CN100532655C - The Method of Re-plating Nickel on Metal Plating Parts - Google Patents
The Method of Re-plating Nickel on Metal Plating Parts Download PDFInfo
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- CN100532655C CN100532655C CNB2005100571367A CN200510057136A CN100532655C CN 100532655 C CN100532655 C CN 100532655C CN B2005100571367 A CNB2005100571367 A CN B2005100571367A CN 200510057136 A CN200510057136 A CN 200510057136A CN 100532655 C CN100532655 C CN 100532655C
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- nickel
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000007747 plating Methods 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 16
- 239000002184 metal Substances 0.000 title claims abstract description 16
- 238000011536 re-plating Methods 0.000 title description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 12
- 238000004140 cleaning Methods 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 238000007796 conventional method Methods 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 230000004913 activation Effects 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 230000000295 complement effect Effects 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 238000005238 degreasing Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
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- Electroplating Methods And Accessories (AREA)
Abstract
Description
技术领域 technical field
本发明属于金属材料表面处理领域,特别涉及一种补镀后结合力好、操作简单的金属镀件补镀镍的方法。The invention belongs to the field of surface treatment of metal materials, and in particular relates to a nickel replating method for a metal plating piece with good bonding force after replating and simple operation.
背景技术 Background technique
工业生产过程中,常需要对零件的表面进行电镀,以提高其表面的防腐性能和装饰性。而在装饰镀铬过程中,由于有时会有一些不可控制的因素,使镀层局部不完整或发花,当出现这种情况时,不合格镀层不必退除重镀,只须补镀,即退掉薄薄的装饰铬层(只有0.25~0.5微米)和部分镍层,补够镍层厚度后,再电镀装饰铬层。目前,采用的补镀的工艺流程为:阳极去油→阴极去油→清洗→清洗→酸活化→补镀亮镍→清洗→清洗→硫酸活化→镀亮铬。这种工艺不仅操作较复杂,整个工艺工作时间长,并且补后镀层结合力不好。有的当时就有表现,有的在交货后才表现出来,给用户留下极坏的印象。In the process of industrial production, it is often necessary to electroplate the surface of parts to improve the anti-corrosion performance and decoration of the surface. In the process of decorative chrome plating, due to some uncontrollable factors sometimes, the coating is partially incomplete or faded. When this happens, the unqualified coating does not need to be removed and re-plated, but only needs to be re-plated, that is, it will be removed. A thin decorative chromium layer (only 0.25-0.5 microns) and a part of the nickel layer are added to the thickness of the nickel layer, and then the decorative chromium layer is electroplated. At present, the process flow of replating is: anode degreasing→cathode degreasing→cleaning→cleaning→acid activation→replating bright nickel→cleaning→cleaning→sulfuric acid activation→bright chrome plating. This process is not only more complicated to operate, but also takes a long time to work in the whole process, and the bonding force of the coating after repairing is not good. Some of them showed up at the time, and some showed up after delivery, leaving a very bad impression on users.
发明内容 Contents of the invention
本发明的目的,是提供一种金属镀件补镀镍的方法。它使补镀后镀层与工件的结合力好,并且工艺简单,产品表面质量好。The purpose of the present invention is to provide a method for re-plating nickel on metal plated parts. It makes the bonding force of the plating layer and the workpiece good after replating, and the process is simple, and the product surface quality is good.
本发明的目的是这样实现的:The purpose of the present invention is achieved like this:
本发明包括以下步骤The present invention comprises the following steps
(1)采用常规的方法对金属镀件表面进行除油、清洗;(1) Use conventional methods to degrease and clean the surface of the metal plated parts;
(2)电解酸活化(2) Electrolytic acid activation
盐酸溶液为 HCl 250~400克/升Hydrochloric acid solution is HCl 250~400 g/L
金属镀件施以2~4安/平方分米的阳极电流,阴极用镍板,时间:1~3分钟;Apply an anode current of 2 to 4 amps/square decimeter to the metal plated parts, and use a nickel plate for the cathode, time: 1 to 3 minutes;
(3)用常规的方法补镍、清洗、活化和镀铬。(3) Nickel supplementation, cleaning, activation and chrome plating are performed by conventional methods.
本发明的优点是:The advantages of the present invention are:
1.采用电解酸活化,使退除的铬层、部分亮镍层和镀前活化的两步工艺并成一步完成,因此可以简化工艺,有操作简单的优点;1. Electrolytic acid activation is used to complete the two-step process of removing the chromium layer, part of the bright nickel layer and pre-plating activation in one step, so the process can be simplified and the operation is simple;
2.由于镍不太活泼,与盐酸和硫酸反应缓慢,采用电解酸活化,才能激活镍,打开镍晶格,使补镀的亮镍层与打开了晶格的镍层能很好的结合,因此保证镀层的结合力。2. Because nickel is not very active, it reacts slowly with hydrochloric acid and sulfuric acid. Only by electrolytic acid activation can nickel be activated and the nickel lattice be opened, so that the bright nickel layer after replating can be well combined with the nickel layer that has opened the lattice. Therefore, the bonding force of the coating is guaranteed.
下面结合实施例对本发明做进一步的说明。Below in conjunction with embodiment the present invention will be further described.
具体实施方式 Detailed ways
实施例1Example 1
采用常规的方法对金属镀件表面进行除油,清洗,按照盐酸:300克/升,采用镍阴极板,以2安/平方分米的阳极电流,时间3分钟的电解酸活化,再用常规的方法补镀亮镍,两次清洗,硫酸活化,镀亮铬,补镀10件换档踏板。镀后用锉刀法测定镀层的结合力,检测结果合格。Use the conventional method to degrease and clean the surface of the metal plated parts, according to the hydrochloric acid: 300 g/liter, use the nickel cathode plate, activate the electrolytic acid with the anode current of 2 amps/square decimeter for 3 minutes, and then use the conventional method The method is to re-plate bright nickel, wash twice, activate sulfuric acid, plate bright chrome, and re-plate 10 shift pedals. After plating, the binding force of the coating was measured by the file method, and the test result was qualified.
实施例2Example 2
采用常规的方法对金属镀件表面进行除油,清洗,按照盐酸:300克/升,采用镍阴极板,以2.5安/平方分米的阳极电流,时间2.5分钟的电解酸活化,再用常规的方法补镀亮镍,两次清洗,硫酸活化,镀亮铬,补镀10件换档踏板。镀后用锉刀法测定镀层的结合力,检测结果合格。Use conventional methods to degrease and clean the surface of metal plated parts. According to hydrochloric acid: 300 g/liter, use nickel cathode plate, activate electrolytic acid with an anode current of 2.5 amps/square decimeter for 2.5 minutes, and then use conventional The method is to re-plate bright nickel, wash twice, activate sulfuric acid, plate bright chrome, and re-plate 10 shift pedals. After plating, the binding force of the coating was measured by the file method, and the test result was qualified.
实施例3Example 3
采用常规的方法对金属镀件表面进行除油,清洗,按照盐酸:330克/升,采用镍阴极板,以3安/平方分米的阳极电流,时间2分钟的电解酸活化,再用常规的方法补镀亮镍,两次清洗,硫酸活化,镀亮铬,补镀10件减震弹簧。镀后用锉刀法测定镀层的结合力,检测结果合格。Use the conventional method to degrease and clean the surface of the metal plated parts. According to hydrochloric acid: 330 g/liter, use nickel cathode plate, activate the electrolytic acid with an anode current of 3 amps/square decimeter for 2 minutes, and then use conventional The method is to re-plate bright nickel, wash twice, activate sulfuric acid, plate bright chrome, and re-plate 10 pieces of shock-absorbing springs. After plating, the binding force of the coating was measured by the file method, and the test result was qualified.
实施例4Example 4
采用常规的方法对金属镀件表面进行除油,清洗,按照盐酸:370克/升,采用镍阴极板,以3.5安/平方分米的阳极电流,时间1.5分钟的电解酸活化,再用常规的方法补镀亮镍,两次清洗,硫酸活化,镀亮铬,补镀10件减震弹簧。镀后用锉刀法测定镀层的结合力,检测结果合格。Use the conventional method to degrease and clean the surface of the metal plated parts, according to the hydrochloric acid: 370 g/liter, use the nickel cathode plate, activate the electrolytic acid with the anode current of 3.5 amps/square decimeter for 1.5 minutes, and then use the conventional The method is to re-plate bright nickel, wash twice, activate sulfuric acid, plate bright chrome, and re-plate 10 pieces of shock-absorbing springs. After plating, the binding force of the coating was measured by the file method, and the test result was qualified.
实施例5Example 5
采用常规的方法对金属镀件表面进行除油,清洗,按照盐酸:400克/升,采用镍阴极板,以4安/平方分米的阳极电流,时间1分钟的电解酸活化,再用常规的方法补镀亮镍,两次清洗,硫酸活化,镀亮铬,补镀10件减震套管。镀后用锉刀法测定镀层的结合力,检测结果合格。Use the conventional method to degrease and clean the surface of the metal plated parts. According to the hydrochloric acid: 400 g/liter, use the nickel cathode plate, activate the electrolytic acid with the anode current of 4 amps/square decimeter for 1 minute, and then use the conventional method. The method is to re-plate bright nickel, wash twice, activate sulfuric acid, plate bright chrome, and re-plate 10 shock-absorbing sleeves. After plating, the binding force of the coating was measured by the file method, and the test result was qualified.
本发明在对金属镀件表面进行除油时,采用零件阴-阳极联合去油效果更好。When the present invention degreases the surface of the metal plated parts, the combination of the anode and cathode of the part is used for better degreasing effect.
Claims (1)
- A kind of method of repair nickel coating no metal coated piece is characterized in that: may further comprise the steps(1) adopt conventional method that metal plating piece surface is cleaned;(2) electrolysis acid activationHydrochloric acid soln is HCl 250~400 grams per litersThe metal plating piece imposes the anodic current of 2~4 peace/square decimeters, negative electrode nickel plate, time: 1~3 minute;(3) mend nickel, cleaning, activation and chromium plating with conventional method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100571367A CN100532655C (en) | 2005-06-22 | 2005-06-22 | The Method of Re-plating Nickel on Metal Plating Parts |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100571367A CN100532655C (en) | 2005-06-22 | 2005-06-22 | The Method of Re-plating Nickel on Metal Plating Parts |
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| Publication Number | Publication Date |
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| CN1724717A CN1724717A (en) | 2006-01-25 |
| CN100532655C true CN100532655C (en) | 2009-08-26 |
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| CNB2005100571367A Expired - Fee Related CN100532655C (en) | 2005-06-22 | 2005-06-22 | The Method of Re-plating Nickel on Metal Plating Parts |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101012571B (en) * | 2006-12-31 | 2010-05-19 | 湖南纳菲尔新材料科技股份有限公司 | Anodic activation treatment process before electroplating |
| CN102268714B (en) * | 2011-06-28 | 2016-06-29 | 中国科学院过程工程研究所 | A kind of electrochemical pre-treatment method of electrolytic extraction of gallium negative electrode |
| CN110846697B (en) * | 2019-10-30 | 2021-05-18 | 贵州天义电器有限责任公司 | Method for repairing nickel-plated layer of metal plated part |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6123790A (en) | 1984-07-12 | 1986-02-01 | Hitachi Cable Ltd | Method for plating ni or ni alloy surface |
| JPH02173291A (en) | 1988-12-26 | 1990-07-04 | Kawasaki Steel Corp | Production of zn or zn-ni alloy plated stainless steel strip |
| CN1113969A (en) * | 1994-05-31 | 1995-12-27 | 中国科学院大连化学物理研究所 | Surface treatment method for titanium matrix metal electrode |
| US6165345A (en) * | 1999-01-14 | 2000-12-26 | Chromalloy Gas Turbine Corporation | Electrochemical stripping of turbine blades |
-
2005
- 2005-06-22 CN CNB2005100571367A patent/CN100532655C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6123790A (en) | 1984-07-12 | 1986-02-01 | Hitachi Cable Ltd | Method for plating ni or ni alloy surface |
| JPH02173291A (en) | 1988-12-26 | 1990-07-04 | Kawasaki Steel Corp | Production of zn or zn-ni alloy plated stainless steel strip |
| CN1113969A (en) * | 1994-05-31 | 1995-12-27 | 中国科学院大连化学物理研究所 | Surface treatment method for titanium matrix metal electrode |
| US6165345A (en) * | 1999-01-14 | 2000-12-26 | Chromalloy Gas Turbine Corporation | Electrochemical stripping of turbine blades |
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| CN1724717A (en) | 2006-01-25 |
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Effective date of registration: 20151124 Address after: 400054 Banan District, Chongqing building Avenue, No. 2, building 1 Patentee after: CHONGQING CONSTRUCTION ELECTROMECHANICAL CO., LTD. Address before: Zheng Jie 400050 Xiejiawan Jiulongpo District of Chongqing City No. 47 Patentee before: Chongqing Jianshe Motorcycle Co., Ltd. |
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