CN115301090B - Dynamic regulation type salt aerosol generator suitable for high back pressure change range - Google Patents
Dynamic regulation type salt aerosol generator suitable for high back pressure change range Download PDFInfo
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- 239000000443 aerosol Substances 0.000 title claims abstract description 69
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- 238000005243 fluidization Methods 0.000 claims description 9
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- 238000012216 screening Methods 0.000 abstract description 2
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- 239000007789 gas Substances 0.000 description 35
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
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- 238000002474 experimental method Methods 0.000 description 5
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- 238000009434 installation Methods 0.000 description 3
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- -1 CsI and CsOH Chemical class 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/29—Mixing systems, i.e. flow charts or diagrams
- B01F23/291—Mixing systems, i.e. flow charts or diagrams for obtaining foams or aerosols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/70—Mixers specially adapted for working at sub- or super-atmospheric pressure, e.g. combined with de-foaming
- B01F33/71—Mixers specially adapted for working at sub- or super-atmospheric pressure, e.g. combined with de-foaming working at super-atmospheric pressure, e.g. in pressurised vessels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/836—Mixing plants; Combinations of mixers combining mixing with other treatments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/211—Measuring of the operational parameters
- B01F35/2113—Pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/211—Measuring of the operational parameters
- B01F35/2115—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2135—Humidity, e.g. moisture content
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/22—Control or regulation
- B01F35/2201—Control or regulation characterised by the type of control technique used
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/22—Control or regulation
- B01F35/221—Control or regulation of operational parameters, e.g. level of material in the mixer, temperature or pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0095—Preparation of aerosols
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
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Abstract
Description
技术领域technical field
本发明属于气溶胶发生器领域,具体涉及一种适用于高背压变化范围的动态调节式盐类气溶胶发生器。The invention belongs to the field of aerosol generators, and in particular relates to a dynamically adjustable salt aerosol generator suitable for high back pressure variation range.
背景技术Background technique
核电站发生严重事故时,如一回路大破口事故伴随着堆芯燃料元件包壳的失效,一回路的冷却剂会大量外泄并携带着从堆芯释放的裂变产物进入安全壳。若进一步发生堆芯熔毁的现象,极高温度的堆芯熔融物质会熔穿反应堆压力容器,裂变产物与冷却剂进一步向安全壳内泄漏。裂变产物与冷却剂泄漏到安全壳内时,由于安全壳内是低温低压的环境,冷却剂会随着环境压力的瞬间下降而发生闪蒸的现象,在冷却剂内溶解的放射性物质则随着水的蒸发变成气溶胶出现在安全壳内部,比如CsI、CsOH等盐类物质,其他的裂变产物也可能在温度降低的条件下通过均相成核及非均相成核现象形成气溶胶,比如SnO2。若伴随着安全壳的完整性受到破坏,气溶胶则会进一步释放到外界环境中,并对周边人员及环境造成严重的放射性危害。为了评估其可能造成的放射性威胁,并设计相应的事故缓解手段,需要对安全壳内放射性气溶胶浓度分布进行准确地评估。When a serious accident occurs in a nuclear power plant, such as a large breach accident in the primary circuit accompanied by the failure of the core fuel element cladding, a large amount of coolant in the primary circuit will leak out and carry fission products released from the core into the containment. If further core meltdown occurs, the extremely high-temperature core molten material will melt through the reactor pressure vessel, and the fission products and coolant will further leak into the containment vessel. When the fission products and coolant leak into the containment vessel, since the containment vessel is a low-temperature and low-pressure environment, the coolant will flash as the ambient pressure drops instantaneously, and the radioactive substances dissolved in the coolant will The evaporation of water turns aerosols into the containment, such as salts such as CsI and CsOH, and other fission products may also form aerosols through homogeneous nucleation and heterogeneous nucleation under the condition of lowered temperature. Such as SnO 2 . If the integrity of the containment vessel is damaged, the aerosol will be further released into the external environment and cause serious radioactive hazards to surrounding personnel and the environment. In order to assess the possible radioactive threats and design corresponding accident mitigation measures, it is necessary to accurately assess the distribution of radioactive aerosol concentrations in the containment.
由于上述两种气溶胶的物性不同,比如亲水性、吸湿性等,根据此性质可以将其划分为可溶性及不溶性气溶胶,这也意味着这两种气溶胶在安全壳内的迁移、凝并及自然沉降特性有着较大的差异,所以需要对不同气溶胶在安全壳内的迁移沉降特性进行系统性实验,以完善基础数据库。为模拟安全壳的复杂热工环境,需要设计高温高压实验装置,这也要求辅助的气溶胶发生装置能够实现在不同背压条件下的长期工作。文献“Aerosolretention in low-subcooling pools under realistic accident conditions”采用了DRAGON气溶胶发生器来产生气溶胶并进行实验,在本实验中通过金属粉末与氧气反应的方式生成了SnO2气溶胶。文献“Development of an aerosol decontamination factorevaluation method using an aerosol spectrometer”采用了干粉式气溶胶发生器来进行实验,利用硫酸钡粉末,活塞推动、旋转叶片刮除并与空气混合的方式俩产生气溶胶。但是上述方式仅适用于不可溶性气溶胶,CsI和CsOH等盐类气溶胶无法像硫酸钡一样通过工业化的方式来形成固体粉末,所以需针对盐类气溶胶设计专用的气溶胶发生器。Due to the different physical properties of the above two aerosols, such as hydrophilicity, hygroscopicity, etc., they can be divided into soluble and insoluble aerosols according to these properties, which also means that the migration and condensation of these two aerosols in the containment There are large differences in the characteristics of aerosols and natural sedimentation, so it is necessary to conduct systematic experiments on the migration and sedimentation characteristics of different aerosols in the containment to improve the basic database. In order to simulate the complex thermal environment of the containment, it is necessary to design a high-temperature and high-pressure experimental device, which also requires the auxiliary aerosol generating device to be able to achieve long-term work under different back pressure conditions. The document "Aerosol retention in low-subcooling pools under realistic accident conditions" used the DRAGON aerosol generator to generate aerosol and conduct experiments. In this experiment, SnO 2 aerosol was generated by the reaction of metal powder and oxygen. The document "Development of an aerosol decontamination factorevaluation method using an aerosol spectrometer" uses a dry powder aerosol generator for experiments, using barium sulfate powder, piston push, rotating blade scraping and mixing with air to generate aerosol. However, the above method is only applicable to insoluble aerosols. Salt aerosols such as CsI and CsOH cannot be industrially formed into solid powders like barium sulfate, so a special aerosol generator needs to be designed for salt aerosols.
专利号200610113301.0提出的一种微纳米级固体氯化钠气溶胶发生方法及其装置,采用溶液雾化及风化的方式来形成固体氯化钠气溶胶,适用于常规实验环境。专利号202120778425.0又提出了一种计数中位径分布可调的固态氯化钠气溶胶发生装置,解决了之前气溶胶发生装置稳定性差的问题,能产生出在一定粒径范围内可调计数中位径的盐类气溶胶。专利号202110682544.0提出的一种纳米级气溶胶发生装置,能够产生雾化液滴,但是缺少风化装置,这要求使用此装置的环境湿度在液滴的风化点以下。专利号202110918345.5提出的一种亚微米级单分散气溶胶发生装置及系统,借助毛细管可以能够产生单分散的盐类气溶胶,有助于气溶胶机理实验的开展。上述发明涉及的装置都是在出口环境为常压的条件下设计的,在背压较高的条件下可能会造成装置漏气或者气溶胶无法配送至目标环境中。Patent No. 200610113301.0 proposes a micronano-scale solid sodium chloride aerosol generating method and its device, which uses solution atomization and weathering to form solid sodium chloride aerosol, which is suitable for conventional experimental environments. Patent No. 202120778425.0 proposes a solid sodium chloride aerosol generating device with adjustable counting median diameter distribution, which solves the problem of poor stability of the previous aerosol generating device and can produce adjustable counting within a certain particle size range. Salt aerosols with a bit diameter. Patent No. 202110682544.0 proposes a nano-scale aerosol generating device that can generate atomized droplets, but lacks a weathering device, which requires the ambient humidity of the device to be below the weathering point of the droplets. Patent No. 202110918345.5 proposes a submicron monodisperse aerosol generating device and system, which can generate monodisperse salt aerosol with the help of capillary, which is helpful for the development of aerosol mechanism experiments. The devices involved in the above inventions are all designed under the condition that the outlet environment is normal pressure. Under the condition of high back pressure, the device may leak or the aerosol cannot be delivered to the target environment.
发明内容Contents of the invention
本发明的目的在于提供一种适用于高背压变化范围的动态调节式盐类气溶胶发生器。The purpose of the present invention is to provide a dynamically adjustable salt aerosol generator suitable for high back pressure variation range.
本发明的目的通过如下技术方案来实现:The purpose of the present invention is achieved through the following technical solutions:
一种适用于高背压变化范围的动态调节式盐类气溶胶发生器,包括液滴混合室、撞击分离室、混合风化室及补液系统;所述撞击分离室的入口与液滴混合室的出口相连,出口与液滴混合室的入口管相连;所述液滴混合室的另一端入口与补液系统相连,补液系统另一端与撞击分离室相连;A dynamically adjustable salt aerosol generator suitable for a high back pressure variation range, including a droplet mixing chamber, an impact separation chamber, a mixing weathering chamber and a liquid replenishment system; the entrance of the impact separation chamber and the droplet mixing chamber The outlet is connected, and the outlet is connected to the inlet pipe of the droplet mixing chamber; the inlet of the other end of the droplet mixing chamber is connected to the liquid replenishment system, and the other end of the liquid replenishment system is connected to the impact separation chamber;
所述液滴混合室包括:高压型雾化器,安装在高压型雾化器上侧的高压引射气管和安装在高压型雾化器下侧的高压补水管,高压引射气管与高压气源相连,高压补水管与补液系统相连;固定在高压型雾化器出口中心轴线的轴向方向上的弧形撞击板,弧形撞击板固定在固定杆上;高压型雾化器外侧连接密封盲板,密封盲板连接密封法兰,密封法兰上安装有贯穿卡套,固定杆依次通过密封盲板的四周开孔、密封法兰四周的贯穿卡套(1.6)到外侧;密封盲板另一侧连接混合容器;The droplet mixing chamber includes: a high-pressure atomizer, a high-pressure ejection pipe installed on the upper side of the high-pressure atomizer, a high-pressure water supply pipe installed on the lower side of the high-pressure atomizer, a high-pressure ejection pipe and a high-pressure air pipe. The high-pressure water replenishment pipe is connected to the liquid replenishment system; the arc-shaped impact plate fixed in the axial direction of the central axis of the outlet of the high-pressure atomizer, and the arc-shaped impact plate is fixed on the fixed rod; the outer connection of the high-pressure atomizer is sealed Blind plate, the sealing blind plate is connected to the sealing flange, the sealing flange is equipped with a through ferrule, and the fixing rod passes through the openings around the sealing blind plate and the penetrating ferrule (1.6) around the sealing flange to the outside in turn; the sealing blind plate The other side is connected to the mixing container;
所述混合风化室包括:混合气腔,安装在混合气腔下方的流化板和上方的压力控制孔板;流化板下部设置气室,侧面安装从高压气源引入的进气管,进气管上安装流量控制器;The mixed weathering chamber includes: a mixed air chamber, a fluidized plate installed below the mixed air chamber, and a pressure control orifice plate above; Install a flow controller on it;
所述补液系统包括:集液箱,与集液箱一侧连接的撞击分离室补液管,与集液箱另一侧依次连接的高压水泵和高压补液箱,高压补液箱再与高压型雾化器相连;高压补液箱侧壁安装液位计和压力传感器,其通过电路与PID控制器相连,提供信号反馈。The liquid replenishment system includes: a liquid collection tank, an impact separation chamber liquid replenishment pipe connected to one side of the liquid collection tank, a high-pressure water pump and a high-pressure liquid replenishment tank sequentially connected to the other side of the liquid collection tank, and the high-pressure liquid replenishment tank is connected with a high-pressure atomizer The liquid level gauge and pressure sensor are installed on the side wall of the high-pressure liquid replenishment tank, which are connected to the PID controller through a circuit to provide signal feedback.
进一步地,所述弧形撞击板的四周斜方45度的位置安装有四个固定长板,各个长板均开孔与固定杆装配,固定杆的最外侧设置有一定长度外螺纹,可利用固定长板两侧螺母来安装固定弧形撞击板,可以调节弧形撞击板的位置;所述贯穿卡套内部采用四氟密封垫圈密封,用于稳定固定杆,调节固定杆及弧形撞击板的位置,防止漏气;所述密封盲板中间开孔用于高压型雾化器的安装,并通过轴向螺栓与密封法兰安装连接,两者间安装有高压型密封胶垫,固定杆通过开孔伸出,借助密封盲板与密封法兰间的配合将固定杆轴向密封,避免在调节固定杆时漏气。Further, four fixed long plates are installed around the arc-shaped impact plate at an oblique angle of 45 degrees, and each long plate has a hole to be assembled with a fixed rod. Fix the nuts on both sides of the long plate to install and fix the arc-shaped impact plate, and the position of the arc-shaped impact plate can be adjusted; the inside of the through ferrule is sealed with a PTFE sealing gasket, which is used to stabilize the fixed rod and adjust the fixed rod and the arc-shaped impact plate position to prevent air leakage; the hole in the middle of the sealing blind plate is used for the installation of the high-pressure atomizer, and is connected to the sealing flange through axial bolts, and a high-pressure sealing pad is installed between the two, and the fixing rod It protrudes through the opening, and the fixing rod is axially sealed by means of the cooperation between the sealing blind plate and the sealing flange, so as to avoid air leakage when adjusting the fixing rod.
进一步地,所述混合容器为双层结构,采用圆柱形及锥形渐缩结构设计,下部设置有集液槽及排液管用于收集及排出经弧形撞击板筛选出的大液滴;混合容器外层设置有环形的干燥气体流道,环形空间内设置有低流动角度的螺旋形导流板,用于引导通过补气管进入的气体;在气体流道最后设置有环形的L型注气孔,L型注气孔的出口与混合容器中心流道侧壁的开辟的锥形导流壁相连。Further, the mixing container is a double-layer structure, designed with a cylindrical and conical tapering structure, and the lower part is provided with a liquid collection tank and a liquid discharge pipe for collecting and discharging the large liquid droplets screened out by the arc-shaped impact plate; mixing The outer layer of the container is provided with an annular dry gas flow channel, and a spiral deflector with a low flow angle is provided in the annular space to guide the gas entering through the gas supply pipe; an annular L-shaped gas injection hole is provided at the end of the gas flow channel , the outlet of the L-shaped gas injection hole is connected with the taper guide wall opened on the side wall of the central flow channel of the mixing vessel.
进一步地,所述撞击分离室内部管路为L型结构,气体流动的迎风面采用平面设计,来流气体中的大尺寸液滴在高速气流的携带下具有较大的惯性,撞击在迎风面上后会被去除,剩余的小尺寸液滴进入混合风化室中,被去除筛选掉的液体可通过下部的补液管进入集液箱中。Further, the internal pipeline of the impact separation chamber is an L-shaped structure, and the windward side of the gas flow adopts a planar design, and the large-sized liquid droplets in the incoming gas have greater inertia under the high-speed airflow, and hit the windward side After being applied, it will be removed, and the remaining small-sized liquid droplets will enter the mixing weathering chamber, and the liquid that is removed and screened can enter the liquid collection tank through the liquid replenishment pipe at the lower part.
进一步地,混合风化室设置有压力、温度及湿度传感器,通过信号反馈利用流量控制器控制补气流量。Furthermore, the mixing weathering chamber is equipped with pressure, temperature and humidity sensors, and the flow controller is used to control the supplementary air flow through signal feedback.
进一步地,所述补液系统设置有PID控制系统,结合高压补液箱的压力传感器提供的信号反馈来控制高压水泵维持补液箱的压力;液位计对高压补液箱液位进行信号反馈,并利用PID控制系统控制高压补液箱及时进行补液;控制高压补液箱的压力以调节补充速度。Further, the liquid replenishment system is equipped with a PID control system, which controls the high-pressure water pump to maintain the pressure of the liquid replenishment tank in combination with the signal feedback provided by the pressure sensor of the high-pressure liquid replenishment tank; the liquid level gauge performs signal feedback on the liquid level of the high-pressure liquid replenishment tank, and uses The control system controls the high-pressure liquid replenishment tank to replenish liquid in time; controls the pressure of the high-pressure liquid replenishment tank to adjust the replenishment speed.
进一步地,所述集液箱采用透明材料,集液箱、高压水泵、高压补液箱之间通过管道连接。Further, the liquid collection tank is made of transparent material, and the liquid collection tank, the high-pressure water pump, and the high-pressure liquid replenishment tank are connected by pipelines.
本发明的有益效果在于:The beneficial effects of the present invention are:
本发明能够在0~1MPa(g)的背压环境下工作,工作压力变化范围较高,最高可在1MPa的背压条件下工作,解决了目前缺乏盐类气溶胶高压配送装置的不足,同时可以根据实验需求来调节配送的气溶胶浓度及粒径分布。The present invention can work under the back pressure environment of 0~1MPa(g), the working pressure variation range is relatively high, and can work under the back pressure condition of 1MPa at the highest, which solves the shortage of the lack of high-pressure dispensing device for salt aerosol at present, and at the same time The distribution of aerosol concentration and particle size distribution can be adjusted according to the experimental requirements.
本发明通过采用湿度、温度及压力测量装置,并辅助以PID控制装置来控制装置内的湿度,可产生风化后的固体盐类气溶胶,在结构设计上减少了雾化液滴在容器内的损失,具有较好的稳定性。The present invention adopts the humidity, temperature and pressure measurement device, and assists the PID control device to control the humidity in the device, can produce the solid salt aerosol after weathering, and reduces the atomized droplet in the container in the structural design. loss, with better stability.
本发明设计有高压及常压工作模式,适用的工作范围较广;能够在不同的背压环境下稳定地产生不同浓度、不同粒径分布的盐类气溶胶,并且可以实现在工作条件下的动态调节,以满足对不同环境下可溶性气溶胶迁移沉降特性的实验研究。The invention is designed with high-pressure and normal-pressure working modes, and is applicable to a wide range of work; it can stably produce salt aerosols with different concentrations and different particle size distributions under different back pressure environments, and can realize the aerosol under working conditions Dynamic adjustment to meet the experimental research on the migration and deposition characteristics of soluble aerosols in different environments.
本发明具有调节气溶胶浓度及气溶胶中值粒径的功能,可根据实验需求进行实时调节。The invention has the function of adjusting the aerosol concentration and the median diameter of the aerosol, which can be adjusted in real time according to experimental requirements.
本发明具有溶液回收的功能,提高溶液的利用率及连续工作时长。The invention has the function of solution recovery, improves the utilization rate of the solution and the continuous working time.
附图说明Description of drawings
图1为本发明适用于高背压变化范围的动态调节式盐类气溶胶发生器的装置结构图;Fig. 1 is the device structural diagram of the dynamically adjustable salt aerosol generator applicable to the high back pressure variation range of the present invention;
图2为本发明适用于高背压变化范围的动态调节式盐类气溶胶发生器的装置主体剖面图;Fig. 2 is the cross-sectional view of the main body of the device of the dynamically adjustable salt aerosol generator applicable to the high back pressure variation range of the present invention;
图3为本发明适用于高背压变化范围的动态调节式盐类气溶胶发生器的弧形撞击板正视图;Fig. 3 is the front view of the curved impact plate of the dynamically adjustable salt aerosol generator suitable for high back pressure variation range of the present invention;
图4为本发明适用于高背压变化范围的动态调节式盐类气溶胶发生器的液滴混合室侧视剖面图;Fig. 4 is the side view sectional view of the liquid drop mixing chamber of the dynamically adjustable salt aerosol generator suitable for high back pressure variation range of the present invention;
图5为本发明适用于高背压变化范围的动态调节式盐类气溶胶发生器的气溶胶粒径分布图。Fig. 5 is an aerosol particle size distribution diagram of the dynamically adjustable salt aerosol generator suitable for a high back pressure variation range according to the present invention.
具体实施方式Detailed ways
下面结合附图对本发明做进一步描述。The present invention will be further described below in conjunction with the accompanying drawings.
根据图1,本发明包括液滴混合室1、撞击分离室2、混合风化室3及补液系统4。液滴混合室1用于产生具有一定尺寸分布的雾化液滴并建立混合气体的动态流动环境;撞击分离室2用于去除混合气体中的大液滴,筛选出小尺寸液滴;混合风化室3用于制造低湿度的液滴风化环境,制造盐类材质的气溶胶颗粒;补液系统4用于储存目标盐溶液,收集在液滴混合室1和撞击分离室2中残余的溶液,并为雾化喷嘴提供溶液。According to FIG. 1 , the present invention includes a droplet mixing chamber 1 , an impact separation chamber 2 , a mixing and weathering chamber 3 and a liquid replenishment system 4 . The droplet mixing chamber 1 is used to generate atomized droplets with a certain size distribution and establish a dynamic flow environment for the mixed gas; the impact separation chamber 2 is used to remove large droplets in the mixed gas and screen out small-sized droplets; mixing and weathering Chamber 3 is used to create a low-humidity droplet weathering environment, and to produce aerosol particles of salt material; the rehydration system 4 is used to store the target salt solution, collect the remaining solution in the droplet mixing chamber 1 and the impact separation chamber 2, and Provide solution to atomizing nozzle.
根据图2,液滴混合室1包括:高压型雾化器1.1、高压引射气管1.2、高压补水管1.3、弧形撞击板1.4、固定杆1.5、贯穿卡套1.6、密封法兰1.7、密封盲板1.8、混合容器1.9、补气管1.10、螺旋式导流板1.11、L型注气孔1.12、锥形导流壁1.13、集液槽1.14及排液管1.15。所述高压型雾化器1.1的上下两侧安装有高压引射气管1.2和高压补水管1.3,分别与高压气源以及补液系统4相连。高压型雾化器1.1设置有外螺纹结构,可与密封盲板1.8中心设置的有内螺纹孔连接,方便拆卸、清理及更换。弧形撞击板1.4采用了圆形截面的设计,如图3所示,在四周斜方45度的位置安装有四个固定长板,各个长板均开孔与固定杆1.5装配,并固定在高压型雾化器1.1出口中心轴线的轴向方向上。固定杆1.5的最外侧设置有一定长度外螺纹,可利用如图2所示的固定长板两侧螺母来安装固定弧形撞击板1.4,可以适当调节弧形撞击板1.4的位置,同时方便拆卸清洗及更换。固定杆1.5依次通过密封盲板1.8的四周开孔、安装在密封法兰1.7四周上的贯穿卡套1.6到外侧,贯穿卡套1.6内部采用四氟密封垫圈来密封,用于稳定固定杆1.5,方便通过拆卸贯穿卡套1.6可以改变固定杆1.5及弧形撞击板1.4的位置,同时防止漏气。密封盲板1.8位于位于混合容器1.9的外侧,中间开孔以方便高压型雾化器1.1的安装,并通过轴向螺栓与密封法兰1.7安装连接,两者间安装有高压型密封胶垫,固定杆1.5通过开孔伸出,借助密封盲板1.8与密封法兰1.7间的配合将固定杆轴向密封,并且避免在调节固定杆1.5时漏气。According to Figure 2, the droplet mixing chamber 1 includes: a high-pressure atomizer 1.1, a high-pressure injection pipe 1.2, a high-pressure water supply pipe 1.3, an arc-shaped impact plate 1.4, a fixed rod 1.5, a through ferrule 1.6, a sealing flange 1.7, a sealing Blind plate 1.8, mixing container 1.9, air supply pipe 1.10, spiral deflector 1.11, L-shaped air injection hole 1.12, conical deflector wall 1.13, liquid collection tank 1.14 and liquid discharge pipe 1.15. The upper and lower sides of the high-pressure atomizer 1.1 are equipped with a high-pressure ejector pipe 1.2 and a high-pressure water replenishment pipe 1.3, which are respectively connected with a high-pressure air source and a liquid replenishment system 4 . The high-pressure atomizer 1.1 is provided with an external thread structure, which can be connected with the internal thread hole provided in the center of the sealing blind plate 1.8, which is convenient for disassembly, cleaning and replacement. The arc-shaped impact plate 1.4 adopts the design of circular section, as shown in Figure 3, four fixed long plates are installed at the position of oblique 45 degrees around, each long plate has a hole and is assembled with the fixed rod 1.5, and is fixed on the High-pressure atomizer 1.1 In the axial direction of the central axis of the outlet. The outermost side of the fixed rod 1.5 is provided with a certain length of external thread, and the nuts on both sides of the fixed long plate as shown in Figure 2 can be used to install and fix the arc-shaped impact plate 1.4, the position of the arc-shaped impact plate 1.4 can be adjusted appropriately, and it is convenient to disassemble Clean and replace. The fixed rod 1.5 sequentially passes through the holes around the sealing blind plate 1.8, and the through ferrule 1.6 installed on the surrounding of the sealing flange 1.7 to the outside, and the inside of the penetrating ferrule 1.6 is sealed with a PTFE sealing gasket to stabilize the fixed rod 1.5. It is convenient to change the positions of the fixed rod 1.5 and the arc impact plate 1.4 by disassembling the through ferrule 1.6, and prevent air leakage at the same time. The sealing blind plate 1.8 is located on the outside of the mixing container 1.9, with a hole in the middle to facilitate the installation of the high-pressure atomizer 1.1, and is connected to the sealing flange 1.7 through axial bolts, and a high-pressure sealing gasket is installed between the two. The fixed rod 1.5 protrudes through the opening, and the fixed rod is axially sealed by the cooperation between the sealing blind plate 1.8 and the sealing flange 1.7, and air leakage is avoided when the fixed rod 1.5 is adjusted.
高压型雾化器1.1利用引射原理,通过高压引射气管1.2引入的高压气体来引射补液系统4中的溶液,并在出口形成随气流高速流动的雾化液滴,通过提高高压引射气管1.2的压力可以维持上下游的压差,使得其在高背压环境下仍能够正常工作。高压补水管1.3能够对高压补液箱4.3中的溶液起到引流的作用。弧形撞击板1.4安装在高压型雾化器1.1出口中心轴线的轴向方向上,雾化液滴随气流撞击弧形撞击板1.4会发生二次破碎,可以起到去除大液滴并且降低液滴尺寸的效果。弧形撞击板1.4安装在固定杆1.5上,可以通过移动固定杆1.5来改变弧形撞击板1.4的位置,配合撞击板采用的弧形结构设计,可以改变液滴接触撞击板时的接触角,进而改变弧形撞击板1.4对液滴的碰撞破碎及筛分效果,进而改变气体内液滴的尺寸分布,弧形的结构设计可以避免对液滴造成太大的滞留效果,从而维持雾化液滴的浓度。The high-pressure atomizer 1.1 utilizes the ejection principle to eject the solution in the liquid replenishment system 4 through the high-pressure gas introduced by the high-pressure ejector trachea 1.2, and forms atomized droplets flowing with the airflow at a high speed at the outlet. The pressure of the trachea 1.2 can maintain the pressure difference between upstream and downstream, so that it can still work normally under high back pressure environment. The high-pressure replenishment pipe 1.3 can drain the solution in the high-pressure replenishment tank 4.3. The arc-shaped impact plate 1.4 is installed in the axial direction of the central axis of the outlet of the high-pressure atomizer 1.1. The atomized liquid droplets hit the arc-shaped impact plate 1.4 with the air flow and will undergo secondary crushing, which can remove large droplets and reduce the liquid The effect of drop size. The arc-shaped impact plate 1.4 is installed on the fixed rod 1.5, and the position of the arc-shaped impact plate 1.4 can be changed by moving the fixed rod 1.5. With the arc structure design adopted by the impact plate, the contact angle when the droplet contacts the impact plate can be changed. Then change the collision breaking and screening effect of the arc-shaped impact plate 1.4 on the droplets, and then change the size distribution of the droplets in the gas. The arc-shaped structural design can avoid too much retention effect on the droplets, so as to maintain the atomized liquid drop concentration.
混合容器1.9采用双层结构设计,其中心流道主要流通气体与液滴的混合物,采用了圆柱形及锥形渐缩结构设计,以减少不规则结构带来的液滴损失,四周的内壁面上设计有四周环绕式的锥形导流壁1.13,其剖面为锥形,混合容器1.9外层设置有环形的干燥气体流道,环形空间内设置有低流动角度的螺旋形导流板,用于引导通过补气管1.10进入的气体,补气管1.10来的气体通过螺旋式导流板1.11改变流动方向,在流道最后设置有环形的L型注气孔1.12,L型注气孔1.12出口与混合容器1.9中心流道侧壁的开辟的锥形导流壁1.13相连,具体如图4所示,气体在径向四周均匀地先后通过呈环形分布的L型注气孔1.12及锥形导流壁1.13进入混合容器1.9内,并与混合容器1.9内壁面呈现一定的角度,利用气流的居中效应,减少雾化液滴在壁面的损失,初步降低气体的湿度,并维持上游压力的稳定,避免气体回流。混合容器1.9下部设置有集液槽1.14及排液管1.15用于收集及排出经弧形撞击板1.4筛选出的大液滴。The mixing container 1.9 adopts a double-layer structure design, and its central flow channel mainly flows through the mixture of gas and liquid droplets. It adopts a cylindrical and tapered tapered structure design to reduce the loss of liquid droplets caused by irregular structures. It is designed with a surrounding conical guide wall 1.13, its section is conical, the outer layer of the mixing container 1.9 is provided with an annular dry gas flow channel, and a spiral guide plate with a low flow angle is provided in the annular space. In order to guide the gas entering through the gas supply pipe 1.10, the gas from the gas supply pipe 1.10 changes the flow direction through the spiral deflector 1.11, and an annular L-shaped gas injection hole 1.12 is arranged at the end of the flow channel, and the outlet of the L-shaped gas injection hole 1.12 is connected to the mixing container 1.9 The conical guide wall 1.13 opened on the side wall of the central flow channel is connected, as shown in Figure 4, the gas enters through the L-shaped gas injection holes 1.12 and the conical guide wall 1.13 in the radial direction evenly and successively. Inside the mixing container 1.9, and present a certain angle with the inner wall of the mixing container 1.9, the centering effect of the air flow is used to reduce the loss of atomized liquid droplets on the wall, initially reduce the humidity of the gas, and maintain the stability of the upstream pressure to avoid gas backflow. The lower part of the mixing container 1.9 is provided with a liquid collection tank 1.14 and a liquid discharge pipe 1.15 for collecting and discharging large liquid droplets screened by the arc-shaped impact plate 1.4.
撞击分离室2的入口管通过法兰与液滴混合室1的出口相连,出口与混合风化室3的入口管相连,内部L型气流空间的拐点迎风面采用平面设计,气体流动的迎风面采用平面设计,来流气体中的大尺寸液滴在高速气流的携带下具有较大的惯性,撞击在迎风面上后会被去除,剩余的小尺寸液滴进入混合风化室3中,被去除筛选掉的液体可通过下部连接的补液管进入集液箱4.1,提高溶液的利用率。上部气体流道及下部补液管流道均向圆形流道均匀过渡,下部补液管与集液箱4.1相连并且安装有排液阀。The inlet pipe of the impact separation chamber 2 is connected to the outlet of the droplet mixing chamber 1 through a flange, and the outlet is connected to the inlet pipe of the mixing weathering chamber 3. The inflection point windward side of the internal L-shaped airflow space adopts a flat design, and the windward surface of the gas flow adopts a Flat design, the large-sized droplets in the incoming gas have greater inertia under the high-speed airflow, and will be removed after hitting the windward surface, and the remaining small-sized droplets will enter the mixing weathering chamber 3 and be removed and screened The lost liquid can enter the liquid collection tank 4.1 through the liquid replenishment pipe connected at the lower part, so as to improve the utilization rate of the solution. Both the upper gas flow channel and the lower liquid replenishment pipe flow channel evenly transition to a circular flow channel, and the lower liquid replenishment pipe is connected with the liquid collection tank 4.1 and is equipped with a liquid discharge valve.
混合风化室3包括混合气腔3.1、流化板3.2、流量控制器3.3及压力控制孔板3.4。混合风化室3整体采用圆柱形设计,下部安装有流化板3.2,流化板3.2采用多孔介质材料以均匀气流。流化板3.2下部设置有气室,其侧面安装有从高压气源引入的进气管,进气管上安装有流量控制器3.3,与混合风化室3的压力、温度及湿度传感器通过PID控制装置相连。压力控制孔板3.4的主体采用了法兰结构设计,四周设计有螺栓孔以方便安装,中间设计有锥形渐变流道,并保证在最小截面处形成节流效果,起到调节阀的效果,此设计可以在减少气溶胶损失的前提下来维持上下游压差及配送流量的稳定。压力控制孔板(3.4)的设置则是为了采用节流的方式,在发生器的内部环境与目标下游环境间形成稳定的压差,此设计可以避免采用常规阀门设计可能造成的气溶胶堵塞现象。从撞击分离室2来的液滴进入混合气腔3.1,到达流化板3.2上方。混合风化室3的补气管先后通过流量控制器3.3及流化板(3.2)进入混合气腔3.1。流化板3.2能够起到均流的效果,使得上升气流均匀流动,减少液滴及气溶胶在容器内壁的损失,提高装置的稳定性。混合风化室3设置有压力、温度及湿度传感器,可根据盐类的风化点进行湿度核算,并通过信号反馈利用流量控制器来控制补气流量,以确保液滴在混合气腔3.1中风化并形成固体盐类气溶胶。可根据实际工作配送流量的需求来设计多个压力控制孔板3.4,可以与工作时从上游高压气源引入的气量调节阀俩配合调节配送总气量。The mixing weathering chamber 3 includes a mixing chamber 3.1, a fluidization plate 3.2, a flow controller 3.3 and a pressure control orifice 3.4. The mixing and weathering chamber 3 adopts a cylindrical design as a whole, and a fluidization plate 3.2 is installed at the lower part, and the fluidization plate 3.2 is made of a porous medium material for uniform airflow. The lower part of the fluidization plate 3.2 is provided with an air chamber, and an air inlet pipe introduced from a high-pressure air source is installed on its side, and a flow controller 3.3 is installed on the air inlet pipe, which is connected with the pressure, temperature and humidity sensors of the mixing weathering chamber 3 through a PID control device . The main body of the pressure control orifice plate 3.4 adopts a flange structure design, and bolt holes are designed around it for easy installation, and a tapered flow channel is designed in the middle to ensure the throttling effect at the smallest cross-section, and play the role of a regulating valve. This design can maintain the stability of upstream and downstream pressure difference and distribution flow under the premise of reducing aerosol loss. The setting of the pressure control orifice (3.4) is to form a stable pressure difference between the internal environment of the generator and the target downstream environment by means of throttling. This design can avoid the aerosol clogging phenomenon that may be caused by the conventional valve design . The liquid droplets from the impact separation chamber 2 enter the gas mixture chamber 3.1 and reach the top of the fluidized plate 3.2. The air supply pipe of the mixing weathering chamber 3 enters the mixing air cavity 3.1 through the flow controller 3.3 and the fluidization plate (3.2) successively. The fluidized plate 3.2 can achieve the effect of equalizing the flow, so that the upward airflow flows evenly, reduces the loss of liquid droplets and aerosols on the inner wall of the container, and improves the stability of the device. The mixing weathering chamber 3 is equipped with pressure, temperature and humidity sensors, which can perform humidity calculation according to the weathering point of the salt, and use the flow controller to control the air supply flow through signal feedback, so as to ensure that the liquid droplets are weathered in the mixed air chamber 3.1 and Forms a solid salt aerosol. A plurality of pressure control orifice plates 3.4 can be designed according to the demand of the actual working distribution flow, and can cooperate with the gas volume regulating valves introduced from the upstream high-pressure gas source during work to adjust the total gas volume of distribution.
补液系统4包括集液箱4.1、高压水泵4.2、高压补液箱4.3及液位计4.4。其中,集液箱4.1采用透明材料设计来观察储存溶液体积,同时与液滴混合室1、撞击分离室2的补液管相连,集液箱4.1、高压水泵4.2、高压补液箱4.3之间利用管道连接,高压补液箱4.3侧壁安装有液位计4.4和压力传感器,其通过电路与PID控制器相连,提供信号反馈,同时PID控制器设置有液位及压力控制模式,用于常压及高压条件下的工作。The liquid replenishment system 4 includes a liquid collection tank 4.1, a high-pressure water pump 4.2, a high-pressure liquid replenishment tank 4.3 and a liquid level gauge 4.4. Among them, the liquid collection tank 4.1 is designed with a transparent material to observe the volume of the storage solution, and is connected to the liquid replenishment pipe of the droplet mixing chamber 1 and the impact separation chamber 2. The liquid collection tank 4.1, the high-pressure water pump 4.2, and the high-pressure liquid replenishment tank 4.3 use pipelines Connection, a liquid level gauge 4.4 and a pressure sensor are installed on the side wall of the high-pressure replenishment tank 4.3, which are connected to the PID controller through a circuit to provide signal feedback. At the same time, the PID controller is equipped with a liquid level and pressure control mode for normal pressure and high pressure work under conditions.
所述集液箱4.1用于储存配置好的盐溶液,并收集从液滴混合室1和撞击分离室2排液管中的溶液,然后利用高压水泵4.2将溶液注入高压补液箱4.3中,并控制高压补液箱4.3的液体压力。设置有PID控制系统,结合高压补液箱4.3的压力传感器提供的信号反馈来控制高压水泵4.2维持补液箱的压力,以确保高压型雾化器1.1的正常工作。液位计4.4同样可以对高压补液箱4.3液位进行信号反馈,并利用PID控制系统控制高压补液箱4.3及时进行补液,此设置可以确保在常压条件下高压补液箱4.3能够为高压型雾化器1.1补充溶液。通过上述的设计可以实现补液系统4在高压及常压模式下的长时间稳定工作。通过控制高压补液箱4.3的压力可以调节溶液的补充速度,改变形成的雾化液滴浓度,进而改变最终产生的气溶胶浓度。The liquid collection tank 4.1 is used to store the configured saline solution, and collect the solution in the liquid discharge pipe from the droplet mixing chamber 1 and the impact separation chamber 2, and then use the high-pressure water pump 4.2 to inject the solution into the high-pressure liquid replenishment tank 4.3, and Control the liquid pressure of the high-pressure liquid supplement tank 4.3. A PID control system is provided, combined with the signal feedback provided by the pressure sensor of the high-pressure liquid replenishment tank 4.3 to control the high-pressure water pump 4.2 to maintain the pressure of the liquid replenishment tank, so as to ensure the normal operation of the high-pressure atomizer 1.1. The liquid level gauge 4.4 can also give signal feedback to the liquid level of the high-pressure liquid replenishment tank 4.3, and use the PID control system to control the high-pressure liquid replenishment tank 4.3 to replenish liquid in time. This setting can ensure that the high-pressure liquid replenishment tank 4.3 can be used for high-pressure atomization under normal pressure conditions 1.1 Supplement solution. Through the above-mentioned design, the long-term stable operation of the liquid replenishment system 4 in the high-pressure and normal-pressure modes can be realized. By controlling the pressure of the high-pressure liquid replenishment tank 4.3, the replenishment speed of the solution can be adjusted, the concentration of the formed atomized droplets can be changed, and then the final concentration of the aerosol produced can be changed.
在实际工作状态时,首先需要根据目标压力及配送流量的需求来选取合适尺寸的压力控制孔板3.4,并往集液箱4.1中添加目标盐溶液。根据目标工作压力来选取补液系统4的PID控制工作模式,并开启高压水泵4.2来补充高压补液箱4.3中的溶液。然后开启液滴混合室1中的补气管1.10阀门,控制气体通过L型注气孔1.12进入液滴混合室1,同时开启流量控制器3.3及管路阀门,维持混合风化室3的补气风化功能,并初步调节发生器的配送流量。最后以此打开高压引射气管1.2和高压补水管1.3上的阀门,液滴混合室1开始工作,液滴先后经过液滴混合室1、撞击分离室2和混合风化室3,最终形成气溶胶进入目标环境。大液滴则通过液滴混合室1和撞击分离室2的排液管进入补液系统4。在实际工作条件下可通过调节高压补液箱4.3的压力和弧形撞击板1.4的位置来控制气溶胶的浓度和尺寸分布。In the actual working state, it is first necessary to select a pressure control orifice plate 3.4 of an appropriate size according to the target pressure and distribution flow requirements, and add the target saline solution to the liquid collection tank 4.1. Select the PID control working mode of the liquid replenishment system 4 according to the target working pressure, and turn on the high-pressure water pump 4.2 to supplement the solution in the high-pressure liquid replenishment tank 4.3. Then open the gas supply pipe 1.10 valve in the droplet mixing chamber 1, control the gas to enter the droplet mixing chamber 1 through the L-shaped gas injection hole 1.12, and open the flow controller 3.3 and the pipeline valve at the same time to maintain the gas supply and weathering function of the mixing weathering chamber 3 , and preliminarily adjust the delivery flow of the generator. Finally, the valves on the high-pressure injection air pipe 1.2 and the high-pressure water supply pipe 1.3 are opened, and the droplet mixing chamber 1 starts to work. The droplets pass through the droplet mixing chamber 1, the impact separation chamber 2 and the mixing weathering chamber 3, and finally form an aerosol into the target environment. The large droplets enter the liquid replenishment system 4 through the droplet mixing chamber 1 and the liquid discharge pipe of the collision separation chamber 2 . Under actual working conditions, the concentration and size distribution of the aerosol can be controlled by adjusting the pressure of the high-pressure replenishment tank 4.3 and the position of the arc-shaped impact plate 1.4.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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| US6877724B1 (en) * | 2003-03-31 | 2005-04-12 | The United States Of America As Represented By The Secretary Of The Navy | Constant concentration delivery device and method for vaporized substances |
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