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CN109136553A - A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique - Google Patents

A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique Download PDF

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Publication number
CN109136553A
CN109136553A CN201811268521.XA CN201811268521A CN109136553A CN 109136553 A CN109136553 A CN 109136553A CN 201811268521 A CN201811268521 A CN 201811268521A CN 109136553 A CN109136553 A CN 109136553A
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Prior art keywords
impurity
active carbon
removing method
desorption
liquid
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CN201811268521.XA
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Chinese (zh)
Inventor
张景河
金琪琳
何涛
高伟
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Xinjiang Jinchuan Mining Co Ltd
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Xinjiang Jinchuan Mining Co Ltd
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Priority to CN201811268521.XA priority Critical patent/CN109136553A/en
Publication of CN109136553A publication Critical patent/CN109136553A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00Obtaining noble metals
    • C22B11/04Obtaining noble metals by wet processes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses a kind of your liquid impurity-removing methods of indirect heap leaching of gold ores technique, active carbon is added in the expensive liquid of heap leaching of gold ores, by 10-30 days, the active carbon of adsorption saturation is taken out, it is desorbed, active carbon after obtaining desorption waste water and desorption, active carbon after desorption is subjected to pickling processes, the acid waste water that pickling processes obtain, and the smelting wastewater that desorption waste water and gold mud generate when being smelted, it is put into sedimentation basin, removal of impurities processing is carried out using efficient impurity removal agent, sediment carries out filters pressing, storage.The present invention uses efficient impurity removal agent, and the impurity such as dust removal rate high, settling velocity fast, copper, mercury, zinc, nickel, the pH range of adaptation is wide, and does not influence the leaching of gold.Realization leachate is recycled for a long time and zero-emission;Impurity low concentration state in leachate is kept, leaching rate is improved;Foreign metal recycling.

Description

A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique
Technical field
The present invention relates to golden production technical fields, are a kind of purification of leaching liquor simple and effective, almost without equipment investment Technology, in particular to a kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique.
Background technique
In gold heaping leaching production, leachate recycles for a long time can add up the impurity such as a large amount of copper, mercury, zinc, nickel, seriously affect Continuing the effect leached, tail washings is discharged in general mine, will cause environmental pollution, and the industry generallys use vulcanized sodium removal of impurities, although Mode is identical, but vulcanized sodium removal of impurities requires PH to be acidified before 3-6, removal of impurities, again adjusts PH after removal of impurities then useless to 9-11 Water could be recycled, while vulcanized sodium rate of deposition is lower.It is at high cost using vulcanized sodium impurity-removing method complex process, while acid Property removal of impurities when, solution generate hydrogen cyanide gas, one causes cyaniding sodium loss, and two cause environmental pollution, third is that if recycling Cymag The complication of removal of impurities process can be increased again.
Summary of the invention
It is an object of the invention to disclose a kind of method of your liquid removal of impurities of indirect heap leaching of gold ores technique, reality may be implemented Existing leachate is recycled for a long time and zero-emission, keeps impurity low concentration state in leachate, improves leaching rate, recycling impurity gold Belong to.
The technical solution of the present invention is as follows:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 10- 30 days, by the active carbon of adsorption saturation, which contained golden Au, silver Ag, copper Cu, mercury Hg, nickel, waits taking-up, is desorbed, Active carbon after desorption is carried out pickling processes by the active carbon after obtaining desorption waste water and desorption, and treated active carbon can be with It reuses, the acid waste water that pickling processes obtain, and the smelting that desorption waste water and gold mud generate when being smelted is useless Water is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, and treated, and water can return to production cycle use, precipitating Object carries out filters pressing, storage.Using the adsorption function of active carbon, by copper, tribute, nickel, lead, etc. in impurity absorptions to active carbon, then benefit With the desorption electrodeposition system of gold loaded carbon, carry out the operations such as pickling, smelting of gold slurry, impurity enter desorption waste water, pickling waste waters with And in smelting wastewater, above-mentioned foreign ion is then precipitated using cleaner, plays the purpose of your liquid removal of impurities indirectly.
Preferably, the efficient impurity removal agent is the mixture of lime sulfur or lime sulfur and polyaluminium sodium.
The lime sulfur be added lime 0.5-2 parts, 1-3 parts of sulphur powder, 8-12 parts of water mixture boil,
Preferably, the lime sulfur be 1 part of lime, 2 parts of sulphur powder, 10 parts of water mixture boil, can also From the purchase of Lianyun Harbour Lan Xing Industrial Technology Co., Ltd.
The efficient impurity removal agent, lime sulfur and polyaluminium sodium weight ratio are 7-13:0.5-3, preferably 10:1.
Need to adjust pH value between 3-12 before using efficient impurity removal agent, it is preferred that PH value is between 5-12.If It is cleaned with vulcanized sodium, PH is adjusted to 5-6, and the PH range that the cleaner is applicable in is wide, between PH=3-12, can effectively remove It is miscellaneous.
It can also be taken out, preferably 20 days for active carbon to be added in the expensive liquid of heap leaching of gold ores, by 17-23 days.
The present invention uses efficient impurity removal agent, the impurity such as dust removal rate high, settling velocity fast, copper, mercury, zinc, nickel, the PH of adaptation Value range is wide, and does not influence the leaching of gold.Realization leachate is recycled for a long time and zero-emission;Keep impurity in leachate low CONCENTRATION STATE improves leaching rate;Foreign metal recycling.The efficient impurity removal agent belongs to low toxic and environment-friendly medicament, cheap, has extensively Prospects for commercial application.Processing method of the present invention is simple and efficient, and reagent consumption is the half of vulcanized sodium, also without adjusting acid, alkali tune Expense, investment and operation cost all substantially reduce, according to leachate impurity situation, can continuously be interrupted, it is convenient, flexible, for a long time Guarantee that leachate is clean and is recycled, really realizes technique of zero discharge.
In impurity absorption to gold loaded carbon, impurity also obtains entering in desorption waste water, acid waste water and smelting wastewater in desorption, These three waste water are handled using efficient impurity removal agent, treated, and water can return to production cycle use.Scheme is implemented simply, Using sedimentation basin, almost without equipment investment.
The present invention uses High-rate sedimentation agent, compares and has the advantage that compared with vulcanized sodium
(1) sedimentation effect is good, rate of deposition can achieve copper >=95%, nickel >=85%, mercury >=95%, zinc >=95%, iron >= 95%;And with vulcanized sodium impurity-removing precipitating rate copper >=75%, nickel >=60%, mercury >=75%, zinc >=85%, iron >=85%.
(2) pH range is wide.
(3) process is simple, Cymag free of losses, economic and environment-friendly.
Detailed description of the invention
Your liquid impurity-removing method flow diagram Fig. 1 is;
Specific embodiment
With reference to the accompanying drawing to a preferred embodiment of the present invention will be described in detail:
Embodiment 1:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique: acticarbon is added in the expensive liquid of heap leaching of gold ores, After about 20 days, by the active carbon of adsorption saturation (contain gold Au, silver Ag, copper Cu, mercury Hg, nickel, etc.) taking-up, is desorbed, obtained Active carbon after desorption is carried out pickling processes by the active carbon to after desorption waste water and desorption, and treated, and active carbon can weigh Smelting wastewater that is multiple to use, being generated during the acid waste water that pickling processes obtain, and desorption waste water and smelting of gold slurry, It is put into sedimentation basin, carries out removal of impurities processing using cleaner, treated, and water can return to production cycle use, and sediment is pressed Filter, storage.
Embodiment 2:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 20 It, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, by the work after desorption Property charcoal carry out what pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud generated when being smelted Smelting wastewater is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is the mixture of lime sulfur and polyaluminium sodium;The lime sulfur is lime 1 Part, 2 parts of sulphur powder, 10 parts of water mixture boil;The mixture of the lime sulfur and polyaluminium sodium, stone sulphur close Agent and polyaluminium sodium weight ratio are 10:1;Need to adjust pH value between 5-12 before using efficient impurity removal agent.
Embodiment 3:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 21 It, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, by the work after desorption Property charcoal carry out what pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud generated when being smelted Smelting wastewater is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is the mixture of lime sulfur and polyaluminium sodium;The lime sulfur is lime 1 Part, 2 parts of sulphur powder, 10 parts of water mixture boil;The mixture of the lime sulfur and polyaluminium sodium, stone sulphur close Agent and polyaluminium sodium weight ratio are 10:1;Need to adjust pH value between 3-12 before using efficient impurity removal agent.
Embodiment 4:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 19 It, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, by the work after desorption Property charcoal carry out what pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud generated when being smelted Smelting wastewater is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is the mixture of lime sulfur and polyaluminium sodium;The lime sulfur is lime 1 Part, 2 parts of sulphur powder, 10 parts of water mixture boil;The mixture of the lime sulfur and polyaluminium sodium, stone sulphur close Agent and polyaluminium sodium weight ratio are 9:0.8;Need to adjust pH value between 5-12 before using efficient impurity removal agent.
Embodiment 5:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 10- 30 days, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, after desorption Active carbon carries out pickling processes, the acid waste water that pickling processes obtain, and generation when being smelted of desorption waste water and gold mud Smelting wastewater, be put into sedimentation basin, carry out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is lime sulfur, and the lime sulfur is that 1 part of lime, 2 parts of sulphur powder, water is added 10 parts of mixture boils.
Embodiment 6:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 21 It, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, by the work after desorption Property charcoal carry out what pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud generated when being smelted Smelting wastewater is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is the mixture of lime sulfur and polyaluminium sodium;The lime sulfur is lime 1 Part, 2 parts of sulphur powder, 10 parts of water mixture boil;The mixture of the lime sulfur and polyaluminium sodium, stone sulphur close Agent and polyaluminium sodium weight ratio are 10:1.
Embodiment 7:
A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique active carbon is added in the expensive liquid of heap leaching of gold ores, by 20 It, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, by the work after desorption Property charcoal carry out what pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud generated when being smelted Smelting wastewater is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, sediment carries out filters pressing, storage;
The efficient impurity removal agent is lime sulfur, and the lime sulfur is that 1 part of lime, 2 parts of sulphur powder, water is added 10 parts of mixture boils;Need to adjust pH value between 3-12 before using efficient impurity removal agent.
Need to adjust pH value between 5-12 before using efficient impurity removal agent.

Claims (10)

1. a kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique, it is characterised in that: the expensive liquid of heap leaching of gold ores is added in active carbon In, by 10-30 days, the active carbon of adsorption saturation is taken out, is desorbed, the active carbon after obtaining desorption waste water and desorption, Active carbon after desorption is subjected to pickling processes, the acid waste water that pickling processes obtain, and desorption waste water and gold mud carries out The smelting wastewater generated when smelting, is put into sedimentation basin, carries out removal of impurities processing using efficient impurity removal agent, and sediment carries out filters pressing, Storage.
2. your as described in claim 1 liquid impurity-removing method, it is characterised in that: the efficient impurity removal agent be lime sulfur or The mixture of lime sulfur and polyaluminium sodium.
3. your liquid impurity-removing method as claimed in claim 2, it is characterised in that: the lime sulfur is that lime 0.5-2 is added Part, 1-3 parts of sulphur powder, 8-12 parts of water mixture boil.
4. your liquid impurity-removing method as claimed in claim 3, it is characterised in that: the lime sulfur is 1 part of lime, sulphur powder 2 parts, 10 parts of water of mixture boils.
5. your liquid impurity-removing method as claimed in claim 2, it is characterised in that: the lime sulfur and polyaluminium sodium mixes Object is closed, lime sulfur and polyaluminium sodium weight ratio are 7-13:0.5-3.
6. your as claimed in claim 5 liquid impurity-removing method, it is characterised in that: lime sulfur is with polyaluminium sodium weight ratio 10:1。
7. your liquid impurity-removing method as described in claim 1, it is characterised in that: need to adjust pH value before using efficient impurity removal agent Between 3-12.
8. your liquid impurity-removing method as claimed in claim 7, it is characterised in that: need to adjust pH value before using efficient impurity removal agent Between 5-12.
9. your liquid impurity-removing method as described in claim 1, it is characterised in that: active carbon is added in the expensive liquid of heap leaching of gold ores, warp 17-23 days are spent, is taken out.
10. your liquid impurity-removing method as claimed in claim 9, it is characterised in that: active carbon is added in the expensive liquid of heap leaching of gold ores, warp 20 days are spent, is taken out.
CN201811268521.XA 2018-10-29 2018-10-29 A kind of your liquid impurity-removing method of indirect heap leaching of gold ores technique Pending CN109136553A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111088435A (en) * 2019-11-01 2020-05-01 新疆金川矿业有限公司 Lime sulfur mixture, preparation method thereof and use method thereof in gold leaching

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CN111088435A (en) * 2019-11-01 2020-05-01 新疆金川矿业有限公司 Lime sulfur mixture, preparation method thereof and use method thereof in gold leaching

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