CN102318635A - Preparation method of compound leather bactericidal and mildew-proof agent - Google Patents
Preparation method of compound leather bactericidal and mildew-proof agent Download PDFInfo
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- CN102318635A CN102318635A CN201110224058A CN201110224058A CN102318635A CN 102318635 A CN102318635 A CN 102318635A CN 201110224058 A CN201110224058 A CN 201110224058A CN 201110224058 A CN201110224058 A CN 201110224058A CN 102318635 A CN102318635 A CN 102318635A
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- 239000010985 leather Substances 0.000 title claims abstract description 33
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 150000001875 compounds Chemical class 0.000 title abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- 238000005260 corrosion Methods 0.000 claims abstract description 22
- 239000003112 inhibitor Substances 0.000 claims abstract description 22
- 238000003756 stirring Methods 0.000 claims abstract description 22
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 230000007797 corrosion Effects 0.000 claims abstract description 21
- -1 guanidine compound Chemical class 0.000 claims abstract description 20
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims abstract description 19
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000010790 dilution Methods 0.000 claims abstract description 5
- 239000012895 dilution Substances 0.000 claims abstract description 5
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 20
- 229920002413 Polyhexanide Polymers 0.000 claims description 19
- KGAZPXNFWZDYHC-UHFFFAOYSA-N azane;butyl formate Chemical compound N.CCCCOC=O KGAZPXNFWZDYHC-UHFFFAOYSA-N 0.000 claims description 19
- 125000002346 iodo group Chemical group I* 0.000 claims description 19
- 239000000126 substance Substances 0.000 claims description 16
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 12
- 238000013329 compounding Methods 0.000 claims description 12
- 229960004025 sodium salicylate Drugs 0.000 claims description 12
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 11
- 235000010234 sodium benzoate Nutrition 0.000 claims description 11
- 239000004299 sodium benzoate Substances 0.000 claims description 11
- VAZJLPXFVQHDFB-UHFFFAOYSA-N 1-(diaminomethylidene)-2-hexylguanidine Polymers CCCCCCN=C(N)N=C(N)N VAZJLPXFVQHDFB-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000003556 assay Methods 0.000 claims description 6
- MSXHSNHNTORCAW-GGLLEASOSA-M sodium;(2s,3s,4s,5r,6s)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O MSXHSNHNTORCAW-GGLLEASOSA-M 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- AJZDHLHTTJRNQJ-UHFFFAOYSA-N 3-[4-(aminomethyl)-6-(trifluoromethyl)pyridin-2-yl]oxy-N-[2-(tetrazol-1-yl)ethyl]benzamide Chemical compound N1(N=NN=C1)CCNC(C1=CC(=CC=C1)OC1=NC(=CC(=C1)CN)C(F)(F)F)=O AJZDHLHTTJRNQJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 4
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 abstract 3
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 abstract 3
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 abstract 3
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000645 desinfectant Substances 0.000 description 6
- 241000233866 Fungi Species 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 241000195493 Cryptophyta Species 0.000 description 3
- 241000235342 Saccharomycetes Species 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
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- 239000008235 industrial water Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- 229940051866 mouthwash Drugs 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
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- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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- 238000004065 wastewater treatment Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention aims to provide a compound leather bactericidal and mildew-proof agent, and in particular provides a preparation method taking the composition of a guanidine compound, 2-bromo-2-nitro-1,3-propanediol, 3-iodo-2-propynyl butylcarbamate, ethylenediaminetetraacetic acid (EDTA) B, a corrosion inhibitor, ethanol and water as the compound leather bactericidal and mildew-proof agent. The compound leather bactericidal and mildew-proof agent comprises the following components by mass percent: 1-15% of guanidine compound, 0.05-3% of EDTA B, 0.1-2% of 2-bromo-2-nitro-1,3-propanediol, 1-50% of ethanol, 0.05-5% of 3-iodo-2-propynyl butylcarbamate, 0.1-20% of corrosion inhibitor and the balance of water. The preparation method is characterized by comprising the following steps of: mixing the guanidine compound, the 2-bromo-2-nitro-1,3-propanediol and the EDTA B with 50% of water by mass percent, and stirring the mixture for 3 hours to prepare a mixture A; mixing the 3-iodo-2-propynyl butylcarbamate, the corrosion inhibitor and the ethanol with the residual 50% of water by mass percent, and stirring the mixture for 3 hours to prepare a mixture B; and stirring the mixture A and the mixture B to react for 2 hours, then standing for 2 hours, determining the content of the mixture of the mixture A and the mixture B, and packaging the qualified mixture, thus obtaining a qualified product. The invention also aims to dilute the compound leather bactericidal and mildew-proof agent, and the dilution ratio is 50-500 times.
Description
Technical field
The invention belongs to the disinfection product scope; Relate to the preparation of a kind of leather composite bactericidal mildew-resistant; Especially a kind of with guanidine compound, 2-bromo-2-nitro-1, the composition of ammediol, iodo propinyl ammonia butyl formate, the upright imperial B of holder, corrosion inhibiter, second alcohol and water is as the preparation of leather composite bactericidal mould inhibitor.
Background technology
Nutriment such as rich in proteins, fat in the leather material very easily receives the intrusion of microorganism in the preservation process, in process, go mouldy easily, in process, adds a large amount of fatting agents simultaneously, also is the hotbed of microbial growth procreation.
The porous of leather structure and polar structure make its easy moisture absorption, make leather be acid, and these factors have constituted the primary condition of going mouldy.The leather that goes mouldy is white in color, the bacterium colony and the color spot of blueness and black, and the mould on surface is along with the time can make wearability, intensity and the elasticity effect of leather to the in-house development of leather.In sum, mould has brought the outside of leather and inside and has seriously influenced, and the control mould is necessary.
Fungus and mildew resistance is the important step of leather industry, selects a kind of mould inhibitor of high effect nontoxic environmental protection to be inevitable.
It is not too desirable that existing industrial fungus and mildew resistance product is handled the leather biocide mildew-resistant, has only the composite synergistic of utilization could realize bactericidal mould proof effect.
Summary of the invention
The objective of the invention is to provides a kind of preparation of leather composite bactericidal mould inhibitor to the various drawbacks of existing biocide mildewcide with for solving the technical problem that exists in the known technology; Especially with guanidine compound, 2-bromo-2-nitro-1; The composition of ammediol, iodo propinyl ammonia butyl formate, the upright imperial B of holder, corrosion inhibiter, second alcohol and water is as the preparation of leather composite bactericidal mould inhibitor, and it has characteristics such as safety, efficient, wide spectrum, low toxicity, environmental protection.
One of the object of the invention provides a kind of leather composite bactericidal mould inhibitor, and it contains following component by mass percent:
| Component | Mass percent % |
| Guanidine compound | 1-15 |
| Tuo Lilong B | 0.05-3 |
| 2-bromo-2-nitro-1, ammediol | 0.1-2 |
| Iodo propinyl ammonia butyl formate | 0.05-5 |
| Ethanol | 1-50 |
| Corrosion inhibiter | 0.1-20 |
| Water | Surplus |
Guanidine compound described in the component is selected from: the mixture of one or more in polyhexamethylene guanide, the poly hexamethylene biguanide etc., or one or more mixture of above-mentioned guanidine compound pharmaceutically acceptable salt.
Wherein the hydrochloride in the polyhexamethylene guanide is a kind of white amorphous powder, and no special odor is soluble in water, and the aqueous solution is colourless to faint yellow, tasteless, does not fire not quick-friedly, and metal material is not had corrosion basically, and decomposition temperature is greater than 400 ℃, and molecular formula is (C
7H
16N
3Cl)
n, to the handle no discoloration in surface, undergoing no deterioration in 2 years, the aqueous solution of 0.1 % concentration has the taste of little hardship.Very extensive in the every field application, can be used as the candida albicans disinfectant of various body surfaces, and can make daily mould inhibitor; Can be widely used in beverage and food-processing industry; Drinking water and swimming pool; Lake water, pool, cooling tower, fountain, remove algae, oil exploitation, construction material mildewproof additive; Plant's sterilization, and be used for textile industry, paper-making industry, wood-processing industry, rubber industry, agricultural etc., also can be used as the flocculant of waste water treatment.
Hexamethylene wherein; Its colorless and odorless, water-soluble fully, stable in properties; Its bactericidal mechanism is different with chlorine-containing disinfectant, and strong oxidation reaction does not take place in the sterilization process, produces precipitation in the cell; The quantity of endocellular phosphorus rises simultaneously, thereby block cell wall and nucleic acid is synthetic; Reduce the cell permeability of the membrane, stop phosphorus to cell exocrine, and the ability bind protein, this disinfectant is widely used in pharmaceuticals industry, has when reporting it as mouthwash, and is very strong to the Gram-negative bacteria property killed.
2-bromo-2-nitro-1 described in the component, ammediol, it is white or canescence crystalline powder; Fusing point is greater than 120 ℃; Soluble in water, have the high-efficiency broad spectrum antibacterial activity, be widely used as cosmetics preservative; Also as agriculture chemicals fungicide, medical disinfectant, with the composite industrial water conditioning agent etc. that also can be used as of other preservatives.
The upright imperial B of holder described in the component is white crystalline powder, and is water-soluble, is insoluble in alcohol, as complexing agent, chelating agent, preservative, anti-oxidant synergist and auxiliary agent.
Iodo propinyl ammonia butyl formate described in the component is a white crystalline powder; Water insoluble; Be soluble in the lower alcohols organic solvent, broad-spectrum sterilization can effectively be killed mould, saccharomycete, algae and bacterium; Fungi there is special efficacy; Be mainly used in cosmetics, household chemicals, paint, leather, plastics, timber, metal cutting solution, Wood Discoloration control, textile, paper-making industry, ink, adhesive etc., with 2-bromo-2-nitro-1, ammediol uses simultaneously and reaches better anti-mold effect.
Corrosion inhibiter described in the component is selected from: the mixture of one or more in Sodium Benzoate, gluconic acid sodium salt, the sodium salicylate etc.
Wherein Sodium Benzoate another name sodium benzoate is white particle or crystalline powder, and odorless is with benzoic smell slightly, and is water-soluble.In water treatment, be used as corrosion inhibiter, food preservative, metallic weapon antirust with emulsion paint, shoe polish, synthetic glue powder fungusproof anti-corrosion agent, the preservative of cosmetics.
Wherein gluconic acid sodium salt another name hexonic acid sodium is white or light yellow crystalline powder, and fragrant smell is arranged, and is water-soluble, also plays the chelation to metal ion, is used as corrosion inhibiter simultaneously.
Wherein sodium salicylate is called septichen sodium, and white flakey or powder crystal are soluble in water, and certain bactericidal action is arranged, and fungi is had good inhibitory effect, can be used as corrosion inhibiter simultaneously.
Water described in the component is deionized water.
Each component is role in the present invention:
Guanidine compound described in the component belongs to cationic surfactant, is low effect disinfectants, has quick-acting bactericidal actions, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, receives organic substance influence slight, good stability;
2-bromo-2-nitro-1 described in the component, ammediol is a disinfectant, broad spectrum antibiotic activity can effectively suppress Gram-negative bacteria, positive bacteria, saccharomycete and mould;
The upright imperial B of holder described in the component has chelating, complexing and synergistic effect, can remove the Ca that exists in the water
2+, Mg
2+, Fe
2+, Mn
2+Deng metal ion, reach purification;
Ethanol described in the component has synergistic effect, has hydrotropy and antifreeze effect simultaneously;
Corrosion inhibiter described in the component plays the corrosion inhibition good to metallic article, and the effect of certain inhibition bacterium is arranged simultaneously, to mucocutaneous non-stimulated, good stability is harmless to article;
Iodo propinyl ammonia butyl formate described in the component is a wide-spectrum bactericide, can effectively kill mould, saccharomycete, algae and bacterium, and fungi is had special efficacy, to mucocutaneous nonirritant, to metal and fabric non-corrosiveness, good stability.
Leather composite bactericidal mould inhibitor of the present invention is the proportioning of following mass percent most preferably:
| Component | Mass percent % |
| Guanidine compound | 2-13 |
| Tuo Lilong B | 0.1-2 |
| 2-bromo-2-nitro-1, ammediol | 0.1-1.5 |
| Iodo propinyl ammonia butyl formate | 0.1-5 |
| Ethanol | 1-30 |
| Corrosion inhibiter | 0.1-18 |
| Water | Surplus |
Guanidine compound described in the component is selected from: the mixture of one or more in polyhexamethylene guanide, the poly hexamethylene biguanide etc., or one or more mixture of above-mentioned guanidine compound pharmaceutically acceptable salt.
Corrosion inhibiter in the component is selected from: the mixture of one or more in Sodium Benzoate, gluconic acid sodium salt, the sodium salicylate etc.
Water described in the component is deionized water.
Another object of the present invention is; A kind of compound method of leather composite bactericidal mould inhibitor is provided; It mainly is to adopt guanidine compound, 2-bromo-2-nitro-1, ammediol, the upright imperial B of holder, iodo propinyl ammonia butyl formate, corrosion inhibiter, second alcohol and water through mix, reaction, stir, leave standstill formulated:
The compound method of the above-mentioned leather composite bactericidal mould inhibitor that contains the mass percent component is following:
1, with guanidine compound, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours;
2, iodo propinyl ammonia butyl formate, corrosion inhibiter, ethanol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances B in 3 hours;
3, with said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Combination matching between each component of leather composite bactericidal mould inhibitor of the present invention has following advantage and good effect:
1, harmless to people, animal, can not produce harmful substance, do not pollute the environment safety and environmental protection;
2, non-stimulated to skin and mucosa, article and fabric there are not corrosivity;
3, have no irritating odor, colourless, do not receive the influence of environment, organic matter, acid, alkali and other physics, chemical factor.
Embodiment
Embodiment 1
| Component | Kilogram kg | Mass percent % |
| Polyhexamethylene guanide | 10 | 10 |
| Tuo Lilong B | 0.3 | 0.3 |
| 2-bromo-2-nitro-1, ammediol | 1 | 1 |
| 95% ethanol | 10 | 10 |
| Iodo propinyl ammonia butyl formate | 0.6 | 0.6 |
| Sodium Benzoate | 1.5 | 1.5 |
| Sodium salicylate | 1.5 | 1.5 |
| Water | 75.1 | 75.1 |
| Amount to | 100 | 100 |
1, with polyhexamethylene guanide, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours;
2, iodo propinyl ammonia butyl formate, Sodium Benzoate, sodium salicylate, ethanol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances B in 3 hours;
3, with said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Embodiment 2
| Component | Kilogram kg | Mass percent % |
| Poly hexamethylene biguanide | 8 | 8 |
| Tuo Lilong B | 0.3 | 0.3 |
| 2-bromo-2-nitro-1, ammediol | 1 | 1 |
| 95% ethanol | 10 | 10 |
| Iodo propinyl ammonia butyl formate | 0.6 | 0.6 |
| Sodium Benzoate | 1 | 1 |
| Sodium salicylate | 1 | 1 |
| Water | 78.1 | 78.1 |
| Amount to | 100 | 100 |
1, with poly hexamethylene biguanide, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours;
2, iodo propinyl ammonia butyl formate, Sodium Benzoate, sodium salicylate, ethanol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances B in 3 hours;
3, with said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Embodiment 3
| Component | Kilogram kg | Mass percent % |
| Poly hexamethylene biguanide | 3 | 3 |
| Polyhexamethylene guanide | 7 | 7 |
| Tuo Lilong B | 0.3 | 0.3 |
| 2-bromo-2-nitro-1, ammediol | 1 | 1 |
| 95% ethanol | 10 | 10 |
| Iodo propinyl ammonia butyl formate | 0.6 | 0.6 |
| Gluconic acid sodium salt | 1.5 | 1.5 |
| Sodium salicylate | 1.5 | 1.5 |
| Water | 75.1 | 75.1 |
| Amount to | 100 | 100 |
1, with poly hexamethylene biguanide, polyhexamethylene guanide, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours;
2, iodo propinyl ammonia butyl formate, gluconic acid sodium salt, sodium salicylate, ethanol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances B in 3 hours;
3, with said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
Embodiment 4
| Component | Kilogram kg | Mass percent % |
| Poly hexamethylene biguanide | 5 | 5 |
| Polyhexamethylene guanide | 5 | 5 |
| Tuo Lilong B | 0.3 | 0.3 |
| 2-bromo-2-nitro-1, ammediol | 1 | 1 |
| 95% ethanol | 10 | 10 |
| Iodo propinyl ammonia butyl formate | 0.6 | 0.6 |
| Sodium Benzoate | 1.5 | 1.5 |
| Sodium salicylate | 1.5 | 1.5 |
| Water | 75.1 | 75.1 |
| Amount to | 100 | 100 |
1, with polyhexamethylene guanide, poly hexamethylene biguanide, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours;
2, iodo propinyl ammonia butyl formate, Sodium Benzoate, sodium salicylate, ethanol are mixed stirring by above-mentioned mass percent with the water of above-mentioned mass percent remaining 50% and be mixed with compounding substances B in 3 hours;
3, with said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed
Mixture carries out assay, and qualified mixture is packed, and is qualified products.
With the product of embodiment 1-4 gained, with the deionized water dilution, dilution arbitrarily in 50-500 scope doubly, effect 10min all can reach more than 99.99% the mould average kill ratio.
The present invention does further elaboration through above embodiment, but does not limit the scope of the invention.
The present invention is with the various variations of described scope of soverlay technique scheme and claim scope; Under the prerequisite that does not depart from technical scheme of the present invention, any improvement that those skilled in the art that the present invention did are realized easily all belongs to the present invention's scope required for protection.
Claims (7)
1. leather composite bactericidal mould inhibitor is characterized in that comprising following component by mass percent:
。
2. leather composite bactericidal mould inhibitor as claimed in claim 1 is characterized in that comprising following most preferably component by mass percent:
。
3. leather composite bactericidal mould inhibitor as claimed in claim 1; It is characterized in that described guanidine compound is selected from: the mixture of one or more in polyhexamethylene guanide, the poly hexamethylene biguanide etc., or one or more mixture of above-mentioned guanidine compound pharmaceutically acceptable salt.
4. leather composite bactericidal mould inhibitor as claimed in claim 1 is characterized in that described corrosion inhibiter is selected from: the mixture of one or more in Sodium Benzoate, gluconic acid sodium salt, the sodium salicylate etc.
5. leather composite bactericidal mould inhibitor as claimed in claim 1 is characterized in that described wet concentration certainly: deionized water.
6. like the described arbitrary leather composite bactericidal mould inhibitor of claim 1-5, it is characterized in that: with described leather composite bactericidal mould inhibitor dilution, dilution ratio is 50-500 times.
7. like the preparation of the described arbitrary leather composite bactericidal mould inhibitor of claim 1-6; It is characterized in that: with guanidine compound, 2-bromo-2-nitro-1, ammediol and Tuo Li dragon B mixes stirring by 50% water of above-mentioned mass percent and above-mentioned mass percent and was mixed with compounding substances A in 3 hours; Iodo propinyl ammonia butyl formate, corrosion inhibiter, ethanol are mixed stirring by above-mentioned mass percent be mixed with compounding substances B in 3 hours with the water of above-mentioned mass percent remaining 50%; With said mixture matter A and said mixture matter B stirring reaction 2 hours, left standstill again 2 hours, mixed mixture is carried out assay, qualified mixture is packed, be qualified products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110224058A CN102318635A (en) | 2011-08-05 | 2011-08-05 | Preparation method of compound leather bactericidal and mildew-proof agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110224058A CN102318635A (en) | 2011-08-05 | 2011-08-05 | Preparation method of compound leather bactericidal and mildew-proof agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102318635A true CN102318635A (en) | 2012-01-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110224058A Pending CN102318635A (en) | 2011-08-05 | 2011-08-05 | Preparation method of compound leather bactericidal and mildew-proof agent |
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| Country | Link |
|---|---|
| CN (1) | CN102318635A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105875621A (en) * | 2016-05-11 | 2016-08-24 | 于文 | Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof |
| CN106879621A (en) * | 2017-03-24 | 2017-06-23 | 五赫兹（厦门）医疗用品有限公司 | A kind of composite disinfectant of long-acting high security |
| CN107460263A (en) * | 2017-08-29 | 2017-12-12 | 安徽乐踏鞋业有限公司 | A kind of Leather mildew-proof method |
-
2011
- 2011-08-05 CN CN201110224058A patent/CN102318635A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105875621A (en) * | 2016-05-11 | 2016-08-24 | 于文 | Shoe and sock anti-bacterium and odor eliminating agent and preparation method thereof |
| CN106879621A (en) * | 2017-03-24 | 2017-06-23 | 五赫兹（厦门）医疗用品有限公司 | A kind of composite disinfectant of long-acting high security |
| CN106879621B (en) * | 2017-03-24 | 2020-01-31 | 五赫兹（厦门）医疗用品有限公司 | long-acting high-safety composite disinfectant |
| CN107460263A (en) * | 2017-08-29 | 2017-12-12 | 安徽乐踏鞋业有限公司 | A kind of Leather mildew-proof method |
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Application publication date: 20120118 |