CN100384945C - A kind of acid dye composition - Google Patents
A kind of acid dye composition Download PDFInfo
- Publication number
- CN100384945C CN100384945C CNB2006102000355A CN200610200035A CN100384945C CN 100384945 C CN100384945 C CN 100384945C CN B2006102000355 A CNB2006102000355 A CN B2006102000355A CN 200610200035 A CN200610200035 A CN 200610200035A CN 100384945 C CN100384945 C CN 100384945C
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- Prior art keywords
- acid
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- brown
- yellow
- black
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000000980 acid dye Substances 0.000 title claims abstract description 44
- 229930014626 natural product Natural products 0.000 claims abstract description 18
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000002253 acid Substances 0.000 claims description 85
- 229920002472 Starch Polymers 0.000 claims description 28
- 235000019698 starch Nutrition 0.000 claims description 28
- 239000008107 starch Substances 0.000 claims description 28
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 23
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 claims description 21
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 claims description 20
- 235000019233 fast yellow AB Nutrition 0.000 claims description 20
- 229920001202 Inulin Polymers 0.000 claims description 18
- 229940029339 inulin Drugs 0.000 claims description 18
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 claims description 10
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 claims description 8
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 claims description 7
- CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims description 7
- 229920001353 Dextrin Polymers 0.000 claims description 6
- 239000004375 Dextrin Substances 0.000 claims description 6
- 235000019425 dextrin Nutrition 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 5
- 150000002016 disaccharides Chemical class 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 150000004043 trisaccharides Chemical class 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims description 4
- 229920002774 Maltodextrin Polymers 0.000 claims description 3
- 239000005913 Maltodextrin Substances 0.000 claims description 3
- VVIVVAIHOWVTHB-UHFFFAOYSA-L disodium;3-[[4-amino-9,10-dioxo-3-[2-sulfonato-4-(2,4,4-trimethylpentan-2-yl)phenoxy]anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC1=CC(OC=2C(=CC(=CC=2)C(C)(C)CC(C)(C)C)S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O VVIVVAIHOWVTHB-UHFFFAOYSA-L 0.000 claims description 3
- 229940035034 maltodextrin Drugs 0.000 claims description 3
- QUBWRMVVDDDDBG-UHFFFAOYSA-M sodium;1-amino-4-(4-butylanilino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(CCCC)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O QUBWRMVVDDDDBG-UHFFFAOYSA-M 0.000 claims description 3
- MHHGZCMFNNAVCQ-UHFFFAOYSA-M sodium;1-amino-4-[3-(2-hydroxyethylsulfamoyl)-4,5-dimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].OCCNS(=O)(=O)C1=C(C)C(C)=CC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)=C1 MHHGZCMFNNAVCQ-UHFFFAOYSA-M 0.000 claims description 3
- PHBKXNWUWOCVEI-UHFFFAOYSA-M sodium;3-[[4-[(2-ethoxy-5-methylphenyl)diazenyl]naphthalen-1-yl]diazenyl]benzenesulfonate Chemical compound [Na+].CCOC1=CC=C(C)C=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC(S([O-])(=O)=O)=C1 PHBKXNWUWOCVEI-UHFFFAOYSA-M 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- QFVHZQCOUORWEI-UHFFFAOYSA-N 4-[(4-anilino-5-sulfonaphthalen-1-yl)diazenyl]-5-hydroxynaphthalene-2,7-disulfonic acid Chemical compound C=12C(O)=CC(S(O)(=O)=O)=CC2=CC(S(O)(=O)=O)=CC=1N=NC(C1=CC=CC(=C11)S(O)(=O)=O)=CC=C1NC1=CC=CC=C1 QFVHZQCOUORWEI-UHFFFAOYSA-N 0.000 claims description 2
- VVMPKPRQECVYDV-UHFFFAOYSA-N 5-butyl-2-[[4-(4-butyl-2-sulfoanilino)-5,8-dihydroxy-9,10-dioxoanthracen-1-yl]amino]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(CCCC)=CC=C1NC(C=1C(=O)C2=C(O)C=CC(O)=C2C(=O)C=11)=CC=C1NC1=CC=C(CCCC)C=C1S(O)(=O)=O VVMPKPRQECVYDV-UHFFFAOYSA-N 0.000 claims description 2
- DLFQBOOBABMDKU-UHFFFAOYSA-N 6637-87-2 Chemical compound OC1=C(N=NC=2C(=C(C=C(C=2)[N+]([O-])=O)[N+]([O-])=O)O)C=C(N=NC=2C3=C(O)C=C(C=C3C=C(C=2)S(O)(=O)=O)S(O)(=O)=O)C(O)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 DLFQBOOBABMDKU-UHFFFAOYSA-N 0.000 claims description 2
- 229920000858 Cyclodextrin Polymers 0.000 claims description 2
- HMEKVHWROSNWPD-UHFFFAOYSA-N Erioglaucine A Chemical compound [NH4+].[NH4+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 HMEKVHWROSNWPD-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- XKTMIJODWOEBKO-UHFFFAOYSA-M Guinee green B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- ANSOKCGDSQQISA-UHFFFAOYSA-N [1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane Chemical compound C1CCCC(C=2C=3C(=CC=C4CCCCC4=3)P(C=3C=CC=CC=3)C=3C=CC=CC=3)=C1C=CC=2P(C=1C=CC=CC=1)C1=CC=CC=C1 ANSOKCGDSQQISA-UHFFFAOYSA-N 0.000 claims description 2
- LIKZXCROQGHXTI-UHFFFAOYSA-M acid blue 25 Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1=CC=CC=C1 LIKZXCROQGHXTI-UHFFFAOYSA-M 0.000 claims description 2
- 229920006320 anionic starch Polymers 0.000 claims description 2
- VUXVWHOCQSLYRN-UHFFFAOYSA-O benzyl-[4-[[4-[benzyl(ethyl)amino]phenyl]-(2,4-disulfophenyl)methylidene]cyclohexa-2,5-dien-1-ylidene]-ethylazanium Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=CC=CC=2)C=2C(=CC(=CC=2)S(O)(=O)=O)S(O)(=O)=O)C=CC=1N(CC)CC1=CC=CC=C1 VUXVWHOCQSLYRN-UHFFFAOYSA-O 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- NKLPQNGYXWVELD-UHFFFAOYSA-M coomassie brilliant blue Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=C1 NKLPQNGYXWVELD-UHFFFAOYSA-M 0.000 claims description 2
- ZEEMBOPWDPAXAI-UHFFFAOYSA-L dipotassium 5-amino-3-[[4-[[4-[(2,4-diaminophenyl)diazenyl]phenyl]sulfamoyl]phenyl]diazenyl]-4-hydroxy-6-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [K+].[K+].NC1=CC=C(N=NC2=CC=C(NS(=O)(=O)C3=CC=C(C=C3)N=NC3=C(O)C4=C(N)C(N=NC5=CC=C(C=C5)[N+]([O-])=O)=C(C=C4C=C3S([O-])(=O)=O)S([O-])(=O)=O)C=C2)C(N)=C1 ZEEMBOPWDPAXAI-UHFFFAOYSA-L 0.000 claims description 2
- GYVPMHHWPSYINH-UHFFFAOYSA-L disodium 2-[4-[[2,4-dihydroxy-3-[[4-(4-nitro-2-sulfonatoanilino)phenyl]diazenyl]phenyl]diazenyl]anilino]-5-nitrobenzenesulfonate Chemical compound [Na+].[Na+].OC1=CC=C(N=NC2=CC=C(NC3=CC=C(C=C3S([O-])(=O)=O)[N+]([O-])=O)C=C2)C(O)=C1N=NC1=CC=C(NC2=CC=C(C=C2S([O-])(=O)=O)[N+]([O-])=O)C=C1 GYVPMHHWPSYINH-UHFFFAOYSA-L 0.000 claims description 2
- XDBZPHDFHYZHNG-UHFFFAOYSA-L disodium 3-[(5-chloro-2-phenoxyphenyl)diazenyl]-4-hydroxy-5-[(4-methylphenyl)sulfonylamino]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].C1=CC(C)=CC=C1S(=O)(=O)NC(C1=C2O)=CC(S([O-])(=O)=O)=CC1=CC(S([O-])(=O)=O)=C2N=NC1=CC(Cl)=CC=C1OC1=CC=CC=C1 XDBZPHDFHYZHNG-UHFFFAOYSA-L 0.000 claims description 2
- VGCGYVHOTSGFBE-UHFFFAOYSA-L disodium 4-amino-3-[(4-aminophenyl)diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(cc1)N=Nc1c(N)c2c(O)c(N=Nc3ccccc3)c(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O VGCGYVHOTSGFBE-UHFFFAOYSA-L 0.000 claims description 2
- GLNHIAPTFHWQKY-UHFFFAOYSA-L disodium 4-amino-3-[[4-[[4-[(2,4-diaminophenyl)diazenyl]phenyl]sulfonylamino]phenyl]diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)S(=O)(=O)Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccccc4)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 GLNHIAPTFHWQKY-UHFFFAOYSA-L 0.000 claims description 2
- OJFUEILETDLNQK-UHFFFAOYSA-L disodium 5-[[2,4-dihydroxy-3-[(2-hydroxy-5-nitrophenyl)diazenyl]phenyl]diazenyl]-4-hydroxy-3-[(4-nitrophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=CC=C(C=C1N=NC1=C(O)C=CC(N=NC2=CC(=CC3=CC(=C(N=NC4=CC=C(C=C4)[N+]([O-])=O)C(O)=C23)S([O-])(=O)=O)S([O-])(=O)=O)=C1O)[N+]([O-])=O OJFUEILETDLNQK-UHFFFAOYSA-L 0.000 claims description 2
- WXUZMLVSQROLEX-UHFFFAOYSA-L disodium 5-[[4-[(4-anilino-3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]-6-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Oc1ccc2cc(ccc2c1N=Nc1ccc(N=Nc2ccc(Nc3ccccc3)c(c2)S([O-])(=O)=O)c2ccccc12)S([O-])(=O)=O WXUZMLVSQROLEX-UHFFFAOYSA-L 0.000 claims description 2
- HRMOLDWRTCFZRP-UHFFFAOYSA-L disodium 5-acetamido-3-[(4-acetamidophenyl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].OC1=C(C(=CC2=CC(=CC(=C12)NC(C)=O)S(=O)(=O)[O-])S(=O)(=O)[O-])N=NC1=CC=C(C=C1)NC(C)=O.[Na+] HRMOLDWRTCFZRP-UHFFFAOYSA-L 0.000 claims description 2
- ARZVLGVDYAMAFX-UHFFFAOYSA-L disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc2cc(cc(O)c2c1N=Nc1ccc(cc1S([O-])(=O)=O)[N+]([O-])=O)S([O-])(=O)=O ARZVLGVDYAMAFX-UHFFFAOYSA-L 0.000 claims description 2
- LERIXBKRKBHLHG-UHFFFAOYSA-L disodium;2-[[5,8-dihydroxy-4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]-5-methylbenzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=C(O)C=CC(O)=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O LERIXBKRKBHLHG-UHFFFAOYSA-L 0.000 claims description 2
- UHXQPQCJDDSMCB-UHFFFAOYSA-L disodium;3-[[9,10-dioxo-4-(2,4,6-trimethyl-3-sulfonatoanilino)anthracen-1-yl]amino]-2,4,6-trimethylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C(C)=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=C(C)C=C(C)C(S([O-])(=O)=O)=C1C UHXQPQCJDDSMCB-UHFFFAOYSA-L 0.000 claims description 2
- UTIACSXEVKXHPT-YIDQSHOPSA-L disodium;4-[(2z)-2-[(5z)-4,6-dioxo-5-[(4-sulfonatonaphthalen-1-yl)hydrazinylidene]cyclohex-2-en-1-ylidene]hydrazinyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C12=CC=CC=C2C(S(=O)(=O)[O-])=CC=C1N\N=C(\C=CC\1=O)C(=O)C/1=N\NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 UTIACSXEVKXHPT-YIDQSHOPSA-L 0.000 claims description 2
- BOXAUJCFZBSNKZ-UHFFFAOYSA-L disodium;5-butyl-2-[[4-(4-butyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(CCCC)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(CCCC)C=C1S([O-])(=O)=O BOXAUJCFZBSNKZ-UHFFFAOYSA-L 0.000 claims description 2
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 claims description 2
- LCZPIYCNOWJWPQ-UHFFFAOYSA-I disodium;chromium(3+);1-[(2-oxidonaphthalen-1-yl)diazenyl]-4-sulfonaphthalen-2-olate;3-oxido-4-[(2-oxidonaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].[Cr+3].C12=CC=CC=C2C(S(=O)(=O)O)=CC([O-])=C1N=NC1=C([O-])C=CC2=CC=CC=C12.C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3[O-])=C([O-])C=C(S([O-])(=O)=O)C2=C1 LCZPIYCNOWJWPQ-UHFFFAOYSA-I 0.000 claims description 2
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- WDPIZEKLJKBSOZ-UHFFFAOYSA-M green s Chemical compound [Na+].C1=CC(N(C)C)=CC=C1C(C=1C2=CC=C(C=C2C=C(C=1O)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](C)C)C=C1 WDPIZEKLJKBSOZ-UHFFFAOYSA-M 0.000 claims description 2
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- MCPLVIGCWWTHFH-UHFFFAOYSA-L methyl blue Chemical compound [Na+].[Na+].C1=CC(S(=O)(=O)[O-])=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[NH+]C=2C=CC(=CC=2)S([O-])(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S([O-])(=O)=O)=CC=2)C=C1 MCPLVIGCWWTHFH-UHFFFAOYSA-L 0.000 claims description 2
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 claims description 2
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- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 2
- QERXHBDEEFLTOL-UHFFFAOYSA-M sodium 1-[[4-[(4-sulfophenyl)diazenyl]phenyl]diazenyl]naphthalen-2-olate Chemical compound [Na+].Oc1ccc2ccccc2c1N=Nc1ccc(cc1)N=Nc1ccc(cc1)S([O-])(=O)=O QERXHBDEEFLTOL-UHFFFAOYSA-M 0.000 claims description 2
- VFYDFVDOOIPQHX-UHFFFAOYSA-M sodium 2-[(4-aminophenyl)diazenyl]-5-sulfonaphthalen-1-olate Chemical compound [Na+].C1=CC(N)=CC=C1N=NC1=CC=C(C(=CC=C2)S([O-])(=O)=O)C2=C1O VFYDFVDOOIPQHX-UHFFFAOYSA-M 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
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- DJDYMAHXZBQZKH-UHFFFAOYSA-M sodium;1-amino-4-(cyclohexylamino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1CCCCC1 DJDYMAHXZBQZKH-UHFFFAOYSA-M 0.000 claims description 2
- OFHDOLUPOLKDSG-UHFFFAOYSA-M sodium;1-amino-4-[3-(benzamidomethyl)-2,4,6-trimethylanilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=C(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)C(C)=C1CNC(=O)C1=CC=CC=C1 OFHDOLUPOLKDSG-UHFFFAOYSA-M 0.000 claims description 2
- SVNACZCPWZXXSW-UHFFFAOYSA-M sodium;1-amino-9,10-dioxo-4-(2,4,6-trimethyl-3-sulfoanilino)anthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=C(S(O)(=O)=O)C(C)=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O SVNACZCPWZXXSW-UHFFFAOYSA-M 0.000 claims description 2
- RRETZLLHOMHNNB-UHFFFAOYSA-M sodium;1-amino-9,10-dioxo-4-(2,4,6-trimethylanilino)anthracene-2-sulfonate Chemical compound [Na+].CC1=CC(C)=CC(C)=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O RRETZLLHOMHNNB-UHFFFAOYSA-M 0.000 claims description 2
- BADRBIXUSUCBEG-UHFFFAOYSA-M sodium;2-[(4-amino-3-methyl-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(C)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O BADRBIXUSUCBEG-UHFFFAOYSA-M 0.000 claims description 2
- GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 claims description 2
- SHBDDIJUSNNBLQ-UHFFFAOYSA-M sodium;3-[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SHBDDIJUSNNBLQ-UHFFFAOYSA-M 0.000 claims description 2
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 claims description 2
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 claims description 2
- NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 claims description 2
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- RIJLWEYDGZAVGC-UHFFFAOYSA-M sodium;5-methyl-2-[[4-(methylamino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(NC)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O RIJLWEYDGZAVGC-UHFFFAOYSA-M 0.000 claims description 2
- FHIODWDKXMVJGO-UHFFFAOYSA-N sodium;8-anilino-5-[[4-[(5-sulfonaphthalen-1-yl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1-sulfonic acid Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC(C1=CC=CC(=C11)S(O)(=O)=O)=CC=C1NC1=CC=CC=C1 FHIODWDKXMVJGO-UHFFFAOYSA-N 0.000 claims description 2
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- ZIUSSTSXXLLKKK-KOBPDPAPSA-N (1e,4z,6e)-5-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,4,6-trien-3-one Chemical compound C1=C(O)C(OC)=CC(\C=C\C(\O)=C\C(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 ZIUSSTSXXLLKKK-KOBPDPAPSA-N 0.000 claims 22
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- 108010053775 Nisin Proteins 0.000 description 1
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- 229940121375 antifungal agent Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229940090204 c.i. acid blue 324 Drugs 0.000 description 1
- ZJKLNUHASXGERK-UHFFFAOYSA-M chembl3185301 Chemical compound [Na+].NC1=CC=C2C=C(S([O-])(=O)=O)C=C(O)C2=C1N=NC1=CC=CC=C1C(F)(F)F ZJKLNUHASXGERK-UHFFFAOYSA-M 0.000 description 1
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- JCGDEGCAEZOBSD-UHFFFAOYSA-L disodium 2-[4-[(2-hydroxynaphthalen-1-yl)diazenyl]-2-sulfonatophenyl]-5-[(3-methyl-5-oxo-1-phenyl-4H-pyrazol-4-yl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].CC1=NN(C(=O)C1N=Nc1ccc(-c2ccc(cc2S([O-])(=O)=O)N=Nc2c(O)ccc3ccccc23)c(c1)S([O-])(=O)=O)c1ccccc1 JCGDEGCAEZOBSD-UHFFFAOYSA-L 0.000 description 1
- SWYAODARJIJAKL-UHFFFAOYSA-L disodium 3-[[4-[1-[4-[(1,7-dihydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-3-methylphenyl]cyclohexyl]-2-methylphenyl]diazenyl]-4,6-dihydroxynaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Cc1cc(ccc1N=Nc1c(O)c2cc(O)ccc2cc1S([O-])(=O)=O)C1(CCCCC1)c1ccc(N=Nc2c(O)c3cc(O)ccc3cc2S([O-])(=O)=O)c(C)c1 SWYAODARJIJAKL-UHFFFAOYSA-L 0.000 description 1
- DMYYMROEUDSFIN-UHFFFAOYSA-L disodium 3-hydroxy-4-[[2-methyl-4-[(2-methylphenyl)diazenyl]phenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].Cc1ccccc1N=Nc1ccc(N=Nc2c(O)c(cc3cc(ccc23)S([O-])(=O)=O)S([O-])(=O)=O)c(C)c1 DMYYMROEUDSFIN-UHFFFAOYSA-L 0.000 description 1
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- YFSRRLXAGNGNNQ-UHFFFAOYSA-L disodium 4-hydroxy-3-[[3-methyl-4-[2-methyl-4-[[4-(4-methylphenyl)sulfonyloxyphenyl]diazenyl]phenyl]phenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound CC1=CC=C(C=C1)S(=O)(=O)OC2=CC=C(C=C2)N=NC3=CC(=C(C=C3)C4=C(C=C(C=C4)N=NC5=C(C=C6C=C(C=CC6=C5[O-])S(=O)(=O)[O-])S(=O)(=O)O)C)C.[Na+].[Na+] YFSRRLXAGNGNNQ-UHFFFAOYSA-L 0.000 description 1
- MHEPHJHRLWJBBX-UHFFFAOYSA-L disodium 4-hydroxy-5-[(4-methylphenyl)sulfonylamino]-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound CC1=CC=C(C=C1)S(=O)(=O)NC2=C3C(=CC(=C2)S(=O)(=O)[O-])C=C(C(=C3[O-])N=NC4=CC=CC=C4)S(=O)(=O)O.[Na+].[Na+] MHEPHJHRLWJBBX-UHFFFAOYSA-L 0.000 description 1
- JCEBMROGCIEFRX-UHFFFAOYSA-L disodium 5-[(2-hydroxynaphthalen-1-yl)diazenyl]-2-[4-[(2-hydroxynaphthalen-1-yl)diazenyl]-2-sulfonatophenyl]benzenesulfonate Chemical compound OC1=C(C2=CC=CC=C2C=C1)N=NC=1C=C(C(=CC=1)C1=CC=C(C=C1S(=O)(=O)[O-])N=NC1=C(C=CC2=CC=CC=C12)O)S(=O)(=O)[O-].[Na+].[Na+] JCEBMROGCIEFRX-UHFFFAOYSA-L 0.000 description 1
- CZWHGIACASUWJC-UHFFFAOYSA-L disodium 5-acetamido-3-[(4-dodecylphenyl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].CCCCCCCCCCCCc1ccc(cc1)N=Nc1c(O)c2c(NC(C)=O)cc(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O CZWHGIACASUWJC-UHFFFAOYSA-L 0.000 description 1
- VNENWQQVIWFWHW-UHFFFAOYSA-L disodium 7-hydroxy-8-[[4-[1-[4-[(4-hydroxyphenyl)diazenyl]phenyl]cyclohexyl]phenyl]diazenyl]naphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].Oc1ccc(cc1)N=Nc1ccc(cc1)C1(CCCCC1)c1ccc(cc1)N=Nc1c(O)ccc2cc(cc(c12)S([O-])(=O)=O)S([O-])(=O)=O VNENWQQVIWFWHW-UHFFFAOYSA-L 0.000 description 1
- SVSHEAJPDAGGCC-UHFFFAOYSA-L disodium 7-hydroxy-8-[[4-[4-[[4-(4-methylphenyl)sulfonyloxyphenyl]diazenyl]phenyl]phenyl]diazenyl]naphthalene-1,3-disulfonate Chemical compound CC1=CC=C(C=C1)S(=O)(=O)OC2=CC=C(C=C2)N=NC3=CC=C(C=C3)C4=CC=C(C=C4)N=NC5=C(C=CC6=CC(=CC(=C65)S(=O)(=O)O)S(=O)(=O)[O-])[O-].[Na+].[Na+] SVSHEAJPDAGGCC-UHFFFAOYSA-L 0.000 description 1
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- RHCZISCTNGVWCV-UHFFFAOYSA-L disodium;1-amino-4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O RHCZISCTNGVWCV-UHFFFAOYSA-L 0.000 description 1
- RISWUWJFSHOUBJ-UHFFFAOYSA-L disodium;1-amino-4-[4-[[4-[(4-amino-9,10-dioxo-3-sulfonatoanthracen-1-yl)amino]phenyl]methyl]anilino]-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(S([O-])(=O)=O)C=C2NC(C=C1)=CC=C1CC(C=C1)=CC=C1NC1=C2C(=O)C3=CC=CC=C3C(=O)C2=C(N)C(S([O-])(=O)=O)=C1 RISWUWJFSHOUBJ-UHFFFAOYSA-L 0.000 description 1
- MIHOYZILGVCGCK-UHFFFAOYSA-L disodium;2-[[1-(2-chloro-5-sulfonatophenyl)-3-methyl-5-oxo-4h-pyrazol-4-yl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].O=C1C(N=NC=2C(=C3C=CC=CC3=CC=2)S([O-])(=O)=O)C(C)=NN1C1=CC(S([O-])(=O)=O)=CC=C1Cl MIHOYZILGVCGCK-UHFFFAOYSA-L 0.000 description 1
- GYGVRMLIQVFLPE-UHFFFAOYSA-L disodium;3-[[n-ethyl-4-[[4-[(3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]anilino]methyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(N=NC=2C3=CC=CC=C3C(N=NC=3C=C(C=CC=3)S([O-])(=O)=O)=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 GYGVRMLIQVFLPE-UHFFFAOYSA-L 0.000 description 1
- ZOESAMNEZGSOPU-UHFFFAOYSA-L disodium;4-[4-[acetyl(methyl)amino]-2-sulfonatoanilino]-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(N(C(C)=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O ZOESAMNEZGSOPU-UHFFFAOYSA-L 0.000 description 1
- ZRYQXQUPWQNYSX-UHFFFAOYSA-L disodium;5-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]-2-[4-[(3-methyl-5-oxo-1-phenyl-4h-pyrazol-4-yl)diazenyl]-2-sulfonatophenyl]benzenesulfonate Chemical compound [Na+].[Na+].CC1=NN(C=2C=CC=CC=2)C(=O)C1N=NC(C=C1S([O-])(=O)=O)=CC=C1C(C(=C1)S([O-])(=O)=O)=CC=C1N=NC(C1=O)C(C)=NN1C1=CC=CC=C1 ZRYQXQUPWQNYSX-UHFFFAOYSA-L 0.000 description 1
- BMYUQZABARGLAD-UHFFFAOYSA-L disodium;8-(4-methylanilino)-5-[[4-[(3-sulfonatophenyl)diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC(C)=CC=C1NC(C1=C(C=CC=C11)S([O-])(=O)=O)=CC=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC(S([O-])(=O)=O)=C1 BMYUQZABARGLAD-UHFFFAOYSA-L 0.000 description 1
- HBINTOQGSKHKJI-UHFFFAOYSA-L disodium;8-[[3-methyl-4-(4-methylphenyl)sulfonyloxyphenyl]diazenyl]-5-[[4-(4-nitro-2-sulfonatoanilino)phenyl]diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].C1=CC(C)=CC=C1S(=O)(=O)OC1=CC=C(N=NC=2C3=CC(=CC=C3C(N=NC=3C=CC(NC=4C(=CC(=CC=4)[N+]([O-])=O)S([O-])(=O)=O)=CC=3)=CC=2)S([O-])(=O)=O)C=C1C HBINTOQGSKHKJI-UHFFFAOYSA-L 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
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- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
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- 239000003755 preservative agent Substances 0.000 description 1
- JXRBVOFBCVPZOV-UHFFFAOYSA-M sodium 4-[4-[(4-hydroxy-2-methylphenyl)diazenyl]anilino]-3-nitrobenzenesulfonate Chemical compound [Na+].Cc1cc(O)ccc1N=Nc1ccc(Nc2ccc(cc2[N+]([O-])=O)S([O-])(=O)=O)cc1 JXRBVOFBCVPZOV-UHFFFAOYSA-M 0.000 description 1
- ILTGBRCWJYLHTC-UHFFFAOYSA-N sodium 6-hydroxy-5-[[4-[(4-sulfophenyl)diazenyl]phenyl]diazenyl]naphthalene-2-sulfonic acid Chemical compound C1=CC(=CC=C1N=NC2=CC=C(C=C2)S(=O)(=O)O)N=NC3=C(C=CC4=C3C=CC(=C4)S(=O)(=O)O)O.[Na+] ILTGBRCWJYLHTC-UHFFFAOYSA-N 0.000 description 1
- MSZHEEJTTAUDJC-UHFFFAOYSA-M sodium 7-acetamido-3-[(4-acetamidophenyl)diazenyl]-4-hydroxynaphthalene-2-sulfonate Chemical compound [Na+].CC(=O)Nc1ccc(cc1)N=Nc1c(O)c2ccc(NC(C)=O)cc2cc1S([O-])(=O)=O MSZHEEJTTAUDJC-UHFFFAOYSA-M 0.000 description 1
- GVLHHJPRNMDLLL-UHFFFAOYSA-M sodium 7-amino-8-[[4-chloro-2-(trifluoromethyl)phenyl]diazenyl]-3-sulfonaphthalen-1-olate Chemical compound NC1=CC=C2C=C(C=C(O)C2=C1N=NC1=CC=C(Cl)C=C1C(F)(F)F)S(=O)(=O)O[Na] GVLHHJPRNMDLLL-UHFFFAOYSA-M 0.000 description 1
- FTYDFSDLKHVWLD-UHFFFAOYSA-M sodium;3-[[4-[(4-ethoxyphenyl)diazenyl]naphthalen-1-yl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1N=NC(C1=CC=CC=C11)=CC=C1N=NC1=CC=CC(S([O-])(=O)=O)=C1 FTYDFSDLKHVWLD-UHFFFAOYSA-M 0.000 description 1
- IXNUVCLIRYUKFB-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)-2-methylphenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].CC1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 IXNUVCLIRYUKFB-UHFFFAOYSA-M 0.000 description 1
- MIBVDSFVCOIWCC-UHFFFAOYSA-M sodium;4-(3-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].CC(=O)NC1=CC=CC(NC=2C=3C(=O)C4=CC=CC=C4C(=O)C=3C(N)=C(C=2)S([O-])(=O)=O)=C1 MIBVDSFVCOIWCC-UHFFFAOYSA-M 0.000 description 1
- VRDAELYOGRCZQD-NFLRKZIHSA-M sodium;4-[(2z)-2-[(5e)-5-[(2,4-dimethylphenyl)hydrazinylidene]-4,6-dioxocyclohex-2-en-1-ylidene]hydrazinyl]benzenesulfonate Chemical compound [Na+].CC1=CC(C)=CC=C1N\N=C(/C(=O)C=C\1)C(=O)C/1=N\NC1=CC=C(S([O-])(=O)=O)C=C1 VRDAELYOGRCZQD-NFLRKZIHSA-M 0.000 description 1
- GNFJBURFXWYRQN-UHFFFAOYSA-M sodium;4-[3-[[2-methyl-4-(4-methylphenyl)sulfonyloxyphenyl]diazenyl]anilino]-3-nitrobenzenesulfonate Chemical compound [Na+].C1=CC(C)=CC=C1S(=O)(=O)OC(C=C1C)=CC=C1N=NC1=CC=CC(NC=2C(=CC(=CC=2)S([O-])(=O)=O)[N+]([O-])=O)=C1 GNFJBURFXWYRQN-UHFFFAOYSA-M 0.000 description 1
- WYLWMAWLDZBLRN-UHFFFAOYSA-M sodium;4-[3-methyl-4-[[4-methyl-3-(phenylsulfamoyl)phenyl]diazenyl]-5-oxo-4h-pyrazol-1-yl]benzenesulfonate Chemical compound [Na+].CC1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC(C=1)=CC=C(C)C=1S(=O)(=O)NC1=CC=CC=C1 WYLWMAWLDZBLRN-UHFFFAOYSA-M 0.000 description 1
- DBSJKTVELUTRJM-UHFFFAOYSA-M sodium;4-[[5-methoxy-4-[(4-methoxyphenyl)diazenyl]-2-methylphenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(OC)=CC=C1N=NC1=CC(C)=C(N=NC=2C=CC(=CC=2)S([O-])(=O)=O)C=C1OC DBSJKTVELUTRJM-UHFFFAOYSA-M 0.000 description 1
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- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- GJRUEHLEWXORDW-UHFFFAOYSA-K trisodium 4-[[8-amino-7-[[4-[4-[[2-(2-methylanilino)-4-oxidophenyl]diazenyl]phenyl]phenyl]diazenyl]-1-oxido-3,6-disulfonaphthalen-2-yl]diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].[Na+].Cc1ccccc1Nc1cc(O)ccc1N=Nc1ccc(cc1)-c1ccc(cc1)N=Nc1c(N)c2c(O)c(N=Nc3ccc(cc3)S([O-])(=O)=O)c(cc2cc1S([O-])(=O)=O)S([O-])(=O)=O GJRUEHLEWXORDW-UHFFFAOYSA-K 0.000 description 1
- PEAGNRWWSMMRPZ-UHFFFAOYSA-L woodstain scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 PEAGNRWWSMMRPZ-UHFFFAOYSA-L 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
技术领域 technical field
本发明属于化工技术领域，特别涉及一类酸性染料组合物。The invention belongs to the technical field of chemical industry, in particular to a kind of acid dye composition.
背景技术 Background technique
聚酰胺纤维通常选用弱酸性染料在弱酸性浴中染色，弱酸性染料染锦纶纤维，由于染料分子对纤维的亲和力较大，因此绝大部分上色率均在80~90％，染色后加入适量的固色剂固色。但由于弱酸性染料染色时上色快，移染性差，因此常在染浴中加入阴离子表面活性剂作为匀染剂。添加不同的匀染剂，均会导致不同程度的竭染率下降。Polyamide fibers are usually dyed with weak acid dyes in a weak acid bath. Nylon fibers are dyed with weak acid dyes. Due to the high affinity of dye molecules to fibers, most of the dyeing rate is 80~90%. After dyeing, add appropriate amount color fixing agent. However, due to the fast coloring and poor migration of weak acid dyes, anionic surfactants are often added to the dye bath as leveling agents. Adding different leveling agents will lead to different degrees of decline in exhaustion rate.
为了实现弱酸性染料染色时的高上染率及染色物的高牢度，可在染料中加入来自天然产物的助剂，该助剂能增加染料溶液稳定性，提高染料的上染率及染色聚酰胺纤维的湿处理牢度性能，具有优良的均匀性。In order to achieve high dye uptake rate and high fastness of dyed products when dyeing with weak acid dyes, additives from natural products can be added to the dye, which can increase the stability of the dye solution, improve the dye uptake rate and dyeing The wet fastness performance of polyamide fiber has excellent uniformity.
迄今为止，尚未见有由酸性染料、来自天然产物的助剂及稳定剂所组成的染料组合物专利发表。So far, there has been no publication of a patent on a dye composition consisting of acid dyes, auxiliary agents and stabilizers derived from natural products.
发明内容 Contents of the invention
本发明的目的是针对现有的印染行业中弱酸性染料在对聚酰胺纤维染色时存在的问题，提供一种染色助剂，使用该助剂与染料按一定比例复配后，能使复配后的酸性染料吸尽率接近100％，同时提高染色后纤维的湿处理牢度。The purpose of the present invention is to provide a kind of dyeing auxiliaries to solve the problems existing in the dyeing of polyamide fibers by weak acid dyes in the existing printing and dyeing industry. The final acid dye exhaustion rate is close to 100%, and at the same time, the wet fastness of the dyed fiber is improved.
本发明的技术方案是：Technical scheme of the present invention is:
本发明的高性能酸性染料组合物按重量百分比是由以下组分所组成：High-performance acid dye composition of the present invention is made up of following components by weight percentage:
弱酸性染料 5％~90％Weak acid dye 5%~90%
来自天然产物的助剂 5％~90％Additives from natural products 5%~90%
稳定剂 0~1％Stabilizer 0~1%
三组分重量百分比的总和为100％。采用一般的方法均匀混合上述组分后，就得到本酸性染料组合物。The sum of the weight percentages of the three components is 100%. The acid dye composition is obtained by uniformly mixing the above-mentioned components by a general method.
本高性能酸性染料组合物各组分按重量百分比含量优选的范围为：The preferred range of each component of the high-performance acid dye composition by weight percentage is:
弱酸性染料 5％~90％Weak acid dye 5%~90%
来自天然产物的助剂 5％~90％Additives from natural products 5%~90%
稳定剂 1‰~19％Stabilizer 1‰~19%
三组分重量百分比的总和为100％。The sum of the weight percentages of the three components is 100%.
本高性能酸性染料组合物各组分按重量百分比另一含量优选的范围为：The preferred scope of each component of this high-performance acid dye composition by weight percentage is:
弱酸性染料 5％~90％Weak acid dye 5%~90%
来自天然产物的助剂 20％~50％Additives from natural products 20%~50%
稳定剂 1‰~19％Stabilizer 1‰~19%
三组分重量百分比的总和为100％。The sum of the weight percentages of the three components is 100%.
在上述高性能酸性染料组合物中，所述的酸性染料选自：In above-mentioned high-performance acid dye composition, described acid dye is selected from:
C.I.酸性黄25、C.I.酸性黄36、C.I.酸性黄40、C.I.酸性黄40:1、C.I.酸性黄42、C.I.酸性黄44、C.I.酸性黄49、C.I.酸性黄61、C.I.酸性黄72、C.I.酸性黄76、C.I.酸性黄79、C.I.酸性黄99、C.I.酸性黄114、C.I.酸性黄116、C.I.酸性黄117、C.I.酸性黄117:1、C.I.酸性黄118、C.I.酸性黄121、C.I.酸性黄127、C.I.酸性黄128、C.I.酸性黄151、C.I.酸性黄158、C.I.酸性黄158:1、C.I.酸性黄194、C.I.酸性黄199、C.I.酸性黄200、C.I.酸性黄219、C.I.酸性黄220、C.I.酸性黄232、C.I.酸性黄242；C.I.酸性橙3、C.I.酸性橙24、C.I.酸性橙33、C.I.酸性橙51、C.I.酸性橙56、C.I.酸性橙60、C.I.酸性橙67、C.I.酸性橙74、C.I.酸性橙87、C.I.酸性橙88、C.I.酸性橙89、C.I.酸性橙95、C.I.酸性橙116、C.I.酸性橙127、C.I.酸性橙154、C.I.酸性橙156、C.I.酸性橙171；C.I.酸性红6、C.I.酸性红35、C.I.酸性红37、C.I.酸性红42、C.I.酸性红57、C.I.酸性红73、C.I.酸性红85、C.I.酸性红97、C.I.酸性红106、C.I.酸性红111、C.I.酸性红114、C.I.酸性红114:1、C.I.酸性红115、C.I.酸性红118、C.I.酸性红119、C.I.酸性红122、C.I.酸性红137、C.I.酸性红138、C.I.酸性红142、C.I.酸性红151、C.I.酸性红154、C.I.酸性红172、C.I.酸性红183、C.I.酸性红186、C.I.酸性红211、C.I.酸性红213、C.I.酸性红215、C.I.酸性红226、C.I.酸性红249、C.I.酸性红251、C.I.酸性红257、C.I.酸性红260、C.I.酸性红266、C.I.酸性红299、C.I.酸性红308、C.I.酸性红315、C.I.酸性红336、C.I.酸性红337、C.I.酸性红359、C.I.酸性红361、C.I.酸性红362、C.I.酸性红374、C.I.酸性红405、C.I.酸性红407、C.I.酸性红410；C.I.酸性紫1、C.I.酸性紫7、C.I.酸性紫17、C.I.酸性紫43、C.I.酸性紫48、C.I.酸性紫49、C.I.酸性紫54、C.I.酸性紫56、C.I.酸性紫68、C.I.酸性紫90；C.I.酸性蓝1、C.I.酸性蓝7、C.I.酸性蓝9、C.I.酸性蓝15、C.I.酸性蓝25、C.I.酸性蓝27、C.I.酸性蓝40、C.I.酸性蓝41、C.I.酸性蓝47、C.I.酸性蓝62、C.I.酸性蓝80、C.I.酸性蓝82、C.I.酸性蓝83、C.I.酸性蓝90、C.I.酸性蓝92、C.I.酸性蓝93、C.I.酸性蓝113、C.I.酸性蓝120、C.I.酸性蓝127、C.I.酸性蓝127:1、C.I.酸性蓝129、C.I.酸性蓝129:1、C.I.酸性蓝138、C.I.酸性蓝140、C.I.酸性蓝142、C.I.酸性蓝145、C.I.酸性蓝158、C.I.酸性蓝168、C.I.酸性蓝171、C.I.酸性蓝182、C.I.酸性蓝183、C.I.酸性蓝185、C.I.酸性蓝193、C.I.酸性蓝209、C.I.酸性蓝225、C.I.酸性蓝230、C.I.酸性蓝260、C.I.酸性蓝264、C.I.酸性蓝277、C.I.酸性蓝284、C.I.酸性蓝317、C.I.酸性蓝324、C.I.酸性蓝328、C.I.酸性蓝350、C.I.酸性蓝371；C.I.酸性绿1、C.I.酸性绿3、C.I.酸性绿5、C.I.酸性绿9、C.I.酸性绿20、C.I.酸性绿25、C.I.酸性绿27、C.I.酸性绿28、C.I.酸性绿41、C.I.酸性绿43、C.I.酸性绿50、C.I.酸性绿54、C.I.酸性绿73；C.I.酸性棕2、C.I.酸性棕4、C.I.酸性棕14、C.I.酸性棕21、C.I.酸性棕28、C.I.酸性棕50、C.I.酸性棕58、C.I.酸性棕75、C.I.酸性棕98、C.I.酸性棕119、C.I.酸性棕121、C.I.酸性棕161、C.I.酸性棕165、C.I.酸性棕191、C.I.酸性棕214、C.I.酸性棕282、C.I.酸性棕283、C.I.酸性棕289、C.I.酸性棕349、C.I.酸性棕354、C.I.酸性棕355、C.I.酸性棕365、C.I.酸性棕440；C.I.酸性黑1、C.I.酸性黑2、C.I.酸性黑24、C.I.酸性黑26、C.I.酸性黑29、C.I.酸性黑31、C.I.酸性黑52、C.I.酸性黑58、C.I.酸性黑60、C.I.酸性黑63、C.I.酸性黑94、C.I.酸性黑107、C.I.酸性黑109、C.I.酸性黑168、C.I.酸性黑170、C.I.酸性黑172、C.I.酸性黑194、C.I.酸性黑207、C.I.酸性黑210、C.I.酸性黑234、C.I.酸性黑243。C.I. Acid Yellow 25, C.I. Acid Yellow 36, C.I. Acid Yellow 40, C.I. Acid Yellow 40:1, C.I. Acid Yellow 42, C.I. Acid Yellow 44, C.I. Acid Yellow 49, C.I. Acid Yellow 61, C.I. Acid Yellow 72, C.I. Acid Yellow 76. C.I. Acid Yellow 79, C.I. Acid Yellow 99, C.I. Acid Yellow 114, C.I. Acid Yellow 116, C.I. Acid Yellow 117, C.I. Acid Yellow 117:1, C.I. Acid Yellow 118, C.I. Acid Yellow 121, C.I. Acid Yellow 127, C.I. Acid Yellow 128, C.I. Acid Yellow 151, C.I. Acid Yellow 158, C.I. Acid Yellow 158:1, C.I. Acid Yellow 194, C.I. Acid Yellow 199, C.I. Acid Yellow 200, C.I. Acid Yellow 219, C.I. Acid Yellow 220, C.I. Acid Yellow 232 , C.I. Acid Yellow 242; C.I. Acid Orange 3, C.I. Acid Orange 24, C.I. Acid Orange 33, C.I. Acid Orange 51, C.I. Acid Orange 56, C.I. Acid Orange 60, C.I. Acid Orange 67, C.I. , C.I. Acid Orange 88, C.I. Acid Orange 89, C.I. Acid Orange 95, C.I. Acid Orange 116, C.I. Acid Orange 127, C.I. Acid Orange 154, C.I. Acid Orange 156, C.I. Acid Orange 171; C.I. Acid Red 6, C.I. , C.I. Acid Red 37, C.I. Acid Red 42, C.I. Acid Red 57, C.I. Acid Red 73, C.I. Acid Red 85, C.I. Acid Red 97, C.I. Acid Red 106, C.I. Acid Red 111, C.I. Acid Red 114, C.I. Acid Red 114 :1, C.I. Acid Red 115, C.I. Acid Red 118, C.I. Acid Red 119, C.I. Acid Red 122, C.I. Acid Red 137, C.I. Acid Red 138, C.I. Acid Red 142, C.I. Acid Red 151, C.I. Acid Red 154, C.I. Acid Red Red 172, C.I. Acid Red 183, C.I. Acid Red 186, C.I. Acid Red 211, C.I. Acid Red 213, C.I. Acid Red 215, C.I. Acid Red 226, C.I. Acid Red 249, C.I. Acid Red 251, C.I. Red 260, C.I. Acid Red 266, C.I. Acid Red 299, C.I. Acid Red 308, C.I. Acid Red 315, C.I. Acid Red 336, C.I. Acid Red 337, C.I. Acid Red 359, C.I. Acid Red 361, C.I. Red 374, C.I. Acid Red 405, C.I. Acid Red 407, C.I. Acid Red 410; C.I. Acid Violet 1, C.I. Acid Violet 7, C.I. Acid Violet 17, C.I. Acid Violet 43, C.I. Acid Violet 48, C.I. Acid Violet 49, C.I. Acid Violet Violet 54, C.I. Acid Violet 56, C.I. Acid Violet 68, C.I. Acid Violet 90; C.I. Acid Blue 1, C.I. Acid Blue 7, C.I. Acid Blue 9, C.I. Acid Blue 15, C.I. Acid Blue 25, C.I. Acid Blue 27, C.I. Acid Acid Blue 40, C.I. Acid Blue 41, C.I. Acid Blue 47, C.I. Acid Blue 62, C.I. Acid Blue 80, C.I. Acid Blue 82, C.I. Acid Blue 83, C.I. Acid Blue 90, C.I. Acid Blue 92, C.I. Acid Blue 93, C.I. Blue 113, C.I. Acid Blue 120, C.I. Acid Blue 127, C.I. Acid Blue 127:1, C.I. Acid Blue 129, C.I. Acid Blue 129:1, C.I. Acid Blue 138, C.I. Acid Blue 140, C.I. Acid Blue 142, C.I. Acid Blue 145, C.I. acid blue 158, C.I. acid blue 168, C.I. acid blue 171, C.I. acid blue 182, C.I. acid blue 183, C.I. acid blue 185, C.I. acid blue 193, C.I. acid blue 209, C.I. acid blue 225, C.I. acid blue 230, C.I. Acid Blue 260, C.I. Acid Blue 264, C.I. Acid Blue 277, C.I. Acid Blue 284, C.I. Acid Blue 317, C.I. Acid Blue 324, C.I. Acid Blue 328, C.I. Acid Blue 350, C.I. Acid Blue 371; C.I. Acid Green 1. C.I. Acid Green 3, C.I. Acid Green 5, C.I. Acid Green 9, C.I. Acid Green 20, C.I. Acid Green 25, C.I. Acid Green 27, C.I. Acid Green 28, C.I. Acid Green 41, C.I. Acid Green 43, C.I. Acid Green 50, C.I. Acid Green 54, C.I. Acid Green 73; C.I. Acid Brown 2, C.I. Acid Brown 4, C.I. Acid Brown 14, C.I. Acid Brown 21, C.I. Acid Brown 28, C.I. Acid Brown 50, C.I. Acid Brown 58, C.I. Acid Brown 75. C.I. Acid Brown 98, C.I. Acid Brown 119, C.I. Acid Brown 121, C.I. Acid Brown 161, C.I. Acid Brown 165, C.I. Acid Brown 191, C.I. Acid Brown 214, C.I. Acid Brown 282, C.I. Acid Brown 283, C.I. Acid Brown 289, C.I. Acid Brown 349, C.I. Acid Brown 354, C.I. Acid Brown 355, C.I. Acid Brown 365, C.I. Acid Brown 440; C.I. Acid Black 1, C.I. Acid Black 2, C.I. Acid Black 24, C.I. Acid Black 26, C.I. Acid Black 29. C.I. Acid Black 31, C.I. Acid Black 52, C.I. Acid Black 58, C.I. Acid Black 60, C.I. Acid Black 63, C.I. Acid Black 94, C.I. Acid Black 107, C.I. Acid Black 109, C.I. Acid Black 168, C.I. Acid Black 170, C.I. Acid Black 172, C.I. Acid Black 194, C.I. Acid Black 207, C.I. Acid Black 210, C.I. Acid Black 234, C.I. Acid Black 243.
在上述高性能酸性染料组合物中，所述的来自天然产物的助剂选自：In above-mentioned high-performance acid dye composition, described auxiliary agent from natural product is selected from:
壳聚糖、淀粉、改性淀粉、酶催化水解淀粉、糊精、菊粉、改性菊粉、明胶、瓜尔豆胶、多糖混合物、葡萄糖或蔗糖。Chitosan, starch, modified starch, enzymatically hydrolyzed starch, dextrin, inulin, modified inulin, gelatin, guar gum, polysaccharide mixture, glucose or sucrose.
改性淀粉选自阴离子淀粉、阳离子淀粉、两性淀粉、酸变性淀粉、氧化淀粉、预糊化淀粉、酯化淀粉、醚化淀粉、淀粉糖或水溶性淀粉。酶催化水解淀粉为四糖以上比例85~100％、三糖0~15％、双糖0~10％或单糖0~5.0％的多糖混合物。糊精选自环状糊精、白糊精、黄糊精或麦芽糊精。改性菊粉选自阴离子菊粉、阳离子菊粉、两性菊粉、酸变性菊粉、氧化菊粉、酯化菊粉、醚化菊粉。The modified starch is selected from anionic starch, cationic starch, amphoteric starch, acid-modified starch, oxidized starch, pregelatinized starch, esterified starch, etherified starch, starch sugar or water-soluble starch. The enzyme-catalyzed hydrolyzed starch is a polysaccharide mixture with a ratio of 85-100% or more of tetrasaccharides, 0-15% of trisaccharides, 0-10% of disaccharides or 0-5.0% of monosaccharides. The paste is selected from cyclodextrin, white dextrin, yellow dextrin or maltodextrin. The modified inulin is selected from anionic inulin, cationic inulin, amphoteric inulin, acid-denatured inulin, oxidized inulin, esterified inulin, etherified inulin.
在上述高性能酸性染料组合物中，所述的稳定剂选自：In above-mentioned high-performance acid dye composition, described stabilizing agent is selected from:
苯甲酸钠、山梨酸钾、乳酸链菌素、壳寡糖等杀菌、抑霉或防腐剂。Sodium benzoate, potassium sorbate, nisin, oligochitosan and other bactericidal, antifungal or preservatives.
本发明的效果和益处是，能使复配后的酸性染料吸尽率接近100％，同时提高染色后纤维的湿处理牢度，不会改变纤维手感，染色后的无色清液中残留的助剂排放后可完全生物降解。它可用于尼龙、丝、羊毛、皮革、合成树脂、纸浆、纸及再生纸等物质的染色，尤其适于各种新型聚酰胺纤维，如塔斯隆(Taslon)等的染色，得到均匀的染色效果。The effect and benefit of the present invention are that it can make the exhaustion rate of the compounded acid dye close to 100%, and at the same time improve the wet treatment fastness of the dyed fiber without changing the hand feel of the fiber, and the residual dye in the colorless clear liquid after dyeing The additive is completely biodegradable after discharge. It can be used for dyeing nylon, silk, wool, leather, synthetic resin, pulp, paper and recycled paper, especially suitable for dyeing various new polyamide fibers, such as Taslon, etc., to obtain uniform dyeing Effect.
本发明是一种基于复配增效原理的均匀混合物，来自天然产物的助剂对于增进染料的上色性能及提高染色纤维的牢度具有明显的效果。当染料及助剂按一定比例混合在一起后，特别是当特定的助剂与特定的酸性染料混合后，可使染料具有优良的上色性能及牢度性能。The invention is a homogeneous mixture based on the principle of compound synergy, and the auxiliary agent from natural products has obvious effects on improving the coloring performance of dyes and improving the fastness of dyed fibers. When dyes and auxiliary agents are mixed together in a certain proportion, especially when specific auxiliary agents are mixed with specific acid dyes, the dyes can have excellent coloring performance and fastness performance.
具体实施方式 Detailed ways
以下结合技术方案详细叙述本发明的具体实施方式和实施例。The specific implementation modes and examples of the present invention will be described in detail below in conjunction with the technical solutions.
本发明的高性能酸性染料组合物是由酸性染料、来自天然产物的助剂、稳定剂所组成，三者均可以直接从市场上购得。The high-performance acid dye composition of the present invention is composed of acid dye, auxiliary agent and stabilizer from natural products, all of which can be purchased directly from the market.
将上述三组分按比例混合，就得到本发明的高性能酸性染料组合物。The above-mentioned three components are mixed in proportion to obtain the high-performance acid dye composition of the present invention.
实施例1Example 1
称取200gC.I.酸性橙116(200％)，150g麦芽糊精，1g苯甲酸，混合均匀，就得到351g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。Weigh 200g of C.I. Acid Orange 116 (200%), 150g of maltodextrin, and 1g of benzoic acid, and mix them uniformly to obtain 351g of a high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance.
例1~10。Example 1~10.
在例1~10中，各组分的重量百分比如下表所示：In example 1～10, the percentage by weight of each component is as shown in the table below:
实施例2Example 2
称取200gC.I.酸性红114(300％)，200g酶催化水解淀粉，1.2g苯甲酸，混合均匀，就得到401.2g高性能酸性染料组合物。将该染料组合物用于塔斯隆(Taslon)纤维的染色，可达到100％的竭染率，优良的牢度性能。酶催化水解淀粉中四糖以上比例85-100％，三糖0-15％，双糖0-10％，单糖0-5.0％。Weigh 200g of C.I. Acid Red 114 (300%), 200g of enzyme-catalyzed hydrolyzed starch, and 1.2g of benzoic acid, and mix them uniformly to obtain 401.2g of a high-performance acid dye composition. The dye composition is used for dyeing Taslon (Taslon) fiber, which can achieve 100% exhaustion rate and excellent fastness performance. The ratio of four or more sugars in the enzyme-catalyzed hydrolyzed starch is 85-100%, trisaccharides are 0-15%, disaccharides are 0-10%, and monosaccharides are 0-5.0%.
例11~20。Example 11~20.
在例11~20中，各组分的重量百分比如下表所示：In example 11～20, the percentage by weight of each component is as shown in the table below:
实施例3Example 3
称取200gC.I.酸性红114及40g酸性红361原染料，60g酶催化水解淀粉，0.9g苯甲酸，混合均匀，就得到300.9g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。酶催化水解淀粉中四糖以上比例80-100％，三糖0-20％，双糖0-15％，单糖0-1.0％；单糖间以1，4、1，6糖苷键形成多糖Weigh 200g C.I. Acid Red 114, 40g Acid Red 361 raw dye, 60g enzyme-catalyzed hydrolyzed starch, 0.9g benzoic acid, and mix evenly to obtain 300.9g high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance. Enzyme-catalyzed hydrolysis of starch with the proportion of tetrasaccharides and above 80-100%, trisaccharides 0-20%, disaccharides 0-15%, monosaccharides 0-1.0%; monosaccharides form polysaccharides with 1, 4, 1, 6 glycosidic bonds
例21~30。Example 21~30.
在例21~30中，各组分的重量百分比如下表所示：In example 21～30, the percentage by weight of each component is as shown in the table below:
实施例4Example 4
称取200gC.I.酸性蓝230(200％)，100g水溶性淀粉，1g苯甲酸，混合均匀，就得到301g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。Weigh 200g of C.I. Acid Blue 230 (200%), 100g of water-soluble starch, and 1g of benzoic acid, and mix them uniformly to obtain 301g of a high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance.
实施例5Example 5
称取200gC.I.酸性蓝225(200％)及20gC.I.酸性紫48，100g酶催化水解淀粉，1g苯甲酸，混合均匀，就得到321g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。酶催化水解淀粉中四糖以上比例75-100％，三糖0-20％，双糖0-10％，单糖0-2.0％。Weigh 200g of C.I. Acid Blue 225 (200%) and 20g of C.I. Acid Violet 48, 100g of enzyme-catalyzed hydrolyzed starch, 1g of benzoic acid, and mix evenly to obtain 321g of a high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance. The enzyme-catalyzed hydrolyzed starch contains 75-100% of tetrasaccharides and above, 0-20% of trisaccharides, 0-10% of disaccharides, and 0-2.0% of monosaccharides.
实施例6Example 6
称取200gC.I.酸性蓝277(200％)，50g羧甲基菊粉，1g苯甲酸，混合均匀，就得到251g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。Weigh 200g of C.I. acid blue 277 (200%), 50g of carboxymethyl inulin, and 1g of benzoic acid, and mix them uniformly to obtain 251g of a high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance.
实施例7Example 7
称取200gC.I.酸性蓝350(200％)，100g菊粉，1g苯甲酸，混合均匀，就得到301g高性能酸性染料组合物。将该染料组合物用于聚酰胺纤维的染色，可达到100％的竭染率，优良的牢度性能。Weigh 200g of C.I. Acid Blue 350 (200%), 100g of inulin, and 1g of benzoic acid, and mix them uniformly to obtain 301g of a high-performance acid dye composition. When the dye composition is used for dyeing polyamide fibers, it can achieve 100% exhaustion rate and excellent fastness performance.
例31~40。Example 31~40.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006102000355A CN100384945C (en) | 2006-01-16 | 2006-01-16 | A kind of acid dye composition |
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| CN1032958A (en) * | 1987-10-31 | 1989-05-17 | 新华皮革化工厂 | Resin type pigment paste for leather processing |
| JP2002104942A (en) * | 2000-09-22 | 2002-04-10 | Kaminomoto Co Ltd | Acidic hair dye composition |
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