[go: up one dir, main page]

CN103717050A - Thin-type flexible thermally-cured electromagnetic shielding glue film - Google Patents

Thin-type flexible thermally-cured electromagnetic shielding glue film Download PDF

Info

Publication number
CN103717050A
CN103717050A CN201310653896.9A CN201310653896A CN103717050A CN 103717050 A CN103717050 A CN 103717050A CN 201310653896 A CN201310653896 A CN 201310653896A CN 103717050 A CN103717050 A CN 103717050A
Authority
CN
China
Prior art keywords
hot curing
electromagnetic shielding
particle
low profile
glued membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310653896.9A
Other languages
Chinese (zh)
Inventor
李成利
闫洪嘉
张鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Crown Advanced Material Co Ltd
Original Assignee
Crown Advanced Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Crown Advanced Material Co Ltd filed Critical Crown Advanced Material Co Ltd
Priority to CN201310653896.9A priority Critical patent/CN103717050A/en
Publication of CN103717050A publication Critical patent/CN103717050A/en
Pending legal-status Critical Current

Links

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention discloses a thin-type flexible thermally-cured electromagnetic shielding glue film. The film comprises a press-fit high-temperature-resistant protection membrane, a composite flexible insulating layer, thermally-cured conducting adhesive, and a release protection membrane, which are laminated sequentially from the bottom to the top. The film is extremely small in thickness and excellent in flexibility, thereby being capable of satisfying the repeated bending and sliding of a soft board during the using process. The whole shielding glue film has a relatively high heat resisting property and does not have delamination and discoloration problems after being subjected to multiple times of reflow soldering tests.

Description

A kind of low profile flexible hot curing electromagnetic shielding glued membrane
Technical field
The present invention relates to flexible circuit board technical field, relate in particular to a kind of low profile flexible hot curing electromagnetic shielding glued membrane.
Background technology
Along with consumer electronics produces brilliant develop rapidly, product function day by day perfect, in use there is the mutual interference problem of a large amount of electromagnetic signals in flexible circuit board, affects the transmission quality of the signal of telecommunication between circuit, so electromangnetic spectrum becomes inevitable.
Current at flexible circuitry board industry, be generally to change blind and head it off with electromagnetic shielding film.The electromagnetic shielding film existing on the market mainly contains following several structure:
The first structure: skin is a kind of insulating barrier, forms layer of metal conductor layer on it, the structure that is coated with conducting resinl on metal conducting layer realizes function of shielding.Owing to there being one deck continuous metal conductor layer, there is higher shielding properties, but this structure is more than frequency is increased to 1GHz, screening effectiveness declines to a great extent, and in production process technique this is more loaded down with trivial details.
If notification number is CN101448362B, name is called the ultra-thin shielding film that < < can change circuit impedance, the Chinese invention patent of circuit board and preparation method thereof > >, and notification number is CN101176388A, name is called < < screened film, shielded printed circuit board, shielded flexible printed circuit board, the Chinese invention patent of method of manufacturing shielding film and method of manufacturing shielded printed circuit board > >, all adopt the first structure, there is certain deficiency.
The second structure: skin is metal conducting layer, internal layer is conductive adhesive layer, if publication number is CN1842245A, name is called < < with the electronic building brick of conductive layer and the Chinese invention patent of conductive adhesive film and its manufacture method > >, this material is not owing to there is no insulating barrier, and the scope of application is subject to certain limitation.
The third structure: sputter layer of metal target on film, or the copper-clad surface coating conducting resinl in the copper-clad plate of the thin property of one deck single-sided flexible, if notification number is CN1819758A, name is called the Chinese invention patent of < < double electromagnetic shielding membrane > >, notification number is CN101521985A, name is called < < shielding construction and has the Chinese invention patent of the flexible printed circuit board > > of this shielding construction.These 2 kinds of structure fabrication technique more complicated, to equipment requirement, this is higher, and cost is high, nocompetitive.
Several structures, having problem more or less aspect shielding properties, bending property, production technology, cost, have certain gap with light, thin, the short and small instructions for use of flexible circuit board above.
Summary of the invention
The present invention is in order to solve the above-mentioned deficiency of prior art, proposed a kind of anti-children that lift sleep by.
In order to solve the problems of the technologies described above; the present invention is by the following technical solutions: a kind of low profile flexible hot curing electromagnetic shielding glued membrane, comprises from bottom to up the superimposed successively high temperature resistant diaphragm of pressing, composite and flexible insulating barrier, hot curing conductive adhesive and release diaphragm.
Described pressing is high temperature resistant, and diaphragm is one or more compound the making in MODIFIED PP film, PET film, PEN film, PI film.
Described composite and flexible insulating barrier is by flexible insulating layer and compound the making of soft magnetism powder thin layer.
Described flexible insulating layer is that one or more in acrylic resin, epoxy resin, polyimide based resin, Modified Epoxy Resin by Elastomers, rubber-like acrylate, alkyd based resin, phenolic resinoid and carbamate resinoid are compounded to form.
Described soft magnetism powder thin layer is that one or more in iron Si system alloy, iron aluminum series alloy, iron silicon aluminum series alloy, nickel iron-based alloy, iron Co-based alloy, soft magnetic ferrite, amorphous soft magnetic alloy and super-microcrystalline soft magnetic alloy are combined to form, and this soft magnetism powder thin layer thickness is 0.1um to 1um.
One or more in acrylic resin, epoxy resin, polyimide based resin, Modified Epoxy Resin by Elastomers, rubber-like acrylate, alkyd based resin, phenolic resinoid and carbamate resinoid of described hot curing conductive adhesive are compounded to form, and conducting particles in this hot curing conductive adhesive fusion.
Described conducting particles comprises carbon powder particle, silver-colored particle, nickel, copper particle, nickel gold grain, copper nickel particle, silver-colored copper-clad particle, silver-colored nickel coat particle, nickel gold grain, silver bag plastic grain and Yin Bao glass particle, and the average diameter of described conducting particles is 1um to 20um.
According to actual service condition, hot curing conductive adhesive is preferentially selected epoxy resin and the acrylic resin that hot curing performance is good, the thickness of hot curing conductive adhesive is preferentially selected 5um to 30um, conducting particles is from the viewpoint of cost and the silver-colored copper-clad of the preferential selection of conductivity, the average diameter of conducting particles is preferentially selected 1um to 20um, and the proportion of conducting particles and glue is preferentially selected 20%-100%.
A kind of manufacture method of low profile flexible hot curing electromagnetic shielding glued membrane comprises following steps:
The first, on the high temperature resistant diaphragm of pressing, form composite and flexible insulating barrier;
The second, on composite and flexible insulating barrier, form conductive layer;
The 3rd, on conductive layer, there is release diaphragm.
Compared with prior art, the present invention has thickness as thin as a wafer, excellent pliability, can meet bending repeatedly and slip in soft board use procedure, and have higher peel strength, whole screened film has higher thermal endurance, through multi-reflow, not delamination nondiscolouring is tested in weldering.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Embodiment
Below in conjunction with drawings and Examples, invention is described in detail.
Embodiment 1
As shown in Figure 1; pressing is high temperature resistant, and diaphragm 105 selection thickness are on 25um to 100um; by coating method, form flexible insulating layer 104, flexible insulating layer adopts the mixture of acrylic resin, epoxy resin, polyimide based resin, Modified Epoxy Resin by Elastomers, rubber-like esters of acrylic acid and phenolic resinoid.
On flexible insulating layer 104, by chemical plating mode, electron gun evaporation plating, sputter plating, plating or its combination process, form soft magnetism powder thin layer 103, thickness is 0.1um to 1um, whole composite and flexible insulating barrier 106 comprises soft magnetism powder thin layer 103 and flexible insulating layer 104, and gross thickness is at 10um to 30um.
On composite and flexible insulating barrier 106, form hot curing conductive adhesive 102, hot curing conductive adhesive is the mixture of olefin(e) acid esters resin, epoxy resin, Modified Epoxy Resin by Elastomers, rubber-like acrylate, phenolic resinoid, the conducting particles wherein adding is carbon dust, silver, nickel, copper particle, nickel gold, copper nickel, silver-colored copper-clad, silver-colored nickel coat, the plastic material of nickel gold, silver, silver bag glass particle, for a kind of or two kinds of above mixtures wherein, conducting particles is from the viewpoint of cost and the silver-colored copper-clad of the preferential selection of conductivity.The thickness of hot curing conductive adhesive 102 is 5um to 30um, and the proportion of conducting particles and glue is preferentially selected 20%-100%.
On hot curing conductive adhesive 102, be compounded with release protective film 101, thickness is 25um to 100um, and material is polyester, mainly protects conductive adhesive not contaminated.Thermal endurance and pressing are high temperature resistant, and diaphragm 105 has gap, and it is indeformable that the latter can carry out 170 ℃ to 190 ℃ pressings.
Embodiment 2 to embodiment 3, and what composite insulation layer resin all adopted is the improved epoxy resin of special process, and the thickness of this resin bed coating is different, and conductive layer resin is ordinary hot thermoset epoxy resin, adds partially modified resin, and thickness is different.
Comparative example 1 and this is example 2, and the matrix resin of composite insulation layer is replaced by LNBR modified epoxy, and other are all identical with embodiment.Concrete testing differentia sees table 1.
In embodiment and comparative example, due to the difference of matrix resin that composite insulation layer adopts, cause the slip test of whole electromagnetic shielding glued membrane to have great difference.Use the epoxy resin of the mixing modification of special process to guarantee splendid flexible, can meet flexible circuit board bending, slide and use.Aspect screening effectiveness, because conductive layer is consistent with soft magnetism powder film layer structure, no significant difference, all can meet user demand.Aspect the peel strength with lamination matrix Copper Foil, all show good adhesive force, meet instructions for use.
Above-described embodiment has only been expressed several execution mode of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, patent of the present invention and protection range should be as the criterion with appended claims.

Claims (7)

1. a low profile flexible hot curing electromagnetic shielding glued membrane, is characterized in that: comprise from bottom to up the superimposed successively high temperature resistant diaphragm of pressing, composite and flexible insulating barrier, hot curing conductive adhesive and release diaphragm.
2. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 1, is characterized in that: described pressing is high temperature resistant, and diaphragm is one or more compound the making in MODIFIED PP film, PET film, PEN film, PI film.
3. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 1, is characterized in that: described composite and flexible insulating barrier is by flexible insulating layer and compound the making of soft magnetism powder thin layer.
4. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 3, is characterized in that: described flexible insulating layer is that one or more in acrylic resin, epoxy resin, polyimide based resin, Modified Epoxy Resin by Elastomers, rubber-like acrylate, alkyd based resin, phenolic resinoid and carbamate resinoid are compounded to form.
5. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 3, it is characterized in that: described soft magnetism powder thin layer is that one or more in iron Si system alloy, iron aluminum series alloy, iron silicon aluminum series alloy, nickel iron-based alloy, iron Co-based alloy, soft magnetic ferrite, amorphous soft magnetic alloy and super-microcrystalline soft magnetic alloy are combined to form, and this soft magnetism powder thin layer thickness is 0.1um to 1um.
6. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 1, it is characterized in that: one or more in acrylic resin, epoxy resin, polyimide based resin, Modified Epoxy Resin by Elastomers, rubber-like acrylate, alkyd based resin, phenolic resinoid and carbamate resinoid of described hot curing conductive adhesive are compounded to form, and conducting particles in this hot curing conductive adhesive fusion.
7. low profile flexible hot curing electromagnetic shielding glued membrane as claimed in claim 6, it is characterized in that: described conducting particles comprises carbon powder particle, silver-colored particle, nickel, copper particle, nickel gold grain, copper nickel particle, silver-colored copper-clad particle, silver-colored nickel coat particle, nickel gold grain, silver bag plastic grain and Yin Bao glass particle, and the average diameter of described conducting particles is 1um to 20um.
CN201310653896.9A 2013-12-03 2013-12-03 Thin-type flexible thermally-cured electromagnetic shielding glue film Pending CN103717050A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310653896.9A CN103717050A (en) 2013-12-03 2013-12-03 Thin-type flexible thermally-cured electromagnetic shielding glue film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310653896.9A CN103717050A (en) 2013-12-03 2013-12-03 Thin-type flexible thermally-cured electromagnetic shielding glue film

Publications (1)

Publication Number Publication Date
CN103717050A true CN103717050A (en) 2014-04-09

Family

ID=50409468

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310653896.9A Pending CN103717050A (en) 2013-12-03 2013-12-03 Thin-type flexible thermally-cured electromagnetic shielding glue film

Country Status (1)

Country Link
CN (1) CN103717050A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105517422A (en) * 2016-01-15 2016-04-20 深圳市金凯新瑞光电股份有限公司 Composite film material
CN107227120A (en) * 2017-07-20 2017-10-03 海宁卓泰电子材料有限公司 A kind of electromagnetic shielding film and preparation method thereof
CN107513351A (en) * 2017-10-11 2017-12-26 广东正业科技股份有限公司 A kind of electromagnetic shielding film and preparation method thereof
CN108297502A (en) * 2017-01-13 2018-07-20 上海量子绘景电子股份有限公司 A kind of the FCCL materials and its manufacturing method of soft magnetic materials base material
CN108928056A (en) * 2018-08-01 2018-12-04 京东方科技集团股份有限公司 Membrane material and preparation method thereof, display base plate
CN110556195A (en) * 2019-09-09 2019-12-10 常州斯威克光伏新材料有限公司 Dampproofing anti warpage encapsulation glued membrane
WO2020020195A1 (en) * 2018-07-25 2020-01-30 深圳市弘海电子材料技术有限公司 Fpc electromagnetic shielding film with polyimide film as insulating layer, and preparation method therefor
CN111697517A (en) * 2020-07-01 2020-09-22 睿惢思工业科技(苏州)有限公司 Manufacturing method of flexible cable shielding grounding device
CN116072010A (en) * 2021-11-02 2023-05-05 武汉华星光电半导体显示技术有限公司 Splicing display panels and display devices
CN116179103A (en) * 2023-01-29 2023-05-30 深圳雷曼光电科技股份有限公司 Magnetic anisotropic conductive adhesive film and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1819211A1 (en) * 2004-12-03 2007-08-15 Nitta Corporation Electromagnetic interference inhibitor, antenna device and electronic communication apparatus
CN101704312A (en) * 2009-11-06 2010-05-12 电子科技大学 Composite electromagnetic shield materials and method for preparing same
CN102300399A (en) * 2011-07-12 2011-12-28 祝琼 Multifunctional laminated electronic diaphragm and production method thereof
CN102711428A (en) * 2012-06-21 2012-10-03 广州方邦电子有限公司 Ultrathin shielding film with high shielding efficiency and production method thereof
CN103002725A (en) * 2011-09-16 2013-03-27 藤森工业株式会社 Electromagnetic wave shielding material for FPC
US20130206315A1 (en) * 2010-06-23 2013-08-15 Inktec Co., Ltd. Method for Manufacturing Electromagnetic Interference Shielding Film

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1819211A1 (en) * 2004-12-03 2007-08-15 Nitta Corporation Electromagnetic interference inhibitor, antenna device and electronic communication apparatus
CN101704312A (en) * 2009-11-06 2010-05-12 电子科技大学 Composite electromagnetic shield materials and method for preparing same
US20130206315A1 (en) * 2010-06-23 2013-08-15 Inktec Co., Ltd. Method for Manufacturing Electromagnetic Interference Shielding Film
CN102300399A (en) * 2011-07-12 2011-12-28 祝琼 Multifunctional laminated electronic diaphragm and production method thereof
CN103002725A (en) * 2011-09-16 2013-03-27 藤森工业株式会社 Electromagnetic wave shielding material for FPC
CN102711428A (en) * 2012-06-21 2012-10-03 广州方邦电子有限公司 Ultrathin shielding film with high shielding efficiency and production method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105517422A (en) * 2016-01-15 2016-04-20 深圳市金凯新瑞光电股份有限公司 Composite film material
CN108297502A (en) * 2017-01-13 2018-07-20 上海量子绘景电子股份有限公司 A kind of the FCCL materials and its manufacturing method of soft magnetic materials base material
CN107227120A (en) * 2017-07-20 2017-10-03 海宁卓泰电子材料有限公司 A kind of electromagnetic shielding film and preparation method thereof
CN107513351A (en) * 2017-10-11 2017-12-26 广东正业科技股份有限公司 A kind of electromagnetic shielding film and preparation method thereof
WO2020020195A1 (en) * 2018-07-25 2020-01-30 深圳市弘海电子材料技术有限公司 Fpc electromagnetic shielding film with polyimide film as insulating layer, and preparation method therefor
CN108928056A (en) * 2018-08-01 2018-12-04 京东方科技集团股份有限公司 Membrane material and preparation method thereof, display base plate
CN110556195A (en) * 2019-09-09 2019-12-10 常州斯威克光伏新材料有限公司 Dampproofing anti warpage encapsulation glued membrane
CN111697517A (en) * 2020-07-01 2020-09-22 睿惢思工业科技(苏州)有限公司 Manufacturing method of flexible cable shielding grounding device
CN116072010A (en) * 2021-11-02 2023-05-05 武汉华星光电半导体显示技术有限公司 Splicing display panels and display devices
WO2023077546A1 (en) * 2021-11-02 2023-05-11 武汉华星光电半导体显示技术有限公司 Spliced display panel and display apparatus
US12205929B2 (en) 2021-11-02 2025-01-21 Wuhan China Star Optoelectronics Semiconductor Display Technology Co., Ltd. Spliced display panel and display device
CN116179103A (en) * 2023-01-29 2023-05-30 深圳雷曼光电科技股份有限公司 Magnetic anisotropic conductive adhesive film and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN103717050A (en) Thin-type flexible thermally-cured electromagnetic shielding glue film
CN108323144B (en) Electromagnetic shielding film, circuit board and preparation method of electromagnetic shielding film
CN108323143B (en) Electromagnetic shielding film, circuit board and preparation method of electromagnetic shielding film
KR20140142708A (en) Ultrathin shielding film of high shielding effectiveness and manufacturing method therefor
CN104885587B (en) Electromagnetic wave absorbing plate, manufacturing method thereof, and electronic device including same
US9609792B2 (en) Electromagnetic wave shielding film and method for producing a circuit board comprising the shielding film
CN101448362B (en) Ultra-thin shielding film and circuit board capable of changing circuit impedance, and method for preparing same
CN102510712B (en) Ultra-thin shielding film of a kind of high screening effectiveness and preparation method thereof
KR101931274B1 (en) Electrically conductive sheet and process for producing same, and electronic component
KR101160497B1 (en) Flat cable
CN108495543B (en) Electromagnetic wave shielding film, method for manufacturing printed circuit board, and method for manufacturing electromagnetic wave shielding film
CN105246313B (en) A kind of electromagnetic shielding film, the preparation method containing the printed wiring board of the screened film and the wiring board
CN202635003U (en) Ultrathin shielding film with high shielding effectiveness
TWI881197B (en) Matte type electromagnetic interference shielding film and preparation method thereof
CN105578851A (en) Thin-type high-transmission electromagnetic-absorbing screened film and manufacturing method thereof
WO2017010447A1 (en) Ferrite laminate and noise suppression sheet
KR20180071072A (en) Metal composite sheet
KR102442175B1 (en) Alloy Film Shielding Electromagnetic Field by Frequency Band and Manufacturing Method Thereof
CN110769667B (en) Electromagnetic shielding film, circuit board and preparation method of electromagnetic shielding film
CN110691499B (en) Electromagnetic shielding film, circuit board and preparation method of electromagnetic shielding film
KR102459013B1 (en) Electromagnetic wave absorber and preparing method thereof
CN203157257U (en) Compound type copper foil base plate with electromagnetic shielding effect
KR102458691B1 (en) FCCL and FPCB Cable for RF
CN201332571Y (en) Super-thin screened film capable of changing circuit impedance and circuit board
TWM527127U (en) Structure of cover film

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140409