CN102162636B - A high-temperature heat storage and evaporation integrated device - Google Patents
A high-temperature heat storage and evaporation integrated device Download PDFInfo
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- 238000005338 heat storage Methods 0.000 title claims abstract description 224
- 238000001704 evaporation Methods 0.000 title claims abstract description 164
- 230000008020 evaporation Effects 0.000 title claims abstract description 129
- 238000010438 heat treatment Methods 0.000 claims abstract description 73
- 239000007788 liquid Substances 0.000 claims abstract description 55
- 238000012546 transfer Methods 0.000 claims abstract description 49
- 238000009413 insulation Methods 0.000 claims abstract description 17
- 150000003839 salts Chemical class 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000012530 fluid Substances 0.000 claims description 8
- 239000013529 heat transfer fluid Substances 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 7
- 239000012782 phase change material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 11
- 239000011232 storage material Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 238000010248 power generation Methods 0.000 description 8
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- 238000005260 corrosion Methods 0.000 description 6
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- 238000004146 energy storage Methods 0.000 description 4
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- 230000007774 longterm Effects 0.000 description 3
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- 230000002441 reversible effect Effects 0.000 description 2
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
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- 238000013517 stratification Methods 0.000 description 1
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- 238000002207 thermal evaporation Methods 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/0034—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using liquid heat storage material
- F28D2020/0047—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using liquid heat storage material using molten salts or liquid metals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2270/00—Thermal insulation; Thermal decoupling
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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Abstract
一种高温储热蒸发一体化装置,包括储热块(5)、储液槽(7)、保温层(4)、加热管(8)、蒸发管(9)。保温层(4)紧贴储液槽(7)外壁;储热块(5)置于储液槽(7)内部;储热块(5)规则地等间距分布有多个通孔;加热管(8)与蒸发管(9)间隔穿过储热块(5)上的通孔。加热管(8)与蒸发管(9)为光管或强化换热管;储液槽(7)容器内部填充高温传热工质。
A high-temperature heat storage and evaporation integrated device, comprising a heat storage block (5), a liquid storage tank (7), an insulation layer (4), a heating pipe (8), and an evaporation pipe (9). The thermal insulation layer (4) is close to the outer wall of the liquid storage tank (7); the heat storage block (5) is placed inside the liquid storage tank (7); the heat storage block (5) has a plurality of through holes regularly distributed at equal intervals; the heating tube (8) pass through the through hole on the heat storage block (5) at intervals with the evaporation tube (9). The heating tube (8) and the evaporating tube (9) are bare tubes or enhanced heat exchange tubes; the container of the liquid storage tank (7) is filled with a high-temperature heat-transfer working medium.
Description
技术领域 technical field
本发明涉及一种储热蒸发一体化装置。The invention relates to a heat storage and evaporation integrated device.
背景技术 Background technique
由于可以通过储热来实现持续稳定的电力供应,聚光型太阳能热发电在当今被世界各国公认为极具潜力的可再生能源发电技术。储热方式以及储热材料性能和成本对于太阳能热发电站建设和运行成本关系重大。用于太阳能热发电系统中的储热材料需要具备如下特点:高的储能密度;储热材料与热交换液体应该有良好的热量交换性能;储热材料应该具备良好的稳定性;储热材料和系统设备之间应该有良好的化学相容性;储热放热循环应可逆;高的性价比。当前储热方式主要有潜热储热、显热储热和化学能储热三种方式。潜热是指在温度保持不变的条件下,物质在从某一个相转变为另一个相的相变过程中所吸入或放出的热量,潜热储热就是利用材料在固相、液相、气相之间相互转变时吸收或放出的潜热来实现热能的存放,这个过程是可逆的,可以双向多次重复,该技术当前研究和应用广泛。常用的潜热储热材料有水、各种水合盐、混合盐等。储热量巨大,但是储热温度受储热材料的种类和物性限制。显热是指当此热量加入或移去后,会导致物质温度的变化,而不发生相变。显热储热是最为简单和成熟的技术,常用的显热储热材料有水、熔融盐、导热油、混凝土、卵石等。储热所需物质的量较大。化学能是物体发生化学反应时所释放的能量,化学能储热比显热和潜热储热的热流密度都大,但是技术复杂,目前尚无工业应用。在太阳能热发电站中已经应用或在文献专利中报道的储热系统类型和特点如下:(1)“高温盐罐+低温盐罐”的双罐储热系统。文献1(Ulf Hermann,Bruce Kelly,Henry Price.Two-tank molten salt storage forparabolic trough solar power plants,Energy,2004,(29):883-893)报告了熔融盐双罐储热系统在槽式太阳能热发电站的应用。熔融盐作为传热、储热一体化工质。熔融盐有较强的腐蚀性,但是相比导热油而言,熔融盐储热具有低成本的优势。而且根据熔融盐种类的不同,储热系统的工作温度范围可在200℃-560℃,工作温度上限较高,有利于提高蒸汽发电机组的工作参数,进而实现较高的发电效率,但该方案需要制造两个熔融盐储热罐,熔融盐使用量也很大。(2)斜温层熔融盐单罐储热系统。文献2(Robert J.Copeland,Lakewood,Colo.,US patent(No.4523629))报道了一种利用熔融盐液相显热储热的斜温层单罐储热装置,其特点是在熔融盐罐中设置了挡板,抑制熔融盐罐内的冷盐与热盐混合,促进熔融盐罐上下段温度分层。文献3(左远志,杨晓西,丁栴,丁静,杨建平,中国发明专利(ZL200710028077.X))报道了一种熔融盐中高温斜温层混合储热装置,在熔融盐罐中装入相变材料,依靠显热换热及相变换热进行储热。与双罐储热系统和熔融盐单罐储热系统比较而言,可以进一步降低储热成本。(3)“砂石+导热油”单罐储热系统。文献4(M.Castro,J.L.Presa,J.Díaz,J.Peire,A.F.Baker,S.E.Faas,L.G.Radosevich,A.C.Skinrood.C.R.S.receiver and storage systems evaluation(J),Solar Energy,1991,47(3):197-207)报道了“砂石+导热油”单罐储热系统的结构特点,在换热、导热油污染、低温难启动等方面还存在需要解决的问题。(4)混凝土储热模块。文献6(Ulf Herrmann,DavidWearney.Survey of thermal energy storage for parabolic trough power plants(J),Journal of solar energy engineering,2002,124:145-152)通过比较分析几种储热材料的发电成本,得出混凝土储热模块性价比最好。中国专利ZL200610112004.4提出了一种利用混凝土的高温储热器及储热方法,使用重力热管解决腐蚀和冻结问题,但是金属管与混凝土膨胀率不同,热胀冷缩会对混凝土结构造成裂纹,金属管与混凝土之间的接触热阻也较大。此外以上文献中报道的储热方式,存在成本高,且不能低温启动的难题。另外,上述装置在太阳能热发电系统中应用时,还需要配备一台蒸发器,才能实现为汽轮发电机组提供运转所需蒸汽。在储热和蒸汽发生的方式上均不能进一步大幅降低成本,提高系统效率和稳定性。Since a continuous and stable power supply can be achieved through heat storage, concentrating solar thermal power generation is recognized by countries all over the world as a renewable energy power generation technology with great potential. The heat storage method as well as the performance and cost of heat storage materials are of great importance to the construction and operation costs of solar thermal power plants. Heat storage materials used in solar thermal power generation systems need to have the following characteristics: high energy storage density; heat storage materials and heat exchange liquids should have good heat exchange performance; heat storage materials should have good stability; heat storage materials There should be good chemical compatibility with the system equipment; the heat storage and release cycle should be reversible; high cost performance. The current heat storage methods mainly include latent heat storage, sensible heat storage and chemical energy storage. Latent heat refers to the heat absorbed or released by a substance during the phase transition process from one phase to another under the condition that the temperature remains constant. The storage of heat energy is realized by the latent heat absorbed or released during the mutual transformation between them. This process is reversible and can be repeated multiple times in both directions. This technology is currently researched and widely used. Commonly used latent heat storage materials include water, various hydrated salts, and mixed salts. The heat storage is huge, but the heat storage temperature is limited by the type and physical properties of the heat storage material. Sensible heat is when this heat is added or removed which results in a change in the temperature of a substance without a phase change. Sensible heat storage is the simplest and most mature technology. Commonly used sensible heat storage materials include water, molten salt, heat transfer oil, concrete, and pebbles. The amount of material required for heat storage is relatively large. Chemical energy is the energy released when an object undergoes a chemical reaction. Chemical energy storage has a higher heat flux density than both sensible heat and latent heat storage. However, the technology is complicated and there is no industrial application at present. The types and characteristics of heat storage systems that have been applied in solar thermal power plants or reported in literature patents are as follows: (1) The double-tank heat storage system of "high temperature salt tank + low temperature salt tank". Document 1 (Ulf Hermann, Bruce Kelly, Henry Price. Two-tank molten salt storage for parabolic trough solar power plants, Energy, 2004, (29): 883-893) reported the application of molten salt double-tank heat storage system in trough solar thermal Applications in power stations. Molten salt is used as an integrated working medium for heat transfer and heat storage. Molten salt is highly corrosive, but compared with heat transfer oil, molten salt heat storage has the advantage of low cost. Moreover, depending on the type of molten salt, the working temperature range of the heat storage system can be 200°C-560°C, and the upper limit of the working temperature is higher, which is conducive to improving the working parameters of the steam generator set, thereby achieving higher power generation efficiency, but this scheme Two molten salt heat storage tanks need to be manufactured, and the amount of molten salt used is also large. (2) Thermocline molten salt single-tank heat storage system. Document 2 (Robert J. Copeland, Lakewood, Colo., US patent (No. 4523629)) reported a thermocline single-tank heat storage device using molten salt liquid phase sensible heat storage, which is characterized in that the molten salt Baffles are installed in the tank to inhibit the mixing of cold salt and hot salt in the molten salt tank and promote temperature stratification in the upper and lower sections of the molten salt tank. Document 3 (Zuo Yuanzhi, Yang Xiaoxi, Ding Wei, Ding Jing, Yang Jianping, Chinese Invention Patent (ZL200710028077.X)) reported a high-temperature thermocline hybrid heat storage device in molten salt, which was installed in the molten salt tank. Materials rely on sensible heat transfer and phase transformation heat storage for heat storage. Compared with the double-tank heat storage system and the molten salt single-tank heat storage system, the cost of heat storage can be further reduced. (3) "Sandstone + heat transfer oil" single-tank heat storage system. Document 4 (M.Castro, J.L.Presa, J.Díaz, J.Peire, A.F.Baker, S.E.Faas, L.G.Radosevich, A.C.Skinrood.C.R.S. receiver and storage systems evaluation (J), Solar Energy, 1991, 47(3): 197-207) reported the structural characteristics of the "sandstone + heat transfer oil" single-tank heat storage system, but there are still problems to be solved in terms of heat transfer, heat transfer oil pollution, and difficult start-up at low temperature. (4) Concrete heat storage module. Document 6 (Ulf Herrmann, David Wearney. Survey of thermal energy storage for parabolic trough power plants (J), Journal of solar energy engineering, 2002, 124: 145-152) compares and analyzes the power generation costs of several heat storage materials, and draws Concrete heat storage modules have the best cost performance. Chinese patent ZL200610112004.4 proposes a high-temperature heat storage and heat storage method using concrete, and uses gravity heat pipes to solve corrosion and freezing problems. However, the expansion rate of metal pipes and concrete is different, and thermal expansion and contraction will cause cracks in the concrete structure. The contact thermal resistance between the metal pipe and the concrete is also relatively large. In addition, the heat storage methods reported in the above literatures have the problems of high cost and inability to start at low temperature. In addition, when the above-mentioned device is applied in a solar thermal power generation system, an evaporator is required to provide the steam required for the operation of the turbo-generator set. Both heat storage and steam generation methods cannot further significantly reduce costs and improve system efficiency and stability.
发明内容 Contents of the invention
本发明的目的是提供一种可应用于太阳能热发电系统的高温储热蒸发一体化装置,它具有结构简单、安全可靠、换热效率高且易于低温启动的特点。The purpose of the present invention is to provide a high-temperature heat storage and evaporation integrated device applicable to solar thermal power generation systems, which has the characteristics of simple structure, safety and reliability, high heat exchange efficiency and easy low-temperature start-up.
本发明高温储热蒸发一体化装置由储热块、储液槽、保温层、加热管、蒸发管等部件组成。保温层紧贴储液槽外壁;储热块置于储液槽内部;储热块上规则地分布有多个水平布置的通孔;加热管和蒸发管相间布置,相间地穿过储热块上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管和蒸发管可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储液槽容器内部填充高温传热工质。The high-temperature heat storage and evaporation integrated device of the present invention is composed of heat storage block, liquid storage tank, insulation layer, heating tube, evaporation tube and other components. The insulation layer is close to the outer wall of the liquid storage tank; the heat storage block is placed inside the liquid storage tank; there are a number of horizontally arranged through holes regularly distributed on the heat storage block; the heating tubes and evaporation tubes are arranged alternately, passing through the heat storage block alternately There are through holes arranged horizontally on the top, and the distance between each heating tube and the adjacent evaporating tube is similar or equal. The heating tube and the evaporating tube can be plain tubes, corrugated tubes, variable cross-section elliptical tubes, threaded tubes, and enhanced heat exchange tubes with fins added. The interior of the liquid storage tank container is filled with high-temperature heat transfer working fluid.
当本发明高温储热蒸发一体化装置储热温度在400℃以内时,储液槽内部填充的高温传热工质为导热油,此时储液槽内的导热油需要惰性气体保护,储液槽为承压结构,加热管内流动的传热工质为导热油或熔融盐。当本发明高温储热蒸发一体化装置储热温度在600℃以内时,储液槽内部填充的高温传热工质为混合熔融盐,此时储液槽为非承压结构。加热管内流动的传热工质为混合熔融盐;蒸发管内的流动传热工质是水蒸气;储热块材料为卵石、陶瓷或混凝土,储热块的材料与储液槽内部填充的高温传热工质有良好相容性;储热块上规则分布的通孔与加热管和蒸发管之间预留有空隙,便于现场安装,也可以保证储热块、加热管和蒸发管在热胀冷缩时彼此不发生干涉而引发结构破坏。When the heat storage temperature of the high-temperature heat storage and evaporation integrated device of the present invention is within 400°C, the high-temperature heat transfer medium filled in the liquid storage tank is heat transfer oil. The tank is a pressure-bearing structure, and the heat transfer fluid flowing in the heating tube is heat transfer oil or molten salt. When the heat storage temperature of the high-temperature heat storage and evaporation integrated device of the present invention is within 600°C, the high-temperature heat transfer working fluid filled in the liquid storage tank is mixed molten salt, and the liquid storage tank is a non-pressure-bearing structure at this time. The heat transfer medium flowing in the heating tube is mixed molten salt; the heat transfer medium flowing in the evaporator tube is water vapor; the material of the heat storage block is pebbles, ceramics or concrete, and the material of the heat storage block is the same as the high temperature heat transfer fluid filled in the liquid storage tank. The thermal working medium has good compatibility; there is a gap reserved between the regularly distributed through holes on the heat storage block and the heating tube and evaporation tube, which is convenient for on-site installation and can also ensure that the thermal expansion of the heat storage block, heating tube and evaporation tube When shrinking, they do not interfere with each other and cause structural damage.
高温储热蒸发一体化装置充热时,高温传热流体从加热管入口进入加热管,与储液槽内部填充的高温传热工质和储热块充分换热后从加热管出口流出。热量储存在储热块与储液槽内部的高温传热工质中。When the high-temperature heat storage and evaporation integrated device is charging, the high-temperature heat transfer fluid enters the heating pipe from the inlet of the heating pipe, and flows out from the outlet of the heating pipe after fully exchanging heat with the high-temperature heat transfer working fluid and heat storage block filled in the liquid storage tank. The heat is stored in the heat storage block and the high-temperature heat transfer fluid inside the liquid storage tank.
高温储热蒸发一体化装置放热时,饱和水或低温蒸汽从蒸发管入口进入蒸发管,与储液槽内部填充的高温传热工质和储热块充分换热后,被加热为高温蒸汽,从蒸发管出口流出。When the high-temperature heat storage and evaporation integrated device releases heat, saturated water or low-temperature steam enters the evaporator tube from the inlet of the evaporator tube, and after fully exchanging heat with the high-temperature heat transfer medium and heat storage block filled in the liquid storage tank, it is heated into high-temperature steam , flowing out from the outlet of the evaporating tube.
高温储热蒸发一体化装置在第一次试运行,或因设备维修等原因导致长期停机,储热块温度较低情况下启动时,如果加热管内流动的传热工质为导热油,由于太阳能热发电站常用的DOWTHEM-A导热油在12℃以下会凝固,所以100℃以下的热水或100℃以上的低温蒸汽从蒸发管入口进入蒸发管,加热储液槽内部填充的高温传热工质,进而加热储热块和插入其中的加热管,换热后从蒸发管出口流出。加热管中凝固的导热油被加热为液态,可以流动循环。当高温储热蒸发一体化装置应用于熔融盐太阳能热发电站中时,高温储热蒸发一体化装置的加热管内传热工质为熔融盐,太阳能热发电站常用的混合硝酸熔盐在220℃以下为固态,所以290℃以上的高温蒸汽从蒸发管入口进入蒸发管,加热储液槽内部填充的高温传热工质、储热块以及加热管,换热后从蒸发管出口流出。加热管中凝固的熔融盐被加热熔为液态,开始流动循环。When the high-temperature heat storage and evaporation integrated device is in the first test run, or it is shut down for a long time due to equipment maintenance and other reasons, when the temperature of the heat storage block is low, if the heat transfer medium flowing in the heating tube is heat transfer oil, due to solar The DOWTHEM-A heat transfer oil commonly used in thermal power stations will solidify below 12°C, so hot water below 100°C or low-temperature steam above 100°C enters the evaporator tube from the inlet of the evaporator tube, and heats the high-temperature heat transfer tool filled in the liquid storage tank. quality, and then heat the heat storage block and the heating tube inserted into it, and flow out from the outlet of the evaporating tube after heat exchange. The solidified heat transfer oil in the heating tube is heated to a liquid state and can flow and circulate. When the high-temperature heat storage and evaporation integrated device is applied to a molten salt solar thermal power station, the heat transfer medium in the heating tube of the high-temperature heat storage and evaporation integrated device is molten salt, and the mixed nitric acid molten salt commonly used in solar thermal power stations is heated at 220°C The following is solid state, so the high-temperature steam above 290°C enters the evaporator tube from the inlet of the evaporator tube, heats the high-temperature heat transfer fluid, heat storage block and heating tube filled in the liquid storage tank, and flows out from the outlet of the evaporator tube after heat exchange. The molten salt solidified in the heating tube is heated and melted into a liquid state, and the flow cycle begins.
本发明的优点在是采用卵石、耐高温的陶瓷、耐高温耐腐蚀的混凝土作为储热块的材料,可掺入密封好的相变材料,充分利用上述材料储热容量大,成本低廉和高温热性能稳定的特点;将储热块置于储液箱中,充分利用储液箱中的高温传热工质填充加热管、蒸发管与储热块通孔之间预留的间隙。一方面可以利用高温传热工质减小换热管与储热块之间的接触热阻,增强换热;另一方面也可以避免换热管与储热块接触过紧热胀冷缩带来的结构损坏。所以本高温储热蒸发一体化装置具有更好的换热特性和可靠性,优于以往的固体储热装置。另外,本发明高温储热蒸发一体化装置的加热管和蒸发管都置于储热块中,高温储热蒸发一体化装置在低温启动时,可以利用热水或蒸汽通过蒸发管,预热储热块,解决高温传热工质在低温下的冻堵,该功能也优于以往的固体储热装置。此外,本发明的高温储热蒸发一体化装置结构紧凑,也可以依照储热温度和蒸汽出口参数的需求,通过改变串联、并联方式,灵活组合使用,可使储热块中的热能根据温度梯级充分利用。由于具有上述特点,所以本发明的高温储热蒸发一体化装置比以往的储热装置有着更高的换热效率,更好的经济性和运行可靠性,特别适用于在400℃以上储热蒸发的太阳能热发电场合。The advantage of the present invention is that pebbles, high-temperature-resistant ceramics, and high-temperature-resistant and corrosion-resistant concrete are used as heat storage block materials, which can be mixed with sealed phase-change materials to make full use of the above-mentioned materials with large heat storage capacity, low cost and high-temperature heat. Stable performance; place the heat storage block in the liquid storage tank, and make full use of the high-temperature heat transfer medium in the liquid storage tank to fill the reserved gap between the heating tube, evaporation tube and the through hole of the heat storage block. On the one hand, the high-temperature heat transfer working medium can be used to reduce the contact thermal resistance between the heat exchange tube and the heat storage block, and enhance the heat exchange; Incoming structural damage. Therefore, the high-temperature heat storage and evaporation integrated device has better heat transfer characteristics and reliability, and is superior to previous solid heat storage devices. In addition, the heating tube and evaporation tube of the high-temperature heat storage and evaporation integrated device of the present invention are placed in the heat storage block. When the high-temperature heat storage and evaporation integrated device is started at a low temperature, hot water or steam can be used to preheat the storage The thermal block solves the freezing blockage of high-temperature heat transfer fluid at low temperature, and this function is also superior to previous solid heat storage devices. In addition, the high-temperature heat storage and evaporation integrated device of the present invention has a compact structure, and can also be flexibly combined and used by changing the series connection and parallel connection according to the requirements of heat storage temperature and steam outlet parameters, so that the heat energy in the heat storage block can be used according to the temperature gradient Take advantage of. Due to the above characteristics, the high-temperature heat storage and evaporation integrated device of the present invention has higher heat exchange efficiency, better economy and operation reliability than previous heat storage devices, and is especially suitable for heat storage and evaporation above 400°C solar thermal power generation occasions.
附图说明 Description of drawings
以下结合附图和具体实施方式对本发明作进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
图1高温储热蒸发一体化装置长方体结构立体图;Figure 1 is a three-dimensional view of the cuboid structure of the high-temperature heat storage and evaporation integrated device;
图2高温储热蒸发一体化装置圆柱体结构立体图;Figure 2 is a three-dimensional view of the cylindrical structure of the high-temperature heat storage and evaporation integrated device;
图3高温储热蒸发一体化装置俯视图;Figure 3 is the top view of the high-temperature heat storage and evaporation integrated device;
图4高温储热蒸发一体化装置正剖视图;Figure 4 is a front sectional view of a high-temperature heat storage and evaporation integrated device;
图5高温储热蒸发一体化装置长方体结构左剖视图;Fig. 5 Left sectional view of cuboid structure of high-temperature heat storage and evaporation integrated device;
图6高温储热蒸发一体化装置圆柱体结构左剖视图;Fig. 6 The left cross-sectional view of the cylinder structure of the high-temperature heat storage and evaporation integrated device;
图7高温储热蒸发一体化装置的长方体储热块与换热管连接方式示意图;Fig. 7 is a schematic diagram of the connection mode between the cuboid heat storage block and the heat exchange tube of the high-temperature heat storage and evaporation integrated device;
图8高温储热蒸发一体化装置的圆柱体储热块与换热管连接方式示意图;Figure 8 is a schematic diagram of the connection method between the cylindrical heat storage block and the heat exchange tube of the high-temperature heat storage and evaporation integrated device;
图9高温储热蒸发一体化装置的加热管示意图;Fig. 9 is a schematic diagram of a heating tube of a high-temperature heat storage and evaporation integrated device;
图10高温储热蒸发一体化装置的蒸发管示意图;Figure 10 is a schematic diagram of the evaporation tube of the high-temperature heat storage and evaporation integrated device;
图11高温储热蒸发一体化装置的长方体储热块示意图;Fig. 11 is a schematic diagram of a cuboid heat storage block of a high-temperature heat storage and evaporation integrated device;
图12高温储热蒸发一体化装置的圆柱体储热块示意图;Figure 12 is a schematic diagram of a cylindrical heat storage block of a high-temperature heat storage and evaporation integrated device;
图13高温储热蒸发一体化装置组成系统应用原理图;Figure 13 Application schematic diagram of the composition system of the high-temperature heat storage and evaporation integrated device;
图中:1加热管入口,2蒸发管入口,3蒸发管出口,4保温层,5储热块,6加热管出口,7储液箱,8加热管,9蒸发管,10阀门A,11阀门B,12阀门C,13阀门D,14阀门E,15阀门F,16阀门G,17阀门H,18阀门I,19阀门J,20阀门K,21阀门L,22阀门M,23阀门N,24阀门O,25阀门P,26高温储热蒸发一体化装置Q,27高温储热蒸发一体化装置R,28高温储热蒸发一体化装置S。In the figure: 1 heating tube inlet, 2 evaporating tube inlet, 3 evaporating tube outlet, 4 insulation layer, 5 heat storage block, 6 heating tube outlet, 7 liquid storage tank, 8 heating tube, 9 evaporating tube, 10 valve A, 11 Valve B, 12 Valve C, 13 Valve D, 14 Valve E, 15 Valve F, 16 Valve G, 17 Valve H, 18 Valve I, 19 Valve J, 20 Valve K, 21 Valve L, 22 Valve M, 23 Valve N , 24 valve O, 25 valve P, 26 high temperature heat storage and evaporation integrated device Q, 27 high temperature heat storage and evaporation integrated device R, 28 high temperature heat storage and evaporation integrated device S.
具体实施方式 Detailed ways
下面结合附图和具体实施方式对本发明作进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1所示,高温储热蒸发一体化装置外形为长方体结构。高温储热蒸发一体化装置最外侧为保温层4。加热管入口1,加热管出口6,蒸发管入口2,蒸发管出口3伸出储液槽7及保温层4外侧。高温储热蒸发一体化装置初次使用时,或者由于维修等原因经历长期停机后启动时,热水或者低温蒸汽从蒸发管入口2流入,从蒸发管出口3流出,完成对高温储热蒸发一体化装置的预热。当高温储热蒸发一体化装置充热时,高温传热工质从加热管入口1流入,从加热管出口6流出,完成热量的储存过程。蒸发放热时,热水或者低温蒸汽从蒸发管入口2流入,经换热后,被加热的高温蒸汽从蒸发管出口3流出。As shown in Figure 1, the high-temperature heat storage and evaporation integrated device has a rectangular parallelepiped structure. The outermost side of the high-temperature heat storage and evaporation integrated device is the
如图2所示,高温储热蒸发一体化装置外形为圆柱体结构。高温储热蒸发一体化装置最外侧为保温层4。加热管入口1,加热管出口6,蒸发管入口2,蒸发管出口3伸出储液槽7及保温层4外侧。高温储热蒸发一体化装置初次使用时,或者由于维修等原因经历长期停机后启动时,热水或者低温蒸汽从蒸发管入口2流入,从蒸发管出口3流出,完成对高温储热蒸发一体化装置的预热。当高温储热蒸发一体化装置充热时,高温传热工质从加热管入口1流入,从加热管出口6流出,完成热量的储存过程。蒸发放热时,热水或者低温蒸汽从蒸发管入口2流入,经换热后,被加热的高温蒸汽从蒸发管出口3流出。As shown in Figure 2, the high-temperature heat storage and evaporation integrated device has a cylindrical structure in shape. The outermost side of the high-temperature heat storage and evaporation integrated device is the
如图3和图4所示,高温储热蒸发一体化装置由储热块5、储液槽7、保温层4、加热管8、蒸发管9组成。加热管入口1,加热管出口6,蒸发管入口2,蒸发管出口3伸出储液槽7及保温层4外侧。储液槽7的材料可以是金属,也可以是非金属。保温层4紧贴储液槽7的外壁;储热块5置于储液槽7内部;储热块5上规则地等间距分布有多个水平的通孔;加热管8和蒸发管9相间布置,相间地穿过储热块5上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管8和蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储液槽7容器内部填充高温传热工质。高温储热蒸发一体化装置初次使用时,或者由于维修等原因经历长期停机后启动时,热水或者低温蒸汽从蒸发管入口2流入,从蒸发管出口3流出,完成对高温储热蒸发一体化装置的预热。当高温储热蒸发一体化装置充热时,高温传热工质从加热管入口1流入,从加热管出口6流出,与储液槽7内的高温传热工质以及储热块5充分换热,完成热量的储存过程。蒸发放热时,热水或者低温蒸汽从蒸发管入口2流入,经与储液槽7内的高温传热工质以及储热块5充分换热后,热水或者低温蒸汽被加热为高温蒸汽从蒸发管出口3流出。As shown in FIGS. 3 and 4 , the high-temperature heat storage and evaporation integrated device is composed of a
如图5所示,外形为长方体结构的高温储热蒸发一体化装置截面形状为矩形,保温层4紧贴储液槽7的外壁;储热块5置于储液槽7内部;储热块5上规则地等间距分布有多个水平的通孔;加热管8和蒸发管9相间布置,相间地穿过储热块5上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管8和蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储液槽7容器内部填充高温传热工质。As shown in Figure 5, the cross-sectional shape of the high-temperature heat storage and evaporation integrated device with a cuboid structure is rectangular, and the
如图6所示,外形为圆柱体结构的高温储热蒸发一体化装置截面形状为圆形,保温层4紧贴储液槽7的外壁;储热块5置于储液槽7内部;储热块5上规则地等间距分布有多个水平布置的通孔;加热管8和蒸发管9相间布置,相间地穿过储热块5上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管8和蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储液槽7容器内部填充高温传热工质。As shown in Figure 6, the cross-sectional shape of the high-temperature heat storage and evaporation integrated device with a cylindrical structure is circular, and the
如图7所示,长方体结构的高温储热蒸发一体化装置内部包含有多个储热块5,储热块5呈长方体结构。储热块5上规则地等间距分布有多个水平布置的通孔。加热管8和蒸发管9相间布置,相间地穿过储热块5上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管8和蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储热块5的材料可采用卵石、耐高温的陶瓷、耐高温耐腐蚀的混凝土,储热块5中可掺入密封好的相变材料。As shown in FIG. 7 , the integrated high-temperature heat storage and evaporation device with a rectangular parallelepiped structure contains a plurality of heat storage blocks 5 , and the heat storage blocks 5 have a rectangular parallelepiped structure. A plurality of horizontally arranged through holes are regularly and equidistantly distributed on the
如图8所示,圆柱体结构的高温储热蒸发一体化装置内部包含有多个储热块5,储热块5呈圆柱体结构。储热块5上规则地等间距分布有多个水平布置的通孔。加热管8和蒸发管9相间布置,相间地穿过储热块5上水平布置的通孔,每支加热管与相邻蒸发管之间的距离相近或相等。加热管8和蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。储热块5的材料可采用卵石、耐高温的陶瓷、耐高温耐腐蚀的混凝土,储热块5中可掺入相变材料。As shown in FIG. 8 , the high-temperature heat storage and evaporation integrated device with a cylindrical structure contains a plurality of heat storage blocks 5 , and the heat storage blocks 5 have a cylindrical structure. A plurality of horizontally arranged through holes are regularly and equidistantly distributed on the
如图9所示,高温储热蒸发一体化装置内部的加热管8可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。As shown in Figure 9, the
如图10所示,高温储热蒸发一体化装置内部的蒸发管9可以是光管,也可以是波纹管、变截面椭圆管、螺纹管、加装肋片的强化换热管。As shown in Figure 10, the
如图11所示,长方体结构的高温储热蒸发一体化装置内部的储热块5呈长方体结构。储热块5上规则地等间距分布有多个水平布置的通孔,通孔29为加热管预留,通孔30为蒸发管预留,两类孔相间布置。储热块5的材料可采用卵石、耐高温的陶瓷、耐高温耐腐蚀的混凝土,储热块5中可掺入密封好的相变材料。As shown in FIG. 11 , the
如图12所示,圆柱体结构的高温储热蒸发一体化装置内部的储热块5呈圆柱体结构。储热块5上规则地等间距分布有多个通孔,通孔29为加热管预留,通孔30为蒸发管预留,两类孔相间的布置。储热块5的材料可采用卵石、耐高温的陶瓷、耐高温耐腐蚀的混凝土,储热块5中可掺入密封好的相变材料。As shown in FIG. 12 , the
图13是由3个高温储热蒸发一体化装置组成多模块系统具体使用方法的原理图。阀门A10,阀门B11,阀门C12,阀门D13,阀门E14,阀门F15,阀门G16,阀门H17均为控制加热管路通断的阀门。阀门I18,阀门J19,阀门K20,阀门L21,阀门M22,阀门N23,阀门O24,阀门P25均为控制蒸发管路通断的阀门。高温储热蒸发一体化装置Q26,高温储热蒸发一体化装置R27,高温储热蒸发一体化装置S28是三个结构相同的高温储热蒸发一体化装置。通过改变阀门开启和关闭状态,可以实现以下多种充热与放热模式:Figure 13 is a schematic diagram of the specific usage method of the multi-module system composed of three high-temperature heat storage and evaporation integrated devices. The valve A10, the valve B11, the valve C12, the valve D13, the valve E14, the valve F15, the valve G16, and the valve H17 are all valves for controlling the on-off of the heating pipeline. The valve I18, the valve J19, the valve K20, the valve L21, the valve M22, the valve N23, the valve O24, and the valve P25 are all valves for controlling the on-off of the evaporation pipeline. The high-temperature heat storage and evaporation integrated device Q26, the high-temperature heat storage and evaporation integrated device R27, and the high-temperature heat storage and evaporation integrated device S28 are three high-temperature heat storage and evaporation integrated devices with the same structure. By changing the opening and closing state of the valve, the following various charging and discharging modes can be realized:
1)高温储热蒸发一体化装置单独充热放热模式。当可提供储存的能量较少时,可对单个高温储热蒸发一体化装置进行充热。可以打开阀门A10,阀门B11,阀门G16,阀门F15,关闭加热管路的其他阀门。高温传热工质会经阀门A10、阀门B11流入高温储热蒸发一体化装置R27,换热后经阀门G16、阀门F15流出。当高温储热蒸发一体化装置R27被加热到预定温度,完成储热过程后,打开阀门A10,阀门C12,阀门H17,阀门F15,关闭加热管路其他阀门,即可单独将高温储热蒸发一体化装置Q26加热到预定温度。同样的,打开阀门A10,阀门D13,阀门E14,阀门F15,关闭加热管路其他阀门,即可单独将高温储热蒸发一体化装置S28加热到预定温度。1) The high-temperature heat storage and evaporation integrated device is in a separate heat-charging and heat-releasing mode. When the available stored energy is less, a single high-temperature heat storage and evaporation integrated device can be charged. Valve A10, valve B11, valve G16, valve F15 can be opened, and other valves of the heating pipeline can be closed. The high-temperature heat transfer medium will flow into the high-temperature heat storage and evaporation integrated device R27 through valve A10 and valve B11, and flow out through valve G16 and valve F15 after heat exchange. When the high-temperature heat storage and evaporation integrated device R27 is heated to the predetermined temperature and the heat storage process is completed, open valve A10, valve C12, valve H17, and valve F15, and close other valves in the heating pipeline, and the high-temperature heat storage and evaporation can be integrated separately. The heating device Q26 is heated to a predetermined temperature. Similarly, open the valve A10, the valve D13, the valve E14, the valve F15, and close the other valves of the heating pipeline, and the high-temperature heat storage and evaporation integrated device S28 can be independently heated to a predetermined temperature.
当使用蒸汽量较小,蒸发所需能量较少,高温储热蒸发一体化装置需要单独提供蒸汽进行放热时,打开阀门I18,阀门N23,阀门J19,阀门M22,关闭蒸发管路的其他阀门,低温蒸汽会经阀门I18、阀门N23,流入高温储热蒸发一体化装置R27,换热后经阀门J19、阀门M22流出。当高温储热蒸发一体化装置R27中的储热降低到不能将蒸汽提供到设定参数时,打开阀门I18,阀门O24,阀门L21,阀门M22,关闭蒸发管路的其他阀门,即可单独使用高温储热蒸发一体化装置Q26将低温蒸汽加热到设定参数。同样的,打开阀门I18,阀门P25,阀门K20,阀门M22,关闭蒸发管路的其他阀门,即可单独使用高温储热蒸发一体化装置S28将低温蒸汽加热到设定参数。When the amount of steam used is small, the energy required for evaporation is small, and the high-temperature heat storage and evaporation integrated device needs to provide steam separately for heat release, open valve I18, valve N23, valve J19, valve M22, and close other valves in the evaporation pipeline , the low-temperature steam will flow into the high-temperature heat storage and evaporation integrated device R27 through the valve I18 and the valve N23, and flow out through the valve J19 and the valve M22 after heat exchange. When the heat storage in the high-temperature heat storage and evaporation integrated device R27 is reduced to the point that the steam cannot be supplied to the set parameters, open valve I18, valve O24, valve L21, valve M22, and close other valves in the evaporation pipeline, and then it can be used alone The high-temperature heat storage and evaporation integrated device Q26 heats the low-temperature steam to the set parameters. Similarly, open valve I18, valve P25, valve K20, valve M22, and close other valves in the evaporation pipeline, and the high-temperature heat storage and evaporation integrated device S28 can be used alone to heat the low-temperature steam to the set parameters.
2)高温储热蒸发一体化装置同时充热放热模式。当可提供储存的能量充裕时,可对系统中的多个高温储热蒸发一体化装置进行同时充热。同时打开加热管路上的阀门A10,阀门B11,阀门C12,阀门D13,阀门E14,阀门F15,阀门G16,阀门H17,高温储热蒸发一体化装置Q26,高温储热蒸发一体化装置R27,高温储热蒸发一体化装置S28相互处于并联状态,高温传热工质可同时将高温储热蒸发一体化装置Q26,高温储热蒸发一体化装置R27,高温储热蒸发一体化装置S28加热到设定温度。2) The high-temperature heat storage and evaporation integrated device simultaneously charges and releases heat. When the stored energy is sufficient, multiple high-temperature heat storage and evaporation integrated devices in the system can be charged simultaneously. Simultaneously open valve A10, valve B11, valve C12, valve D13, valve E14, valve F15, valve G16, valve H17 on the heating pipeline, high-temperature heat storage and evaporation integrated device Q26, high-temperature heat storage and evaporation integrated device R27, high-temperature storage The thermal evaporation integrated device S28 is in a parallel state with each other, and the high-temperature heat transfer working medium can simultaneously heat the high-temperature heat storage and evaporation integrated device Q26, the high-temperature heat storage and evaporation integrated device R27, and the high-temperature heat storage and evaporation integrated device S28 to the set temperature .
当使用蒸汽量较大,蒸发所需能量较多,需要多个高温储热蒸发一体化装置同时工作加热蒸汽时,同时打开蒸发管路上的阀门I18,阀门J19,阀门K20,阀门L21,阀门M22,阀门N23,阀门O24,阀门P25,低温蒸汽被高温储热蒸发一体化装置Q26、高温储热蒸发一体化装置R27、高温储热蒸发一体化装置同时加热到设定参数。When the amount of steam used is large, the energy required for evaporation is large, and multiple high-temperature heat storage and evaporation integrated devices are required to work at the same time to heat the steam, open the valve I18, valve J19, valve K20, valve L21, and valve M22 on the evaporation pipeline at the same time , valve N23, valve O24, valve P25, the low-temperature steam is simultaneously heated to the set parameters by the high-temperature heat storage and evaporation integrated device Q26, the high-temperature heat storage and evaporation integrated device R27, and the high-temperature heat storage and evaporation integrated device.
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| CN104344756A (en) * | 2013-07-26 | 2015-02-11 | 国电新能源技术研究院 | Novel photo-thermal power station thermal storage device |
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