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CN109012160A - Device and method for treating volatile organic compounds in oilfield chamber and application of device and method - Google Patents

Device and method for treating volatile organic compounds in oilfield chamber and application of device and method Download PDF

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Publication number
CN109012160A
CN109012160A CN201810971513.5A CN201810971513A CN109012160A CN 109012160 A CN109012160 A CN 109012160A CN 201810971513 A CN201810971513 A CN 201810971513A CN 109012160 A CN109012160 A CN 109012160A
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CN
China
Prior art keywords
volatile organic
shell
oil field
organic compounds
air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810971513.5A
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Chinese (zh)
Inventor
周娟
张海玲
杨琴
赵敏
任小荣
李岩
周立辉
穆谦益
冀忠伦
邱奇
李照林
任鹏
刘宁
刘沛华
张璇
蒋继辉
朱妍
同宵
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Petrochina Co Ltd
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Petrochina Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petrochina Co Ltd filed Critical Petrochina Co Ltd
Priority to CN201810971513.5A priority Critical patent/CN109012160A/en
Publication of CN109012160A publication Critical patent/CN109012160A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • B01D46/12Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces in multiple arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

The invention provides a device and a method for treating volatile organic compounds in oil field rooms and application thereof, which are suitable for indoor places such as oil field oil and gas station pump rooms, dosing rooms, metering rooms, duty rooms and the like. The photocatalytic reactor can degrade volatile organic compounds into carbon dioxide and water, meets the environmental protection requirement and avoids secondary pollution.

Description

A kind of device and method and its application handling oil field indoor volatile organic compounds
Technical field
The present invention relates to a kind of device and method and its application for handling oil field indoor volatile organic compounds, are suitable for oil field The processing of oil gas station indoor volatile organic compounds.
Background technique
Indoor (between pump room, metering room, the dosing, duty room) VOCs in defeated turn of station of crude oil transmission technical process Crude Oil The group of (volatile organic compounds, volatile organic compounds) becomes C2-C12 hydro carbons, and major pollutants are Hexamethylene, benzene, toluene etc., its main source are pump static and dynamic sealing point, equipment checking maintenance or leakage, drug volatilization etc..By Do not circulate in room air, factors, the VOCs such as outdoor air pollution easily assemble indoors, and employee most of working time be Indoor development, even if VOCs concentration is very low, long term will also result in great threat in human body, to health.
Indoor VOCs control at present mainly uses absorption, plasma technique and photocatalysis technology, activity in adsorption technology The adsorbent materials such as charcoal, which are easily saturated, loses adsorption function, and the active carbon after absorption is dangerous waste;Plasma technique is decomposing dirt It is generated when contaminating object with by-products such as ozone, it can long-living secondary pollution;Photocatalysis technology at room temperature can be by contaminant degradation For carbon dioxide and water, but it not can solve suspended matter and particulate matter in air, and catalyst is easy inactivation.
Summary of the invention
The problem of first is that when solving absorption VOCs, adsorbent material is easily saturated the purpose of the present invention, loses adsorption function;Purpose Second is that can be carbon dioxide and water by contaminant degradation, while it can also adsorb large particle;Purpose avoids third is that protection environment Secondary pollution.
For this purpose, the present invention provides a kind of device for handling oil field indoor volatile organic compounds, the shell including pipeline shape, The bottom port of the shell is air inlet, and top port is gas outlet, and outlet port is installed with blower, and the blower is explosion-proof Blower, housing cavity are successively installed with low efficient filter screen, high efficiency particulate air and photo catalysis reactor to gas outlet from air inlet;
Volatile organic gases enters in shell from shell air inlet, by low efficient filter screen by this kind of big of hair, willow catkins flying in the air Grain object filters out, and filters out dust, this kind of partial size of pollen in 0.3 micron or more of finely ground particles using high efficiency particulate air, most Enter photo catalysis reactor afterwards, light-catalyzed reaction occurs, volatile organic matter is degraded to carbon dioxide and water, the gas after reaction Body is discharged through shell gas outlet.
Further, the photo catalysis reactor includes square casing, and the upper lower opposite face of square casing is strainer shape, side More ultraviolet tubes are disposed in shape shell, square casing surrounding inner wall is covered with activated carbon fibre, the surface of activated carbon fibre Coated with TiO 2-based catalyst.
Further, particulate matter can be monitored and detection is waved by being mounted on the tube wall of the air inlet and air outlet of the shell The VOCs detection sensor of hair property organic concentration.
Further, the low efficient filter screen is non-woven fabrics, and high efficiency particulate air is glass filter paper.
Further, the low efficient filter screen and high efficiency particulate air are radially laid on housing cavity along the internal diameter of shell, The square casing of photo catalysis reactor is immobilized in the shell on tube wall.
Further, the ultraviolet tube is covered with Explosion-proof globe.
Further, a method of processing oil field indoor volatile organic compounds are had using volatility in processing oil field room The device of machine object, includes the following steps:
It opens blower and ultraviolet tube, volatile organic gases enters in shell from shell air inlet, by low efficient filter screen This kind of large particle of hair, willow catkins flying in the air is filtered out, using high efficiency particulate air by dust, this kind of partial size of pollen 0.3 micron with On finely ground particles filter out, finally enter photo catalysis reactor, volatile organic matter, which is adsorbed, is gathered in active carbon fibre dimension table Under the action of ultraviolet tube and TiO 2-based catalyst light-catalyzed reaction occurs for face, and volatile organic matter is degraded to Carbon dioxide and water, the gas after reaction are discharged through shell gas outlet;
Further, the volatile organic matter is during catalysis oxidation, in VOCs detection sensor real-time display shell The concentration of chamber particulate matter and volatile organic matter.
Further, a kind of application for the device handling oil field indoor volatile organic compounds: volatility in processing oil field room The device of organic matter be fixedly mounted between pump room, metering room, dosing or the indoor wall of duty room on, and bottom end distance ground Face 110cm, handle oil field indoor volatile organic compounds device far between pump room, metering room, dosing or duty room go out Mouthful.
Beneficial effects of the present invention: the device and method of this processing oil field indoor volatile organic compounds provided by the invention And its application, be applicable in oilfield station pump house, between dosing, the indoor spaces such as metering room and duty room, volatile organic matter according to It is secondary to pass through low efficient filter screen and high efficiency particulate air, fine particle is filtered out, photo catalysis reactor is entered back into, VOCs is adsorbed It degrades, the VOCs of the carbon fiber adsorption and catalytic combustion in photo catalysis reactor regenerates after photocatalysis removes, and extends using the longevity Life, solves the problem of existing adsorbent material is easily saturated, loses adsorption function.Photo catalysis reactor can the property of will volatilize organic matter It is degraded to carbon dioxide and water, meets environmental requirement, avoids secondary pollution.
The present invention is described in further details below with reference to attached drawing.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for handling the device of oil field indoor volatile organic compounds.
Fig. 2 is the side view for handling the device of oil field indoor volatile organic compounds.
Fig. 3 is the flow diagram for handling the method for oil field indoor volatile organic compounds.
Description of symbols:
1. shell;2. low efficient filter screen;3. high efficiency particulate air;4. photo catalysis reactor;5. ultraviolet lamp;6.VOCs detection sensing Device;7. blower.
Specific embodiment
Embodiment 1:
As depicted in figs. 1 and 2, a kind of device for handling oil field indoor volatile organic compounds, including pipeline are present embodiments provided The bottom port of the shell 1 of shape, the shell 1 is air inlet, and top port is gas outlet, and outlet port is installed with blower 7, shell 1 inner cavity of body is successively installed with low efficient filter screen 2, high efficiency particulate air 3 and photo catalysis reactor 4 from air inlet to gas outlet;
Volatile organic gases enters in shell 1 from 1 air inlet of shell, by low efficient filter screen 2 by this kind of big of hair, willow catkins flying in the air Particulate matter filters out, and filters out dust, this kind of partial size of pollen in 0.3 micron or more of finely ground particles using high efficiency particulate air 3, Photo catalysis reactor 4 is finally entered, light-catalyzed reaction occurs, volatile organic matter is degraded to carbon dioxide and water, after reaction Gas through 1 gas outlet of shell be discharged.
Specifically, the device of this processing oil field indoor volatile organic compounds provided by the invention, is applicable in oilfield field It stands between pump house, dosing, indoor spaces, the volatile organic matter such as metering room and duty room successively pass through low efficient filter screen and efficient mistake Strainer filters out fine particle, enters back into photo catalysis reactor, VOCs is carried out absorption degradation, the work in photo catalysis reactor Property Carbon fibe absorption VOCs regenerated after photocatalysis removes, extend service life, it is easy to solve existing adsorbent material The problem of being saturated, losing adsorption function.Photo catalysis reactor can the property of will volatilize organic matter degradation be carbon dioxide and water, meet Environmental requirement avoids secondary pollution.
Embodiment 2:
On the basis of embodiment 1, specifically, the photo catalysis reactor 4 includes square casing, the opposition up and down of square casing Face is strainer shape, is disposed with more ultraviolet tubes 5 in square casing, and square casing surrounding inner wall is covered with activated carbon fibre, living Property Carbon fibe surface be coated with TiO 2-based catalyst.
It should be noted that the course of work of photo catalysis reactor 4 is as follows:
TiO 2-based catalyst is coated to activated carbon fibre surface, is attached to the above and below of square casing, in square casing Four or five ultraviolet tubes 5 of arrangement are used as light source, and VOCs is gathered in after entering photo catalysis reactor 4 in active carbon fibre dimension table Carbon dioxide and water are resolved under ultraviolet light and catalyst action in face.
Compared with existing adsorption technology or photocatalysis technology, photo catalysis reactor 4 provided in this embodiment can will pollute Object is degraded to carbon dioxide and water, while can also adsorb large particle, particularly first passes through double-filtration net and removes in VOCs Large particle, then the VOCs on activated carbon fibre surface is degraded to carbon dioxide and water by light-catalyzed reaction, that is to say, that VOCs in activated carbon fibre can be degraded immediately in adsorption saturation, that is, solve existing absorption VOCs by activated carbon fibre When, adsorbent material is easily saturated, the problem of losing adsorption function.Therefore, the VOCs of the carbon fiber adsorption and catalytic combustion of the present embodiment is through light It is regenerated after catalytic action removal, extends service life.
Embodiment 3:
On the basis of embodiment 1, as shown in Figure 1, being mounted on the tube wall of the air inlet and air outlet of the shell 1 can supervise It surveys particulate matter and detects the VOCs detection sensor 6 of volatile organic matter concentration.
Particulate matter and detection volatile organic matter concentration can be monitored in real time in VOCs detection sensor 6, and staff can be with The concentration value of observation volatile organic matter in real time, it is ensured that the normal operation of the device of processing oil field indoor volatile organic compounds.It needs It should be particularly noted that, VOCs detection sensor be it is existing can be commercially available, specific structure is not as guarantor of the invention Point is protected, therefore is not described in detail.
Embodiment 4:
On the basis of embodiment 1, preferably, the low efficient filter screen 2 is non-woven fabrics, high efficiency particulate air 3 is glass filter paper. The low efficient filter screen 2 and high efficiency particulate air 3 are radially laid on 1 inner cavity of shell, photo catalysis reactor 4 along the internal diameter of shell 1 Square casing be fixed on 1 inner tubal wall of shell.
Embodiment 5:
On the basis of embodiment 2, the blower 7 is explosion-proof fan, and ultraviolet tube 5 is covered with Explosion-proof globe.Therefore at entirety The device of reason oil field indoor volatile organic compounds meets explosion-proof criteria.
Embodiment 6:
A method of processing oil field indoor volatile organic compounds, using the device of processing oil field indoor volatile organic compounds, such as Shown in Fig. 3, include the following steps:
Blower 7 and ultraviolet tube 5 are opened, under the action of blower 7, volatile organic gases enters shell from 1 air inlet of shell In body 1, this kind of large particle of hair, willow catkins flying in the air is filtered out by low efficient filter screen 2, using high efficiency particulate air 3 by dust, flower This kind of partial size of powder is filtered out in 0.3 micron or more of finely ground particles, finally enters photo catalysis reactor 4, volatile organic matter quilt Adsorpting aggregation is on activated carbon fibre surface, and under the action of ultraviolet tube 5 and TiO 2-based catalyst, it is anti-that photocatalysis occurs It answers, volatile organic matter is degraded to carbon dioxide and water, and the gas after reaction is discharged through 1 gas outlet of shell.
Specifically, air-flow enters device, filters out the large particles such as hair, willow catkins flying in the air by low efficient filter screen 2, using height It imitates finely ground particles of the filter screen 3 by partial sizes such as dust, pollen at 0.3 micron or more to filter out, it is anti-to enter photocatalysis later Area is answered, VOCs is attracted to activated carbon fibre surface, and under ultraviolet lamp irradiation, TiO 2-based catalyst divides VOCs oxidation Solution is carbon dioxide and water.
Light-catalyzed reaction area, inner wall attachment activity Carbon fibe catalyst layer, activated carbon fibre specific surface area is larger, have compared with Big adsorption capacity.Using the adsorption function of activated carbon fibre, the concentration of activated carbon fibre surface VOCs increases, and VOCs is adsorbed on two Titania-based catalyst particle periphery, ultraviolet lamp irradiation under, occur light-catalyzed reaction, VOCs be degraded to carbon dioxide and Water.Meanwhile the VOCs of carbon fiber adsorption and catalytic combustion regenerates after photocatalysis removes, and extends service life.
Embodiment 7:
On the basis of embodiment 6, in order to ensure the normal operation of device, to prevent going wrong, the volatile organic matter exists During catalysis oxidation, the concentration of 6 real-time display shell of VOCs detection sensor 1 inner cavity particulate matter and volatile organic matter.
Embodiment 8:
A kind of application for the device handling oil field indoor volatile organic compounds: the device of processing oil field indoor volatile organic compounds is solid Dingan County is between pump room, metering room, dosing or on the indoor wall of duty room, and bottom end is apart from ground 110cm, processing oil The device of field indoor volatile organic compounds is far between pump room, metering room, the dosing or outlet of duty room.
The device of this processing oil field indoor volatile organic compounds provided by the invention, applicable oilfield station pump house, Between dosing, indoor spaces, the volatile organic matter such as metering room and duty room successively pass through low efficient filter screen and high efficiency particulate air, will Fine particle filters out, and enters back into photo catalysis reactor, VOCs is carried out absorption degradation, the activated carbon fibre in photo catalysis reactor The VOCs of absorption regenerates after photocatalysis removes, and extends service life, solves existing adsorbent material and is easily saturated, loses The problem of adsorption function.Photo catalysis reactor can the property of will volatilize organic matter degradation be carbon dioxide and water, meet environmental requirement, Avoid secondary pollution.
The foregoing examples are only illustrative of the present invention, does not constitute the limitation to protection scope of the present invention, all It is within being all belonged to the scope of protection of the present invention with the same or similar design of the present invention.The portion that the present embodiment does not describe in detail The well-known components and common structure or conventional means of part and the structure category industry, do not describe one by one here.

Claims (8)

1. a kind of device for handling oil field indoor volatile organic compounds, it is characterised in that: the shell (1) including pipeline shape, it is described The bottom port of shell (1) is air inlet, and top port is gas outlet, and outlet port is installed with blower (7), the blower (7) For explosion-proof fan, shell (1) inner cavity be successively installed with from air inlet to gas outlet low efficient filter screen (2), high efficiency particulate air (3) and Photo catalysis reactor (4);
Volatile organic gases enters in shell (1) from shell (1) air inlet, by low efficient filter screen (2) by hair, willow catkins flying in the air this The large particle of class filters out, using high efficiency particulate air (3) by dust, this kind of partial size of pollen in small of 0.3 micron or more Grain object filters out, and finally enters photo catalysis reactor (4), and light-catalyzed reaction occurs, and volatile organic matter is degraded to carbon dioxide And water, the gas after reaction are discharged through shell (1) gas outlet.
2. the device of processing oil field indoor volatile organic compounds as described in claim 1, it is characterised in that: the photocatalysis is anti- Answering device (4) includes square casing, and the upper lower opposite face of square casing is strainer shape, is disposed with more ultraviolet lamps in square casing It manages (5), square casing surrounding inner wall is covered with activated carbon fibre, and the surface of activated carbon fibre is coated with TiO 2-based catalyst.
3. the device of processing oil field indoor volatile organic compounds as described in claim 1, it is characterised in that: the shell (1) Air inlet and air outlet tube wall on be mounted on can monitor particulate matter and detect volatile organic matter concentration VOCs detection Sensor (6).
4. the device of processing oil field indoor volatile organic compounds as described in claim 1, it is characterised in that: the thick effect filtering Net (2) is non-woven fabrics, and high efficiency particulate air (3) is glass filter paper.
5. the device of processing oil field indoor volatile organic compounds as claimed in claim 2, it is characterised in that: the thick effect filtering Net (2) and high efficiency particulate air (3) are radially laid on shell (1) inner cavity along the internal diameter of shell (1), photo catalysis reactor (4) Square casing is fixed on shell (1) inner tubal wall.
6. the device of processing oil field indoor volatile organic compounds as claimed in claim 2, it is characterised in that: the ultraviolet lamp Pipe (5) is covered with Explosion-proof globe.
7. a kind of method of the processing oil field indoor volatile organic compounds as described in any claim in claim 1~6, is adopted With the device of processing oil field indoor volatile organic compounds, which comprises the steps of:
Blower (7) and ultraviolet tube (5) are opened, volatile organic gases enters in shell (1) from shell (1) air inlet, warp Low efficient filter screen (2) is crossed to filter out this kind of large particle of hair, willow catkins flying in the air, using high efficiency particulate air (3) by dust, pollen this Class partial size is filtered out in 0.3 micron or more of finely ground particles, finally enters photo catalysis reactor (4), and volatile organic matter is inhaled It is attached to be gathered in activated carbon fibre surface, under the action of ultraviolet tube (5) and TiO 2-based catalyst, it is anti-that photocatalysis occurs It answers, volatile organic matter is degraded to carbon dioxide and water, and the gas after reaction is discharged through shell (1) gas outlet;
The volatile organic matter is during catalysis oxidation, VOCs detection sensor (6) real-time display shell (1) inner cavity The concentration of grain object and volatile organic matter.
8. a kind of application for the device for handling oil field indoor volatile organic compounds, it is characterised in that: volatility in processing oil field room The device of organic matter be fixedly mounted between pump room, metering room, dosing or the indoor wall of duty room on, and bottom end distance ground Face 110cm, handle oil field indoor volatile organic compounds device far between pump room, metering room, dosing or duty room go out Mouthful.
CN201810971513.5A 2018-08-24 2018-08-24 Device and method for treating volatile organic compounds in oilfield chamber and application of device and method Pending CN109012160A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810971513.5A CN109012160A (en) 2018-08-24 2018-08-24 Device and method for treating volatile organic compounds in oilfield chamber and application of device and method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810971513.5A CN109012160A (en) 2018-08-24 2018-08-24 Device and method for treating volatile organic compounds in oilfield chamber and application of device and method

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CN109012160A true CN109012160A (en) 2018-12-18

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109794162A (en) * 2019-01-24 2019-05-24 河海大学 An indoor volatile organic compound removal device based on thermal desorption and cold extraction
CN119860951A (en) * 2023-10-20 2025-04-22 中国石油天然气股份有限公司 Volatile organic compound detection device with cleaning function and sampling method thereof

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CN200948409Y (en) * 2006-01-20 2007-09-19 中国科学院广州地球化学研究所 Air purifier based on titanium dioxide/activated carbon fiber photocatalyst
CN101371929A (en) * 2008-10-14 2009-02-25 广东工业大学 Photocatalytic air purifier with light emitting diode as light source
CN201399313Y (en) * 2009-04-21 2010-02-10 张国栋 An indoor air purification device
CN204006398U (en) * 2014-08-21 2014-12-10 天津城建大学 Vehicular solar photocatalysis air cleaning device
CN204447757U (en) * 2015-02-02 2015-07-08 广东东日环保有限公司 A kind of organic pollutant photocatalyst treating apparatus
CN207056335U (en) * 2017-07-12 2018-03-02 青岛青力环保设备有限公司 A kind of box photo catalysis reactor
CN207430012U (en) * 2017-09-28 2018-06-01 中国石油天然气股份有限公司 Oil field volatile organic compound processing apparatus

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200948409Y (en) * 2006-01-20 2007-09-19 中国科学院广州地球化学研究所 Air purifier based on titanium dioxide/activated carbon fiber photocatalyst
CN101371929A (en) * 2008-10-14 2009-02-25 广东工业大学 Photocatalytic air purifier with light emitting diode as light source
CN201399313Y (en) * 2009-04-21 2010-02-10 张国栋 An indoor air purification device
CN204006398U (en) * 2014-08-21 2014-12-10 天津城建大学 Vehicular solar photocatalysis air cleaning device
CN204447757U (en) * 2015-02-02 2015-07-08 广东东日环保有限公司 A kind of organic pollutant photocatalyst treating apparatus
CN207056335U (en) * 2017-07-12 2018-03-02 青岛青力环保设备有限公司 A kind of box photo catalysis reactor
CN207430012U (en) * 2017-09-28 2018-06-01 中国石油天然气股份有限公司 Oil field volatile organic compound processing apparatus

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109794162A (en) * 2019-01-24 2019-05-24 河海大学 An indoor volatile organic compound removal device based on thermal desorption and cold extraction
CN109794162B (en) * 2019-01-24 2020-09-22 河海大学 Indoor volatile organic compound removing device based on thermal desorption and cold extraction
CN119860951A (en) * 2023-10-20 2025-04-22 中国石油天然气股份有限公司 Volatile organic compound detection device with cleaning function and sampling method thereof

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Application publication date: 20181218