CN1006443B - Method for reducing tar content in cigarette - Google Patents
Method for reducing tar content in cigaretteInfo
- Publication number
- CN1006443B CN1006443B CN 87108147 CN87108147A CN1006443B CN 1006443 B CN1006443 B CN 1006443B CN 87108147 CN87108147 CN 87108147 CN 87108147 A CN87108147 A CN 87108147A CN 1006443 B CN1006443 B CN 1006443B
- Authority
- CN
- China
- Prior art keywords
- tobacco
- tar
- cigarette
- content
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 14
- 241000208125 Nicotiana Species 0.000 claims abstract description 40
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 40
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 claims abstract description 11
- 229960001471 sodium selenite Drugs 0.000 claims abstract description 11
- 239000011781 sodium selenite Substances 0.000 claims abstract description 11
- 235000015921 sodium selenite Nutrition 0.000 claims abstract description 11
- 239000004246 zinc acetate Substances 0.000 claims abstract description 11
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000779 smoke Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 239000000654 additive Substances 0.000 abstract description 13
- 230000000996 additive effect Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 8
- 239000011573 trace mineral Substances 0.000 abstract description 7
- 235000013619 trace mineral Nutrition 0.000 abstract description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- 239000011669 selenium Substances 0.000 abstract description 6
- 229910052711 selenium Inorganic materials 0.000 abstract description 6
- 229940091258 selenium supplement Drugs 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 4
- 239000011701 zinc Substances 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000003205 fragrance Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000011269 tar Substances 0.000 description 34
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 8
- 239000003546 flue gas Substances 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 230000009931 harmful effect Effects 0.000 description 6
- 230000036541 health Effects 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 230000000711 cancerogenic effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 238000003421 catalytic decomposition reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011285 coke tar Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PMYDPQQPEAYXKD-UHFFFAOYSA-N 3-hydroxy-n-naphthalen-2-ylnaphthalene-2-carboxamide Chemical compound C1=CC=CC2=CC(NC(=O)C3=CC4=CC=CC=C4C=C3O)=CC=C21 PMYDPQQPEAYXKD-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000010876 biochemical test Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 235000019788 craving Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011321 prophylaxis Methods 0.000 description 1
- 229960001881 sodium selenate Drugs 0.000 description 1
- 239000011655 sodium selenate Substances 0.000 description 1
- 235000018716 sodium selenate Nutrition 0.000 description 1
- -1 sodium selenite compound Chemical class 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention adopts trace elements of selenium and zinc which are beneficial to human bodies to reduce the content of tar and polycyclic aromatic hydrocarbon generated in the combustion process of tobacco, and has obvious effect. Meanwhile, the selenium and zinc levels in smokers are improved, and the epidemic prevention capability of human bodies to certain diseases is enhanced.
The method is to add a compound additive into the cut tobacco, the components of which are zinc acetate and sodium selenite, and the weight percentage of the compound additive added into the cut tobacco is as follows: 1 to 4% and 0.0001 to 0.0003%. Has the advantages of convenient preparation and suitability for the cigarette production industry in China. Basically does not change the original color and the fragrance, has low cost, is convenient to popularize and the like.
Description
The present invention adds compound additive reduces the tar that tobacco produces effectively in combustion process a kind of method in pipe tobacco, this kind additive is to utilize human body beneficial's trace element zinc, selenium are made.
The past people only think that contained nicotine is the main component that diminishes health in the tobacco.Modern science then thinks, what in the tobacco health is had more harm is not nicotine, but the tar ingredients in the flue gas.Contain a large amount of tar in the cigarette smoke, a regular-size cigarette tar content can reach about 30 milligrams.Think through the pharmacology evaluation: contain carcinogen in the tarry matters in smoke, therefore proof: tarry matters in smoke are the serious threats to health.Because the carcinogen in the discovery tobacco in the tar ingredients of flue gas, thereby harm of smoking is generally accepted by public institute.The many countries in west forbid that with the government decree form tobacconist advertises.Anti-in addition cigarette group occurs in succession, conducts vigorous propaganda harm of smoking.Face huge pressure from public opinion, the tobacconist just steps up to develop low-coke tar cigarette in order to extricate oneself from a predicament.Low-coke tar cigarette is born under this situation.
British government was announced the various cigarette tar contents of home sale in 1973, selected for the smoker.British government is divided into several levels with the height of tar content again in the near future.Its standard is as follows:
The division of above-mentioned tar is admitted for various countries in fact now and is accepted, and the U.S. just indicates national tobaccoman various trade mark cigarette tar contents to be reduced to below 15 milligrams to nineteen eighty-three at that time.The Chinese government also made stipulations in 1986: must indicate the class of tar content from the cigarette case of the various trades mark in 1987, and the regulation tar content divides high, normal, basic three shelves:
China is the first production and marketing big country now in the world, and cigarette quality particularly also lags behind international most advanced level in the work of reduction tobacco tar Study on content.Only there is a small amount of low tar cigarette listing in China at present, can not satisfy numerous smokers' demand far away.Therefore reduce no matter tar content is from raising people ' s health level in the flue gas, the cigarette product of China is squeezed into the international market more, obtaining bigger several respects such as economic benefit all is imperative key subjects.
Since the sixties, external tar content for the reduction smoke of tobacco has carried out number of research projects.Except the improvement tobacco bred, adopt the method for physics more, these methods comprise: improve the tobacco leaf processing method, improve the air permeability of cigarette paper, improve the filtration of filter tip and render a service or the like.These class methods are effectively reducing on the harmful components of flue gas, but flue gas also desalinated simultaneously, and the bigger people of craving for tobacco is not being met.Therefore, they tend to dark suction, heavily inhale and inhale morely, thereby make the total amount of the harmful components that these people suck and may not be certain to have tangible minimizing.
Improve the growing and cultivation technology of tobacco, improve quality of tobacco, this yes a kind of good method of improving quality of tobacco.But the time that obvious this way needs is long, and it is slow to take effect, and cost also can correspondingly increase.
Reducing the content of tar with the way of chemistry, at present, mainly is to add some combustion adjuvant, diluent, catalyst etc. in cigarette.Reduce the content of tar by the efficiency of combustion that improves cigarette, and can reduce some harmful components in the flue gas selectively, as people such as U.S. Norman V, with zinc oxide as additive in cigarette, polycyclic aromatic hydrocarbon content in the catalytic decomposition flue gas, it lowers efficiency and can reach 50%.(seeing CA Vol77149831111972).Use this way, additive is to do to mix to mix pipe tobacco, does not meet the present tobacco curing technology of China.And the method for indication of the present invention, its zinc acetate and sodium selenite compound additive can be water-soluble fully, can be sprayed on the pipe tobacco equably.
The objective of the invention is to use the additive in cigarette that human body beneficial's trace element is made, can reduce the content of tar, might play the prophylactic treatment effect to some disease again, (ArchEnvironHealth39(6) 419-4241984 among this way is being studied abroad) but do not see that formal achievement in research is arranged.
The present invention uses human body beneficial's trace element is handled tobacco, has promoted the completing combustion of pipe tobacco, has reduced the tar content in the flue gas.Its mechanism is speculated as: as the very easy decomposes of the zinc acetate of additive, under the situation of pipe tobacco burning, change zinc oxide into, reaction equation is:
In above-mentioned reaction, acetate is oxidized to carbon dioxide and water, emits a large amount of heat energy, the combustion heat △ H of acetic gas
298=-104.3 kcal/mol.Play combustion-supporting effect thereby improved ignition temperature, the zinc oxide of generation plays the catalytic decomposition polycyclic aromatic hydrocarbon.
In addition, the polycyclic aromatic hydrocarbon in the tar is considered to carcinogenic chief culprit.The sodium selenate that adds can be absorbed by the body.EPDML research and zoopery have proved that body improves the generation that the selenium level can effectively prevent diseases such as lung cancer.Having shown also in our biochemical test that sodium selenite has the reduction effect to the toxicity of tar, might be that selenium can be removed harmful free radical that polycyclic aromatic hydrocarbon produces.
Adopt the pipe tobacco that the present invention handled, the tar content in the cigarette smoke can be reduced by 16%～20%.The content of polycyclic aromatic hydrocarbon reduces by 30%～50%, and free-radical contents reduces by 20%.The result of study of relevant polycyclic aromatic hydrocarbon is tested with U.S. Hewlett Packard5880A type capillary chromatography; Tar is tested because of Filtrona-302 type smoking machine with English; The tar free radical is that the JES-FEIX type electron spin resonanceapparatus that Japan produces is tested.(seeing the data of consulting for details)
The preparation and the embodiment of the micro-compound additive that this method adopted are described below: zinc acetate is dissolved in the sodium selenite that adds certain ratio in the water more fully with its maximum solubility, then solution is diluted to certain volume.Compound additive is sprayed on the tobacco leaf before the perfuming equably, and the sprinkling amount is that per 100 gram pipe tobaccos add zinc acetate 1～4 gram; Sodium selenite 0.0001 gram～0.0003 gram.
The concrete prescription of compound additive has following a few example:
Example one, zinc acetate and sodium selenite add percentage by weight in the pipe tobacco be 3% and the weight of the weight/pipe tobacco of 0.0002%(zinc acetate or sodium selenite).Before tobacco perfuming, be sprayed on the pipe tobacco.
Result: reduce tar 16.22%, polycyclic aromatic hydrocarbon 28.5%, free radical 19.2%
Example two, the percentage by weight that zinc acetate and sodium selenite add in the pipe tobacco is 4% and 0.0001%.(weight of the weight/pipe tobacco of zinc acetate and sodium selenite) before tobacco perfuming, is sprayed on the pipe tobacco.
Result: reduce tar 18.32%, polycyclic aromatic hydrocarbon 39.2%, free radical 18.82%
In sum, be very significant with tobacco additive agent of the present invention to tar content, polycyclic aromatic hydrocarbon and the free-radical contents effect that reduces in the smoke of tobacco.And can improve the level of smoker to healthy trace elements with household in involuntary smoker's body, strengthen body immunity.
From the color, smell and taste aspect of cigarette, the cigarette that the tobacco of handling with the present invention is made, through the smoker and relevantly comment the cigarette expert appraisal: color, smell and taste do not have harmful effect, and the assorted gas and the excitant of cigarette alleviate to some extent.
From the possibility of promoting, the adding of trace element zinc, selenium does not change existing cigarette process.And 1 fen of cost less than of every bag cigarette increase.All kinds of cigarettes all can add, and the scope of application is wide.
Therefore it seems, the present invention because it to content of harmful in the tar reduce effect remarkable, easy to make, with low cost, be convenient to healthy and helpful to human body of the trace element promoting, added, will inevitably to tobacco change from now on cigarette product structure, produce low-toxic cigarette and produce positive role and obtain good effect.Its economic benefit also is very considerable.
Tar rank tar content
High more than 29 milligrams
In paramount 23 to 28 milligrams
In 17 to 22 milligrams
In being low to moderate 11 to 16 milligrams
Low 5 to 10 milligrams
Special low 4 milligrams
High tar content 30～25mg/ props up
Middle tar content 25～15mg/ props up
Low tar content＜15mg/ props up
Claims (2)
1, a kind of method that can reduce tar in the cigarette smoke, polycyclic aromatic hydrocarbon and free-radical contents; It is characterized in that zinc acetate and sodium selenite are mixed with the aqueous solution, be sprayed at then on the preceding pipe tobacco of perfuming.Consumption is respectively 1～4 gram and 0.0001 gram～0.0003 gram by the amount that adds zinc acetate and sodium selenite in each hectogram pipe tobacco.
2, method according to claim 1 is characterized in that the aqueous solution is to be sprayed on the pipe tobacco with spray-on process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87108147 CN1006443B (en) | 1987-12-14 | 1987-12-14 | Method for reducing tar content in cigarette |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87108147 CN1006443B (en) | 1987-12-14 | 1987-12-14 | Method for reducing tar content in cigarette |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1035039A CN1035039A (en) | 1989-08-30 |
| CN1006443B true CN1006443B (en) | 1990-01-17 |
Family
ID=4816381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 87108147 Expired CN1006443B (en) | 1987-12-14 | 1987-12-14 | Method for reducing tar content in cigarette |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1006443B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6789548B2 (en) | 2000-11-10 | 2004-09-14 | Vector Tobacco Ltd. | Method of making a smoking composition |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201032738A (en) * | 2009-01-23 | 2010-09-16 | Japan Tobacco Inc | Cigarette |
| CN103005653B (en) * | 2012-12-13 | 2015-02-04 | 湖北中烟工业有限责任公司 | Method for improving content of selenium in tobacco leaf |
| CN108185507B (en) * | 2018-01-04 | 2020-12-08 | 中国烟草总公司广东省公司 | A selenium-enriched tobacco chewable tablet |
| CN115644486A (en) * | 2022-10-31 | 2023-01-31 | 江西中烟工业有限责任公司 | Method for reducing content of polycyclic aromatic hydrocarbon in cigarette smoke tar |
-
1987
- 1987-12-14 CN CN 87108147 patent/CN1006443B/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6789548B2 (en) | 2000-11-10 | 2004-09-14 | Vector Tobacco Ltd. | Method of making a smoking composition |
| US6959712B2 (en) | 2000-11-10 | 2005-11-01 | Vector Tobacco Ltd. | Method of making a smoking composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1035039A (en) | 1989-08-30 |
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Legal Events
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| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
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| C19 | Lapse of patent right due to non-payment of the annual fee | ||
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