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CN100545325C - 具有功能效果的纤维素形式和其制造方法 - Google Patents

具有功能效果的纤维素形式和其制造方法 Download PDF

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Publication number
CN100545325C
CN100545325C CNB2004800091522A CN200480009152A CN100545325C CN 100545325 C CN100545325 C CN 100545325C CN B2004800091522 A CNB2004800091522 A CN B2004800091522A CN 200480009152 A CN200480009152 A CN 200480009152A CN 100545325 C CN100545325 C CN 100545325C
Authority
CN
China
Prior art keywords
fibers
ions
cellulose
bactericide
ion exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB2004800091522A
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English (en)
Chinese (zh)
Other versions
CN1816651A (zh
Inventor
莱纳·巴特纳
哈代·马克维兹
卡门·诺贝斯多夫
拉尔夫·鲍尔
弗兰克·梅斯特
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Smart Polymer Ltd By Share Ltd
Original Assignee
Thuringian Institute For Textile And Plastic Research And Registration
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of CN1816651A publication Critical patent/CN1816651A/zh
Application granted granted Critical
Publication of CN100545325C publication Critical patent/CN100545325C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42Oxides or hydroxides of copper, silver or gold
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/20Chemically or biochemically modified fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904Staple length fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904Staple length fiber
    • Y10T428/2905Plural and with bonded intersections only

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Pest Control & Pesticides (AREA)
  • Biochemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Artificial Filaments (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Knitting Of Fabric (AREA)
  • Nonwoven Fabrics (AREA)
  • Paper (AREA)
CNB2004800091522A 2003-04-04 2004-04-01 具有功能效果的纤维素形式和其制造方法 Expired - Lifetime CN100545325C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10315749.2 2003-04-04
DE10315749A DE10315749A1 (de) 2003-04-04 2003-04-04 Verfahren zur Herstellung von cellulosischen Formkörpern mit funktionaler Wirkung

Publications (2)

Publication Number Publication Date
CN1816651A CN1816651A (zh) 2006-08-09
CN100545325C true CN100545325C (zh) 2009-09-30

Family

ID=32981104

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800091522A Expired - Lifetime CN100545325C (zh) 2003-04-04 2004-04-01 具有功能效果的纤维素形式和其制造方法

Country Status (9)

Country Link
US (1) US20060283567A1 (pl)
EP (1) EP1611272B1 (pl)
JP (1) JP2006522232A (pl)
CN (1) CN100545325C (pl)
AT (1) ATE440981T1 (pl)
DE (2) DE10315749A1 (pl)
PL (1) PL1611272T3 (pl)
RU (1) RU2340710C2 (pl)
WO (1) WO2004088009A1 (pl)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006056977B3 (de) 2006-11-30 2008-05-08 Smart Fiber Ag Verwendung eines textilen mikrobioziden Speichers
DE102007012972B4 (de) * 2007-03-14 2010-09-02 Smart Fiber Ag Vorrichtung zur bioziden Behandlung von Wäsche
DE102007019768A1 (de) * 2007-04-25 2008-11-13 Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. Verfahren zur Herstellung einer bioaktiven Cellulosefaser mit hohem Weißgrad
DE102007054702B4 (de) * 2007-11-14 2018-10-18 Smartpolymer Gmbh Verfahren zur Herstellung von cellulosischen Formkörpern, cellulosischer Formkörper und dessen Verwendung
DE102009010968A1 (de) 2009-02-27 2010-09-02 Flockfaser GmbH Thüringen Antibakteriell aktive Flockfasern
CN102220730B (zh) * 2011-04-13 2013-08-28 成都印钞有限公司 钞票用银锌磷酸锆复合抗菌剂及其制备方法
RU2472892C1 (ru) * 2011-10-13 2013-01-20 Леонид Асхатович Мазитов Способ получения бактерицидной бумаги
GB2511528A (en) 2013-03-06 2014-09-10 Speciality Fibres And Materials Ltd Absorbent materials
CN104389245B (zh) * 2014-09-29 2016-02-17 吉特利环保科技(厦门)有限公司 一种纳米银抗菌纤维餐具的制备工艺
CN105200844A (zh) * 2015-08-21 2015-12-30 西南石油大学 一种抗菌消毒薄页纸的制备方法
US20220061327A1 (en) * 2020-08-28 2022-03-03 Uop Llc Antiviral metal treatments for fiber substrates, filter media having antiviral metal treatments, and processes for treating fiber substrates
DE102022109459A1 (de) * 2021-04-21 2022-10-27 Smartpolymer Gmbh Waschpermanente bioaktive Cellulosefaser mit antibakteriellen und antiviralen Eigenschaften

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1181392A (zh) * 1996-10-14 1998-05-13 株式会社日本触媒 水可溶胀的交联聚合物,其制造方法,和测量溶胀的交联聚合物孔体积的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0622540B2 (ja) * 1985-12-18 1994-03-30 株式会社祥光化学研究所 消臭抗菌能を有する構造物
JP2528914B2 (ja) * 1986-12-16 1996-08-28 株式会社日本触媒 体液吸収物品
US4842593A (en) * 1987-10-09 1989-06-27 The Procter & Gamble Company Disposable absorbent articles for incontinent individuals
JPH0813905B2 (ja) * 1989-06-23 1996-02-14 大和紡績株式会社 イオン交換機能を持ったセルロース系組成物
JP2520321B2 (ja) * 1990-06-19 1996-07-31 大和紡績株式会社 イオン交換機能を持ったセルロ―ス系組成物
EP0763364B1 (en) * 1995-09-14 2003-07-16 Nippon Shokubai Co., Ltd. Absorbent composite, absorbent article and methods for their production
US6258368B1 (en) * 1997-06-04 2001-07-10 The Procter & Gamble Company Antimicrobial wipes
DE19805447A1 (de) * 1998-02-11 1999-08-12 Bayer Ag Modifizierte Superabsorber auf Basis von Polyacrylnitril-Emulsionen
US6110533A (en) * 1998-03-16 2000-08-29 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Natural Resources Polymeric desiccant articles and process for their manufacture
JP2000211901A (ja) * 1998-11-17 2000-08-02 Hisao Ishiguro 二酸化塩素含有ゲル状組成物とその製造方法及びその保管方法並びに二酸化塩素含有ゲル状組成物の充填体と二酸化塩素含有ゲル状組成物の充填体収納袋及び二酸化塩素含有ゲル状組成物収納容器
JP2000273313A (ja) * 1999-03-23 2000-10-03 Mizusawa Ind Chem Ltd 繊維乃至膜用配合剤及び繊維乃至膜形成用樹脂組成物
DE19917614C2 (de) * 1999-04-19 2001-07-05 Thueringisches Inst Textil Verfahren zur Herstellung von cellulosischen Formkörpern mit hohem Adsorptionsvermögen
US6660903B1 (en) * 1999-10-01 2003-12-09 Kimberly-Clark Worldwide, Inc. Center-fill absorbent article with a central rising member
DE10009471B4 (de) * 2000-02-28 2006-07-27 Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. Verfahren zur Herstellung einer Lösung erhöhter thermischer Stabilität von Cellulose in wässrigem Aminoxid
US6828014B2 (en) * 2001-03-22 2004-12-07 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
DE10140772A1 (de) * 2001-08-20 2003-03-13 Zimmer Ag Verfahren zur Entfernung von Schwermetallen aus schwermetallhaltigen Medien unter Verwendung eines Lyocell-Formkörpers sowie Lyocell-Formkörper mit adsorbierten Schwermetallen und deren Verwendung
US7655112B2 (en) * 2002-01-31 2010-02-02 Kx Technologies, Llc Integrated paper comprising fibrillated fibers and active particles immobilized therein
JP2004123662A (ja) * 2002-10-07 2004-04-22 Lion Corp 角質除去シート

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1181392A (zh) * 1996-10-14 1998-05-13 株式会社日本触媒 水可溶胀的交联聚合物,其制造方法,和测量溶胀的交联聚合物孔体积的方法

Also Published As

Publication number Publication date
ATE440981T1 (de) 2009-09-15
US20060283567A1 (en) 2006-12-21
PL1611272T3 (pl) 2009-12-31
CN1816651A (zh) 2006-08-09
DE502004009966D1 (de) 2009-10-08
RU2005134210A (ru) 2006-05-10
RU2340710C2 (ru) 2008-12-10
JP2006522232A (ja) 2006-09-28
WO2004088009A1 (de) 2004-10-14
EP1611272A1 (de) 2006-01-04
EP1611272B1 (de) 2009-08-26
DE10315749A1 (de) 2004-10-14

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Granted publication date: 20090930