CN1008107B - Shifting pressure-sensitive paste band for architecture - Google Patents
Shifting pressure-sensitive paste band for architectureInfo
- Publication number
- CN1008107B CN1008107B CN 87102005 CN87102005A CN1008107B CN 1008107 B CN1008107 B CN 1008107B CN 87102005 CN87102005 CN 87102005 CN 87102005 A CN87102005 A CN 87102005A CN 1008107 B CN1008107 B CN 1008107B
- Authority
- CN
- China
- Prior art keywords
- parts
- pressure
- sensitive adhesive
- rosin
- bicarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 15
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 12
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 7
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000006260 foam Substances 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 claims abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 235000010216 calcium carbonate Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000011297 pine tar Substances 0.000 claims description 4
- 229940068124 pine tar Drugs 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 101100535994 Caenorhabditis elegans tars-1 gene Proteins 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000009434 installation Methods 0.000 abstract description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 abstract 2
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229960003471 retinol Drugs 0.000 abstract 1
- 235000020944 retinol Nutrition 0.000 abstract 1
- 239000011607 retinol Substances 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- -1 poly-ethylethylene ether Chemical compound 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 239000000037 vitreous enamel Substances 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
Landscapes
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a shifting pressure-sensitive adhesive band for construction, which is composed of flexible base materials, adhesives and isolation paper, wherein foam pressure sensitive adhesive layers are coated on both surfaces of each base material, the formula of the adhesive has the main components of styrene-butadiene-styrene block polymer (SBS), rosin and retinol, and the primary viscosity of the adhesive is 20 g/30 DEG, and the stripping strength is 750 g/cm at 180 DEG. The adhesive band having the advantages of easy use, low cost and good tightness can be used for the installation of doors and windows on buildings and have wide application in mechanical industry, automobile manufacturing industry and decoration industry.
Description
The present invention relates to a kind of shifting pressure-sensitive paste band for architecture, belong to pressure-sensitive adhesive tape.
The installation of buildings upper glass door and window, traditional method are after earlier glass and sash being fastened with nail or wire clip, stick with glue agent or putty again and make glass and sash bonding.This not only requires operator that a twist of the wrist will be arranged, and labour intensity is bigger, and the time one is long, and putty or tackiness agent come off easily.
As everyone knows, outstanding advantage such as the pressure sensitive sealing tape is easy to use with it, bond strength is big is applied to every field more and more widely.Pressuresensitive Tape is made up of base material, tackiness agent, separant, comprise compositions such as tackiness agent, tackifying resin, anti-aging agent, weighting agent in its adhesive formulation, general tackiness agent commonly used mostly is polyacrylate(s) and rubber-like, and its concrete prescription is to be formulated by the application target of sealing tape.A kind of double-sided pressure-sensitive adhesive tape is disclosed among the US Patent specification 4574-098, be used for the model of an object is transferred to another body surface, adhesive therefor is synthetic or natural rubber, poly-ethylethylene ether or a polyacrylate(s) of high-molecular weight, and the bond strength of this sealing tape is not ideal enough.
The purpose of this invention is to provide that a kind of production technique is simple, with low cost, New Building Materials-shifting pressure-sensitive paste band easy to use during bonding strength Datong District, come glass door and window on bonding buildings with its.
The present invention is made up of base material, tackiness agent, interleaving paper, is illustrated respectively below.
1. base material: adopt polyvinyl alcohol fiber non-woven fabrics or textile-like.
2. tackiness agent: with styrene butadiene styrene
Segmented copolymer (SBS) is a tackiness agent, and rosin, refining pine tar are tackifier, and bicarbonate of ammonia is a kind of ageing-resistant foam type pressure-sensitive adhesive that whipping agent is formed, and its prescription is (weight part) with the composition scope:
A, SBS 5-20 part
B, rosin 5-50 part
C, refining pine tar 5-20 part
D, Rutile type Titanium Dioxide 0.5-2 part
E, light calcium carbonate 0.25-10 part
F, T202 0.06-0.48 part
G, T501 0.04-0.32 part
H, bicarbonate of ammonia 2-8 part
I, No. 120 industrial naptha 2.5-10 parts
J, dimethylbenzene 5-20 part
Styrene content is a 35%(weight among the used SBS), the chemical name of T202 is a zinc dialkyl dithiophosphate, T501 is the 2.6-ditertbutylparacresol.
The optimum formula of pressure-sensitive adhesive of the present invention is (weight part):
10 parts of a, SBS
20 parts of b, rosin
10 parts of c, refining pine tars
1 part of d, Rutile type Titanium Dioxide
5 parts of e, light calcium carbonates
0.24 part of f, T202
0.16 part of g, T501
4 parts in h, bicarbonate of ammonia
5 parts of i, No. 120 industrial napthas
10 parts of j, dimethylbenzene
3. interleaving paper:
The base material of interleaving paper can adopt the papery composite base material, as kraft paper, separant is uniformly coated on the two sides of base material and makes.It is main body that separant of the present invention adopts silicon rubber and polymethyl silicane, and adds suitable solidifying agent, catalyzer.This separant also is applicable to the pressure-sensitive adhesive tape of other type, its prescription and composition scope following (weight part):
A, 107 silicon rubber 1-10 parts
B, poly-Union carbide A-162 0.2-18 part
C, tetrabutyl titanate 0.04-0.4 part
D, dibutyl tin laurate 0.05-0.6 part
E, No. 120 industrial naptha 200-300 parts
F, dimethylbenzene 0-50 part
Whether the adding of dimethylbenzene reaches add-on is decided on the dissolving situation of raw material.
The optimum formula of separant is (weight part):
10 parts in a, 107 silicon rubber
16 parts of b, poly-Union carbide A-162s
0.4 part of c, tetrabutyl titanate
0.5 part of d, dibutyl tin laurate
245 parts of e, No. 120 industrial napthas
35 parts of f, dimethylbenzene
Above-mentioned base material, foam type pressure-sensitive adhesive, interleaving paper by impregnation formula coating machine, just can once be finished the double-sided pressure-sensitive adhesive tape that the present invention proposes.
Pressure-sensitive adhesive tape of the present invention, the door and window that not only can be used in building trade is installed, and also can be used on label, car industry, shipbuilding industry and the decoration industry of mechanical industry, and purposes is very extensive.Its production technique is simple, and (every meter only several sharing money) with low cost, bond strength is big, good seal performance.
Accompanying drawing is the viewgraph of cross-section of pressure-sensitive adhesive tape of the present invention, wherein, and 1-foam type pressure-sensitive adhesive, 2-base material (polyvinyl alcohol fiber non-woven fabrics), the two-sided interleaving paper that scribbles separant of 3-.
Embodiment 1: the production of tackiness agent
According to above-mentioned optimum formula 2., i, J, three kinds of raw materials of a are added in the glue mixing bucket (styrene content is 35% among the raw material a), soak after 8 hours, start stirrer, add d, e and stir.With b, c, four kinds of component heat fused of f, g, temperature is controlled at 120 ℃ ± 5 in another bucket, fuses even postcooling to 60 ℃ ± 5, joins in the above-mentioned glue mixing bucket again, continues to stir.When temperature is lower than 35 ℃ in the glue mixing bucket, add h, till the batching in the glue mixing bucket is stirred into uniform rubber cement.It is standby that rubber cement is put into 120 purpose rubber strainers filtration back.
Embodiment 2: the production of interleaving paper
According to above-mentioned optimum formula 3., two kinds of solvents of e, f are added in the porcelain enamel barrel, after mixing, under the prerequisite that stirs along a direction, be sequentially added into a, b, four kinds of raw materials of c, d, the adding method is a kind of after adding after preceding a kind of material dissolving fully again, so analogize, fully dissolve until last a kind of material, stand-by.
The separant base material adopts the 20g/m of two-sided multiple High-Pressure Polyethylene Film
2Kraft paper is contained in above-mentioned kraft paper on the unicoater, and the separant for preparing is added in the glue groove of coating machine, starts coating machine, and the coating thickness of separant is controlled at about 1 μ m, and oven temperature is controlled at 125 ℃ ± 5, control storing time 60 seconds ± 5.Display after the coated paper rolling temperature more than 20 ℃, relative humidity greater than 85% environment in 7 days, promptly become the interleaving paper of double spread, standby.
Embodiment 3: sealing tape production
Sealing tape base material proposed by the invention adopts the polyvinyl alcohol fiber non-woven fabrics, in its impregnation formula coating machine of packing into, the rubber cement that again example 1 made adds in the steeping vat, and control is 2mm to the gap of nip drum, and the interleaving paper that example 3 is made is put into entrusting of coating machine and rolled at last.Start coating machine, the control oven temperature is 80-90 ℃, can obtain the double-sided pressure-sensitive adhesive tape that thickness is 4mm, is product through rolling, after cutting.
The product test result:
The prepared sealing tape product of the foregoing description is carried out salient features to be measured, recording tack is 20g/30 °, 180 ° of stripping strengths are 750g/cm, expose in the sun that the top layer colloid begins hardening after 7 days, form the elastomerics of tough and tensile rubber like after one month.Test condition is: temperature 23 ℃ ± 1, and relative humidity 65% ± 3, tack is measured with " rolling ball method ", and promptly the stainless steel spin of 20g is on 30 ° inclined-plane, and run-up distance 100mm can cling in 100mm; 180 ° of peeling forces are to test on the puller system of lowering speed 300mm/ branch ± 3mm, and test panel is
8 stainless steel substrates.
During use, glue face of sealing tape is embedded in the groove of sash, remove interleaving paper then, load onto glass.In other words, only need remove interleaving paper, two faces that scribble tackiness agent are treated that with two kinds sticking object surfaces contacts and pushes a little respectively, bonding process is just accused and is finished.
Claims (2)
1, a kind of shifting pressure-sensitive paste band for architecture, form by flexible parent metal, tackiness agent, interleaving paper, separate application has formation of pressure-sensitive adhesive layer and release agent layer on the two sides of base material and interleaving paper, pressure-sensitive adhesive system adopts based on styrene butadiene styrene segmented copolymer (SBS) and rosin, zinc dialkyl dithiophosphate (T202), ditertbutylparacresol (T501), bicarbonate of ammonia and is equipped with the foam type pressure-sensitive adhesive of an amount of solvent and filler, it is characterized in that adding in the pressure-sensitive adhesive refining pine tar, its prescription is (weight part) with composition range:
Styrene butadiene styrene segmented copolymer (SBS) 5-20 part
Rosin 5-50 part
Refining pine tar 5-20 part
Rutile type Titanium Dioxide 0.5-2 part
Light calcium carbonate 0.25-10 part
Zinc dialkyl dithiophosphate (T202) 0.06-0.48 part
Ditertbutylparacresol (T501) 0.04-0.32 part
Bicarbonate of ammonia 2-8 part
No. 120 industrial naptha 2.5-10 parts
Dimethylbenzene 5-20 part
2, pressure-sensitive adhesive tape according to claim 1 is characterized in that the prescription of tackiness agent is (weight part):
10 parts of styrene butadiene styrene segmented copolymers
20 parts of rosin
10 parts of refining pine tars
1 part of Rutile type Titanium Dioxide
5 parts of light calcium carbonates
0.24 part of zinc dialkyl dithiophosphate
0.16 part of ditertbutylparacresol
4 parts in bicarbonate of ammonia
5 parts of No. 120 industrial napthas
10 parts of dimethylbenzene
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87102005 CN1008107B (en) | 1987-03-26 | 1987-03-26 | Shifting pressure-sensitive paste band for architecture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87102005 CN1008107B (en) | 1987-03-26 | 1987-03-26 | Shifting pressure-sensitive paste band for architecture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87102005A CN87102005A (en) | 1988-10-19 |
| CN1008107B true CN1008107B (en) | 1990-05-23 |
Family
ID=4813716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 87102005 Expired CN1008107B (en) | 1987-03-26 | 1987-03-26 | Shifting pressure-sensitive paste band for architecture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1008107B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100452558B1 (en) * | 2001-11-20 | 2004-10-14 | 주식회사 엘지화학 | Paper coating latex using ionic monomer |
| CN1305964C (en) * | 2004-06-18 | 2007-03-21 | 张秋声 | Water-proof coiled material |
| EP3075772B1 (en) * | 2015-04-02 | 2020-08-26 | tesa SE | Removable adhesive tape |
-
1987
- 1987-03-26 CN CN 87102005 patent/CN1008107B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN87102005A (en) | 1988-10-19 |
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| SE01 | Entry into force of request for substantive examination | ||
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| C13 | Decision | ||
| GR02 | Examined patent application | ||
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| CF01 | Termination of patent right due to non-payment of annual fee |