CN103710135A - A kind of pure plant modifier before supercritical CO2 extraction of Lycium barbarum seed oil - Google Patents
A kind of pure plant modifier before supercritical CO2 extraction of Lycium barbarum seed oil Download PDFInfo
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- 244000241838 Lycium barbarum Species 0.000 title claims abstract description 29
- 235000015459 Lycium barbarum Nutrition 0.000 title claims abstract description 29
- 235000015112 vegetable and seed oil Nutrition 0.000 title claims abstract description 20
- 241000196324 Embryophyta Species 0.000 title claims abstract description 15
- 239000003607 modifier Substances 0.000 title claims abstract description 10
- 238000000605 extraction Methods 0.000 title abstract description 24
- 239000000284 extract Substances 0.000 claims abstract description 25
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 244000118350 Andrographis paniculata Species 0.000 claims abstract description 8
- 235000007516 Chrysanthemum Nutrition 0.000 claims abstract description 8
- 240000008042 Zea mays Species 0.000 claims abstract description 8
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 8
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 8
- 210000000988 bone and bone Anatomy 0.000 claims abstract description 8
- 235000005822 corn Nutrition 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 241000723353 Chrysanthemum Species 0.000 claims description 7
- 235000015468 Lycium chinense Nutrition 0.000 abstract description 22
- 239000000843 powder Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 235000016709 nutrition Nutrition 0.000 abstract description 2
- 244000189548 Chrysanthemum x morifolium Species 0.000 abstract 1
- 239000012530 fluid Substances 0.000 description 4
- 208000002874 Acne Vulgaris Diseases 0.000 description 3
- 206010000496 acne Diseases 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- OENHQHLEOONYIE-UKMVMLAPSA-N all-trans beta-carotene Natural products CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 description 2
- 235000013734 beta-carotene Nutrition 0.000 description 2
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 description 2
- 239000011648 beta-carotene Substances 0.000 description 2
- 229960002747 betacarotene Drugs 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 2
- DMASLKHVQRHNES-UPOGUZCLSA-N (3R)-beta,beta-caroten-3-ol Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C DMASLKHVQRHNES-UPOGUZCLSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- 201000001320 Atherosclerosis Diseases 0.000 description 1
- 239000004212 Cryptoxanthin Substances 0.000 description 1
- 208000031226 Hyperlipidaemia Diseases 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000002360 beta-cryptoxanthin Nutrition 0.000 description 1
- DMASLKHVQRHNES-ITUXNECMSA-N beta-cryptoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2=C(C)CCCC2(C)C DMASLKHVQRHNES-ITUXNECMSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- 208000029078 coronary artery disease Diseases 0.000 description 1
- 235000019244 cryptoxanthin Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 230000000378 dietary effect Effects 0.000 description 1
- 230000002892 effect on hypertension Effects 0.000 description 1
- 230000000517 effect on sleep Effects 0.000 description 1
- 235000004626 essential fatty acids Nutrition 0.000 description 1
- VZCCETWTMQHEPK-UHFFFAOYSA-N gamma-Linolensaeure Natural products CCCCCC=CCC=CCC=CCCCCC(O)=O VZCCETWTMQHEPK-UHFFFAOYSA-N 0.000 description 1
- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 description 1
- 235000020664 gamma-linolenic acid Nutrition 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 229960002733 gamolenic acid Drugs 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
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- Medicines Containing Plant Substances (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
本发明公开了一种用于超临界CO2萃取枸杞籽油前的纯植物改性剂，乙酸乙酯100份、玉米骨提取液30-40份、穿心莲提取液3-6份、柠檬酸2-4份、VE0.5-2份、金菊花提取液0.1-2份。本发明所提供的用于超临界CO2萃取枸杞籽油前的纯植物改性剂，采用纯植物成分，对身体不仅无影响，反而可以曾加枸杞籽油的营养价值，在超临界CO2萃取前对枸杞籽粉先进行改性，可以有效提高了萃取率的同时避免了萃取后的除溶剂处理带来的麻烦。The invention discloses a pure plant modifier for supercritical CO2 extraction of wolfberry seed oil, comprising 100 parts of ethyl acetate, 30-40 parts of corn bone extract, 3-6 parts of Andrographis paniculata extract, 2 citric acid -4 parts, VE0.5-2 parts, chrysanthemum flower extract 0.1-2 parts. The pure plant modifying agent provided by the present invention for supercritical CO2 extraction of wolfberry seed oil uses pure plant ingredients, which not only has no effect on the body, but can also increase the nutritional value of wolfberry seed oil, and can be used in supercritical CO2 The wolfberry seed powder is modified before extraction, which can effectively improve the extraction rate and avoid the trouble caused by the solvent removal after extraction.
Description
技术领域 technical field
本发明涉及一种萃取工艺。 The invention relates to an extraction process.
背景技术 Background technique
枸杞籽即枸杞的种子，含有孕育生命发育和生长的丰富而全面的生物活性物质。而枸杞籽油正是以枸杞籽为原料，利用现代化萃取技术提取的，有效的保留了枸杞的多种功能成分如：亚油酸、γ-亚麻酸、VE、β-胡萝卜素、生物碱等的保健品，其中人体必需脂肪酸含量高达80%以上，不饱和脂肪酸总含量达99%，β-胡罗卜素、维生素E、有机硒、隐黄质等含量极高。 Lycium barbarum seeds, the seeds of wolfberry, contain rich and comprehensive biologically active substances that nurture life development and growth. Lycium barbarum seed oil is extracted from wolfberry seeds using modern extraction technology, effectively retaining various functional components of wolfberry such as: linoleic acid, γ-linolenic acid, VE, β-carotene, alkaloids, etc. Health care products, in which the content of essential fatty acids is as high as 80%, the total content of unsaturated fatty acids is 99%, and the content of β-carotene, vitamin E, organic selenium and cryptoxanthin is extremely high.
枸杞籽油可降低人体血浆胆固醇含量，防止血脂及动脉粥样硬化症；对高血脂所引起的高血压、冠心病有显著的缓解作用；直接参与皮肤新陈代谢，消除氧自由基，延缓皮肤衰老，加强皮肤水合功能，使皮肤柔软并富有弹性，有明显增白效果；此外，食用枸杞籽油还可以消除人体皮肤中的褐色斑、黑色素，令皮肤更有光泽，可抑制青春痘、痤疮、暗疮的再生，能缓解体力疲劳，有效改善睡眠等功效。因此，充分开发利用枸杞籽油源，对于改善我国人民的膳食结构，提高人民的生活水平有着重大的意义。 Lycium barbarum seed oil can reduce human plasma cholesterol content, prevent blood lipids and atherosclerosis; it has a significant alleviating effect on hypertension and coronary heart disease caused by hyperlipidemia; it directly participates in skin metabolism, eliminates oxygen free radicals, and delays skin aging. Strengthen the hydration function of the skin, make the skin soft and elastic, and have obvious whitening effect; in addition, eating wolfberry seed oil can also eliminate brown spots and melanin in the human skin, make the skin more shiny, and inhibit acne, acne, and acne Regeneration, can relieve physical fatigue, effectively improve sleep and other effects. Therefore, the full development and utilization of wolfberry seed oil source has great significance for improving the dietary structure of our people and improving people's living standards.
超临界CO2流体萃取（SFE）是利用超临界流体的溶解能力与其密度的关系，即利用压力和温度对超临界流体溶解能力的影响而进行的。在超临界状态下，将超临界流体与待分离的物质接触，使其有选择性地把极性大小、沸点高低和分子量大小的成分依次萃取出来。在枸杞籽油的萃取工艺中，现代更回倾向超临界CO2萃取枸杞籽油。然而，由于枸杞籽的拥有很坚固的细胞壁，所以严重影响了萃取的效率，而现有的枸杞籽结构改性剂即使能够提高萃取率，也会给后期的除溶剂带来很大的麻烦，影响油脂的品质。 Supercritical CO2 fluid extraction (SFE) is carried out by using the relationship between the dissolving power of supercritical fluid and its density, that is, using the influence of pressure and temperature on the dissolving power of supercritical fluid. In the supercritical state, the supercritical fluid is contacted with the substance to be separated, so that it selectively extracts the components of polarity, boiling point and molecular weight in sequence. In the extraction process of wolfberry seed oil, modern times are more inclined to supercritical CO 2 extraction of wolfberry seed oil. However, due to the strong cell wall of wolfberry seeds, the extraction efficiency is seriously affected, and even if the existing structure modifiers of wolfberry seeds can improve the extraction rate, it will bring great trouble to the solvent removal in the later stage. affect the quality of the oil.
发明内容 Contents of the invention
本发明要解决的技术问题是克服现有的缺陷，提供了一种可以有效提高萃取率的用于超临界CO2萃取枸杞籽油前的纯植物改性剂。 The technical problem to be solved in the present invention is to overcome the existing defects and provide a pure plant modifier for supercritical CO2 extraction of wolfberry seed oil that can effectively improve the extraction rate.
本发明的目的通过以下技术方案来具体实现： The purpose of the present invention is specifically achieved through the following technical solutions:
一种用于超临界CO2萃取枸杞籽油前的纯植物改性剂，乙酸乙酯100份、玉米骨提取液30-40份、穿心莲提取液3-6份、柠檬酸2-4份、VE 0.5-2份、金菊花提取液0.1-2份。 A pure plant modifier for supercritical CO2 extraction of wolfberry seed oil, 100 parts of ethyl acetate, 30-40 parts of corn bone extract, 3-6 parts of Andrographis paniculata extract, 2-4 parts of citric acid, 0.5-2 parts of VE, 0.1-2 parts of golden chrysanthemum extract.
作为优选方案，上述的用于超临界CO2萃取枸杞籽油前的纯植物改性剂，其组分按重量份计，乙酸乙酯100份、玉米骨提取液40份、穿心莲提取液4份、柠檬酸2.5份、VE 1.5份、金菊花提取液1份。 As a preferred version, the above-mentioned pure plant modifying agent used for supercritical CO Extraction of Lycium barbarum seed oil, its components are by weight, 100 parts of ethyl acetate, 40 parts of corn bone extract, 4 parts of Andrographis paniculata extract , 2.5 parts of citric acid, 1.5 parts of VE, and 1 part of golden chrysanthemum flower extract.
萃取前，先将枸杞籽粉与本发明纯植物改性剂充分混合，在40-60℃下搅拌1-3h后，抽滤萃取。 Before extraction, fully mix the wolfberry seed powder with the pure plant modifier of the present invention, stir at 40-60°C for 1-3 hours, and then extract by suction.
本发明的有益效果： Beneficial effects of the present invention:
本发明所提供的用于超临界CO2萃取枸杞籽油前的纯植物改性剂，采用纯植物成分，对身体不仅无影响，反而可以曾加枸杞籽油的营养价值，在超临界CO2萃取前对枸杞籽粉先进行改性，可以有效提高了萃取率的同时避免了萃取后的除溶剂处理带来的麻烦。 The pure plant modifying agent provided by the present invention for supercritical CO2 extraction of wolfberry seed oil uses pure plant ingredients, which not only has no effect on the body, but can also increase the nutritional value of wolfberry seed oil, and can be used in supercritical CO2 The wolfberry seed powder is modified before extraction, which can effectively improve the extraction rate and avoid the trouble caused by the solvent removal after extraction.
具体实施方式 Detailed ways
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。 Preferred embodiments of the present invention are described below, and it should be understood that the preferred embodiments described here are only used to illustrate and explain the present invention, and are not intended to limit the present invention.
实施例1：Example 1:
一种用于超临界CO2萃取枸杞籽油前的纯植物改性剂，乙酸乙酯100份、玉米骨提取液40份、穿心莲提取液3份、柠檬酸4份、VE 0.5份、金菊花提取液2份。 A pure plant modifier for supercritical CO2 extraction of wolfberry seed oil, 100 parts of ethyl acetate, 40 parts of corn bone extract, 3 parts of Andrographis paniculata extract, 4 parts of citric acid, 0.5 parts of VE, golden chrysanthemum Extract 2 parts.
实施例2：Example 2:
一种用于超临界CO2萃取枸杞籽油前的纯植物改性剂，乙酸乙酯100份、玉米骨提取液40份、穿心莲提取液4份、柠檬酸2.5份、VE 1.5份、金菊花提取液1份。 A pure plant modifier for supercritical CO2 extraction of wolfberry seed oil, 100 parts of ethyl acetate, 40 parts of corn bone extract, 4 parts of Andrographis paniculata extract, 2.5 parts of citric acid, 1.5 parts of VE, golden chrysanthemum 1 part extract.
实施例3：Example 3:
一种用于超临界CO2萃取枸杞籽油前的纯植物改性剂，乙酸乙酯100份、玉米骨提取液30份、穿心莲提取液6份、柠檬酸2份、VE 2份、金菊花提取液0.1份。 A pure plant modifier for supercritical CO2 extraction of wolfberry seed oil, 100 parts of ethyl acetate, 30 parts of corn bone extract, 6 parts of Andrographis paniculata extract, 2 parts of citric acid, 2 parts of VE, golden chrysanthemum Extract 0.1 part.
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。 The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art can still understand the foregoing embodiments The recorded technical solutions are modified, or some of the technical features are equivalently replaced. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6422304A (en) * | 1987-04-29 | 1989-01-25 | Univ Toronto Innovation Found | Extraction of component from granular substance |
| US20080181999A1 (en) * | 2005-12-13 | 2008-07-31 | Lanqin Yang | Water Leaching Method to Extract Oil Plant Products |
| CN101461424A (en) * | 2009-01-13 | 2009-06-24 | 江苏江大源生态生物科技有限公司 | Supercritical CO2 extraction method of medlar seed oil |
| CN102911095A (en) * | 2011-10-26 | 2013-02-06 | 江苏江大源生态生物科技有限公司 | Method for supercritical CO2 extraction of effective ingredients of Haematococcus pluvialis spore powder |
-
2013
- 2013-12-13 CN CN201310674041.4A patent/CN103710135B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6422304A (en) * | 1987-04-29 | 1989-01-25 | Univ Toronto Innovation Found | Extraction of component from granular substance |
| US20080181999A1 (en) * | 2005-12-13 | 2008-07-31 | Lanqin Yang | Water Leaching Method to Extract Oil Plant Products |
| CN101461424A (en) * | 2009-01-13 | 2009-06-24 | 江苏江大源生态生物科技有限公司 | Supercritical CO2 extraction method of medlar seed oil |
| CN102911095A (en) * | 2011-10-26 | 2013-02-06 | 江苏江大源生态生物科技有限公司 | Method for supercritical CO2 extraction of effective ingredients of Haematococcus pluvialis spore powder |
Non-Patent Citations (1)
| Title |
|---|
| 张炎强，等: "天然产物有效成分超临界流体萃取过程的强化技术", 《广东化工》, vol. 33, no. 5, 31 December 2006 (2006-12-31) * |
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