CN100579678C - A deodorizing method for biological pretreatment of urban waste - Google Patents
A deodorizing method for biological pretreatment of urban waste Download PDFInfo
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Description
技术领域:Technical field:
本发明属于城市垃圾除臭方法这一技术领域,特别属于城市垃圾生物预处理的除臭方法这一技术领域。The invention belongs to the technical field of urban garbage deodorization methods, in particular to the technical field of urban garbage biological pretreatment deodorization methods.
背景技术:Background technique:
随着经济发展,城市垃圾越来越多,垃圾的生物回收已经成为一种新的趋势,垃圾生物回收法与现行的垃圾填埋法、垃圾焚烧法相比具有占地少,对环境不产生污染等特点。垃圾生物回收主要包括粗分选工序,破袋工序、生物预处理工序、一次分选工序、再发酵工序、二次分选工序、烘干工序、精选工序、有机肥工序。原生垃圾先经过粗分选工序,将其中的竹木类包装箱、橡胶轮胎予以分开、并将大件破碎;将粗分选过的垃圾进行破袋处理,将破袋后的垃圾进行生物预处理,生物预处理所产生的渗滤水进入污水处理系统,产生的废气进入废气处理系统;将经过生物预处理过的垃圾进行一次分选,利用风力、重力、磁力、弹跳、形状、速度等技术分选出竹木类、废电池、塑料、玻璃、打火机、金属、织物等进行回收,将砖瓦石块等无机材料用于新型建材的制造;将经过第一次分选过的垃圾进行再发酵,将再发酵过的垃圾进行二次分选,分选出垃圾中可燃物及沙石、细小玻璃等,将二次分选过的垃圾进行烘干,精选、制肥,在生物预处理过程及再发酵过程中,经常伴有恶臭,中国专利03118139提供了一种除臭剂、除臭促进剂及其垃圾堆肥除臭处理的方法,其所用的除臭剂及除臭促进剂在生物预处理及再发酵过程中是相同的,由于生物预处理工序及再发酵工序为不同的发酵工艺,因此除臭剂及促进剂针对性不强With the development of the economy, more and more urban garbage, the biological recycling of garbage has become a new trend, compared with the current landfill method and garbage incineration method, the biological recycling method of garbage occupies less land and does not pollute the environment Features. Waste biological recycling mainly includes rough sorting process, bag breaking process, biological pretreatment process, primary sorting process, re-fermentation process, secondary sorting process, drying process, selection process, and organic fertilizer process. Raw garbage first undergoes a rough sorting process, separating the bamboo and wood packaging boxes and rubber tires, and breaking the large pieces; the rough sorted garbage is broken into bags, and the broken bags are subjected to biological pretreatment. Treatment, the infiltration water produced by biological pretreatment enters the sewage treatment system, and the waste gas generated enters the waste gas treatment system; the garbage that has undergone biological pretreatment is sorted once, using wind force, gravity, magnetic force, bounce, shape, speed, etc. The technology sorts out bamboo and wood, waste batteries, plastics, glass, lighters, metals, fabrics, etc. for recycling, and uses inorganic materials such as bricks, tiles and stones for the manufacture of new building materials; the garbage that has been sorted for the first time is recycled. Re-fermentation, the re-fermented garbage is sorted for the second time, and the combustibles, sand and stones, fine glass, etc. in the garbage are sorted out, and the second-sorted garbage is dried, selected, and fertilized. During the pretreatment process and the re-fermentation process, there are often foul odors. Chinese patent 03118139 provides a deodorant, a deodorizing accelerator and a method for deodorizing the composting of garbage. The deodorant and deodorizing accelerator used in it are It is the same in the biological pretreatment and re-fermentation process, because the biological pre-treatment process and the re-fermentation process are different fermentation processes, so the deodorant and accelerator are not very targeted
发明内容:Invention content:
本发明所要解决的技术问题是提供一种针对性强的一种城市垃圾生物预处理的除臭方法。The technical problem to be solved by the present invention is to provide a highly targeted deodorization method for biological pretreatment of urban waste.
本发明解决技术问题的技术方案为:一种城市垃圾生物预处理的除臭方法,在粗分选过的垃圾中加入混合除臭菌种,所述的混合除臭菌种为中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,小红酵母(Rhodotorula minuta)CGMCC2.277,米根霉(Rhizopus oryzae)CGMCC3.1263,师岗链轮丝菌(Streptoverticilliummorookaense)CGMCC 4.1122。The technical solution of the present invention to solve the technical problem is: a deodorization method for biological pretreatment of urban garbage, adding mixed deodorizing bacteria to the roughly sorted garbage, and the mixed deodorizing bacteria are Chinese Buhler bombs Bullera sinensis Li CGMCC 2.1614, Rhodotorula minuta CGMCC 2.277, Rhizopus oryzae CGMCC 3.1263, Streptoverticillium morookaense CGMCC 4.1122.
上述菌种的保藏单位均为中国普通微生物菌种保藏保管理中心。The preservation units of the above-mentioned strains are China Ordinary Microorganism Culture Collection and Management Center.
中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,小红酵母(Rhodotorula minuta)CGMCC 2.277,米根霉(Rhizopus oryzae)CGMCC3.1263,师岗链轮丝菌(Streptoverticillium morookaense)CGMCC 4.1122,其扩大培养液混合的体积比为1-5∶1-10∶3-15∶1-5。China Bullera sinensis Li CGMCC 2.1614, Rhodotorula minuta CGMCC 2.277, Rhizopus oryzae CGMCC 3.1263, Streptoverticillium morookaense CGMCC 4.1122, and its expanded The mixing volume ratio of the culture solution is 1-5:1-10:3-15:1-5.
为了增强生物预处理的除臭效果,还可在混合除臭菌种添加谷氏链霉菌(Streptomyces gougerotii)CGMCC 4.28,其与中国布勒弹孢酵母(Bullerasinensis Li)CGMCC 2.1614,的扩大培养液混合的体积比为1∶1-5。In order to enhance the deodorizing effect of biological pretreatment, Streptomyces gougerotii CGMCC 4.28 can also be added to the mixed deodorizing bacteria, which is mixed with the expanded culture medium of Bullerasinensis Li CGMCC 2.1614 in China The volume ratio is 1:1-5.
所述的生物预处理工序为,在原生垃圾中加入混合菌种,所述的混合菌种为木糖氧化碱菌反硝化亚种(Alcaligenes xylosoxidans subsp)CGMCC 1.768、解淀粉芽孢杆菌(Bacillus amyloliquefaciens)CGMCC 1.1177、汉逊德巴利酵母汉逊变种(Debaryomyces hansenii)CGMCC 2.1831;菱型伊萨酵母(Issatchenkiascutulata)CGMCC 2.1592,嗜角蛋白粉落霉(Aleuisma keratinophilum)CGMCC3.3544,巴氏诺卡菌(Nocardia brasiliensis)CGMCC 4.1128。The biological pretreatment process is to add mixed strains to the raw garbage, and the mixed strains are Alcaligenes xylosoxidans subsp CGMCC 1.768, Bacillus amyloliquefaciens CGMCC 1.1177, Debaryomyces hansenii CGMCC 2.1831; Issatchenkiascutulata CGMCC 2.1592, Aleuisma keratinophilum CGMCC3.3544, Nocardia pasteurii ( Nocardia brasiliensis) CGMCC 4.1128.
木糖氧化碱菌反硝化亚种(Alcaligenes xylosoxidans subsp)CGMCC 1.768、解淀粉芽孢杆菌(Bacillus amyloliquefaciens)CGMCC 1.1177、汉逊德巴利酵母汉逊变种(Debaryomyces hansenii)CGMCC 2.1831;菱型伊萨酵母(Issatchenkiascutulata)CGMCC 2.1592,嗜角蛋白粉落霉(Aleuisma keratinophilum)CGMCC3.3544,巴氏诺卡菌(Nocardia brasiliensis)CGMCC 4.1128,其扩大培养液混合的体积比为10-15∶5-10∶10-20∶1-30∶5-15∶10-20。Alcaligenes xylosoxidans subsp CGMCC 1.768, Bacillus amyloliquefaciens CGMCC 1.1177, Debaryomyces hansenii CGMCC 2.1831; Issatchenkiascutulata) CGMCC 2.1592, Aleuisma keratinophilum (Aleuisma keratinophilum) CGMCC3.3544, Pasteur Nocardia (Nocardia brasiliensis) CGMCC 4.1128, the volume ratio of the mixed culture solution is 10-15:5-10:10- 20: 1-30: 5-15: 10-20.
本发明所用菌种的扩大培养基均参照《CGMCC菌种目录》。The expansion culture medium of bacterial classification used in the present invention all refers to " CGMCC bacterial classification catalogue ".
混合除臭菌种的使用方法为:The method of using the mixed deodorizing bacteria is as follows:
将混合除臭菌种按照体积比1∶50-100用水稀释,将稀释好的混合除臭菌种按照垃圾重量的0.5-5%(V/W)加入,按垃圾生物预处理工序进行发酵即可。Dilute the mixed deodorizing bacteria with water according to the volume ratio of 1:50-100, add the diluted mixed deodorizing bacteria according to 0.5-5% (V/W) of the weight of the garbage, and carry out fermentation according to the garbage biological pretreatment process. Can.
本发明与现有技术相比,利用多种菌群对生物预处理过程中所释放出的恶臭进行生物清除,能够有效的降低垃圾气体中氨类化合物的浓度。Compared with the prior art, the present invention utilizes a variety of bacterial groups to biologically remove the stench released during the biological pretreatment process, and can effectively reduce the concentration of ammonia compounds in the garbage gas.
附图说明:Description of drawings:
图1为本发明所述的垃圾生物回收法的流程图。Fig. 1 is a flow chart of the garbage biological recovery method of the present invention.
具体实施方式:Detailed ways:
下面结合实施例对本发明做详细的说明。Below in conjunction with embodiment the present invention is described in detail.
实施例1:Example 1:
原生垃圾先经过粗分选工序,将其中的竹木类包装箱、橡胶轮胎予以分开、并将大件破碎;Raw garbage first undergoes a rough sorting process, separating the bamboo and wood packaging boxes and rubber tires, and breaking the large pieces;
粗分选过的垃圾进行破袋,将破袋后的垃圾进行混合、称重,在混合过程中加入混合菌种,将菌种经扩大培养后,按如下体积比混合:木糖氧化碱菌反硝化亚种(Alcaligenes xylosoxidans subsp)CGMCC 1.768:解淀粉芽孢杆菌(Bacillus amyloliquefaciens)CGMCC 1.1177:耐放射异常球菌(Deinococcusradiodurans)CGMCC 1.633:汉逊德巴利酵母汉逊变种(Debaryomyces hansenii)CGMCC 2.1831:菱型伊萨酵母(Issatchenkia scutulata)CGMCC 2.1592,嗜角蛋白粉落霉(Aleuisma keratinophilum)CGMCC 3.3544:巴氏诺卡菌(Nocardiabrasiliensis)CGMCC 4.1128=10∶5∶10∶1∶5∶10。(每毫升液体中含有2×107个活性菌体以上)。The coarsely sorted garbage is broken into bags, and the broken bags are mixed and weighed. During the mixing process, mixed bacteria are added. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio: Alcalibacter xylosoxidans Alcaligenes xylosoxidans subsp CGMCC 1.768: Bacillus amyloliquefaciens CGMCC 1.1177: Deinococcus radiodurans CGMCC 1.633: Debaryomyces hansenii CGMCC 2.1831: Issatchenkia scutulata CGMCC 2.1592, Aleuisma keratinophilum CGMCC 3.3544: Nocardia brasiliensis CGMCC 4.1128=10:5:10:1:5:10. (There are more than 2×10 7 active bacteria in every milliliter of liquid).
在混合过程中,也一并加入混合除臭菌种,将菌种经扩大培养后,按如下体积比混合:During the mixing process, the mixed deodorizing bacteria are also added together. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio:
中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,小红酵母(Rhodotorula minuta)CGMCC 2.277,米根霉(Rhizopus oryzae)CGMCC3.1263,师岗链轮丝菌(Streptoverticillium morookaense)CGMCC 4.1122,其扩大培养液混合的体积比为1∶1∶3∶1。(每毫升液体中含有2×107个活性菌体以上)China Bullera sinensis Li CGMCC 2.1614, Rhodotorula minuta CGMCC 2.277, Rhizopus oryzae CGMCC 3.1263, Streptoverticillium morookaense CGMCC 4.1122, and its expanded The mixing volume ratio of the culture solution is 1:1:3:1. (There are more than 2× 107 active bacteria in each milliliter of liquid)
将上述两种菌种均按照体积比1∶50用水稀释,将稀释好的混合菌种分别按照垃圾重量的0.5%(V/W)加入,通风供氧发酵5天,温度控制在40-50℃,将生物预处理所产生的渗滤水经发酵罐底管道进入污水处理系统,产生的废气经过发酵罐上部的管道进入废气处理系统;将发酵好的垃圾称重后,输送到一次分选系统中进行分选。Dilute the above two strains with water according to the volume ratio of 1:50, add the diluted mixed strains according to 0.5% (V/W) of the weight of the garbage, and ferment for 5 days with ventilation and oxygen supply, and the temperature is controlled at 40-50°C. ℃, the percolation water produced by biological pretreatment enters the sewage treatment system through the pipeline at the bottom of the fermentation tank, and the waste gas generated enters the waste gas treatment system through the pipeline at the upper part of the fermentation tank; the fermented garbage is weighed and transported to the primary sorting sorting in the system.
实施例2:Example 2:
原生垃圾先经过粗分选工序,将其中的竹木类包装箱、橡胶轮胎予以分开、并将大件破碎;Raw garbage first undergoes a rough sorting process, separating the bamboo and wood packaging boxes and rubber tires, and breaking the large pieces;
粗分选过的垃圾进行破袋,将破袋后的垃圾进行混合、称重,在混合过程中加入混合菌种,将菌种经扩大培养后,按如下体积比混合:木糖氧化碱菌反硝化亚种(Alcaligenes xylosoxidans subsp)CGMCC 1.768:解淀粉芽孢杆菌(Bacillus amyloliquefaciens)CGMCC 1.1177:耐放射异常球菌(Deinococcusradiodurans)CGMCC 1.633:汉逊德巴利酵母汉逊变种(Debaryomyces hansenii)CGMCC 2.1831:菱型伊萨酵母(Issatchenkia scutulata)CGMCC 2.1592,嗜角蛋白粉落霉(Aleuisma keratinophilum)CGMCC 3.3544:巴氏诺卡菌(Nocardiabrasiliensis)CGMCC 4.1128=12∶7∶15∶15∶10∶15。(每毫升液体中含有2×107个活性菌体以上)。The coarsely sorted garbage is broken into bags, and the broken bags are mixed and weighed. During the mixing process, mixed bacteria are added. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio: Alcalibacter xylosoxidans Alcaligenes xylosoxidans subsp CGMCC 1.768: Bacillus amyloliquefaciens CGMCC 1.1177: Deinococcus radiodurans CGMCC 1.633: Debaryomyces hansenii CGMCC 2.1831: Issatchenkia scutulata CGMCC 2.1592, Aleuisma keratinophilum CGMCC 3.3544: Nocardia brasiliensis CGMCC 4.1128=12:7:15:15:10:15. (There are more than 2×10 7 active bacteria in every milliliter of liquid).
在混合过程中,也一并加入混合除臭菌种,将菌种经扩大培养后,按如下体积比混合:During the mixing process, the mixed deodorizing bacteria are also added together. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio:
中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,小红酵母(Rhodotorula minuta)CGMCC 2.277,米根霉(Rhizopus oryzae)CGMCC3.1263,师岗链轮丝菌(Streptoverticillium morookaense)CGMCC 4.1122,其扩大培养液混合的体积比为3∶5∶10∶2。(每毫升液体中含有2×107个活性菌体以上)China Bullera sinensis Li CGMCC 2.1614, Rhodotorula minuta CGMCC 2.277, Rhizopus oryzae CGMCC 3.1263, Streptoverticillium morookaense CGMCC 4.1122, and its expanded The mixing volume ratio of the culture solution is 3:5:10:2. (There are more than 2× 107 active bacteria in each milliliter of liquid)
将上述两种混合菌种均按照体积比1∶75用水稀释,将稀释好的混合菌种均按照垃圾重量的2.5%(V/W)加入,通风供氧发酵6天,温度控制在40-50℃,将生物预处理所产生的渗滤水经发酵罐底管道进入污水处理系统,产生的废气经过发酵罐上部的管道进入废气处理系统;将发酵好的垃圾称重后,输送到一次分选系统中进行分选,Dilute the above two mixed strains with water according to the volume ratio of 1:75, add the diluted mixed strains according to 2.5% (V/W) of the weight of the garbage, ventilate and supply oxygen for fermentation for 6 days, and the temperature is controlled at 40- 50°C, the infiltration water produced by biological pretreatment enters the sewage treatment system through the bottom pipeline of the fermentation tank, and the waste gas generated enters the waste gas treatment system through the pipeline on the upper part of the fermentation tank; after weighing the fermented garbage, it is transported to the primary separation sorting in the selection system,
实施例3:Example 3:
原生垃圾先经过粗分选工序,将其中的竹木类包装箱、橡胶轮胎予以分开、并将大件破碎;Raw garbage first undergoes a rough sorting process, separating the bamboo and wood packaging boxes and rubber tires, and breaking the large pieces;
粗分选过的垃圾进行破袋,将破袋后的垃圾进行混合、称重,在混合过程中加入混合菌种,将菌种经扩大培养后,按如下体积比混合:木糖氧化碱菌反硝化亚种(Alcaligenes xylosoxidans subsp)CGMCC 1.768:解淀粉芽孢杆菌(Bacillus amyloliquefaciens)CGMCC 1.1177:耐放射异常球菌(Deinococcusradiodurans)CGMCC 1.633:汉逊德巴利酵母汉逊变种(Debaryomyces hansenii)CGMCC 2.1831:菱型伊萨酵母(Issatchenkia scutulata)CGMCC 2.1592,嗜角蛋白粉落霉(Aleuisma keratinophilum)CGMCC 3.3544:巴氏诺卡菌(Nocardiabrasiliensis)CGMCC 4.1128=15∶10∶20∶30∶15∶20。(每毫升液体中含有2×107个活性菌体以上)。The coarsely sorted garbage is broken into bags, and the broken bags are mixed and weighed. During the mixing process, mixed bacteria are added. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio: Alcalibacter xylosoxidans Alcaligenes xylosoxidans subsp CGMCC 1.768: Bacillus amyloliquefaciens CGMCC 1.1177: Deinococcus radiodurans CGMCC 1.633: Debaryomyces hansenii CGMCC 2.1831: Issatchenkia scutulata CGMCC 2.1592, Aleuisma keratinophilum CGMCC 3.3544: Nocardia brasiliensis CGMCC 4.1128=15:10:20:30:15:20. (There are more than 2×10 7 active bacteria in every milliliter of liquid).
在混合过程中,也一并加入混合除臭菌种,将菌种经扩大培养后,按如下体积比混合:During the mixing process, the mixed deodorizing bacteria are also added together. After the bacteria are expanded and cultivated, they are mixed according to the following volume ratio:
中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,小红酵母(Rhodotorula minuta)CGMCC 2.277,米根霉(Rhizopus oryzae)CGMCC3.1263,师岗链轮丝菌(Streptoverticillium morookaense)CGMCC 4.1122,其扩大培养液混合的体积比为5∶10∶15∶10。(每毫升液体中含有2×107个活性菌体以上)China Bullera sinensis Li CGMCC 2.1614, Rhodotorula minuta CGMCC 2.277, Rhizopus oryzae CGMCC 3.1263, Streptoverticillium morookaense CGMCC 4.1122, and its expanded The mixing volume ratio of culture solution is 5:10:15:10. (There are more than 2× 107 active bacteria in each milliliter of liquid)
将上述两种混合菌种均按照体积比1∶100用水稀释,将稀释好的混合菌种分别按照垃圾重量的5%(V/W)加入,通风供氧发酵7天,温度控制在40-50℃,产生的废气经过发酵罐上部的管道进入废气处理系统;将发酵好的垃圾称重后,输送到一次分选系统中进行分选,Dilute the above two mixed strains with water according to the volume ratio of 1:100, add the diluted mixed strains according to 5% (V/W) of the weight of the garbage, and ferment for 7 days with ventilation and oxygen supply, and the temperature is controlled at 40- 50°C, the waste gas generated enters the waste gas treatment system through the pipeline on the upper part of the fermentation tank; after weighing the fermented waste, it is transported to the primary sorting system for sorting,
实施例4:Example 4:
除在混合除臭菌种添加谷氏链霉菌(Streptomyces gougerotii)CGMCC 4.28,其与中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,的扩大培养液混合的体积比为1∶1外,其余与实施例2相同。In addition to adding Streptomyces gougerotii CGMCC 4.28 to the mixed deodorizing strains, the volume ratio of the expanded culture medium mixed with Chinese Bullera sinensis Li CGMCC 2.1614 is 1:1, and the rest Same as Example 2.
实施例5:Example 5:
除在混合除臭菌种添加谷氏链霉菌(Streptomyces gougerotii)CGMCC 4.28,其与中国布勒弹孢酵母(Bullera sinensis Li)CGMCC 2.1614,的扩大培养液混合的体积比为1∶5外,其余与实施例2相同。In addition to adding Streptomyces gougerotii CGMCC 4.28 to the mixed deodorizing strains, the volume ratio of the expanded culture medium mixed with Chinese Bullera sinensis Li CGMCC 2.1614 is 1:5, and the rest Same as Example 2.
将实施例1-5处理后的气体进行检测,氨的去除率达到85%,甲胺的去除率达到80%,乙胺的去除率达到82%。The gas after the treatment of Examples 1-5 is detected, and the removal rate of ammonia reaches 85%, the removal rate of methylamine reaches 80%, and the removal rate of ethylamine reaches 82%.
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| CN200710021187A CN100579678C (en) | 2007-03-31 | 2007-03-31 | A deodorizing method for biological pretreatment of urban waste |
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| CN100579678C true CN100579678C (en) | 2010-01-13 |
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| CN102925372B (en) * | 2012-08-27 | 2014-11-12 | 浙江工业大学 | Marine fungus rhodotorula minuta and application thereof in preparing anti-tumor medicines |
| CN103509743A (en) * | 2013-09-09 | 2014-01-15 | 深圳市三盛环保科技有限公司 | Microbial compound preparation and preparation method |
| CN105779357A (en) * | 2016-04-18 | 2016-07-20 | 福建美家园生物科技股份有限公司 | Deodorant organic compost fermentation inoculant and application thereof |
| CN106085929B (en) * | 2016-08-28 | 2019-06-25 | 广东创美达环保科技有限公司 | A method of municipal waste disposal |
| CN115141693A (en) * | 2022-08-02 | 2022-10-04 | 王启含 | Beer preparation method based on active polypeptide |
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