CN109825385B - Toilet bowl deodorizing soap ball prepared from citrus peel residues - Google Patents
Toilet bowl deodorizing soap ball prepared from citrus peel residues Download PDFInfo
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- CN109825385B CN109825385B CN201811630651.3A CN201811630651A CN109825385B CN 109825385 B CN109825385 B CN 109825385B CN 201811630651 A CN201811630651 A CN 201811630651A CN 109825385 B CN109825385 B CN 109825385B
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- 239000000344 soap Substances 0.000 title claims abstract description 46
- 241000207199 Citrus Species 0.000 title claims abstract description 36
- 235000020971 citrus fruits Nutrition 0.000 title claims abstract description 36
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000000203 mixture Substances 0.000 claims abstract description 30
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004327 boric acid Substances 0.000 claims abstract description 19
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008188 pellet Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- 235000011187 glycerol Nutrition 0.000 claims description 18
- 238000004332 deodorization Methods 0.000 claims description 5
- 239000002781 deodorant agent Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 6
- 241000723346 Cinnamomum camphora Species 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- 229960000846 camphor Drugs 0.000 description 6
- 229930008380 camphor Natural products 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 210000002700 urine Anatomy 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010773 plant oil Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- VHLJDTBGULNCGF-UHFFFAOYSA-N Limonin Natural products CC1(C)OC2CC(=O)OCC23C4CCC5(C)C(CC(=O)C6OC56C4(C)C(=O)CC13)c7cocc7 VHLJDTBGULNCGF-UHFFFAOYSA-N 0.000 description 1
- 206010070863 Toxicity to various agents Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- -1 aromatic terpenoid Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000005619 boric acid group Chemical group 0.000 description 1
- PEEKVIHQOHJITP-UHFFFAOYSA-N boric acid;propane-1,2,3-triol Chemical compound OB(O)O.OCC(O)CO PEEKVIHQOHJITP-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- KBDSLGBFQAGHBE-MSGMIQHVSA-N limonin Chemical compound C=1([C@H]2[C@]3(C)CC[C@H]4[C@@]([C@@]53O[C@@H]5C(=O)O2)(C)C(=O)C[C@@H]2[C@]34COC(=O)C[C@@H]3OC2(C)C)C=COC=1 KBDSLGBFQAGHBE-MSGMIQHVSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000015205 orange juice Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a toilet bowl deodorizing soap pellet prepared from citrus peel residues, which is prepared from the following components in parts by weight: 100 parts of fresh orange peel residues, 0.08-0.12 part of isothiazolinone, 3-4 parts of glycerol, 2.2-3.2 parts of boric acid and 20-25 parts of soap base; wherein, fresh orange peel residue is firstly crushed into particles with the particle size less than 0.4 mm; adding the isothiazolinone into the isothiazolinone, and uniformly stirring to obtain a first mixture; adding glycerol and boric acid into the first mixture, and uniformly stirring to obtain a second mixture; heating soap base in water bath to 58 deg.C for melting; adding the second mixture into the melted soap base, and uniformly stirring to obtain a third mixture; quickly pouring the third mixture into a mold, compacting, strickling, cooling and demolding to obtain the material; the invention has simple component proportion, easily obtained raw materials, low cost, easy popularization and effective removal of peculiar smell, is an innovation on the toilet bowl deodorant and has obvious economic and social benefits.
Description
Technical Field
The invention relates to a sanitary product, in particular to a toilet bowl deodorizing soap pellet prepared from citrus peel residues.
Background
At present, most of domestic wall-mounted urinals in public toilets generally adopt camphor balls to remove peculiar smell, the camphor balls are chemically synthesized camphor, contain p-dichlorobenzene and naphthalene, have strong volatility, cover the peculiar smell only through the smell, but do not really degrade and eliminate the peculiar smell such as ammonia gas, hydrogen sulfide and the like, and in addition, the camphor balls can cause the toxic symptoms of human bodies, such as lassitude, dizziness, headache, diarrhea and the like. Camphor balls containing p-dichlorobenzene and naphthalene belong to pesticide products, are generally used for mothproofing of industrial products or agricultural products, and are not suitable for living goods. A large number of practices prove that naphthalene and benzene substances have great harmfulness to human health. Therefore, the world health organization has identified it as a strong potential carcinogen, and therefore, improvements and innovations in toilet bowl deodorizers are imperative.
China is a large country for producing oranges, the produced oranges mainly take fresh foods as main materials, and the industrial processing amount of the oranges is increased rapidly along with the rapid increase of the yield. It is estimated that can obtain about 50% % of citrus peel residue from juice press production during industrial citrus processing, and 25% % of citrus peel from can processing. The peel residues contain abundant pectin, essential oil, unique aromatic terpenoid, limonin, pigment and other byproducts with higher economic value, so the processing and comprehensive utilization potential of the citrus peel residues is huge. However, according to statistics, the comprehensive utilization rate of the citrus peel residues in China is only over ten percent. The fresh citrus peel dregs are rich in volatile aromatic substances, so that the fresh citrus peel dregs have faint scent and pleasant smell and also have acidic chemical properties, so that how to prepare the urinal deodorant by using the citrus peel dregs is very necessary, but no public report is found so far.
Disclosure of Invention
In view of the above situation, in order to overcome the defects of the prior art, the invention aims to provide the toilet bowl deodorizing soap ball prepared from the citrus peel residues, which can effectively solve the problems that the existing camphor ball deodorant harms human health and improves the utilization rate of the citrus peel residues.
The technical scheme for solving the problem is that the toilet bowl deodorizing soap pellets prepared from citrus peel residues are prepared from the following components in parts by weight: 100 parts of fresh orange peel residues, 0.08-0.12 part of isothiazolinone, 3-4 parts of glycerol, 2.2-3.2 parts of boric acid and 20-25 parts of soap base; wherein, fresh orange peel residue is firstly crushed into particles with the particle size less than 0.4 mm; adding isothiazolinone, and stirring uniformly to obtain a first mixture; adding glycerol and boric acid into the first mixture, and uniformly stirring to obtain a second mixture; heating soap base in water bath to 58 deg.C for melting; adding the second mixture into the melted soap base, and uniformly stirring to obtain a third mixture; and quickly pouring the third mixture into a mold, compacting, strickling, cooling and demolding to obtain the product.
The invention has simple component proportion, easily obtained raw materials, low cost, easy popularization, comprehensive utilization of orange juice leftover waste, normal pressure production process, no three-waste discharge, pollution-free product, environmental protection, good use effect, slow-release sterilization effect, acid system and natural orange fragrance, can inhibit the fermentation and decomposition of urea and other substances in urine, neutralize ammonia gas, absorb hydrogen sulfide and effectively remove peculiar smell, is an innovation of toilet urinal deodorant, and has obvious economic and social benefits.
Detailed Description
The following detailed description of the embodiments of the present invention will be given with reference to the accompanying specific cases and examples.
Example 1: the invention relates to a toilet bowl deodorization soap pellet prepared from citrus peel residues, which is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.09-0.11 part of isothiazolinone, 3.2-3.8 parts of glycerol, 2.5-3.0 parts of boric acid and 22-24 parts of soap base; wherein, fresh orange peel residue is firstly crushed into particles with the particle size less than 0.4 mm; adding isothiazolinone, and stirring uniformly to obtain a first mixture; adding glycerol and boric acid into the first mixture, and uniformly stirring to obtain a second mixture; heating soap base in water bath to 58 deg.C for melting; adding the second mixture into the melted soap base, and uniformly stirring to obtain a third mixture; and quickly pouring the third mixture into a mold, compacting, strickling, cooling and demolding to obtain the product.
Example 2: the invention relates to a toilet bowl deodorization soap pellet prepared from citrus peel residues, which is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.08 part of isothiazolinone, 3 parts of glycerol, 2.2 parts of boric acid and 20 parts of soap base; the preparation method is the same as example 1.
Example 3: the invention relates to a toilet bowl deodorization soap pellet prepared from citrus peel residues, which is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.12 part of isothiazolinone, 4 parts of glycerol, 3.2 parts of boric acid and 25 parts of soap base; the preparation method is the same as example 1.
Example 4: the invention relates to a toilet bowl deodorization soap pellet prepared from citrus peel residues, which is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.1 part of isothiazolinone, 3.5 parts of glycerol, 2.7 parts of boric acid and 23 parts of soap base; the preparation method is the same as example 1.
The soap base is a commercial product, such as a plant soap base prepared and sold by Shenzhen Shanghai daily chemical products Limited company, and the Ba Sha transparent soap base is prepared by taking pure natural refined plant oil as a main raw material and mixing the pure natural refined plant oil with glycerol, fatty acid and other raw materials, and has the characteristics of high transparency, high moisture retention, high stability, abundant foam and the like.
The invention has the following action principle: the fresh citrus peel residues are rich in volatile aromatic substances, have faint scent and pleasant smell, the pH value is 3.2-4.5, an acidic system is favorable for cleaning the surface of a urinal and neutralizing ammonia gas, and the crushed fresh citrus peel residues have large surface area and strong adsorbability; isothiazolinone is added to play a role in inhibiting and killing bacteria of fresh orange peel residues and integral products; the action of glycerol and boric acid forms a boric acid complex (glycerol boric acid) to enhance the acidity of boric acid, so that the pH value can be continuously adjusted, and the glycerol also has an adsorption effect on hydrogen sulfide. Under the combined action of isothiazolinone, boric acid and glycerin, urea in urine can be inhibited from being fermented and decomposed, ammonia gas can be neutralized, hydrogen sulfide can be absorbed, and pleasant fragrance contained in citrus peel residues can be maintained. Adding soap base to wrap and mix the materials for molding, so that the orange peel residue is kept fresh, the slow dissolution and release of effective components are facilitated, and the fragrance is lasting.
When the soap ball is used specifically, a plurality of soap ball particles are directly placed at the bottom of a wall-mounted urinal, urine is filtered and washed by tap water, and when the soap ball is about to be used up, a new soap ball is placed again.
The application effect of the invention is very good after trial, and the related experimental data are as follows:
selecting 4 unused wall-mounted urinals, wherein the numbers of the wall-mounted urinals are 1, 2, 3 and 4 respectively, placing products prepared in the embodiments of the invention, 2, 3 and 4 at the bottoms of the wall-mounted urinals of No. 1, 2 and 3 respectively, and then putting the wall-mounted urinals into use (when the consumption of the soap pellets is over, replacing new soap pellets); no. 4 hanging urinal does not do the processing, and the input is used, and after 2 months, the pH value and the sense organ of each hanging urinal experience see the following table:
in the materials used in the invention, isothiazolinone is a broad-spectrum, high-efficiency, low-toxicity and non-oxidative bactericide, has no volatility, has a very small to negligible content, and does not affect water. The other components are flushed with tap water, and the dissolved citrus peel dregs, dissolved boric acid, glycerin and soap base belong to nontoxic and pollution-free substances, have very small concentration content, are in a safe discharge range, and do not influence the ecological environment. The particle size of the fragments of the citrus peel residues is small and the fragments are slowly released, so that the circulation of a pipeline is not influenced.
The urinal deodorizing soap pellets prepared from the orange peel residues have a slow-release sterilization effect, an acidic system and natural orange fragrance, can inhibit the fermentation and decomposition of substances such as urea in urine, neutralize ammonia gas, absorb hydrogen sulfide and effectively remove peculiar smell, are prepared under normal pressure, do not discharge three wastes, are pollution-free, and are beneficial to environmental protection. The invention has simple and effective component proportion and simple preparation method, comprehensively utilizes orange juicing leftover waste, has easily obtained raw materials, low cost and easy popularization, is an innovation of the urinal deodorant and has obvious economic and social benefits.
Claims (5)
1. A urinal deodorization soap ball prepared by using citrus peel residues is characterized in that: the composition is prepared from the following components in parts by weight: 100 parts of fresh orange peel residues, 0.08-0.12 part of isothiazolinone, 3-4 parts of glycerol, 2.2-3.2 parts of boric acid and 20-25 parts of soap base; wherein, fresh orange peel residue is firstly crushed into particles with the particle size less than 0.4 mm; adding isothiazolinone, and stirring uniformly to obtain a first mixture; adding glycerol and boric acid into the first mixture, and uniformly stirring to obtain a second mixture; heating soap base in water bath to 58 deg.C for melting; adding the second mixture into the melted soap base, and uniformly stirring to obtain a third mixture; and quickly pouring the third mixture into a mold, compacting, strickling, cooling and demolding to obtain the product.
2. The toilet bowl deodorizing soap pellet prepared from citrus peel residues according to claim 1, wherein: the composition is prepared from the following components in parts by weight: 100 portions of fresh orange peel dregs, 0.09-0.11 portion of isothiazolinone, 3.2-3.8 portions of glycerin, 2.5-3.0 portions of boric acid and 22-24 portions of soap base.
3. The toilet bowl deodorizing soap pellet prepared from citrus peel residues according to claim 1, wherein: the composition is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.08 part of isothiazolinone, 3 parts of glycerol, 2.2 parts of boric acid and 20 parts of soap base.
4. The toilet bowl deodorizing soap pellet prepared from citrus peel residues according to claim 1, wherein: the composition is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.12 part of isothiazolinone, 4 parts of glycerol, 3.2 parts of boric acid and 25 parts of soap base.
5. The toilet bowl deodorizing soap pellet prepared from citrus peel residues according to claim 1, wherein: the composition is prepared from the following components in parts by weight: 100 parts of fresh citrus peel residues, 0.1 part of isothiazolinone, 3.5 parts of glycerol, 2.7 parts of boric acid and 23 parts of soap base.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811630651.3A CN109825385B (en) | 2018-12-29 | 2018-12-29 | Toilet bowl deodorizing soap ball prepared from citrus peel residues |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811630651.3A CN109825385B (en) | 2018-12-29 | 2018-12-29 | Toilet bowl deodorizing soap ball prepared from citrus peel residues |
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| Publication Number | Publication Date |
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| CN109825385A CN109825385A (en) | 2019-05-31 |
| CN109825385B true CN109825385B (en) | 2021-02-05 |
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| CN201811630651.3A Expired - Fee Related CN109825385B (en) | 2018-12-29 | 2018-12-29 | Toilet bowl deodorizing soap ball prepared from citrus peel residues |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110484375A (en) * | 2019-09-07 | 2019-11-22 | 阜阳洁平日化有限公司 | One kind is high performance to be quantitatively sustained bottled detergent for toilet and preparation method thereof |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1009113B (en) * | 1986-06-06 | 1990-08-08 | 西北大学 | Preparation method of solid anti-scaling deodorant for urinal |
| CN1064620A (en) * | 1991-03-05 | 1992-09-23 | 李怀桔 | Deodorant for toilet |
| CN1095408A (en) * | 1993-05-18 | 1994-11-23 | 韦户民 | Efficient cleaning agent |
| CN1127524A (en) * | 1993-07-23 | 1996-07-24 | 尤尼剑马化学股份有限公司 | Process for producing transparent soap material |
| CN1124284A (en) * | 1994-09-30 | 1996-06-12 | 王翔 | Producing method for solid multifunctional cleaning agent |
| CN1055250C (en) * | 1995-06-27 | 2000-08-09 | 张兴权 | Deodorant agent |
| CN1141199A (en) * | 1995-07-27 | 1997-01-29 | 福州大学 | Deodorant and method for preparing same |
| GB2364709B (en) * | 2000-07-12 | 2004-12-22 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system and method |
| CN1958078A (en) * | 2005-11-03 | 2007-05-09 | 黄素芳 | Multi purpose fresh deodorizer |
| CN101239194B (en) * | 2008-03-17 | 2012-11-28 | 张博 | Deodorizing sterilizing foamed liquid for water closet |
| CN101672790A (en) * | 2009-10-13 | 2010-03-17 | 北京化工大学 | Quick detecting tube for micro-hydrogen sulfide gas |
| CN101691530A (en) * | 2009-10-23 | 2010-04-07 | 贝欧泰科技(苏州)有限公司 | Microbial deodorant soap for cleaning urinal and preparation method thereof |
| US20140286890A1 (en) * | 2011-11-06 | 2014-09-25 | Nbip, Llc | Compositions and methods for eradication of odors |
| CN103656723A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Antibiotic deodorant for closestool |
| CN104307019A (en) * | 2014-10-30 | 2015-01-28 | 上海今拓环保设备工程有限公司 | Plant extract deodorizer for removing harmful gases |
| CN107773776A (en) * | 2016-08-25 | 2018-03-09 | 赖婷婷 | Use in toilet eliminating smell agent and preparation method thereof |
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