CN1095099A - Preparation method of multicolor flame candle - Google Patents
Preparation method of multicolor flame candle Download PDFInfo
- Publication number
- CN1095099A CN1095099A CN 94102000 CN94102000A CN1095099A CN 1095099 A CN1095099 A CN 1095099A CN 94102000 CN94102000 CN 94102000 CN 94102000 A CN94102000 A CN 94102000A CN 1095099 A CN1095099 A CN 1095099A
- Authority
- CN
- China
- Prior art keywords
- heart yearn
- grams
- milliliters
- burning
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- 229920000742 Cotton Polymers 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000446 fuel Substances 0.000 claims abstract description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000002485 combustion reaction Methods 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003595 mist Substances 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- 239000002956 ash Substances 0.000 claims abstract description 5
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims abstract description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 4
- 240000000233 Melia azedarach Species 0.000 claims abstract description 4
- 239000010883 coal ash Substances 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 230000007797 corrosion Effects 0.000 claims abstract description 4
- 238000005260 corrosion Methods 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 238000007654 immersion Methods 0.000 claims abstract description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 241000894007 species Species 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 6
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 6
- 229910001510 metal chloride Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 229920006026 co-polymeric resin Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229910021550 Vanadium Chloride Inorganic materials 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical class ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 229960003280 cupric chloride Drugs 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 229910052602 gypsum Inorganic materials 0.000 claims description 3
- 239000010440 gypsum Substances 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- 229940079938 nitrocellulose Drugs 0.000 claims description 3
- PFPYHYZFFJJQFD-UHFFFAOYSA-N oxalic anhydride Chemical compound O=C1OC1=O PFPYHYZFFJJQFD-UHFFFAOYSA-N 0.000 claims description 3
- LIYKJALVRPGQTR-UHFFFAOYSA-M oxostibanylium;chloride Chemical compound [Cl-].[Sb+]=O LIYKJALVRPGQTR-UHFFFAOYSA-M 0.000 claims description 3
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 239000010803 wood ash Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims 1
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000012916 chromogenic reagent Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Landscapes
- Fats And Perfumes (AREA)
Abstract
The invention provides a kind of preparation method of multicolor flame candle.It forms main fuel by urethane, stearic acid, vinyl acetate-ethylene, the common resin of EVA etc.The heart yearn that combustion parts adopts the plant cotton to make, with plant ash, paper ash, each portion of coal ash, add water and soaked at normal temperatures 48 hours, add water by Platinic chloride, caustic soda, micro mist aluminum oxide, hydrazine hydrate again the cotton heart yearn was soaked 48 hours, make the burning heart yearn after drying.Color development partly adopts the burning heart yearn immersion corrosion of different metal oxides to making, and makes color development heart yearns such as red, green, white respectively.The core rope that two kinds of heart yearns are made ties up on worker's mould at last, injects the main fuel of heating, and Lian worker's mould constitutes color flame candle together after cooling.The present invention has that manufacture craft is simple, cost is low, flameholding, the yellow core of nothing, one's eyes drop millstones etc., and is safe and reliable, environmentally safe.
Description
The present invention relates to colour candle, particularly a kind of preparation method of multicolor flame candle.
The technology of preparing of color flame candles was early reported at home and abroad the patent documentation several years ago.Employing paraffin that has in these technology or paraffin wax type incendiary material are main fuel, add some kinds of metal chlorides as chromogenic reagent.As the patent No. is such technology of report in [USP4,386,904, the clear 611-16996 of Japanese Patent], because its paraffin is long carbochain hydro carbons, the temperature of luminous flame district and air contact part is lower during burning, and the oxidation rate of carbon granules is slow and can not fully burn.And the small grain of unoxidized heat makes flame produce very dark gold zone when stopping in flame, and the color that causes chromogenic reagent to produce is difficult to cover gold zone, has a strong impact on color effect.In addition, also be prone to prosperous cigarette during the burning of this color flame candle, do branch, quality problems such as shed tears.For addressing these problems, there are many people to develop in recent years with non-paraffin wax type incendiary material.As the patent No. is in the patent documentation of CN86105053A and CN8910615.6, and successively disclosing a kind of is the preparation method of the flame candle of main fuel with the urethane.Though this method can solve the sort of gold zone of traditional candle, smolders, do branch, phenomenon such as shed tears, but in the preparation owing to do not grasp the solvent temperature of urethane well, do not adopt an effective measure yet and continue its solubleness, therefore, when the temperature on average of weather reaches 30 degree when above, this product one dispatches from the factory will moistening profit, thereby has influenced the appearance of product.In addition, because its burning heart yearn is dealt with improperly, cause combustionvelocity too slow, can not maintain an equal level with the same heart yearn combustionvelocity of urethane upper surface, face rings the practicality of product.Defective such as its complex manufacturing technology, cost height causes this patented technology still to can not get effective enforcement so far in addition.
The objective of the invention is to overcome above-mentioned deficiency, provide a kind of manufacture craft simple, have attractive appearance, can effectively slow down the urethane combustionvelocity, the preparation method of the color flame candle that the burning of guaranteeing heart yearn and urethane combustionvelocity are fair.
Technical solution of the present invention is: based on urethane, be mixed with several raw materials composition main fuels such as senior stearic acid, form the color development part with multiple metal chloride, form oxygenant by multiple mixing raw material, wherein main fuel is by urethane 93%, stearic acid 3%, vinyl acetate-ethylene, dehydration apple oxalic anhydride copolymerization 2%, EVA copolymer resins 2% constitutes.Combustion parts is after adopting the plant cotton to be processed into heart yearn, again with 1 part of natural grass wood ash, and 1 part in paper ash, 1 part of coal ash, adds water and soaked 48 hours for 3 liters, as the oxidation contact first time of heart yearn by totally 5 kilograms.Adopt Platinic chloride 0.1 gram, caustic soda 13 grams, micro mist aluminum oxide 40 grams, 30 milliliters of hydrazine hydrates, 3000 milliliters in water carries out the oxidation second time to the cotton heart yearn and soaks, and treats to dry after 48 hours, and making the cotton rope promptly becomes the burning heart yearn.Color development partly is the burning heart yearn that will make, adopt different metal chlorides that it is corroded, after making multicolour such as red, green, white respectively, the cotton rope is surrounded burning core as acknowledgment copy by left and right directions with the color development core with hand rib machine, worker's mould of gypsum manufacturing is fastened the core rope again main fuel heating 60 degree are injected worker's mould, Lian worker's mould constitutes a broken colour candle together after cooling.
The burning heart yearn of color development part of the present invention, comprise multicolour such as red, green, white, wherein by lithium chloride 3.5 grams, Preparation of Metallic Strontium 2 grams, polyvinyl alcohol 1.2 grams, platinum matchmaker powder 0.005 gram, red the color producing species of 100 milliliters of compositions of water, wherein platinum melts matchmaker's powder: be made up of platinum chloride 0.0005 gram, caustic soda 5 grams, 30 milliliters of hydrazine hydrates, micro mist aluminum oxide 30 grams.By cupric chloride 60 grams, 100 milliliters in water, platinum melt matchmaker's powder 0.001 gram, and the combustion of three chloroethenes is formed green the color producing species for 85 milliliters.Form white the color producing species for 50 milliliters by antimony oxychloride 40 grams, vanadium chloride 15 grams, pyroxylin (e) cement 5 grams, acetic acid formicester.Form the cotton of different color by three assembly sides respectively and restrict, carried out immersion corrosion at normal temperatures 2 hours, then the cotton rope of handling well is dried, promptly become the burning heart yearn that can send different color.
The invention has the advantages that: in main fuel, increase the lipid acid of certain proportioning, protect shape EVA copolymer resins and strengthen its molten point.Adopt vinyl acetate-ethylene to make the present invention not only inflammable but also plasticity arranged.Have characteristics such as manufacture craft is simple, cost is low, flameholding, the yellow core of nothing, one's eyes drop millstones, the dried branch of nothing.The present invention measures through environmental administration, meets the environmentally-friendly sanitary standard.Safe and reliable, can not pollute environment.
Embodiment:
The preparation of main fuel: by urethane 93%, stearic acid 3%, vinyl acetate-ethylene, dehydration apple oxalic anhydride copolymerization 2%, it is standby that EVA copolymer resins 2% mixes the back.
Combustion parts is after adopting the plant cotton to be processed into heart yearn, again with 1 part of natural grass wood ash, and 1 part in paper ash, 1 part of coal ash, adds 3 liters in water and soaks the each oxidation contact as heart yearn in 48 hours by totally 5 kilograms, adopt Platinic chloride 0.1 gram, caustic soda 13 grams, micro mist aluminum oxide 40 grams, 30 milliliters of hydrazine hydrates, 3000 milliliters in water, the cotton heart yearn is carried out the oxidation second time soak, treat to dry after 48 hours, making the cotton rope promptly becomes the burning heart yearn.
The preparation of color development part: (with red example)
With the burning heart yearn that makes, employing is by lithium chloride 3.5 grams, Preparation of Metallic Strontium 2 grams, polyvinyl alcohol 1.2 grams, platinum matchmaker powder 0.005 gram, the metal chloride of 100 milliliters of compositions of water corrodes it, wherein platinum melts matchmaker's powder by platinum chloride 0.0005 gram, caustic soda 5 gram, 30 milliliters of hydrazine hydrates, micro mist aluminum oxide 30 are restrained.
Green the color producing species, by cupric chloride 60 grams, 100 milliliters in water, platinum melt matchmaker's powder 0.001 gram, and 85 milliliters of three chloroethenes combustions need not add thermal etching and dry the cotton rope after 2 hours.
White the color producing species: form for 50 milliliters by antimony oxychloride 40 gram, vanadium chloride 15 grams, pyroxylin (e) cement 5 grams, acetic acid formicester, with above-mentioned identical preparation method to its immersion corrosion.
After above work finished, the color development core is surrounded burn heart yearn standby with hand rib machine by left and right directions in the cotton rope for preparing.To the core rope be fastened with worker's mould of gypsum manufacturing at last, and again main fuel heating 60 degree be injected plaster mould, Lian worker's mould and candle constitute product together after cooling.
Claims (2)
1, a kind of preparation method of colorful flame candle, based on urethane, be mixed with several raw materials composition main fuels such as senior stearic acid, form the color development part with multiple metal chloride, form oxygenant by multiple mixing raw material, it is characterized in that: main fuel is by urethane 93%, stearic acid 3%, vinyl acetate-ethylene, dehydration apple oxalic anhydride copolymerization 2%, EVA copolymer resins 2%, combustion parts is after adopting the plant cotton to be processed into heart yearn, again with 1 part of natural grass wood ash, 1 part in paper ash, 1 part of coal ash, totally 5 kilograms, adding water soaked 48 hours for 3 liters, the oxidation contact first time as heart yearn, adopt Platinic chloride 0.1 gram, caustic soda 13 grams, micro mist aluminum oxide 40 grams, 30 milliliters of hydrazine hydrates, 3000 milliliters in water carries out the oxidation second time to the cotton heart yearn and soaks, and treats to dry after 48 hours, make the cotton rope and promptly become the burning heart yearn, color development partly is the burning heart yearn that will make, and adopts different metal chlorides that it is corroded, and makes red respectively, green, after the multicolour such as white, the cotton rope is surrounded burning core as acknowledgment copy by left and right directions with the color development core with hand rib machine, worker's mould of gypsum manufacturing is fastened the core rope again, main fuel heating 60 degree are injected worker's mould, Lian worker's mould constitutes a broken colour candle together after cooling.
2, preparation method of multicolor flame candle according to claim 1, it is characterized in that: the burning heart yearn of said color development part, comprise red, green, multicolour such as white, wherein by lithium chloride 3.5 grams, Preparation of Metallic Strontium 2 grams, polyvinyl alcohol 1.2 grams, platinum matchmaker powder 0.005 gram, red the color producing species of 100 milliliters of compositions of water, by cupric chloride 60 grams, 100 milliliters in water, platinum melt matchmaker's powder 0.001 gram, the combustion of three chloroethenes is formed green the color producing species for 85 milliliters, by antimony oxychloride 40 grams, vanadium chloride 15 grams, pyroxylin (e) cement 5 grams, 50 milliliters of acetic acid formicesters are formed white the color producing species, and the cotton rope with three kinds of different colors making carried out immersion corrosion 2 hours at normal temperatures, then the cotton rope of handling well is dried, promptly become the burning heart yearn that can send different color.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94102000 CN1095099A (en) | 1994-03-15 | 1994-03-15 | Preparation method of multicolor flame candle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94102000 CN1095099A (en) | 1994-03-15 | 1994-03-15 | Preparation method of multicolor flame candle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1095099A true CN1095099A (en) | 1994-11-16 |
Family
ID=5030471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94102000 Pending CN1095099A (en) | 1994-03-15 | 1994-03-15 | Preparation method of multicolor flame candle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1095099A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002099022A1 (en) * | 2001-06-04 | 2002-12-12 | Novaflame Pty Ltd | Candles with coloured flames |
| US6712865B2 (en) | 2002-07-12 | 2004-03-30 | Xin Lu | Colored flame candle and manufacture thereof |
-
1994
- 1994-03-15 CN CN 94102000 patent/CN1095099A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002099022A1 (en) * | 2001-06-04 | 2002-12-12 | Novaflame Pty Ltd | Candles with coloured flames |
| AU2002257373B2 (en) * | 2001-06-04 | 2005-05-12 | Novaflame Pty Ltd | Candles with coloured flames |
| US6712865B2 (en) | 2002-07-12 | 2004-03-30 | Xin Lu | Colored flame candle and manufacture thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |