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CN100479176C - Image sensing element and manufacturing method thereof - Google Patents

Image sensing element and manufacturing method thereof Download PDF

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CN100479176C
CN100479176C CNB2006100773626A CN200610077362A CN100479176C CN 100479176 C CN100479176 C CN 100479176C CN B2006100773626 A CNB2006100773626 A CN B2006100773626A CN 200610077362 A CN200610077362 A CN 200610077362A CN 100479176 C CN100479176 C CN 100479176C
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substrate
sensing area
optical sensing
grid
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CN101064328A (en
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高境鸿
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United Microelectronics Corp
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Abstract

The invention relates to a method for manufacturing an image sensing element, which mainly forms a dielectric protective layer on a light sensing area before forming a grid of an MOS (metal oxide semiconductor), thereby avoiding surface damage of the light sensing area caused by plasma or etching in the process of forming an MOS component and further improving the phenomenon of dark current generation. The invention also discloses an image sensing element manufactured by the method, which is characterized in that the grid electrode is partially laminated above the dielectric protection layer, and the surface of the light sensing area is smooth, so that the image sensing element has good performance.

Description

影像感测元件及其制法 Image sensing element and its manufacturing method

技术领域 technical field

本发明涉及一种影像传感器及其制法,特别是涉及一种使用感光二极管的互补式金氧半导体晶体管影像传感器及其制法。The invention relates to an image sensor and its manufacturing method, in particular to a complementary metal oxide semiconductor transistor image sensor using a photosensitive diode and its manufacturing method.

背景技术 Background technique

互补式金氧半导体晶体管影像传感器(CMOS image sensor,CIS)和电荷耦合装置(charge-coupled devices,CCDs)都是现有技术中常用来将光转换为电子信号的光学电路元件,两者的应用范围皆很广泛,包括有扫描仪、摄影机、以及照相机等等,但是因为载子耦合装置受限于价位高以及体积大的问题,所以目前市面上以互补式金氧半导体晶体管影像传感器较为普及。互补式金氧半导体晶体管影像传感器,是以传统的半导体工艺制作,因此可以大幅减少所需成本及元件尺寸,目前大致分为线型、面型两种,而线型互补式金氧半导体晶体管影像传感器以应用在扫瞄器等产品为主,面型互补式金氧半导体晶体管影像传感器则以应用在数码相机等产品为主。Complementary metal oxide semiconductor transistor image sensors (CMOS image sensors, CIS) and charge-coupled devices (charge-coupled devices, CCDs) are optical circuit components commonly used in the prior art to convert light into electronic signals. The application of the two The range is very wide, including scanners, video cameras, and cameras, etc. However, because the carrier coupling device is limited by the high price and large size, currently the complementary metal oxide semiconductor transistor image sensor is more popular in the market. Complementary metal-oxide-semiconductor transistor image sensors are manufactured by traditional semiconductor technology, so the required cost and component size can be greatly reduced. At present, they are roughly divided into two types: linear and surface-type, and linear complementary metal-oxide-semiconductor transistor image sensors Sensors are mainly used in scanners and other products, while area complementary metal oxide semiconductor transistor image sensors are mainly used in digital cameras and other products.

对于CMOS影像感测元件的性能而言,暗电流是重要指标,希望不存在。暗电流与制造期间发生的浅沟槽隔离结构(STI)(或局部硅氧化(LOCOS))引起的缺陷、等离子体缺陷、晶片不纯物等等有关。例如,CMOS影像感测元件的感光二极管层于等离子体蚀刻工艺期间易受损坏,因此严生暗电流。For the performance of CMOS image sensing elements, dark current is an important index, and it is hoped that it does not exist. Dark current is related to shallow trench isolation (STI) (or local oxidation of silicon (LOCOS)) induced defects, plasma defects, wafer impurities, etc. that occur during fabrication. For example, the photodiode layer of the CMOS image sensor device is easily damaged during the plasma etching process, so dark current is severely generated.

美国专利第6,906,364号揭示一种CMOS影像感测元件的结构以减少暗电流的产生,其包括一感光二极管感测区、一晶体管区元件、一自对准区块(self-aligned block)、及一保护层。感光二极管感测区及晶体管元件区形成于基底中,自对准区块形成于感光二极管感测区上。保护层形成于整个基底上,覆盖自对准区块。如此感光二极管感测区可于后续的后段工艺中受到保护而免于损坏,以减少暗电流产生。然而,栅极于保护层形成之前所形成,感光二极管感测区于使用等离子体蚀刻工艺形成栅极期间仍有受损的风险。U.S. Patent No. 6,906,364 discloses a structure of a CMOS image sensing element to reduce the generation of dark current, which includes a photodiode sensing area, a transistor area element, a self-aligned block (self-aligned block), and A protective layer. The photodiode sensing region and the transistor element region are formed in the substrate, and the self-alignment block is formed on the photodiode sensing region. The protective layer is formed on the entire substrate, covering the self-aligned area. In this way, the sensing area of the photodiode can be protected from damage in the subsequent back-end process, so as to reduce the generation of dark current. However, since the gate is formed before the passivation layer is formed, there is still a risk of damage to the sensing region of the photodiode during the formation of the gate using the plasma etching process.

因此,仍需要一种具有更少量暗电流的影像感测元件,及其制法。Therefore, there is still a need for an image sensing device with a lower amount of dark current, and a method for making the same.

发明内容 Contents of the invention

本发明的一个目的为提供一种影像感测元件,其具有改善的暗电流现象。An object of the present invention is to provide an image sensing device with improved dark current phenomenon.

本发明的另一目的为提供一种制造影像感测元件的方法,以制得具有改善的暗电流的影像感测元件。Another object of the present invention is to provide a method for manufacturing an image sensing device, so as to obtain an image sensing device with improved dark current.

依据本发明的影像感测元件包括一基底、一光感测区、一介电保护层、一栅极绝缘层、一栅极、及一掺杂区。光感测区是位于基底中。介电保护层是位于光感测区上,以作为光感测区的保护层。栅极绝缘层是位于基底上,邻接介电保护层。栅极是位于栅极绝缘层上,其一侧跨至介电保护层的一部分上。掺杂区是位于基底中。The image sensing device according to the present invention includes a substrate, a photo-sensing region, a dielectric protection layer, a gate insulating layer, a gate, and a doped region. The light sensing area is located in the base. The dielectric protection layer is located on the photo-sensing area to serve as a protection layer for the photo-sensing area. The gate insulation layer is located on the base and adjacent to the dielectric protection layer. The gate is located on the gate insulation layer, and one side of the gate crosses over a part of the dielectric protection layer. The doped region is located in the substrate.

依据本发明的制造影像感测元件的方法包括下列步骤。首先,提供一基底,其包括一光感测区于基底中。其次,形成一介电保护层于光感测区上。然后,形成一栅极绝缘层于基底上并邻接介电保护层。形成一栅极于栅极绝缘层上并且使栅极的一侧延伸至介电保护层的一部分上。最后,分别于栅极的另一侧的基底中形成一掺杂区及于光感测区形成一感光层。The method for manufacturing an image sensing device according to the present invention includes the following steps. Firstly, a substrate is provided, which includes a light sensing area in the substrate. Secondly, a dielectric protection layer is formed on the photo-sensing area. Then, a gate insulation layer is formed on the base and adjacent to the dielectric protection layer. A gate is formed on the gate insulating layer and one side of the gate is extended to a part of the dielectric protection layer. Finally, a doped region is formed in the substrate on the other side of the gate and a photosensitive layer is formed in the photosensitive region.

于本发明的另一方面,依据本发明的制造影像感测元件的方法包括下列步骤。首先,提供一基底,其包括一光感测区于基底中。接着,形成一介电保护层于光感测区上。于光感测区形成一感光层。然后,形成一栅极绝缘层于基底上并邻接介电保护层。形成一栅极于栅极绝缘层上并且使栅极的一侧延伸至介电保护层的一部分上。最后,于栅极的另一侧的基底中形成一掺杂区。In another aspect of the present invention, the method for manufacturing an image sensing device according to the present invention includes the following steps. Firstly, a substrate is provided, which includes a light sensing area in the substrate. Next, a dielectric protection layer is formed on the photo-sensing area. A photosensitive layer is formed in the photosensitive area. Then, a gate insulation layer is formed on the base and adjacent to the dielectric protection layer. A gate is formed on the gate insulating layer and one side of the gate is extended to a part of the dielectric protection layer. Finally, a doped region is formed in the substrate on the other side of the gate.

于本发明的仍另一方面,依据本发明的制造影像感测元件的方法包括下列步骤。首先,提供一基底,其包括一光感测区及一栅极区于基底中,其中栅极区被光感测区围绕。其次,形成一介电保护层于光感测区上。于栅极区的基底中形成一掺杂区。接着,形成一栅极绝缘层于栅极区的基底上并邻接介电保护层。形成一栅极于栅极绝缘层上并且使栅极的侧边延伸至介电保护层的一部分上。最后,于光感测区中形成一感光层。In yet another aspect of the present invention, the method for manufacturing an image sensor device according to the present invention includes the following steps. Firstly, a substrate is provided, which includes a photo-sensing region and a gate region in the substrate, wherein the gate region is surrounded by the photo-sensing region. Secondly, a dielectric protection layer is formed on the photo-sensing area. A doped region is formed in the base of the gate region. Next, a gate insulation layer is formed on the base of the gate region and adjacent to the dielectric protection layer. A gate is formed on the gate insulating layer and the side of the gate is extended to a part of the dielectric protection layer. Finally, a photosensitive layer is formed in the photosensitive area.

于本发明的又另一方面,依据本发明的制造影像感测元件的方法包括下列步骤。首先,提供一基底,其包括一光感测区及一栅极区于基底中,其中栅极区被光感测区围绕。其次,形成一介电保护层于光感测区上。分别于光感测区中形成一感光层及于栅极区的基底中形成一掺杂区。接着,形成一栅极绝缘层于栅极区的基底上并邻接介电保护层。最后,形成一栅极于栅极绝缘层上并且使栅极的侧边延伸至介电保护层的一部分上。In yet another aspect of the present invention, the method for manufacturing an image sensing device according to the present invention includes the following steps. Firstly, a substrate is provided, which includes a photo-sensing region and a gate region in the substrate, wherein the gate region is surrounded by the photo-sensing region. Secondly, a dielectric protection layer is formed on the photo-sensing area. A photosensitive layer is formed in the photosensitive region and a doped region is formed in the base of the gate region respectively. Next, a gate insulation layer is formed on the base of the gate region and adjacent to the dielectric protection layer. Finally, a gate is formed on the gate insulating layer and the side of the gate is extended to a part of the dielectric protection layer.

依据本发明的影像感测元件,先于光感测区上形成一介电保护层作为保护层,再于基底上形成栅极,尤其是所形成的栅极的一侧边跨至介电保护层的一部分上。因此,此介电保护层可保护光感测区的感光层,可减少感光层于以等离子体进行光致抗蚀剂去除、栅极蚀刻、及间隙壁蚀刻时所造成的损坏,而改善暗电流。此外,于本发明的另一具体实施例中,使栅极尽量不接触STI边界而位于光感测区包围的区域内,如此不会受到STI诱发的缺陷的影响,可降低漏电流(即,暗电流)。再者,栅极不接触STI边界时,则不会有STI窄宽度效应,就不会在栅极下方造成一遮障,而影响光感测区的电荷传出。因此,依据本发明的影像感测元件可具有良好的性能。According to the image sensing element of the present invention, a dielectric protection layer is first formed on the photo-sensing region as a protection layer, and then a gate is formed on the substrate, especially one side of the formed gate is across the dielectric protection layer. part of the layer. Therefore, this dielectric protection layer can protect the photosensitive layer of the photosensitive area, and can reduce the damage caused by the photoresist removal, gate etching, and spacer etching of the photosensitive layer by plasma, and improve the dark area. current. In addition, in another specific embodiment of the present invention, the gate is located in the area surrounded by the photo-sensing region as far as possible without touching the STI boundary, so that it will not be affected by the defects induced by the STI, and the leakage current can be reduced (that is, dark current). Furthermore, when the gate is not in contact with the STI boundary, there will be no STI narrow width effect, and a barrier will not be formed under the gate, which will affect the charge transfer of the photo-sensing region. Therefore, the image sensing device according to the present invention can have good performance.

附图说明 Description of drawings

图1显示依据本发明的影像感测元件的一具体实施例的顶视示意图。FIG. 1 shows a schematic top view of an embodiment of an image sensing device according to the present invention.

图2显示沿着图1所示的AA’线段的剖面示意图。Fig. 2 shows a schematic cross-sectional view along line AA' shown in Fig. 1 .

图3显示依据本发明的影像感测元件的另一具体实施例的顶视示意图。FIG. 3 shows a schematic top view of another embodiment of an image sensing device according to the present invention.

图4显示沿着图3所示的AA’线段的剖面示意图。Fig. 4 shows a schematic cross-sectional view along line AA' shown in Fig. 3 .

图5至8显示依据本发明的影像感测元件的制造方法的一具体实施例。5 to 8 show a specific embodiment of the manufacturing method of the image sensing device according to the present invention.

图9至13显示依据本发明的影像感测元件的制造方法的另一具体实施例。9 to 13 show another specific embodiment of the manufacturing method of the image sensing device according to the present invention.

图14至15显示依据本发明的影像感测元件的制造方法的又一具体实施例。14 to 15 show another specific embodiment of the manufacturing method of the image sensing device according to the present invention.

图16显示依据本发明的影像感测元件的制造方法的又另一具体实施例。FIG. 16 shows yet another specific embodiment of the manufacturing method of the image sensing device according to the present invention.

简单符号说明simple notation

20、50      基底        21        浅沟槽隔离结构20, 50 Substrate 21 Shallow trench isolation structure

22、52      光感测区    23、31、33光致抗蚀剂层22, 52 photosensitive area 23, 31, 33 photoresist layer

24、54      介电保护层  26、56    栅极绝缘层24, 54 Dielectric protective layer 26, 56 Gate insulating layer

27          离子注入    28、58    栅极27 Ion implantation 28, 58 Grid

29          离子注入    30、60    掺杂区29 ion implantation 30, 60 doping region

32、62      感光层      34、64    轻掺杂层32, 62 photosensitive layer 34, 64 lightly doped layer

30a、34a    轻掺杂区    35        轻离子注入30a, 34a Lightly doped region 35 Light ion implantation

36、66    重掺杂层    38、68    氧化硅层36, 66 heavily doped layer 38, 68 silicon oxide layer

40、70    氮化硅层    42        间隙壁40, 70 Silicon nitride layer 42 Spacer

具体实施方式 Detailed ways

请参阅图1及2,图2是图1中沿着AA’线段的剖面图。依据本发明的影像感测元件可为CMOS影像感测元件,包括一基底20、一光感测区22、一介电保护层24、一栅极绝缘层26、一栅极28、及一掺杂区30。此影像感测元件以浅沟槽隔离结构21与其它元件隔离。依据本发明的影像感测元件亦适用其它方式例如LOCOS的隔离。Please refer to Figures 1 and 2, Figure 2 is a cross-sectional view along line AA' in Figure 1. The image sensing element according to the present invention can be a CMOS image sensing element, including a substrate 20, a photo-sensing region 22, a dielectric protection layer 24, a gate insulating layer 26, a gate 28, and a doped Miscellaneous area 30. The image sensing device is isolated from other devices by the shallow trench isolation structure 21 . The image sensing device according to the present invention is also suitable for isolation in other ways such as LOCOS.

基底20可为p型或n型半导体基底。光感测区22是位于基底20中。光感测区22可包括一感光层32,为感光材料,例如,当基底20为p型基底时,感光层32可包括一n型轻掺杂层34及一p型重掺杂层36。PIN(p型-本质-n型)感光二极管、APD感光二极管、或其它一般的感光二极管均可作为感光层,但不限于此。The substrate 20 can be a p-type or n-type semiconductor substrate. The light sensing region 22 is located in the substrate 20 . The photosensitive region 22 may include a photosensitive layer 32 , which is a photosensitive material. For example, when the substrate 20 is a p-type substrate, the photosensitive layer 32 may include an n-type lightly doped layer 34 and a p-type heavily doped layer 36 . PIN (p-type-intrinsic-n-type) photodiodes, APD photodiodes, or other general photodiodes can be used as the photosensitive layer, but not limited thereto.

介电保护层24是位于光感测区22,例如位于感光层32之上,以作为光感测区22的保护层。介电保护层可为单层或多层介电层。单层介电层可为例如氧化硅层等介电材料层。多层介电层可为例如一层氧化硅层38及一层氮化硅层40位于该氧化硅层上,或是交替堆栈的多层氧化硅层及多层氮化硅层。介电保护层是作为保护光感测区以免于后续工艺例如等离子体工艺中受到损坏,介电保护层的厚度可为不影响透光而可达保护功能的厚度,优选总厚度不大于约

Figure C20061007736200091
例如使用氧化硅层时,其厚度可为50至而氮化硅层可为50至当介电保护层配合适当厚度时,例如300至
Figure C20061007736200094
亦可具有抗反射层的功用。The dielectric protection layer 24 is located on the photo-sensing region 22 , for example, on the photo-sensing layer 32 , so as to serve as a protection layer for the photo-sensing region 22 . The dielectric protection layer can be a single layer or multiple dielectric layers. The single dielectric layer can be a layer of dielectric material such as a silicon oxide layer. The multilayer dielectric layer can be, for example, a silicon oxide layer 38 and a silicon nitride layer 40 on the silicon oxide layer, or alternately stacked silicon oxide layers and silicon nitride layers. The dielectric protection layer is used to protect the photosensitive region from being damaged in subsequent processes such as plasma processes. The thickness of the dielectric protection layer can be a thickness that does not affect light transmission and can reach a protective function. The preferred total thickness is not more than about
Figure C20061007736200091
For example, when using a silicon oxide layer, its thickness can be 50 to While the silicon nitride layer can be 50 to When the dielectric protective layer is matched with an appropriate thickness, such as 300 to
Figure C20061007736200094
It can also function as an anti-reflection layer.

栅极绝缘层26是位于基底20上,邻接介电保护层24。栅极绝缘层可为栅极氧化层,厚度优选小于

Figure C20061007736200095
栅极28是位于栅极绝缘层26上,其一侧跨至介电保护层24的一部分上。栅极28包括导电性材料,例如多晶硅。栅极28的侧壁上可进一步具有一间隙壁42。间隙壁可为氧化硅层,或多层介电层。掺杂区30是位于栅极28的另一例的基底20中,以于晶体管功能中作为漏极或源极。掺杂区可包括一部分轻掺杂区及一部分重掺杂区,其电性与感光二极管的轻掺杂层34及重掺杂层36的电性相同。The gate insulating layer 26 is located on the substrate 20 adjacent to the dielectric protection layer 24 . The gate insulating layer can be a gate oxide layer, and the thickness is preferably less than
Figure C20061007736200095
The gate 28 is located on the gate insulating layer 26 , and one side thereof crosses over a part of the dielectric protection layer 24 . Gate 28 includes a conductive material, such as polysilicon. A spacer 42 may be further provided on the sidewall of the gate 28 . The spacers can be silicon oxide layers, or multiple dielectric layers. The doped region 30 is located in the substrate 20 which is another example of the gate 28 to function as a drain or a source in the transistor function. The doped region may include a part of the lightly doped region and a part of the heavily doped region, and its electrical property is the same as that of the lightly doped layer 34 and the heavily doped layer 36 of the photodiode.

依据本发明的影像感测元件,具有一主要特征在于光感测区的感光层具有一介电保护层作为保护层,而栅极具有一侧边跨至介电保护层的一部分上,因此,光感测区、栅极、及掺杂区相互间的位置并无特别限制,只要是光感测区及掺杂区不与栅极直接接触到即可。因此,掺杂区可位于栅极的另一侧的基底中,或有一部分位于栅极下方的基底中,形状并无特别限制。According to the image sensing device of the present invention, a main feature is that the photosensitive layer of the photosensitive region has a dielectric protection layer as the protection layer, and the gate has a side that spans a part of the dielectric protection layer, therefore, The positions of the photo-sensing region, the gate, and the doped region are not particularly limited, as long as the photo-sensing region and the doped region are not in direct contact with the gate. Therefore, the doped region can be located in the substrate on the other side of the gate, or partly located in the substrate below the gate, and the shape is not particularly limited.

或者,栅极所在的区域可被光感测区围绕,如图3显示依据本发明的影像感测元件的另一具体实施例,及图4显示于图3中沿着BB’线段的剖面图。其中,栅极58是位于被光感测区52包围的区域的基底上并以其侧边跨于介电保护层54的一部分上,及掺杂区60部分位于栅极58下方的基底中。介电保护层54包括氧化硅层68及氧化氮层70位于感光层62上,以作为感光层62的保护层。感光层62可包括轻掺杂层64及重掺杂层66。栅极绝缘层56位于基底50上,邻接介电保护层54。栅极58位于栅极绝缘层56上,其侧边跨至介电保护层54的一部分上。掺杂区60是位于基底50中,于栅极58的下方。掺杂区60可部分位于栅极58下方的基底50中,或可位于栅极58的侧边基底50中而不位于栅极下方。使栅极位于被光感测区包围的区域的基底上的如此配置的优点是,使得栅极不会碰触浅沟槽结构或LOCOS边界,或是仅少许部分碰触,所以不会受到STI诱发的缺陷的影响,可降低暗电流。再者,栅极不接触STI边界时,则不会有STI窄宽度效应,而不会在栅极下方造成一遮障影响光感测区的电荷传出。Alternatively, the region where the gate is located can be surrounded by the photo-sensing region, as shown in FIG. 3 another specific embodiment of the image sensing element according to the present invention, and FIG. 4 shows a cross-sectional view along line BB' in FIG. 3 . Wherein, the gate 58 is located on the substrate of the area surrounded by the photo-sensing region 52 and spans a part of the dielectric protection layer 54 with its side, and the doped region 60 is partially located in the substrate below the gate 58 . The dielectric protection layer 54 includes a silicon oxide layer 68 and a nitrogen oxide layer 70 on the photosensitive layer 62 to serve as a protective layer for the photosensitive layer 62 . The photosensitive layer 62 may include a lightly doped layer 64 and a heavily doped layer 66 . A gate insulating layer 56 is located on the substrate 50 adjacent to the dielectric protection layer 54 . The gate 58 is located on the gate insulating layer 56 , and its side crosses over a portion of the dielectric protection layer 54 . The doped region 60 is located in the substrate 50 below the gate 58 . The doped region 60 may be located partially in the substrate 50 below the gate 58, or may be located in the substrate 50 on the side of the gate 58 but not below the gate. The advantage of having the gate located on the substrate in the area surrounded by the photo-sensing region is that the gate does not touch the shallow trench structure or the LOCOS boundary, or touches only a small part, so it is not affected by STI. The effect of induced defects can reduce the dark current. Furthermore, when the gate is not in contact with the boundary of the STI, there will be no narrow width effect of the STI, and a barrier will not be formed under the gate to affect the charge transmission of the photo-sensing region.

图5至8显示依据本发明的影像感测元件的制造方法的一具体实施例。请参阅图5,首先提供一基底20,其中已制备完成浅沟槽隔离结构21,并且具有一光感测区(未示出)。可通过热氧化法于基底表面形成氧化硅层,及通过等离子体增强化学气相沉积法使用硅烷与氨气作为处理气体,于氧化硅层上形成氮化硅层,以作为介电材料层。若需要,可重复此步骤若干次,以制得多层介电材料层。然后,以光刻工艺形成具有对应图案的光致抗蚀剂层23,遮住对应于光感测区的介电保护层预定区,以进行蚀刻去除未遮住的介电材料层部分。氮化硅层的蚀刻,可利用干蚀刻方法进行,例如等离子体蚀刻。氧化硅层的蚀刻,则可利用干蚀刻或湿蚀刻。如此,界定出包括氧化硅层38与氮化硅层40的介电保护层24覆盖于光感测区之上。然后,将光致抗蚀剂层移除。5 to 8 show a specific embodiment of the manufacturing method of the image sensing device according to the present invention. Referring to FIG. 5 , firstly, a substrate 20 is provided, in which the shallow trench isolation structure 21 has been fabricated and has a photo-sensing region (not shown). A silicon oxide layer can be formed on the surface of the substrate by thermal oxidation, and a silicon nitride layer can be formed on the silicon oxide layer as a dielectric material layer by using silane and ammonia as processing gases by plasma enhanced chemical vapor deposition. This step can be repeated several times, if desired, to produce multiple layers of dielectric material. Then, a photoresist layer 23 with a corresponding pattern is formed by a photolithography process to cover a predetermined area of the dielectric protection layer corresponding to the photo-sensing area, so as to perform etching to remove the part of the dielectric material layer that is not covered. The silicon nitride layer can be etched by dry etching, such as plasma etching. The silicon oxide layer can be etched by dry etching or wet etching. In this way, the dielectric protection layer 24 including the silicon oxide layer 38 and the silicon nitride layer 40 is defined to cover the photo-sensing region. Then, the photoresist layer is removed.

请参阅图6,进行一栅极氧化层工艺,例如热氧化工艺,形成一氧化层于基底20之上,为栅极绝缘层26,邻接介电保护层24。于形成栅极绝缘层之前,亦可视需要而先于基底20中形成阱(未示出)。Referring to FIG. 6 , a gate oxide layer process, such as a thermal oxidation process, is performed to form an oxide layer on the substrate 20 as the gate insulating layer 26 adjacent to the dielectric protection layer 24 . Before forming the gate insulating layer, a well (not shown) may also be formed in the substrate 20 if necessary.

请参阅图7及8,通过例如化学气相沉积方法形成导电层,例如多晶硅层、多晶硅化金属(polycide)层,再进行光刻与蚀刻工艺,形成栅极28于栅极绝缘层26之上,栅极28的一侧制作于介电保护层24的一部分上。由于所形成的栅极边缘是跨在作为光感测区保护层的介电保护层上,因此,于将导电层蚀刻(例如等离子体蚀刻)以形成栅极时,或是于蚀刻去除栅极上方的光致抗蚀剂时,光感测层不会受到蚀刻的损坏。然后,进行形成掺杂区与感光层的工艺,例如通过离子注入27,以栅极28为掩模,对基底20进行离子的注入,于栅极28的一侧的基底中形成一轻掺杂区30a。于光感测区的基底中,亦进行离子注入,形成一轻掺杂区34a。轻掺杂的电性为n型或p型依基底20的掺杂物为p型或n型而定。n型掺杂物可为例如磷或砷。p型掺杂物可为例如硼。Referring to FIGS. 7 and 8, a conductive layer, such as a polysilicon layer and a polycide layer, is formed by, for example, a chemical vapor deposition method, and then photolithography and etching processes are performed to form a gate 28 on the gate insulating layer 26. One side of the gate 28 is formed on a portion of the dielectric capping layer 24 . Since the edge of the formed gate straddles the dielectric protective layer as the protective layer of the photo-sensing area, when the conductive layer is etched (such as plasma etching) to form the gate, or when the gate is removed by etching When the photoresist is placed above, the light sensing layer will not be damaged by etching. Then, the process of forming the doped region and the photosensitive layer is carried out, for example, by ion implantation 27, using the grid 28 as a mask, the substrate 20 is implanted with ions, and a lightly doped layer is formed in the substrate on one side of the grid 28. Zone 30a. In the substrate of the photo-sensing region, ion implantation is also performed to form a lightly doped region 34a. The electrical property of the light doping is n-type or p-type depending on whether the dopant of the substrate 20 is p-type or n-type. The n-type dopant can be, for example, phosphorous or arsenic. The p-type dopant can be, for example, boron.

可进一步于栅极28的侧壁形成间隙壁42,例如通过化学气相沉积方法形成氧化硅层,于基底20上,再进行各向异性蚀刻,可形成间隙壁。之后,可进一步进行更重的离子注入,于间隙壁42外侧的基底20中形成重掺杂区(未示出),及于光感测区22形成一重掺杂区。如此,制得如图1及2所示的影像感测元件。A spacer 42 can be further formed on the sidewall of the gate 28 , for example, a silicon oxide layer is formed by chemical vapor deposition, and anisotropic etching is performed on the substrate 20 to form a spacer. Afterwards, heavier ion implantation can be further performed to form a heavily doped region (not shown) in the substrate 20 outside the spacer 42 , and to form a heavily doped region in the photo-sensing region 22 . In this way, the image sensing device shown in FIGS. 1 and 2 is produced.

请参阅图9至13,于依据本发明的另一具体实施例中,感光层可于形成介电保护层后即制备。图9显示于形成介电保护层24的步骤后,进行离子注入29,可使用光致抗蚀剂层31作为掩模,以于光感测区形成一轻掺杂层34,及进一步形成一重掺杂层36,成为感光层32。图10显示去除光致抗蚀剂层后,形成栅极绝缘层26邻接介电保护层24。图11显示于栅极绝缘层26之上以如上述的方法形成一栅极28,其一侧跨至介电保护层24的一部分上,因此于工艺中,介电保护层24下方的感光层32可受到保护。Referring to FIGS. 9 to 13 , in another embodiment according to the present invention, the photosensitive layer can be prepared after forming the dielectric protection layer. Figure 9 shows that after the step of forming the dielectric protection layer 24, ion implantation 29 can be performed, and the photoresist layer 31 can be used as a mask to form a lightly doped layer 34 in the photo-sensing area, and further form a heavily doped layer. The doped layer 36 becomes the photosensitive layer 32 . FIG. 10 shows that after removing the photoresist layer, a gate insulating layer 26 is formed adjacent to the dielectric protection layer 24 . FIG. 11 shows that a gate 28 is formed on the gate insulating layer 26 in the above-mentioned method, and one side of it spans over a part of the dielectric protection layer 24. Therefore, in the process, the photosensitive layer below the dielectric protection layer 24 32 can be protected.

图12显示掺杂区的制造。将光感测区以图案化的光致抗蚀剂层33遮蔽,进行轻离子注入35,形成一轻掺杂区30a。请参阅图13,再如上述形成间隙壁42,进行重离子注入,形成一重掺杂区,如此形成掺杂区30。然后,去除光致抗蚀剂层33,制得如图1及2所示的影像感测元件。Figure 12 shows the fabrication of doped regions. The photo-sensing region is covered with a patterned photoresist layer 33, and light ion implantation 35 is performed to form a lightly doped region 30a. Referring to FIG. 13 , the spacers 42 are formed as described above, and heavy ion implantation is performed to form a heavily doped region, thus forming the doped region 30 . Then, the photoresist layer 33 is removed to manufacture the image sensing device as shown in FIGS. 1 and 2 .

于依据本发明的影像感测元件配置如图3及4所示的情形时,因为掺杂区60部分位于栅极58的下方,因此需于形成栅极58之前形成掺杂区60,如图14至15所示。图14显示介电保护层54,其包括氧化硅层68及氮化硅层70,已形成于光感测区上。可使用图案化光致抗蚀剂层作为掩模,进行离子注入,以形成掺杂区60。此掺杂区60的宽度W及形成的光感测区52图形将一起决定栅极58的宽度。接着,如图15所示,于基底50及掺杂区60上形成栅极绝缘层56。接着,于栅极绝缘层56上形成栅极58,其侧边跨至介电保护层54的部分上。最后,进行离子注入工艺,于光感测区52先后进行轻离子注入及重离子注入,形成轻掺杂层64及重掺杂层66,成为感光层62,制得如图3及4所示的影像感测元件。When the image sensing element according to the present invention is configured as shown in FIGS. 3 and 4 , because the doped region 60 is partly located below the gate 58, it is necessary to form the doped region 60 before forming the gate 58, as shown in FIG. 14 to 15 are shown. FIG. 14 shows a dielectric protection layer 54, which includes a silicon oxide layer 68 and a silicon nitride layer 70, formed over the photo-sensing region. Ion implantation may be performed using the patterned photoresist layer as a mask to form the doped region 60 . The width of the doped region 60 and the pattern of the photo-sensing region 52 will determine the width of the gate 58 together. Next, as shown in FIG. 15 , a gate insulating layer 56 is formed on the substrate 50 and the doped region 60 . Next, a gate 58 is formed on the gate insulating layer 56 , and its side crosses over a portion of the dielectric protection layer 54 . Finally, the ion implantation process is performed, and light ion implantation and heavy ion implantation are performed successively in the photosensitive region 52 to form a lightly doped layer 64 and a heavily doped layer 66, which become the photosensitive layer 62, as shown in Figures 3 and 4. image sensing element.

或者,于另一具体实施例中,可于形成栅极58之前形成掺杂区60及感光层62。如图16所示,介电保护层54,其包括氧化硅层68及氮化硅层70,已形成于光感测区上。通过离子注入工艺形成掺杂区60(可包括轻掺杂区及重掺杂区)与感光层62(可包括轻掺杂层64及重掺杂层66)。接着,于基底50及掺杂区60上形成栅极绝缘层56,再形成栅极58,其侧边跨至介电保护层54的部分上。亦可制得如图3及4所示的影像感测元件。Alternatively, in another embodiment, the doped region 60 and the photosensitive layer 62 may be formed before forming the gate 58 . As shown in FIG. 16, a dielectric protection layer 54, which includes a silicon oxide layer 68 and a silicon nitride layer 70, has been formed over the photo-sensing region. The doped region 60 (which may include a lightly doped region and a heavily doped region) and the photosensitive layer 62 (which may include a lightly doped layer 64 and a heavily doped layer 66 ) are formed by ion implantation. Next, a gate insulating layer 56 is formed on the substrate 50 and the doped region 60 , and then a gate 58 is formed, the side of which crosses over a portion of the dielectric protection layer 54 . Image sensing devices as shown in FIGS. 3 and 4 can also be fabricated.

以上所述仅为本发明的优选实施例,凡依本发明申请专利范围所做的均等变化与修饰,皆应属本发明的涵盖范围。The above descriptions are only preferred embodiments of the present invention, and all equivalent changes and modifications made according to the scope of the patent application of the present invention shall fall within the scope of the present invention.

Claims (26)

1. Image Sensor comprises:
Substrate;
Optical sensing area is arranged in this substrate;
Dielectric protection layer is positioned on this optical sensing area, with the protective layer as this optical sensing area;
Gate insulator is positioned in this substrate, in abutting connection with this dielectric protection layer;
Grid is positioned on this gate insulator, and the one side is striden to the part of this dielectric protection layer; And
Doped region is arranged in this substrate.
2. Image Sensor as claimed in claim 1, wherein this optical sensing area comprises photosensitive layer, and this dielectric protection layer is to be positioned on this photosensitive layer, with as protective layer.
3. Image Sensor as claimed in claim 1, wherein this dielectric protection layer comprises multilayer dielectric layer.
4. Image Sensor as claimed in claim 3, wherein this multilayer dielectric layer comprises that one deck silicon oxide layer and one deck silicon nitride layer are positioned on this silicon oxide layer.
5. Image Sensor as claimed in claim 3, wherein this multilayer dielectric layer comprises alternately the multilayer silicon oxide layer and the nitride multilayer silicon layer of storehouse.
6. Image Sensor as claimed in claim 1 comprises that also clearance wall is positioned on the sidewall of this grid.
7. Image Sensor as claimed in claim 1, wherein this doped region is this substrate that is arranged in the opposite side of this grid.
8. Image Sensor as claimed in claim 1, wherein this grid be positioned at by in the substrate of this optical sensing area area surrounded and with its side on the part of this dielectric protection layer, and the part of this doped region is arranged in this substrate of this grid below.
9. Image Sensor as claimed in claim 1, wherein this grid be positioned at by in the substrate of this optical sensing area area surrounded and with its side on the part of this dielectric protection layer, and this doped region is this substrate that is arranged in the opposite side of this grid.
10. a method of making Image Sensor comprises the following steps:
Substrate is provided, and it comprises that optical sensing area is in this substrate;
Form dielectric protection layer on this optical sensing area;
Form gate insulator in this substrate and in abutting connection with this dielectric protection layer;
Form grid on this gate insulator and a side of this grid is extended on the part of this dielectric protection layer; And
Respectively at forming doped region in this substrate of the opposite side of this grid and forming photosensitive layer in this optical sensing area.
11. method as claimed in claim 10 wherein should form the step of dielectric protection layer on this optical sensing area, comprising:
Form dielectric materials layer in this substrate and cover this optical sensing area, and
Partly remove this dielectric materials layer by photoetching process and etch process.
12. method as claimed in claim 10 wherein should form dielectric protection layer and form multilayer dielectric layer on this optical sensing area in the step on this optical sensing area.
13. method as claimed in claim 12, wherein this multilayer dielectric layer comprises that one deck silicon oxide layer and one deck silicon nitride layer are on this silicon oxide layer.
14. method as claimed in claim 11, the step that wherein should form a dielectric materials layer is for forming one deck silicon oxide layer and forming one deck silicon nitride layer.
15. method as claimed in claim 14 wherein is somebody's turn to do the step that partly remove this dielectric materials layer by photoetching process and etch process, comprising:
Form the photoresist pattern, wherein the photoresist layer of this photoresist pattern covers this optical sensing area;
Carry out dry ecthing to remove this silicon nitride layer;
Carry out wet etching to remove this silicon oxide layer; And
This photoresist pattern is removed.
16. method as claimed in claim 11, wherein the step of this formation dielectric materials layer is the step that hockets and repeatedly form one deck silicon oxide layer and form one deck silicon nitride layer.
17. method as claimed in claim 10 in forming gate insulator in this substrate and before the step of this dielectric protection layer, further forms trap in this substrate.
18. method as claimed in claim 10, wherein this forms doped region and in the step of this optical sensing area formation photosensitive layer, comprising in this substrate of the opposite side of this grid:
In this substrate, form a light doping section with the light ion injection technology, and form lightly-doped layer in this optical sensing area;
Sidewall in this grid forms clearance wall; And
With heavy ion injection technology this light doping section top, form heavily doped region, and form a heavily doped layer in this lightly-doped layer top in a side of this clearance wall.
19. a method of making Image Sensor comprises the following steps:
Substrate is provided, and it comprises that optical sensing area is in this substrate;
Form a dielectric protection layer on this optical sensing area;
Form photosensitive layer in this optical sensing area;
Form gate insulator in this substrate and in abutting connection with this dielectric protection layer;
Form grid on this gate insulator and a side of this grid is extended on the part of this dielectric protection layer; And
In the substrate of the opposite side of this grid, form doped region.
20. method as claimed in claim 19 wherein should form the step of dielectric protection layer on this optical sensing area, comprising:
Form dielectric materials layer in this substrate and cover this optical sensing area, and
Partly remove this dielectric materials layer by photoetching process and etch process.
21. method as claimed in claim 20, the step that wherein should form dielectric materials layer is for forming one deck silicon oxide layer and forming one deck silicon nitride layer.
22. method as claimed in claim 21 wherein is somebody's turn to do the step that partly remove this dielectric materials layer by photoetching process and etch process, comprising:
Form the photoresist pattern, wherein the photoresist layer of this photoresist pattern covers this optical sensing area;
Carry out dry ecthing to remove this silicon nitride layer;
Carry out wet etching to remove this silicon oxide layer; And
This photoresist pattern is removed.
23. method as claimed in claim 19, wherein this forms the step of doped region in this substrate of the opposite side of this grid, comprising:
In this substrate, form light doping section with the light ion injection technology;
Sidewall in this grid forms clearance wall; And
With heavy ion injection technology this light doping section top, form heavily doped region in a side of this clearance wall.
24. method as claimed in claim 19 wherein should comprise in the step of this optical sensing area formation photosensitive layer:
Form lightly-doped layer with the light ion injection technology in this optical sensing area; And
Form heavily doped layer with the heavy ion injection technology in this lightly-doped layer top.
25. a method of making Image Sensor comprises the following steps:
Substrate is provided, and it comprises optical sensing area and gate regions in this substrate, and wherein this gate regions is surrounded by this optical sensing area;
Form dielectric protection layer on this optical sensing area;
In the substrate of this gate regions, form doped region;
Form gate insulator in the substrate of this gate regions and in abutting connection with this dielectric protection layer;
Form grid on this gate insulator and the side of this grid is extended on the part of this dielectric protection layer; And
In this optical sensing area, form photosensitive layer.
26. a method of making Image Sensor comprises the following steps:
Substrate is provided, and it comprises optical sensing area and gate regions in this substrate, and wherein this gate regions is surrounded by this optical sensing area;
Form dielectric protection layer on this optical sensing area;
Respectively at forming photosensitive layer in this optical sensing area and in the substrate of this gate regions, forming doped region;
Form gate insulator in the substrate of this gate regions and in abutting connection with this dielectric protection layer; And
Form grid on this gate insulator and the side of this grid is extended on the part of this dielectric protection layer.
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