CN101591486A - Anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning and production method - Google Patents
Anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning and production method Download PDFInfo
- Publication number
- CN101591486A CN101591486A CNA2009100323774A CN200910032377A CN101591486A CN 101591486 A CN101591486 A CN 101591486A CN A2009100323774 A CNA2009100323774 A CN A2009100323774A CN 200910032377 A CN200910032377 A CN 200910032377A CN 101591486 A CN101591486 A CN 101591486A
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- Prior art keywords
- graffiti
- easy cleaning
- monomer
- flow agent
- weight percent
- Prior art date
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- 238000004140 cleaning Methods 0.000 title claims abstract description 21
- 150000001252 acrylic acid derivatives Chemical class 0.000 title claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000003999 initiator Substances 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- QWYSJTTWCUXHQO-UHFFFAOYSA-N [F].OC(=O)C=C Chemical compound [F].OC(=O)C=C QWYSJTTWCUXHQO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000001282 organosilanes Chemical class 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- -1 difluoro heptyl esters Chemical class 0.000 claims description 6
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical group COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical group CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 3
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 10
- 230000002209 hydrophobic effect Effects 0.000 abstract description 2
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning, is that the raw material mixing is formed by acrylate monomer, vinylformic acid fluorine monomer, organosilane monomer, initiator, solvent.The present invention can make coating have anti-graffiti and the easy cleaning function, and solvent-borne type marking pen on coating surface is drawn is as long as xerotripsis can be removed its hydrophobic and also raising greatly of oleophobic property fully.
Description
Technical field:
The present invention relates to a kind of coating flow agent.
Background technology:
Existing coating does not have anti-graffiti and the easy cleaning function, makes use range be restricted.
Summary of the invention:
The object of the present invention is to provide a kind of have anti-graffiti and fluorinated silicone modified acrylate flow agent of the anti-graffiti and easy cleaning easy cleaning function and production method.
Technical solution of the present invention is:
A kind of anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning, it is characterized in that: the raw material by following weight item is formed:
Acrylate monomer 5-30%
Vinylformic acid fluorine monomer 1-15%
Organosilane monomer 20-70%
Initiator 1-30%
Solvent 20-70%.
Acrylate monomer is lauryl methacrylate(LMA), stearyl methacrylate, butyl acrylate or Isooctyl acrylate monomer.
The vinylformic acid fluorine monomer is vinylformic acid 19 fluorine heptyl esters, vinylformic acid trifluoro butyl ester, methacrylic acid ten difluoro heptyl esters, vinylformic acid hexafluoro butyl ester or perfluoroalkyl acrylate.
Initiator is benzoyl peroxide or Diisopropyl azodicarboxylate.
Solvent is propylene glycol monomethyl ether, N-BUTYL ACETATE or 1-Methoxy-2-propyl acetate.
A kind of production method of the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning is characterized in that: comprise the following steps:
At first the solvent of 15-60% weight percent is poured in the reactor, be warming up to 115-150 ℃, solvent refluxing 30 minutes; Simultaneously with the acrylate monomer of 5-30% weight percent, the vinylformic acid fluorine monomer of 1-15% weight percent, after the initiator of the organosilane monomer of 20-70% weight percent and 0.5-20% weight percent mixes, under 115-150 ℃ temperature, be added drop-wise in the reactor in 3-5 hour, carry out solution polymerization, drip and finish back insulation 2-5 hour; Add solvent and initiator, make that the weight percent of solvent reaches 20～70%, the weight percent of initiator reaches 1～30%; Be incubated 2-3 hour again after drip finishing, cool off product.
The present invention can make coating have anti-graffiti and the easy cleaning function, and solvent-borne type marking pen on coating surface is drawn is as long as xerotripsis can be removed its hydrophobic and also raising greatly of oleophobic property fully.Succeeding in developing of this flow agent changed the unitary system making method of making anti-graffiti and easy cleaning coating originally with fluorine silicon resin, also greatly reduces anti-graffiti and production cost easy cleaning coating.As long as in common paint, add a certain amount of anti-graffiti and easy cleaning flow agent, can make anti-graffiti and easy cleaning coating.
The invention will be further described below in conjunction with embodiment.
Embodiment:
At first the solvent propylene glycol monomethyl ether (or N-BUTYL ACETATE or 1-Methoxy-2-propyl acetate) of 15-60% weight percent (example 25%, 45%, 65%) is poured in the reactor, be warming up to 115-150 ℃, solvent refluxing 30 minutes; Simultaneously with 5-30% (example 5%, 15%, 30%) the acrylate monomer lauryl methacrylate(LMA) of weight percent (or stearyl methacrylate or butyl acrylate or Isooctyl acrylate monomer), 1-15% (1%, 5%, 15%) the vinylformic acid fluorine monomer vinylformic acid 19 fluorine heptyl esters of weight percent (or vinylformic acid trifluoro butyl ester or methacrylic acid ten difluoro heptyl esters or vinylformic acid hexafluoro butyl ester or perfluoroalkyl acrylate), 20-70% (example 20%, 50%, 70%) organosilane monomer of weight percent (Dow Corning Corporation's product, as: Dow Coming32#, 6502#, 81#) and 0.5-20% (example 0.5%, 10%, 20%) after the initiator benzoyl peroxide (or Diisopropyl azodicarboxylate) of weight percent mixes, under 115-150 ℃ temperature, be added drop-wise in the reactor in 3-5 hour, carry out solution polymerization, drip and finish back insulation 2-5 hour; Add solvent and initiator, make that the weight percent of solvent reaches 20～70%, the weight percent of initiator reaches 1～30%; Be incubated 2-3 hour again after drip finishing, cool off to such an extent that be used for the fluorinated silicone modified acrylate flow agent of anti-graffiti and easy cleaning of coating.
Claims (6)
1, a kind of anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning, it is characterized in that: the raw material by following weight item is formed:
Acrylate monomer 5-30%
Vinylformic acid fluorine monomer 1-15%
Organosilane monomer 20-70%
Initiator 1-30%
Solvent 20-70%.
2, the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning according to claim 1, it is characterized in that: acrylate monomer is lauryl methacrylate(LMA), stearyl methacrylate, butyl acrylate or Isooctyl acrylate monomer.
3, the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning according to claim 1 is characterized in that: the vinylformic acid fluorine monomer is vinylformic acid 19 fluorine heptyl esters, vinylformic acid trifluoro butyl ester, methacrylic acid ten difluoro heptyl esters, vinylformic acid hexafluoro butyl ester or perfluoroalkyl acrylate.
4, the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning according to claim 1, it is characterized in that: initiator is benzoyl peroxide or Diisopropyl azodicarboxylate.
5, the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning according to claim 1, it is characterized in that: solvent is propylene glycol monomethyl ether, N-BUTYL ACETATE or 1-Methoxy-2-propyl acetate.
6, a kind of production method of the anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning is characterized in that: comprise the following steps:
At first the solvent of 15-60% weight percent is poured in the reactor, be warming up to 115-150 ℃, solvent refluxing 30 minutes; Simultaneously with the acrylate monomer of 5-30% weight percent, the vinylformic acid fluorine monomer of 1-15% weight percent, after the initiator of the organosilane monomer of 20-70% weight percent and 0.5-20% weight percent mixes, under 115-150 ℃ temperature, be added drop-wise in the reactor in 3-5 hour, carry out solution polymerization, drip and finish back insulation 2-5 hour; Add solvent and initiator, make that the weight percent of solvent reaches 20～70%, the weight percent of initiator reaches 1～30%; Be incubated 2-3 hour again after drip finishing, cool off product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100323774A CN101591486A (en) | 2009-06-12 | 2009-06-12 | Anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning and production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100323774A CN101591486A (en) | 2009-06-12 | 2009-06-12 | Anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning and production method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101591486A true CN101591486A (en) | 2009-12-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009100323774A Pending CN101591486A (en) | 2009-06-12 | 2009-06-12 | Anti-graffiti and fluorinated silicone modified acrylate flow agent of easy cleaning and production method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101591486A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134415A (en) * | 2011-03-11 | 2011-07-27 | 陈永康 | Fluorine-containing acrylate leveling agent for solvent type coating |
| CN102134416A (en) * | 2011-03-11 | 2011-07-27 | 陈永康 | Fluorine-containing acrylate leveling agent for environment-friendly type water-soluble coating |
| CN102181198A (en) * | 2011-05-25 | 2011-09-14 | 陈永康 | Fluoride-containing anti-flood and anti-float hyperdispersant used for solvent-based coating ink and preparation method of hyperdispersant |
| CN102241910A (en) * | 2011-05-25 | 2011-11-16 | 陈永康 | Hyper-dispersant with leveling function for solvent-based coating and ink and preparation method thereof |
| CN102634246A (en) * | 2011-06-21 | 2012-08-15 | 漳州鑫展旺化工有限公司 | Additive for improving appearance of paint and synthesis method thereof |
| WO2012122722A1 (en) * | 2011-03-11 | 2012-09-20 | Chen Yongkang | Fluorocarbon anti-cratering levelling agent for coatint and ink |
| WO2013028326A1 (en) * | 2011-08-19 | 2013-02-28 | Neenah Paper, Inc. | Durable, heat resistant, erasable release coatings, release coated substrates, and their methods of manufacture |
| CN103319722A (en) * | 2013-07-04 | 2013-09-25 | 安徽嘉智信诺化工有限公司 | Modified polysiloxane flatting agent containing fluorinated polyether for paint ink |
| CN105175622A (en) * | 2015-07-31 | 2015-12-23 | 安徽嘉智信诺化工股份有限公司 | Reaction-type paint, auxiliary agent for printing ink and synthetic method |
| CN106833099A (en) * | 2017-02-17 | 2017-06-13 | 重庆文理学院 | A kind of surface control agent and preparation method thereof |
| CN107652746A (en) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | A kind of esters of acrylic acid levelling agent |
-
2009
- 2009-06-12 CN CNA2009100323774A patent/CN101591486A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012122722A1 (en) * | 2011-03-11 | 2012-09-20 | Chen Yongkang | Fluorocarbon anti-cratering levelling agent for coatint and ink |
| CN102134416A (en) * | 2011-03-11 | 2011-07-27 | 陈永康 | Fluorine-containing acrylate leveling agent for environment-friendly type water-soluble coating |
| CN102134415A (en) * | 2011-03-11 | 2011-07-27 | 陈永康 | Fluorine-containing acrylate leveling agent for solvent type coating |
| CN102181198A (en) * | 2011-05-25 | 2011-09-14 | 陈永康 | Fluoride-containing anti-flood and anti-float hyperdispersant used for solvent-based coating ink and preparation method of hyperdispersant |
| CN102241910A (en) * | 2011-05-25 | 2011-11-16 | 陈永康 | Hyper-dispersant with leveling function for solvent-based coating and ink and preparation method thereof |
| CN102634246B (en) * | 2011-06-21 | 2014-12-24 | 漳州鑫展旺化工有限公司 | Additive for improving appearance of paint and synthesis method thereof |
| CN102634246A (en) * | 2011-06-21 | 2012-08-15 | 漳州鑫展旺化工有限公司 | Additive for improving appearance of paint and synthesis method thereof |
| WO2013028326A1 (en) * | 2011-08-19 | 2013-02-28 | Neenah Paper, Inc. | Durable, heat resistant, erasable release coatings, release coated substrates, and their methods of manufacture |
| US8758548B2 (en) | 2011-08-19 | 2014-06-24 | Neenah Paper, Inc. | Durable, heat resistant, erasable release coatings, release coated substrates, and their methods of manufacture |
| US10519320B2 (en) | 2011-08-19 | 2019-12-31 | Neenah, Inc. | Durable, heat resistant, erasable release coatings, release coated substrates, and their methods of manufacture |
| CN103319722A (en) * | 2013-07-04 | 2013-09-25 | 安徽嘉智信诺化工有限公司 | Modified polysiloxane flatting agent containing fluorinated polyether for paint ink |
| CN105175622A (en) * | 2015-07-31 | 2015-12-23 | 安徽嘉智信诺化工股份有限公司 | Reaction-type paint, auxiliary agent for printing ink and synthetic method |
| CN107652746A (en) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | A kind of esters of acrylic acid levelling agent |
| CN106833099A (en) * | 2017-02-17 | 2017-06-13 | 重庆文理学院 | A kind of surface control agent and preparation method thereof |
| CN106833099B (en) * | 2017-02-17 | 2020-07-07 | 重庆文理学院 | Surface control agent and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20091202 |