CN100566805C - Method of formulating transparent diesel oil emulsifier - Google Patents
Method of formulating transparent diesel oil emulsifier Download PDFInfo
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- CN100566805C CN100566805C CNB2005100097652A CN200510009765A CN100566805C CN 100566805 C CN100566805 C CN 100566805C CN B2005100097652 A CNB2005100097652 A CN B2005100097652A CN 200510009765 A CN200510009765 A CN 200510009765A CN 100566805 C CN100566805 C CN 100566805C
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- parts
- diesel oil
- emulsifier
- ethanolamine
- span
- Prior art date
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 12
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 8
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005642 Oleic acid Substances 0.000 claims abstract description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 8
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 5
- -1 span Chemical compound 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MMKZAICYSVWBPW-UHFFFAOYSA-N 2-[[2-(difluoromethoxy)phenyl]methylamino]-1-[3-(trifluoromethyl)phenyl]ethanol Chemical group C=1C=CC(C(F)(F)F)=CC=1C(O)CNCC1=CC=CC=C1OC(F)F MMKZAICYSVWBPW-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- Liquid Carbonaceous Fuels (AREA)
- Medicinal Preparation (AREA)
Abstract
本发明涉及乳化剂，具体为一种柴油透明乳化剂配制方法。其特点是：它包含环烷酸、司盘、乙醇胺、磷酸三丁酯、异戊醇、油酸。其组份的具体重量份数配比为：环烷酸50-60份、司盘-805-10份、乙醇胺5-10份、磷酸三丁酯5-10份、异戊醇5-10份、油酸5-10份，将原料按上述的先后顺序倒入合成釜中，在1400转每分钟转速下搅拌10分钟即可。本发明的优点是：配方结构简单、成本低廉、安全可靠、操作使用方便，与柴油合配使用可达到国际标准的要求。The invention relates to an emulsifier, in particular to a method for preparing a transparent emulsifier for diesel oil. Its characteristic is: it contains naphthenic acid, span, ethanolamine, tributyl phosphate, isoamyl alcohol, oleic acid. The specific weight ratio of its components is: 50-60 parts of naphthenic acid, 5-10 parts of Span-805, 5-10 parts of ethanolamine, 5-10 parts of tributyl phosphate, 5-10 parts of isoamyl alcohol , 5-10 parts of oleic acid, pour the raw materials into the synthesis kettle according to the above sequence, and stir for 10 minutes at 1400 rpm. The invention has the advantages of simple formula structure, low cost, safety and reliability, convenient operation and use, and can meet the requirements of international standards when used together with diesel oil.
Description
技术领域： Technical field:
本发明涉及乳化剂，具体为一种柴油透明乳化剂配制方法。The invention relates to an emulsifier, in particular to a method for preparing a transparent emulsifier for diesel oil.
背景技术： Background technique:
目前，在我国柴油乳化剂和乳化柴油有许多配方，但是它们都没有达到最佳效果，技术指标也不高。At present, there are many formulas for diesel emulsifiers and emulsified diesel in our country, but none of them have achieved the best results, and the technical indicators are not high.
发明内容： Invention content:
本发明的目的在于提供一种结构简单、成本低廉、安全可靠、使用方便的柴油透明乳化剂配制方法。本发明的目的是这样实现的：它包含环烷酸、司盘、乙醇胺、磷酸三丁酯、异戊醇、油酸。所述柴油透明乳化剂中各组份重量分数配比为：环烷酸50-60份、司盘-80 5-10份、乙醇胺5-10份、磷酸三丁酯5-10份、异戊醇5-10份、油酸5-10份，将原料按上述的先后顺序倒入合成釜中，在1400转每分钟转速下搅拌10分钟即可。本发明的优点是：配方结构简单、成本低廉、安全可靠、操作使用方便，与柴油合配使用可达到国际标准的要求。The purpose of the present invention is to provide a simple structure, low cost, safe and reliable, easy to use diesel oil transparent emulsifier preparation method. The object of the present invention is achieved like this: it comprises naphthenic acid, Span, ethanolamine, tributyl phosphate, isoamyl alcohol, oleic acid. The weight fraction ratio of each component in the diesel oil transparent emulsifier is: 50-60 parts of naphthenic acid, 5-10 parts of Span-80, 5-10 parts of ethanolamine, 5-10 parts of tributyl phosphate, isoamyl 5-10 parts of alcohol, 5-10 parts of oleic acid, pour the raw materials into the synthesis kettle according to the above sequence, and stir at 1400 rpm for 10 minutes. The invention has the advantages of simple formula structure, low cost, safety and reliability, convenient operation and use, and can meet the requirements of international standards when used together with diesel oil.
具体实施方式： Detailed ways:
所述柴油透明乳化剂中各组份重量分数配比为：环烷酸50-60份、司盘-80 5-10份、乙醇胺5-10份、磷酸三丁酯5-10份、异戊醇5-10份、油酸5-10份，将原料按上述的先后顺序倒入合成釜中，在1400转每分钟转速下搅拌10分钟即可。The weight fraction ratio of each component in the diesel oil transparent emulsifier is: 50-60 parts of naphthenic acid, 5-10 parts of Span-80, 5-10 parts of ethanolamine, 5-10 parts of tributyl phosphate, isoamyl 5-10 parts of alcohol, 5-10 parts of oleic acid, pour the raw materials into the synthesis kettle according to the above sequence, and stir at 1400 rpm for 10 minutes.
例1，将环烷酸60份、司盘-80 10份、乙醇胺5份、磷酸三丁酯10份、异戊醇5份、油酸10份按上述的先后顺序倒入合成釜中搅拌10分钟(转数1400转/分钟)即为本发明成品。将柴油60％与本发明20％柴油乳化剂放入一起搅拌均匀，再将水20％(水温45℃以上为好)放入搅拌均匀，可调成透明柴油，与国标油在外观上完全一样，可用于各种柴油内燃机。Example 1, pour 60 parts of naphthenic acid, 10 parts of Span-80, 5 parts of ethanolamine, 10 parts of tributyl phosphate, 5 parts of isoamyl alcohol, and 10 parts of oleic acid into the synthesis kettle according to the above sequence and stir for 10 Minutes (number of revolutions 1400 revs/min) is the finished product of the present invention. Put 60% diesel oil and 20% diesel emulsifier of the present invention together and stir evenly, then put 20% water (preferably water temperature above 45°C) and stir evenly, it can be adjusted into transparent diesel oil, which is exactly the same as the national standard oil in appearance , can be used in various diesel internal combustion engines.
例2，将环烷酸60份、司盘-80 10份、乙醇胺5份、磷酸三丁酯10份、异戊醇5份、油酸10份按上述的先后顺序倒入合成釜中搅拌10分钟(转数1400转/分钟)即为本发明成品。将柴油75％与本发明5％的柴油乳化剂放入一起搅拌均匀，再将水20％(水温45℃以上为好)放入搅拌均匀，可调成透明乳化柴油，可用于柴油机，而且稳定性好，排放量小，优于普通柴油，改善燃烧环境。在本发明中再加入15％的乙醇可降低油品的闪点，直接用于工业燃烧器。若用超声空化乳化机效果更好。Example 2, pour 60 parts of naphthenic acid, 10 parts of Span-80, 5 parts of ethanolamine, 10 parts of tributyl phosphate, 5 parts of isoamyl alcohol, and 10 parts of oleic acid into the synthesis kettle according to the above sequence and stir for 10 Minutes (number of revolutions 1400 revs/min) is the finished product of the present invention. Put 75% of diesel oil and 5% of the diesel emulsifier of the present invention together and stir evenly, then put 20% of water (preferably water temperature above 45°C) into and stir evenly, and it can be adjusted into transparent emulsified diesel oil, which can be used in diesel engines and is stable Good performance, low emission, superior to ordinary diesel, and improves the combustion environment. Adding 15% ethanol in the present invention can reduce the flash point of the oil product and can be directly used in industrial burners. It is better to use ultrasonic cavitation emulsification machine.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100097652A CN100566805C (en) | 2005-02-25 | 2005-02-25 | Method of formulating transparent diesel oil emulsifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100097652A CN100566805C (en) | 2005-02-25 | 2005-02-25 | Method of formulating transparent diesel oil emulsifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1818029A CN1818029A (en) | 2006-08-16 |
| CN100566805C true CN100566805C (en) | 2009-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100097652A Expired - Fee Related CN100566805C (en) | 2005-02-25 | 2005-02-25 | Method of formulating transparent diesel oil emulsifier |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007139925A2 (en) | 2006-05-26 | 2007-12-06 | Amyris Biotechnologies, Inc. | Fuel components, fuel compositions and methods of making and using same |
| EP2024504B2 (en) | 2006-05-26 | 2022-12-14 | Amyris, Inc. | Production of isoprenoids |
| CN101987982A (en) * | 2010-07-01 | 2011-03-23 | 烟台汽车工程职业学院 | Emulsified diesel fuel and emulsifying agent preparation method |
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2005
- 2005-02-25 CN CNB2005100097652A patent/CN100566805C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1818029A (en) | 2006-08-16 |
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Granted publication date: 20091209 Termination date: 20100225 |