CN114145310A - Herbicide composition containing glufosinate-ammonium - Google Patents
Herbicide composition containing glufosinate-ammonium Download PDFInfo
- Publication number
- CN114145310A CN114145310A CN202111621695.1A CN202111621695A CN114145310A CN 114145310 A CN114145310 A CN 114145310A CN 202111621695 A CN202111621695 A CN 202111621695A CN 114145310 A CN114145310 A CN 114145310A
- Authority
- CN
- China
- Prior art keywords
- glufosinate
- ammonium
- herbicide composition
- flumioxazin
- haloxyfop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000004009 herbicide Substances 0.000 title claims abstract description 38
- 241000196324 Embryophyta Species 0.000 claims abstract description 32
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 claims abstract description 18
- MFSWTRQUCLNFOM-SECBINFHSA-N haloxyfop-P-methyl Chemical group C1=CC(O[C@H](C)C(=O)OC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MFSWTRQUCLNFOM-SECBINFHSA-N 0.000 claims abstract description 15
- 238000009333 weeding Methods 0.000 claims abstract description 12
- 239000000575 pesticide Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract 2
- 239000000839 emulsion Substances 0.000 claims description 9
- 239000005561 Glufosinate Substances 0.000 claims description 5
- 239000002552 dosage form Substances 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 239000004563 wettable powder Substances 0.000 claims description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 12
- 239000003814 drug Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 108020001991 Protoporphyrinogen Oxidase Proteins 0.000 description 2
- 102000005135 Protoporphyrinogen oxidase Human genes 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MFSWTRQUCLNFOM-UHFFFAOYSA-N methyl 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MFSWTRQUCLNFOM-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XOGODJOZAUTXDH-UHFFFAOYSA-M (N-methylanilino)methanesulfonate Chemical compound CN(CS([O-])(=O)=O)c1ccccc1 XOGODJOZAUTXDH-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000005602 Propyzamide Substances 0.000 description 1
- -1 alkylbenzene sulfonate Chemical class 0.000 description 1
- QKZIVVMOMKTVIK-UHFFFAOYSA-M anilinomethanesulfonate Chemical compound [O-]S(=O)(=O)CNC1=CC=CC=C1 QKZIVVMOMKTVIK-UHFFFAOYSA-M 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 229940127089 cytotoxic agent Drugs 0.000 description 1
- 239000002254 cytotoxic agent Substances 0.000 description 1
- 231100000599 cytotoxic agent Toxicity 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 102000005396 glutamine synthetase Human genes 0.000 description 1
- 108020002326 glutamine synthetase Proteins 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 230000001338 necrotic effect Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 231100000434 photosensitization Toxicity 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- PHNUZKMIPFFYSO-UHFFFAOYSA-N propyzamide Chemical compound C#CC(C)(C)NC(=O)C1=CC(Cl)=CC(Cl)=C1 PHNUZKMIPFFYSO-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the technical field of herbicides, and discloses a herbicide composition containing glufosinate-ammonium, which comprises effective components and pesticide auxiliary agents; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl; the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 10-15: 0.5-2: 1.5 to 4. The herbicide composition provided by the invention jointly uses glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl, has a synergistic effect, can effectively remove gramineous weeds and broadleaf weeds, is wide in weeding spectrum, long in lasting period and small in application amount, and reduces the pollution to the environment.
Description
Technical Field
The invention relates to the technical field of herbicides, and discloses a herbicide composition containing glufosinate-ammonium.
Background
The herbicide is a pesticide for preventing and killing or controlling the growth or harm of weeds, and the use of the herbicide for weeding is the most economic and effective means in preventing and killing weeds in farmlands.
The chemical formula of the refined glufosinate-ammonium is C5H12NO4P has the function of inhibiting the activity of glutamine synthetase, and can accumulate the ammonium ion as cytotoxic agent in plant body while inhibiting photosynthesis seriously to reach the aim of weeding. The refined glufosinate-ammonium is mainly contact-killing and weeding, can not be transferred to other places, is safe to succeeding crops, and is safe to annual and perennial dicotyledonous and gramineous weedsThe grass has better weeding effect. The refined glufosinate-ammonium has good water solubility and stable structure, and is convenient to process and mix for use. However, the long-term use of a large amount of the same herbicide can cause the drug resistance of weeds, and the weeding efficiency of the herbicide is reduced. In this case, the amount of the herbicide used is increased to achieve the desired herbicidal effect, and further environmental pollution is increased. Therefore, a new herbicide composition is needed to solve the above technical problems.
Disclosure of Invention
The invention aims to overcome the defects and provide a herbicide composition containing glufosinate-ammonium.
In order to achieve the purpose, the invention is implemented according to the following technical scheme:
the herbicide composition containing the glufosinate-ammonium comprises effective components and pesticide auxiliaries; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl; the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 10-15: 0.5-2: 1.5 to 4.
Preferably, the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 13: 1.5: 2.5.
preferably, the effective component accounts for 10-60 wt% of the herbicide composition.
Preferably, the dosage form of the weeding composition is one of wettable powder, water dispersible granules, aqueous emulsion and microemulsion.
Preferably, the herbicide composition containing the glufosinate-ammonium is used for preventing and controlling grassy weeds and broad-leaved weeds.
Preferably, the pesticide adjuvant is at least one of a dispersant, an emulsifier, a solvent, a carrier, a filler, a stabilizer, a synergist, a wetting agent, a penetrating agent, a sticking agent, a defoaming agent, an antifreezing agent and a solvent.
The specific type of pesticide adjuvant used in the present invention can be selected by those skilled in the art according to the requirements of the actual dosage form.
The invention has the following function principle:
propyzamide can inhibit protoporphyrinogen oxidase (PPO), which is an important enzyme in plant chlorophyll synthesis, and causes irreversible damage to cell membrane function and structure due to photosensitization and peroxidation of cell membrane lipid, sensitive weed stem and leaf necrosis after stem and leaf treatment, and death after sunlight irradiation; the buds of sensitive weeds are necrotic after soil treatment and die after a short period of sunlight exposure. Can be used for preventing and treating annual broadleaf weeds and part of gramineous weeds.
After the high-efficiency haloxyfop-methyl is applied, the haloxyfop-methyl can be quickly absorbed by leaves of gramineous weeds and is conducted to the whole plant, and the growth of plant meristems is inhibited, so that the weeds are killed. The herbicide composition has long lasting period and good control effect on annual and perennial grassy weeds from the seedling stage to the tillering stage and the heading stage. Is highly safe to various broad-leaved crops under normal use conditions. The excellent weeding effect can be still shown under the conditions of low temperature and drought.
Compared with the prior art, the invention has the beneficial effects that:
the herbicide composition provided by the invention jointly uses glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl, has a synergistic effect, can effectively remove gramineous weeds and broadleaf weeds, is wide in weeding spectrum, long in lasting period and small in application amount, and reduces the pollution to the environment.
Detailed Description
The present invention will be further described with reference to specific examples, which are illustrative of the invention and are not to be construed as limiting the invention.
Example 1
The herbicide composition containing the glufosinate-ammonium comprises effective components and pesticide auxiliaries; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl, and the mass ratio of the glufosinate-ammonium to the flumioxazin is 13: 1.5: 2.5. the effective component accounts for 20 wt% of the herbicide composition.
The water emulsion type herbicide composition containing the glufosinate-ammonium comprises the following components in percentage by mass: 20% of active ingredients, 10% of cyclohexanone, 6% of alkylbenzene sulfonate, 4% of urea, 2% of polyvinyl alcohol stabilizer and the balance of deionized water.
The herbicide composition containing the glufosinate-ammonium is used for preventing and controlling grassy weeds and broad-leaved weeds.
Example 2
The herbicide composition containing the glufosinate-ammonium comprises effective components and pesticide auxiliaries; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl, and the mass ratio of the glufosinate-ammonium to the flumioxazin is 15: 2: 1.5. the effective component accounts for 15 wt% of the herbicide composition.
The water emulsion type herbicide composition containing the glufosinate-ammonium comprises the following components in percentage by mass: 15% of active ingredients, 8% of cyclohexanone, 5% of alkylbenzene sulfonate, 3% of urea, 2% of polyvinyl alcohol stabilizer and the balance of deionized water.
The herbicide composition containing the glufosinate-ammonium is used for preventing and controlling grassy weeds and broad-leaved weeds.
Example 3
The herbicide composition containing the glufosinate-ammonium comprises effective components and pesticide auxiliaries; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl, and the mass ratio of the glufosinate-ammonium to the flumioxazin is 10: 0.5: 1.5. the effective component accounts for 55 wt% of the herbicide composition.
The water emulsion type herbicide composition containing the glufosinate-ammonium comprises the following components in percentage by mass: 55% of active ingredients, 13% of cyclohexanone, 8% of alkylbenzene sulfonate, 6% of urea, 2% of polyvinyl alcohol stabilizer and the balance of deionized water.
The herbicide composition containing the glufosinate-ammonium is used for preventing and controlling grassy weeds and broad-leaved weeds.
Test of
Test site: orchard garden
Test agents:
composition a: in the 20 wt% aqueous emulsion type herbicide composition containing glufosinate-ammonium, the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 13: 1.5: 2.5;
and (b) a medicament b: 20 wt% of an essential glufosinate solution;
and (c) a medicament c: 20 wt% flumioxazin suspension;
a drug d: 20 wt% haloxyfop-R-methyl water emulsion;
clear water blank control.
The experiment was performed in 5 treatments, 4 replicates, 20 treatment cells each having an area of 20 square meters, and randomly arranged in blocks.
The composition a, the medicament b, the medicament c and the medicament d are diluted by water, uniformly stirred and uniformly sprayed. The amounts of the composition a, the drug b, the drug c and the drug d used are calculated based on the weight of the drugs themselves.
Weather conditions on the test day: clear, no wind, temperature 20 ℃.
(2) Test purposes and methods:
the weeding effect is as follows: 4 points are randomly selected from each plot, 1/4 square meters are investigated at each point, investigation is carried out once in 20 days and 30 days after the application of the herbicide, the species and the number of the weeds are respectively recorded, and the control effect percentage is calculated.
(3) And (3) test results:
the weeding effect is as follows: see tables 1 and 2.
TABLE 1 weed control Effect after 20 days after application
TABLE 2 weed control Effect after 30 days after application
As can be seen from tables 1 and 2, the 20 wt% aqueous emulsion type herbicidal composition containing glufosinate-ammonium according to the present invention has a significant effect of controlling various weeds observed after 20 days of application; and the control effect of the other three test agents is obviously lower than that of the invention. The observation of 30 days after the application shows that the 20 wt% aqueous emulsion type herbicide composition containing the glufosinate-ammonium has a remarkable effect on preventing and removing various weeds.
The technical solution of the present invention is not limited to the limitations of the above specific embodiments, and all technical modifications made according to the technical solution of the present invention fall within the protection scope of the present invention.
Claims (5)
1. A herbicide composition containing glufosinate-ammonium, which is characterized in that: the herbicide composition containing glufosinate-ammonium comprises an effective component and a pesticide auxiliary agent; the effective components comprise glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl; the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 10-15: 0.5-2: 1.5 to 4.
2. An essential glufosinate-containing herbicidal composition according to claim 1, characterized in that: the mass ratio of glufosinate-ammonium, flumioxazin and haloxyfop-R-methyl is 13: 1.5: 2.5.
3. an essential glufosinate-containing herbicidal composition according to claim 1, characterized in that: the effective component accounts for 10-60 wt% of the herbicide composition.
4. An essential glufosinate-containing herbicidal composition according to claim 1, characterized in that: the dosage form of the weeding composition is one of wettable powder, water dispersible granules, aqueous emulsion and microemulsion.
5. An essential glufosinate-containing herbicidal composition according to any one of claims 1 to 4, characterized in that: the herbicide composition containing the glufosinate-ammonium is used for preventing and controlling grassy weeds and broad-leaved weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111621695.1A CN114145310A (en) | 2021-12-28 | 2021-12-28 | Herbicide composition containing glufosinate-ammonium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111621695.1A CN114145310A (en) | 2021-12-28 | 2021-12-28 | Herbicide composition containing glufosinate-ammonium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114145310A true CN114145310A (en) | 2022-03-08 |
Family
ID=80452311
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111621695.1A Pending CN114145310A (en) | 2021-12-28 | 2021-12-28 | Herbicide composition containing glufosinate-ammonium |
Country Status (1)
| Country | Link |
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| CN (1) | CN114145310A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115152786A (en) * | 2022-07-01 | 2022-10-11 | 江苏七洲绿色化工股份有限公司 | Herbicide composition and application thereof |
| CN117397689A (en) * | 2023-10-18 | 2024-01-16 | 吉林省农业科学院(中国农业科技东北创新中心) | Ternary compound herbicide and preparation method and application thereof |
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| CN105557748A (en) * | 2015-12-30 | 2016-05-11 | 北京明德立达农业科技有限公司 | Weedicide composition and application thereof |
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| CN112715571A (en) * | 2021-01-06 | 2021-04-30 | 合肥尚邦植保科技有限公司 | Ternary weeding composition and application thereof |
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2021
- 2021-12-28 CN CN202111621695.1A patent/CN114145310A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115152786A (en) * | 2022-07-01 | 2022-10-11 | 江苏七洲绿色化工股份有限公司 | Herbicide composition and application thereof |
| CN117397689A (en) * | 2023-10-18 | 2024-01-16 | 吉林省农业科学院(中国农业科技东北创新中心) | Ternary compound herbicide and preparation method and application thereof |
| CN117397689B (en) * | 2023-10-18 | 2025-09-23 | 吉林省农业科学院(中国农业科技东北创新中心) | A ternary compound herbicide and its preparation method and application |
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