CN109553836A - A kind of environmental protection portable rubber sole and its manufacture craft - Google Patents
A kind of environmental protection portable rubber sole and its manufacture craft Download PDFInfo
- Publication number
- CN109553836A CN109553836A CN201811167259.XA CN201811167259A CN109553836A CN 109553836 A CN109553836 A CN 109553836A CN 201811167259 A CN201811167259 A CN 201811167259A CN 109553836 A CN109553836 A CN 109553836A
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- China
- Prior art keywords
- rubber
- environmental protection
- corn flour
- protection portable
- sulphur
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- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 33
- 239000005060 rubber Substances 0.000 title claims abstract description 33
- 230000007613 environmental effect Effects 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 15
- 240000008042 Zea mays Species 0.000 claims abstract description 14
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 14
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 14
- 235000005822 corn Nutrition 0.000 claims abstract description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005864 Sulphur Substances 0.000 claims abstract description 13
- 235000013312 flour Nutrition 0.000 claims abstract description 13
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 10
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 10
- REQPQFUJGGOFQL-UHFFFAOYSA-N dimethylcarbamothioyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SC(=S)N(C)C REQPQFUJGGOFQL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 10
- 229920001194 natural rubber Polymers 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims abstract description 9
- 229920003051 synthetic elastomer Polymers 0.000 claims abstract description 9
- 239000005061 synthetic rubber Substances 0.000 claims abstract description 9
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910000010 zinc carbonate Inorganic materials 0.000 claims abstract description 8
- 235000004416 zinc carbonate Nutrition 0.000 claims abstract description 8
- 239000011667 zinc carbonate Substances 0.000 claims abstract description 8
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 229920006335 epoxy glue Polymers 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 4
- 239000004700 high-density polyethylene Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000003723 Smelting Methods 0.000 claims description 3
- 235000009508 confectionery Nutrition 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 3
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 239000004113 Sepiolite Substances 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 229920005555 halobutyl Polymers 0.000 claims description 2
- 125000004968 halobutyl group Chemical group 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052624 sepiolite Inorganic materials 0.000 claims description 2
- 235000019355 sepiolite Nutrition 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 239000002210 silicon-based material Substances 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims 2
- 230000000704 physical effect Effects 0.000 abstract description 5
- 230000006978 adaptation Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of environmental protection portable rubber soles, including natural rubber, synthetic rubber 1502#, cis-butadiene cement, sulphur, M, DM, TMTM, zinc carbonate, stearic acid, anti-aging agent TSD, white carbon black, diethylene glycol (DEG), white oil, carapace powder and corn flour.The invention also discloses the manufacture crafts of above-mentioned environmental protection portable rubber sole.It has the advantage that as follows: 1, because using carapace powder and corn flour, making the reduction of outsole weight；2, because increasing carapace powder and corn flour, keep outsole more environmentally-friendly, healthy, snugness of fit is more preferably；3, the stability that physical property is able to maintain while above-mentioned 1st, 2 performance is kept；4, concise production process is convenient, and adaptation range is extensive, has good market promotion prospect.
Description
Technical field
The present invention relates to a kind of rubber sole, especially a kind of environmental protection portable rubber sole.The invention further relates in one kind
State the manufacture craft of environmental protection portable rubber sole.
Background technique
With economic and technology development, the living standard of the majority of consumers is also continuously improved, quality of the people to shoes
Performance, safety and environmental protection, comfortably the various aspects of performance such as light are increasingly paid attention to.
Domestic at present irregular for light, environment protection sole R & D Level, up to standard fewer and fewer of physical property is
Increase environmentally friendly, the light performance of shoes, it is ensured that the comfort and health of consumer's dress, research and development particular interface are light
Just, environmentally friendly rubber soles are imperative.
Summary of the invention
In view of the deficiency of background technique, technical problem to be solved by the invention is to provide a kind of the light of more environmental protection portable
Just environment-friendly rubber outsole.The technical problem to be solved by the invention also includes providing a kind of systems of above-mentioned environmental protection portable rubber sole
Make technique.
For this purpose, the present invention is to adopt the following technical scheme that realize:
A kind of environmental protection portable rubber sole, including natural rubber, synthetic rubber 1502#, cis-butadiene cement, sulphur, M, DM, TMTM, carbon
Sour zinc, stearic acid, anti-aging agent TSD, white carbon black, diethylene glycol (DEG), white oil, carapace powder and corn flour.
Further, quality proportioning are as follows: natural rubber -3, synthetic rubber 1502#- 15, cis-butadiene cement -10, sulphur -
0.56, M -0.28, DM -0.4, TMTM -0.04, zinc carbonate -1.7, stearic acid -0.2, anti-aging agent TSD -0.3, hard charcoal
Black -15, diethylene glycol (DEG) -1.5, white oil -2, carapace powder -1 and corn flour -1.4.
The present invention also provides the manufacture crafts of environmental protection portable rubber sole described above, comprising the following steps:
(1) it is weighed according to formula rate: natural rubber -3, synthetic rubber 1502#- 15, cis-butadiene cement -10, sulphur -0.56,
It is M -0.28, DM -0.4, TMTM -0.04, zinc carbonate -1.7, stearic acid -0.2, TSD -0.3, white carbon black -15, two sweet
Alcohol -1.5, white oil -2, carapace powder -1 and corn flour -1.4；And above-mentioned material is put into mixing in mixer, mix mixing 5
Minute, mixing smelting temperature reaches 120-125 degree, then to export epoxy glue spare；
(2) sulphur, vulcanization accelerator have been weighed according to the ratio, the epoxy glue that it is prepared with step 1 is kneaded on the double roll mill,
After being kneaded 7-10 times, adjustment roller spacing to required thickness slice, by the sheet material of slice and being mixed by cold water and zinc stearate
At mixed liquor, the film not glued；
(3) non cohesive gel piece prepared by step 2 is punched into according to shoe style consistent with rubber soles shape, weight, is put into and matches
Rubber boots mould in, 155-165 degree be molded sulfidization molding, obtain light, the environment-friendly rubber outsole.
After adopting the above technical scheme, specific advantage is as follows: 1, because using carapace powder and corn flour, dropping outsole weight
It is low；2, because increasing carapace powder and corn flour, keep outsole more environmentally-friendly, healthy, snugness of fit is more preferably；3, keep it is above-mentioned 1st,
The stability of physical property is able to maintain while 2 performances；4, concise production process is convenient, and adaptation range is extensive, has very
Good market promotion prospect.
Specific embodiment
The environmental protection portable rubber sole that the first embodiment of the invention provides, including natural rubber, synthetic rubber 1502#、
Cis-butadiene cement, sulphur, M, DM, TMTM, zinc carbonate, stearic acid, anti-aging agent TSD, white carbon black, diethylene glycol (DEG), white oil, carapace powder and corn
Powder.Its quality proportioning are as follows: natural rubber -3, synthetic rubber 1502#- 15, cis-butadiene cement -10, sulphur -0.56, M -0.28,
DM -0.4, TMTM -0.04, zinc carbonate -1.7, stearic acid -0.2, anti-aging agent TSD -0.3, white carbon black -15, diethylene glycol (DEG) -
1.5, white oil -2, carapace powder -1 and corn flour -1.4.
The present invention also provides the manufacture crafts of above-mentioned environmental protection portable rubber sole, comprising the following steps:
(1) it is weighed according to formula rate: natural rubber -3, synthetic rubber 1502#- 15, cis-butadiene cement -10, sulphur -0.56,
It is M -0.28, DM -0.4, TMTM -0.04, zinc carbonate -1.7, stearic acid -0.2, TSD -0.3, white carbon black -15, two sweet
Alcohol -1.5, white oil -2, carapace powder -1 and corn flour -1.4；And above-mentioned material is put into mixing in mixer, mix mixing 5
Minute, mixing smelting temperature reaches 120-125 degree, then to export epoxy glue spare；
(2) sulphur, vulcanization accelerator have been weighed according to the ratio, the epoxy glue that it is prepared with step 1 is kneaded on the double roll mill,
After being kneaded 7-10 times, adjustment roller spacing to required thickness slice, by the sheet material of slice and being mixed by cold water and zinc stearate
At mixed liquor, the film not glued；
(3) non cohesive gel piece prepared by step 2 is punched into according to shoe style consistent with rubber soles shape, weight, is put into and matches
Rubber boots mould in, 155-165 degree be molded sulfidization molding, obtain light, the environment-friendly rubber outsole.
The physical property of above-mentioned environmental protection portable rubber sole is embodied below by way of list mode:
Table: test the rubber sole physical property sample comparison of 1-3.
From above-mentioned list can be seen that using formula and production method of the invention to rubber sole items it is strong
Degree, wearability are all strengthened significantly, have occurred that qualitative change.
Second of embodiment of the invention and the first embodiment are essentially identical, and difference is the base in above-described embodiment 1
It further include 1 .5 of graphite, inorganic silicon materials 2.2 in above-mentioned material proportion to enhance the non-skid property of rubber sole on plinth,
Halobutyl 2.2,1 .5 of aluminium hydroxide, sepiolite 0.5, silicon carbide 4, silicon nitride 3, boron nitride 3,1 .5 of glass fibre, lemon
Sour tributyl 3, montmorillonite 1.2,1 .5 of lithium bentonite, butyl titanate 0.5, high density polyethylene (HDPE) 2.5.The material mixture ratio can
To increase rubber article property, increase its surface tension, enhance the adhesive force to ground, makes sizing material that there is preferably resistance to cut
Cutting property generates biggish tractive force and adhesive force.
Claims (4)
1. a kind of environmental protection portable rubber sole, including natural rubber, synthetic rubber 1502#, cis-butadiene cement, sulphur, M, DM, TMTM, carbon
Sour zinc, stearic acid, anti-aging agent TSD, white carbon black, diethylene glycol (DEG), white oil, carapace powder and corn flour.
2. environmental protection portable rubber sole according to claim 1, it is characterized in that: quality proportioning are as follows: natural rubber -3 closes
At rubber 1502#- 15, cis-butadiene cement -10, sulphur -0.56, M -0.28, DM -0.4, TMTM -0.04, zinc carbonate -1.7,
Stearic acid -0.2, anti-aging agent TSD -0.3, white carbon black -15, diethylene glycol (DEG) -1.5, white oil -2, carapace powder -1 and corn flour -
1.4。
3. environmental protection portable rubber sole according to claim 2, it is characterized in that: further including 1 .5 of graphite, inorganic silicon materials
2.2, halobutyl 2.2,1 .5 of aluminium hydroxide, sepiolite 0.5, silicon carbide 4, silicon nitride 3, boron nitride 3,1 .5 of glass fibre,
Tributyl citrate 3, montmorillonite 1.2,1 .5 of lithium bentonite, butyl titanate 0.5, high density polyethylene (HDPE) 2.5.
4. the manufacture craft of environmental protection portable rubber sole described in a kind of claim 2, characterized in that the following steps are included:
(1) it is weighed according to formula rate: natural rubber -3, synthetic rubber 1502#- 15, cis-butadiene cement -10, sulphur -0.56,
It is M -0.28, DM -0.4, TMTM -0.04, zinc carbonate -1.7, stearic acid -0.2, TSD -0.3, white carbon black -15, two sweet
Alcohol -1.5, white oil -2, carapace powder -1 and corn flour -1.4；And above-mentioned material is put into mixing in mixer, mix mixing 5
Minute, mixing smelting temperature reaches 120-125 degree, then to export epoxy glue spare；
(2) sulphur, vulcanization accelerator have been weighed according to the ratio, the epoxy glue that it is prepared with step 1 is kneaded on the double roll mill,
After being kneaded 7-10 times, adjustment roller spacing to required thickness slice, by the sheet material of slice and being mixed by cold water and zinc stearate
At mixed liquor, the film not glued；
(3) non cohesive gel piece prepared by step 2 is punched into according to shoe style consistent with rubber soles shape, weight, is put into and matches
Rubber boots mould in, 155-165 degree be molded sulfidization molding, obtain light, the environment-friendly rubber outsole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811167259.XA CN109553836A (en) | 2018-10-08 | 2018-10-08 | A kind of environmental protection portable rubber sole and its manufacture craft |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811167259.XA CN109553836A (en) | 2018-10-08 | 2018-10-08 | A kind of environmental protection portable rubber sole and its manufacture craft |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109553836A true CN109553836A (en) | 2019-04-02 |
Family
ID=65864775
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811167259.XA Pending CN109553836A (en) | 2018-10-08 | 2018-10-08 | A kind of environmental protection portable rubber sole and its manufacture craft |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109553836A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143049A (en) * | 2020-09-28 | 2020-12-29 | 温州大道鞋业有限公司 | Leather shoes and production method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102344591A (en) * | 2010-07-22 | 2012-02-08 | 陈汇宏 | Preparation method of composition used for rubber product, and product thereof |
| CN102898698A (en) * | 2012-09-29 | 2013-01-30 | 广东智达行新材料有限公司 | Synthetic non-slip rubber for soles and preparation method for synthetic non-slip rubber |
| CN103937048A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Non-frosting rubber used for dark-color shoe sole and preparing method thereof |
| CN106220912A (en) * | 2016-09-30 | 2016-12-14 | 邱亚琴 | A kind of anti-skidding foaming sole material |
| CN206025371U (en) * | 2016-06-24 | 2017-03-22 | 莆田市龙翔鞋业有限公司 | Sole structure of shock attenuation light integrated into one piece , composite plant fibre plate |
| CN107266743A (en) * | 2017-08-17 | 2017-10-20 | 广州市政鑫橡塑有限公司 | A kind of special decomposable asymmetric choice net rubber composition of sole and preparation method thereof |
-
2018
- 2018-10-08 CN CN201811167259.XA patent/CN109553836A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102344591A (en) * | 2010-07-22 | 2012-02-08 | 陈汇宏 | Preparation method of composition used for rubber product, and product thereof |
| CN102898698A (en) * | 2012-09-29 | 2013-01-30 | 广东智达行新材料有限公司 | Synthetic non-slip rubber for soles and preparation method for synthetic non-slip rubber |
| CN103937048A (en) * | 2013-01-23 | 2014-07-23 | 广东智达行新材料有限公司 | Non-frosting rubber used for dark-color shoe sole and preparing method thereof |
| CN206025371U (en) * | 2016-06-24 | 2017-03-22 | 莆田市龙翔鞋业有限公司 | Sole structure of shock attenuation light integrated into one piece , composite plant fibre plate |
| CN106220912A (en) * | 2016-09-30 | 2016-12-14 | 邱亚琴 | A kind of anti-skidding foaming sole material |
| CN107266743A (en) * | 2017-08-17 | 2017-10-20 | 广州市政鑫橡塑有限公司 | A kind of special decomposable asymmetric choice net rubber composition of sole and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112143049A (en) * | 2020-09-28 | 2020-12-29 | 温州大道鞋业有限公司 | Leather shoes and production method thereof |
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Application publication date: 20190402 |
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