CN101614107B - Matrix drill bits and method of manufacture - Google Patents
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Abstract
本发明公开了一种胎体钻头以及由胎体材料的复合物制造胎体钻头体的方法。可以利用两种或者更多种胎体材料形成复合胎体钻头体。可以选择第一胎体材料,以便对于胎体钻头体的诸如刀具承窝、切削结构、刀身、排屑槽以及和啮合并除去地层材料相关的其它部分,提供最佳的耐破裂性(坚韧性),以及最佳的抗腐蚀性、耐磨耗性和耐磨损性。可以选择第二胎体材料,以便提供向所需的热的液体粘合剂材料与第一胎体材料的熔渗,以便形成坚固的粘在一起的复合胎体钻头体。
The invention discloses a matrix drill bit and a method for manufacturing a matrix drill bit body from a matrix material compound. Composite matrix bit bodies may be formed using two or more matrix materials. The first matrix material may be selected to provide optimum fracture resistance (toughness) to the matrix bit body such as the tool socket, cutting structure, cutter body, flute and other portions associated with engaging and removing formation material. ), and the best corrosion resistance, abrasion resistance and wear resistance. The second carcass material can be selected to provide the required infiltration of the hot liquid binder material with the first carcass material to form a strong bonded composite carcass bit body.
Description
本发明专利申请是申请日为2006年4月13日、申请号为200610073633.0、发明名称为“胎体钻头及制造方法”的发明专利申请的分案申请。The patent application of the present invention is a divisional application of the patent application for invention with the filing date being April 13, 2006, the application number being 200610073633.0, and the title of the invention being "matrix drill bit and manufacturing method".
相关申请related application
本申请要求2005年4月14日提出的申请序列号为60/671,272、标题为“MATRIX DRILL BITS AND METHOD OFMANUFACTURE,”(胎体钻头及制造方法)的美国临时专利申请的优先权。This application claims priority to U.S. Provisional Patent Application Serial No. 60/671,272, filed April 14, 2005, and entitled "MATRIX DRILL BITS AND METHOD OF MANUFACTURE," (matrix drill bit and method of manufacture).
技术领域 technical field
本发明涉及旋转式钻头,更具体地说,涉及具有复合胎体(matrix)钻头体的胎体钻头(matrix drill bit),所述复合胎体钻头体部分地由至少第一胎体材料和第二胎体材料形成。The present invention relates to rotary drill bits, and more particularly, to matrix drill bits having a matrix drill bit body composed in part of at least a first matrix material and a second matrix material. Two carcass materials are formed.
背景技术 Background technique
旋转式钻头常常用于钻油井和气井、地热井以及水井。旋转式钻头一般可以分为旋转锥或滚锥钻头,以及固定刀具钻进设备(fixedcutter drilling equipment)或者切削型钻头。固定刀具钻头或者切削型钻头常常利用胎体钻头体形成,所述胎体钻头体具有设置在该胎体钻头体的外部的选定位置上的切削单元或者嵌入件(insert)。典型地,在胎体钻头体上形成流体流动通道,以便能够从相关的表面钻进设备的通过安装在胎体钻头体上的钻杆柱或者钻管传送钻井液。这种固定刀具钻头或者切削型钻头有时可以被称为“胎体钻头”。Rotary drill bits are often used to drill oil and gas wells, geothermal wells, and water wells. Rotary drills can generally be divided into rotary cone or roller cone drills, and fixed cutter drilling equipment or cutting drills. Fixed cutter bits or cutting bits are often formed using a matrix bit body with cutting elements or inserts disposed at selected locations on the exterior of the matrix bit body. Typically, fluid flow channels are formed in the matrix bit body to enable the transfer of drilling fluid from the associated surface drilling equipment through a drill string or drill pipe mounted on the matrix bit body. Such fixed cutter bits or cutting bits may sometimes be referred to as "matrix bits".
典型地,胎体钻头通过将松散的胎体材料(有时称为“胎体粉末”)放入到模具内,并利用例如铜合金等粘合剂熔渗胎体材料。模具可以通过铣削例如石墨等材料块确定出模腔,该模腔带有通常与所获得的胎体钻头的所需外部特征相对应的特征。通过成形模腔和/或通过在模腔的内部配置临时置换(displacement)材料,可以提供所制成的胎体钻头各种特征,例如刀身、刀槽(cutter pocket)、和/或流体流动通道。可以将预制钢柄或者钻头坯件放入模腔内,以便加强胎体钻头体,并允许所制成的胎体钻头与钻杆柱的连接。Typically, a carcass drill is formed by placing loose carcass material (sometimes called "carcass powder") into a mold and infiltrating the carcass material with a binder such as a copper alloy. The mold can be defined by milling a block of material such as graphite to define a cavity with features that generally correspond to the desired external features of the resulting matrix bit. By shaping the mold cavity and/or by disposing a temporary displacement material inside the mold cavity, various features of the resulting matrix drill bit, such as blades, cutter pockets, and/or fluid flow channels, can be provided. . A prefabricated steel shank or bit blank may be placed into the mold cavity to reinforce the matrix bit body and allow the connection of the finished matrix bit to the drill string.
然后,将一定量的典型地为粉末形式的胎体材料放入模腔内。可以利用熔融的金属合金或者粘合剂对胎体材料进行熔渗,在粘合剂凝固之后,和胎体材料一起形成胎体钻头体。通常使用碳化钨粉末形成传统的胎体钻头体。A quantity of carcass material, typically in powder form, is then placed into the mold cavity. The matrix material may be infiltrated with a molten metal alloy or a binder, and after the binder solidifies, forms the matrix bit body together with the matrix material. Tungsten carbide powder is often used to form the body of a conventional matrix bit.
发明内容 Contents of the invention
根据本公开的教导,将第一胎体材料和第二胎体材料相互配合,以便消除或者充分减少在形成没有内部缺陷的致密的胎体钻头时所遇到的问题。本公开的一个方面,可以包括:将第一胎体材料装入到模具内以便形成刀身、刀槽、排屑槽(junk slots)和相关的胎体钻头的其它外部部分。可以将金属坯料或者铸芯安装在模具内第一胎体材料的上方。然后可以将第二胎体材料添加到模具内。可以选择第二胎体材料,以便允许液体粘合剂材料快速地熔渗到第一胎体材料中,或者能够快速地遍及第一胎体材料流动。从而,可以充分地减少或者消除粘合剂材料和第一胎体材料在最后凝固的部分中的合金偏析。第一胎体材料对于相关的复合胎体钻头,还可以提供所需的横向断裂强度、冲击强度、腐蚀、磨耗和磨损特性的增强。In accordance with the teachings of the present disclosure, the first and second carcass materials are mated to eliminate or substantially reduce the problems encountered in forming a dense carcass bit free of internal defects. One aspect of the present disclosure may include loading a first carcass material into a mold to form the body, sipe, junk slots and other exterior portions of the associated carcass bit. A metal blank or casting core may be mounted in the mold above the first carcass material. A second carcass material can then be added to the mold. The second carcass material may be selected so as to allow the liquid binder material to infiltrate rapidly into, or flow rapidly throughout, the first carcass material. Thereby, alloy segregation of the binder material and the first carcass material in the portion that solidifies last can be substantially reduced or eliminated. The first matrix material may also provide desirable enhancements in transverse rupture strength, impact strength, corrosion, abrasion and wear properties for an associated composite matrix bit.
第二胎体材料和粘合剂之间的配合,可以充分地减少和/或消除与粘合剂材料不能令人满意地通过第一胎体材料熔渗相关的质量问题。通过添加第二胎体材料,可以减少或者消除多孔性、收缩、龟裂、偏析和/或粘合剂材料与第一胎体材料的不粘合。第一胎体材料可以是单独的钨、钛、钽、铌、铬、钒、钼、铪的硬质合金,或者它们的组合和/或球形碳化物。第二胎体材料可以是粗结晶碳化钨和/或钨铸造碳化物。但是,本公开并不局限于烧结的钨碳化物、球形碳化物、粗结晶碳化钨和/或铸造钨碳化物或者它们的混合物。并且,本公开的教导可以用于制造或者铸造比较大的复合胎体钻头体以及比较小的、复杂的复合胎体钻头体。The cooperation between the second carcass material and the binder substantially reduces and/or eliminates quality problems associated with unsatisfactory infiltration of the binder material through the first carcass material. By adding the second carcass material, porosity, shrinkage, cracking, segregation, and/or non-bonding of the binder material from the first carcass material can be reduced or eliminated. The first matrix material may be cemented carbide of tungsten, titanium, tantalum, niobium, chromium, vanadium, molybdenum, hafnium alone, or combinations thereof and/or spherical carbides. The second carcass material may be coarse crystalline tungsten carbide and/or tungsten cast carbide. However, the present disclosure is not limited to sintered tungsten carbide, spherical carbide, coarse crystalline tungsten carbide and/or cast tungsten carbide or mixtures thereof. Also, the teachings of the present disclosure may be used to manufacture or cast relatively large composite matrix bit bodies as well as relatively small, complex composite matrix bit bodies.
本公开的技术效果包括但并不局限于:消除或者充分地减少与胎体钻头的不完全熔渗或者与坚硬的颗粒物质的结合相关的质量问题。这种质量问题的例子包括但并不局限于:合金偏析的减少,不希望的金属间化合物的形成,在相关的胎体钻头体中形成多孔性和/或不希望的孔或者孔隙。Technical effects of the present disclosure include, but are not limited to, eliminating or substantially reducing quality problems associated with incomplete infiltration of matrix bits or bonding with hard particulate matter. Examples of such quality problems include, but are not limited to, reduction of alloy segregation, formation of undesired intermetallic compounds, formation of porosity and/or undesired pores or voids in the associated matrix bit body.
本公开的一个方面包括形成胎体钻头,该钻头具有第一部分或第一区域,所述第一部分或第一区域部分地由硬质合金和/或球形碳化物形成,并且连同改进的耐磨耗性、耐腐蚀性和耐磨损性一起,提供增大的韧度,该钻头还具有第二部分或第二区域,所述第二部分或第二区域部分地由粗结晶碳化钨和/或铸造碳化物形成,该第二部分或第二区域增强热的、液体粘合剂材料在整个硬质合金和/或球形碳化物中的熔渗。An aspect of the present disclosure includes forming a matrix drill bit having a first portion or region formed in part from cemented carbide and/or spherical carbide, along with improved wear resistance properties, corrosion resistance and wear resistance together, providing increased toughness, the drill bit also has a second portion or second region, the second portion or second region is partially composed of coarse crystalline tungsten carbide and/or Cast carbide formation, the second portion or region enhances the infiltration of hot, liquid binder material throughout the cemented carbide and/or spherical carbide.
附图说明 Description of drawings
通过参考下面结合附图所进行的描述,可以对本实施例及其优点得到更完全和充分的理解,在所述附图中,类似的参考标号表示类似的特征,其中:A more complete and adequate understanding of the present embodiments and their advantages may be obtained by referring to the following description taken in conjunction with the accompanying drawings, in which like reference numerals indicate like features, in which:
图1是示意图,表示根据本公开的教导形成的具有胎体钻头体的固定刀具钻头的等角视图;1 is a schematic diagram representing an isometric view of a fixed cutter bit having a matrix bit body formed in accordance with the teachings of the present disclosure;
图2是将部分剖去的剖面示意图,表示模具组件的一个例子,该模具组件带有适合于形成根据本公开的教导的胎体钻头的第一胎体材料和第二胎体材料;2 is a schematic, partially broken-away cross-sectional view illustrating an example of a mold assembly with first and second carcass materials suitable for forming a carcass drill bit according to the teachings of the present disclosure;
图3是将部分剖去的剖面示意图,表示在粘合剂材料熔渗到第一胎体材料和第二胎体材料中之后,从图2所示的模具中取出的胎体钻头体;以及FIG. 3 is a partially cutaway schematic cross-sectional view showing the carcass bit body removed from the mold shown in FIG. 2 after the binder material has infiltrated the first and second carcass materials; and
图4是将部分剖去的剖面示意图,表示适合用于形成根据本公开的教导的胎体钻头体的模具的一个例子。4 is a schematic, partially broken-away cross-sectional view of one example of a mold suitable for use in forming a carcass bit body in accordance with the teachings of the present disclosure.
具体实施方式 Detailed ways
通过参照图1-4,可以最好地理解本公开的优选实施例及其优点,其中,在图1-4中,类似的数字表示相同和类似的部件。Preferred embodiments of the present disclosure and advantages thereof are best understood by referring to FIGS. 1-4 , wherein like numerals indicate like and like parts throughout FIGS. 1-4 .
在本申请中,术语“胎体钻头”和“多个胎体钻头”用于表示“旋转式切削型钻头”、“切削型钻头”、“固定刀具钻头”,或者体现本公开的教导的任何其它的钻头。这种钻头可以用于在地层中形成井眼或者钻孔。In this application, the terms "casing bit" and "matrix bits" are used to mean "rotary cutter bit", "cutting bit", "fixed cutter bit", or any other tool embodying the teachings of this disclosure. Other drill bits. Such a drill bit may be used to form a borehole or drill a hole in an earth formation.
体现本公开的教导的胎体钻头,可以包括胎体钻头体,该胎体钻头体部分地由至少第一胎体材料和第二胎体材料形成。可以将这种胎体钻头描述为具有复合胎体钻头体,因为可以利用至少具有不同工作特性的两种不同胎体材料形成钻头体。如后面将要详细描述的那样,可以利用两种以上的胎体材料形成根据本公开的教导的胎体钻头体。A matrix bit embodying the teachings of the present disclosure may include a matrix bit body formed in part from at least a first matrix material and a second matrix material. Such a matrix bit may be described as having a composite matrix bit body because the bit body may be formed from two different matrix materials having at least different operating characteristics. As will be described in detail below, more than two matrix materials may be utilized to form a matrix bit body according to the teachings of the present disclosure.
对于某些应用,第一胎体材料可以具有增强的韧度或者高的抗破裂性,并且提供所需的抗腐蚀性、抗磨耗性和抗磨损性。优选地,第二胎体材料只有有限数量(如果有的话)的合金材料或者其它污染。第一胎体材料可以包括但不局限于硬质合金或者球形碳化物。第二胎体材料可以包括但不局限于粗结晶碳化钨和/或铸造碳化物。For certain applications, the first carcass material may have enhanced toughness or high fracture resistance and provide desirable corrosion, wear and abrasion resistance. Preferably, the second carcass material has only a limited, if any, amount of alloy material or other contamination. The first carcass material may include, but is not limited to, cemented carbide or spherical carbide. The second carcass material may include, but is not limited to, coarse crystalline tungsten carbide and/or cast carbide.
可以利用各种类型的粘合剂材料熔渗胎体材料,以便形成胎体钻头体。粘合剂材料可以包括但不局限于单独的铜(Cu)、镍(Ni)、钴(Co)、铁(Fe)、钼(Mo)或者以这些金属为基础的合金。合金元素可以包括但不局限于以下元素之一或者多个:锰(Mn)、镍(Ni)、锡(Sn)、锌(Zn)、硅(Si)、钼(Mo)、钨(W)、硼(B)和磷(P)。胎体钻头体可以安装到金属柄上。钻具接头可以安装到该金属柄上,所述钻具接头具有螺纹连接部,该螺纹连接部可操作地使相关的胎体钻头体与钻杆柱、钻管、底部孔组件或者钻井马达可释放地接合。Various types of binder materials may be utilized to infiltrate the matrix material to form the matrix bit body. Binder materials may include, but are not limited to, copper (Cu), nickel (Ni), cobalt (Co), iron (Fe), molybdenum (Mo) alone or alloys based on these metals. Alloying elements may include, but are not limited to, one or more of the following elements: manganese (Mn), nickel (Ni), tin (Sn), zinc (Zn), silicon (Si), molybdenum (Mo), tungsten (W) , boron (B) and phosphorus (P). The matrix bit body can be mounted to a metal shank. A tool joint may be mounted to the metal shank, the tool joint having a threaded connection that operably connects the associated matrix bit body to the drill string, drill pipe, bottom hole assembly or drilling motor. Engage releasably.
在本发明申请中使用的术语“硬质合金”和“多种硬质合金”包括:WC、MoC、TiC、TaC、NbC、Cr3C2、VC以及混合碳化物的固溶体,例如,在金属粘合剂(胎体)相中的WC-TiC、WC-TiC-TaC、WC-TiC(Ta,Nb)C。典型地,可以利用Co、Ni、Fe、Mo和/或其它合金形成金属粘合剂。硬质合金有时也可以称为“复合”碳化物或者烧结碳化物。有些硬质合金也被称之为球形碳化物。但是,硬质合金可以具有不同于球形的很多结构和形状。The terms "tungsten carbide" and "a variety of cemented carbides" used in the application of the present invention include solid solutions of WC, MoC, TiC, TaC, NbC, Cr 3 C 2 , VC and mixed carbides, for example, in metal WC-TiC, WC-TiC-TaC, WC-TiC(Ta,Nb)C in the binder (matrix) phase. Typically, Co, Ni, Fe, Mo, and/or other alloys can be utilized to form the metal binder. Cemented carbides are also sometimes referred to as "composite" carbides or cemented carbides. Some cemented carbides are also called spherical carbides. However, cemented carbide can have many structures and shapes other than spherical.
硬质合金通常被描述为粉末状难熔金属碳化物,利用诸如钴、铁、镍、钼和/或它们的合金等粘合剂材料,通过加压和加热被结合到一起。硬质合金也可以被烧结、粉碎、过筛和/或进行进一步的适当的处理。硬质合金小粒可以用于形成胎体钻头体。粘合剂材料提供延展性和韧性,与铸造碳化物、粗结晶钨碳化物和/或其配制物相比,这种延展性和韧性通常导致硬质合金团粒、球或其它结构具有较大的抗破裂性(韧度)。Cemented carbides are generally described as powdered refractory metal carbides bonded together by pressure and heat using binder materials such as cobalt, iron, nickel, molybdenum and/or their alloys. Cemented carbide can also be sintered, crushed, sieved and/or subjected to further suitable treatments. Carbide pellets may be used to form the matrix bit body. The binder material provides ductility and toughness which generally result in larger cemented carbide grains, balls or other structures compared to cast carbides, coarse crystalline tungsten carbides and/or formulations thereof. Crack resistance (toughness).
在本申请中,有时将用于形成硬质合金的粘合剂材料称为“粘合材料”,以便帮助区分用于形成硬质合金的粘合剂材料与用于形成胎体钻头的粘合剂材料。In this application, the binder material used to form cemented carbide is sometimes referred to as "bonding material" to help distinguish the binder material used to form cemented carbide from the bond used to form the matrix bit agent material.
如后面将要详细描述的,在和硬质合金相关的粘合材料中的金属元素和/或它们的合金,在熔融的熔渗剂通过硬质合金时,在凝固以便形成所需的胎体之前,有可能“污染”如以铜为基础的合金等热的液体(熔化的)熔渗剂,以及与形成胎体钻头相关的其它类型的粘合剂材料。熔融熔渗剂的这种“污染”(熔渗剂被来自于硬质合金的粘合材料的富集),当熔渗剂在毛细管作用的影响下通过硬质合金行进时,会改变熔渗剂的固相线(在该温度以下,熔渗剂全部是固体)和液相线(在该温度以上,熔渗剂全部为液体)。这种现象,对于硬质合金的可润湿性具有不利的作用,会导致在凝固形成所需的胎体之前,硬质合金缺乏令人满意的熔渗。As will be described in detail later, the metal elements and/or their alloys in the cemented carbide-related bonding materials, when the molten infiltrant passes through the cemented carbide, before solidification to form the desired matrix , has the potential to "contaminate" hot liquid (molten) infiltrants such as copper-based alloys, and other types of binder materials associated with forming the matrix bit. This "contamination" of the melt infiltrant (enrichment of the infiltrant by the binder material from the cemented carbide) alters the infiltration as it travels through the cemented carbide under the influence of capillary action The solidus line of the agent (below this temperature, the infiltration agent is all solid) and the liquidus line (above this temperature, the infiltration agent is all liquid). This phenomenon, which has an adverse effect on the wettability of the cemented carbide, can lead to a lack of satisfactory infiltration of the cemented carbide before solidification to form the desired matrix.
铸造碳化物一般可以被描述为具有两相,一碳化钨和碳化二钨。铸造碳化物常常具有不同于硬质合金或球形碳化物的特性,如硬度、可润湿性以及对污染的热的液体粘合剂作出的响应等特性。Cast carbides can generally be described as having two phases, tungsten carbide and ditungsten carbide. Cast carbides often have properties different from cemented carbide or spherical carbides, such as hardness, wettability, and response to contaminated hot liquid binders.
粗结晶碳化钨一般可以被描述为碳化一钨的单晶的比较小的颗粒(粉末),在所述碳化一钨中,带有铸造碳化物、Ni、Fe、以及Fe和Ni等的羰基化合物。硬质合金和粗结晶碳化钨通常均被描述为硬的材料,具有很高的耐磨耗、耐腐蚀以及耐磨损等性能。粗结晶碳化钨也可能具有不同于硬质合金或球形碳化物的特性,如硬度、可润湿性以及对污染的热的液体粘合剂作出的响应等特性。Coarse crystalline tungsten carbide can generally be described as relatively small particles (powder) of single crystals of monotungsten carbide in which carbonyl compounds with cast carbides, Ni, Fe, and Fe and Ni etc. . Both cemented carbide and coarse crystalline tungsten carbide are generally described as hard materials with high resistance to wear, corrosion and wear. Coarse crystalline tungsten carbide may also have properties different from cemented carbide or spherical carbides, such as hardness, wettability, and response to contaminating hot liquid binders.
在本申请中采用的术语“粘合剂”或者“粘合剂材料”包括:铜、钴、镍、铁、这些元素的任何一种合金,或者任何一种能够适合用于形成胎体钻头的其它材料。这种粘合剂一般为相关的胎体钻头提供所需的延展性、韧性以及导热性。其它材料,例如、但不局限于碳化钨,以前已经被用作粘合剂材料,用于提供胎体钻头的耐磨耗性、耐腐蚀性以及耐磨损性。粘合剂材料可以和根据本公开的教导选择出来的两种或更多种不同类型的胎体材料配合,以便形成复合胎体钻头体,与很多传统的胎体钻头相比,所述复合胎体钻头体具有增大的韧性和耐磨损性。The term "binder" or "binder material" as used in this application includes: copper, cobalt, nickel, iron, any alloy of these elements, or any material suitable for forming a matrix bit. other materials. This binder generally provides the required ductility, toughness, and thermal conductivity for the associated matrix bit. Other materials, such as, but not limited to, tungsten carbide, have previously been used as a binder material to provide wear resistance, corrosion resistance, and wear resistance to matrix bits. The binder material can be combined with two or more different types of carcass materials selected in accordance with the teachings of the present disclosure to form a composite carcass bit body that is more compact than many conventional carcass bits. The body bit body has increased toughness and wear resistance.
图1是示意图,表示利用根据根据本公开的教导的复合胎体钻头体形成的胎体钻头或者固定刀具钻头的一个例子。对于如图1所示的实施例,胎体钻头20可以包括金属柄30,复合胎体钻头体50牢固地安装在该金属柄上。金属柄30可以被描述为具有一个部分地被图3中的流体流动通道32所限定的大致中空圆筒形的结构。在金属柄30上,在复合胎体钻头体50相反侧,可以形成各种类型的螺纹连接部,例如American Petroleum Institute(API)接头或者螺纹销34。FIG. 1 is a schematic diagram illustrating one example of a matrix bit or fixed cutter bit formed using a composite matrix bit body according to the teachings of the present disclosure. For the embodiment shown in FIG. 1 , the matrix bit 20 may include a
对于某些应用,可以利用各种技术将大致为圆柱形的金属坯件或者铸坯36(见图2和图3)安装到大致中空圆筒形的金属柄30上。在坯件36和柄30的相邻部分之间,例如,可以形成环形的焊接槽38(见图3)。在坯件36与柄30之间的槽38内可以形成焊缝39。参见图1。流体流动通道或者纵向孔32优选地通过金属柄30和金属坯件36延伸。金属坯件36和金属柄30可以用各种钢合金或者其它与制造旋转钻头相关的金属合金形成。For certain applications, a generally cylindrical metal blank or cast 36 (see FIGS. 2 and 3 ) may be mounted to the generally hollow
胎体钻头可以包括多个形成或者安装在相关的钻头体的外部的切削元件、嵌入件、刀槽、刀身、切削结构、排屑槽、和/或流体流动通道。对于图1、2和3所示的实施例,在复合胎体钻头体50的外部可以形成多个刀身52。刀身52在复合胎体钻头体50上可以相互隔开,以便在它们之间形成流体流动通道或者排屑槽。A matrix bit may include a plurality of cutting elements, inserts, sipes, blades, cutting structures, flutes, and/or fluid flow passages formed or mounted on the exterior of an associated bit body. For the embodiment shown in FIGS. 1 , 2 and 3 , a plurality of blades 52 may be formed on the exterior of the composite
在复合胎体钻头体50上可以形成多个喷嘴口54。在每个喷嘴口54内可以配置各个喷嘴56。对于某些应用,可以将喷嘴56描述为“可互换的”喷嘴。可以将各种钻井液通过利用螺纹接头34安装的钻杆柱(未明确地表示出来)和流体流动通道32从地面钻井设备(未明确地表示出来)抽吸出来,从一个或多个喷嘴56中排出。切屑、钻井岩屑、地层流体和/或钻井液可以通过形成在钻杆柱的外部与相关的井眼(未明确地表示出来)的内部之间的环形部(未明确地表示出来)返回到井面。A plurality of
多个槽或者凹槽58可以形成在刀身52的选定的位置上。见图3。各个切削元件或者嵌入件60可以牢固地安装到每个槽58上,以便与井下地层的相邻的部分啮合并将该部分除去。在胎体钻头20被所连接的钻杆柱旋转的过程中,切削元件60可以从井眼的底部和侧面上刮削和刨削地层材料。对于某些应用,作为嵌入件60,可以令人满意地使用多晶金刚石复合片(PDC)刀具。具有这种PDC刀具的胎体钻头,有时被称作“PDC钻头”。A plurality of slots or
标题为“Bladed Drill Bit with Centrally Distributed DiamondCutters”(“带有配置在中心的金刚石刀具的有刀身的钻头”)的美国专利U.S.Patent 6,296,069,以及标题为“Drag-Bit Drilling withMultiaxial Tooth Inserts”(带有多轴齿嵌入件的切削型钻头的钻削)的美国专利U.S.Patent 6,302,224给出了各种刀身和/或切削元件的例子,所述刀身和切削元件可以和体现本公开的教导的复合胎体钻头一起使用。对于本领域普通技术人员而言,显而易见,各种各样的固定刀具钻头、切削型钻头以及其它钻头,都可以令人满意地利用体现根据本公开的教导复合胎体钻头形成。本公开并不局限于图1-4所示的胎体钻头20或者任何特定的部件。U.S. Patent 6,296,069 entitled "Bladed Drill Bit with Centrally Distributed Diamond Cutters" ("Bladed Drill Bit with Centrally Distributed Diamond Cutters"), and U.S. Patent 6,296,069 entitled "Drag-Bit Drilling with Multiaxial Tooth Inserts" (with U.S. Patent 6,302,224 to U.S. Patent 6,302,224 gives examples of various blades and/or cutting elements that can be combined with a composite matrix embodying the teachings of this disclosure Use with a drill. It will be apparent to those of ordinary skill in the art that a wide variety of fixed cutter drills, cutting drills, and other drills can be satisfactorily formed using composite matrix drills embodying the teachings in accordance with the present disclosure. The present disclosure is not limited to the carcass bit 20 shown in FIGS. 1-4 or to any particular components.
可以令人满意地将各种各样的模具用于形成根据本公开的教导的复合胎体钻头体以及相关的胎体钻头。图2和4所示的模具组件100只代表适合于在形成根据本公开的复合胎体钻头体时使用的模具组件的一个例子。标题为“Method And Apparatus For Manufacturing AndInspecting The Quality Of A Matrix Body Drill Bit”(“用于制造胎体钻头以及检查的该钻头的质量的方法和设备”)的美国专利U.S.Patent5,373,907,给出了与有关的模具组件及传统的胎体钻头体的补充细节。A wide variety of molds may be satisfactorily used to form composite carcass bit bodies and related carcass bits according to the teachings of the present disclosure. The
图2和4中所示的模具组件100可以包括几个构件,例如,模具102、环规或者连接器环110和浇口(funnel)120。模具102、环规110和浇口120可以用石墨或者其它适合的材料制成。可以采用各种技术,包括但不局限于将石墨坯料进行机械加工,以便制造带有模腔104的模具102,该模腔104具有用于所制成的固定刀具钻头的所需的外部特征的负轮廓或者相反轮廓。例如,模腔104可以具有对应于图1所示的刀身52和排屑槽或者形成在它们之间的流体流动通道的外部轮廓或者结构的负轮廓。The
如图4所示,可以将多个模具插入件106放入模腔104内,以便形成刀身52中的各个槽58。模具插入件106在模腔104中的位置,与把切削元件60安装到相关的刀身52中所需的位置相对应。模具插入件106可以利用各种类型的材料制成,例如,但不局限于固结砂和石墨。可以利用各种技术,例如硬钎焊,用于将切削元件60安装到各个槽58内。As shown in FIG. 4 , a plurality of mold inserts 106 may be placed into the
可以根据所制成的胎体钻头的所需的结构,将各种类型的临时置换材料令人满意地安装到模腔104内。可以将由诸如固结砂和/或石墨等各种材料形成的附加的模具插入件(未明确地表示出来)配置在模腔104内。可以很好地利用各种树脂形成固结砂。这种模具插入件,可以具有与所需的复合胎体钻头体50的外部部件、例如与形成在相邻的刀身52之间的流体流动通道相对应的结构。如后面将要详细描述的,可以将具有增大的坚韧性或者抗破裂性的第一胎体材料装载到模腔104内,以便形成相关的复合胎体钻头体的部分,所述钻头体的部分在井眼的钻进过程中与井下地层材料啮合,并将其除去。Various types of temporary replacement material may be satisfactorily installed within the
复合胎体钻头体50可以包括比较大的流体腔或室32,该流体腔或室32带有多个从该腔或室延伸的流体流动通道42和44。见图3。如图2所示,可以将诸如固结砂等置换材料安装到模具组件100内的所需部位上,以便形成腔32以及从该腔起延伸的流体流动通道42和44。这种置换材料可以具有各种结构。可以选择固结砂腿142和144的取向和结构,使之和相关的流体流动通道42和44的所需位置和结构相对应,其中,所述流体流动通道42和44从腔32通向各个喷嘴排出口54。流体流动通道42和44可以接纳螺纹插座(未明确地示出),用于将各个喷嘴保持在其内。The composite
可以将一个比较大的、大致为圆柱形的固结砂芯150置于腿142和144上。芯150和腿142及144有时可以被描述为具有“鸦爪”(crow’sfoot)形。芯150也可以称之为“茎”(stalk)。从芯150延伸的腿的数目以在所制成的复合钻头体上的所需的喷嘴开口的数目为依据。腿142和144和芯150也可以用石墨或者其它合适的材料形成。A relatively large, generally cylindrical core of
在包括芯150和腿142及144在内的所需的置换材料已经被安装到模具组件100内之后,可以将具有最佳的耐破裂特性(坚韧性)以及最佳的耐腐蚀性、耐磨耗性以及耐磨损性的第一胎体材料131放入到模具组件100内。第一胎体材料131将优选地形成将大致对应于复合胎体钻头体50的外部部分的第一区域或者第一层,所述第一区域或第一层在井眼的钻进过程中与地层材料接触,并将其除去。添加到模具组件120中的第一胎体材料131优选是有限的,使得胎体材料131不与芯150的端部152接触。本公开允许利用具有最佳韧度以及耐磨损特性的胎体材料形成固定刀具钻头或者切削型钻头。After the required replacement material, including the
然后,可以将大致为中空圆筒形金属坯料36放置到模具组件100内。金属坯料36优选地包括比砂芯150的外径大的内径37。可以利用各种夹具(未明确示出)将金属坯料36定位到模具组件100内与第一胎体材料131隔开的所需位置处。A generally hollow cylindrical metal blank 36 may then be placed into the
然后,可以将第二胎体材料132装载到模具组件100内,以便填充形成在砂芯150的外径154与金属坯料36的内径37之间的孔隙或者环带。优选地,第二胎体材料132覆盖第一胎体材料131,包括靠近芯150的端部152并且与之隔开的第一胎体材料131的部分在内。A
对于某些应用,优选地,第二胎体材料132以如下的方式装载,即,消除第二胎体材料132暴露在复合胎体钻头体50外部的部分,或者将该暴露部分降低到最低限度。第一胎体材料131主要被用于形成在胎体钻头20旋转以便形成井眼的过程中与切削、刨削和刮削井下地层材料相关的复合胎体钻头体50的外部部分。第二胎体材料132主要用于形成通常与切削、刨削和刮削井下地层材料不相关的复合胎体钻头体50的内部部分和外部部分。见图2和3。For some applications, it is preferred that the
对于有些应用,然后可以将诸如钨粉末等第三胎体材料133放入到模具组件100中的金属坯料36的外径40与漏斗120的内径122之间。第三胎体材料133可以是比较软的粉末,该第三胎体材料形成接下来可以被机械加工以便提供所需的外部结构以及胎体钻头体50与金属柄36的之间的过渡部的胎体。第三胎体材料133有时被描述为“熔渗的可加工的粉末”。装载第三胎体材料133,以便覆盖全部或者基本上全部靠近复合胎体钻头体50的外部的第二胎体材料132。见图2和3。For some applications, a
在胎体材料131、132和133的装载过程中,必须注意,防止第一胎体材料131和第二胎体材料132之间的不希望的混合,以及第二胎体材料132和第三胎体材料133之间的不希望的混合。在界面处轻微的混合以便避免不同胎体材料之间的明显的分界,对于相邻层之间的结合,可以提供顺滑的过渡。当把硬质合金和球形碳化物配置在与用于固定切削器钻头的胎体钻头体相关的比较复杂的模具组件中时,以前的经验和试验已经显示出与利用热的、液体粘合剂材料熔渗硬质合金和球形碳化物相关的各种问题。当试图利用硬质合金和/或球形碳化物形成用于和钻探及建造油气井相关的其它类型的复杂的井下工具时,也注意到了类似的问题。During the loading of the
与利用硬质合金和/或球形碳化物作为胎体材料相关的制造问题以及所造成的质量问题,一般与在所制成的胎体钻头体的内部的熔渗不足、多孔性、收缩、龟裂以及粘合剂材料组分的偏析有关。很多固定切削器钻头的比较错综复杂的设计和大的尺寸,对于具有硬质合金和/或球形碳化物作为胎体材料的钻头体的可制造性提出困难的挑战。在至少部分地利用硬质合金和球形碳化物的胎体形成的诸如铰刀、扩孔器以及组合的铰刀/钻头等其它的井下工具的制造过程中,也会发生同样的质量问题。这种组合的井下工具的一个例子,在标题为“Bi-center And Bit Method For Enhenced Stability.”(“用于提高稳定性的双中心和钻头法”)美国专利U.S.Patent 5,678,644中给出。The manufacturing problems associated with utilizing cemented carbide and/or spherical carbide as the matrix material, as well as resulting quality issues, are generally related to insufficient infiltration, porosity, shrinkage, torsion, etc. Cracking and segregation of binder material components. The relatively intricate design and large size of many fixed cutter bits present difficult challenges to the manufacturability of bit bodies having cemented carbide and/or spherical carbide as matrix material. The same quality problems occur in the manufacture of other downhole tools, such as reamers, reamers, and combined reamer/drill bits, formed at least in part with a matrix of cemented carbide and spherical carbide. An example of such a combined downhole tool is given in U.S. Patent 5,678,644 entitled "Bi-center And Bit Method For Enhanced Stability."
以前,通过将硬质合金和/或球形碳化物和粗结晶碳化钨和/或铸造碳化物粉末预先混合所作的试验和实验,常常不能制造出可靠的、高质量的胎体钻头。增加粘合剂材料在这种硬质合金和/或球形碳化物与粗结晶碳化钨和/或铸造碳化物粉末混合物内的浸泡时间,不能明显地消除与收缩、合金偏析、熔渗不足、多孔性相关的问题,以及与硬质合金和/或球形碳化物不能充分的熔渗相关的其它问题。而且,提高用于这种混合物的熔渗的热的液体粘合剂材料的温度,也不能显著地减少相关的质量问题。已经确认,液体粘合剂材料的最后凝固的部分在硬质合金和/或球形碳化物与结晶碳化物和/或铸造碳化物的各种混合物内的高的合金偏析,是在这种混合物内的粘合不足、不希望有的收缩、多孔性以及其它质量问题的一个原因。Previous trials and experiments by pre-mixing cemented carbide and/or spherical carbide and coarse crystalline tungsten carbide and/or cast carbide powders have often failed to produce reliable, high quality matrix drill bits. Increasing the immersion time of the binder material in such mixtures of cemented carbide and/or spherical carbides with coarse crystalline tungsten carbide and/or cast carbide powders does not significantly eliminate the effects of shrinkage, alloy segregation, insufficient infiltration, porosity problems related to infiltration, and other problems associated with insufficient infiltration of cemented carbide and/or spherical carbides. Furthermore, increasing the temperature of the hot liquid binder material used for infiltration of such mixtures does not significantly reduce the associated quality problems. It has been confirmed that the high alloy segregation of the last solidified portion of the liquid binder material in various mixtures of cemented carbide and/or spherical carbides with crystalline carbides and/or cast carbides, is in such mixtures A cause of insufficient adhesion, unwanted shrinkage, porosity, and other quality issues.
利用第一胎体材料131形成第一层或者区域,与利用第二胎体材料132形成和第一胎体材料131邻接的第二层或者区域相结合,可以充分地减少或者消除在热的、液体粘合剂材料和第一胎体材料131的最后凝固的部分的合金的偏析。在形成于芯150的外径154与金属坯料36的内径37之间的环形部内添加第二胎体材料132,并且如图2所示覆盖第一胎体材料131,可以充分地减少或者消除与熔渗不足、多孔性、收缩、龟裂和/或粘合剂组分在第一胎体材料131内的偏析相关的问题。这些改进的一个原因,可能是因为热的液体粘合剂材料能够很容易熔渗粗结晶碳化钨和/或铸造碳化物粉末的缘故。Utilizing the
如从前注意到的那样,热的液体粘合剂材料可以从用于形成硬质合金的结合材料中滤取或者除去少量的合金和/或其它污染物。被滤取的合金和/或其它污染物可能具有比与胎体钻头的制造相关的典型的粘合剂材料高的熔点。从而,被滤取的合金和/或其它污染物会在相邻的硬质合金团粒、球或者形状之间的小的间隙或者孔隙内凝固,并阻碍热的液体粘合剂材料在这种硬质合金形状之间进一步熔渗。As previously noted, the hot liquid binder material can leach or remove small amounts of alloy and/or other contaminants from the bonding material used to form the cemented carbide. Alloys and/or other contaminants that are leached may have higher melting points than typical binder materials associated with the manufacture of carcass bits. Thus, leached alloy and/or other contaminants can solidify in the small gaps or pores between adjacent cemented carbide pellets, balls or shapes and prevent the hot liquid binder material Further infiltration between the alloy shapes.
“被污染的”熔渗剂或者热的液体粘合剂材料,可能具有不同于“纯的”粘合剂材料的固相线温度和液相线温度。在粘合剂材料的凝固过程中,作为将溶质污染物排斥到凝固前沿的前面的热液体中的结果,可能会发生熔渗剂被污染物的“富集”。除了在凝固的较后的阶段的污染物(溶质)的偏析之外,任何定向凝固的缺乏,都会引起一些潜在的问题,包括但并不局限于收缩、多孔性和/或热裂。"Contaminated" infiltrants, or hot liquid binder materials, may have different solidus and liquidus temperatures than "pure" binder materials. During the setting of the binder material, "enrichment" of the infiltration agent with the contaminants may occur as a result of repelling solute contaminants into the hot liquid ahead of the solidification front. Any lack of directional solidification, in addition to segregation of contaminants (solutes) at later stages of solidification, causes potential problems including, but not limited to, shrinkage, porosity and/or thermal cracking.
粗结晶碳化钨和铸造碳化物粉末,可以基本上没有与用于形成硬质合金的粘合材料相关的合金或其它污染物。可以选择第二胎体材料使之具有小于百分之五(5%)的合金或其它潜在的污染物。从而,热的液体粘合剂材料经过根据本公开的教导所选择的第二胎体材料的熔渗,基本上不会滤取大量的合金或其它潜在的污染物。Coarsely crystalline tungsten carbide and cast carbide powders may be substantially free of alloying or other contaminants associated with binder materials used to form cemented carbides. The second carcass material may be selected to have less than five percent (5%) alloys or other potential contaminants. Thus, infiltration of the hot liquid binder material through the second carcass material selected in accordance with the teachings of the present disclosure does not substantially leach large quantities of alloys or other potential contaminants.
如前面所述,第一胎体材料131可以是硬质合金和/或球形碳化物。钴、铁和/或镍的合金可以用于形成硬质合金和/或球形碳化物。对于某些胎体钻头的设计而言,在第一胎体材料中大约百分之六的合金浓度会提供最佳的结果。对于某些胎体钻头设计而言,百分之三到百分之六之间的合金浓度,以及约百分之六到百分之十五之间的合金浓度,也可以是令人满意的。但是,大于约百分之十五的合金浓度和小于约百分之三的合金浓度会导致所获得的胎体钻头体不能达到最佳特性。As mentioned above, the
第二胎体材料132可以是粗结晶碳化钨或者铸造碳化物粉末。这种粉末的例子包括P-90和P-100,可以从位于Fallon,Nevada的Kennametal,Inc.购得。标题为“Macrocrystalline TungstenMonocarbide Powder and Process for Producing”(粗结晶一碳化钨粉末及其生产工艺)的转让给Kennametal的美国专利U.S.Patent4,834,963,描述了可以用于生产粗结晶碳化钨的技术。第三胎体材料133可以是钨粉,例如M-70,这种钨粉可以从H.C.Starck,OsramSylvania and Kennametal购得。在第二胎体材料132中的典型的合金浓度,可以在约百分之一到百分之二之间。具有约百分之五或更高的合金浓度的第二胎体材料,对于相关的胎体钻头体,可能导致不能令人满意的操作特性。The
对于铸造的复合胎体钻头体50的典型的熔渗过程,可以通过形成模具组件100开始。可以将环规110拧到模具102的顶部。可以将浇口120拧到环规110的顶部,以便将模具组件100延伸到所需的高度,用以保持前面描述的胎体材料和粘合剂材料。然后,可以将置换材料,例如,但并不局限于,模具插入件106、腿142和144以及芯150,如果事先没有放入到模腔104内的话,装载到模具组件100内。如前面所述,可以将胎体材料131、132、133和金属坯料36装载到模具组件100内。A typical infiltration process for a cast composite
在模具组件100被胎体材料填充的情况下,可以在模具组件100内引起一系列的振动循环,以帮助填密胎体材料131、132和133的每一层或区域。这种振动可以在达到复合胎体钻头体50所要求的特性的各个范围内,帮助确保胎体材料131、132和133的每一层的一致的密度。应当避免胎体材料131、132和133的不希望的混合。With
可以将粘合剂材料160放置在层132和133、金属坯料36和芯150的顶部。可以用助熔剂层(未明确示出)覆盖粘合剂材料160。可以将罩或者盖(未明确示出)放置在模具组件100的上方。可以将模具组件100和配置于其内材料进行预热,然后将其置于加热炉内(未明确示出)。当加热炉的温度达到粘合剂材料160的熔点时,液体粘合剂材料160可以熔渗胎体材料131、132和133。如以前已经注意到的那样,第二胎体材料132允许热的液体粘合剂材料160更均匀地熔渗第一胎体材料131,以便避免在液体粘合剂材料160和第一胎体材料131的最后凝固部分中的不希望有的偏析。
模具组件100的上面部分、例如浇口120与模具102相比,可以具有增强的绝热性能(未明确示出)。从而,在热的液体粘合剂材料与第二胎体材料132凝固之前,在模具组件100的下部部分的液体粘合剂材料开始与第一胎体材料131凝固。在凝固中的这种差异,有可能允许热的液体粘合剂材料把从第一胎体材料131中滤取的合金和其它潜在的污染物“漂浮”或者输送到第二胎体材料132中。由于热的液体胎体材料在熔渗第一胎体材料131之前熔渗通过第二胎体材料132,所以,从第一胎体材料131输送来的合金以及其它污染物,对于所制成的胎体钻头体50的质量,不会造成象合金及其它污染物残留在第一胎体材料131中那样大的影响。此外,优选地,第二胎体材料包含小于百分之四(4%)的这种合金或污染物。The upper portion of the
在靠近诸如喷嘴开口54和槽58等特征的部位,粘合剂材料160与第一胎体材料131的恰当的熔渗和凝固是特别重要的。通过提高粘合剂材料160向形成各个刀身52的第一胎体材料131的部分内的熔渗获得的改进的质量控制,可以设计更薄的刀身52。也可以将刀身52以更具有侵进性的切削角度取向,带有形成在相邻的刀身52之间更大的流体流动面积。Proper infiltration and solidification of the
与具有只利用市场上可以获得的粗结晶碳化钨和/或铸造碳化物粉末或它们配制物形成的胎体钻头体的固定刀具钻头的相同设计相比,对于某些根据本公开的教导形成的带有第一胎体材料和第二胎体材料的复合钻头体的固定刀具钻头的设计而言,可以将耐磨耗性改进百分之五十(50%),耐腐蚀性改进百分之百(100%),横向抗破裂强度改进百分之五十(50%),有时抗冲击性的改进超过百分之百(100%)。Compared to the same design of a fixed cutter bit having a matrix bit body formed using only coarse crystalline tungsten carbide and/or cast carbide powders or formulations thereof that are commercially available, for certain drill bits formed in accordance with the teachings of the present disclosure Fifty percent (50 percent) improvements in wear resistance and one hundred percent (100 percent) improvements in corrosion resistance are possible for designs of fixed cutter drill bits with a composite bit body of a first matrix material and a second matrix material. %), fifty percent (50%) improvement in transverse rupture strength, and sometimes more than one hundred percent (100%) improvement in impact resistance.
然后,可以将模具组件100从加热炉中移出,并以受控制的速度冷却。一旦冷却,可以将模具组件100脱去,使复合胎体钻头体50暴露出来,如图3所示。可以根据公知的技术采用后续处理,以便制造胎体钻头20。The
尽管详细地描述了本公开及其优点,但是,应当理解,在不超出由下面的权利要求所限定的本公开的精神和范围内,可以进行各种变化、取代和变换。Although the present disclosure and its advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the disclosure as defined by the following claims.
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| CN107923224A (en) * | 2015-09-22 | 2018-04-17 | 哈里伯顿能源服务公司 | Mechanically Interlocked Reinforced Particles for Metal Matrix Composites Tools |
| CN106424854A (en) * | 2016-09-26 | 2017-02-22 | 卓拓精密工具(苏州)有限公司 | Hard alloy drill bit |
| CA3071977C (en) | 2017-08-04 | 2021-02-09 | Bly Ip Inc. | Diamond bodies and tools for gripping drill rods |
| CN107739882A (en) * | 2017-10-17 | 2018-02-27 | 成都哈顿石油钻采工具有限公司 | A kind of matrix drill bits immersion solder and preparation method thereof |
| CN110643880B (en) * | 2019-11-07 | 2020-11-13 | 广东省材料与加工研究所 | Drill bit matrix material and preparation method thereof |
| WO2021168297A1 (en) * | 2020-02-19 | 2021-08-26 | Esco Group Llc | Wear member |
| CN111822714B (en) * | 2020-06-15 | 2021-06-08 | 中国地质大学(武汉) | Diamond-impregnated bit matrix material and method for manufacturing high-adaptability diamond bit by using same |
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| US4884477A (en) * | 1988-03-31 | 1989-12-05 | Eastman Christensen Company | Rotary drill bit with abrasion and erosion resistant facing |
| CN2078789U (en) * | 1990-12-03 | 1991-06-12 | 地质矿产部探矿工程研究所 | Diamond bit for oil drilling |
| US6045750A (en) * | 1997-10-14 | 2000-04-04 | Camco International Inc. | Rock bit hardmetal overlay and proces of manufacture |
| US6089123A (en) * | 1996-09-24 | 2000-07-18 | Baker Hughes Incorporated | Structure for use in drilling a subterranean formation |
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| US6095265A (en) * | 1997-08-15 | 2000-08-01 | Smith International, Inc. | Impregnated drill bits with adaptive matrix |
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- 2006-04-13 CN CNB2006100736330A patent/CN100567696C/en not_active Expired - Fee Related
- 2006-04-13 CN CN 200910140144 patent/CN101614107B/en not_active Expired - Fee Related
Patent Citations (5)
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|---|---|---|---|---|
| US4274769A (en) * | 1978-04-21 | 1981-06-23 | Acker Drill Company, Inc. | Impregnated diamond drill bit construction |
| US4884477A (en) * | 1988-03-31 | 1989-12-05 | Eastman Christensen Company | Rotary drill bit with abrasion and erosion resistant facing |
| CN2078789U (en) * | 1990-12-03 | 1991-06-12 | 地质矿产部探矿工程研究所 | Diamond bit for oil drilling |
| US6089123A (en) * | 1996-09-24 | 2000-07-18 | Baker Hughes Incorporated | Structure for use in drilling a subterranean formation |
| US6045750A (en) * | 1997-10-14 | 2000-04-04 | Camco International Inc. | Rock bit hardmetal overlay and proces of manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101614107A (en) | 2009-12-30 |
| CN100567696C (en) | 2009-12-09 |
| CN1904306A (en) | 2007-01-31 |
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