CN109052675A - Environment-friendly type anti-incrustation corrosion inhibitor and preparation method thereof - Google Patents
Environment-friendly type anti-incrustation corrosion inhibitor and preparation method thereof Download PDFInfo
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- CN109052675A CN109052675A CN201810932737.5A CN201810932737A CN109052675A CN 109052675 A CN109052675 A CN 109052675A CN 201810932737 A CN201810932737 A CN 201810932737A CN 109052675 A CN109052675 A CN 109052675A
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- Prior art keywords
- acrylamide
- corrosion inhibitor
- incrustation corrosion
- environment
- acrylic acid
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- 230000007797 corrosion Effects 0.000 title claims abstract description 76
- 238000005260 corrosion Methods 0.000 title claims abstract description 76
- 239000003112 inhibitor Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 46
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 42
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920001897 terpolymer Polymers 0.000 claims abstract description 26
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 20
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 16
- QLCAGXDTDCDEGN-UHFFFAOYSA-N 3-sulfanylcarbonylhexanedioic acid Chemical compound OC(=O)CCC(C(O)=S)CC(O)=O QLCAGXDTDCDEGN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 16
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 16
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 16
- 229920000141 poly(maleic anhydride) Polymers 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 230000007062 hydrolysis Effects 0.000 claims abstract description 14
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000003852 triazoles Chemical class 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 9
- 239000011574 phosphorus Substances 0.000 abstract description 9
- 239000011701 zinc Substances 0.000 abstract description 9
- 229910052725 zinc Inorganic materials 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 6
- 239000002455 scale inhibitor Substances 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 11
- 229910000975 Carbon steel Inorganic materials 0.000 description 8
- 239000010962 carbon steel Substances 0.000 description 8
- 239000003814 drug Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 238000004457 water analysis Methods 0.000 description 6
- 239000000498 cooling water Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 230000003020 moisturizing effect Effects 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 230000003301 hydrolyzing effect Effects 0.000 description 3
- -1 imidazoline quaternary ammonium salt Chemical class 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000013589 supplement Substances 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000000116 mitigating effect Effects 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920006027 ternary co-polymer Polymers 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 150000003751 zinc Chemical class 0.000 description 2
- BFOCLBAICAUQTA-UHFFFAOYSA-N 2-methylpropane;prop-2-enamide Chemical compound CC(C)C.NC(=O)C=C BFOCLBAICAUQTA-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- MOFINMJRLYEONQ-UHFFFAOYSA-N [N].C=1C=CNC=1 Chemical class [N].C=1C=CNC=1 MOFINMJRLYEONQ-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 229940030188 solu-delta-cortef Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
- C02F5/125—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/08—Corrosion inhibition
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of environment-friendly type anti-incrustation corrosion inhibitors and preparation method thereof, each component and its weight percent relative to the anti-incrustation corrosion inhibitor gross weight are as follows: hydrolysis of polymaleic anhydride 10%~15%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer 14%~20%, ammonium persulfate 0.5%~1%, carboxyethyl thiosuccinic acid 5%~10%, sodium gluconate 5%~8%, methyl benzotriazazole 1%~2%, surplus are deionized water.Anti-incrustation corrosion inhibitor of the invention is without phosphorus, without zinc, environmentally friendly, while scale inhibitor excellent effect.
Description
Technical field
The present invention relates to a kind of industrial water conditioning agents, and in particular to a kind of environment-friendly type for industrial circulating cooling water processing
Anti-incrustation corrosion inhibitor and preparation method thereof.
Background technique
Currently, the medicament of phosphorous formula is still occupied an leading position in industrial circulating water water treatment agent field, phosphorous medicament
Technology maturation, cost is controllable, and treatment effect substantially conforms to the standard of country or relevant industries.But with the row of phosphorus-containing wastewater
It puts, in fact on the one hand exacerbates the process of water eutrophication, destroy original ecosystem, on the other hand also increase
The difficulty of waste water treatment and cycling and reutilization.In these years, as the people and public organization are to the gradually pass of environmental protection cause
The use of the enhancing of note and environmental consciousness, phosphorous medicament has had become increasingly limited, and researches and develops and produce environment-friendly type resistance
The hot topic that dirty corrosion inhibiter has become water process practitioner captures field.
In addition to phosphorus-containing compound in water treatment agent, zinc salt is also currently used cooling water corrosion inhibitor.Zinc salt mainly by
Zn2+Ion plays corrosion inhibition, forms a film rapider, when cooperateing with use with other corrosion inhibiter such as phosphate, organic phosphonate etc.,
Good corrosion mitigating effect can be obtained.But zinc is toxic, is necessarily less than 5mg/L using concentration.Zinc is to fish and aquatile
The toxicity that toxicity compares people is big, therefore fishery water quality requires to be 0.1mg/L.In addition, zinc has generation heavy when the pH of system is greater than 8.3
The tendency in shallow lake.
In these cases, it has been very urgent for developing without phosphorus environment-friendly type anti-incrustation corrosion inhibitor without zinc.
About without phosphorus environment-friendly type anti-incrustation corrosion inhibitor without zinc, Chinese patent literature CN102351328B(application number
201110274827.8) a kind of green total organic carbon steel anti-incrustation corrosion inhibitor for recirculating cooling water system, the scale inhibition are disclosed
Corrosion inhibiter is made of antisludging agent and corrosion inhibiter, and wherein antisludging agent is by hydrolysis of polymaleic anhydride and polyacrylic acid, polymethylacrylic acid,
Acrylic acid/hydroxypropyl acrylate copolymer, acrylic acid/hydroxypropyl acrylate/methyl acrylate terpolymer, acrylic acid/2-
Acrylamido -2- methyl propane sulfonic acid analog copolymer is one such or several compositions, corrosion inhibiter by oxalic acid or oxalates and
Alpha-hydroxy carboxylic acid compounds or its salt and silicate composition.The anti-incrustation corrosion inhibitor meets environmental requirement, but silicon is added in anti-incrustation corrosion inhibitor
Hydrochlorate easily forms silicon dirt in high hardness water, limits its scope of application.
Chinese patent literature CN102010077A(application number 201010610661.8) disclose a kind of non-phosphorus scale inhibition
Agent and preparation process, non-phosphorus scale and corrosion inhibitor include 3 kinds of scale inhibition ingredient, 4 kinds of inhibition ingredient, and 3 kinds of scale inhibition ingredients are polycyclic oxygen amber
Meticortene Solu-Delta-cortef, hydrolysis of polymaleic anhydride, acrylic acid/ethyl acrylate/2- acrylamide-2-methyl propane sulfonic copolymer；4 kinds of inhibitions
Ingredient is methylbenzotrazole, sodium gluconate, sodium tungstate, corrosion inhibiter imidazoline quaternary ammonium salt；The mass percent of its raw material is
Polyepoxy sodium succinate 40%~50%, hydrolysis of polymaleic anhydride 5%~10%, acrylic acid/ethyl acrylate/2- acrylamide -2-
Methyl propane sulfonic acid copolymer 5%~10%；Methylbenzotrazole 1%~3%, sodium gluconate 8%~10%, sodium tungstate 1%~3%, miaow
Oxazoline quaternary ammonium salt 10%~15%.The anti-incrustation corrosion inhibitor has preferably taken into account anticorrosion-antiscaling property, but imidazoline quaternary ammonium salt belongs to table
Face activating agent, during actual use be also easy to produce more foam, cannot be used in the circulation of air separation unit.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of without phosphorus, environment-friendly types for working well without zinc, scale inhibitor
Anti-incrustation corrosion inhibitor and preparation method thereof.
The technical solution for realizing an object of the present disclosure is a kind of environment-friendly type anti-incrustation corrosion inhibitor, each component and its relative to institute
State the weight percent of anti-incrustation corrosion inhibitor gross weight are as follows: hydrolysis of polymaleic anhydride 10%~15%, acrylic acid/2- acrylamide -2- first
Base propane sulfonic acid/N tert butyl acrylamide terpolymer 14%~20%, ammonium persulfate 0.5%~1%, carboxyethyl thiosuccinic acid
5%~10%, sodium gluconate 5%~8%, methyl benzotriazazole 1%~2%, surplus is deionized water.
The acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer is propylene
Three kinds of acid, 2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide monomers are sent out under the action of ammonium persulfate initiator
The terpolymer that raw free radical polymerization obtains, acrylic acid, 2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide
Mass ratio be 8~10: 3~5: 3~5.
The dosage of the ammonium persulfate and the mass ratio of acrylic acid are 0.5~1: 8~10.
Further, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer phase
Weight percent for the anti-incrustation corrosion inhibitor gross weight is 16%~18%.
Further, carboxyethyl thiosuccinic acid relative to the anti-incrustation corrosion inhibitor gross weight weight percent be 5%~
8%。
A kind of preparation method of environment-friendly type anti-incrustation corrosion inhibitor as described above, comprising the following steps:
1. preparing acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer.
2. sequentially adding hydrolysis of polymaleic anhydride, carboxyethyl thiosuccinic acid, sodium gluconate, first into terpolymer
Base benzotriazole and balance deionized water, stir.
3. filtering, pack.
Step 1. in, by 2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide and portions of de-ionized water according to
Secondary investment reaction kettle opens stirring, is warming up to 80 DEG C~90 DEG C, after reaching temperature, and over cure is added dropwise simultaneously respectively into reaction kettle
Sour aqueous ammonium and acrylic acid, time for adding are 3~4 hours, heat preservation are added dropwise 1~2 hour, obtain acrylic acid/2- propylene
Amide -2- methyl propane sulfonic acid/N tert butyl acrylamide terpolymer.
Acrylic acid, 2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide mass ratio be 8~10: 3~5: 3
~5.
Step 2. in, after 1. terpolymer obtained is cooled to room temperature after step, add other materials.
The present invention has the effect of positive: (1) anti-incrustation corrosion inhibitor of the invention it is without phosphorus, without zinc, it is environmentally friendly, hinder simultaneously
Dirty corrosion mitigating effect is excellent.
(2) the scale inhibition ingredient in anti-incrustation corrosion inhibitor of the invention is acrylic acid/2- acrylamide-2-methyl propane sulfonic/N-
N-tert-butyl acrylamide terpolymer and hydrolysis of polymaleic anhydride, wherein acrylic acid/2- acrylamide-2-methyl propane sulfonic/
N tert butyl acrylamide terpolymer has fine antiscaling dispersion effect, finds by many experiments, when the polymer phase
When being 3000~4000 to molecular weight, antiscaling dispersion effect is best.The molecular weight of polymer by three kinds of monomers proportion, cause
The amount and reaction temperature of agent determines.
Hydrolysis of polymaleic anhydride has excellent scale-inhibiting properties, and thermal stability is good, terpolymer and hydrolyzed polymaleic anhydride
After acid anhydride compounding, since synergistic effect scale-inhibiting properties greatly enhance.Pass through " GB/T16632-2008 water treatment agent scale-inhibiting properties
Measurement tosca method " test compared with similar product, find product of the present invention scale inhibition performance can reach 96% or more,
It is better than similar product.
(3) inhibition ingredient in anti-incrustation corrosion inhibitor of the invention is by carboxyethyl thiosuccinic acid, sodium gluconate, methylbenzene
And triazole forms, carboxyethyl thiosuccinic acid is a kind of dispersion detergent of superior performance, has good antirust inhibition function
Can, there is outstanding chelating dispersibility to metal ions such as calcium, magnesium, iron, copper.Sodium gluconate is that one kind is low in cost, can give birth to
Strong, the environmental-friendly corrosion-mitigation scale-inhibition ingredient of object degradability has very strong complexing power to calcium, magnesium, molysite.Methyl benzo three
Nitrogen azoles is mainly used as the antirust and inhibition of metal (such as silver, copper, lead, nickel, zinc), and there especially have to copper and copper alloy to be unique and excellent
Different inhibition protection effect.It is tested by " the measurement rotary hanging plate method of GB/T 18175-2014 water treatment agent corrosion inhibition ",
It was found that product of the present invention all reaches 95% or more to the corrosion inhibition rate of carbon steel, brass, stainless steel, it is superior to similar product.
Specific embodiment
Each component in environment-friendly type anti-incrustation corrosion inhibitor of the invention and its weight relative to the anti-incrustation corrosion inhibitor gross weight
Percentage are as follows: hydrolysis of polymaleic anhydride 10%~15%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N- tert-butyl acryloyl
Amine terpolymer 14%~20%, ammonium persulfate 0.5%~1%, carboxyethyl thiosuccinic acid 5%~10%, sodium gluconate 5%~
8%, methyl benzotriazazole 1%~2%, surplus is deionized water.
Acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer is acrylic acid, 2-
Three kinds of acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide monomers occur certainly under the action of ammonium persulfate initiator
The terpolymer being polymerize by base, the matter of acrylic acid, 2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide
Amount is than being 8~10: 3~5: 3~5；The dosage of ammonium persulfate and the mass ratio of acrylic acid are 0.5~1: 8~10.
(embodiment 1)
Each component in the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment and its weight hundred relative to the anti-incrustation corrosion inhibitor gross weight
Divide ratio are as follows: hydrolysis of polymaleic anhydride 10%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide ternary
Copolymer 1 8%, ammonium persulfate 0.5%, carboxyethyl thiosuccinic acid 8%, sodium gluconate 8%, methyl benzotriazazole 1%, surplus
For deionized water.
The preparation method of the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment the following steps are included:
1. preparing acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer.
By the 2- acrylamide-2-methyl propane sulfonic of 50kg, the N tert butyl acrylamide of 30kg and 120kg go from
Sub- water successively puts into reaction kettle, opens stirring, is warming up to 80 DEG C~90 DEG C (they being 85 DEG C in the present embodiment), after reaching temperature, to
The ammonium persulfate aqueous solution and 100kg propylene of 5kg ammonium persulfate and 50kg deionized water composition is added dropwise in reaction kettle simultaneously respectively
Acid, time for adding are 3~4 hours, and heat preservation 1~2 hour (being 2 hours in the present embodiment) is added dropwise.
Acrylic acid made from the present embodiment/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide ternary polymerization
The molecular weight of object is 3800.
2. sequentially adding 100kg into reaction kettle when the reactor temperature of step 1. is cooled to room temperature and hydrolyzing poly- horse
Come acid anhydrides, 80kg carboxyethyl thiosuccinic acid, 80kg sodium gluconate, 10kg methyl benzotriazazole and 375kg deionized water,
It stirring 1~2 hour (being 1 hour in the present embodiment), stirs.
3. opening reaction kettle bottom valve, specified container containing will be packed into as required by the medicament of filter bag, measure at
Product environment-friendly type anti-incrustation corrosion inhibitor.
(embodiment 2)
Each component in the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment and its weight hundred relative to the anti-incrustation corrosion inhibitor gross weight
Divide ratio are as follows: hydrolysis of polymaleic anhydride 15%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide ternary
Copolymer 1 4%, ammonium persulfate 0.75%, carboxyethyl thiosuccinic acid 5%, sodium gluconate 5%, methyl benzotriazazole 2%, surplus
For deionized water.
The preparation method of the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment the following steps are included:
1. preparing acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer.
By the 2- acrylamide-2-methyl propane sulfonic of 30kg, the N tert butyl acrylamide of 30kg and 120kg go from
Sub- water successively puts into reaction kettle, opens stirring, is warming up to 80 DEG C, after reaching temperature, and 7.5kg is added dropwise simultaneously respectively into reaction kettle
The ammonium persulfate aqueous solution and 80kg acrylic acid of ammonium persulfate and 75kg deionized water composition, time for adding are 3~4 hours, drop
Add Bi Baowen 1.5 hours.
Acrylic acid made from the present embodiment/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide ternary polymerization
The molecular weight of object is 3580.
2. sequentially adding 150kg into reaction kettle when the reactor temperature of step 1. is cooled to room temperature and hydrolyzing poly- horse
Come acid anhydrides, 50kg carboxyethyl thiosuccinic acid, 50kg sodium gluconate, 20kg methyl benzotriazazole and 387.5kg deionization
Water is stirred 2 hours, is stirred.
3. opening reaction kettle bottom valve, specified container containing will be packed into as required by the medicament of filter bag, measure at
Product environment-friendly type anti-incrustation corrosion inhibitor.
(embodiment 3)
Each component in the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment and its weight hundred relative to the anti-incrustation corrosion inhibitor gross weight
Divide ratio are as follows: hydrolysis of polymaleic anhydride 12.5%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide three
Membered copolymer 16%, ammonium persulfate 1%, carboxyethyl thiosuccinic acid 7.5%, sodium gluconate 7%, methyl benzotriazazole 1.5%,
Surplus is deionized water.
The preparation method of the environment-friendly type anti-incrustation corrosion inhibitor of the present embodiment the following steps are included:
1. preparing acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer.
By the 2- acrylamide-2-methyl propane sulfonic of 40kg, the N tert butyl acrylamide of 40kg and 120kg go from
Sub- water successively puts into reaction kettle, opens stirring, is warming up to 80 DEG C, after reaching temperature, and 10kg is added dropwise simultaneously respectively into reaction kettle
The ammonium persulfate aqueous solution and 80kg acrylic acid of ammonium persulfate and 75kg deionized water composition, time for adding are 3~4 hours, drop
Add Bi Baowen 1.5 hours.
Acrylic acid made from the present embodiment/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide ternary polymerization
The molecular weight of object is 3250.
2. sequentially adding 125kg into reaction kettle when the reactor temperature of step 1. is cooled to room temperature and hydrolyzing poly- horse
Come acid anhydrides, 75kg carboxyethyl thiosuccinic acid, 70kg sodium gluconate, 15kg methyl benzotriazazole and 350kg deionized water,
Stirring 2 hours, stirs.
3. opening reaction kettle bottom valve, specified container containing will be packed into as required by the medicament of filter bag, measure at
Product environment-friendly type anti-incrustation corrosion inhibitor.
(4~embodiment of embodiment 8)
Each component in the environment-friendly type anti-incrustation corrosion inhibitor of 4~embodiment of embodiment 8 and its relative to the anti-incrustation corrosion inhibitor gross weight
Weight percent see the table below the terpolymer in 1(table 1 be acrylic acid/2- acrylamide-2-methyl propane sulfonic/tertiary fourth of N-
Base acrylamide copolymer).
The component and weight percent (wt%) of 1 anti-incrustation corrosion inhibitor of table
The preparation method is the same as that of Example 1 for the environment-friendly type anti-incrustation corrosion inhibitor of 4~embodiment of embodiment 8.
The anticorrosion-antiscaling property of environment-friendly type anti-incrustation corrosion inhibitor of the invention is detected.
(test example 1)
Water and fresh water press 1:1 as recirculated cooling water moisturizing in the use of Shanghai coke-oven plant, and water analysis is shown in Table 2.
2 Shanghai coke-oven plant moisturizing water analysis table of table
Remarks: calcium hardness, total hardness, total alkalinity are with CaCO3Meter.
It is middle hardness moderate alkalinity water quality that data, which can be seen that system supplement water, from table 2, is needed by user's requirement
It is run under 4 times of cycles of concentration, especially the moisturizing half is the middle water of sewage treatment plant, and content of microorganisms is high, and system has knot
The various problems such as dirt deposition, burn into biological clay, while District of Shanghai is located in the Changjiang river Taihu Lake basin, institute stringent to environmental requirement
The water treatment agent used is necessary for non-phosphate environment-friendly type medicament.
The environment-friendly type anti-incrustation corrosion inhibitor for using the cooling water of the coke-oven plant embodiment of the present invention 1, according to test tube monthly
Monitoring data, for carbon steel test tube corrosion rate in 0.02~0.04mm/a, carbon steel test tube adheres to rate in 5~10mcm, is much better than
National standard (national standard GB50050-2017 regulation corrosion of carbon steel rate≤0.075mm/a, carbon steel test tube adherency rate≤
15mcm)。
Operation opened heat exchanger after 24 months, and heat exchanger tube surface-brightening is also corrosion-free both without fouling and Stickydeposit, fills
The excellent antiscaling dispersion of bright medicament of the present invention of defending oneself, corrosion inhibition.
(test example 2)
Water is shown in Table 3 as circulating cooling make-up water, water analysis in the coal chemical industry enterprises whole use of the Inner Mongol.
3 Inner Mongol coal chemical industry enterprises water analysis table of table
Remarks: calcium hardness, total hardness, total alkalinity are with CaCO3Meter.
As can be seen from Table 3, system supplement water is high rigidity, high alkalinity water quality, chloride ion, sulfate ion
It is very high, have very strong fouling corrosion tendency, while moisturizing all is from middle water, content of microorganisms is high, can aggravate rotten under foundry loam
Erosion occurs.
The enterprise uses the environment-friendly type anti-incrustation corrosion inhibitor of the embodiment of the present invention 2, and run 24 months and observe: system is run just
Often, and cycles of concentration is stepped up from 2.5 times to 3 times or more, saves considerable operating cost for enterprise.
According to lacing film detection monthly, carbon steel lacing film corrosion rate is in 0.03~0.05mm/a, stainless steel, brass lacing film
Corrosion rate≤0.001mm/a, be much better than national standard (national standard GB50050-2017 provide corrosion of carbon steel rate≤
0.075mm/a, stainless steel, brass rate of corrosion≤0.005mm/a).
(test example 3)
Water is shown in Table 4 as circulating cooling make-up water, water analysis in the whole use of Beijing steam power plant.
4 Beijing steam power plant water analysis table of table
Remarks: calcium hardness, total hardness, total alkalinity are with CaCO3Meter.
As can be seen from Table 4, system supplement water is high calcium hardness, high total alkalinity water quality, has very strong fouling
Tendency.
The factory uses the environment-friendly type anti-incrustation corrosion inhibitor of the embodiment of the present invention 3, system normal operation, and cycles of concentration is from 2 times
It steps up to 2.5 times or more, coagulator observation, stainless steel coagulator heat exchanger tube surface-brightening, nothing is opened after operation 12 months
Fouling and Stickydeposit phenomenon.
Claims (9)
1. a kind of environment-friendly type anti-incrustation corrosion inhibitor, which is characterized in that each component and its weight relative to the anti-incrustation corrosion inhibitor gross weight
Measure percentage are as follows: hydrolysis of polymaleic anhydride 10%~15%, acrylic acid/2- acrylamide-2-methyl propane sulfonic/N- tert-butyl propylene
Amide terpolymer 14%~20%, ammonium persulfate 0.5%~1%, carboxyethyl thiosuccinic acid 5%~10%, sodium gluconate 5%
~8%, methyl benzotriazazole 1%~2%, surplus is deionized water.
2. environment-friendly type anti-incrustation corrosion inhibitor according to claim 1, it is characterised in that: acrylic acid/2- acrylamide -2- methyl
Propane sulfonic acid/N tert butyl acrylamide terpolymer is acrylic acid, 2- acrylamide-2-methyl propane sulfonic, N- tert-butyl third
The terpolymer that free radical polymerization obtains occurs under the action of ammonium persulfate initiator for three kinds of monomers of acrylamide, acrylic acid,
2- acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide mass ratio be 8~10: 3~5: 3~5.
3. environment-friendly type anti-incrustation corrosion inhibitor according to claim 2, it is characterised in that: the dosage of ammonium persulfate and acrylic acid
Mass ratio is 0.5~1: 8~10.
4. environment-friendly type anti-incrustation corrosion inhibitor according to claim 1, it is characterised in that: acrylic acid/2- acrylamide -2- methyl
Propane sulfonic acid/N tert butyl acrylamide terpolymer relative to the anti-incrustation corrosion inhibitor gross weight weight percent be 16%~
18%。
5. environment-friendly type anti-incrustation corrosion inhibitor according to claim 1, it is characterised in that: carboxyethyl thiosuccinic acid is relative to institute
The weight percent for stating anti-incrustation corrosion inhibitor gross weight is 5%~8%.
6. a kind of preparation method of environment-friendly type anti-incrustation corrosion inhibitor as described in claim 1, it is characterised in that the following steps are included:
1. preparing acrylic acid/2- acrylamide-2-methyl propane sulfonic/N tert butyl acrylamide terpolymer；
2. sequentially adding hydrolysis of polymaleic anhydride, carboxyethyl thiosuccinic acid, sodium gluconate, methylbenzene into terpolymer
And triazole and balance deionized water, it stirs；
3. filtering, pack.
7. the preparation method of environment-friendly type anti-incrustation corrosion inhibitor according to claim 6, it is characterised in that: step 1. in, by 2-
Acrylamide-2-methyl propane sulfonic, N tert butyl acrylamide and portions of de-ionized water successively put into reaction kettle, open stirring,
80 DEG C~90 DEG C, after reaching temperature are warming up to, ammonium persulfate aqueous solution and acrylic acid is added dropwise simultaneously respectively into reaction kettle, is added dropwise
Time is 3~4 hours, heat preservation is added dropwise 1~2 hour, obtains acrylic acid/2- acrylamide-2-methyl propane sulfonic/tertiary fourth of N-
Base acrylamide copolymer.
8. the preparation method of environment-friendly type anti-incrustation corrosion inhibitor according to claim 7, it is characterised in that: acrylic acid, 2- propylene
Amide -2- methyl propane sulfonic acid, N tert butyl acrylamide mass ratio be 8~10: 3~5: 3~5.
9. the preparation method of environment-friendly type anti-incrustation corrosion inhibitor according to claim 7, it is characterised in that: step 2. in, to step
Suddenly after 1. terpolymer obtained is cooled to room temperature, other materials are added.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7241391B1 (en) * | 2004-05-12 | 2007-07-10 | Cortec Corporation | Biodegradable scale and corrosion inhibitor composition |
| CN103833150A (en) * | 2014-02-21 | 2014-06-04 | 常州科威天使环保科技有限公司 | Dirt dispersion agent for circulating cooling water system and preparation method of dirt dispersion agent |
| CN104355419A (en) * | 2014-12-03 | 2015-02-18 | 天津天和环能科技有限公司 | Multifunctional scale and corrosion inhibitor and preparation method thereof |
| CN105800802A (en) * | 2016-05-21 | 2016-07-27 | 中山市绿浪助剂有限公司 | Composite type phosphorous-free corrosion and scale inhibitor |
| CN106145391A (en) * | 2016-08-16 | 2016-11-23 | 深圳市爱康泉水处理服务有限公司 | Anti-incrustation corrosion inhibitor compositions and anti-incrustation corrosion inhibitor and application thereof |
| CN108056107A (en) * | 2017-12-11 | 2018-05-22 | 常州中翔科技有限公司 | A kind of compound corrosion-mitigation scale-inhibition fungicide and preparation method thereof |
-
2018
- 2018-08-16 CN CN201810932737.5A patent/CN109052675A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7241391B1 (en) * | 2004-05-12 | 2007-07-10 | Cortec Corporation | Biodegradable scale and corrosion inhibitor composition |
| CN103833150A (en) * | 2014-02-21 | 2014-06-04 | 常州科威天使环保科技有限公司 | Dirt dispersion agent for circulating cooling water system and preparation method of dirt dispersion agent |
| CN104355419A (en) * | 2014-12-03 | 2015-02-18 | 天津天和环能科技有限公司 | Multifunctional scale and corrosion inhibitor and preparation method thereof |
| CN105800802A (en) * | 2016-05-21 | 2016-07-27 | 中山市绿浪助剂有限公司 | Composite type phosphorous-free corrosion and scale inhibitor |
| CN106145391A (en) * | 2016-08-16 | 2016-11-23 | 深圳市爱康泉水处理服务有限公司 | Anti-incrustation corrosion inhibitor compositions and anti-incrustation corrosion inhibitor and application thereof |
| CN108056107A (en) * | 2017-12-11 | 2018-05-22 | 常州中翔科技有限公司 | A kind of compound corrosion-mitigation scale-inhibition fungicide and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 许立国等: "《火电厂水处理技术》", 30 September 2006, 中国电力出版社 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111349528A (en) * | 2018-12-24 | 2020-06-30 | 上海梅山钢铁股份有限公司 | Chelating dispersant for cleaning scale in converter waste heat boiler and preparation method thereof |
| CN111943368A (en) * | 2019-05-14 | 2020-11-17 | 科威天使环保科技集团股份有限公司 | Grey water dispersant and preparation method thereof |
| CN112226772A (en) * | 2019-07-15 | 2021-01-15 | 中国石油化工股份有限公司 | Composite corrosion inhibitor and method for inhibiting carbon steel corrosion in Fischer-Tropsch synthesis reaction water by using same |
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| CN111533285A (en) * | 2020-04-20 | 2020-08-14 | 中国神华能源股份有限公司国华电力分公司 | Phosphorus-free slow-release scale inhibitor |
| CN113582332A (en) * | 2021-06-21 | 2021-11-02 | 四川弘业环保科技有限公司 | Sewage anaerobic stabilizing agent and preparation method thereof |
| CN114262071A (en) * | 2021-09-18 | 2022-04-01 | 自然资源部天津海水淡化与综合利用研究所 | Application of carbon steel corrosion inhibitor in reclaimed water heat supply network transmission and distribution |
| CN114262071B (en) * | 2021-09-18 | 2023-10-20 | 自然资源部天津海水淡化与综合利用研究所 | Application of carbon steel corrosion inhibitor in reclaimed water heating network transmission and distribution |
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