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CN100999643A - Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof - Google Patents

Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof Download PDF

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Publication number
CN100999643A
CN100999643A CN 200610156034 CN200610156034A CN100999643A CN 100999643 A CN100999643 A CN 100999643A CN 200610156034 CN200610156034 CN 200610156034 CN 200610156034 A CN200610156034 A CN 200610156034A CN 100999643 A CN100999643 A CN 100999643A
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whisker
resistant
wear
curable coating
agent
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Pending
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CN 200610156034
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Chinese (zh)
Inventor
姚伯龙
赵子千
陈明清
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Jiangnan University
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Jiangnan University
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Abstract

一种晶须耐磨紫外光固化涂料及其制备方法，属于光固化涂层复合材料技术领域。本发明涉及用晶须填充紫外光固化涂料以提高其耐磨性，其组成为：主要包含光敏低聚物、活性稀释剂、光引发剂、晶须、填料及助剂。该涂料可涂于木材、密度板、金属、玻璃或陶瓷表面，形成的涂层性能优异，增韧效果明显，涂膜的耐磨性能得到很大提高，其耐磨性可达0.005～0.02g/(500r，750g)。本发明的晶须耐磨紫外光固化涂料不添加有机溶剂，有利于环保，且施工方便，具有明显的环境效益、社会效益及经济效益。A whisker wear-resistant ultraviolet light curing coating and a preparation method thereof belong to the technical field of light curing coating composite materials. The invention relates to filling ultraviolet curable paint with whiskers to improve its wear resistance. The composition mainly includes photosensitive oligomers, reactive diluents, photoinitiators, whiskers, fillers and auxiliary agents. The coating can be applied to the surface of wood, MDF, metal, glass or ceramics. The formed coating has excellent performance, obvious toughening effect, and the wear resistance of the coating film is greatly improved. The wear resistance can reach 0.005-0.02g / (500r, 750g). The whisker wear-resistant ultraviolet light curing coating of the present invention does not add organic solvents, is beneficial to environmental protection, and is convenient for construction, and has obvious environmental benefits, social benefits and economic benefits.

Description

A kind of crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof
Technical field
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof relates to a kind of wear-resistant paint that can be used for timber, density board, metal, glass, ceramic surface, belongs to the light solidifying coating technical field of composite materials.
Background technology
(UV) is coating material solidified for UV-light, and it is a kind of pollution-free, resource-saving, less energy-consumption, the safe and reliable friendly type coating of high-tech green environment, and its society and environmental benefit are huge; This product meets world's material technology trend, is coating circle new growth point, and the huge fund research and development are just competitively thrown in countries in the world.Now, on the occasion of advocate energetically because of the scarcity of China's energy, resource make up Sustainable development, conservation-minded society when, UV is coating material solidified has applied significance.The coating material solidified output of whole world UV was about 300,000 tons in 2005, and wherein Chinese about 100,000 tons, and annual with the speed increment more than 25%.In China, surpass the coating material solidified application that is used for the floor of UV of 70% sales volume, and also there are many problems in the wear resistance of current UV curing Floor paint.Study a kind of ultraviolet-curing paint that is applied to surface such as timber, density board, pottery, be the target of domestic and international coating circle pursuit with the wear resistance on surfaces such as comprehensive raising timber, density board, pottery always.The present invention mainly selects special wear-resisting crystal whisker materials for use, is equipped with photosensitive oligomer and filler etc. and has prepared the high-performance abrasion-proof ultraviolet-curing paint.
Summary of the invention
The purpose of this invention is to provide a kind of crystal whisker wear-resistant ultraviolet ray solidified paint and preparation method thereof, select that crystal whisker materials and the compound preparation of high performance photosensitive oligomer are a kind of to have better wear resistance, a more high-intensity whisker ultraviolet-curing paint for use.
Technical scheme of the present invention: a kind of crystal whisker wear-resistant ultraviolet ray solidified paint, (%) is as follows for the composition of its each component and weight percent:
Photosensitive oligomer 35～50
Reactive thinner 28～42
Light trigger 3～9
Whisker 5～18
Filler 3～16
Auxiliary agent 1～1.5
Described photosensitive oligomer is one or more in epoxy acrylic oligoesters, urethane acrylate quasi-oligomer, the polyester acrylic oligoesters; Described reactive thinner is in tripropylene glycol diacrylate, Viscoat 295,1,6 hexanediol diacrylate, pentaerythritol triacrylate, neopentylglycol diacrylate, the Isooctyl acrylate monomer two kinds or several; Described light trigger is benzophenones/amines system, benzil two ketals, Benzoin ethyl ether, 1-hydroxyl-phenylcyclohexane ethyl ketone, α, one or more in alpha-alpha-dimethyl-α hydroxy acetophenone, the thioxanthones; Described whisker is a kind of in calcium carbonate crystal whisker, potassium titanate crystal whisker, the ZnOw, and diameter range is 0.5～2 μ m, and length range is 20～40 μ m, carries out the surface modification treatment mistake by silane coupling agent or titanate coupling agent; Described filler is one or more in hollow glass microbead, silicon-dioxide, the elastic particle; Described auxiliary agent comprises wetting dispersing agent, anti-settling agent, flow agent and defoamer.Wetting dispersing agent is the derivatives class of polymer unsaturated polyester carboxylic-acid or poly carboxylic acid/amine; Anti-settling agent is organobentonite class or polyethylene wax; Flow agent is silicone based or polyacrylate(s); Defoamer is silicone based.
The preparation method of crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention: by the composition and the weight percent of above-mentioned each component, reactive thinner, the wetting dispersing agent that adds in the component by proportioning in mixing tank mixes earlier, add gradually while stirring through surface-treated whisker, add filler, high speed dispersion is even, add anti-settling agent, flow agent and defoamer in photosensitive oligomer, the auxiliary agent then, adding light trigger again continues to mix, homodisperse, packing promptly makes crystal whisker wear-resistant ultraviolet ray solidified paint.
Beneficial effect of the present invention: the coating performance excellence that crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention forms at timber, density board, metal, glass, ceramic surface, toughening effect is obvious, the wear resisting property of filming is greatly improved, its wear resistance can reach 0.005～0.02g/ (500r, 750g).Crystal whisker wear-resistant ultraviolet ray solidified paint of the present invention does not add organic solvent, helps environmental protection, and easy construction, has tangible environmental benefit, social benefit and economic benefit.
Embodiment
Embodiment 1
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 20%, epoxy acrylate oligomer 20%, tripropylene glycol diacrylate 15%, Viscoat 295 10%, 1,6 hexanediol diacrylate 9%, calcium carbonate crystal whisker 15%, filler 5%, 1-hydroxyl-phenylcyclohexane ethyl ketone 4.5%, wetting dispersing agent 0.4%, anti-settling agent 0.6%, flow agent 0.3%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 2
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 46%, tripropylene glycol diacrylate 8%, neopentylglycol diacrylate 8%, Viscoat 295 6%, Isooctyl acrylate monomer 6%, potassium titanate crystal whisker 5%, filler 15%, α, alpha-alpha-dimethyl-α hydroxy acetophenone 5%, wetting dispersing agent 0.2%, anti-settling agent 0.4%, flow agent 0.2%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 3
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by epoxy acrylate oligomer 27%, polyester acrylic ester oligomer 8%, tripropylene glycol diacrylate 10%, 1,6 hexanediol diacrylate 13%, Viscoat 295 5%, pentaerythritol triacrylate 4%, Isooctyl acrylate monomer 5%, calcium carbonate crystal whisker 10%, filler 10%, benzophenone 3%, tertiary amine acrylate 2%, α, alpha-alpha-dimethyl-α hydroxy acetophenone 2%, wetting dispersing agent 0.2%, anti-settling agent 0.4%, flow agent 0.2%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.
Embodiment 4
A kind of crystal whisker wear-resistant ultraviolet ray solidified paint (weight percent) is by urethane acrylate oligomer 40%, epoxy acrylate oligomer 10%, tripropylene glycol diacrylate 12%, 1,6 hexanediol diacrylate 12%, Viscoat 295 7%, Isooctyl acrylate monomer 5%, ZnOw 7%, filler 3%, benzil two ketals 3%, wetting dispersing agent 0.2%, anti-settling agent 0.35%, flow agent 0.25%, defoamer 0.2% is formulated.The preparation method is with above-mentioned.

Claims (8)

1、一种晶须耐磨紫外光固化涂料，其特征是各组分的组成及重量百分比为：1. A whisker wear-resistant UV-curable coating, characterized in that the composition and weight percentage of each component are: 光敏低聚物    35～50Photosensitive oligomer 35～50 活性稀释剂    28～42Active diluent 28～42 光引发剂      3～9Photoinitiator 3～9 晶须          5～18Whiskers 5～18 填料          3～16Packing 3～16 助剂          1～1.5Auxiliary 1～1.5 2、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述的光敏低聚物为：环氧丙烯酸酯类低聚物、聚氨酯丙烯酸酯类低聚物、聚酯丙烯酸酯类低聚物中的一种或几种。2. The whisker-resistant UV-curable coating according to claim 1, characterized in that the photosensitive oligomer is: epoxy acrylate oligomer, polyurethane acrylate oligomer, polyester acrylic acid One or more of ester oligomers. 3、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述活性稀释剂为三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、1，6-己二醇二丙烯酸酯、季戊四醇三丙烯酸酯、新戊二醇二丙烯酸酯、丙烯酸异辛酯中的二种或几种。3. The whisker-resistant UV-curable coating according to claim 1, characterized in that the reactive diluent is tripropylene glycol diacrylate, trimethylolpropane triacrylate, 1,6-hexanediol diacrylate Two or more of acrylate, pentaerythritol triacrylate, neopentyl glycol diacrylate, and isooctyl acrylate. 4、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述光引发剂为：二苯甲酮/胺体系、苯偶酰二缩酮、安息香乙醚、1-羟基-环己基苯乙酮、α，α-二甲基-α羟基苯乙酮、硫杂蒽酮类中的一种或几种。4. The whisker wear-resistant UV-curable coating according to claim 1, characterized in that the photoinitiator is: benzophenone/amine system, benzil diketal, benzoin ethyl ether, 1-hydroxy- One or more of cyclohexylacetophenone, α,α-dimethyl-αhydroxyacetophenone, and thioxanthones. 5、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述晶须为：碳酸钙晶须、钛酸钾晶须、氧化锌晶须中的一种，直径范围为0.5～2μm，长度范围为20～40μm，均由硅烷偶联剂或钛酸酯偶联剂经表面改性处理过。5. The whisker wear-resistant UV-curable coating according to claim 1, characterized in that the whisker is one of calcium carbonate whisker, potassium titanate whisker, and zinc oxide whisker, with a diameter ranging from 0.5 to 2 μm, and the length ranges from 20 to 40 μm, all of which have been surface-modified by a silane coupling agent or a titanate coupling agent. 6、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述填料为中空玻璃微珠、二氧化硅、弹性微粒中的一种或几种。6. The whisker-resistant UV-curable coating according to claim 1, characterized in that the filler is one or more of hollow glass microspheres, silicon dioxide, and elastic particles. 7、根据权利要求1所述的晶须耐磨紫外光固化涂料，其特征是所述助剂为润湿分散剂、防沉剂、流平剂、消泡剂；润湿分散剂为高分子不饱和聚羧酸类或聚羧酸/胺的衍生物类；防沉剂为有机膨润土类或聚乙烯蜡；流平剂为有机硅类或聚丙烯酸酯类；消泡剂为有机硅类。7. The whisker-resistant UV-curable coating according to claim 1, characterized in that the additives are wetting and dispersing agents, anti-settling agents, leveling agents, and defoamers; the wetting and dispersing agents are polymers Unsaturated polycarboxylic acid or polycarboxylic acid/amine derivatives; anti-settling agent is organic bentonite or polyethylene wax; leveling agent is silicone or polyacrylate; defoaming agent is silicone. 8、权利要求1所述的晶须耐磨紫外光固化涂料的制备方法，其特征是按照权利要求1所述的各组分的组成及重量百分比，先在混合器中按配比加入组分中的活性稀释剂、润湿分散剂搅拌混合均匀，边搅拌边逐渐加入经表面处理过的晶须，加入填料，高速分散均匀，然后加入光敏低聚物、助剂中的防沉剂、流平剂和消泡剂，再加入光引发剂继续搅拌混合，均匀分散，包装，即制得晶须耐磨紫外光固化涂料。8. The preparation method of the whisker wear-resistant UV-curable coating according to claim 1, which is characterized in that according to the composition and weight percentage of each component described in claim 1, first add the components in the mixer according to the proportion The active diluent and wetting and dispersing agent are stirred and mixed evenly. While stirring, gradually add the surface-treated whiskers, add fillers, disperse evenly at high speed, and then add photosensitive oligomers, anti-settling agents in additives, and leveling agents. Agent and defoamer, then add photoinitiator and continue to stir and mix, evenly disperse, pack, and obtain whisker-resistant UV-curable coating.
CN 200610156034 2006-12-30 2006-12-30 Crystal whisker wear-resistant ultraviolet ray solidified paint and preparation process thereof Pending CN100999643A (en)

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Cited By (28)

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CN101942261A (en) * 2010-08-24 2011-01-12 上海雅达特种涂料有限公司 Ultraviolet curing coating
CN102146226A (en) * 2010-12-28 2011-08-10 西安航天三沃化学有限公司 Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film
CN102264850A (en) * 2008-12-23 2011-11-30 Posco公司 Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same
CN102516837A (en) * 2011-12-19 2012-06-27 成都展辰化工有限公司 Ultraviolet (UV) cured roller coating embellishing clear finish coating
CN101570653B (en) * 2008-04-29 2012-10-03 汉达精密电子(昆山)有限公司 Fingerprint resisting ultraviolet curing paint and operating method thereof
CN102942836A (en) * 2012-11-28 2013-02-27 长沙岱勒新材料科技有限公司 Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof
CN103333590A (en) * 2013-07-01 2013-10-02 江苏达胜热缩材料有限公司 Heat-resistant insulating paint with fast curing speed
CN103396737A (en) * 2013-07-10 2013-11-20 淮南联合大学 High temperature resistant ultraviolet curing coating and preparation method of same
CN103525257A (en) * 2013-09-30 2014-01-22 安徽蓝柯复合材料有限公司 Stone surface crystallization ultraviolet photocurable coating and preparation method thereof
CN103834276A (en) * 2014-03-04 2014-06-04 芜湖市艾德森自动化设备有限公司 UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof
CN103881028A (en) * 2014-04-01 2014-06-25 张家港康得新光电材料有限公司 Abrasion-proof optical material, preparation method and application of optical material
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CN104152027A (en) * 2014-07-30 2014-11-19 苏州聚康新材料科技有限公司 Elastic coating for leather and preparation method of elastic coating
CN104152034A (en) * 2014-08-28 2014-11-19 苏州洛特兰新材料科技有限公司 Ultraviolet curing acrylic ester composition paint used for ceramic
CN104178018A (en) * 2014-09-09 2014-12-03 苏州圣谱拉新材料科技有限公司 Acrylic coating for ceramic
CN104177992A (en) * 2014-08-28 2014-12-03 苏州洛特兰新材料科技有限公司 Radiation curable acrylate resin coating for ceramics
CN104194615A (en) * 2014-09-09 2014-12-10 苏州圣谱拉新材料科技有限公司 Metalized ceramic paint
CN104530959A (en) * 2014-12-11 2015-04-22 惠州市长润发涂料有限公司 Anti-sinking UV transparent primer
CN104817938A (en) * 2015-04-30 2015-08-05 广西高农机械有限公司 Glass-surface wear-proof ultraviolet curing coating for spraying machines
CN105176336A (en) * 2015-10-20 2015-12-23 苏州群力防滑材料有限公司 Multifunctional hardware coating material
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Cited By (33)

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CN101570653B (en) * 2008-04-29 2012-10-03 汉达精密电子(昆山)有限公司 Fingerprint resisting ultraviolet curing paint and operating method thereof
CN102264850A (en) * 2008-12-23 2011-11-30 Posco公司 Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same
CN102264850B (en) * 2008-12-23 2014-05-21 Posco公司 Ultraviolet curable resin composition for transparent color-painted steel sheet, and steel sheet using same
CN101942261A (en) * 2010-08-24 2011-01-12 上海雅达特种涂料有限公司 Ultraviolet curing coating
CN102146226A (en) * 2010-12-28 2011-08-10 西安航天三沃化学有限公司 Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film
CN102516837A (en) * 2011-12-19 2012-06-27 成都展辰化工有限公司 Ultraviolet (UV) cured roller coating embellishing clear finish coating
CN102942836A (en) * 2012-11-28 2013-02-27 长沙岱勒新材料科技有限公司 Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof
CN103333590B (en) * 2013-07-01 2016-06-08 江苏达胜热缩材料有限公司 The high temperature insulation coating that a kind of curing rate is fast
CN103333590A (en) * 2013-07-01 2013-10-02 江苏达胜热缩材料有限公司 Heat-resistant insulating paint with fast curing speed
CN103396737A (en) * 2013-07-10 2013-11-20 淮南联合大学 High temperature resistant ultraviolet curing coating and preparation method of same
CN103525257A (en) * 2013-09-30 2014-01-22 安徽蓝柯复合材料有限公司 Stone surface crystallization ultraviolet photocurable coating and preparation method thereof
CN103834276A (en) * 2014-03-04 2014-06-04 芜湖市艾德森自动化设备有限公司 UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof
CN103834276B (en) * 2014-03-04 2016-03-30 芜湖市艾德森自动化设备有限公司 The fast UV of the good curing speed of a kind of sticking power is coating material solidified and preparation method thereof
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CN104177992A (en) * 2014-08-28 2014-12-03 苏州洛特兰新材料科技有限公司 Radiation curable acrylate resin coating for ceramics
CN104152034A (en) * 2014-08-28 2014-11-19 苏州洛特兰新材料科技有限公司 Ultraviolet curing acrylic ester composition paint used for ceramic
CN104194615A (en) * 2014-09-09 2014-12-10 苏州圣谱拉新材料科技有限公司 Metalized ceramic paint
CN104178018A (en) * 2014-09-09 2014-12-03 苏州圣谱拉新材料科技有限公司 Acrylic coating for ceramic
CN104292400B (en) * 2014-09-22 2016-11-23 南京航空航天大学 Photocuring 3 D-printing material that a kind of CNT strengthens and preparation method thereof
CN104530959A (en) * 2014-12-11 2015-04-22 惠州市长润发涂料有限公司 Anti-sinking UV transparent primer
CN104817938A (en) * 2015-04-30 2015-08-05 广西高农机械有限公司 Glass-surface wear-proof ultraviolet curing coating for spraying machines
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CN107474605A (en) * 2017-08-18 2017-12-15 华南师范大学 A kind of optical fiber doping coating layer material and preparation method thereof
CN110938340A (en) * 2018-09-21 2020-03-31 独山县玉水鸿浩门业有限公司 Door panel uv anti-cracking paint and preparation method thereof
CN110128935A (en) * 2019-05-24 2019-08-16 临沂优彩新能源环保科技有限公司 A kind of UV ceramics special surface treating agent
CN112521851A (en) * 2020-12-15 2021-03-19 北京化工大学常州先进材料研究院 Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof
CN112680103A (en) * 2020-12-15 2021-04-20 北京化工大学常州先进材料研究院 Ultrahigh-strength hydrophobic antifogging coating composition and application thereof
CN112521851B (en) * 2020-12-15 2022-03-15 北京化工大学常州先进材料研究院 Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof
CN115304985A (en) * 2022-08-15 2022-11-08 广东新纪源复合材料股份有限公司 Acrylate wear-resistant anti-fouling coating and preparation method thereof
CN116218333A (en) * 2023-01-10 2023-06-06 江南大学 A kind of photocuring coating and preparation method thereof

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