CN108899606A - Useless power battery comprehensive reutilization method - Google Patents
Useless power battery comprehensive reutilization method Download PDFInfo
- Publication number
- CN108899606A CN108899606A CN201810776755.9A CN201810776755A CN108899606A CN 108899606 A CN108899606 A CN 108899606A CN 201810776755 A CN201810776755 A CN 201810776755A CN 108899606 A CN108899606 A CN 108899606A
- Authority
- CN
- China
- Prior art keywords
- battery
- crushed
- battery core
- power battery
- useless power
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000005520 cutting process Methods 0.000 claims abstract description 18
- 238000012216 screening Methods 0.000 claims abstract description 11
- 238000000926 separation method Methods 0.000 claims abstract description 7
- 230000005484 gravity Effects 0.000 claims abstract description 6
- 239000002351 wastewater Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 12
- 230000008676 import Effects 0.000 claims description 11
- 239000004576 sand Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000004080 punching Methods 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011889 copper foil Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 239000005030 aluminium foil Substances 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 abstract description 5
- 238000005336 cracking Methods 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 229910001634 calcium fluoride Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- SOXUFMZTHZXOGC-UHFFFAOYSA-N [Li].[Mn].[Co].[Ni] Chemical class [Li].[Mn].[Co].[Ni] SOXUFMZTHZXOGC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- -1 hexafluorophosphoric acid Lithium Chemical group 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
A kind of useless power battery comprehensive reutilization method, including following steps, the wet process discharge cutting of useless power battery, battery core of rushing to summit, battery battery core be crushed, sieve, be crushed, sieve again, in shaking table gravity separation, waste water and reuse.Useless power battery comprehensive reutilization method of the invention, by discharge cutting, rush to summit, be crushed, sieve, the processes such as separation by shaking table make useless power battery obtain disassembling sorting preferablely, safer, more environmentally friendly, it passes through wet process discharge cutting, wet crushing and screening are higher to avoid brings problem of environmental pollution, the sorting rate of recovery such as electrolyte volatilization, dust volatilization and diaphragm cracking.
Description
Technical field
The present invention relates to a kind of useless power battery comprehensive reutilization methods.
Background technique
The fast development of new energy brings the loss of a large amount of power battery, comprehensively utilizes the money in useless power battery
Source is that historical background determines.For power battery based on lithium battery, lithium battery is classified as LiFePO4 series, cobalt acid lithium system
Column, ternary cobalt nickel manganese lithium series, LiMn2O4 series, wherein the resource of recoverable is substantially metallic element cobalt, nickel, manganese, lithium
Deng.The structure composition of power battery has：Shell（Steel shell and aluminum hull）, anode, cathode, diaphragm, electrolyte, anode by powder and aluminium
Together by adhesive bond, cathode is bonded together foil by powdered carbon and copper foil, and diaphragm is plastics, and electrolyte is hexafluorophosphoric acid
Lithium.The comprehensive reutilization of power battery includes physics dismantling sorting and hydrometallurgy purification, and the emphasis of the application is that physics is torn open
The technique for solving sorting.
Summary of the invention
Low, simple process that it is an object of the invention to provide a kind of production costs, can make aluminium hydroxide big with non-ferrous metal
It is partially separated, give up power battery comprehensive reutilization method.
Useless power battery comprehensive reutilization method of the invention, includes the following steps：
1, wet process discharge cutting：Selected device is automatic gas cutting machine, battery is ranked into unified direction, automatic gas cutting machine is in waterpower
Battery is cut under washing away on one side, while putting remaining electricity in water in the case where cutting short circuit, then remove battery and be packed into punching machine
In mold；
2, it rushes to summit battery core：The battery that mold is packed into after cutting places punching machine and is punched out operation, goes out the battery core in battery, manually
Classify, battery case and battery core pile up separately；
3, battery battery core is broken：Battery battery core is broken to select rotary knife to hammer breaking device into shape, and battery battery core is sent into rotary knife and hammers breaking device into shape, together
When by pipeline import flushing water, be crushed Xi Du≤10mm, be crushed after material import sifting vibrating sieve；
4, it sieves：Above-mentioned be crushed material crosses 50 mesh vibrating screens and carries out waterpower screening, and screenings enters collecting pit collection, then
Packet is filled after squeezing by plate and frame filter press, water circulation is carried out using oversize enters another rotary knife hammer breaking device and is crushed；
5, it is crushed：Oversize is imported into rotary knife hammer breaking device and carries out hydraulic fracture, is crushed Xi Du≤2mm, broken material imports water
Force vibration is sieved；
6, it sieves again：The broken material generated imports 50 mesh hydraulic vibrations and is sieved, and 4 collecting pit of screenings steps for importing is received
Collection, oversize are transferred to waterpower shaking table；
7, shaking table gravity separation：Sand shaking table carries out gravity separation in oversize importing, and heavy sand is copper foil, and middle sand is aluminium foil, tailings
For plastic diaphragms, classification is packed；
8, in waste water and reuse：Because of the dissolution of electrolyte in assorting room waste water, there is F in water-、PO4 3-, lime precipitation is added
F-、PO4 3-Generate CaF2, Ca3(PO4)2After be recycled.
Useless power battery comprehensive reutilization method of the invention by discharge cutting, is rushed to summit, is crushed, is sieved, shaking table point
The processes such as choosing make useless power battery obtain disassembling sorting preferablely, safer, more environmentally friendly, it is wet by wet process discharge cutting
Method is broken and sieves to avoid the brings problem of environmental pollutions such as electrolyte volatilization, dust volatilization and diaphragm cracking, sorting recycling
Rate is higher.
Specific embodiment
A kind of useless power battery comprehensive reutilization method, includes the following steps：
1, battery is ranked into unified direction, automatic gas cutting machine cuts battery on one side under sluicing, while in cutting short circuit
In the case where put remaining electricity in water, then remove battery and be fitted into punching machine mold；
2, the battery that mold is packed into after cutting places punching machine and is punched out operation, goes out the battery core in battery；
3, battery battery core is broken：Battery battery core is sent into rotary knife and hammers breaking device into shape, while flushing water is imported by pipeline, is crushed fineness
≤ 10mm, material imports sifting vibrating sieve after being crushed；
4, the material being crushed crosses 50 mesh vibrating screens and carries out waterpower screening, and screenings enters collecting pit collection, then passes through sheet frame
Packet is filled after filter press squeezing, oversize enters another rotary knife hammer breaking device and is crushed；
5, oversize is imported into rotary knife hammer breaking device and carries out hydraulic fracture, be crushed Xi Du≤2mm, broken material imports hydraulic vibration
It is sieved；
6, it sieves again：The broken material generated imports 50 mesh hydraulic vibrations and is sieved, and screenings imports above-mentioned collecting pit and receives
Collection, oversize are transferred to waterpower shaking table；
7, sand shaking table carries out gravity separation in oversize importing, and heavy sand is copper foil, and middle sand is aluminium foil, and tailings is plastic diaphragms, point
Class is packed；
8, lime precipitation F is added in assorting room waste water-、PO4 3-Generate CaF2, Ca3(PO4)2After be recycled.
Claims (1)
1. a kind of useless power battery comprehensive reutilization method, it is characterised in that：It includes the following steps：
（1）, wet process discharge cutting：Selected device is automatic gas cutting machine, battery is ranked into unified direction, automatic gas cutting machine is in water
Power cuts battery on one side, while putting remaining electricity in water in the case where cutting short circuit under washing away, then remove battery and be packed into punching
In bed mold；
（2）, battery core of rushing to summit：The battery that mold is packed into after cutting places punching machine and is punched out operation, goes out the battery core in battery, people
Work is classified, battery case and battery core pile up separately；
（3）, battery battery core it is broken：Battery battery core is broken to select rotary knife to hammer breaking device into shape, and battery battery core is sent into rotary knife and hammers breaking device into shape,
Flushing water is imported by pipeline simultaneously, is crushed Xi Du≤10mm, material imports sifting vibrating sieve after being crushed；
（4）, screening：Above-mentioned be crushed material crosses 50 mesh vibrating screens and carries out waterpower screening, and screenings enters collecting pit collection, so
It fills and wraps after being squeezed afterwards by plate and frame filter press, water circulation is carried out using oversize enters another rotary knife hammer breaking device and is crushed；
（5）, it is broken：Oversize is imported into rotary knife hammer breaking device and carries out hydraulic fracture, is crushed Xi Du≤2mm, broken material imports
Hydraulic vibration is sieved；
（6）, again sieve：The broken material generated imports 50 mesh hydraulic vibrations and is sieved, 4 collecting pit of screenings steps for importing
It collects, oversize is transferred to waterpower shaking table；
（7）, shaking table gravity separation：Sand shaking table carries out gravity separation in oversize importing, and heavy sand is copper foil, and middle sand is aluminium foil, tail
Sand is plastic diaphragms, and classification is packed；
（8）, in waste water and reuse：Lime precipitation F is added in assorting room waste water-、PO4 3-After be recycled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810776755.9A CN108899606A (en) | 2018-07-16 | 2018-07-16 | Useless power battery comprehensive reutilization method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810776755.9A CN108899606A (en) | 2018-07-16 | 2018-07-16 | Useless power battery comprehensive reutilization method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108899606A true CN108899606A (en) | 2018-11-27 |
Family
ID=64349576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810776755.9A Pending CN108899606A (en) | 2018-07-16 | 2018-07-16 | Useless power battery comprehensive reutilization method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108899606A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109524739A (en) * | 2019-01-17 | 2019-03-26 | 广东世合科技有限公司 | A kind of waste lithium cell recovery process |
| CN110323511A (en) * | 2019-07-10 | 2019-10-11 | 泽晖新能源材料研究院(珠海)有限公司 | Chemical method disposes waste lithium cell system and waste lithium battery treatment |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1177011A (en) * | 1997-09-02 | 1999-03-23 | Mitsui Mining & Smelting Co Ltd | How to recover valuable resources from waste batteries |
| CN102148414A (en) * | 2011-03-07 | 2011-08-10 | 尚诚德 | Energy-saving and environment-friendly automatic disassembly and separation system for waste batteries |
| CN105811041A (en) * | 2016-05-19 | 2016-07-27 | 株洲鼎端装备股份有限公司 | Recycling and disposal system for waste lithium-ion power battery |
| CN106558739A (en) * | 2016-11-28 | 2017-04-05 | 安徽得盈再生资源回收有限公司 | Separating technology is reclaimed based on lithium ion battery environment-friendly high-efficiency in waste mobile phone |
| CN107017443A (en) * | 2017-03-28 | 2017-08-04 | 北京科技大学 | A kind of method of the comprehensively recovering valuable metal from waste and old lithium ion battery |
| CN107689465A (en) * | 2016-08-05 | 2018-02-13 | 北京有色金属研究总院 | A kind of technique for reclaiming valuable metal in waste and old ternary electrical core of power battery |
-
2018
- 2018-07-16 CN CN201810776755.9A patent/CN108899606A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1177011A (en) * | 1997-09-02 | 1999-03-23 | Mitsui Mining & Smelting Co Ltd | How to recover valuable resources from waste batteries |
| CN102148414A (en) * | 2011-03-07 | 2011-08-10 | 尚诚德 | Energy-saving and environment-friendly automatic disassembly and separation system for waste batteries |
| CN105811041A (en) * | 2016-05-19 | 2016-07-27 | 株洲鼎端装备股份有限公司 | Recycling and disposal system for waste lithium-ion power battery |
| CN107689465A (en) * | 2016-08-05 | 2018-02-13 | 北京有色金属研究总院 | A kind of technique for reclaiming valuable metal in waste and old ternary electrical core of power battery |
| CN106558739A (en) * | 2016-11-28 | 2017-04-05 | 安徽得盈再生资源回收有限公司 | Separating technology is reclaimed based on lithium ion battery environment-friendly high-efficiency in waste mobile phone |
| CN107017443A (en) * | 2017-03-28 | 2017-08-04 | 北京科技大学 | A kind of method of the comprehensively recovering valuable metal from waste and old lithium ion battery |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109524739A (en) * | 2019-01-17 | 2019-03-26 | 广东世合科技有限公司 | A kind of waste lithium cell recovery process |
| CN110323511A (en) * | 2019-07-10 | 2019-10-11 | 泽晖新能源材料研究院(珠海)有限公司 | Chemical method disposes waste lithium cell system and waste lithium battery treatment |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN112246835B (en) | Method for disassembling and separating waste lithium ion batteries | |
| CN102569940B (en) | Method for recycling negative electrode material of waste lithium ion battery | |
| CN110694771B (en) | Flexible airflow powder removing method for waste ternary lithium battery | |
| CN105671316A (en) | Method for recovering valuable metals from waste lithium-ion power batteries | |
| CN114147043A (en) | Sorting method for recycling anode powder and cathode powder of waste lithium battery | |
| CN108832216A (en) | A pretreatment method for recycling waste power lithium batteries | |
| CN108711651A (en) | A kind of resource utilization of old and useless battery utilizes technique and system | |
| CN107293817A (en) | A kind of waste and old lithium ion battery each component is efficiently dissociated and classified reclaiming method | |
| CN113199657B (en) | Method for recycling diaphragm material from waste lithium ion battery | |
| CN101692510B (en) | Recycling separation process of electrode component materials of used lithium batteries | |
| CN205926578U (en) | Useless lithium battery processing system | |
| CN110523639A (en) | Method and system for processing decoration waste | |
| CN111525207B (en) | Lithium-ion power battery recycling method | |
| CN108461855A (en) | A kind of the dismantling recovery system and dismantling recovery method of waste lithium cell | |
| CN208526948U (en) | A kind of waste power battery pole piece sorting and recycling device | |
| CN107689465B (en) | Process for recovering valuable metals in waste ternary power battery cell | |
| CN216322551U (en) | Lithium battery pole piece powder removing, sorting and recycling line | |
| CN212284283U (en) | Waste lithium battery recovery device | |
| CN108899606A (en) | Useless power battery comprehensive reutilization method | |
| CN1563440A (en) | Techhnique for reclaiming metal concentrate in obsolete PCB physically | |
| WO2021209074A1 (en) | Lithium ion traction battery recycling method | |
| CN114300776B (en) | Method for recycling and screening lithium ion battery material | |
| CN104014414A (en) | Secondary sorting method for waste lead-acid battery broken materials | |
| CN118946677A (en) | Method and apparatus for reusing battery cells or parts of battery cells | |
| CN107293818A (en) | A kind of method of copper foil aluminium foil in recovery waste lithium ion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181127 |
|
| WD01 | Invention patent application deemed withdrawn after publication |