CN103911206B - Without barium without sulfonate electrostatic painting anticorrosive oil - Google Patents
Without barium without sulfonate electrostatic painting anticorrosive oil Download PDFInfo
- Publication number
- CN103911206B CN103911206B CN201410168119.XA CN201410168119A CN103911206B CN 103911206 B CN103911206 B CN 103911206B CN 201410168119 A CN201410168119 A CN 201410168119A CN 103911206 B CN103911206 B CN 103911206B
- Authority
- CN
- China
- Prior art keywords
- oil
- sulfonate
- barium
- electrostatic painting
- painting anticorrosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000010422 painting Methods 0.000 title claims abstract description 16
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 title claims abstract description 15
- 229910052788 barium Inorganic materials 0.000 title claims abstract description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 title claims abstract description 8
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims abstract description 12
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 12
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims abstract description 12
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000000470 constituent Substances 0.000 claims abstract description 6
- 239000003921 oil Substances 0.000 description 36
- 238000005516 engineering process Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000010960 cold rolled steel Substances 0.000 description 7
- 238000007590 electrostatic spraying Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 238000010292 electrical insulation Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 238000004080 punching Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 159000000009 barium salts Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 239000010731 rolling oil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses one without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: No. 15 machinery oil of 80 ~ 90%, the zinc naphthenate of 2 ~ 10%, 1 ~ 6% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 2 ~ 10%, the 2,6 ditertiary butyl p cresol of 1 ~ 5%.Slushing oil of the present invention without intense stimulus smell, not baric and sulfonate, health environment-friendly; There is excellent rust-preventing characteristic, stable performance, and there is good lubricity.
Description
Technical field
The present invention relates to guard technology field, particularly refer to one without barium without sulfonate electrostatic painting anticorrosive oil.
Background technology
The automobile developed rapidly, especially Car Manufacturing and household appliances manufacturing, not only require that the mechanical property of cold-rolled steel sheet and surface quality reach corresponding standard, and require that the slushing oil of product surface coating is coated with oil mass when 0.5 ~ 2.0g/m2, good rust-preventing characteristic, rust removability, stampability and the consistency with electrophoretic painting technique must be had, this even includes in the terms of delivery of auto sheet by some automobile works, and therefore, cold-rolled steel sheet adopts more advanced Electrostatic Spray Technology.
Due to low cost, easy and simple to handle, be easy to construction, be easy to advantages such as removing, result of use is good, slushing oil obtains widespread production and use at home and abroad.At present, slushing oil product is towards stdn, seriation, environmental protection future development.Barium salt and sulfonate favorable rust preventing effect, the rust-preventive agent that electrostatic painting anticorrosive oil is conventional is substantially all based on barium salt and sulfonate, but barium salt and sulfonate pollute the environment, and do not conform to environmental requirement, and can produce huge injury to human body.Thus, adopt the rush-resisting material meeting environmental requirement, the electrostatic painting anticorrosive oil product developing not baric and sulfonate becomes very urgent and important.
Summary of the invention
For slushing oil product environmental protection problem, object of the present invention will provide one exactly without barium without sulfonate electrostatic painting anticorrosive oil, and this slushing oil is baric and sulfonate not, belongs to environmentfriendly products, high rust resistance, is applicable to electrostatic spraying.
For achieving the above object, provided by the invention without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: No. 15 machinery oil of 80 ~ 90%, the zinc naphthenate of 2 ~ 10%, 1 ~ 6% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 2 ~ 10%, the 2,6 ditertiary butyl p cresol of 1 ~ 5%.
As a kind of preferred version, its constituent mass per-cent is as follows: No. 15 machinery oil of 85 ~ 81%, the zinc naphthenate of 3 ~ 6%, 2 ~ 5% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 4 ~ 7%, the 2,6 ditertiary butyl p cresol of 2 ~ 3%.
As another preferred version, its constituent mass per-cent is as follows: No. 15 machinery oil of 85%, the zinc naphthenate of 6%, 2% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 4%, the 2,6 ditertiary butyl p cresol of 3%.
The effect of each component of the zinc-plated very thin plate cold rolling oil of environmental protection of the present invention is as follows:
Oil based on No. 15 machinery oil; it is the carrier of inhibiter; multiple corrosion inhibition additive can be used mutually to mix, dissolve and disperse sufficiently uniformly; base oil molecules can be deep between the inhibitor molecular of oriented adsorption; make the adsorption film of hydrophobic tightr; also make absorption polar molecule loosely not easily desorption, thus more effectively protect metal, generally account for more than 80%.
Zinc naphthenate, KORANTIN SH stearylamine, dodecenylsuccinic acid are as rust-inhibiting additive, additive effect is played during multiple additives compound use, very thin tectum can be formed in metallic surface, metal and corrosive medium are completely cut off, the anodic dissolution processes of metal can not be carried out, effectively prevent metal from producing corrosion, reach good rust-proof effect.
2,6 ditertiary butyl p cresol is as antioxidant.Because organism all contains unsatisfied chemical bond, can react with other compound generation number of chemical, as oxidizing reaction and polyreaction, the oxidizing reaction of oil makes oil thinning, and acid number increases, viscosity reduces, oil film is thinning, occurs the phenomenons such as muddiness and cannot use, and is unfavorable for transport and standing storage, polyreaction causes grease to solidify, and easily makes strip produce mottling.
Tool of the present invention has the following advantages: slushing oil of the present invention without intense stimulus smell, not baric and sulfonate, health environment-friendly; There is excellent rust-preventing characteristic, stable performance, and there is good lubricity.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment one:
Get No. 15 machinery oil 80% by mass percentage, zinc naphthenate 10%, KORANTIN SH stearylamine 6%, dodecenylsuccinic acid 2%, 2,6 ditertiary butyl p cresol 2%, these raw material Homogeneous phase mixing are made electrostatic painting anticorrosive oil, this slushing oil all has excellent rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment two:
Get No. 15 machinery oil 80% by mass percentage, zinc naphthenate 4%, KORANTIN SH stearylamine 1%, dodecenylsuccinic acid 10%, 2,6 ditertiary butyl p cresol 5%, these raw material Homogeneous phase mixing are made electrostatic painting anticorrosive oil, this slushing oil all has excellent rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment three:
Get No. 15 machinery oil 90% by mass percentage, zinc naphthenate 2%, KORANTIN SH stearylamine 3%, dodecenylsuccinic acid 4%, 2,6 ditertiary butyl p cresol 1%, these raw material Homogeneous phase mixing are made electrostatic painting anticorrosive oil, this slushing oil all has excellent rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment four:
Get No. 15 machinery oil 85% by mass percentage, zinc naphthenate 6%, KORANTIN SH stearylamine 2%, dodecenylsuccinic acid 4%, 2,6 ditertiary butyl p cresol 3%, these raw material Homogeneous phase mixing are made electrostatic painting anticorrosive oil, this slushing oil all has excellent rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Embodiment five:
Get No. 15 machinery oil 81% by mass percentage, zinc naphthenate 3%, KORANTIN SH stearylamine 5%, dodecenylsuccinic acid 7%, 2,6 ditertiary butyl p cresol 4%, these raw material Homogeneous phase mixing are made electrostatic painting anticorrosive oil, this slushing oil all has excellent rust-preventing characteristic to cold-rolled steel sheet, steel plate galvanized, and electrical insulation capability is suitable for the electrostatic spraying under high-voltage, and punching performance reaches automobile production line technology requirement.
Claims (2)
1. one kind without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: No. 15 machinery oil of 85 ~ 81%, the zinc naphthenate of 3 ~ 6%, 2 ~ 5% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 4 ~ 7%, the 2,6 ditertiary butyl p cresol of 2 ~ 3%.
2. according to claim 1 without barium without sulfonate electrostatic painting anticorrosive oil, it is characterized in that: its constituent mass per-cent is as follows: No. 15 machinery oil of 85%, the zinc naphthenate of 6%, 2% KORANTIN SH stearylamine, the dodecenylsuccinic acid of 4%, the 2,6 ditertiary butyl p cresol of 3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410168119.XA CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410168119.XA CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103911206A CN103911206A (en) | 2014-07-09 |
| CN103911206B true CN103911206B (en) | 2015-12-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410168119.XA Expired - Fee Related CN103911206B (en) | 2014-04-24 | 2014-04-24 | Without barium without sulfonate electrostatic painting anticorrosive oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103911206B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841432A (en) * | 2018-05-28 | 2018-11-20 | 湖北三环化学新材料股份有限公司 | A kind of degradable punching oil of food-grade and preparation method thereof |
| CN111117739A (en) * | 2019-12-12 | 2020-05-08 | 沈阳防锈包装材料有限责任公司 | Gas-phase anti-rust oil and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
-
2014
- 2014-04-24 CN CN201410168119.XA patent/CN103911206B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101643683A (en) * | 2008-08-08 | 2010-02-10 | 沈阳防锈包装材料有限责任公司 | Environmentally-friendly barium-free thixotropic antirust oil |
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| Publication number | Publication date |
|---|---|
| CN103911206A (en) | 2014-07-09 |
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| C06 | Publication | ||
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Effective date of registration: 20170725 Address after: 430083, Hubei Wuhan Qingshan District Factory No. 2 Gate joint stock company organs Patentee after: Wuhan iron and Steel Company Limited Address before: 430080 Wuchang, Hubei Friendship Road, No. A, block, floor 999, 15 Patentee before: Wuhan Iron & Steel (Group) Corp. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151209 Termination date: 20190424 |