CN100467635C - A kind of preparation method of aluminum-titanium-carbon master alloy - Google Patents
A kind of preparation method of aluminum-titanium-carbon master alloy Download PDFInfo
- Publication number
- CN100467635C CN100467635C CNB2007100163066A CN200710016306A CN100467635C CN 100467635 C CN100467635 C CN 100467635C CN B2007100163066 A CNB2007100163066 A CN B2007100163066A CN 200710016306 A CN200710016306 A CN 200710016306A CN 100467635 C CN100467635 C CN 100467635C
- Authority
- CN
- China
- Prior art keywords
- titanium
- aluminum
- master alloy
- carbon
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
本发明属金属材料领域，涉及一种用于细化铝及铝合金晶粒的铝-钛-碳中间合金的制备方法。该制备方法以铝-碳中间合金和铝-钛中间合金作为元素碳及钛的来源。制备方法是首先在感应炉中将纯铝及铝-钛中间合金熔化并升温至900-1300℃，然后加入铝-碳二元中间合金，保温并机械搅拌2-30分钟后加入预留的铝-钛中间合金冷料降温，直接浇注成锭或制备成线材。利用该方法制备铝-钛-碳中间合金，工艺简单，成本低，制备的铝-钛-碳中间合金细化效果具有高效性和长效性。The invention belongs to the field of metal materials, and relates to a preparation method of an aluminum-titanium-carbon intermediate alloy used for refining aluminum and aluminum alloy grains. The preparation method uses an aluminum-carbon master alloy and an aluminum-titanium master alloy as sources of elemental carbon and titanium. The preparation method is to melt pure aluminum and aluminum-titanium master alloy in an induction furnace and raise the temperature to 900-1300°C, then add aluminum-carbon binary master alloy, keep warm and mechanically stir for 2-30 minutes, then add the reserved aluminum - The titanium master alloy cold material is cooled, and directly cast into ingots or prepared into wire rods. The method for preparing an aluminum-titanium-carbon master alloy has simple process and low cost, and the refinement effect of the prepared aluminum-titanium-carbon master alloy has high efficiency and long-term effect.
Description
Technical field
The invention belongs to metal material field, particularly a kind of preparation method who is used for the aluminium-titanium-carbon master alloy of refinement aluminium and aluminium alloy crystal grain.
Background technology
The aluminium-titanium-carbon master alloy is the ternary master alloy fining agent that proposes prior to aluminium-titanium-boron master alloy, is the important topic that Chinese scholars is extremely paid close attention to its research always.But since the wettability extreme difference between carbon and the aluminium, the alloying difficulty, and the preparation of aluminium-titanium-carbon for a long time all is a technical barrier.Last century the forties, Britain scholar Cibula just attempts ining all sorts of ways adding carbon in aluminium-titanium solution, wishes to obtain to contain a large amount of TiC particulate aluminium-titanium-carbon master alloys, but does not all have successfully.Up to 1985, Banerji and Reif have obtained the breakthrough of aluminium-titanium-carbon master alloy preparation by the violent stirring method, but at high temperature long-time violent stirring molten aluminium can make, and alloy is seriously air-breathing, oxidization burning loss, a large amount of inclusiones of generation, and energy consumption increases, and has increased production cost greatly; Because the carbon reaction is incomplete, often contain free carbon in the master alloy of preparation in addition, so strict condition and requirement have limited its application in actual production.The patent No. is the production method that 98119378 Chinese patent has been reported a kind of aluminium-titanium-carbon master alloy: aluminum-titanium alloy is melted to 1000-1200 ℃, adds activator, add Graphite Powder 99 again, pour into a tablet form the aluminium-titanium-carbon master alloy then.The characteristics of this technology are to prepare aluminum-titanium alloy earlier, and then with it remelting, and need to add activator, its technology is more complicated also, and the cost height.Document (Journal of Alloys and Compounds, 2005,396:143-150) reported and used K
2TiF
6With the method that Graphite Powder 99 is produced the aluminium-titanium-carbon master alloy, the shortcoming of this method is to emit a large amount of KF and AlF in the production process
3Deng toxic gas, contaminate environment, and often contain salt type impurity etc. in the master alloy, thus polluted aluminium alloy.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, provide that a kind of cost is low, technology is simple and the preparation method of the aluminium-titanium-carbon master alloy of free of contamination suitable suitability for industrialized production.
The present invention realizes in the following manner:
A kind of preparation method of aluminium-titanium-carbon master alloy is characterized in that may further comprise the steps:
(1) at first be ready to prepare the required raw material of aluminium-titanium-carbon master alloy by following mass percent:
The aluminium of the aluminium of 5.00%-40.00%-carbon binary master alloy, 10.00%-60.00%-titanium binary master alloy, surplus is fine aluminium; The content (wt%) of carbon is 0.50-30.00 in wherein used aluminium-carbon master alloy, and the content (wt%) of titanium is 2.00-40.00 in used aluminium-titanium master alloy;
(2) aluminium-titanium master alloy of reserving 5%-30% places remaining aluminium-titanium master alloy the induction furnace fusing and is warming up to 900-1300 ℃ together with fine aluminium as cold burden;
(3) ready aluminium-carbon master alloy is joined in the melt, insulation and mechanical stirring 2-30 minute, aluminium-titanium master alloy of add reserving then makes melt be chilled to 700-900 ℃ soon, directly casting ingot-forming or be prepared into wire rod.
With consisting of of the aluminium-titanium-carbon master alloy of this method preparation:
Component content (wt%)
Aluminium (Al) 65.00-99.00
Titanium (Ti) 0.20-30.00
Carbon (C) 0.01-6.00
The present invention is that the source of carbon prepares the aluminium-titanium-carbon master alloy with aluminium-carbon binary master alloy, because carbon wherein and compound thereof react with the dissolved titanium than simple substance carbon is easier, thereby preparation process can carry out under lower temperature, and the specific absorption height of carbon, reacts completely; Need not specific installation in the preparation process, preparation technology is simple, production efficiency is high, cost is low; The aluminium-titanium-carbon master alloy thinning effect of preparation has high efficiency and long-lasting, is fit to scale operation and application.
Embodiment
Provide three most preferred embodiments of the present invention below:
Embodiment 1
(1) at first is ready to raw material: 8.00% aluminium-carbon master alloy and aluminium-titanium master alloy of 50.00% by following mass percent, surplus is fine aluminium, the content (wt%) of carbon is 5.00 in wherein used aluminium-carbon master alloy, and the content (wt%) of titanium is 10.00 in used aluminium-titanium master alloy;
(2) reserve aluminium-titanium master alloy of 15% as cold burden, in induction furnace with remaining aluminium-titanium master alloy together with the fine aluminium fusing and be warming up to 1050 ℃;
(3) ready aluminium-carbon master alloy is joined in the melt, insulation and mechanical stirring add aluminium-titanium master alloy of reserving after 15 minutes makes melt be chilled to 850 ℃ soon, direct casting ingot-forming or be prepared into wire rod.
Consisting of of made aluminium-titanium-carbon master alloy:
Component content (wt%)
Aluminium (Al) 94.60
Titanium (Ti) 5.00
Carbon (C) 0.40
Embodiment 2
(1) at first is ready to raw material: 25.00% aluminium-carbon master alloy and aluminium-titanium master alloy of 50.00% by following mass percent, surplus is fine aluminium, the content (wt%) of carbon is 20.00 in wherein used aluminium-carbon master alloy, and the content (wt%) of titanium is 30.00 in used aluminium-titanium master alloy;
(2) reserve aluminium-titanium master alloy of 10% as cold burden, in induction furnace with remaining aluminium-titanium master alloy and fine aluminium fusing and be warming up to 1300 ℃;
(3) ready aluminium-carbon master alloy is joined in the melt, insulation and mechanical stirring add aluminium-titanium master alloy of reserving after 20 minutes makes melt be chilled to 900 ℃ soon, direct casting ingot-forming or be prepared into wire rod.
Consisting of of made aluminium-titanium-carbon master alloy:
Component content (wt%)
Aluminium (Al) 80.00
Titanium (Ti) 15.00
Carbon (C) 5.00
Embodiment 3
(1) at first is ready to raw material: 20.00% aluminium-carbon master alloy and aluminium-titanium master alloy of 80.00% by following mass percent, the content (wt%) of carbon is 10.00 in wherein used aluminium-carbon master alloy, and the content (wt%) of titanium is 10.00 in used aluminium-titanium master alloy;
(2) reserve aluminium-titanium master alloy of 10% as cold burden, in induction furnace with remaining aluminium-titanium master alloy fusing and be warming up to 1150 ℃;
(3) ready aluminium-carbon master alloy is joined in the melt, insulation and mechanical stirring add aluminium-titanium master alloy of reserving after 20 minutes makes melt be cooled to 900 ℃, direct casting ingot-forming or be prepared into wire rod.
Consisting of of made aluminium-titanium-carbon master alloy:
Component content (wt%)
Aluminium (Al) 90.00
Titanium (Ti) 8.00
Carbon (C) 2.00
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100163066A CN100467635C (en) | 2007-07-20 | 2007-07-20 | A kind of preparation method of aluminum-titanium-carbon master alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100163066A CN100467635C (en) | 2007-07-20 | 2007-07-20 | A kind of preparation method of aluminum-titanium-carbon master alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101117670A CN101117670A (en) | 2008-02-06 |
| CN100467635C true CN100467635C (en) | 2009-03-11 |
Family
ID=39053928
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100163066A Expired - Fee Related CN100467635C (en) | 2007-07-20 | 2007-07-20 | A kind of preparation method of aluminum-titanium-carbon master alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100467635C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108034845A (en) * | 2018-01-19 | 2018-05-15 | 广东省材料与加工研究所 | A kind of aluminium-cobalt-boron intermediate alloy and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108118170A (en) * | 2018-01-19 | 2018-06-05 | 广东省材料与加工研究所 | A kind of aluminium-chromium-boron intermediate alloy and preparation method thereof |
| CN108193063A (en) * | 2018-01-19 | 2018-06-22 | 广东省材料与加工研究所 | A kind of aluminium-manganese-boron intermediate alloy and preparation method thereof |
-
2007
- 2007-07-20 CN CNB2007100163066A patent/CN100467635C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108034845A (en) * | 2018-01-19 | 2018-05-15 | 广东省材料与加工研究所 | A kind of aluminium-cobalt-boron intermediate alloy and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101117670A (en) | 2008-02-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101608270A (en) | A high-efficiency and low-cost aluminum and aluminum alloy refiner and preparation method thereof | |
| CN109385542B (en) | Preparation method of aluminum-niobium-boron alloy rod for grain refinement | |
| CN102703738A (en) | Preparation method of Al-Ti-B-C quaternary grain refiner | |
| CN103409628A (en) | Method for preparing titanium-aluminum alloy | |
| CN110157935A (en) | Al-V-B refining agent for casting aluminum-silicon alloy, its preparation method and application | |
| CN109234808A (en) | It is a kind of to prepare TiSi simultaneously2With the method for titanium silicon | |
| CN106381408B (en) | A kind of method that aluminothermic reduction prepares scandium bearing master alloy in elpasolite fused salt | |
| CN102041420B (en) | Magnesium-aluminum-titanium-carbon intermediate alloy and preparation method thereof | |
| CN100410400C (en) | Method for preparing aluminum-scandium alloy by aluminothermic reduction | |
| CN100467635C (en) | A kind of preparation method of aluminum-titanium-carbon master alloy | |
| CN101358308A (en) | A kind of aluminum-titanium-carbon-boron-nitrogen master alloy and its preparation method | |
| CN101538666A (en) | Al-Sb-Y-Mg modifier for hypoeutectic Al-Si alloy and preparation process thereof | |
| CN116752008B (en) | Al-Ti-Nb-B intermediate alloy and preparation method and application thereof | |
| CN102220524B (en) | Preparation method of aluminum-nickel-titanium-carbon intermediate alloy | |
| CN113136496A (en) | Based on metal oxides MxOyPreparation method of Al-M-B refiner | |
| CN1109767C (en) | Method for preparing aluminium-titanium-carbon intermediate alloy | |
| CN102329998A (en) | Aluminium-magnesium-phosphorus intermediate alloy and preparation method thereof | |
| CN101591737A (en) | A zinc-aluminum-titanium-carbon master alloy refiner and its preparation method and application | |
| CN106591637A (en) | Aluminum-niobium-boron intermediate alloy and preparation method thereof | |
| CN105695805A (en) | Preparation method of strontium aluminum alloy with high strontium content | |
| CN107488794A (en) | A kind of aluminium cobalt titanium carbon intermediate alloy and preparation method thereof | |
| CN107326228A (en) | A kind of composite inoculating transcocrystallized Al-Si alloy and preparation method thereof | |
| CN114381628B (en) | A kind of refining agent and its preparation method and application | |
| CN105777128A (en) | Method for synthesizing hafnium carbide ceramic powder at low temperature through assisting of molten salts and magnesiothermic reduction | |
| CN110144501A (en) | A kind of long-acting rotten silumin and its modification process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 250000 hi tech Development Park, Ji'nan, Shandong Patentee after: SHANDONG AL&MG MELT TECHNOLOGY Co.,Ltd. Address before: 250061, No. ten, No. 73, Lixia District, Ji'nan City, Shandong Province Patentee before: SHANDONG SHANDA LVMEI MELTS TE |
|
| CP03 | Change of name, title or address | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090311 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |