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CN1098910C - Thermal-cracking decoking biomass gasification furnace - Google Patents

Thermal-cracking decoking biomass gasification furnace Download PDF

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CN1098910C
CN1098910C CN00101428A CN00101428A CN1098910C CN 1098910 C CN1098910 C CN 1098910C CN 00101428 A CN00101428 A CN 00101428A CN 00101428 A CN00101428 A CN 00101428A CN 1098910 C CN1098910 C CN 1098910C
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furnace
gas
cracking
pipe
wall
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CN1303905A (en
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朱锡锋
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University of Science and Technology of China USTC
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Abstract

本发明涉及农作物废弃物处理利用及由固态含碳物料生产燃气的设备制造。它包括现有固定床下吸式气化炉的炉体、炉排,上料口、配风口、排渣口、燃气出口等,其特征在于炉排下方设有设置有一个燃气气流迂回流道。也能够在炉底上增设裂解催化床,本发明强迫燃气流在流道中缓行,延长了燃气在高温环境中的停留时间,使燃气中的部分焦油被裂解。在设置催化床的情形下,其裂解反应更为充分,进一步提高了焦油裂解率、气化效率和燃气热值。

Figure 00101428

The invention relates to the processing and utilization of agricultural waste and the manufacture of equipment for producing gas from solid carbonaceous materials. It includes a furnace body, a fire grate, a feed port, an air distribution port, a slag discharge port, a gas outlet, etc. of an existing fixed-bed downdraft gasifier. It is also possible to add a cracking catalytic bed on the bottom of the furnace. The invention forces the gas flow to slow down in the flow channel, prolongs the residence time of the gas in the high-temperature environment, and cracks part of the tar in the gas. In the case of setting the catalytic bed, the cracking reaction is more sufficient, further improving the tar cracking rate, gasification efficiency and gas calorific value.

Figure 00101428

Description

热裂解除焦生物质气化炉Thermal cracking decoking biomass gasifier

本发明涉及农作物的废弃物的处理利用技术,也涉及由固态含碳物料生产燃气的设备制造。The invention relates to the treatment and utilization technology of the waste of crops, and also relates to the manufacture of equipment for producing gas from solid carbonaceous materials.

生物质气化是利用气化装置将生物质在缺氧状态下进行燃烧,使大部分可燃烧物质转化为可燃气体,经冷却净化后供发电或炊事用。根据燃烧方式的不同,气化装置有多种形式,现有技术中最为常见的是固定床下吸式气化炉,其具有结构简单、造价低廉、容易操作等特点,很适合我国国情,尤其适合我国农村用以处理农作物废弃物,例如秸杆、稻壳、树枝、杂草等。但由于这种气化炉本身结构上的制约,其气化效率及燃气热值均偏低,而且燃气中的焦油含量偏高。这种燃气不利于储存和输送,从而影响了该技术的进一步利用。Biomass gasification is to use a gasification device to burn biomass in an oxygen-deficient state, so that most of the combustible substances are converted into combustible gases, which are cooled and purified for power generation or cooking. According to different combustion methods, there are many types of gasification devices. The most common one in the prior art is the fixed bed downdraft gasifier, which has the characteristics of simple structure, low cost, and easy operation. It is very suitable for my country's national conditions, especially for In rural areas of our country, it is used to deal with crop waste, such as straw, rice husk, branches, weeds, etc. However, due to the structural constraints of the gasifier itself, its gasification efficiency and gas calorific value are both low, and the tar content in the gas is high. This gas is not conducive to storage and transportation, thereby affecting the further utilization of this technology.

本发明的目的在于,对现有的固定床下吸式气化炉的结构作出改进,提供一种能提高气化效率和燃气热值,并能对产出燃气中的焦油进行裂解的生物质气化炉。The purpose of the present invention is to improve the structure of the existing fixed-bed downdraft gasifier, to provide a biomass gas that can improve the gasification efficiency and the calorific value of the gas, and can crack the tar in the output gas Furnace.

本发明的目的通过以下方式来实现。The purpose of the present invention is achieved in the following ways.

本发明的热裂解除焦生物质气化炉,包括现有技术中的固定床下吸式气化炉的炉体、炉排,以及设置在炉壁上的上料口、配风口、排渣口、燃气出口,其特征在于,在炉排下方设置有一个燃气气流迂回流道。该迂回流道能够这样构成:在炉排下方连接有一倒锥管形挡板,其底与炉壁连接,其下端口连接有一段直管,在炉底板上还设置有一个大圆管,该管口低于直管上端口,直管内、直管外壁与大圆管之间、大圆管外壁与炉壁之间三者的截面积相等或相近,在大圆管壁上接装有排渣管并延伸到炉壁外,燃气出口设置在炉体下部。也能够在炉底上设置裂解催化反应床,它由块状或颗粒状催化剂及其盖板构成,所述盖板上表面与大圆管下端口连接,在大圆管外壁与炉壁间的盖板上设有用作燃气流道的通孔,燃气出口设置在催化反应床段的炉壁上,所述催化剂是常用的热裂解催化剂,例如颗粒状的白云石、氧化铁、活性碳等。The thermal cracking and decoking biomass gasification furnace of the present invention includes the furnace body and fire grate of the fixed bed downdraft gasification furnace in the prior art, and the feeding port, air distribution port and slag discharge port arranged on the furnace wall . The gas outlet is characterized in that a detour of gas flow is provided under the fire grate. The roundabout flow channel can be constructed as follows: an inverted cone tubular baffle is connected under the grate, its bottom is connected to the furnace wall, a section of straight pipe is connected to its lower port, and a large round pipe is arranged on the furnace floor. The mouth is lower than the upper port of the straight pipe, and the cross-sectional areas of the inside of the straight pipe, between the outer wall of the straight pipe and the large circular pipe, and between the outer wall of the large circular pipe and the furnace wall are equal or similar. A slag discharge pipe is installed on the wall of the large circular pipe and extends To the outside of the furnace wall, the gas outlet is arranged at the lower part of the furnace body. It is also possible to set a cracking catalytic reaction bed on the bottom of the furnace, which is composed of a block or granular catalyst and a cover plate thereof. There are through holes used as gas flow passages on the top, and the gas outlet is set on the furnace wall of the catalytic reaction bed section. The catalyst is a commonly used thermal cracking catalyst, such as granular dolomite, iron oxide, activated carbon, etc.

本发明的热裂解除焦生物质气化炉,一方面保存了现有技术中的固定床下吸式气化炉的结构简单、造价较低等特点,同时由于增设了燃气气流迂回流道,强迫燃气气流在流道中缓行,延迟了气流在炉内的停留时间,使所产生的燃气在高温环境下产生热裂解反应,燃气中的部分焦油被裂解。在设置催化反应床的情形下,由于催化剂的作用,其裂解反应更为充分,进一步提了焦油裂解率、气化效率和燃气热值。The thermal cracking and decoking biomass gasification furnace of the present invention, on the one hand, retains the characteristics of the fixed bed downdraft gasification furnace in the prior art, such as simple structure and low cost; The gas flow slows down in the flow channel, delaying the residence time of the gas flow in the furnace, causing the generated gas to undergo thermal cracking reaction in a high-temperature environment, and part of the tar in the gas is cracked. In the case of setting a catalytic reaction bed, due to the action of the catalyst, the cracking reaction is more sufficient, further improving the tar cracking rate, gasification efficiency and gas calorific value.

下面结合实施例及其附图作进一步描述。Further description will be made below in conjunction with the embodiments and accompanying drawings.

图1是现有技术中的固定床下吸式气化炉的整体结构示意图。Fig. 1 is a schematic diagram of the overall structure of a fixed-bed downdraft gasifier in the prior art.

图2是本发明所述的热裂解除焦生物质气化炉的一种实施例整体结构示意图。Fig. 2 is a schematic diagram of the overall structure of an embodiment of the thermal cracking and decoking biomass gasifier according to the present invention.

图3是本发明所述的热裂解除焦生物质气化炉的另一种实施例整体结构示意图。Fig. 3 is a schematic diagram of the overall structure of another embodiment of the thermal cracking and decoking biomass gasifier according to the present invention.

参见图1,(1)为炉体,(2)为炉排,该炉排将炉膛分为上下两部分,(3)为配风口,(4)为进料口,(5)一次排渣口,(6)为二次排渣口。(7)为燃气出口。从图可看出,农作物废料在上炉膛内不完全燃烧产生的气体直接由设在燃气出口处的抽风机吸出,其流道行程较短,燃气在炉膛内停留的时间较少,来不及发生裂解反应,因此,其焦油含量较高。See Figure 1, (1) is the furnace body, (2) is the fire grate, which divides the furnace into upper and lower parts, (3) is the air distribution port, (4) is the feed port, and (5) is one-time slag discharge Port, (6) is the secondary slag discharge port. (7) is gas outlet. It can be seen from the figure that the gas generated by the incomplete combustion of crop waste in the upper furnace is directly sucked out by the exhaust fan installed at the gas outlet. The flow path stroke is short, and the gas stays in the furnace for a short time, so there is no time for cracking The reaction, therefore, has a higher tar content.

参见图2,本实施例在炉排下方设置了燃气气流迂回流道,倒锥形管(8)设置在炉排下方,其锥底角约为45°左右,该管上底与炉壁连接,下端口连接有一段直管(9),(10)为设在炉底上的大圆管,该管上管口低于直管的上端。倒锥形管(8)及直管(9)的高度分别占下炉膛高度的1/3,直管内、大圆管内壁至直管外壁间距、大圆管外壁至炉内壁间三者的截面积大致相等,以保证燃气流动畅通。燃气出口被设置在炉壁下方,可增加燃气行程。图中箭头表示燃气在炉膛内的流动方向。由此可看出,燃气被迫在下炉膛内沿迂回流动缓行,直至从出口(7)被抽风机抽出送至冷却净化装置。相比现有技术,本实施例的装置延长了燃气在高温环境中的停留时间,能保证发生裂解反应,减少重分子焦油含量,提高了气化效率。Referring to Fig. 2, in this embodiment, a roundabout flow channel for gas flow is provided under the fire grate, and an inverted conical tube (8) is arranged under the fire grate, and the bottom angle of the cone is about 45°, and the upper bottom of the tube is connected to the furnace wall , the lower port is connected with a section of straight pipe (9), and (10) is a large round pipe located on the bottom of the furnace, and the upper end of the tube is lower than the upper end of the straight pipe. The heights of the inverted tapered pipe (8) and the straight pipe (9) respectively account for 1/3 of the height of the lower furnace, and the cross-sectional areas of the inside of the straight pipe, the distance from the inner wall of the large circular pipe to the outer wall of the straight pipe, and the distance between the outer wall of the large circular pipe and the inner wall of the furnace are approximately equal to ensure smooth flow of gas. The gas outlet is set under the furnace wall, which can increase the gas stroke. The arrows in the figure indicate the flow direction of gas in the furnace. It can be seen from this that the gas is forced to slowly travel along the circuitous flow in the lower furnace until it is drawn out by the exhaust fan from the outlet (7) and sent to the cooling and purification device. Compared with the prior art, the device of this embodiment prolongs the residence time of the gas in the high-temperature environment, ensures the cracking reaction, reduces the content of heavy molecular tar, and improves the gasification efficiency.

实验表明,使用本结构的气化炉处理农作物废弃物,所产燃气中的焦油能够裂解60%。相比现有技术中的固定床下吸式气化炉,其气化效率提高12%,燃气热值提高15%。Experiments show that the tar in the produced gas can be cracked by 60% by using the gasifier with this structure to treat crop waste. Compared with the fixed-bed downdraft gasifier in the prior art, the gasification efficiency is increased by 12%, and the calorific value of the gas is increased by 15%.

参见图3,本实施例是在炉底上增设了充满催化剂的催化反应床,(11)为颗粒状催化剂,颗粒直径约为1-3cm,如颗粒状白云石。(12)为盖板,大圆管固定在该盖板上,使催化反应床与大圆管内腔分隔开。在大圆管与炉壁间的盖板上均匀分布有通孔,用作燃气流通道。炉底至盖板间的高度约占下炉膛高度的2/5。倒锥形管(8)及直管(9)的高度分别占下炉膛其余高度的1/3,直管及大圆管的径向尺寸与上一实施例相同,以保证燃气流动畅通。从燃气出口接装有一出气管(13),它伸入在颗粒催化剂中间部分,将与催化剂充分反应后的燃气抽吸出炉体。Referring to Fig. 3, present embodiment is to set up the catalytic reaction bed that is full of catalyst on the hearth, (11) is granular catalyst, and particle diameter is about 1-3cm, as granular dolomite. (12) is a cover plate, and the large circular tube is fixed on the cover plate, so that the catalytic reaction bed is separated from the large circular tube inner cavity. Through holes are evenly distributed on the cover plate between the large round tube and the furnace wall, which are used as gas flow channels. The height between the bottom of the furnace and the cover plate accounts for about 2/5 of the height of the lower furnace. The height of the inverted tapered pipe (8) and the straight pipe (9) accounts for 1/3 of the remaining height of the lower furnace respectively, and the radial dimensions of the straight pipe and the large circular pipe are the same as those of the previous embodiment to ensure the smooth flow of gas. A gas outlet pipe (13) is connected from the gas outlet, and it stretches into the middle part of the particle catalyst, and the gas that has fully reacted with the catalyst is sucked out of the furnace body.

本实施例中,不仅增加了合理的气流流道,而且还使已在下炉膛内迂回流动的燃气从大圆管外壁的空间吸入到催化反应床中,在催化剂的作用下,燃气中的焦油充分发生裂解反应后再被抽出,因此输出燃气中焦油含量低,热值高。实验表明,使用本结构的气化炉处理农作物废弃物,所产燃气中焦油能够裂解60%。相比现有技术中的固定床下吸式气化炉,其气化效率能提高15%,燃气热值提高20%。In this embodiment, not only a reasonable air flow channel is added, but also the gas that has been flowing in a circuitous manner in the lower furnace is sucked into the catalytic reaction bed from the space on the outer wall of the large circular tube. Under the action of the catalyst, the tar in the gas is fully produced. After the cracking reaction, it is pumped out, so the tar content in the output gas is low and the calorific value is high. Experiments show that when the gasification furnace with this structure is used to treat crop wastes, 60% of the tar in the produced gas can be cracked. Compared with the fixed-bed downdraft gasifier in the prior art, the gasification efficiency can be increased by 15%, and the calorific value of the gas can be increased by 20%.

Claims (2)

1. thermal-cracking decoking biomass gasification furnace, the body of heater that comprises fixed bed downdraft vapourizing furnace of the prior art, fire grate, and be arranged on feeding port on the furnace wall, air distribution outlet, slag-drip opening, gas outlet, it is characterized in that, below fire grate, be provided with the circuitous runner of a fuel gas flow, the circuitous runner of this fuel gas flow constitutes like this: be connected with a tubular baffle plate of back taper below fire grate, its end, be connected with the furnace wall, its lower port is connected with straight-run of pipe, on drop-bottom, also be provided with a big pipe, this mouth of pipe is lower than the straight tube upper end, in the straight tube, between straight tube outer wall and big pipe, big circular tube external wall equates with twere three's sectional area or is close, tipping has scum pipe and extends to outside the furnace wall on the great circle tube wall, and gas outlet is arranged on the body of heater bottom.
2. thermal-cracking decoking biomass gasification furnace as claimed in claim 1, it is characterized in that, the cracking and catalyzing reaction bed also is set on furnace bottom, it is made of pellet type catalyst and cover plate thereof, described cover plate upper surface is connected with the great circle infratubal port, be provided with the through hole as the combustion gas runner on the cover plate of big pipe and twere, gas outlet is arranged on the furnace wall of catalytic bed section, and described catalyzer is the thermal cracking catalyst of using always.
CN00101428A 2000-01-12 2000-01-12 Thermal-cracking decoking biomass gasification furnace Expired - Fee Related CN1098910C (en)

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JP4312632B2 (en) * 2004-03-03 2009-08-12 中外炉工業株式会社 Biomass gasification system and operation method thereof
CN1301789C (en) * 2005-02-25 2007-02-28 许庆华 Biomass gasification catalyst and its production method
CN101592344B (en) * 2008-05-26 2011-06-01 周德国 Biomass energy heating device
CN101338204B (en) * 2008-08-18 2011-08-03 北京乡电电力有限公司 Integration biomass gasification stove catalytic splitting process and device thereof
CN101407722B (en) * 2008-10-10 2011-11-09 哈尔滨工业大学 Biomass high temperature pyrolysis and gasification and high temperature pyrolysis gas catalytic purification process
CN101768452B (en) * 2009-02-23 2013-03-13 深圳市兖能环保科技有限公司 System for making coal gas and/or activated carbon with sorted garbage as raw material, and device and method thereof
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CN104178188A (en) * 2014-08-08 2014-12-03 南京理工大学 Method for reducing pyrolysis activation energy of rice hulls
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