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CN115849537A - Treatment process of oily heavy metal industrial wastewater - Google Patents

Treatment process of oily heavy metal industrial wastewater Download PDF

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CN115849537A
CN115849537A CN202211477184.1A CN202211477184A CN115849537A CN 115849537 A CN115849537 A CN 115849537A CN 202211477184 A CN202211477184 A CN 202211477184A CN 115849537 A CN115849537 A CN 115849537A
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suction nozzle
scum
pipe
treatment process
industrial wastewater
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CN115849537B (en
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苏珊珊
孙伟峰
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Sichuan Dashan River Environmental Protection Engineering Co ltd
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Abstract

本发明涉及水处理领域,具体为一种含油重金属工业废水的处理工艺,包括箱体,箱体上安装有清理装置,清理装置包括安装架和抽气装置,安装架内活动安装有吸嘴,吸嘴顶部固定安装有管一,抽气装置包括管二,管二一端与管一固定连接,另一端与抽气泵固定连接,管一两端分别与吸嘴和管二固定连接,安装架上固定安装有用于使吸嘴移动的驱动装置,驱动装置包括两个丝杠,两个丝杠转动安装在安装架上,且丝杠的轴向方向与安装架的长边平行。本发明通过设置清理装置对浮渣进行抽离含油重金属废液中的浮渣,防止气浮机在去除浮渣时与浮渣接触破坏气泡与絮体的结合,使絮体沉降至水下,降低含油重金属废水的净化效果。

Figure 202211477184

The invention relates to the field of water treatment, in particular to a treatment process for industrial wastewater containing oil and heavy metals, comprising a box body on which a cleaning device is installed, the cleaning device includes a mounting frame and an air extraction device, and a suction nozzle is movably installed in the mounting frame, Pipe 1 is fixedly installed on the top of the suction nozzle, and the suction device includes pipe 2. One end of pipe 2 is fixedly connected to pipe 1, and the other end is fixedly connected to the suction pump. Both ends of pipe 1 are fixedly connected to suction nozzle and pipe 2 respectively. A drive device for moving the suction nozzle is fixedly installed on the top, the drive device includes two lead screws, and the two lead screws are rotatably installed on the mounting frame, and the axial direction of the lead screw is parallel to the long side of the mounting frame. The invention extracts the scum from the oily heavy metal waste liquid by setting a cleaning device, prevents the air flotation machine from contacting the scum when removing the scum, destroys the combination of air bubbles and flocs, and makes the flocs sink to the water. Reduce the purification effect of oily heavy metal wastewater.

Figure 202211477184

Description

一种含油重金属工业废水的处理工艺A treatment process for oily heavy metal industrial wastewater

技术领域technical field

本发明涉及水处理领域,具体为一种含油重金属工业废水的处理工艺。The invention relates to the field of water treatment, in particular to a treatment process for industrial wastewater containing oily heavy metals.

背景技术Background technique

在机械加工、矿山开采、金属冶炼和电镀等生产领域中会产生大量的含油重金属废水,这些废液中的重金属具有毒性,如果直接排放重金属污染物会在大气、水、沉积物、土壤等环境中存留,我国目前被重金属污染的土地已经达到上千万平方公顷,在土壤被重金属污染的影响下,近年来频频报道因重金属污染而导致的健康问题,无一不在敲打着警钟,警示目前重金属对土壤的污染的影响在不断的扩大,因此对重金属废水的预防治理工作十分重要。In the fields of mechanical processing, mining, metal smelting and electroplating, a large amount of oily heavy metal wastewater will be produced. The heavy metals in these waste liquids are toxic. If the heavy metal pollutants are directly discharged, they will be released in the atmosphere, water, sediment, soil and other environments. In my country, the land contaminated by heavy metals has reached tens of millions of square hectares. Under the influence of heavy metal pollution in the soil, health problems caused by heavy metal pollution have been frequently reported in recent years, and all of them are ringing the alarm bells to warn that the current heavy metal pollution The impact of soil pollution is constantly expanding, so the prevention and treatment of heavy metal wastewater is very important.

在现有的技术中对含油重金属的处理方法主要有化学处理和物理处理还有化学和物理混合处理,目前对含油重金属废水处理采用较多的是综合化学和物理方法的气浮机处理,在气浮机内加入絮凝剂和混凝剂,利用混凝剂使悬浮物和油脂相互絮结,利用絮凝剂对混凝剂形成的小颗粒相互吸附、联接,从而形成迅速从水分离出来的大絮体,然后气浮机的溶气系统在气浮机的结合区内释放微小气泡,这些微小气泡附着在絮体上使絮体上浮,然后对上浮后的浮渣使刮板清理,通过混凝剂和絮凝剂使含油重金属废水中的油和重金属的絮结形成絮体在利用气泡使絮体上浮,然后利用刮板对上浮的絮体浮渣进行刮走清理来实现含油重金属的净化作用,但是在现有的气浮机中,对浮渣清理是利用滚动的刮板对浮渣进行刮走,这种方法需要准确的控制刮板的刮动频率和刮动速度,由于刮板的刮动频率是不经常调整的,而浮渣的形成速度会根据含油重金属废液中的细小颗粒含量而不断变化,如果刮动频率低于浮渣的形成速度,那么较多的浮渣厚度会变厚,变厚的浮渣含水量变少,含水量减少的浮渣被刮至污泥槽内,再通过传输装置使浮渣传输到浮渣处理装置内对浮渣进行处理,而且刮渣板对浮渣刮动时需要与还未出水的浮渣接触,这时刮板会对絮体上的微小气泡造成破裂,絮体失去气泡的浮力作用会继续下沉到水中,但是如果浮渣的含水量减少后比较干的浮渣会对传输装置造成堵塞,如果刮动频率过快,这就要要求刮板的移动速度加快,刮板移动速度过快就会加大对浮渣的作用力,这就更容易破坏浮渣,造成废水净化效果降低。In the existing technology, the treatment methods for oily heavy metals mainly include chemical treatment, physical treatment and mixed chemical and physical treatment. At present, the treatment of oily heavy metal wastewater is mostly the air flotation machine treatment of comprehensive chemical and physical methods. The flocculant and coagulant are added into the air flotation machine, and the coagulant is used to flocculate the suspended matter and oil, and the flocculant is used to adsorb and connect the small particles formed by the coagulant to each other, thus forming large particles that are quickly separated from the water. Then the dissolved air system of the air flotation machine releases tiny bubbles in the bonding area of the air flotation machine. These tiny bubbles attach to the flocs and make the flocs float up. Coagulants and flocculants make the oil and heavy metals in the oily heavy metal wastewater flocculate to form flocs. The air bubbles are used to float the flocs, and then the scrapers are used to scrape and clean the floating flocs and scum to realize the purification of oily heavy metals. , but in the existing air flotation machine, the scum is cleaned by using the rolling scraper to scrape away the scum. This method needs to accurately control the scraping frequency and scraping speed of the scraper. The frequency of scraping is adjusted infrequently, and the formation speed of scum will change continuously according to the content of fine particles in the oily heavy metal waste liquid. If the frequency of scraping is lower than the formation speed of scum, more scum thickness will be Thickened, the thickened scum has less water content, and the scum with reduced water content is scraped into the sludge tank, and then the scum is transported to the scum treatment device through the transmission device to treat the scum, and the scraper plate When scraping the scum, it needs to be in contact with the scum that has not yet come out of the water. At this time, the scraper will break the tiny air bubbles on the flocs, and the flocs will continue to sink into the water without the buoyancy of the air bubbles. After the water content is reduced, the drier scum will block the transmission device. If the scraping frequency is too fast, this requires the scraper to move faster. If the scraper moves too fast, it will increase the force on the scum , which makes it easier to destroy the scum and reduce the effect of wastewater purification.

为此,为了防止在对浮渣清理时接触破坏浮渣,絮体沉降到水中影响净水效果,提出一种含油重金属工业废水的处理工艺。For this reason, in order to prevent the scum from being contacted and damaged during the scum cleaning, and the flocs settling into the water to affect the water purification effect, a treatment process for industrial wastewater containing oily heavy metals is proposed.

发明内容Contents of the invention

本发明的目的在于提供一种含油重金属工业废水的处理工艺,通过设置抽气装置和吸嘴,在不与浮渣接触的情况下对浮渣进行清理,The purpose of the present invention is to provide a treatment process for industrial wastewater containing oily heavy metals. By setting up an air extraction device and a suction nozzle, the scum is cleaned without contact with the scum.

以解决上述背景技术中提出的问题。To solve the problems raised in the background technology above.

为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:

一种含油重金属工业废水的处理工艺,包括以下步骤:A treatment process for oily heavy metal industrial wastewater, comprising the following steps:

S1:含油重金属废水进入箱体的污水反应区,在反应区内加入絮凝剂(PAC)和助凝剂(PAM),絮凝剂(PAC)和助凝剂(PAM)使含油重金属废水中的细小颗粒结合形成体积较大的絮体;S1: Oily heavy metal wastewater enters the sewage reaction zone of the tank, and flocculant (PAC) and coagulant aid (PAM) are added in the reaction zone, and the flocculant (PAC) and coagulant aid (PAM) make the oily heavy metal wastewater fine Particles combine to form larger flocs;

S2:启动溶气装置,使微小气泡与絮体结合,含油重金属废水开始进行处理;S2: Start the air-dissolving device to combine micro-bubbles with flocs, and start to treat oily and heavy metal wastewater;

S3:浮渣上升至液面,浮渣的上升触发检测装置,检测装置控制清理装置启动;S3: The scum rises to the liquid level, the rising of the scum triggers the detection device, and the detection device controls the cleaning device to start;

S4:上浮的浮渣经过清理装置抽至污泥池;S4: The floating scum is pumped to the sludge tank through the cleaning device;

S5:废水处理结束时,启动升降装置,升降装置控制清理装置下降吸水,水流通过清理装置抽至污泥池,在水流的作用下完成清理装置的清洗,所述清理装置包括安装架和抽气装置,所述安装架内活动安装有吸嘴,所述吸嘴顶部螺纹连接有管一,所述抽气装置包括管二,所述管二一端与管一固定连接,另一端与抽气泵固定连接,所述管一两端分别与吸嘴和管二螺纹连接,所述管二连接有抽气装置,所述安装架上固定安装有用于使吸嘴移动的驱动装置,絮体和微小气泡在箱体下方结合,絮体在微小气泡浮力的作用下上浮至液面,大量的絮体上浮在液面处堆积形成浮渣,这时安装在安装架内处于液面上方的吸嘴在抽气装置的作用下对浮渣进行抽离,使用吸嘴和抽气装置在对浮渣进行清除时可以不接触到浮渣就可以对液面上的浮渣进行清理,防止在清理浮渣的时候接触到浮渣造成浮渣的气泡破裂导致絮体继续沉入水中,从而导致含油重金属废水清除效果变差的问题。S5: At the end of the wastewater treatment, start the lifting device, the lifting device controls the cleaning device to descend and absorb water, the water flow is pumped to the sludge pool through the cleaning device, and the cleaning device is cleaned under the action of the water flow. The cleaning device includes a mounting frame and an air extraction device, a suction nozzle is movable installed in the mounting frame, a pipe 1 is threadedly connected to the top of the suction nozzle, and the air extraction device includes a pipe 2, one end of the pipe 2 is fixedly connected to the pipe 1, and the other end is connected to the air pump Fixedly connected, the two ends of the first pipe are threadedly connected with the suction nozzle and the second pipe respectively, the second pipe is connected with an air extraction device, and the driving device for moving the suction nozzle is fixedly installed on the mounting frame, and the flocs and tiny The air bubbles combine under the box, and the flocs float up to the liquid surface under the action of the buoyancy of the tiny air bubbles, and a large number of flocs float up and accumulate on the liquid surface to form scum. At this time, the suction nozzle installed in the installation frame above the liquid surface is The scum is extracted under the action of the air extraction device, and the scum on the liquid surface can be cleaned without touching the scum when using the suction nozzle and the air extraction device to prevent the scum from being cleaned. When it comes into contact with scum, the bubbles of the scum burst and the flocs continue to sink into the water, which leads to the problem of poor removal effect of oily heavy metal wastewater.

本发明中,抽气装置可以利用压缩气体系统,在释放压缩气体时产生的负压抽取浮渣,该系统产生的吸力较大,但是该系统的使用成本更高,结构复杂,因此选用气泵和管二作为本发明的抽气装置可以节省成本,结构简单。In the present invention, the air pumping device can use the compressed gas system to extract the scum under the negative pressure generated when the compressed gas is released. The suction force generated by the system is relatively large, but the system has higher cost and complex structure, so the air pump and Pipe two can save cost as the air extraction device of the present invention and has a simple structure.

优选的,所述驱动装置包括两个丝杠,两个所述丝杠转动安装在安装架上,且轴向方向与安装架的长边平行,两个所述丝杠上安装有滚珠螺母,所述滚珠螺母下方固定安装有固定板,所述固定板上开有孔,所述管一穿过孔,所述固定板两侧滑动安装有支撑杆一,所述支撑杆一的一端与吸嘴螺纹连接,两个所述丝杠通过同步带与电机一连接,在吸嘴对浮渣进行清理时,电机一启动,通过同步带使丝杠转动,通过丝杠的转动使滚珠螺母在丝杠上左右运动,通过螺纹连接在滚珠螺母上的固定板跟着滚珠螺母做同步运动,通过支撑杆一连接在固定板上的吸嘴跟着固定板左右运动,浮渣在液面上持续生成,而且浮渣并不流动,通过驱动装置使吸嘴左右移动对浮渣进行往复清理,实现浮渣的均匀完整的清理。Preferably, the driving device includes two lead screws, the two lead screws are rotatably mounted on the mounting frame, and the axial direction is parallel to the long side of the mounting frame, ball nuts are installed on the two lead screws, A fixing plate is fixedly installed under the ball nut, and a hole is opened on the fixing plate, and the tube one passes through the hole, and a support rod one is slidably installed on both sides of the fixing plate, and one end of the support rod one is connected with the suction The nozzles are threaded, and the two lead screws are connected to the motor through the timing belt. When the suction nozzle cleans up the scum, the motor is started, and the lead screw is rotated through the timing belt. Through the rotation of the lead screw, the ball nut is on the wire The bar moves left and right, the fixed plate connected to the ball nut through the thread moves synchronously with the ball nut, and the suction nozzle connected to the fixed plate through the support rod moves left and right with the fixed plate, and the scum is continuously generated on the liquid surface, and The scum does not flow, and the suction nozzle moves left and right through the driving device to reciprocate and clean the scum, so as to realize the uniform and complete cleaning of the scum.

同时,本方案的驱动装置还可以选用皮带传动或着链传动,通过在皮带上或者链条上安装固定板,使安装在固定板上的吸嘴跟着皮带或链条的移动而左右运动,但是皮带和链条会产生拉伸变形,造成传动效果降低,吸嘴下降造成浮渣的破坏,因此在本发明中选用滚珠螺母丝杠传动为最优方案。At the same time, the driving device of this program can also choose belt transmission or chain transmission. By installing a fixed plate on the belt or chain, the suction nozzle installed on the fixed plate can move left and right with the movement of the belt or chain, but the belt and the chain The chain will be stretched and deformed, which will reduce the transmission effect, and the drop of the suction nozzle will cause the destruction of scum. Therefore, the ball nut screw drive is the optimal solution in the present invention.

优选的,所述固定板上通过升降机构与吸嘴连接,所述升降机构用于实现吸嘴的上下移动,所述升降机构包括螺纹连接在支撑杆一上的齿条,所述齿条上啮合有齿轮,所述齿轮通过键连接在转轴上,所述转轴通过联轴器转动安装在电机二上,吸嘴和抽气装置对浮渣进行抽离的过程中,浮渣会吸附在吸嘴内壁和管一、管二的内壁上,如果不对这部分浮渣进行清理,浮渣就会一直堆积造成吸嘴、管一和管二的壁厚增加,造成通风量减少达不到有效的抽浮渣效果,通过设置升降机构,在完成浮渣的清理时,电机二启动,使齿轮转动,齿轮的转动使齿条向下运动,与齿条螺纹连接的支撑杆一使吸嘴向下运动,使吸嘴位于液面下,在抽气装置的作用下净化后的水进入吸嘴通过管一和管二流到浮渣收集处,吸附在吸嘴、管一和管二内壁上的浮渣在水流的作用下被冲刷走,实现吸嘴、管一和管二内壁的清理效果。Preferably, the fixed plate is connected with the suction nozzle through a lifting mechanism, and the lifting mechanism is used to move the suction nozzle up and down. The lifting mechanism includes a rack threaded on the support rod one, and the rack The gear is meshed, the gear is connected to the rotating shaft through a key, and the rotating shaft is rotated and installed on the second motor through a coupling. During the process of extracting the scum by the suction nozzle and the suction device, the scum will be adsorbed on the suction On the inner wall of the nozzle and the inner wall of tube 1 and tube 2, if this part of scum is not cleaned up, the scum will continue to accumulate, causing the wall thickness of the suction nozzle, tube 1 and tube 2 to increase, resulting in a decrease in the ventilation rate that cannot reach the effective level. The scum pumping effect, by setting the lifting mechanism, when the scum is cleaned, the motor 2 is started to rotate the gear, the rotation of the gear makes the rack move downward, and the support rod 1 threaded with the rack makes the suction nozzle downward Movement, so that the suction nozzle is located under the liquid surface, and the purified water enters the suction nozzle and flows through the pipe 1 and pipe 2 to the scum collection place under the action of the suction device, and is adsorbed on the scum on the inner walls of the suction nozzle, pipe 1 and pipe 2 The slag is washed away under the action of the water flow, and the cleaning effect of the suction nozzle, the inner wall of the first pipe and the second pipe is realized.

本发明中,升降机构还可以使用气缸对吸嘴进行升降运动,气缸的输出力和运动速度比较好调节,但是在本发明中,对升降的力和速度的要求并不高,而且气缸需要外接气管才能实现升降的功能,增加的机构的复杂性,因此在本发明至使用电机二和齿轮齿条作为升降机构可以使发明的整体结构简单,齿轮齿条的使用寿命长,能够更好的实现吸嘴的升降功能。In the present invention, the lifting mechanism can also use the cylinder to lift the suction nozzle. The output force and movement speed of the cylinder are relatively easy to adjust, but in the present invention, the requirements for the lifting force and speed are not high, and the cylinder needs to be connected externally. The air pipe can realize the function of lifting, and the complexity of the mechanism increases, so in the present invention, the use of motor two and the rack and pinion as the lifting mechanism can make the overall structure of the invention simple, and the service life of the rack and pinion is long, which can better realize The lifting function of the suction nozzle.

优选的,所述吸嘴通过浮动装置与箱体内的液面连接,通过设置浮动装置控制吸嘴与浮渣的距离,保证吸嘴与浮渣有一定的距离,在箱体内水位变化时,防止吸嘴离浮渣太远达不到抽离效果,也防止吸嘴离浮渣太近对浮渣造成破坏,使絮体沉降到净化的水中,达不到含油重金属废水的净化效果。Preferably, the suction nozzle is connected to the liquid level in the tank through a floating device, and the distance between the suction nozzle and the scum is controlled by setting the floating device to ensure that there is a certain distance between the suction nozzle and the scum, and when the water level in the tank changes, preventing The suction nozzle is too far away from the scum to achieve the extraction effect, and it also prevents the suction nozzle from being too close to the scum to cause damage to the scum, causing the flocs to settle into the purified water, and the purification effect of the oily heavy metal wastewater cannot be achieved.

优选的,所述浮动装置包括浮板二,所述浮板二安装在浮力开关与箱体侧壁之间的空隙处,所述吸嘴的两端螺纹连接有支撑杆二,所述支撑杆二的下端转动安装有滚轮,所述滚轮在浮板二上滚动,浮板二利用浮力漂浮在液面上,浮板二的高度随着箱体内水位高低的变化而变化,在浮板二上滚动的滚轮也会随着水位的变化实现高低变化,螺纹连接在吸嘴两端的支撑杆二与滚轮通过轴承连接,因此,当箱体内的水位发生变化时,吸嘴在支撑杆二、滚轮和浮板二的作用下实现自动调节与浮渣之间的距离,因为浮板二、支撑杆和滚轮的都是简单耐用的零件,使用寿命长,反应及时的优点,因此十分合适在该设备中作为浮动装置。Preferably, the floating device includes a floating plate 2, the floating plate 2 is installed in the gap between the buoyancy switch and the side wall of the box, the two ends of the suction nozzle are threadedly connected with the support rod 2, and the support rod The lower end of the second floating plate is rotatably equipped with rollers, which roll on the second floating plate. The second floating plate floats on the liquid surface by buoyancy. The rolling roller will also change in height with the change of water level. The support rod two threaded at both ends of the suction nozzle is connected with the roller through bearings. The distance between the floating plate 2 and the scum can be automatically adjusted under the action of the floating plate 2, because the floating plate 2, support rods and rollers are simple and durable parts with long service life and timely response, so they are very suitable for this equipment as a floating device.

同时作为浮动装置的还可以使用光电液位感应器和电机二与支撑杆一作为浮动装置,通过光电液位传感器测量水位的高度,控制电机二驱动支撑杆一升降进行吸嘴与浮渣的距离控制,利用光电液位传感器可以使浮动装置的结构更紧凑,安装更方便,可以测量极少数液体,但是其缺点也是很明显的由于传感器需要接触液体,需要接通电源,而且含油金属废水中的絮体会吸附在光电液位传感器的棱镜上造成测量不准确,导致吸嘴与浮渣的距离调节变差,因此选用浮板二和支撑杆二作为浮动装置在本发明中作为浮动装置效果更好。At the same time, as a floating device, a photoelectric liquid level sensor, motor 2 and support rod 1 can also be used as a floating device, and the height of the water level can be measured by the photoelectric liquid level sensor, and the distance between the suction nozzle and the scum can be determined by controlling the motor 2 to drive the support rod 1 up and down. Control, the use of photoelectric liquid level sensors can make the structure of the floating device more compact, more convenient to install, and can measure very few liquids, but its disadvantages are also obvious because the sensor needs to be in contact with the liquid and needs to be connected to the power supply, and the oily metal wastewater The flocs will be adsorbed on the prism of the photoelectric liquid level sensor, resulting in inaccurate measurement, resulting in poor adjustment of the distance between the suction nozzle and the scum. Therefore, it is better to use the second floating plate and the second support rod as the floating device in the present invention. .

优选的,所述箱体内壁上螺纹连接有斜导板一,所述斜导板上方安装有斜导板二,所述斜导板二下端低于斜导板一的上端,所述斜导板二的上端与箱体端面平齐,絮体和微小气泡在箱体下方结合时竖直向上往液面处上浮,所述斜导板二选用质量轻防腐蚀的PP材料制成,通过在箱体内安装斜导板一和斜导板二,使絮体在上浮的时候经过斜导板的导向作用使箱体边缘的絮体往箱体的中间移动,通过斜导板的作用使箱体边缘的絮体往箱体中间汇集,可以在吸附浮渣时吸嘴能够完全覆盖在浮渣的上面,从而实现对浮渣的完整清理,不会有浮渣残留在箱体内壁上。Preferably, the first inclined guide plate is threaded on the inner wall of the box, the second inclined guide plate is installed above the inclined guide plate, the lower end of the second inclined guide plate is lower than the upper end of the first inclined guide plate, the upper end of the second inclined guide plate is connected The end surface of the body is even, and when the flocs and micro-bubbles are combined at the bottom of the box, they float vertically upward to the liquid surface. The second inclined guide plate is made of light-weight and anti-corrosion PP material. The second inclined guide plate makes the flocs on the edge of the box move to the middle of the box through the guiding effect of the inclined guide plate when they float up, and the flocs on the edge of the box are collected in the middle of the box through the action of the inclined guide plate, which can When absorbing the scum, the suction nozzle can completely cover the scum, so as to realize the complete cleaning of the scum, and no scum will remain on the inner wall of the box.

优选的,所述斜导板二的顶端螺纹连接有浮板一,所述浮板一两端螺纹连接有导板,所述导板滑动安装在箱体上,通过设置浮板一,使箱体边缘上浮的絮体聚集浮板一内,浮渣在浮板一限制下不会在液面上方飘散,而且浮板一是漂浮在水面上的,可以在含油金属废水水位变化时跟着改变斜导板二的位置,通过浮板一改变斜导板二根据液位的变化二改变可以在吸嘴对浮渣进行升降时,导板二不会阻挡到吸嘴的行程。Preferably, the top of the inclined guide plate 2 is threaded with a floating plate 1, and the two ends of the floating plate 1 are threaded with a guide plate, and the guide plate is slidably installed on the box body, and the edge of the box body is floated by setting the floating plate 1 The flocs gather in the first floating plate, and the scum will not float above the liquid surface under the restriction of the first floating plate, and the first floating plate floats on the water surface, and can follow the change of the inclined guide plate two when the water level of the oily metal wastewater changes The position is changed through the floating plate 1 and the inclined guide plate 2 can be changed according to the change of the liquid level. When the suction nozzle lifts the scum, the guide plate 2 will not block the stroke of the suction nozzle.

优选的,所述浮板一上端固定安装有导柱,所述导柱内部安装有浮力开关,浮渣的生成量受到含油金属废液内的絮体含量而发生改变,当生成量较大时,为了保证浮渣的抽离效果,要求吸嘴的移动速度更快,抽风的风力更强,通过在浮板一的上端设置导柱,使导柱与浮板一连通,浮渣通过浮板一进入导柱,通过在导柱内设置浮力开关,当含油重金属废液中的絮体较多时,生成的浮渣较多,浮渣使浮力开关上浮,通过浮力开关检测到与液面的距离控制抽风装置和驱动装置加大功率,以达到浮渣的抽离要求,当含油金属废液中的絮体较少使,生成的浮渣量较少,浮渣与液面的高度降低,浮力开关下降,控制抽气装置和浮力装置降低功率,以达到节能的效果。Preferably, a guide post is fixedly installed on the upper end of the floating plate, and a buoyancy switch is installed inside the guide post. The amount of scum generated is changed by the floc content in the oily metal waste liquid. When the amount of scum generated is large , in order to ensure the removal effect of scum, the moving speed of the suction nozzle is required to be faster, and the wind force of the draft is stronger. By setting the guide post on the upper end of the floating plate 1, the guide post is connected with the floating plate 1, and the scum passes through the floating plate. Once entering the guide column, by setting the buoyancy switch in the guide column, when there are more flocs in the oily heavy metal waste liquid, more scum will be generated, and the scum will make the buoyancy switch float up, and the distance from the liquid surface will be detected by the buoyancy switch Control the exhaust device and the driving device to increase the power to meet the requirements of scum extraction. When the flocs in the oily metal waste liquid are less, the amount of scum generated is less, and the height between the scum and the liquid surface decreases, and the buoyancy The switch is lowered to control the suction device and the buoyancy device to reduce the power, so as to achieve the effect of energy saving.

优选的,所述吸嘴选用质量轻耐腐蚀的材料,由于吸嘴与浮渣的距离是靠浮力控制的,含油金属废液具有腐蚀性,因此要求吸嘴的材料具有质量轻耐腐蚀的性能,所以选用的材料为PP塑料,PP材料的密度仅有0.9,而且具有较强的耐腐蚀性,符合设备的使用要求。Preferably, the suction nozzle is made of light and corrosion-resistant materials. Since the distance between the suction nozzle and the scum is controlled by buoyancy, and the oily metal waste liquid is corrosive, the material of the suction nozzle is required to have light weight and corrosion resistance. , so the material selected is PP plastic, the density of PP material is only 0.9, and it has strong corrosion resistance, which meets the requirements of the equipment.

优选的,所述管一与吸嘴的连接处安装有单向阀,当抽离装置完成对浮渣的吸附停机时,吸附在管一上的浮渣失去风力的作用,在重力的作用下向下滴落降落到箱体内,对箱体造成污染,影响下一次气浮机对含油中金属的净化,通过在管一与吸嘴的连接处安装单向阀,在抽气装置停止工作时防止浮渣掉落。Preferably, a one-way valve is installed at the connection between the pipe one and the suction nozzle. When the extraction device completes the adsorption of scum and shuts down, the scum adsorbed on the pipe one loses the effect of wind force, and under the action of gravity It will drop down and fall into the box, causing pollution to the box and affecting the purification of the metal in the oil by the air flotation machine next time. Prevents scum from falling out.

与现有技术相比,本发明的有益效果为:Compared with prior art, the beneficial effect of the present invention is:

1、本发明所述的一种含油重金属工业废水的处理工艺,通过在安装架上安装清理装置对含油重金属废液中的浮渣进行不接触抽离,防止气浮机在去除浮渣时与浮渣接触破坏气泡与絮体的结合,使絮体沉降至水下,造成含油重金属废液净化效果差的影响。1, a kind of treatment process of oily heavy metal industrial wastewater according to the present invention, by installing cleaning device on the mounting frame, the scum in the oily heavy metal waste liquid is extracted without contact, preventing the air flotation machine from interacting with the scum when removing the scum The contact of scum destroys the combination of air bubbles and flocs, causing the flocs to settle underwater, resulting in poor purification effect of oily heavy metal waste liquid.

2、本发明所述的一种含油重金属工业废水的处理工艺,通过设置浮板一和浮板二不需要额外动力即可以随着水位调节吸嘴与浮渣的距离,保证了吸嘴在运动过程中不会接触到浮渣的同时还能保持吸嘴与浮渣的距离保证浮渣的抽离效果。2. According to the treatment process of a kind of oily heavy metal industrial wastewater according to the present invention, the distance between the suction nozzle and the scum can be adjusted according to the water level by setting the floating plate 1 and the floating plate 2 without additional power, so as to ensure that the suction nozzle is moving While not touching the scum during the process, the distance between the suction nozzle and the scum can be maintained to ensure the effect of removing the scum.

3、本发明所述的一种含油重金属工业废水的处理工艺,通过在浮板一上设置导柱并在导柱内安装浮力开关,通过浮力开关调节吸嘴的移动速度,当浮渣形成较多时加快移动速度,当浮渣形成较少时降低移动速度,通过改变吸嘴的移动速度来保证浮渣的清理效果以及节约能耗的效果。3. In the treatment process of a kind of oil-containing heavy metal industrial wastewater according to the present invention, a guide post is arranged on the floating plate and a buoyancy switch is installed in the guide post, and the moving speed of the suction nozzle is adjusted by the buoyancy switch. Increase the moving speed for a long time, reduce the moving speed when there is less scum, and change the moving speed of the suction nozzle to ensure the cleaning effect of scum and the effect of saving energy.

附图说明Description of drawings

图1为本发明的结构示意图;Fig. 1 is a structural representation of the present invention;

图2为本发明的剖视图;Fig. 2 is a sectional view of the present invention;

图3为本发明图2中A处局部放大图;Fig. 3 is a partial enlarged view of place A in Fig. 2 of the present invention;

图4为本发明的局部剖视图;Fig. 4 is a partial sectional view of the present invention;

图5为本发明的俯视图:Fig. 5 is the top view of the present invention:

图6为本发明的剖视图;Fig. 6 is a sectional view of the present invention;

图7为本发明的左视图;Fig. 7 is the left view of the present invention;

图8为本发明实施例二的结构示意图。FIG. 8 is a schematic structural diagram of Embodiment 2 of the present invention.

图中:1、箱体;2、安装架;3、吸嘴;4、管一;5、管二;6、丝杠;7、滚珠螺母;8、固定板;9、支撑杆一;10、电机一;12、斜导板一;13、斜导板二;14、浮板一;15、浮板二;16、导柱;17、浮力开关;18、支撑杆二;19、滚轮;20、单向阀;21、电机二;22、齿条;23、浮渣;24、防护罩;25、导板。In the figure: 1. Box body; 2. Mounting frame; 3. Suction nozzle; 4. Pipe one; 5. Pipe two; 6. Lead screw; 7. Ball nut; 8. Fixed plate; 9. Support rod one; 10 1, motor one; 12, inclined guide plate one; 13, inclined guide plate two; 14, floating plate one; 15, floating plate two; 16, guide post; 17, buoyancy switch; 18, support rod two; Check valve; 21, motor two; 22, rack; 23, scum; 24, protective cover; 25, guide plate.

具体实施方式Detailed ways

实施例一,如图1至图8所示,该实施例中,气浮机安装在室内,浮渣不受外界环境影响,具体如下:Embodiment 1, as shown in Figures 1 to 8, in this embodiment, the air flotation machine is installed indoors, and the scum is not affected by the external environment, as follows:

一种含油重金属工业废水的处理工艺,包括箱体1,箱体1上螺纹连接有清理装置,清理装置包括安装架2和抽气装置,安装架2内活动安装有吸嘴3,吸嘴3顶部螺纹连接有管一4,管一4两端分别与吸嘴3和管二5螺纹连接,管二5连接有抽气装置,抽气装置包括抽气泵,抽气泵的一端连接污泥池,另一端连接管二5,安装架2上固定安装有用于使吸嘴3移动的驱动装置,驱动装置包括两个丝杠6,两个丝杠6转动安装在安装架2上,且轴向方向与安装架2的长边平行,两个丝杠6上安装有滚珠螺母7,滚珠螺母7下方固定安装有固定板8,固定板8上开有孔,管一4穿过孔,固定板8两侧滑动安装有支撑杆一9,支撑杆一9的一端与吸嘴3螺纹连接,固定板8上通过升降机构与吸嘴3连接,升降机构用于实现吸嘴3的上下移动,升降机构包括螺纹连接在支撑杆一9上的齿条22,齿条22上啮合有齿轮,齿轮通过键连接在转轴上,转轴通过联轴器转动安装在电机二21上,吸嘴3通过浮动装置与箱体1内的液面连接,浮动装置包括浮板二15,浮板二15安装在浮力开关17与箱体1侧壁之间的空隙处,吸嘴3的两端螺纹连接有支撑杆二18,支撑杆二18的下端转动安装有滚轮19,滚轮19在浮板二15上滚动,箱体1内壁上螺纹连接有斜导板一12,斜导板上方安装有斜导板二13,斜导板二13下端低于斜导板一12的上端,斜导板二13的上端与箱体1端面平齐,斜导板二13的顶端螺纹连接有浮板一14,浮板一14两端螺纹连接有导板,导板滑动安装在箱体1上,浮板一14上端固定安装有导柱16,导柱16内部安装有浮力开关17,管一4与吸嘴3的连接处安装有单向阀20。A treatment process for oily heavy metal industrial wastewater, comprising a box body 1, a cleaning device is threadedly connected to the box body 1, the cleaning device includes a mounting frame 2 and an air extraction device, and a suction nozzle 3 is movable installed in the mounting frame 2, and the suction nozzle 3 The top is threadedly connected with pipe one 4, and the two ends of pipe one 4 are threadedly connected with suction nozzle 3 and pipe two 5 respectively, and pipe two 5 is connected with an air extraction device, the air extraction device includes an air pump, and one end of the air pump is connected to the sludge pool, The other end is connected to the pipe 2 5, and the mounting frame 2 is fixedly installed with a driving device for making the suction nozzle 3 move. The driving device includes two leading screws 6, and the two leading screws 6 are rotatably mounted on the mounting frame 2, and the axial direction Parallel to the long side of the installation frame 2, ball nuts 7 are installed on the two lead screws 6, and a fixed plate 8 is fixedly installed under the ball nuts 7, and a hole is opened on the fixed plate 8, and the tube one 4 passes through the hole, and the fixed plate 8 Support rod one 9 is slidingly installed on both sides, and one end of support rod one 9 is threadedly connected with the suction nozzle 3, and the fixed plate 8 is connected with the suction nozzle 3 through a lifting mechanism. The lifting mechanism is used to realize the up and down movement of the suction nozzle 3. It includes a rack 22 threaded on the support rod 9, a gear is engaged on the rack 22, the gear is connected to the rotating shaft through a key, and the rotating shaft is installed on the motor 2 21 through a coupling, and the suction nozzle 3 is connected to the motor 2 through a floating device. The liquid level connection in the box body 1, the floating device includes a floating plate 2 15, and the floating plate 2 15 is installed in the gap between the buoyancy switch 17 and the side wall of the box body 1, and the two ends of the suction nozzle 3 are threadedly connected with the support rod 2 18. The lower end of the support rod 2 18 is rotated with a roller 19, and the roller 19 rolls on the floating plate 15. The inner wall of the box body 1 is threaded with a slanted guide plate 1 12, and the slanted guide plate 13 is installed above the slanted guide plate. The lower end of 13 is lower than the upper end of inclined guide plate one 12, the upper end of inclined guide plate two 13 is flush with the end face of casing 1, the top of inclined guide plate two 13 is threaded with floating plate one 14, and the two ends of floating plate one 14 are threadedly connected with guide plate, The guide plate is slidably installed on the casing 1, the upper end of the floating plate 14 is fixedly equipped with a guide post 16, the inside of the guide post 16 is equipped with a buoyancy switch 17, and the joint of the pipe one 4 and the suction nozzle 3 is equipped with a one-way valve 20.

具体工作流程。Specific workflow.

工作时,待处理的含油重金属废水经过输送管,在输送管内调节PH后进入气浮机内的反应区,在反应区内加入絮凝剂(PAC)和混凝剂(PAM)使含油重金属废液中的细小微粒凝聚成大块的絮体,絮体与水进入到接触区,溶气系统通过释放器产生的微小气泡吸附到絮体上,一起进入箱体1内的分离区,在分离区内絮体竖直上升,安装在箱体1内的斜导板一12和斜导板二13使絮体斜向上运动,把浮渣23汇集到箱体1的中间,浮渣23在浮板一14内汇集堆积,堆积的浮渣23使浮力开关17向上移动,当浮力开关17向上移动后控制电机一10和抽气装置启动,电机一10驱动丝杠6,使安装在丝杠6上的滚珠螺母7移动,安装在滚珠螺母7上的固定板8也跟着移动,通过支撑杆一9与固定板8连接的吸嘴3也跟移动,通过吸嘴3的移动对浮渣23进行全面清理,抽气系统使浮渣23从吸嘴3处进入,通过管一4和管二5使浮渣23进入到浮渣23处理装置,当浮渣23的上表面与液面的距离每变化0.5cm,浮力开关17控制电机一10转速变化500r/min,控制抽气装置的气流风速增减5m/s,在吸嘴3移动时,通过支撑杆二18与滚轮19支撑在浮板二15上,利用浮板二15的浮力作为吸嘴3的支撑力,使吸嘴3与浮渣23保持1cm的距离,防止吸嘴3对浮渣23造成破坏从而使絮体下降,当含油金属废液进入箱体1内的分离区的量减少时,箱体1内的液面下降,浮板二15与浮板一14都下降,保证吸嘴3与浮渣23始终保持1cm的距离,当设备完成对浮渣23的清理后,关闭电机一10,同时打开电机二21,吸嘴3在电机二21的驱动下向下移动5cm,箱体1内净化的水在抽气装置的作用通过吸嘴3和管一4、管二5流到污泥池内,通过干净水流的作用对吸嘴3和管一4、管二5内壁上吸附的浮渣23进行清理,这时整个设备工作完成。When working, the oily heavy metal wastewater to be treated passes through the delivery pipe, adjusts the PH in the delivery pipe, and then enters the reaction zone in the air flotation machine, and adds flocculant (PAC) and coagulant (PAM) in the reaction zone to make the oily heavy metal waste liquid The fine particles in the water condense into large flocs, and the flocs and water enter the contact area, and the dissolved air system absorbs on the flocs through the tiny air bubbles generated by the releaser, and enters the separation area in the box 1 together. The inner flocs rise vertically, and the inclined guide plate 12 and inclined guide plate 2 13 installed in the box body 1 make the flocs move obliquely upwards, and collect the scum 23 in the middle of the box body 1, and the scum 23 is on the floating plate 14 The accumulated scum 23 makes the buoyancy switch 17 move upwards. When the buoyancy switch 17 moves upwards, the motor one 10 and the air extraction device are controlled to start. The motor one 10 drives the lead screw 6, so that the balls installed on the lead screw 6 When the nut 7 moves, the fixed plate 8 installed on the ball nut 7 also moves, and the suction nozzle 3 connected to the fixed plate 8 through the support rod 9 also moves, and the scum 23 is fully cleaned by the movement of the suction nozzle 3. The air suction system makes the scum 23 enter from the suction nozzle 3, and the scum 23 enters the scum 23 treatment device through the first pipe 4 and the second pipe 5. When the distance between the upper surface of the scum 23 and the liquid surface changes by 0.5cm , buoyancy switch 17 controls motor one 10 rotating speed to change 500r/min, the airflow wind speed of control suction device increases or decreases 5m/s, when suction nozzle 3 moves, is supported on floating plate two 15 by support bar two 18 and roller 19, Utilize the buoyancy of the floating plate 2 15 as the supporting force of the suction nozzle 3, keep the suction nozzle 3 and the scum 23 at a distance of 1 cm, prevent the suction nozzle 3 from causing damage to the scum 23 and make the flocs drop, when the oily metal waste liquid enters When the amount of the separation area in the box body 1 decreases, the liquid level in the box body 1 drops, and the floating plate two 15 and the floating plate one 14 both drop to ensure that the distance between the suction nozzle 3 and the scum 23 is always maintained at 1 cm. When the equipment is completed After cleaning the scum 23, turn off the motor one 10, and turn on the motor two 21 at the same time, the suction nozzle 3 moves down 5cm under the drive of the motor two 21, and the water purified in the box body 1 passes through the suction nozzle under the action of the suction device. 3 and pipe one 4 and pipe two 5 flow into the sludge tank, and the scum 23 adsorbed on the inner wall of the suction nozzle 3 and pipe one 4 and pipe two 5 is cleaned by the action of clean water flow, and the whole equipment work is completed at this time.

实施例二,如图1至图8所示,该实施例中,气浮机安装在室外,下雨时,雨滴落到气浮机的箱体1上,对浮渣23造成击打效果,浮渣23在雨点的击打下使絮体和气泡分离,失去气泡的浮力后絮体沉降到水中,为了使气浮机能够在室外下雨的条件下正常进行净水工作,因此在安装架2上安装防护罩24,具体如下:Embodiment two, as shown in Figures 1 to 8, in this embodiment, the air flotation machine is installed outdoors, and when it rains, the raindrops fall on the casing 1 of the air flotation machine, causing the impact effect on the scum 23, The scum 23 separates the flocs from the air bubbles under the impact of the raindrops, and after losing the buoyancy of the air bubbles, the flocs settle into the water. Protective cover 24 is installed on the top, specifically as follows:

安装架2上通过铰链安装有防护罩24,防护罩24覆盖整个安装架2,管二5连接抽气装置和防护罩24的侧面,处于防护罩24外面,管一4安装在防护罩24里面,两端分别连接管二5和吸嘴3。A protective cover 24 is installed on the mounting frame 2 through a hinge, and the protective cover 24 covers the entire mounting frame 2. The second tube 5 connects the air extraction device and the side of the protective cover 24, and is outside the protective cover 24, and the tube one 4 is installed in the protective cover 24. , the two ends are respectively connected to the pipe two 5 and the suction nozzle 3.

实施例一中,由于没有安装防护罩24,因此适合在没有降落物对浮渣23造成破坏的环境内,这就对使用环境有一定的要求,但是设备的使用成本也会降低,首先不需要生产制造防护罩,其次方便工人检查清理装置是否有异常,不用打开防护罩24减少了人工的操作,实施例二中,在安装架2上通过铰链安装有防护罩24,可以防止降落物下降到浮渣23上对浮渣造成破坏,可以使用在有降落物掉落的环境中,但是由于加设了防护罩24,因此会增加设备的成本,在检查清理装置的时候需要打开防护罩24才能对清理装置进行检修。In the first embodiment, since the protective cover 24 is not installed, it is suitable for use in an environment where there is no damage to the scum 23 caused by falling objects, which has certain requirements for the use environment, but the use cost of the equipment will also be reduced. Production and manufacture of protective cover, secondly, it is convenient for workers to check whether the cleaning device is abnormal, without opening the protective cover 24 to reduce manual operations, in embodiment two, the protective cover 24 is installed on the mounting frame 2 by hinges, which can prevent falling objects from falling to The scum 23 damages the scum, and can be used in an environment where falling objects fall, but because the protective cover 24 is added, the cost of the equipment will be increased, and the protective cover 24 needs to be opened when checking the cleaning device. Overhaul the cleaning device.

对于实施例二中未提及的实施方式,均与实施例一相同,在此不做过多赘述。The implementation manners not mentioned in the second embodiment are the same as those in the first embodiment, and will not be repeated here.

尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications and substitutions can be made to these embodiments without departing from the principle and spirit of the present invention. and modifications, the scope of the invention is defined by the appended claims and their equivalents.

Claims (10)

1. A treatment process of oily heavy metal industrial wastewater is characterized by comprising the following steps:
s1: the oily heavy metal wastewater enters a sewage reaction zone of the box body (1), and a flocculating agent (PAC) and a coagulant aid (PAM) are added into the reaction zone;
s2: starting a gas dissolving device, and treating the oily heavy metal wastewater;
s3: the scum (23) rises to the liquid level, and triggers the detection device which controls the cleaning device to start;
s4, pumping the floating scum (23) to a sludge tank through a cleaning device;
s5: and when the wastewater treatment is finished, starting the lifting device, controlling the cleaning device to descend and absorb water by the lifting device, and finishing the cleaning of the cleaning device.
2. The treatment process of the industrial wastewater containing oil and heavy metals, according to claim 1, is characterized in that: cleaning device includes mounting bracket (2) and air exhaust device, movable mounting has suction nozzle (3) in mounting bracket (2), suction nozzle (3) top fixed mounting has pipe (4), pipe (4) are the hose, be connected with pipe two (5) on pipe (4), be connected with air exhaust device on pipe two (5), fixed mounting has the drive arrangement who is used for making suction nozzle (3) removal on mounting bracket (2), drive arrangement includes two lead screw (6), two lead screw (6) rotate and install on mounting bracket (2), and the axial direction of lead screw (6) is parallel with the long limit of mounting bracket (2), two all install ball nut (7) on lead screw (6), two the common fixed mounting in ball nut (7) below has fixed plate (8), it has the hole to open on fixed plate (8), pipe one (4) pass the hole, fixed plate (8) both sides slidable mounting has one (9), the one end and suction nozzle (3) fixed connection of bracing piece (9), fixed mounting bracket (2) is gone up fixed mounting bracket (10), motor (10) are connected through one hold-in-time.
3. The treatment process of the industrial wastewater containing oil and heavy metals according to claim 2, characterized in that: install elevating system on fixed plate (8), elevating system is used for realizing reciprocating of suction nozzle (3), elevating system includes rack (22) of fixed mounting on bracing piece (9), the meshing has the gear on rack (22), gear fixed mounting is in the pivot, the pivot is rotated and is installed on motor two (21).
4. The treatment process of the industrial wastewater containing oil and heavy metals according to claim 2, characterized in that: the box is characterized in that a first inclined guide plate (12) is fixedly mounted on the inner wall of the box body (1), a second inclined guide plate (13) is mounted above the first inclined guide plate (12), the lower end of the second inclined guide plate (13) is lower than the upper end of the first inclined guide plate (12), and the upper end of the second inclined guide plate (13) is flush with the end face of the box body (1).
5. The treatment process of the industrial wastewater containing oil and heavy metals, according to claim 4, is characterized in that: the top fixed mounting of oblique baffle two (13) has kickboard one (14), kickboard one (14) both ends fixed mounting has limiting plate (25), limiting plate (25) slidable mounting is on box (1).
6. The treatment process of the industrial wastewater containing oil and heavy metals, according to claim 5, is characterized in that: the detection device comprises a guide post (16) fixedly installed at the upper end of a first floating plate (14), and a buoyancy switch (17) is installed on the guide post (16) in a sliding mode.
7. The treatment process of the industrial wastewater containing oil and heavy metals according to claim 2, characterized in that: the floating device is arranged on the suction nozzle (3) and used for controlling the distance between the suction nozzle (3) and the liquid level in the box body (1).
8. The treatment process of the oily heavy metal industrial wastewater according to claim 7, characterized in that: the floating device comprises a floating plate II (15), the floating plate II (15) is arranged in a gap between a buoyancy switch (17) and the side wall of the box body (1), two support rods II (18) are fixedly arranged at two ends of the suction nozzle (3), the lower ends of the support rods II (18) are rotated to install rollers (19), and the rollers (19) are in contact with the upper surface of the floating plate II (15).
9. The treatment process of the industrial wastewater containing oil and heavy metals according to claim 2, characterized in that: the suction nozzle (3) is made of PP plastic materials with light weight and corrosion resistance.
10. The treatment process of the industrial wastewater containing oil and heavy metals according to claim 2, characterized in that: and a one-way valve (20) is arranged at the joint of the first pipe (4) and the suction nozzle (3).
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