CN115354105B - A system and method for reducing exhaust gas circulation with gas-based direct reduction of iron - Google Patents
A system and method for reducing exhaust gas circulation with gas-based direct reduction of iron Download PDFInfo
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- CN115354105B CN115354105B CN202210988593.1A CN202210988593A CN115354105B CN 115354105 B CN115354105 B CN 115354105B CN 202210988593 A CN202210988593 A CN 202210988593A CN 115354105 B CN115354105 B CN 115354105B
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
- C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/66—Heat exchange
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Abstract
Description
技术领域Technical Field
本发明属于金属冶炼技术领域,具体涉及一种还原乏气循环的气基直接还原铁的系统与方法。The invention belongs to the technical field of metal smelting, and in particular relates to a system and method for gas-based direct reduction of iron by reducing a waste gas cycle.
背景技术Background technique
本发明背景技术中公开的信息仅仅旨在增加对本发明的总体背景的理解,而不必然被视为承认或以任何形式暗示该信息构成已经成为本领域一般技术人员所公知的现有技术。The information disclosed in the background of the invention is only intended to enhance the understanding of the overall background of the invention and should not be necessarily regarded as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to a person skilled in the art.
目前,钢铁生产过程主要是以烧结和高炉的长流程工艺为主,运行过程存在工艺流程复杂、能耗高、污染物排放量大等问题。另一方面,随着工业化进程深入,废钢回收率增大,废钢的利用对直接还原铁(海绵铁)的需求也显著提高。直接还原铁是一种工业原料,主要用于电炉炼钢,部分代替废钢或与废钢搭配使用,以改善炉料。At present, the steel production process is mainly based on the long process of sintering and blast furnace, and the operation process has problems such as complex process flow, high energy consumption, and large pollutant emissions. On the other hand, with the deepening of industrialization, the recycling rate of scrap steel has increased, and the demand for direct reduced iron (sponge iron) for the utilization of scrap steel has also increased significantly. Direct reduced iron is an industrial raw material, mainly used in electric furnace steelmaking, partially replacing scrap steel or used in combination with scrap steel to improve furnace charges.
气基直接还原的短流程炼铁工艺不仅可以满足对直接还原铁生产的需求,并且还具有工艺流程短、污染物排放量低的优点。但是气基直接还原铁能耗相比于高炉高,其主要原因在于传统高炉冶炼过程充分利用了还原气的还原势和逆流换热,排出的高炉煤气热值低、温度低;而短流程铁冶炼过程排出的还原乏气还原势高、温度高,因此降低气基直接还原铁的能耗是短流程直接还原铁大规模工业化应用必须解决的问题。The short-process ironmaking process of gas-based direct reduction can not only meet the demand for direct reduced iron production, but also has the advantages of short process flow and low pollutant emissions. However, the energy consumption of gas-based direct reduced iron is higher than that of blast furnace. The main reason is that the traditional blast furnace smelting process fully utilizes the reducing potential and countercurrent heat exchange of the reducing gas, and the discharged blast furnace gas has low calorific value and low temperature; while the reducing exhaust gas discharged from the short-process iron smelting process has high reducing potential and high temperature. Therefore, reducing the energy consumption of gas-based direct reduced iron is a problem that must be solved for the large-scale industrial application of short-process direct reduced iron.
发明内容Summary of the invention
鉴于目前我国能源现状及气基直接还原铁过程能耗高的双重问题,本发明提供一种还原乏气循环的气基直接还原铁的系统与方法。本发明提出利用煤炭或者生物质等富碳原料气化制备还原气,并且根据气基直接还原铁工艺过程,将具有一定还原势和显热能的还原乏气,实现还原乏气热、质回用,重新返回至直接还原铁冶炼过程,从而降低气基短流程炼铁过程的能耗。In view of the current energy situation in my country and the high energy consumption of the gas-based direct reduction of iron process, the present invention provides a system and method for gas-based direct reduction of iron with a reduction exhaust gas cycle. The present invention proposes to prepare reducing gas by gasifying carbon-rich raw materials such as coal or biomass, and according to the gas-based direct reduction of iron process, the reduction exhaust gas with a certain reduction potential and sensible heat energy is recycled to realize the heat and quality recovery of the reduction exhaust gas and return it to the direct reduction of iron smelting process, thereby reducing the energy consumption of the gas-based short-process ironmaking process.
为实现上述目的,本发明采用如下的技术方案:To achieve the above object, the present invention adopts the following technical solution:
本发明第一方面,提供一种还原乏气循环的气基直接还原铁的系统,包括:气化装置、混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置、变压吸附提纯装置、还原铁粉冷却器、磁选装置和热压装置;所述气化装置、混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置和变压吸附提纯装置依次相连,所述矿粉预热单元、矿粉还原单元、还原铁粉冷却器、磁选装置和热压装置依次相连。In a first aspect, the present invention provides a system for reducing gas-spent-gas-circulated gas-based direct-reduced iron, comprising: a gasification device, a mixing unit, a ore powder reduction unit, a ore powder preheating unit, a heat recovery device, a waste heat boiler, a dust removal device, a pressure swing adsorption purification device, a reduced iron powder cooler, a magnetic separation device and a hot pressing device; the gasification device, the mixing unit, the ore powder reduction unit, the ore powder preheating unit, the heat recovery device, the waste heat boiler, the dust removal device and the pressure swing adsorption purification device are connected in sequence, and the ore powder preheating unit, the ore powder reduction unit, the reduced iron powder cooler, the magnetic separation device and the hot pressing device are connected in sequence.
进一步的,所述系统还包括燃烧装置;所述燃烧装置的入口与除尘装置相连,所述燃烧装置的出口管道和回热装置的出口管道相连并汇合成一管道与混合单元相连。Furthermore, the system also includes a combustion device; the inlet of the combustion device is connected to the dust removal device, and the outlet pipe of the combustion device is connected to the outlet pipe of the heat recovery device and merged into a pipe connected to the mixing unit.
本发明提供一种还原乏气循环的气基直接还原铁的方法。所述方法包括如下步骤:The present invention provides a method for reducing gas-based direct reduction of iron by exhaust gas circulation. The method comprises the following steps:
(1)富碳原料在气化装置中与气化剂发生反应,生成富H2、CO的气体,除尘装置出口温度较低的部分还原乏气回送至气化装置调温;(1) The carbon-rich raw material reacts with the gasifying agent in the gasification device to generate H 2 and CO-rich gas, and the reduced exhaust gas with a lower outlet temperature of the dust removal device is returned to the gasification device for temperature adjustment;
(2)气化装置产生的气化气在混合单元,与提纯升温后的循环还原气混合成还原气,进入矿粉还原单元发生铁矿粉的还原反应;铁矿粉转化为直接还原铁粉产品,直接还原铁粉产品经铁粉冷却器冷却,进入磁选装置实现初次筛选提纯,再经热压装置热压成块,然后输送至下一工序;(2) The gasification gas generated by the gasification device is mixed with the purified and heated circulating reducing gas in the mixing unit to form reducing gas, which then enters the ore powder reduction unit to undergo a reduction reaction of the iron ore powder; the iron ore powder is converted into a direct reduced iron powder product, which is cooled in an iron powder cooler and enters a magnetic separation device for primary screening and purification, and then is hot-pressed into blocks in a hot pressing device and transported to the next process;
(3)直接还原反应发生后,还原气转化为还原乏气;还原乏气进入矿粉预热单元对铁矿粉原料进行预热,随后还原乏气进入回热装置,在回热装置中还原乏气与提纯后的循环还原气进行热量交换,还原乏气的温度降至200-500℃,然后进入余热锅炉回收剩余显热能;(3) After the direct reduction reaction occurs, the reducing gas is converted into reducing exhaust gas; the reducing exhaust gas enters the ore powder preheating unit to preheat the iron ore powder raw material, and then the reducing exhaust gas enters the heat recovery device, where the reducing exhaust gas exchanges heat with the purified circulating reducing gas, and the temperature of the reducing exhaust gas drops to 200-500°C, and then enters the waste heat boiler to recover the remaining sensible heat energy;
(4)从余热锅炉出口排出的还原乏气,经除尘后,大部分还原乏气进入变压吸附提纯装置,脱除还原气中的H2O和CO2,得到提纯后的循环还原气,然后循环还原气经过回热装置回收还原乏气部分显热,一部分还原乏气在燃烧装置中燃烧将回热装置出来的循环还原气温度提升,在混合单元与气化装置产的气化气混合;另一部分还原乏气进入气化装置参与气化气调温。(4) After dust removal, most of the reduced exhaust gas discharged from the outlet of the waste heat boiler enters the pressure swing adsorption purification device to remove H2O and CO2 in the reduced gas to obtain purified circulating reduced gas. The circulating reduced gas then passes through the heat recovery device to recover part of the sensible heat of the reduced exhaust gas. A part of the reduced exhaust gas is burned in the combustion device to increase the temperature of the circulating reduced gas from the heat recovery device, and is mixed with the gasified gas produced by the gasification device in the mixing unit; the other part of the reduced exhaust gas enters the gasification device to participate in the temperature control of the gasified gas.
进一步的,富碳原料包括煤炭、生物质等。气化剂包括纯O2、H2O、CO2。Furthermore, the carbon-rich raw materials include coal, biomass, etc. The gasifying agent includes pure O 2 , H 2 O, CO 2 .
进一步的,气化装置中,富碳原料和气化剂在1200-2000℃的高温范围内发生反应;部分余热锅炉出口温度较低的还原乏气回送至气化装置调温,最终气化装置出口气化气的温度为800-1300℃。Furthermore, in the gasification device, the carbon-rich raw material and the gasifying agent react in the high temperature range of 1200-2000°C; part of the reducing exhaust gas with a lower outlet temperature of the waste heat boiler is returned to the gasification device for temperature adjustment, and finally the temperature of the gasified gas at the outlet of the gasification device is 800-1300°C.
进一步的,气化气的组成为:CO体积百分比为30~60%,H2体积百分比为20~40%,CO2体积百分比为0~15%,H2O的体积百分比为0~10%。Furthermore, the composition of the gasification gas is: 30-60% by volume of CO, 20-40% by volume of H2 , 0-15% by volume of CO2 , and 0-10% by volume of H2O .
进一步的,还原后的铁矿粉经铁粉冷却器,温度降至25-700℃。Furthermore, the reduced iron ore powder passes through an iron powder cooler and its temperature drops to 25-700°C.
进一步的,还原气组分为:CO体积百分比为40~60%,H2体积百分比为30~40%,CO2体积百分比为0~5%,H2O的体积百分比为0~5%。还原气温度为800~1300℃。Further, the reducing gas composition is: CO volume percentage is 40-60%, H 2 volume percentage is 30-40%, CO 2 volume percentage is 0-5%, and H 2 O volume percentage is 0-5%. The reducing gas temperature is 800-1300°C.
还原反应温度控制在800~1100℃之间。The reduction reaction temperature is controlled between 800 and 1100°C.
进一步的,直接还原反应发生后,还原气转化为还原乏气,其温度为700-1000℃。Furthermore, after the direct reduction reaction occurs, the reducing gas is converted into reducing exhausted gas, the temperature of which is 700-1000°C.
进一步的,还原乏气将常温下铁矿粉原料预热至500-800℃。Furthermore, the reduction exhaust gas preheats the iron ore powder raw material at room temperature to 500-800°C.
进一步的,从矿粉预热单元出的还原乏气,温度为600-900℃,在回热装置中与提纯后的循环还原气进行热量交换,还原乏气的温度降至200-500℃。Furthermore, the reduction exhaust gas from the ore powder preheating unit has a temperature of 600-900°C, and exchanges heat with the purified circulating reduction gas in the heat recovery device, so that the temperature of the reduction exhaust gas drops to 200-500°C.
进一步的,从余热锅炉出口排出的还原乏气温度为100-300℃。Furthermore, the temperature of the reduction exhaust gas discharged from the outlet of the waste heat boiler is 100-300°C.
进一步的,通过燃烧部分还原乏气将循环还原气温度提升至800-1300℃。Furthermore, the temperature of the circulating reducing gas is increased to 800-1300°C by burning part of the reducing exhaust gas.
进一步的,经过变压吸附提纯的循环还原气中CO2和H2O体积百分比为0~5%,CO体积百分比为50~60%,H2体积百分比为40~50%。Furthermore, the volume percentages of CO 2 and H 2 O in the circulating reducing gas purified by pressure swing adsorption are 0-5%, the volume percentage of CO is 50-60%, and the volume percentage of H 2 is 40-50%.
进一步的,利用燃烧装置燃烧部分还原乏气,燃烧产生的高温烟气热量传递给循环还原气,可以利用蓄热式换热器或耐高温的管壳式换热器实现。Furthermore, a combustion device is used to burn part of the reducing exhaust gas, and the heat of the high-temperature flue gas generated by the combustion is transferred to the circulating reducing gas, which can be achieved by using a heat storage heat exchanger or a high-temperature resistant shell and tube heat exchanger.
进一步的,所述铁矿粉的粒径为50~1000微米。Furthermore, the particle size of the iron ore powder is 50 to 1000 microns.
进一步的,气体输送过程由引风机或者送风机提供输送动力。Furthermore, the gas conveying process is powered by an induced draft fan or a forced draft fan.
进一步的,所述除尘装置可以是布袋除尘、旋风分离器、轴流式旋流子分离器、静电除尘器等。Furthermore, the dust removal device may be a bag dust collector, a cyclone separator, an axial flow cyclone separator, an electrostatic precipitator, or the like.
本发明的有益效果:本发明提出一种气基直接还原铁的还原乏气循环的工艺及方法。根据短流程直接还原铁工艺过程中还原乏气还原势和温度较高的特点,通过合理布置还原乏气提纯及循环方式,实现还原气热/质循环利用,增大铁矿粉还原处理量,降低系统吨铁能耗,提高系统经济性,具有广阔的应用前景。Beneficial effects of the invention: The invention proposes a process and method for recycling reduction exhaust gas of gas-based direct reduction of iron. According to the characteristics of high reduction potential and temperature of reduction exhaust gas in the short-process direct reduction of iron process, by rationally arranging the purification and circulation mode of reduction exhaust gas, the heat/quality recycling of reduction gas is realized, the reduction processing capacity of iron ore powder is increased, the energy consumption per ton of iron of the system is reduced, and the economy of the system is improved, which has broad application prospects.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
构成本发明的一部分的说明书附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。The accompanying drawings in the specification, which constitute a part of the present invention, are used to provide a further understanding of the present invention. The exemplary embodiments of the present invention and their descriptions are used to explain the present invention and do not constitute improper limitations on the present invention.
图1为本发明的气基直接还原铁的还原乏气循环的工艺示意图。FIG1 is a schematic diagram of the process of reducing exhaust gas circulation for gas-based direct reduction of iron according to the present invention.
具体实施方式Detailed ways
应该指出,以下详细说明都是例示性的,旨在对本发明提供进一步的说明。除非另有指明,本文使用的所有技术和科学术语具有与本发明所属技术领域的普通技术人员通常理解的相同含义。It should be noted that the following detailed descriptions are all illustrative and intended to provide further explanation of the present invention. Unless otherwise specified, all technical and scientific terms used herein have the same meanings as those commonly understood by those skilled in the art to which the present invention belongs.
如图1所示,本发明提供一种还原乏气循环的气基直接还原铁的系统与方法。As shown in FIG. 1 , the present invention provides a system and method for reducing waste gas circulation to directly reduce iron.
本发明提供一种气基直接还原铁的还原乏气循环的系统,包括:气化装置、还原气混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置、变压吸附提纯装置、燃烧装置、还原铁粉冷却器、磁选装置和热压装置。所述气化装置、混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置和变压吸附提纯装置依次相连,所述矿粉预热单元、矿粉还原单元、还原铁粉冷却器、磁选装置和热压装置依次相连。The present invention provides a system for reducing exhaust gas circulation of gas-based direct reduced iron, comprising: a gasification device, a reducing gas mixing unit, a mineral powder reduction unit, a mineral powder preheating unit, a heat recovery device, a waste heat boiler, a dust removal device, a pressure swing adsorption purification device, a combustion device, a reduced iron powder cooler, a magnetic separation device and a hot pressing device. The gasification device, the mixing unit, the mineral powder reduction unit, the mineral powder preheating unit, the heat recovery device, the waste heat boiler, the dust removal device and the pressure swing adsorption purification device are connected in sequence, and the mineral powder preheating unit, the mineral powder reduction unit, the reduced iron powder cooler, the magnetic separation device and the hot pressing device are connected in sequence.
本发明还提供一种气基直接还原铁的还原乏气循环的方法。The present invention also provides a method for recycling reduction exhaust gas in gas-based direct reduction of iron.
首先,煤炭或者生物质等富碳原料在1200-2000℃的高温范围内与纯O2、H2O、CO2等气化剂反应,生成富H2、CO的气化气,发生的主要反应有C+O2=CO2,C+O2=2CO,C+CO2=2CO,C+H2O=CO+H2。部分余热锅炉出口温度较低的还原乏气回送至气化装置调温,最终气化装置出口气化气的温度为800-1300℃。根据富碳原料的不同,所述气化装置产的气化气浓度在一定范围内变化,其中CO体积百分比为30~60%,H2体积百分比为20~40%,CO2体积百分比为0~15%,H2O的体积百分比为0~10%。First, carbon-rich raw materials such as coal or biomass react with gasifying agents such as pure O 2 , H 2 O, and CO 2 at a high temperature range of 1200-2000°C to generate gasification gas rich in H 2 and CO. The main reactions that occur are C+O 2 =CO 2 , C+O 2 =2CO, C+CO 2 =2CO, and C+H 2 O =CO+H 2. Part of the reduced exhaust gas with a lower outlet temperature of the waste heat boiler is returned to the gasification device for temperature adjustment, and the temperature of the gasification gas at the outlet of the gasification device is finally 800-1300°C. Depending on the different carbon-rich raw materials, the concentration of the gasification gas produced by the gasification device varies within a certain range, wherein the volume percentage of CO is 30-60%, the volume percentage of H 2 is 20-40%, the volume percentage of CO 2 is 0-15%, and the volume percentage of H 2 O is 0-10%.
气化装置产的气化气在混合单元,与提纯升温后的循环还原气混合成还原气,进入矿粉还原单元发生铁矿粉的还原反应,主要反应有3Fe2O3+CO=2Fe3O4+CO2,Fe3O4+CO=3FeO+CO2,FeO+CO=Fe+CO2,Fe2O3+CO=2FeO+CO2,3Fe2O3+H2=2Fe3O4+H2O,Fe3O4+H2=3FeO+H2O,FeO+H2=Fe+H2O,Fe2O3+H2=2FeO+H2O。反应中,还原气中有效成分CO和H2最终剥夺铁矿粉中的氧原子,生成CO2和H2O(还原气中CO和H2部分转化为CO2和H2O,但CO和H2仍是主要部分)。同时铁矿粉转化为直接还原铁粉产品,还原后的铁矿粉经铁粉冷却器,温度可降至25-700℃,降温的作用是防止直接还原铁的二次氧化。冷却后的直接还原铁粉进入磁选装置实现初次筛选提纯,再经热压装置热压成块,然后输送至下一工序。The gasification gas produced by the gasification device is mixed with the purified and heated circulating reducing gas in the mixing unit to form reducing gas , and then enters the ore powder reduction unit to undergo reduction reaction of iron ore powder. The main reactions are 3Fe2O3 +CO=2Fe3O4 + CO2 , Fe3O4+CO= 3FeO + CO2 , FeO+CO = Fe + CO2 , Fe2O3+CO= 2FeO + CO2 , 3Fe2O3 + H2 = 2Fe3O4 + H2O , Fe3O4 + H2=3FeO+H2O, FeO+H2 = Fe + H2O , Fe2O3 + H2 =2FeO + H2O . During the reaction, the effective components CO and H2 in the reducing gas eventually deprive the oxygen atoms in the iron ore powder to generate CO2 and H2O (CO and H2 in the reducing gas are partially converted into CO2 and H2O , but CO and H2 are still the main parts). At the same time, the iron ore powder is converted into a direct reduced iron powder product. The reduced iron ore powder passes through an iron powder cooler, and the temperature can be reduced to 25-700℃. The cooling function is to prevent the secondary oxidation of the direct reduced iron. The cooled direct reduced iron powder enters the magnetic separation device for primary screening and purification, and then is hot-pressed into blocks by a hot pressing device, and then transported to the next process.
直接还原反应发生后,还原气转化为还原乏气(H2和CO还原势有所降低),但是还具有一定的还原势及显热能,温度为700-1000℃,放散会造成能源的直接浪费,但是由于还原乏气还具有热值低、气量小的等特点,直接燃烧发电回收能量的节能方式往往是不节能的。因此,本发明提出,对还原后的还原乏气实现热/质回收。回收还原乏气的显热,首先对铁矿粉原料进行预热,将常温下铁矿粉原料预热至500-800℃。从矿粉预热单元出的还原乏气,温度约为600-900℃,在回热装置中与提纯后的循环还原气进行热量交换,还原乏气的温度降至200-500℃,然后进入余热锅炉回收剩余显热能。After the direct reduction reaction occurs, the reducing gas is converted into reducing exhaust gas (the reduction potential of H2 and CO is reduced), but it still has a certain reduction potential and sensible heat energy, and the temperature is 700-1000°C. Dissipation will cause direct waste of energy. However, since the reducing exhaust gas also has the characteristics of low calorific value and small gas volume, the energy-saving method of directly burning to generate electricity and recover energy is often not energy-saving. Therefore, the present invention proposes to realize heat/mass recovery of the reduced exhaust gas after reduction. To recover the sensible heat of the reducing exhaust gas, first preheat the iron ore powder raw material to 500-800°C at room temperature. The reducing exhaust gas from the ore powder preheating unit has a temperature of about 600-900°C. It exchanges heat with the purified circulating reducing gas in the heat recovery device, and the temperature of the reducing exhaust gas drops to 200-500°C, and then enters the waste heat boiler to recover the remaining sensible heat energy.
从余热锅炉出口排出的还原乏气温度约为100-300℃,经除尘后,大部分还原乏气进入变压吸附提纯装置,脱除还原气中的CO2和H2O,提高循环还原气的还原势,然后经过回热装置回收还原乏气部分显热,通过燃烧部分还原乏气将循环还原气温度提升至800-1300℃,在混合单元与气化装置产的气化气混合。所述经过变压吸附提纯的循环还原气中CO2和H2O体积百分比约为0~5%,CO体积百分比为50~60%,H2体积百分比为40~50%。The temperature of the reduced exhaust gas discharged from the outlet of the waste heat boiler is about 100-300℃. After dust removal, most of the reduced exhaust gas enters the pressure swing adsorption purification device to remove CO2 and H2O in the reduced gas, improve the reduction potential of the circulating reduced gas, and then recovers part of the sensible heat of the reduced exhaust gas through the heat recovery device. The temperature of the circulating reduced gas is increased to 800-1300℃ by burning part of the reduced exhaust gas, and is mixed with the gasified gas produced by the gasification device in the mixing unit. The volume percentages of CO2 and H2O in the circulating reduced gas purified by pressure swing adsorption are about 0-5%, the volume percentage of CO is 50-60%, and the volume percentage of H2 is 40-50%.
在一些实施方式中,利用燃烧装置燃烧部分还原乏气,燃烧产生的高温烟气热量传递给循环还原气,可以利用蓄热式换热器或耐高温的管壳式换热器实现。In some embodiments, a combustion device is used to burn part of the reducing exhaust gas, and the heat of the high-temperature flue gas generated by the combustion is transferred to the circulating reducing gas, which can be achieved by using a heat storage heat exchanger or a high-temperature resistant shell and tube heat exchanger.
在一些实施方式中,所述铁矿粉的粒径为50~1000微米。In some embodiments, the iron ore powder has a particle size of 50 to 1000 microns.
在一些实施方式中,所述气化装置可以为多种形式,可以是回转窑、移动床、气流床、流化床、沸腾床、鼓泡床、喷动床、沉降床等;所述矿粉预热和还原单元的反应器结构形式可以为回转窑、移动床、气流床、流化床、沸腾床、鼓泡床、喷动床、沉降床等。还原气和铁矿粉的流动方向整体为逆势,增大换热温差,提高热、质交换效率。In some embodiments, the gasification device may be in various forms, such as a rotary kiln, a moving bed, an entrained bed, a fluidized bed, an ebullating bed, a bubbling bed, a spouted bed, a settling bed, etc. The reactor structure of the ore powder preheating and reduction unit may be a rotary kiln, a moving bed, an entrained bed, a fluidized bed, an ebullating bed, a bubbling bed, a spouted bed, a settling bed, etc. The flow direction of the reducing gas and the iron ore powder is countercurrent as a whole, which increases the heat exchange temperature difference and improves the heat and mass exchange efficiency.
在一些实施方式中,上述气体输送过程由引风机或者送风机提供输送动力。In some embodiments, the gas delivery process is powered by an induced draft fan or a forced draft fan.
在一些实施方式中,上述除尘装置可以是布袋除尘、旋风分离器、轴流式旋流子分离器、静电除尘器等。In some embodiments, the dust removal device may be a bag dust collector, a cyclone separator, an axial flow cyclone separator, an electrostatic precipitator, or the like.
整个工艺过程实现还原乏气零外排,大部分还原乏气进入变压吸附提纯装置转化为循环还原气,少部分去往气化装置调温或者送至燃烧器燃烧使用;其中,进入变压吸附提纯装置中的还原乏气占总还原气量/还原乏气量的85~95%;进入燃烧器和送往气化装置调温的还原乏气占总还原气量/还原乏气量的5%~15%。The whole process achieves zero external discharge of reduction exhaust gas. Most of the reduction exhaust gas enters the pressure swing adsorption purification device to be converted into circulating reduction gas, and a small part goes to the gasification device for temperature adjustment or is sent to the burner for combustion. Among them, the reduction exhaust gas entering the pressure swing adsorption purification device accounts for 85% to 95% of the total reduction gas volume/reduction exhaust gas volume; the reduction exhaust gas entering the burner and sent to the gasification device for temperature adjustment accounts for 5% to 15% of the total reduction gas volume/reduction exhaust gas volume.
利用变压吸附提纯装置去除循环还原气中大部分H2O和CO2,根据气化装置设计容量及对还原气成分要求,将脱除下的H2O和CO2作为气化剂送入气化装置参与气化反应,实现H2O/CO2回质循环,降低外排量。The pressure swing adsorption purification device is used to remove most of the H 2 O and CO 2 in the circulating reducing gas. According to the design capacity of the gasification device and the requirements for the reducing gas composition, the removed H 2 O and CO 2 are sent to the gasification device as gasification agents to participate in the gasification reaction, realizing the H 2 O/CO 2 mass return cycle and reducing the external discharge volume.
本发明的创新点在于充分利用了直接还原铁系统中还原乏气还原势和温度较高的特点,对还原乏气热/质回用,从而降低能耗。The innovation of the present invention is to make full use of the high reduction potential and temperature of the reduction exhaust gas in the direct reduction iron system, recycle the heat/mass of the reduction exhaust gas, and thus reduce energy consumption.
实施例1Example 1
一种气基直接还原铁的还原乏气循环的系统,包括:气化装置、还原气混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置、变压吸附提纯装置、燃烧装置、还原铁粉冷却器、磁选装置和热压装置。所述气化装置、混合单元、矿粉还原单元、矿粉预热单元、回热装置、余热锅炉、除尘装置和变压吸附提纯装置依次相连,所述矿粉预热单元、矿粉还原单元、还原铁粉冷却器、磁选装置和热压装置依次相连。A system for reducing exhaust gas circulation of gas-based direct reduced iron comprises: a gasification device, a reducing gas mixing unit, a mineral powder reduction unit, a mineral powder preheating unit, a heat recovery device, a waste heat boiler, a dust removal device, a pressure swing adsorption purification device, a combustion device, a reduced iron powder cooler, a magnetic separation device and a hot pressing device. The gasification device, the mixing unit, the mineral powder reduction unit, the mineral powder preheating unit, the heat recovery device, the waste heat boiler, the dust removal device and the pressure swing adsorption purification device are connected in sequence, and the mineral powder preheating unit, the mineral powder reduction unit, the reduced iron powder cooler, the magnetic separation device and the hot pressing device are connected in sequence.
一种基于上述系统的气基直接还原铁的还原乏气循环的方法,包括如下步骤:A method for recycling the reduction exhaust gas of gas-based direct iron reduction based on the above system comprises the following steps:
(1)生物质在气化装置中与氧气发生反应,生成富H2、CO的气体,除尘装置出口温度较低的部分还原乏气回送至气化装置调温;气化装置中,富碳原料和气化剂在1200-2000℃的高温范围内发生反应;部分余热锅炉出口温度较低的还原乏气回送至气化装置调温,最终气化装置出口气化气的温度范围为800-1300℃。(1) Biomass reacts with oxygen in the gasification device to generate H2 and CO-rich gas. Part of the reduced exhaust gas with a lower outlet temperature of the dust removal device is returned to the gasification device for temperature adjustment. In the gasification device, the carbon-rich raw material and the gasifying agent react at a high temperature range of 1200-2000°C. Part of the reduced exhaust gas with a lower outlet temperature of the waste heat boiler is returned to the gasification device for temperature adjustment. Finally, the temperature range of the gasified gas at the outlet of the gasification device is 800-1300°C.
(2)气化装置产生的气化气在混合单元,与提纯升温后的循环还原气混合成还原气,进入矿粉还原单元发生铁矿粉的还原反应;铁矿粉转化为直接还原铁粉产品,直接还原铁粉产品经铁粉冷却器冷却,进入磁选装置实现初次筛选提纯,再经热压装置热压成块,然后输送至下一工序;还原后的铁矿粉经铁粉冷却器,温度降至100℃左右。直接还原反应发生后,还原气转化为还原乏气,其温度为700℃。(2) The gasification gas generated by the gasification device is mixed with the purified and heated circulating reduction gas in the mixing unit to form reduction gas, which enters the ore powder reduction unit to undergo a reduction reaction of the iron ore powder; the iron ore powder is converted into a direct reduced iron powder product, which is cooled by an iron powder cooler and enters a magnetic separation device for primary screening and purification, and then is hot-pressed into blocks by a hot pressing device and then transported to the next process; the reduced iron ore powder passes through an iron powder cooler and its temperature drops to about 100°C. After the direct reduction reaction occurs, the reduction gas is converted into reduced exhaust gas, the temperature of which is 700°C.
(3)直接还原反应发生后,还原气转化为还原乏气;还原乏气进入矿粉预热单元对铁矿粉原料进行预热,随后还原乏气进入回热装置,在回热装置中还原乏气与提纯后的循环还原气进行热量交换,还原乏气的温度降至200℃,然后进入余热锅炉回收剩余显热能;还原乏气将常温下铁矿粉原料预热至500℃左右。(3) After the direct reduction reaction occurs, the reducing gas is converted into reducing exhaust gas; the reducing exhaust gas enters the ore powder preheating unit to preheat the iron ore powder raw material, and then the reducing exhaust gas enters the heat recovery device, where the reducing exhaust gas exchanges heat with the purified circulating reducing gas, and the temperature of the reducing exhaust gas drops to 200°C, and then enters the waste heat boiler to recover the remaining sensible heat energy; the reducing exhaust gas preheats the iron ore powder raw material at room temperature to about 500°C.
(4)从余热锅炉出口排出的还原乏气,经除尘后,大部分还原乏气进入变压吸附提纯装置,脱除还原气中的H2O和CO2,得到提纯后的循环还原气,然后循环还原气经过回热装置回收还原乏气部分显热,一部分还原乏气在燃烧装置中燃烧将回热装置出来的循环还原气温度提升,在混合单元与气化装置产的气化气混合;另一部分还原乏气进入气化装置参与气化气调温。从矿粉预热单元出的还原乏气,温度为600℃,在回热装置中与提纯后的循环还原气进行热量交换,还原乏气的温度降至200℃。从余热锅炉出口排出的还原乏气温度为100℃。通过燃烧部分还原乏气将循环还原气温度提升至800℃。(4) After dust removal, most of the reduced exhaust gas discharged from the outlet of the waste heat boiler enters the pressure swing adsorption purification device to remove H 2 O and CO 2 in the reduced gas to obtain the purified circulating reduced gas. Then, the circulating reduced gas passes through the heat recovery device to recover part of the sensible heat of the reduced exhaust gas. Part of the reduced exhaust gas is burned in the combustion device to increase the temperature of the circulating reduced gas from the heat recovery device, and is mixed with the gasification gas produced by the gasification device in the mixing unit; the other part of the reduced exhaust gas enters the gasification device to participate in the temperature adjustment of the gasification gas. The reduced exhaust gas discharged from the mineral powder preheating unit has a temperature of 600°C. It exchanges heat with the purified circulating reduced gas in the heat recovery device, and the temperature of the reduced exhaust gas drops to 200°C. The temperature of the reduced exhaust gas discharged from the outlet of the waste heat boiler is 100°C. The temperature of the circulating reduced gas is increased to 800°C by burning part of the reduced exhaust gas.
气体输送过程由引风机提供输送动力。所述除尘装置为布袋除尘。The induced draft fan provides the conveying power for the gas conveying process. The dust removal device is a bag dust removal device.
以上所述仅为本发明的优选实施例,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and variations. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
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