体上硅晶圆的上表面光刻刻蚀释放孔6和冷却液进出孔8;在所述冷却液进出孔8的外侧侧壁和所述绝缘体上硅上表面的第一钝化层二氧化硅5上涂布厚光刻胶9,其中所述厚光刻胶9的厚度≥10微米,在具体实施中,光刻胶的厚度取决于台阶的厚度,为了保证微流道壁厚,一般会选择大于5微米的器件层SOI晶圆,因此本申请厚光刻胶9的厚度优选为10微米;通过所述释放孔6和冷却液进出孔8将所述释放孔6下方的埋氧层二氧化硅7湿法腐蚀,形成供冷却液水平方向流动的微流道10。在具体实施中,光刻刻蚀所述第一钝化层二氧化硅5、所述SOI晶圆1的上表面硅形成埋氧层释放孔6(图1中的(c)),光刻刻蚀所述SOI晶圆1的上表面硅和埋氧层二氧化硅7形成冷却液进出孔8(图1中的(d)),用旋涂或者喷涂的方式涂布厚光刻胶9,光刻形成只有所述微流体进出孔的内侧侧壁和内侧底部和暴露出来而外侧侧壁及外表面被光刻胶保护的结构(图1中的(e))。用湿法工艺优选氢氟酸将所述SOI晶圆1的埋氧层二氧化硅7释放,形成微流道10。Specifically, the release hole 6 and the cooling liquid inlet and
在释放孔6电镀铜封闭步骤的具体实施中,在所述绝缘体上硅晶圆的上表面和所述释放孔6的侧壁沉积种子层金属,基于所述种子层电镀铜形成铜柱封闭所述微流道10的上表面;In the specific implementation of the copper electroplating sealing step of the release hole 6, a seed layer metal is deposited on the upper surface of the silicon-on-insulator wafer and the sidewall of the release hole 6, and the copper pillar is formed by electroplating copper on the seed layer to form a closed hole. The upper surface of the
具体地,在所述绝缘体上硅晶圆的上表面和所述释放孔6的侧壁沉积铬/铜种子层;通过电镀的方法在所述释放孔6中生长铜形成铜柱热沉,剥离表面的厚光刻胶9;在所述绝缘体上硅晶圆的下表面沉积第二钝化层二氧化硅12。在具体实施中,优选溅射铬/铜,在所述释放孔6的侧壁和外表面形成种子层,并进行电镀铜形成闭合柱体11,既起到封闭所述微流道10上部侧壁的作用,又起到热沉的作用。电镀完成后剥离在所述冷却液进出孔8的外侧侧壁和所述绝缘体上硅上表面的第一钝化层二氧化硅5上涂布的厚光刻胶9。最后,在所述SOI晶圆1的下表面用PECVD沉积第二钝化层二氧化硅12(图1中的(f))。Specifically, a chromium/copper seed layer is deposited on the upper surface of the silicon-on-insulator wafer and the sidewall of the release hole 6; copper is grown in the release hole 6 by electroplating to form a copper pillar heat sink, and the A thick photoresist 9 on the surface; a second passivation
在微流道10内壁无机镀铜步骤的具体实施中,使用化学法在所述微流道10的内壁上下表面镀上铜散热层。In the specific implementation of the inorganic copper plating step on the inner wall of the micro-channel 10 , a copper heat dissipation layer is plated on the upper and lower surfaces of the inner wall of the micro-channel 10 by using a chemical method.
具体地,将所述绝缘体上硅晶圆浸入化学镀铜溶液中,则在所述微流道10的内壁的上下表面形成上表面铜沉积层13和下表面铜沉积层14。在具体实施中,将所述SOI晶圆1浸入化学镀铜溶液中,则在硅表面形成铜沉积,而在不活泼的氧化硅表面无铜沉积。这样在所述微流道10的内壁上下表面也形成了上表面铜沉积层13和下表面铜沉积层14,进一步提升了所述微流道10的散热能力(图1中的(g))。所述化学镀金属层的方法包括但不局限于铜、金、镍。以化学镀铜为例,所述化学镀铜溶液包括激活液和反应溶液,所述绝缘体上硅晶圆先浸入所述激活液中激活,再浸入所述反应溶液中镀铜,其中所述激活液的成分包括但不局限于去离子水、氢氟酸和氯化钯,所述反应溶液的成分包括但不局限于硫酸铜和甲醛。Specifically, by immersing the silicon-on-insulator wafer into an electroless copper plating solution, an upper surface
在所述微流道10内壁无机镀铜步骤之后,去除所述第二钝化层二氧化硅12(图1中的(h))。After the step of inorganic copper plating on the inner wall of the micro-channel 10 , the second passivation
图3中的(a)所示为一种含有压阻式流量检测功能的晶圆散热微流道10的俯视示意图。微流体流速的测量原理是压阻式,工作时冷却液流动会带动所述悬臂梁结构的第一力敏应变结构2产生弹性形变,导致力敏电阻3的电阻值发生改变,通过检测电阻值变化就可以得到相应的冷却液的流速和流量。由于力敏电阻3的电阻值对温度敏感,因此本发明在所述力敏电阻3附近设置有铂测温电阻4,用于对所述力敏电阻3进行温度漂移补偿。图3中(b)所示为本发明的基于梁-平板结构的第一力敏应变结构2的实施例。(a) in FIG. 3 is a schematic top view of a
本申请还提供一种根据上述方法制造得到的用于三维集成晶圆系统散热的流量可测的微流道的应用,用于制备带有硅垂直通孔或重布线层的硅晶圆转接板,以用于多层集成电路芯片或晶圆的三维垂直堆叠集成。图4展示了该用于三维集成晶圆系统散热的流量可测的微流道在三维集成应用领域的一个实施例。集成电路芯片16通过微凸点17与带有重布线层18和散热微流道10的硅晶圆转接板键合,信号通过硅垂直通孔19(TSV)从底部引出,可以有效提升三维集成系统的散热能力。The present application also provides an application of a flow measurable microfluidic channel for the heat dissipation of a three-dimensional integrated wafer system manufactured according to the above method, which is used to prepare a silicon wafer transfer with a silicon vertical via hole or a rewiring layer boards for three-dimensional vertical stack integration of multilayer integrated circuit chips or wafers. FIG. 4 shows an embodiment of the flow-measurable microfluidic channel for heat dissipation of a three-dimensional integrated wafer system in the application field of three-dimensional integration. The
本领域技术人员在考虑说明书及实践这里公开的内容后,将容易想到本申请的其它实施方案。本申请旨在涵盖本申请的任何变型、用途或者适应性变化,这些变型、用途或者适应性变化遵循本申请的一般性原理并包括本申请未公开的本技术领域中的公知常识或惯用技术手段。Other embodiments of the present application will readily occur to those skilled in the art from consideration of the specification and practice of the disclosure herein. This application is intended to cover any modification, use or adaptation of the application, these modifications, uses or adaptations follow the general principles of the application and include common knowledge or conventional technical means in the technical field not disclosed in the application .
应当理解的是,本申请并不局限于上面已经描述并在附图中示出的精确结构,并且可以在不脱离其范围进行各种修改和改变。It should be understood that the present application is not limited to the precise constructions which have been described above and shown in the accompanying drawings, and various modifications and changes may be made without departing from the scope thereof.
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| WO2012005706A1 (en) * | 2010-07-07 | 2012-01-12 | Haluk Kulah | Cmos compatible microchannel heat sink for electronic cooling and its fabrication |
| CN110739231A (en) * | 2019-09-24 | 2020-01-31 | 杭州臻镭微波技术有限公司 | three-dimensional stacking radio frequency optical module manufacturing method |
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