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CN114903817A - A shampoo and bath bubble containing natural vegetable oil and fat, and its preparation method - Google Patents

A shampoo and bath bubble containing natural vegetable oil and fat, and its preparation method Download PDF

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Publication number
CN114903817A
CN114903817A CN202210500674.2A CN202210500674A CN114903817A CN 114903817 A CN114903817 A CN 114903817A CN 202210500674 A CN202210500674 A CN 202210500674A CN 114903817 A CN114903817 A CN 114903817A
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parts
weight
vegetable oil
shampoo
oil
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CN114903817B (en
Inventor
程恒光
李晓霞
蒋晴
郭春景
蒋云杰
吴凯宾
滑翔
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Hangzhou Qiandaohu Tianxin Co ltd
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Hangzhou Qiandaohu Tianxin Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/06Preparations for care of the skin for countering cellulitis
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The invention relates to the field of washing and care products, and discloses a washing and bathing bubble containing natural vegetable oil and a preparation method thereof, aiming at solving the problems that the addition amount of the vegetable oil in a washing and bathing bubble water aqua product is not high and the safety risk is caused by solubilizing the vegetable oil by using PEG (polyethylene glycol) raw materials in the prior art, wherein the washing and bathing bubble comprises the following components in parts by weight: 40-60 parts of water, 10-30 parts of anionic surfactant, 3-8 parts of polyhydric alcohol, 0.1-3.0 parts of vegetable oil, 3-20 parts of nonionic surfactant, 3-15 parts of amphoteric surfactant, 0.6-3.5 parts of emulsifier, 0.5-1 part of preservative, 0.1-0.2 part of conditioner and 0.4-0.6 part of pH regulator. The shampoo provided by the invention contains more vegetable oil, has good cleaning effect and moisturizing effect, is rich in foam, is transparent and stable in shampoo and bath bubble system, does not precipitate the vegetable oil, and is low in safety risk.

Description

A shampoo and bath bubble containing natural vegetable oil and fat, and its preparation method
Technical Field
The invention relates to the field of washing and caring products, in particular to a shampoo and bath bubble containing natural vegetable oil and fat and a preparation method thereof.
Background
The grease can play a role in moistening skin, establishing barrier protection and cleaning skin in the washing and caring product. The oil comprises mineral oil and animal and vegetable oil, wherein the mineral oil is a liquid hydrocarbon mixture extracted from petroleum, has a good water locking effect, but is easy to block pores, so that the consumption intention of consumers on products containing the mineral oil is limited; the extraction cost of the animal fat is higher, and the animal fat is less used in washing and caring products; the vegetable oil has rich sources and the structure is close to that of the sebum of a human body, so that the vegetable oil has good compatibility with the skin, is easy to be absorbed by the skin, can inhibit water evaporation, has relatively moist skin feel and can soften the skin. Although vegetable oil has the advantages of good safety, good affinity and the like, at present, the vegetable oil is mainly applied to products in cream emulsion and condensation formulations and is rarely applied to products in shampoo and bath bubble type because the mutual dissolving effect of the vegetable oil and water in the shampoo and bath bubble products is poor. In the shampoo and bath bubble type products added with vegetable oil, in order to make the system clear, transparent and stable, the vegetable oil is generally solubilized by adopting PEG-containing raw materials. Even if the mode is used, the addition amount of the vegetable oil in the product is still small, the skin moistening effect cannot be achieved, meanwhile, the PEG raw material can generate impurities such as 1, 4-dioxane, ethylene glycol, ethylene oxide, diethylene glycol and the like as byproducts in the production process, the impurities belong to carcinogens, skin can be irritated, skin allergy is caused, and the safety risk of the product is increased.
For example, in the Chinese patent literature, "a shampoo" is disclosed, with the publication number of CN105534744A, the shampoo is made from the following components by weight percentage: 6-10% of sodium dodecyl sulfate, 5-7% of disodium lauroamphodipropionate, 0.3-0.6% of sandalwood oil, 1-5% of emulsified silicone oil, 0.5-2.0% of ammonium xylene sulfonate, 2-8% of polyethylene glycol ester, 0.3-1% of citric acid and the balance of water. The shampoo uses sandalwood oil to improve the using effect of the shampoo, the addition amount of the sandalwood oil is small, meanwhile, the formula also uses polyethylene glycol to improve the mixing effect of the vegetable oil and other base materials, and the polyethylene glycol brings certain safety risk for PEG materials.
Disclosure of Invention
In order to solve the problems that the addition amount of vegetable oil and fat in shampoo and bath bubble water aqua products in the prior art is not high and the safety risk is caused by solubilizing the vegetable oil and fat by using PEG raw materials, the invention provides the shampoo and bath bubble containing the natural vegetable oil and fat. The invention also provides a preparation method of the shampoo and bath bubble containing the natural vegetable oil, the preparation method has simple steps, and the prepared shampoo and bath bubble system is clear and stable.
In order to achieve the purpose, the invention adopts the following technical scheme:
a shampoo and bath bubble containing natural vegetable oil comprises the following components in parts by weight: 40-60 parts of water, 10-30 parts of anionic surfactant, 3-8 parts of polyhydric alcohol, 0.1-3.0 parts of vegetable oil, 3-20 parts of nonionic surfactant, 3-15 parts of amphoteric surfactant, 0.6-3.5 parts of emulsifier, 0.5-1 part of preservative, 0.1-0.2 part of conditioner and 0.4-0.6 part of pH regulator.
The shampoo and bath bubble consists of a phase A, a phase B and a phase C, wherein the phase A comprises water, an anionic surfactant and polyhydric alcohol, the phase B comprises vegetable oil, a nonionic surfactant, an amphoteric surfactant and an emulsifier, and the phase C comprises a preservative, a conditioner and a pH regulator. In the phase B, the mutual solubility effect of the vegetable oil and the water is improved by the matching use of the nonionic surfactant, the amphoteric surfactant and the emulsifier, and the nonionic surfactant and the amphoteric surfactant not only have the function of solubilizing the vegetable oil, but also are compounded with the anionic surfactant in the phase A, so that the foaming effect is improved.
Preferably, the anionic surfactant is one or more of sodium lauroyl glutamate, potassium cocoyl hydrolyzed oat protein and lauryl hydroxy sulfobetaine.
Sodium lauroyl glutamate, potassium cocoyl hydrolyzed oat protein, and lauryl hydroxy sulfobetaine have little irritation to skin, and are not prone to cause allergy.
Preferably, the polyalcohol is one or more of glycerol and butanediol.
Preferably, the vegetable oil is one or more of camellia oil, sunflower oil, linseed oil, jojoba oil and meadowfoam seed oil.
The camellia oil, the sunflower seed oil, the linseed oil, the jojoba oil and the meadowfoam seed oil have good moisturizing effects, and meanwhile, the vegetable oil contains different components, so that the vegetable oil respectively has the functions of antibiosis, antivirus, antioxidation, restoration and the like, and the added vegetable oil can be selected according to the product needs.
Preferably, the nonionic surfactant is one or more of lauryl glucoside, coco glucoside and cetearyl glucoside.
Preferably, the amphoteric surfactant is a betaine-type amphoteric surfactant.
Preferably, the emulsifier is a combination of emulsifiers having an HLB value within a range of 3.0 to 4.0 and an HLB value within a range of 9.0 to 10.0.
The emulsifier with the HLB value of 3.0-4.0 and the HLB value of 9.0-10.0 is used in a matching way to be used as an intermediate between vegetable oil and water, so that the solubility of the vegetable oil in a water-based system is improved.
Preferably, the emulsifier is a combination of polyglyceryl-6 stearate and glyceryl stearate.
The HLB value of polyglycerin-6 stearate is 9.5, the HLB value of glyceryl stearate is 3.5, and it is preferable that the polyglycerin-6 stearate is 0.4 to 2.0 parts by weight and the glyceryl stearate is 0.2 to 1.5 parts by weight.
Preferably, the preservative is one or more of potassium sorbate, sodium benzoate, phenoxyethanol and ethylhexyl glycerin.
Preferably, the conditioning agent is polyquaternium-10, and the pH regulator is one of citric acid, lactic acid and glycolic acid.
A method for preparing shampoo and bath bubbles containing natural vegetable oil comprises the following steps:
a) mixing water, anionic surfactant and polyalcohol, and heating to 70-75 deg.C to obtain phase A;
b) mixing vegetable oil and emulsifier, and heating to 70-75 deg.C;
c) mixing nonionic surfactant and amphoteric surfactant, and heating to 70-75 deg.C;
d) adding the mixture obtained in the step B) into the mixture obtained in the step c), and mixing for 10min to obtain a phase B;
e) adding phase B into phase A, stirring at 70-75 deg.C for 10min, cooling, and adding antiseptic, conditioner and pH regulator.
In the preparation process, all the phase components are mixed in batches and then all the phases are mixed, and in the mixing process of the phase B, the vegetable oil and the emulsifier are mixed and then are mixed with the nonionic surfactant and the amphoteric surfactant, so that the separation of the vegetable oil and the fat can be avoided, and the stability of the whole system is improved.
Therefore, the invention has the following beneficial effects: (1) the shampoo and bath bubbles contain more vegetable oil, have good cleaning effect and moisturizing effect, are transparent and stable, and do not precipitate the vegetable oil; (2) the formula is mild, the irritation to skin is small, PEG raw materials are not used, and the safety risk is small; (3) convenient to use, can be foamed after being pressed, and has abundant foam.
Detailed Description
The invention is further described below with reference to specific embodiments.
Example 1
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 58.3 parts by weight of water into a main pot, and heating to 75 ℃ to obtain a phase A;
b) adding 1 weight part of camellia oil, 0.5 weight part of polyglycerol-6 stearate and 0.3 weight part of glycerol stearate into barrel A, and heating to 75 ℃;
c) adding 10 parts by weight lauryl glucoside and 8 parts by weight cocamidopropyl betaine to barrel B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Example 2
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 13 parts by weight of potassium cocoyl hydrolyzed oat protein, 3 parts by weight of butanediol and 43 parts by weight of water into a main pot, and heating to 75 ℃ to obtain a phase A;
b) adding 3.0 parts by weight of camellia oil, 1.7 parts by weight of polyglycerol-6 stearate and 1.3 parts by weight of glycerol stearate into barrel A, and heating to 75 ℃;
c) adding 20 parts by weight lauryl glucoside and 13 parts by weight cocamidopropyl betaine to bucket B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Example 3
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of potassium cocoyl hydrolyzed oat protein, 3 parts by weight of butanediol and 50 parts by weight of water into a main pot, and heating to 75 ℃ to obtain a phase A;
b) adding 2.5 parts by weight of linseed oil, 1.3 parts by weight of polyglycerol-6 stearate and 0.9 parts by weight of glycerol stearate to barrel A, and heating to 75 ℃;
c) adding 16 parts by weight lauryl glucoside and 9 parts by weight cocamidopropyl betaine to barrel B and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 part by weight of polyquaternium-10, 0.9 part by weight of phenoxyethanol and 0.1 part by weight of ethylhexyl glycerol, stirring to clarify, cooling to 55 ℃, adding 0.6 part by weight of inulin, stirring to clarify, adding 0.6 part by weight of citric acid, and adjusting the pH to about 6.0.
Example 4
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 10 parts by weight of lauryl hydroxy sulfobetaine, 5 parts by weight of potassium cocoyl hydrolyzed oat protein, 5 parts by weight of butanediol and 58.35 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 0.8 weight part of high oleic sunflower oil, 0.6 weight part of polyglycerol-6 stearate and 0.2 weight part of glycerol stearate into a barrel A, and heating to 75 ℃;
c) adding 8 parts by weight lauryl glucoside and 5 parts by weight cocamidopropyl betaine to barrel B, heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding the phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 part by weight of polyquaternium-10, 0.9 part by weight of phenoxyethanol and 0.1 part by weight of ethylhexyl glycerol, stirring to clarify, cooling to 55 ℃, adding 0.6 part by weight of inulin, stirring to clarify, adding 0.55 part by weight of citric acid, and adjusting the pH value to about 6.0.
Example 5
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 44 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 2 parts by weight of jojoba oil, 1 part by weight of polyoxyethylene lauryl ether and 0.6 part by weight of sorbitan sesquioleate into a barrel A, and heating to 75 ℃;
c) adding 15 parts by weight lauryl glucoside and 10 parts by weight cocamidopropyl betaine to barrel B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Comparative example 1
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 58.3 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 1 weight part of camellia oil and 0.8 weight part of glycerol stearate into a barrel A, and heating to 75 ℃;
c) adding 10 parts by weight lauryl glucoside and 8 parts by weight cocamidopropyl betaine to barrel B, heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 part by weight of polyquaternium-10, 0.3 part by weight of potassium sorbate and 0.4 part by weight of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 part by weight of inulin, stirring to clarify, adding 0.6 part by weight of citric acid, and adjusting the pH to about 6.0.
Comparative example 2
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 58.3 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 1 weight part of camellia oil, 0.5 weight part of ethylene glycol stearate and 0.3 weight part of polyoxyethylene sorbitol lanolin derivative into barrel A, and heating to 75 deg.C;
c) adding 10 parts by weight lauryl glucoside and 8 parts by weight cocamidopropyl betaine to barrel B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Comparative example 3
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 58.3 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 1 weight part of camellia oil, 0.5 weight part of polyglycerol-6 stearate and 0.3 weight part of glycerol stearate into barrel A, and heating to 75 ℃;
c) adding 18 parts by weight of cocamidopropyl betaine into a barrel B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Comparative example 4
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 13 parts by weight of potassium cocoyl hydrolyzed oat protein, 3 parts by weight of butanediol and 43 parts by weight of water into a main pot, and heating to 75 ℃ to obtain a phase A;
b) heating 3 parts by weight of camellia oil, 20 parts by weight of lauryl glucoside, 13 parts by weight of cocamidopropyl betaine, 1.7 parts by weight of polyglycerol-6 stearate and 1.3 parts by weight of glycerol stearate to 75 ℃ to obtain a phase B;
c) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Comparative example 5
A shampoo and bath bubble containing natural vegetable oil is prepared by the following steps:
a) adding 15 parts by weight of sodium lauroyl glutamate, 5 parts by weight of glycerol and 58.3 parts by weight of water into a main boiler, and heating to 75 ℃ to obtain a phase A;
b) adding 1 weight part of camellia oil and 1 weight part of polyethylene glycol into the barrel A, and heating to 75 ℃;
c) adding 10 parts by weight lauryl glucoside and 8 parts by weight cocamidopropyl betaine to barrel B, and heating to 75 ℃;
d) mixing barrel A and B, homogenizing for 5min to obtain phase B;
e) adding phase B into a main pot, stirring for 10min, cooling to 65 ℃, adding 0.1 weight part of polyquaternium-10, 0.3 weight part of potassium sorbate and 0.4 weight part of sodium benzoate, stirring to clarify, cooling to 55 ℃, adding 0.6 weight part of inulin, stirring to clarify, adding 0.6 weight part of citric acid, and adjusting the pH value to about 6.0.
Sensory and physicochemical indexes of the shampoo and bath bubbles obtained in the above examples and comparative examples were measured, wherein the detection standard of the physicochemical index was GB/T29679, and the obtained data are shown in the following table.
Figure BDA0003634196350000071
The shampoo and bath bubble system is transparent and stable, is not layered when placed at high temperature or low temperature, and has abundant foam.
In comparative example 1, where only one emulsifier was used, the emulsifiers used in comparative example 2 had HLB values of 2.7 and 13.0, respectively, and both of the shampoo and bath bubble systems were cloudy and opaque, whereas in comparative example 3, where no nonionic surfactant was used, the bubbles appeared to delaminate after standing at high or low temperatures, indicating that the combination of nonionic surfactant, amphoteric surfactant, and emulsifier improved the stability of the shampoo and bath bubble system.
Comparative example 4 in the mixing operation of phase B, vegetable oil was directly mixed with the remaining components, which resulted in the precipitation of vegetable oil, which in turn resulted in the clouding of shampoo and bath bubbles.
In comparative example 5, polyethylene glycol was used to solubilize the vegetable oil and fat, and the polyethylene glycol was less effective in solubilizing the vegetable oil and fat than in example 1.

Claims (10)

1. A shampoo and bath bubble containing natural vegetable oil is characterized by comprising the following components in parts by weight: 40-60 parts of water, 10-30 parts of anionic surfactant, 3-8 parts of polyalcohol, 0.1-3.0 parts of vegetable fat, 3-20 parts of nonionic surfactant, 3-15 parts of amphoteric surfactant, 0.6-3.5 parts of emulsifier, 0.5-1 part of preservative, 0.1-0.2 part of conditioner and 0.4-0.6 part of pH regulator.
2. The hair washing and bathing bubble containing natural vegetable fat and oil as claimed in claim 1, wherein said anionic surfactant is one or more of sodium lauroyl glutamate, potassium cocoyl hydrolyzed oat protein, and lauryl hydroxysultaine.
3. The hair and body wash bubble of claim 1, wherein said polyol is one or more of glycerin and butylene glycol.
4. The shampoo and bath bubble as claimed in claim 1, wherein the vegetable oil is one or more of camellia oil, sunflower oil, linseed oil, jojoba oil and meadowfoam oil.
5. The shampoo bath bubble containing natural vegetable fats and oils of claim 1, wherein said nonionic surfactant is one or more of lauryl glucoside, coco glucoside, and cetearyl glucoside.
6. The hair and bath bubbles containing natural vegetable fats and oils of claim 1, wherein said amphoteric surfactant is a betaine-type amphoteric surfactant.
7. The shampoo shower bubble containing natural vegetable fats and oils as claimed in claim 1, 5 or 6, wherein said emulsifier is a combination of emulsifiers having HLB value ranging from 3.0 to 4.0 and HLB value ranging from 9.0 to 10.0.
8. The shampoo and bath foam as claimed in claim 1, wherein the antiseptic is one or more of potassium sorbate, sodium benzoate, phenoxyethanol and ethylhexylglycerin.
9. The hair wash and bath bubble with natural vegetable oils and fats as claimed in claim 1, wherein said conditioner is polyquaternium-10 and said pH adjusting agent is one of citric acid, lactic acid and glycolic acid.
10. A method of producing the shampoo shower bubble containing natural vegetable fats and oils of any one of claims 1 to 9, comprising the steps of:
a) mixing water, anionic surfactant and polyalcohol, and heating to 70-75 deg.C to obtain phase A;
b) mixing vegetable oil and emulsifier, and heating to 70-75 deg.C;
c) mixing nonionic surfactant and amphoteric surfactant, and heating to 70-75 deg.C;
d) adding the mixture obtained in the step B) into the mixture obtained in the step c), and mixing for 10min to obtain a phase B;
e) adding phase B into phase A, stirring at 70-75 deg.C for 10min, cooling, and adding antiseptic, conditioner and pH regulator.
CN202210500674.2A 2022-05-09 2022-05-09 A shampoo bath foam containing natural vegetable oil and its preparation method Active CN114903817B (en)

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