CN103937326A - Ceramic ink-jet printing ink and its use methods - Google Patents
Ceramic ink-jet printing ink and its use methods Download PDFInfo
- Publication number
- CN103937326A CN103937326A CN201410094020.XA CN201410094020A CN103937326A CN 103937326 A CN103937326 A CN 103937326A CN 201410094020 A CN201410094020 A CN 201410094020A CN 103937326 A CN103937326 A CN 103937326A
- Authority
- CN
- China
- Prior art keywords
- ceramic
- ink
- agent
- polyurethane resin
- flux
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 205
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000007641 inkjet printing Methods 0.000 title abstract description 24
- 239000000049 pigment Substances 0.000 claims abstract description 38
- 238000007639 printing Methods 0.000 claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 12
- 238000005516 engineering process Methods 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000000976 ink Substances 0.000 claims description 218
- 239000003795 chemical substances by application Substances 0.000 claims description 54
- 230000004907 flux Effects 0.000 claims description 42
- 229920005749 polyurethane resin Polymers 0.000 claims description 38
- 239000003086 colorant Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 22
- 239000012466 permeate Substances 0.000 claims description 19
- 239000000080 wetting agent Substances 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 18
- 239000013543 active substance Substances 0.000 claims description 15
- 239000000975 dye Substances 0.000 claims description 15
- 230000003750 conditioning effect Effects 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 13
- 239000004925 Acrylic resin Substances 0.000 claims description 12
- 229920000178 Acrylic resin Polymers 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 230000000855 fungicidal effect Effects 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 239000003755 preservative agent Substances 0.000 claims description 6
- 230000002335 preservative effect Effects 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 238000005374 membrane filtration Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010023 transfer printing Methods 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- WQOWVZHCDBGDRU-UHFFFAOYSA-J ethyl carbamate prop-2-enoate silicon(4+) Chemical compound C(C=C)(=O)[O-].NC(=O)OCC.[Si+4].C(C=C)(=O)[O-].C(C=C)(=O)[O-].C(C=C)(=O)[O-] WQOWVZHCDBGDRU-UHFFFAOYSA-J 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- VUUAEBBAUMJPRE-UHFFFAOYSA-N ethyl n-fluorocarbamate Chemical compound CCOC(=O)NF VUUAEBBAUMJPRE-UHFFFAOYSA-N 0.000 claims 1
- 238000010187 selection method Methods 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 28
- -1 alkylbenzene ketone Chemical class 0.000 description 15
- 239000000463 material Substances 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000004075 alteration Effects 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 235000011194 food seasoning agent Nutrition 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical class C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010428 oil painting Methods 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000006748 scratching Methods 0.000 description 2
- 230000002393 scratching effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- DWHJJLTXBKSHJG-HWKANZROSA-N (e)-5-hydroxy-2-methylpent-2-enoic acid Chemical group OC(=O)C(/C)=C/CCO DWHJJLTXBKSHJG-HWKANZROSA-N 0.000 description 1
- UWGOKHFOOHXWLA-UHFFFAOYSA-N 1,1'-biphenyl pentan-3-one Chemical compound C(C)C(=O)CC.C1(=CC=CC=C1)C1=CC=CC=C1 UWGOKHFOOHXWLA-UHFFFAOYSA-N 0.000 description 1
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 description 1
- VRLOVGDBPHSFCM-UHFFFAOYSA-N 1-(1-ethoxypropan-2-yloxy)-2-methylpropane Chemical compound CCOCC(C)OCC(C)C VRLOVGDBPHSFCM-UHFFFAOYSA-N 0.000 description 1
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- KTSVVTQTKRGWGU-UHFFFAOYSA-N 1-[2-[2-(2-butoxyethoxy)ethoxy]ethoxy]butane Chemical compound CCCCOCCOCCOCCOCCCC KTSVVTQTKRGWGU-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 1
- KIAMPLQEZAMORJ-UHFFFAOYSA-N 1-ethoxy-2-[2-(2-ethoxyethoxy)ethoxy]ethane Chemical compound CCOCCOCCOCCOCC KIAMPLQEZAMORJ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- DSCZKKBQLCGKDI-UHFFFAOYSA-N NC(=O)OCC.[Si].[F] Chemical compound NC(=O)OCC.[Si].[F] DSCZKKBQLCGKDI-UHFFFAOYSA-N 0.000 description 1
- ORFCMOKLZKHQKR-UHFFFAOYSA-N S(=O)(=O)(O)C1=C(C=2C(C3=CC=CC=C3SC=2C=C1)=O)OCCC Chemical compound S(=O)(=O)(O)C1=C(C=2C(C3=CC=CC=C3SC=2C=C1)=O)OCCC ORFCMOKLZKHQKR-UHFFFAOYSA-N 0.000 description 1
- 239000004283 Sodium sorbate Substances 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical class C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000000138 intercalating agent Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 239000001327 prunus amygdalus amara l. extract Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention relates to a ceramic ink-jet printing ink and its use methods, and concretely relates to a selection method of a ceramic pigment, five formula schemes of the ceramic ink-jet printing ink, and two use methods of the ceramic ink-jet printing ink. A preparation method of the ceramic ink-jet printing ink is optimized, and a printing device is arranged according to the different physical and chemical indexes of the ceramic ink-jet printing ink, so the cost using a ceramic ink-jet technology is reduced.
Description
Technical field
The present invention relates to a kind of ink for ink-jet print, be specifically related to a kind of ceramic ink jet ink.
Background technology
In the whole world, stamp ceramic field has huge market; Ceramic ink jet printing technique just replaces traditional ceramic printing technology with its huge advantage; Present ceramic ink jet printing technique, is generally that ceramic ink jet printing ink is contained on ceramic ink jet printing machine, by ink-jet, pattern is imprinted on the ceramic cooked flake through glazing, through firing fixed pattern, covers layer of transparent glaze above again; Ink-jet decorating machine domestic millions of/platform, several ten million/platforms of import; Ceramic ink jet ink is high and rare with its technical difficulty, and price is very high; Ceramic ink jet printing technique is by abroad being monopolized; All of these factors taken together affects the universal of ceramic ink jet printing technique; The gordian technique of ceramic ink jet printing technique is to manufacture ceramic ink jet printing ink.
The present patent application people did market survey, found the deficiency of existing ceramic ink jet printing technology.
1. aberration is obvious: the present patent application people finds, existing ceramic ink jet stamp is not also seen defect aspect printed patterns, but copy and print on character image at oil painting product, there is obvious aberration in ceramic ink jet stamp, aspect the form and aspect of color, lightness, purity, all has notable difference with oil painting, color darkness is obscure, lackluster, particularly darker regions is opaque, has a strong impact on picture effect.Analyze its reason, the tinting material of ceramic ink jet ink is the metal oxide in mineral dye, variant with the Lab value of standard colour chart.
2. storage stability and printing fluency deficiency: the colorant particles state of ceramic ink jet ink exists, and is dispersed in carrier by dispersion agent, and therefore very easily reunion, sedimentation, is difficult for stable preservation easily stopped up shower nozzle simultaneously in the time of printing; Special ceramic ink jet printing machine, particularly shower nozzle is expensive, and ink easily stops up shower nozzle can increase ceramic ink jet stamp cost undoubtedly.Prior art data is introduced, and this gave and preserved and use ceramic ink jet ink to bring difficulty about two months preservation stationary phase of ceramic ink jet ink.Analyze its reason, ceramic ink storage stability and printing fluency are subject to the impact of the several factors such as material choice, manufacturing technology, and one of them factor is that the particulate in ceramic ink is excessive; Present ceramic ink is that ceramic colorant and ceramic flux are refined jointly, makes particulate, and particle diameter is more than 800 nanometers; This is unfavorable for expanding the range of choice of ceramic pigment, and ceramic flux quality is hard simultaneously, is difficult for making trickle particulate.
3. the cementability deficiency of ceramic ink jet ink and base material, rub resistance, the water tolerance of ceramic ink jet ink are inadequate: ceramic ink jet ink printed on base material after, carrier volatilization in ink, colorant is deposited on substrate surface, because traditional ceramic ink jet ink does not have caking agent, therefore the cementability deficiency of ceramic ink jet ink and base material, the rub resistance of ceramic ink jet ink is inadequate; Simultaneously ceramic pigment and the ceramic flux in ceramic ink has water-absorbent, can absorb airborne steam, between the base material on printed ink-jet pottery and ceramic ink because of bonding bad the coming off of water absorption and swelling; On rainy day, printed ink-jet pottery is placed on outdoor, and it is swelling bonding bad that ceramic base material and ceramic ink absorb large quantity of moisture, can cause the ceramic of not firing after printing to damage.
4. the bright property of ceramic ink jet ink is inadequate, need to impose transparent flux protection: traditional ceramic ink jet ink, and using metal oxide as colorant, colorant darkness is obscure, lackluster; Outside colorant is directly exposed to, under easily drawing, rub in wiping, damage simultaneously, therefore need on ink-jet colorant, impose again layer of transparent flux, to protect ink-jet ceramic pigment, increase ceramic bright property simultaneously, increased like this cost of ceramic ink jet product.
5. existing ceramic ink jet ink lacks the ceramic ink jet printing device of special coupling: present ceramic ink jet ink, due to the reason of manufactured materials and manufacturing technology, quality is not often fine, need to obtain the quality authentication of producing ceramic ink jet printing machine manufacturer, increase like this chance of technical monopoly; The reason of analyzing ceramic ink jet ink poor quality, is that physical and chemical index-surface tension, pH value, the specific conductivity of ceramic ink jet ink is all easily up to standard, is exactly that viscosity usually can exceed standard, and causes a lot of inkjet-printing devices not print; If reduce the viscosity of ceramic ink jet ink to be applicable to other inkjet-printing device, not that ceramic ink jet printing device also can be printed ceramic ink jet ink, so just needn't buy expensive ceramic ink jet printer, can produce the result that the cost of ceramic ink jet printing is significantly declined.
Summary of the invention
The present patent application people, in order to overcome the deficiency of existing ceramic ink jet ink, proposes a kind of technical scheme of ceramic ink jet ink.
The application also provides the preparation method of this ceramic ink jet ink.
The application also provides the using method of this ceramic ink jet ink.
Technical scheme of the present invention is.
A kind of ceramic ink jet ink, is characterized in that the following component that contains weight percent: ceramic pigment 1-20%, and ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, all the other are carrier.
Wherein, described ceramic pigment is 300-1400 DEG C of baking 30 minutes-3 hours, ceramic flux melting, and colorant is unconverted, pigment dyestuff, mineral dye, metalluster pigment, dispersed dye; Particle diameter <100 nanometer; Mineral dye comprises traditional ceramics colorant, traditional ceramics colorant particle diameter 100-300 nanometer.
Described ceramic flux is pyroceramic flux, medium temperature ceramics flux, low-temp ceramics flux, the very low temperature ceramic flux of traditional ceramics manufacturing technology, and melt temperature is at 300-1400 DEG C; Particle diameter <100 nanometer.
Described modified polyurethane resin is selected from: at least one in epoxy resin-polyurethane resin, epoxy resin and acrylic ester-urethane resin, Viscotrol C-acrylate-polyurethane resin, acrylate-polyurethane resin, polysiloxane-polyurethane resin, organic silicon-acrylate-urethane resin, fluorine silicon-urethane resin, fluorine modified polyurethane resin, aliphatic polyurethane resin, polyester-polyurethane resin, polyethers-urethane resin, polyureas-urethane resin etc.; 24 hours water-intake rate≤10% after film forming; Modified polyurethane resin has or does not have ultraviolet light polymerization performance; Modified polyurethane resin is solia particle or emulsion, particle diameter <100 nanometer.
Described dispersion agent is organic high molecular polymer.
The system of selection of this programme ceramic pigment: the ratio with ceramic pigment: ceramic flux=1:1-0.5 mixes is toasted 30 minutes-3 hours with 300-1400 DEG C in baking box, ceramic flux melting, and colorant is unconverted, as ceramic pigment.
Carrier described in this programme, is to contain wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, surplus deionized water water base.
Wherein, the first scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, surplus deionized water.
Carrier described in this programme, can be also the solvent-based that contains wetting Agent for Printing Inks, permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6.
Wherein, first scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, surplus is the mixture of wetting Agent for Printing Inks and permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6.
Carrier described in this programme, also can contain light trigger 1-10%, reactive thinner 1-85%; Described modified polyurethane resin has ultraviolet light polymerization performance.
Wherein, the third scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, light trigger 1-10%, reactive thinner 1-85%.
The 4th kind of scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, light trigger 1-10%, reactive thinner 1-85%, surplus deionized water.
The 5th kind of scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, light trigger 1-10%, reactive thinner 1-85%, surplus is the mixture of wetting Agent for Printing Inks and permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6.
In modified polyurethane resin in this programme, can also compositely have acrylic resin modifiedly, acrylic resin modified is the acrylic resin of at least one modification in epoxy resin, organosilicon, organic fluorine, urethane resin; Particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming; Acrylic resin modified have or do not have a ultraviolet light polymerization performance; Acrylic resin modified and modified polyurethane resin sum is no more than 15% of ink for ink-jet print gross weight; Acrylic resin modified can be solia particle or emulsion.
At least one in this programme in BYK-2163, the BYK-2164 of the preferred Bi Ke chemistry of dispersion agent organic high molecular polymer, BYK-180, BYK184, BYK-190, BYK2012, BYK-2020 dispersion agent.
As preferably: described light trigger is bitter almond oil camphor and derivative (st-yrax, benzoin dimethylether, Benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether), benzil class (phenylbenzene ethyl ketone, α, alpha, alpha-dimethyl oxygen base-α-phenyl methyl phenyl ketone), alkylbenzene ketone (α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones), acyl group phosphorous oxides (aroyl phosphorous oxides, two benzoylphenyl phosphorus oxide), benzophenone (benzophenone, 2, 4-dihydroxy benaophenonel, Michler's keton), thioxanthones (sulfo-propoxy-thioxanthone, isopropyl thioxanthone), dibenzoyl, salicylate class, group-substituted acrylonitrile, triazines, hindered amines etc.Light trigger usage quantity is at 1-10%, preferably usage quantity 3-10%.
Further preferably use two or more above-mentioned light triggers composite, its performance is better than the light trigger of any independent use.
In this programme, reactive thinner is single functionality reactive thinner, difunctionality reactive thinner, polyfunctionality reactive thinner, single, double, three (many) functionality reactive thinner is composite with 3-6:0-4:0-1.
As preferably: reactive thinner is hydroxyethyl methacrylic acid, vinylformic acid lauryl alcohol fat, hexanediyl ester, diethylene glycol diacrylate, tripropylene glycol diacrylate, Viscoat 295 etc.
Wetting Agent for Printing Inks can be selected the raw material of safety non-toxic.The alcohols such as such as Virahol, ethanol, isopropylcarbinol; Glycol ether, propylene glycol, butyleneglycol, triglycol, Tetraglycol 99, polyoxyethylene glycol, polypropylene glycol, glycerine, 1,2-PD, BDO, 1,3-PD, BDO, 1,3-PD, 1, the polyalcohols such as 2-hexylene glycol.
Permeate agent is selected from: diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propandiol butyl ether, propylene glycol ethyl isobutyl ether, diethylene glycol monobutyl ether, diethylene glycol monomethyl ether, the only butyl ether of Diethylene Glycol, triethylene glycol monomethyl ether, Triethylene glycol ethyl ether, TRIGLYME, triethylene glycol diethyl ether, triethylene glycol dibutyl ether, tetraethyleneglycol dimethyl ether, TEG diethyl ether, monoethylene glycol and polyoxyethylene glycol phenyl ether, MPG and polypropylene glycol phenyl ether, 2-Pyrrolidone, METHYLPYRROLIDONE etc.
Above-mentioned tensio-active agent, the raw material of selection safety non-toxic.For example: nonionogenic tenside, anion surfactant, amphoterics.Nonionogenic tenside, is preferably polyoxyethylene aliphatic alcohol ether (AEO), polyoxyethylene fatty acid ester (AE), polyol ester, Sucrose Fatty Acid Ester, alcohol ether carboxylate (AEC-H), alkyl polyglycoside (APG); Anion surfactant, is preferably alcohol ether carboxylate surfactant (AEC), sulphosuccinates, secondary alkyl sulfonate (MES), fatty alcohol-polyoxyethylene ether sulfuric acid ester salt (AES), a-alkenyl sulphonate.Amphoterics, is preferably betaine type amphoteric surfac-tant, imidazoline type amphoterics.The consumption of tensio-active agent is in 0-2 % by weight.
Further preferably use two or more above-mentioned surfactant compounds, its performance is better than the tensio-active agent of any independent use.
Above-mentioned PH conditioning agent, the raw material of selection safety non-toxic.PH conditioning agent is selected from citric acid, Tripotassium Citrate, lactic acid, oxysuccinic acid, Trisodium Citrate, hydrochloric acid, Potassium Hydrogen Phthalate, potassium hydroxide, sodium hydroxide, quaternary ammonium hydroxide, for example tetramethyl-ammonium; Carbonate: for example salt of wormwood, sodium carbonate, Quilonum Retard; Phosphoric acid salt; METHYLPYRROLIDONE; Ethamine, diethanolamine, trolamine, ammoniacal liquor etc.
Anticorrosion and bactericidal agent is selected the raw material of safety and environmental protection.Such as sodium sorbate, potassium sorbate, isothiazolinone, BIT class etc.
In order to improve ceramic ink jet ink performance, can also add the conventional auxiliary agent that improves ink performance.As viscosity modifier, conductivity adjustment agent, stablizer, intercalating agent, defoamer, coupling agent, flow agent, thinner etc.
Ceramic ink jet ink of the present invention, its preparation method is.
(1) each component of preparation ink, stirs grinding machinery speed lapping (500-3000 rev/min) 1-30 hour; Detect maximum particulate fineness≤100 nanometer, obtain ink mixture; (traditional ceramics colorant particle diameter 100-300 nanometer).
(2) ink mixture leaves standstill slaking in-7 days in 12 hours.
(3) detect the every physical and chemical index of ink mixture.
(4) use successively 1 micron, 0.45 micron membrane filtration, obtain finished product.
The using method of ceramic ink jet ink of the present invention; to be configured in various applicable type printers according to the physical and chemical index of ceramic ink; transfer printing or be printed on ceramic green, ripe base; under glaze, in glaze, on glaze; in baking box, with 300-1400 DEG C of baking 30 minutes-3 hours, resulting product needn't apply protection glaze.
Solve the method for ceramic ink jet ink aberration, the firstth, the range of choice of expansion ceramic pigment, the secondth, the method for employing ceramic pigment mixing colorant match, to reduce aberration; Use color difference meter to detect the Lab value difference distance of ceramic product color and standard colour chart, difference should be tried one's best little or is zero, just can reach desirable effect by test of many times.The choice and operation quantity of ceramic pigment and the ratio of mixing colorant match, to just can accurately determine according to different formulas, different type printers, different print media, different Method of printing, different storing temperatures etc. the numerical value that neither one is general.
According to the configuration of five kinds of ceramic ink jet inks above, or using method, select according to concrete service condition.Should be noted that especially according to the physical and chemical parameter of ink and select inkjet-printing device, water-base ink is selected aqueous jet device, solvent-based inks of the present invention can be selected solvent-borne type ink discharge device, also can select aqueous jet device, the curing ink of UV is selected the curing ink discharge device of UV, be select transfer printing or directly print, determine according to the specific environment situation using.
Beneficial effect of the present invention and advantage are.
1. with concrete colorant system of selection, expand the range of choice of colorant, dwindled the aberration of colorant.
2. ceramic pigment and ceramic flux ground respectively and prepared, being conducive to expand the range of choice of colorant, being conducive to dwindle the particle diameter of ceramic flux simultaneously.
3. the fineness of being strict with component in ceramic ink jet ink, except traditional ceramics colorant requires 100-300 nanometer, all the other particulates all require below 100 nanometers; Be conducive to the storage stability of ink for ink-jet print and the raising of printing fluency.
4. in ceramic ink, add the modified polyurethane resin of excellent properties, be conducive to improve the over-all properties of ceramic ink, be conducive to improve the storage stability of ink for ink-jet print and print fluency; Be conducive to the grinding steps of ceramic ink, reduce particulate fineness.
5. preferably very low temperature ceramic flux, as component, is conducive to reduce the storing temperature of ceramic ink jet product, is conducive to save energy.
6. strict every physical and chemical index of controlling ceramic ink jet ink, needn't use dedicated ceramic inkjet-printing device to print ceramic ink, has expanded ceramic ink use range, has reduced ceramic ink jet utilization cost.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.(but this should be interpreted as to the scope of the above-mentioned theme of the present invention only limits to following embodiment).
Embodiment 1: certain brand very low temperature ceramic flux of buying from market, has the following component of weight percent, 780 DEG C of melt temperatures: (in table 1).
。
Embodiment 2: the selection of ceramic pigment, 5 grams of pigment dyestuff carbon blacks of particle diameter 100 nanometers and the very low temperature ceramic flux of 2.5 grams of embodiment 1 are mixed, put into baking box, toast 160 minutes (600-780 DEG C, 6 DEG C/min of temperature rise rates; 780-500 DEG C, rate of temperature fall 20-25 DEG C/min, 500-25 DEG C, rate of temperature fall 2-5 DEG C/min).
Conclusion: ceramic flux melting, pigment dyestuff carbon black form and aspect do not change, and can be used as ceramic ink jet ink dyestuff.
Embodiment 3: the selection of ceramic pigment, 5 grams of mineral dye rutile types of particle diameter 100 nanometers and the very low temperature ceramic flux of 5 grams of embodiment 1 are mixed, put into baking box, toast 160 minutes (600-780 DEG C, 6 DEG C/min of temperature rise rates; 780-500 DEG C, rate of temperature fall 20-25 DEG C/min, 500-25 DEG C, rate of temperature fall 2-5 DEG C/min).
Conclusion: ceramic flux melting, rutile type form and aspect do not change, and can be used as ceramic ink jet ink dyestuff.
Ceramic ink jet ink of the present invention, its preparation method is.
(1) each component of preparation ink, stirs grinding machinery speed lapping (500-3000 rev/min) 1-30 hour; Detect maximum particulate fineness≤100 nanometer, obtain ink mixture; (traditional ceramics colorant particle diameter 100-300 nanometer).
(2) ink mixture leaves standstill slaking in-7 days in 12 hours.
(3) detect the every physical and chemical index of ink mixture.
(4) use successively 1 micron, 0.45 micron membrane filtration, obtain finished product.
Embodiment 4-7: the starting material configuration of ceramic ink jet ink the first scheme: (water base ceramic ink jet ink) (in table 2).
。
The application's the first scheme (water base ceramic ink jet ink) is 1.5-4 m Pa the viscosity of 20 DEG C. S, surface tension 25-45 m N/m, pH value 7-9, specific conductivity 103-10
4μ S/cm.
Embodiment 8-11: the starting material configuration of ceramic ink jet ink first scheme: (solvent-based ceramic ink jet ink) (in table 3).
。
The application's first scheme (solvent-based ceramic ink jet ink) is 1.5-20 m Pa the viscosity of 20 DEG C. S, surface tension 25-45 m N/m, pH value 7-9, specific conductivity 103-10
4μ S/cm.
Embodiment 12-15: the starting material configuration of the third scheme of ceramic ink jet ink: (the ceramic ink jet ink of ultraviolet light polymerization) (in table 4).
。
The third scheme of the application (the ceramic ink jet ink of ultraviolet light polymerization) detects at 20 DEG C, and viscosity is 1.5-30 m Pa. S, surface tension 25-45 m N/m, pH value 7-9, specific conductivity 103-10
4μ S/cm.
Embodiment 16-19: the starting material configuration of the 4th kind of scheme of ceramic ink jet ink: (the water base ceramic ink jet ink of ultraviolet light polymerization) (in table 5).
。
The 4th kind of scheme of the application (the water base ceramic ink jet ink of ultraviolet light polymerization) is 1.5-10 m Pa.S the viscosity of 20 DEG C, surface tension 25-45 m N/m, pH value 7-9, specific conductivity 103-10
4μ S/cm.
Embodiment 20-23: the starting material configuration of the 5th kind of scheme of ceramic ink jet ink: (the solvent-based ceramic ink jet ink of ultraviolet light polymerization) (in table 6).
。
The 5th kind of scheme of the application (the solvent-based ceramic ink jet ink of ultraviolet light polymerization) is 1.5-25 m Pa the viscosity of 20 DEG C. S, surface tension 25-45 m N/m, pH value 7-9, specific conductivity 103-10
4μ S/cm.
Shown according to do experiment, ink system viscosity with ceramic pigment, ceramic flux, reactive thinner particularly the addition of three-functionality-degree, polyfunctionality reactive thinner increase, adding deionized water can make ink system viscosity significantly reduce, add organic solvent and also can make ink system reduced viscosity, pigment dyestuff is made colorant also can reduce ink system viscosity; 20 DEG C of viscosity of the application's ceramic ink jet ink system are at 1.5-30mPa.S, surface tension 25-45 mN/m, pH value 7-9, specific conductivity 103-10
4μ S/cm and can regulating and controlling, can manufacture ceramic ink jet ink as required.In the situation that meeting result of use, select the lower starting material of viscosity, add deionized water, ink system viscosity can be controlled at very low scope, to be applicable to various types of ink-jet printers.
According to the physical and chemical index of the various embodiments described above, water-based or solvent-based inks are configured in Epson R230 type ink-jet printer, are transferred on ceramic cooked flake; The curing ink of UV is configured in the curing printer of UV (Epson UV flat-panel printer STYLUS PRO 4880C), be printed on Ceramic glaze, detect printing stability and print fluency, winter hardiness according to test item and examination criteria below: (in table 7).
。
Embodiment 24-28: according to the physical and chemical index of the various embodiments described above, water-based or solvent-based inks are configured in Epson R230 type ink-jet printer, are transferred on ceramic cooked flake; The curing ink of UV is configured in the curing printer of UV (Epson UV flat-panel printer STYLUS PRO 4880C), is printed on Ceramic glaze, and products obtained therefrom detects following items.
Water tolerance.
Detection method: in deionized water, flood after 24h, take out seasoning, and with contrasting colour mark ready visual contrast.
Salt tolerant is acid to be detected.
Detection method: in 10% (volume ratio) aqueous hydrochloric acid, flood after 24h, in deionized water, flood 10min, take out seasoning, and with contrasting colour mark ready visual contrast.
Resistance to ethanol detects.
Detection method: in 50% (volume ratio) aqueous ethanolic solution, flood after 10min, take out seasoning, and with contrasting colour mark ready visual contrast.
Resistance to ammoniacal liquor detects.
Detection method: in 10% (mass percent) ammonia soln, flood after 24h, in deionized water, flood 10min, take out seasoning, and with contrasting colour mark ready visual contrast.
Rub resistance.
Detection method: after treating that ink is bone dry, on ink marks, rub with coin, until there is abrasion mark in writing, record friction number of times.By the strength generally scratching, the angle that coin and word table face 45 are spent scratches back and forth on the surface of word, until vestige appears scratching in writing surface, record scratches number of times, determines ink rub resistance of the present invention.(in table 8).
。
Embodiment 29-33: according to the physical and chemical index of the various embodiments described above, water-based or solvent-based inks are configured in Epson R230 type ink-jet printer, are transferred on ceramic cooked flake; The curing ink of UV is configured in the curing printer of UV (Epson UV flat-panel printer STYLUS PRO 4880C), is printed on Ceramic glaze, and in baking box, with 300-1400 DEG C of baking 30 minutes-3 hours, resulting product needn't apply protection glaze.Products obtained therefrom detects following items: (in table 9).
Claims (10)
1. a ceramic ink jet ink, is characterized in that the following component that contains weight percent: ceramic pigment 1-20%, and ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, all the other are carrier;
Wherein, described ceramic pigment is 300-1400 DEG C of baking 30 minutes-3 hours, ceramic flux melting, and colorant is unconverted, pigment dyestuff, mineral dye, metalluster pigment, dispersed dye; Particle diameter <100 nanometer; Mineral dye comprises traditional ceramics colorant, traditional ceramics colorant particle diameter 100-300 nanometer;
Described ceramic flux is pyroceramic flux, medium temperature ceramics flux, low-temp ceramics flux, the very low temperature ceramic flux of traditional ceramics manufacturing technology, and melt temperature is at 300-1400 DEG C; Particle diameter <100 nanometer;
Described modified polyurethane resin is selected from: at least one in epoxy resin-polyurethane resin, epoxy resin and acrylic ester-urethane resin, Viscotrol C-acrylate-polyurethane resin, acrylate-polyurethane resin, polysiloxane-polyurethane resin, organic silicon-acrylate-urethane resin, fluosilicic-urethane resin, fluoro-urethane resin, aliphatic polyurethane resin, polyester-polyurethane resin, polyethers-urethane resin, polyureas-urethane resin etc.; Particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming; Modified polyurethane resin has or does not have ultraviolet light polymerization performance; Modified polyurethane resin is solia particle or emulsion;
Described dispersion agent is organic high molecular polymer.
2. the system of selection of the ceramic pigment described in claim 1: the ratio with ceramic pigment: ceramic flux=1:1-0.5 mixes is toasted 30 minutes-3 hours with 300-1400 DEG C in baking box, ceramic flux melting, and colorant is unconverted, as ceramic pigment.
3. the carrier described in claim 1, is to contain wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, surplus deionized water water base;
Wherein, the first scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, surplus deionized water.
4. the carrier described in claim 1, is the solvent-based that contains wetting Agent for Printing Inks, permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6;
Wherein, first scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, surplus is the mixture of wetting Agent for Printing Inks and permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6.
5. the carrier described in claim 1, contains light trigger 1-10%, reactive thinner 1-85%; Described modified polyurethane resin has ultraviolet light polymerization performance;
Wherein, the third scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, light trigger 1-10%, reactive thinner 1-85%;
The 4th kind of scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, wetting Agent for Printing Inks 5-25%, permeate agent 5-15%, fungicidal preservative 0.1-0.5%, light trigger 1-10%, reactive thinner 1-85%, surplus deionized water;
The 5th kind of scheme: a kind of ceramic ink jet ink, the following component that contains weight percent: ceramic pigment 1-20%, ceramic flux 1-10%, modified polyurethane resin 1-15%, dispersion agent 1-5%, tensio-active agent 0-2%, PH conditioning agent 0-2%, light trigger 1-10%, reactive thinner 1-85%, surplus is the mixture of wetting Agent for Printing Inks and permeate agent, wetting Agent for Printing Inks: permeate agent=1:1-0.6.
6. ceramic ink jet ink claimed in claim 1, is characterized in that: also composite in modified polyurethane resin have acrylic resin modifiedly, and acrylic resin modified is the acrylic resin of at least one modification in epoxy resin, organosilicon, organic fluorine, urethane resin; Particle diameter <100 nanometer, 24 hours water-intake rate≤10% after film forming; Acrylic resin modified have or do not have a ultraviolet light polymerization performance; Acrylic resin modified and modified polyurethane resin sum is no more than 15% of ink for ink-jet print gross weight; Acrylic resin modified is solia particle or emulsion.
7. ink for ink-jet print claimed in claim 1, is characterized in that: described organic high molecular polymer is at least one in BYK-2163, BYK-2164, BYK-180, BYK184, BYK-190, BYK2012, the BYK-2020 dispersion agent of Bi Ke chemistry.
8. ceramic ink jet ink claimed in claim 5, is characterized in that: reactive thinner is single functionality reactive thinner, difunctionality reactive thinner, polyfunctionality reactive thinner, single, double, polyfunctionality reactive thinner is composite with 3-6:0-4:0-1.
9. ceramic ink jet ink claimed in claim 1, its preparation method is:
(1) each component of preparation ink, stirs grinding machinery speed lapping (500-3000 rev/min) 1-30 hour; Detect maximum particulate fineness≤100 nanometer, obtain ink mixture; (traditional ceramics colorant particle diameter 100-300 nanometer)
(2) ink mixture leaves standstill slaking in-7 days in 12 hours;
(3) detect the every physical and chemical index of ink mixture;
(4) use successively 1 micron, 0.45 micron membrane filtration, obtain finished product.
10. the using method of ceramic ink jet ink claimed in claim 1; to be configured in various applicable type printers according to the physical and chemical index of ceramic ink; transfer printing or be printed on ceramic green, ripe base; under glaze, in glaze, on glaze; in baking box, with 300-1400 DEG C of baking 30 minutes-3 hours, resulting product needn't apply protection glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410094020.XA CN103937326A (en) | 2014-03-14 | 2014-03-14 | Ceramic ink-jet printing ink and its use methods |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410094020.XA CN103937326A (en) | 2014-03-14 | 2014-03-14 | Ceramic ink-jet printing ink and its use methods |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103937326A true CN103937326A (en) | 2014-07-23 |
Family
ID=51185212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410094020.XA Pending CN103937326A (en) | 2014-03-14 | 2014-03-14 | Ceramic ink-jet printing ink and its use methods |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103937326A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104133352A (en) * | 2014-08-09 | 2014-11-05 | 鲁继烈 | Toner for laser printers |
| CN104761952A (en) * | 2015-03-27 | 2015-07-08 | 广东道氏技术股份有限公司 | Ceramic inkjet printing ink with adjustable penetration depth and method thereof |
| WO2016042097A1 (en) * | 2014-09-19 | 2016-03-24 | Ceramco S.P.A. | Ceramic ink for inkjet printing |
| CN105504972A (en) * | 2016-02-23 | 2016-04-20 | 谭海林 | Waterborne UV cured ceramic printing ink and preparation method thereof |
| CN105585899A (en) * | 2016-02-23 | 2016-05-18 | 谭海林 | Water-based UV-curing ceramic spraying ink and preparation method thereof |
| CN105585902A (en) * | 2016-02-23 | 2016-05-18 | 佛山市彩贵新型材料有限公司 | Waterborne UV curing spraying printing ink and preparation method thereof |
| CN106084985A (en) * | 2016-08-23 | 2016-11-09 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink auxiliary agent |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
| CN106336724A (en) * | 2016-08-23 | 2017-01-18 | 佛山市彩贵新型材料有限公司 | Composition for enhancing permeability of ink |
| CN106349802A (en) * | 2016-08-23 | 2017-01-25 | 佛山市彩贵新型材料有限公司 | Permeation-promoter composition |
| CN106349820A (en) * | 2016-08-23 | 2017-01-25 | 佛山市彩贵新型材料有限公司 | Tile ink-jet permeability-increasing agent |
| CN107298897A (en) * | 2017-07-27 | 2017-10-27 | 汪国军 | Couple the application method of material |
| CN108368367A (en) * | 2015-10-19 | 2018-08-03 | 图像电子公司 | Radiation-curable ink-jet ink suitable for glass, ceramics or metal |
| CN109161248A (en) * | 2018-09-30 | 2019-01-08 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED UV-curable waterborne printing ink and preparation method thereof |
| CN109535838A (en) * | 2018-11-27 | 2019-03-29 | 山东国瓷康立泰新材料科技有限公司 | A kind of ceramic ink jet printing ink and preparation method thereof of the adjustable finishing impression effect of glossiness |
| CN111363410A (en) * | 2020-05-14 | 2020-07-03 | 山东国瓷康立泰新材料科技有限公司 | Ink-jet printing decorative ink for domestic ceramics and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382518A (en) * | 2011-11-23 | 2012-03-21 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN103497589A (en) * | 2013-10-10 | 2014-01-08 | 鲁继烈 | Aqueous disperse dye ink-jet printing ink |
| CN103555066A (en) * | 2013-10-30 | 2014-02-05 | 澧县新鹏陶瓷有限公司 | Colored glaze mixed type ink for ceramic ink-jet printing and preparation method thereof |
| CN103627254A (en) * | 2013-12-05 | 2014-03-12 | 江西锦绣现代化工有限公司 | Ceramic ink-jet printing used yellow glaze printing ink for ceramic ink-jet printing and preparation method thereof |
-
2014
- 2014-03-14 CN CN201410094020.XA patent/CN103937326A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382518A (en) * | 2011-11-23 | 2012-03-21 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN103497589A (en) * | 2013-10-10 | 2014-01-08 | 鲁继烈 | Aqueous disperse dye ink-jet printing ink |
| CN103555066A (en) * | 2013-10-30 | 2014-02-05 | 澧县新鹏陶瓷有限公司 | Colored glaze mixed type ink for ceramic ink-jet printing and preparation method thereof |
| CN103627254A (en) * | 2013-12-05 | 2014-03-12 | 江西锦绣现代化工有限公司 | Ceramic ink-jet printing used yellow glaze printing ink for ceramic ink-jet printing and preparation method thereof |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104133352A (en) * | 2014-08-09 | 2014-11-05 | 鲁继烈 | Toner for laser printers |
| WO2016042097A1 (en) * | 2014-09-19 | 2016-03-24 | Ceramco S.P.A. | Ceramic ink for inkjet printing |
| CN106715608A (en) * | 2014-09-19 | 2017-05-24 | 司马塞拉姆科公司 | Ceramic ink for inkjet printing |
| CN104761952A (en) * | 2015-03-27 | 2015-07-08 | 广东道氏技术股份有限公司 | Ceramic inkjet printing ink with adjustable penetration depth and method thereof |
| CN108368367B (en) * | 2015-10-19 | 2022-07-12 | 图像电子公司 | Radiation curable inkjet inks suitable for glass, ceramic or metal |
| CN108368367A (en) * | 2015-10-19 | 2018-08-03 | 图像电子公司 | Radiation-curable ink-jet ink suitable for glass, ceramics or metal |
| CN105504972A (en) * | 2016-02-23 | 2016-04-20 | 谭海林 | Waterborne UV cured ceramic printing ink and preparation method thereof |
| CN105585899A (en) * | 2016-02-23 | 2016-05-18 | 谭海林 | Water-based UV-curing ceramic spraying ink and preparation method thereof |
| CN105585902A (en) * | 2016-02-23 | 2016-05-18 | 佛山市彩贵新型材料有限公司 | Waterborne UV curing spraying printing ink and preparation method thereof |
| CN106349820A (en) * | 2016-08-23 | 2017-01-25 | 佛山市彩贵新型材料有限公司 | Tile ink-jet permeability-increasing agent |
| CN106349802A (en) * | 2016-08-23 | 2017-01-25 | 佛山市彩贵新型材料有限公司 | Permeation-promoter composition |
| CN106336724A (en) * | 2016-08-23 | 2017-01-18 | 佛山市彩贵新型材料有限公司 | Composition for enhancing permeability of ink |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
| CN106084985A (en) * | 2016-08-23 | 2016-11-09 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink auxiliary agent |
| CN107298897A (en) * | 2017-07-27 | 2017-10-27 | 汪国军 | Couple the application method of material |
| CN109161248A (en) * | 2018-09-30 | 2019-01-08 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED UV-curable waterborne printing ink and preparation method thereof |
| CN109535838A (en) * | 2018-11-27 | 2019-03-29 | 山东国瓷康立泰新材料科技有限公司 | A kind of ceramic ink jet printing ink and preparation method thereof of the adjustable finishing impression effect of glossiness |
| CN109535838B (en) * | 2018-11-27 | 2021-11-23 | 山东国瓷康立泰新材料科技有限公司 | Ceramic ink-jet printing ink with adjustable glossiness and accurate carving effect and preparation method thereof |
| CN111363410A (en) * | 2020-05-14 | 2020-07-03 | 山东国瓷康立泰新材料科技有限公司 | Ink-jet printing decorative ink for domestic ceramics and preparation method thereof |
| CN111363410B (en) * | 2020-05-14 | 2022-04-12 | 山东国瓷康立泰新材料科技有限公司 | Ink-jet printing decorative ink for domestic ceramics and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937326A (en) | Ceramic ink-jet printing ink and its use methods | |
| CN103319953B (en) | Water-based pigment ink for quality improvement | |
| CN103436095B (en) | Ultraviolet-curing water-based inkjet ink | |
| CN103497589A (en) | Aqueous disperse dye ink-jet printing ink | |
| JPH02132169A (en) | Recording liquid and inkjet recording method using the same | |
| CN104449042B (en) | Weak solvent ink-jet ink | |
| CN101891984B (en) | Printing ink combination, printing ink and method for forming image on ceramic surface | |
| CN103087586A (en) | Waterproof and light-resistant water-based resin dye jet ink | |
| JPH0778191B2 (en) | Ink and recording method | |
| CN102817254B (en) | Cold-transfer printing digital proofing method | |
| CN111254721A (en) | Novel pyrograph printing ink and preparation method and application thereof | |
| US6899753B2 (en) | Highly bleed-alleviating ink composition | |
| CN104845452A (en) | Waterproof dye-based ink for ink-jet printing and preparation method thereof | |
| CN102501675A (en) | Matte polypropylene inkjet photo paper suitable for ECO-solvent ink | |
| CN102558943A (en) | Black water-based pigment ink | |
| CN103468058B (en) | For the Weak solvent ink for ink-jet print and preparation method thereof of industrial piezo jets | |
| JP2009269964A (en) | Ink composition for inkjet recording | |
| CN101705029B (en) | Solvent dye ink-jet printing ink and preparation method thereof | |
| CN101117469A (en) | A dry erasable whiteboard marker ink | |
| CN105440798B (en) | A kind of ink-jet printer ink and preparation method thereof | |
| CN113025122B (en) | Water-based lasting erasable ink and preparation method thereof | |
| CN101451032A (en) | Ink composition for ink jet recording and ink jet recording method | |
| CN102558950A (en) | Water-based inkjet ink containing metal oxide | |
| CN115709607B (en) | Printing process for surface diversification of books | |
| CN115584162B (en) | Water-based ink for gravure printing of PVC edge banding strip and synthesis process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140723 |