CN1035649A - The manufacture method of mineral water enriched material - Google Patents
The manufacture method of mineral water enriched material Download PDFInfo
- Publication number
- CN1035649A CN1035649A CN 88105224 CN88105224A CN1035649A CN 1035649 A CN1035649 A CN 1035649A CN 88105224 CN88105224 CN 88105224 CN 88105224 A CN88105224 A CN 88105224A CN 1035649 A CN1035649 A CN 1035649A
- Authority
- CN
- China
- Prior art keywords
- enriched material
- mineral water
- water
- mineral
- hydrochloric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 24
- 239000011707 mineral Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004575 stone Substances 0.000 claims abstract description 11
- 239000006228 supernatant Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 238000007738 vacuum evaporation Methods 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims abstract 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229910052626 biotite Inorganic materials 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims 1
- 235000010755 mineral Nutrition 0.000 abstract description 19
- 239000011573 trace mineral Substances 0.000 abstract description 7
- 235000013619 trace mineral Nutrition 0.000 abstract description 7
- 230000009286 beneficial effect Effects 0.000 abstract description 6
- 239000000047 product Substances 0.000 abstract description 5
- 238000001556 precipitation Methods 0.000 abstract description 4
- 238000010790 dilution Methods 0.000 abstract description 3
- 239000012895 dilution Substances 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract description 2
- 239000012141 concentrate Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 239000002253 acid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229910052892 hornblende Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
Landscapes
- Non-Alcoholic Beverages (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The present invention is a kind of method of being made the mineral water enriched material by the Laoshan medical stone.Wherein the ore with certain particle size mixes with the polymer solution in water of dilute hydrochloric acid or hydrochloric acid, behind the reaction certain hour, tells its supernatant liquor, concentrates with vacuum-evaporation after filtration and promptly obtains the mineral water enriched material.This enriched material can fully dissolve and not have precipitation promptly drinkable through dilution.Production method is simple, and is cheap, and product is convenient to transportation, and is wherein contained to people's beneficial trace elements A wide selection of colours and designs, the content height, and harmful element concentration is extremely low.
Description
The invention belongs to water-treatment technology field.
Utilization contains the natural mineral of multiple element, porousness mineral processing water particularly, absorption (comprising the mineral ion exchange) effect and Decomposition by mineral, can reduce deleterious composition in the water, stripping by mineral can make the trace element that increases in the water the human body beneficial, and this method is known already.Here foremost in the said natural mineral is exactly medical stone." medical stone " speech derives from Compendium of Material Medica one book that China Ming Dynasty medicine great master LI Shi-Zhen is shown, and the back is that the Japanese is used often.Refer to quartz porphyry in Japan, in fact it can comprise many natural porousness mineral, and hornblende andesite, quartzy diorite-porphyrite etc. are wherein just arranged more.Mentioning with trachyandesite in the J57-207592 patent is porousness mineral processing tap water, the effect that has absorption to remove objectionable impurities and chlorine.In the J61-1195 patent, mention the method for handling tap water and well water with quartzy diorite-porphyrite or hornblende andesite, comprising ore is immersed in the water, and use ultrasonic irradiation.The data of relevant treating water income effect is not provided in last patent, in one patent of back, has only SiO in the treated water yet
2With the data of residual chlorine content, PH and taste, but also not mentioned to human body beneficial's trace element.
The objective of the invention is to,, make every effort to utilize the most reasonable and effective treatment process and the mineral water that obtains to be of value to HUMAN HEALTH near the medical stone of Qingdao, finding (, mainly being biotite asperities andesitic porphyrite) hereinafter referred to as the Laoshan medical stone.
For this reason, the present invention adopts the Laoshan medical stone to handle distilled water and tap water etc., and has made the mineral water enriched material, and it contains the element more than 24 kinds, and wherein beneficial trace elements is dense, and the microelement concentration that is pernicious to people is very low.Concrete grammar is as follows:
1, the Laoshan medical stone with fragmentation is crushed to certain particle size with ball mill, for example the 120-200 order;
2, the certain density HCl aqueous solution of preparation and polymer solution in water; Acid concentration will be hanged down, and acid concentration is big, and iron stripping just are easy to produce precipitation more;
3, the above-mentioned acid solution a certain amount of above-mentioned chippy Laoshan medical stone and certain volume is mixed in a container, and is stirred every now and then, makes it fully react (time generally needs 6-8 hour);
When 4, treating that supernatant liquor is neutral (PH=6.5-7.0), tell supernatant liquor, and it is used filter paper filtering.The mineral precipitation that leaches can be handled once with acid solution again;
5, above-mentioned gained filtrate is carried out at a certain temperature vacuum-evaporation and concentrate, be concentrated to stoste about 1/100, be the mineral water enriched material.This product mainly is a liquid, also contains small amounts of solid matter.A large amount of crystal will occur during as further evaporation, we think that it is much better that the enriched material ratio is entirely crystal.
By the mineral water enriched material that the present invention makes, promptly drinkable with suitable quantity of water (for example in 1 gram enriched material, adding 2000ml water) dilution, meet the drinking water standard that United Nations's health organization is stipulated fully.During dilution, original solids dissolving does not produce new precipitation yet, and can keep PH neutrality.Make the mineral water enriched material by the present invention, method is simple, and beneficial trace elements is very fast by stripping in the ore, save time, and product price is cheap.Because healthy trace elements with household A wide selection of colours and designs in the enriched material, so drinking of said product is for because of lacking the multiple endemy that some beneficial element suffers from obvious curative effects being arranged.The mineral water that the concentration ratio of healthy trace elements with household is general in this product is high about 2000 times, helps carrying or transporting, and is convenient to family or tourism use.
Embodiment 1
In the beaker of 3000ml, add 1000 grams, 200 purpose Laoshan medical stones, adding concentration is 0.16% hydrochloric acid soln 2000ml, stirring makes its mixing, react 7 hours to supernatant liquor PH be 7.0, shift supernatant liquor, and use filter paper filtering, and analyze the content of some elements in the filtrate, the results are shown in table 1.Supernatant liquor is carried out vacuum-evaporation be concentrated into the supernatant liquid measure under 50 ℃
The content of some elements (ppm) in table 1 supernatant liquor
| K?171.88 Na?280.00 Ca?1735 Mg?715.0 Mn?104.5 Fe?1532 Al?0.124 Zn?3.26 Sr?0.570 V?0.020 | Co?0.069 Mo T SiO 264 (solubility) Se, 0.055 B, 0.105 Cu, 1.29 Cr, 0.066 Ni, 0.224 Ti 0.020 | PO 4?0.01 Pb t Hg t As?0.47 Cd?0.06 |
* t represents trace in the table
1/100, get the mineral water enriched material, its analytical results is as shown in table 2.
Embodiment 2
Change hydrochloric acid soln among the embodiment 1 into acid concentration identical polymer solution in water, all the other are fully identical with embodiment 1, and the result is similar for gained.
T represents trace in the table
Claims (3)
1, a kind of method of making the mineral water enriched material with the medical stone treating water, it is characterized in that used medical stone is a biotite asperities andesitic porphyrite, when making mineral water, it is mixed with the aqueous solution or the polymer solution in water of HCl, behind the reaction certain hour, tell supernatant liquor, filter, and its vacuum-evaporation is concentrated;
2, the method for manufacturing mineral water enriched material as claimed in claim 1 is characterized in that described concentration of hydrochloric acid solution is preferably 0.16%
3,, it is characterized in that the reaction times is (6～8) hour by the method for the described manufacturing mineral water of claim 1 enriched material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105224 CN1035649A (en) | 1988-03-11 | 1988-03-11 | The manufacture method of mineral water enriched material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105224 CN1035649A (en) | 1988-03-11 | 1988-03-11 | The manufacture method of mineral water enriched material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1035649A true CN1035649A (en) | 1989-09-20 |
Family
ID=4833438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88105224 Pending CN1035649A (en) | 1988-03-11 | 1988-03-11 | The manufacture method of mineral water enriched material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1035649A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102550603A (en) * | 2010-12-29 | 2012-07-11 | 北京市松浦经贸发展公司 | Extraction method of mineral concentrate for environmental restoration and application thereof |
| CN104229916A (en) * | 2013-06-06 | 2014-12-24 | 济南大学 | Method for adsorption of heavy metal lead ions by andesitic porphyrite mineral |
| WO2019024127A1 (en) * | 2017-07-31 | 2019-02-07 | 席坚一 | Functional mineral water and preparation method therefor |
-
1988
- 1988-03-11 CN CN 88105224 patent/CN1035649A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102550603A (en) * | 2010-12-29 | 2012-07-11 | 北京市松浦经贸发展公司 | Extraction method of mineral concentrate for environmental restoration and application thereof |
| CN102550603B (en) * | 2010-12-29 | 2014-03-05 | 北京市松浦经贸发展公司 | Extraction method of mineral concentrate for environmental restoration and application thereof |
| CN104229916A (en) * | 2013-06-06 | 2014-12-24 | 济南大学 | Method for adsorption of heavy metal lead ions by andesitic porphyrite mineral |
| WO2019024127A1 (en) * | 2017-07-31 | 2019-02-07 | 席坚一 | Functional mineral water and preparation method therefor |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |