CN108996629A - Potassium Monopersulfate compound effervescent tablet and preparation method thereof for the improvement of water quality substrate - Google Patents
Potassium Monopersulfate compound effervescent tablet and preparation method thereof for the improvement of water quality substrate Download PDFInfo
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- CN108996629A CN108996629A CN201811006745.3A CN201811006745A CN108996629A CN 108996629 A CN108996629 A CN 108996629A CN 201811006745 A CN201811006745 A CN 201811006745A CN 108996629 A CN108996629 A CN 108996629A
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- parts
- sodium
- potassium
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- water quality
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- 239000012425 OXONE® Substances 0.000 title claims abstract description 42
- -1 Potassium Monopersulfate compound Chemical class 0.000 title claims abstract description 35
- 239000007938 effervescent tablet Substances 0.000 title claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 230000006872 improvement Effects 0.000 title claims abstract description 21
- 239000000758 substrate Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 29
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 28
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 25
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims abstract description 25
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 16
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 15
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 14
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 14
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000008116 calcium stearate Substances 0.000 claims abstract description 13
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 13
- 229940037627 magnesium lauryl sulfate Drugs 0.000 claims abstract description 13
- HBNDBUATLJAUQM-UHFFFAOYSA-L magnesium;dodecyl sulfate Chemical compound [Mg+2].CCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCCCCCCOS([O-])(=O)=O HBNDBUATLJAUQM-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 13
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 13
- OKBMCNHOEMXPTM-UHFFFAOYSA-M potassium peroxymonosulfate Chemical compound [K+].OOS([O-])(=O)=O OKBMCNHOEMXPTM-UHFFFAOYSA-M 0.000 claims abstract description 13
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 12
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 12
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001110 calcium chloride Substances 0.000 claims abstract description 12
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 12
- 235000011090 malic acid Nutrition 0.000 claims abstract description 12
- 239000001630 malic acid Substances 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 12
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 claims abstract description 11
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 9
- 235000015165 citric acid Nutrition 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 12
- HDMGAZBPFLDBCX-UHFFFAOYSA-M potassium;sulfooxy sulfate Chemical compound [K+].OS(=O)(=O)OOS([O-])(=O)=O HDMGAZBPFLDBCX-UHFFFAOYSA-M 0.000 claims description 11
- 239000003826 tablet Substances 0.000 claims description 9
- 229960004106 citric acid Drugs 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 6
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 claims description 4
- 229960004543 anhydrous citric acid Drugs 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 230000001954 sterilising effect Effects 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 238000006213 oxygenation reaction Methods 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 8
- 206010016766 flatulence Diseases 0.000 description 8
- 235000017550 sodium carbonate Nutrition 0.000 description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000005030 aluminium foil Substances 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 3
- 244000248349 Citrus limon Species 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000607598 Vibrio Species 0.000 description 3
- 206010047400 Vibrio infections Diseases 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Medicinal Preparation (AREA)
Abstract
The present invention relates to chemical fields, disclose a kind of Potassium Monopersulfate compound effervescent tablet and preparation method thereof for the improvement of water quality substrate, it is grouped as by the group of following parts by weight: 20 ~ 50 parts of potassium peroxymonosulfate, sodium peroxydisulfate, SODIUM PERCARBONATE or 10 ~ 20 parts of percarbamide, anhydrous sodium sulfate, anhydrous magnesium sulfate or 0 ~ 20 part of calcium chloride, sodium carbonate or 5 ~ 10 parts of sodium bicarbonate, citric acid or 10 ~ 20 parts of malic acid, polyvinylpyrrolidone or 3 ~ 5 parts of magnesium laurylsulfate, magnesium stearate or 0.1 ~ 0.5 part of calcium stearate.Sterilization effect, oxygenation effect, detoxifying effect and the stability for the compound effervescent tablet that method in the present invention is prepared are superior to similar product.
Description
Technical field
The present invention relates to chemical field, in particular to a kind of Potassium Monopersulfate for the improvement of water quality substrate is compound
Effervescent tablet and preparation method thereof.
Background technique
Currently, potassium peroxymonosulfate product sterilizing function in the market is poor, product stability is bad, and corrosivity is too
By force, potassium peroxymonosulfate is a kind of strong oxidizer, and oxidation enhances in acidic environment, cannot such as provide acyclic acidic
Border, sterilization effect are very poor；The stabilizer that product is selected is critically important, potassium peroxymonosulfate water during compounding, film-making
Divide exceeded, the excessively high oxidation of temperature that will display, easily corrodes packaging, or even the danger of flatulence, explosion occurs.
Summary of the invention
Goal of the invention: aiming at the problems existing in the prior art, the present invention provides a kind of for the improvement of water quality substrate
Potassium Monopersulfate compound effervescent tablet and preparation method thereof, sterilization effect, oxygenation effect, the detoxifying effect of the compound effervescent tablet
And stability is superior to similar product.
Technical solution: the present invention provides a kind of Potassium Monopersulfate composite effervescents for the improvement of water quality substrate
Piece is grouped as by the group of following parts by weight: 20 ~ 50 parts of potassium peroxymonosulfate, sodium peroxydisulfate, SODIUM PERCARBONATE or mistake phosphinylidyne
10 ~ 20 parts of amine, anhydrous sodium sulfate, anhydrous magnesium sulfate or 0 ~ 20 part of calcium chloride, sodium carbonate or 5 ~ 10 parts of sodium bicarbonate, citric acid or
10 ~ 20 parts of malic acid, polyvinylpyrrolidone or 3 ~ 5 parts of magnesium laurylsulfate, magnesium stearate or 0.1 ~ 0.5 part of calcium stearate.
Preferably, the Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate, by following parts by weight
Group be grouped as: 50 parts of potassium hydrogen persulfate composite salts, 10 parts of sodium peroxydisulfate, 10 parts of anhydrous sodium sulfate, 5 parts of sodium bicarbonate, apple
20 parts of tartaric acid, 4.5 parts of magnesium laurylsulfate, 0.5 part of magnesium stearate.
Preferably, the Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate, by following parts by weight
Group be grouped as: 40 parts of potassium hydrogen persulfate composite salts, 10 parts of SODIUM PERCARBONATE, 15 parts of anhydrous magnesium sulfate, 5 parts of sodium carbonate, lemon
15 parts, 4.5 parts of polyvinylpyrrolidone, 0.5 part of calcium stearate of acid.
Preferably, the Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate, by following parts by weight
Group be grouped as: 30 parts of potassium hydrogen persulfate composite salts, 20 parts of SODIUM PERCARBONATE, 20 parts of anhydrous magnesium sulfate, 10 parts of sodium carbonate, apple
10 parts, 3 parts of polyvinylpyrrolidone, 0.2 part of calcium stearate of acid.
Preferably, the Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate, by following parts by weight
Group be grouped as: into 20 parts of a potassium acid sulfate complex salt, 20 parts of percarbamide, 20 parts of calcium chloride, 8 parts of sodium bicarbonate, citric acid
10 parts, 5 parts of magnesium laurylsulfate, 0.1 part of magnesium stearate.
The present invention also provides a kind of preparations of Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate
Method, comprising the following steps: S1: by above-mentioned all raw material moisture controls below 1%；S2: successively that Potassium Monopersulfate is compound
Salt, malic acid or citric acid, anhydrous sodium sulfate, anhydrous magnesium sulfate or calcium chloride, sodium peroxydisulfate, SODIUM PERCARBONATE or percarbamide,
Polyvinylpyrrolidone or magnesium laurylsulfate, magnesium stearate or calcium stearate are mixed evenly；S3: it is lower than 30 in temperature
DEG C, in environment of the relative humidity less than 50%, the tablet or particle of different shape, weight are made of pelletizer or rotary pelleting machine.
The utility model has the advantages that the Potassium Monopersulfate compound effervescent tablet in the present invention is during the preparation process, according to avoiding soda acid, oxygen
Each component is successively uniformly mixed by the sequence for changing reduction reaction.Such as sodium peroxydisulfate, SODIUM PERCARBONATE or percarbamide it
Anhydrous sodium sulfate, anhydrous magnesium sulfate or calcium chloride is added before preceding addition, enables potassium peroxymonosulfate anhydrous
Sodium sulphate, anhydrous magnesium sulfate or calcium chloride dilution, cladding, enable potassium peroxymonosulfate and sodium peroxydisulfate, percarbonic acid
Sodium or percarbamide isolation, prevent from chemically reacting therebetween, increase the stability of effervescent tablet in the present invention.
The present invention has the advantage that compared with similar products
(1) due to the presence of stabilizer anhydrous sodium sulfate, anhydrous magnesium sulfate or calcium chloride, so that the monopersulfate in the present invention
The stability of potassium compound effervescent tablet is good, relatively wet in temperature 50 C after being sealed with market similar product using identical aluminium foil bag
It spends in 60% environment after storing 7 days, similar product obviously generates flatulence, aluminium foil bag seriously corroded, and this formulation product is not any
Flatulence, packaging bag are intact；
(2) due to containing organic acid in product of the present invention --- citric acid or malic acid composition are rich in vitamin C, can effectively solve
Except the toxin in water body, sterilization effect is significant；After this product is dissolved in water, inject in vibrios and Escherichia coli culture dish, sterilizing rate
Up to 99.5% or more, it is 2-3 times of similar product；
(3) due to the presence of sodium peroxydisulfate, SODIUM PERCARBONATE or percarbamide, oxygenation effect is increased, makes the active oxygen of this product
Content is as many as 3 times of market similar product up to 6%.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.
Embodiment 1:
Present embodiments provide for a kind of Potassium Monopersulfate compound effervescent tablets for the improvement of water quality substrate, by following heavy
The group of amount part is grouped as: 50 parts of potassium hydrogen persulfate composite salts, 10 parts of sodium peroxydisulfate, and 10 parts of anhydrous sodium sulfate, sodium bicarbonate 5
Part, 20 parts of malic acid, 4.5 parts of magnesium laurylsulfate, 0.5 part of magnesium stearate.
Above-mentioned Potassium Monopersulfate compound effervescent tablet is prepared by following steps: successively that potassium hydrogen peroxymonosulfate is compound
Salt, malic acid, anhydrous sodium sulfate, sodium peroxydisulfate, sodium bicarbonate, magnesium laurylsulfate, magnesium stearate are added to V-type or multidigit is mixed
It is mixed 15 minutes in conjunction machine, is lower than 30 DEG C in temperature after blanking, uses pelletizer or rotation in environment of the relative humidity less than 50%
Turn tablet or particle that dimension is made in tablet press machine.
Embodiment 2:
Present embodiments provide for a kind of Potassium Monopersulfate compound effervescent tablets for the improvement of water quality substrate, by following heavy
The group of amount part is grouped as: 40 parts of potassium hydrogen persulfate composite salts, 10 parts of SODIUM PERCARBONATE, and 15 parts of anhydrous magnesium sulfate, 5 parts of sodium carbonate,
15 parts of citric acid, 4.5 parts of polyvinylpyrrolidone, 0.5 part of calcium stearate.
Above-mentioned Potassium Monopersulfate compound effervescent tablet is prepared by following steps: successively that potassium hydrogen peroxymonosulfate is compound
Salt, citric acid, anhydrous magnesium sulfate, SODIUM PERCARBONATE, sodium carbonate, polyvinylpyrrolidone, calcium stearate are added to V-type or multidigit is mixed
It is mixed 15 minutes in conjunction machine, is lower than 30 DEG C in temperature after blanking, uses pelletizer or rotation in environment of the relative humidity less than 50%
Turn tablet or particle that dimension is made in tablet press machine.
Embodiment 3:
Present embodiments provide for a kind of Potassium Monopersulfate compound effervescent tablets for the improvement of water quality substrate, by following heavy
The group of amount part is grouped as: 30 parts of potassium hydrogen persulfate composite salts, 20 parts of SODIUM PERCARBONATE, and 20 parts of anhydrous magnesium sulfate, 10 parts of sodium carbonate,
10 parts of malic acid, 3 parts of polyvinylpyrrolidone, 0.2 part of calcium stearate.
Above-mentioned Potassium Monopersulfate compound effervescent tablet is prepared by following steps: successively that potassium hydrogen peroxymonosulfate is compound
Salt, malic acid, anhydrous magnesium sulfate, SODIUM PERCARBONATE, sodium carbonate, polyvinylpyrrolidone, calcium stearate are added to V-type or multidigit is mixed
It is mixed 15 minutes in conjunction machine, is lower than 30 DEG C in temperature after blanking, uses pelletizer or rotation in environment of the relative humidity less than 50%
Turn tablet or particle that dimension is made in tablet press machine.
Embodiment 4:
Present embodiments provide for a kind of Potassium Monopersulfate compound effervescent tablets for the improvement of water quality substrate, by following heavy
The group of amount part is grouped as: 20 parts of potassium hydrogen persulfate composite salts, 20 parts of percarbamide, and 20 parts of calcium chloride, 8 parts of sodium bicarbonate, lemon
10 parts, 5 parts of magnesium laurylsulfate, 0.1 part of magnesium stearate of lemon acid.
Above-mentioned Potassium Monopersulfate compound effervescent tablet is prepared by following steps: successively that potassium hydrogen peroxymonosulfate is compound
Salt, citric acid, calcium chloride, percarbamide, sodium bicarbonate, magnesium laurylsulfate, magnesium stearate are added to V-type or multidigit mixing machine
It is middle to be mixed 15 minutes, it is lower than 30 DEG C in temperature after blanking, is pressed in environment of the relative humidity less than 50% with pelletizer or rotation
The tablet or particle of dimension are made in piece machine.
Comparative example: existing common Potassium Monopersulfate compound effervescent tablet component is as follows: ammonium persulfate-sodium bisulfate 10-30
Part, 60-70 parts of anhydrous sodium sulphate, sodium bicarbonate or 5 parts of soda ash, 0.1-0.2 parts of magnesium stearate.
Embodiment 1 to 4 is compared with the stability of the Potassium Monopersulfate compound effervescent tablet in comparative example, is made
It is sealed, is stored in temperature 50 C, 60% environment of relative humidity 7 days, as a result such as table 1 with identical aluminium foil bag.
Table 1
| Number | Aluminium foil bag corrosion condition | Whether there is or not flatulence generations |
| Embodiment 1 | It is corrosion-free | Without flatulence |
| Embodiment 2 | It is corrosion-free | Without flatulence |
| Embodiment 3 | It is corrosion-free | Without flatulence |
| Comparative example | Seriously corroded | Generate obvious flatulence |
The stability of the Potassium Monopersulfate compound effervescent tablet in the present invention is more excellent compared with similar product as can be seen from Table 1.
Embodiment 1 to 4 is compared with the sterilization effect of the Potassium Monopersulfate compound effervescent tablet in comparative example, it will
Product in embodiment 1 to 4 and comparative example is dissolved in water respectively, is then injected into the vibrios and Escherichia coli culture dish of equivalent,
It is detected using MPN counting method method, as a result such as table 2.
Table 2
| Number | Vibrios sterilizing rate | Escherichia coli sterilizing rate |
| Embodiment 1 | 99.5% | 99.8% |
| Embodiment 2 | 99.7% | 99.9% |
| Embodiment 3 | 99.5% | 99.7% |
| Comparative example | 86.7% | 88.1% |
The sterilizing rate of the Potassium Monopersulfate compound effervescent tablet in the present invention is up to 99.5% or more as can be seen from Table 2, is similar
2-3 times of product.
Embodiment 1 to 4 is compared with the oxygenation effect of the Potassium Monopersulfate compound effervescent tablet in comparative example, is made
It is detected with fluorescence probe DCFH-DA detection method method, as a result such as table 3.
Table 3
| Number | Active o content |
| Embodiment 1 | 6.15% |
| Embodiment 2 | 6.21% |
| Embodiment 3 | 6.18% |
| Comparative example | 2.24% |
From table 3 it can be seen that the active o content of this product is up to 6%, it is as many as 3 times of market similar product.
The technical concepts and features of above embodiment only to illustrate the invention, its object is to allow be familiar with technique
People cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention
The equivalent transformation or modification that Spirit Essence is done, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of Potassium Monopersulfate compound effervescent tablet for the improvement of water quality substrate, which is characterized in that by following weight
The group of part is grouped as: 20 ~ 50 parts of potassium peroxymonosulfate, sodium peroxydisulfate, SODIUM PERCARBONATE or 10 ~ 20 parts of percarbamide, and nothing
Aqueous sodium persulfate, anhydrous magnesium sulfate or 0 ~ 20 part of calcium chloride, sodium carbonate or 5 ~ 10 parts of sodium bicarbonate, citric acid or malic acid 10 ~ 20
Part, polyvinylpyrrolidone or 3 ~ 5 parts of magnesium laurylsulfate, magnesium stearate or 0.1 ~ 0.5 part of calcium stearate.
2. the Potassium Monopersulfate compound effervescent tablet according to claim 1 for the improvement of water quality substrate, feature
It is, is grouped as by the group of following parts by weight: 50 parts of potassium hydrogen persulfate composite salts, 10 parts of sodium peroxydisulfate, anhydrous sodium sulfate 10
Part, 5 parts of sodium bicarbonate, 20 parts of malic acid, 4.5 parts of magnesium laurylsulfate, 0.5 part of magnesium stearate.
3. the Potassium Monopersulfate compound effervescent tablet according to claim 1 for the improvement of water quality substrate, feature
It is, is grouped as by the group of following parts by weight: 40 parts of potassium hydrogen persulfate composite salts, 10 parts of SODIUM PERCARBONATE, anhydrous magnesium sulfate 15
Part, 5 parts of sodium carbonate, 15 parts of citric acid, 4.5 parts of polyvinylpyrrolidone, 0.5 part of calcium stearate.
4. the Potassium Monopersulfate compound effervescent tablet according to claim 1 for the improvement of water quality substrate, feature
It is, is grouped as by the group of following parts by weight: 30 parts of potassium hydrogen persulfate composite salts, 20 parts of SODIUM PERCARBONATE, anhydrous magnesium sulfate 20
Part, 10 parts of sodium carbonate, 10 parts of malic acid, 3 parts of polyvinylpyrrolidone, 0.2 part of calcium stearate.
5. the Potassium Monopersulfate compound effervescent tablet according to claim 1 for the improvement of water quality substrate, feature
It is, is grouped as by the group of following parts by weight: 20 parts of potassium hydrogen persulfate composite salts, 20 parts of percarbamide, 20 parts of calcium chloride, carbon
8 parts of sour hydrogen sodium, 10 parts of citric acid, 5 parts of magnesium laurylsulfate, 0.1 part of magnesium stearate.
6. the Potassium Monopersulfate composite effervescent described according to claim 1 ~ any one of 5 for the improvement of water quality substrate
The preparation method of piece, which comprises the following steps:
S1: by above-mentioned all raw material moisture controls below 1%；
S2: successively by potassium peroxymonosulfate, malic acid or citric acid, anhydrous sodium sulfate, anhydrous magnesium sulfate or calcium chloride,
Sodium peroxydisulfate, SODIUM PERCARBONATE or percarbamide, polyvinylpyrrolidone or magnesium laurylsulfate, magnesium stearate or calcium stearate are mixed
Conjunction stirs evenly；
S3: in temperature lower than in 30 DEG C, environment of the relative humidity less than 50%, not similar shape is made with pelletizer or rotary pelleting machine
The tablet or particle of shape, weight.
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| CN109892280A (en) * | 2019-03-27 | 2019-06-18 | 青岛中仁动物药品有限公司 | A kind of tablet and preparation method thereof improving breeding water body dissolved oxygen |
| CN110054276A (en) * | 2019-05-14 | 2019-07-26 | 江苏祥豪实业股份有限公司 | Water quality composite purifying agent and preparation method thereof for aquaculture system |
| CN110326624A (en) * | 2019-07-18 | 2019-10-15 | 无锡中顺生物技术有限公司 | The disinfection oxidant and its application that the one seed shrimp pool uses |
| CN110615512A (en) * | 2019-09-29 | 2019-12-27 | 湖南农业大学 | Water quality improvement method for improving out-of-season breeding performance of breeding geese |
| CN111170595A (en) * | 2020-01-16 | 2020-05-19 | 常州市金太阳动物保健品有限公司 | Pool cleaning bottom modifying agent and preparation method thereof |
| CN113383791A (en) * | 2021-07-23 | 2021-09-14 | 湖南微草生物饲料科技有限公司 | Reinforced potassium hydrogen persulfate compound disinfectant and preparation process thereof |
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| CN113415832A (en) * | 2021-05-25 | 2021-09-21 | 河南金天鱼生物科技有限公司 | Fruit acid bottom-modifying tablet for aquaculture pond and preparation method thereof |
| CN113383791A (en) * | 2021-07-23 | 2021-09-14 | 湖南微草生物饲料科技有限公司 | Reinforced potassium hydrogen persulfate compound disinfectant and preparation process thereof |
| CN114766508A (en) * | 2022-05-24 | 2022-07-22 | 山东润兴环保科技有限公司 | Potassium monopersulfate composite disinfectant for hospital sewage treatment and preparation method thereof |
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| CN117566874A (en) * | 2023-10-07 | 2024-02-20 | 江苏逐水环境科技有限公司 | In-situ ecological improvement restoration agent for substrate based on river and lake habitat improvement |
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