CN108706912A - A kind of poly- sand sound absorber and preparation method thereof - Google Patents
A kind of poly- sand sound absorber and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
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- C—CHEMISTRY; METALLURGY
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/52—Sound-insulating materials
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
Description
技术领域technical field
本发明涉及一种聚砂吸声装置及其制备方法,属于建筑化学材料领域。The invention relates to a sand-accumulating sound-absorbing device and a preparation method thereof, belonging to the field of building chemical materials.
背景技术Background technique
现代建筑中大量使用高声音反射率的面层材料,如混凝土、玻璃、大理石和金属等,导致吸声率较低,产生令人不安的噪声或令人不悦的声音反射。聚砂板原料选自天然砂,可使砂粒外层之间发生一层溶融再固化反应,由此,砂粒就像被焊接一样聚在一起。因为每颗砂粒的微观形状是不规则且独一无二的,聚合积压在一起时,砂粒之间天然地形成了大量的、不规则的、相互连通的微小孔隙。现有的聚砂板的吸声性能和/或透气性能较差,且不具有防渗透的特性。The extensive use of surface materials with high sound reflectivity in modern buildings, such as concrete, glass, marble, and metal, results in low sound absorption, disturbing noise or unpleasant sound reflections. The raw material of the sand gathering board is selected from natural sand, which can cause a layer of melting and re-solidification reaction between the outer layers of the sand grains, so that the sand grains gather together as if they were welded. Because the microscopic shape of each sand grain is irregular and unique, when aggregated and accumulated together, a large number of irregular and interconnected tiny pores are naturally formed between the sand grains. The existing sand gathering boards have poor sound absorption and/or air permeability, and do not have anti-permeation properties.
CN105330232A提供一种新型双层免烧高强透水地砖,其由下列重量份的原料制成:沙漠砂50-53、热塑性酚醛树脂4-5、乌洛托品0.6-0.7、硬脂酸钙0.2-0.22、水适量、标号为42.5的硅酸盐水泥42-45、粉煤灰5-6、水性氟碳乳液4-5、可再分散胺粉7-9、蜂窝煤渣9-11、椰壳活性炭5-6、陶粒100-110、硅砂23-26、硅灰粉30-33、琉酸铝2-30。因此,该地砖需要很强的透水性能,因此,所制备得到的地砖是可渗透的。CN105330232A provides a novel double-layer fire-free high-strength permeable floor tile, which is made of the following raw materials in parts by weight: desert sand 50-53, thermoplastic phenolic resin 4-5, urotropine 0.6-0.7, calcium stearate 0.2- 0.22, appropriate amount of water, 42.5 Portland cement 42-45, fly ash 5-6, water-based fluorocarbon emulsion 4-5, redispersible amine powder 7-9, honeycomb cinder 9-11, coconut shell activated carbon 5-6, ceramsite 100-110, silica sand 23-26, silica fume powder 30-33, aluminum sulfonate 2-30. Therefore, the floor tile needs strong water permeability, and therefore, the prepared floor tile is permeable.
发明内容Contents of the invention
发明要解决的问题The problem to be solved by the invention
本发明的目的在于提供一种聚砂吸声装置及其制备方法。通过调整聚砂组合物的配方比例,从而可以改变聚砂组合物的表面结构,使聚砂吸声装置具有吸声性能和透气性能,并且还具有防渗漏、耐高温的特性。The object of the present invention is to provide a sand-accumulating sound-absorbing device and a preparation method thereof. By adjusting the formula ratio of the sand-accumulating composition, the surface structure of the sand-accumulating composition can be changed, so that the sand-accumulating sound-absorbing device has sound absorption performance and air permeability, and also has the characteristics of anti-leakage and high temperature resistance.
进一步地,本发明还提供一种聚砂吸声装置的制备方法,该制备方法的原料易得,且操作简单易行。Furthermore, the present invention also provides a method for preparing a sand-accumulating sound-absorbing device, the raw materials of which are readily available, and the operation is simple and easy.
用于解决问题的方案solutions to problems
本发明提供一种聚砂吸声装置,其中,所述聚砂吸声装置由聚砂组合物模压而成;所述聚砂组合物包括基材、粘结剂、固化剂以及润滑剂;其中,以所述基材的质量百分比为100%计,所述粘结剂的加入量为1-5%,优选2-4%,固化剂的加入量为0.05-0.5%,优选0.1-0.4%,润滑剂的加入量为0.2-0.5%,优选0.3-0.4%。The present invention provides a sand-accumulating sound-absorbing device, wherein the sand-accumulating sound-absorbing device is molded from a sand-accumulating composition; the sand-accumulating composition includes a base material, a binder, a curing agent and a lubricant; wherein , based on 100% of the mass percentage of the substrate, the addition of the binder is 1-5%, preferably 2-4%, and the addition of the curing agent is 0.05-0.5%, preferably 0.1-0.4% , The amount of lubricant added is 0.2-0.5%, preferably 0.3-0.4%.
根据本发明的聚砂吸声装置,其中,所述基材包括硅砂、沙漠砂、石英砂、河砂、湖砂、宝珠砂、山砂、海砂、金属砂、镁橄榄石砂、陶粒砂、锆石砂、耐火黏土和玻璃珠中的至少一种,优选地,所述基材的平均粒径为10-100目,优选为50-60目。According to the sand-accumulating sound-absorbing device of the present invention, wherein, the base material includes silica sand, desert sand, quartz sand, river sand, lake sand, pearl sand, mountain sand, sea sand, metal sand, forsterite sand, ceramsite At least one of sand, zircon sand, refractory clay and glass beads. Preferably, the average particle size of the substrate is 10-100 mesh, preferably 50-60 mesh.
根据本发明的聚砂吸声装置,其中,所述固化剂包括乙二胺、三甲基六亚甲基二胺、六次甲基四胺、二乙基三胺、羟甲基乙二胺、羟乙基乙二胺、二羟乙基乙二胺、羟乙基二乙烯三胺、二羟乙基乙二胺、羟乙基二乙烯三胺、二羟乙基二乙烯三胺、羟乙基己二胺、一氰乙基乙二胺、二氰乙基乙二胺、二氰乙基己二胺、双氰胺和环己二胺中的至少一种。According to the polysand sound-absorbing device of the present invention, wherein, the curing agent includes ethylenediamine, trimethylhexamethylenediamine, hexamethylenetetramine, diethylenetriamine, methylolethylenediamine , hydroxyethylethylenediamine, dihydroxyethylethylenediamine, hydroxyethyldiethylenetriamine, dihydroxyethylethylenediamine, hydroxyethyldiethylenetriamine, dihydroxyethyldiethylenetriamine, hydroxyl At least one of ethylhexamethylenediamine, monocyanoethylethylenediamine, dicyanoethylethylenediamine, dicyanoethylhexamethylenediamine, dicyandiamide and cyclohexanediamine.
根据本发明的聚砂吸声装置,其中,所述粘结剂包括热固性酚醛树脂和/或热固性丙烯酸树脂;优选地,所述润滑剂包括聚四氟乙烯、硬脂酸钙、硬脂酸锌和硬脂酸钠中的至少一种。According to the polysand sound-absorbing device of the present invention, wherein, the binder includes thermosetting phenolic resin and/or thermosetting acrylic resin; preferably, the lubricant includes polytetrafluoroethylene, calcium stearate, zinc stearate and at least one of sodium stearate.
根据本发明的聚砂吸声装置,其中,所述聚砂组合物还包括硅烷和/或石墨,以所述基材的质量百分比计,所述硅烷的加入量为0.1-0.5%,优选为0.2-0.4%,所述石墨的加入量为0.05-0.5%,优选为0.1-0.2%。According to the sand-accumulating sound-absorbing device of the present invention, wherein the sand-accumulating composition further includes silane and/or graphite, and the added amount of the silane is 0.1-0.5% based on the mass percentage of the substrate, preferably 0.2-0.4%, the added amount of graphite is 0.05-0.5%, preferably 0.1-0.2%.
根据本发明的聚砂吸声装置,其中,所述聚砂吸声装置还包括硅溶胶,以所述聚砂组合物中基材的质量百分比计,所述硅溶胶的加入量为2-5%,优选为3-4%。According to the sand-accumulating sound-absorbing device of the present invention, wherein the sand-accumulating sound-absorbing device further includes silica sol, the addition amount of the silica sol is 2-5 %, preferably 3-4%.
本发明提供一种根据本发明的聚砂吸声装置的制备方法,其中,包括采用模压的方法制备所述聚砂吸声装置。The present invention provides a method for preparing the sand-accumulating sound-absorbing device according to the present invention, which includes preparing the sand-accumulating sound-absorbing device by molding.
根据本发明的制备方法,其中,包括以下步骤:The preparation method according to the present invention, wherein, comprises the following steps:
预热步骤:将模具预热后,进行合模;Preheating step: After preheating the mold, close the mold;
注砂步骤:向模具中注入聚砂组合物;Sand injection step: inject the sand-accumulating composition into the mould;
热压步骤:将注入聚砂组合物后的模具进行热压,获得聚砂吸声装置。Hot-pressing step: hot-press the mold injected with the sand-accumulating composition to obtain a sand-accumulating sound-absorbing device.
根据本发明的制备方法,其中,所述预热步骤和所述注砂步骤之间,还包括将所述聚砂组合物与硅溶胶混合的步骤。According to the preparation method of the present invention, between the preheating step and the sand injection step, a step of mixing the sand gathering composition with silica sol is also included.
根据本发明的制备方法,其中,所述聚砂组合物的制备方法包括将所述聚砂组合物的各组分混合的步骤。According to the preparation method of the present invention, wherein, the preparation method of the sand gathering composition includes the step of mixing the components of the sand gathering composition.
发明的效果The effect of the invention
本发明通过调整聚砂组合物的配方比例,从而可以调整聚砂组合物的表面结构,使制备得到的聚砂吸声装置具有吸声性能和透气性能,并且还具有防渗漏、耐高温的特性。The present invention can adjust the surface structure of the sand-gathering composition by adjusting the formula ratio of the sand-gathering composition, so that the prepared sand-gathering sound-absorbing device has sound absorption performance and air permeability, and also has anti-leakage and high temperature resistance. characteristic.
进一步地,本发明制备得到的聚砂吸声装置可以广泛用于潮湿场所吸声降噪、隧道降噪、地铁降噪、室外声景观建造、室外交通声屏障工程等。还可用于通风管道的吸声材料、消声器内壁材料等。Furthermore, the sand-accumulating sound-absorbing device prepared by the present invention can be widely used in sound absorption and noise reduction in wet places, tunnel noise reduction, subway noise reduction, outdoor soundscape construction, outdoor traffic sound barrier engineering, etc. It can also be used as sound-absorbing material for ventilation ducts, inner wall material of muffler, etc.
具体实施方式Detailed ways
以下将详细说明本发明的各种示例性实施例、特征和方面。在这里专用的词“示例性”意为“用作例子、实施例或说明性”。这里作为“示例性”所说明的任何实施例不必解释为优于或好于其它实施例。Various exemplary embodiments, features, and aspects of the invention are described in detail below. The word "exemplary" is used exclusively herein to mean "serving as an example, embodiment, or illustration." Any embodiment described herein as "exemplary" is not necessarily to be construed as superior or better than other embodiments.
另外,为了更好地说明本发明,在下文的具体实施方式中给出了众多的具体细节。本领域技术人员应当理解,没有某些具体细节,本发明同样可以实施。在另外一些实例中,对于本领域技术人员熟知的方法、手段、器材和步骤未作详细描述,以便于凸显本发明的主旨。In addition, in order to better illustrate the present invention, numerous specific details are given in the specific embodiments below. It will be understood by those skilled in the art that the present invention may be practiced without certain of the specific details. In other instances, methods, means, devices and steps well known to those skilled in the art are not described in detail in order to highlight the gist of the present invention.
<第一实施方式><First Embodiment>
本发明的第一实施方式提供一种聚砂吸声装置,所述聚砂吸声装置由聚砂组合物模压而成;所述聚砂组合物包括基材、粘结剂、固化剂以及润滑剂;其中,以所述基材的质量百分比为100%计,所述粘结剂的加入量为1-5%,优选2-4%;固化剂的加入量为0.05-0.5%,优选0.1-0.4%;润滑剂的加入量为0.2-0.5%,优选0.3-0.4%。本发明通过调整聚砂组合物的配方比例,从而可以调整聚砂组合物表面结构,使制备得到的聚砂吸声装置具有吸声性能和透气性能,并且还具有防渗漏、耐高温的特性。The first embodiment of the present invention provides a sand-accumulating sound-absorbing device, which is molded from a sand-accumulating composition; the sand-accumulating composition includes a base material, a binder, a curing agent, and a lubricant agent; wherein, based on the mass percentage of the substrate as 100%, the addition of the binder is 1-5%, preferably 2-4%; the addition of the curing agent is 0.05-0.5%, preferably 0.1 -0.4%; the amount of lubricant added is 0.2-0.5%, preferably 0.3-0.4%. The present invention can adjust the surface structure of the sand-gathering composition by adjusting the formula ratio of the sand-gathering composition, so that the prepared sand-gathering sound-absorbing device has sound absorption performance and air permeability, and also has the characteristics of anti-leakage and high temperature resistance .
根据本发明的聚砂吸声装置,在本发明中,对基材可以不作具体限定,一般可用的砂粒均可。优选地,在本发明中,所述基材包括硅砂、沙漠砂、石英砂、河砂、湖砂、宝珠砂、山砂、海砂、金属砂、镁橄榄石砂、陶粒砂、锆石砂、耐火黏土和玻璃珠中的至少一种。更优选地,所述基材的平均粒径为10-100目,优选为50-60目。当所述基材的平均粒径在10-80目之间时,可以更好的获得具有优异的吸声性能及透气性能的聚砂吸声装置。According to the sand-accumulating sound-absorbing device of the present invention, in the present invention, the base material may not be specifically limited, and generally available sand grains may be used. Preferably, in the present invention, the substrate includes silica sand, desert sand, quartz sand, river sand, lake sand, pearl sand, mountain sand, sea sand, metal sand, forsterite sand, ceramsite sand, zircon At least one of sand, fireclay and glass beads. More preferably, the average particle diameter of the substrate is 10-100 mesh, preferably 50-60 mesh. When the average particle size of the base material is between 10 and 80 meshes, a sand-accumulated sound-absorbing device with excellent sound-absorbing performance and air-permeable performance can be better obtained.
根据本发明的聚砂吸声装置,所述粘结剂包括热固性酚醛树脂和/或热固性丙烯酸树脂。在本发明中,以所述基材的质量百分比为100%计,所述粘结剂的加入量为1-5%,优选2-4%。当粘结剂的加入量在1-5%之时,制备得到的聚砂吸声装置具有优异的吸声透气性能;当粘结剂的加入量大于5%时,制备得到的聚砂吸声装置透气性较差;当粘结剂的加入量小于1%时,制备得到的聚砂吸声装置强度较低。According to the sand-accumulating sound-absorbing device of the present invention, the binder includes thermosetting phenolic resin and/or thermosetting acrylic resin. In the present invention, based on the base material being 100% by mass, the binder is added in an amount of 1-5%, preferably 2-4%. When the amount of binder added is 1-5%, the prepared sand-accumulated sound-absorbing device has excellent sound-absorbing and air-permeable properties; The air permeability of the device is poor; when the amount of binder added is less than 1%, the strength of the prepared sand-acoustic sound-absorbing device is low.
根据本发明的聚砂吸声装置,所述固化剂包括乙二胺、三甲基六亚甲基二胺、六次甲基四胺、二乙基三胺、羟甲基乙二胺、羟乙基乙二胺、二羟乙基乙二胺、羟乙基二乙烯三胺、二羟乙基乙二胺、羟乙基二乙烯三胺、二羟乙基二乙烯三胺、羟乙基己二胺、一氰乙基乙二胺、二氰乙基乙二胺、二氰乙基己二胺、双氰胺和环己二胺中的至少一种。According to the sand-accumulating sound-absorbing device of the present invention, the curing agent includes ethylenediamine, trimethylhexamethylenediamine, hexamethylenetetramine, diethylenetriamine, methylolethylenediamine, hydroxyl Ethylethylenediamine, dihydroxyethylethylenediamine, hydroxyethyldiethylenetriamine, dihydroxyethylethylenediamine, hydroxyethyldiethylenetriamine, dihydroxyethyldiethylenetriamine, hydroxyethyl At least one of hexamethylenediamine, monocyanoethylethylenediamine, dicyanoethylethylenediamine, dicyanoethylhexamethylenediamine, dicyandiamide and cyclohexanediamine.
在本发明中,以所述基材的质量百分比为100%计,所述固化剂的加入量为0.05-0.5%,优选0.1-0.4%。一般而言,在本发明中,当固化剂的含量小于0.05%,制备得到的聚砂吸声装置的硬度较低;当固化剂的含量大于0.5%时,在制备聚砂组合物的过程中干的太快,影响聚砂吸声装置的性能的发挥。优选地,在本发明中,固化剂的加入量为粘结剂加入量的1-10%,优选5-10%。其含量可以随粘结剂的含量进行增减。In the present invention, based on 100% by mass of the substrate, the curing agent is added in an amount of 0.05-0.5%, preferably 0.1-0.4%. Generally speaking, in the present invention, when the content of the curing agent is less than 0.05%, the hardness of the prepared sand-gathering sound-absorbing device is low; when the content of the curing agent is greater than 0.5%, in the process of preparing the sand-gathering composition If it dries too fast, it will affect the performance of the sand gathering sound-absorbing device. Preferably, in the present invention, the amount of curing agent added is 1-10%, preferably 5-10%, of the amount of binder added. Its content can be increased or decreased with the content of the binder.
根据本发明的聚砂吸声装置,所述润滑剂包括聚四氟乙烯、硬脂酸钙、硬脂酸锌和硬脂酸钠中的至少一种。According to the polysand sound-absorbing device of the present invention, the lubricant includes at least one of polytetrafluoroethylene, calcium stearate, zinc stearate and sodium stearate.
在本发明中,以所述基材的质量百分比为100%计,所述润滑剂加入量为0.2-0.5%,优选0.3-0.4%。在本发明中,润滑剂的含量在0.2-0.5%之间时,在制备聚砂组合物时能够搅拌分散均匀,从而可以保证聚砂吸声装置易于脱膜。当润滑剂的含量大于0.5%时,会使得制备得到的聚砂吸声装置的强度较低;当润滑剂的含量小于0.2%时,会使得在制备聚砂组合物时分散不匀,容易粘模。In the present invention, based on 100% by mass of the base material, the added amount of the lubricant is 0.2-0.5%, preferably 0.3-0.4%. In the present invention, when the content of the lubricant is between 0.2-0.5%, the sand-gathering composition can be stirred and dispersed evenly when preparing the sand-gathering composition, thereby ensuring easy release of the sand-gathering sound-absorbing device. When the content of the lubricant is greater than 0.5%, the strength of the prepared sand-accumulating sound-absorbing device will be low; mold.
根据本发明的聚砂吸声装置,所述聚砂组合物还包括硅烷和/或石墨,以所述基材的质量百分比计,所述硅烷的加入量为0.1-0.5%,优选为0.2-0.4%,所述石墨的加入量为0.05-0.5%,优选为0.1-0.2%。在本发明中,加入硅烷和/或石墨可以进一步起到辅助脱模的作用。一般而言,在本发明中,所述硅烷可以是甲硅烷、乙硅烷、丙硅烷中的至少一种。According to the sand-gathering sound-absorbing device of the present invention, the sand-gathering composition also includes silane and/or graphite, and the addition amount of the silane is 0.1-0.5%, preferably 0.2- 0.4%, the added amount of graphite is 0.05-0.5%, preferably 0.1-0.2%. In the present invention, adding silane and/or graphite can further play the role of assisting demoulding. Generally speaking, in the present invention, the silane may be at least one of monosilane, disilane and trisilane.
另外,本发明的聚砂组合物中,还可以含有耐高温添加剂,增韧性添加剂等。In addition, the sand gathering composition of the present invention may also contain high temperature resistant additives, toughening additives and the like.
根据本发明的聚砂吸声装置,所述聚砂吸声装置还可以包括硅溶胶,以所述聚砂组合物中所述基材的质量百分比计,所述硅溶胶的加入量为2-5%,优选为3-4%。通过使用硅溶胶,可以使得聚砂吸声装置具有防渗透的作用。硅溶胶在干燥后,能够形成疏水性的膜,填补与砂粒之间的孔隙,从而使聚砂吸声装置进一步具有防渗透的作用。According to the sand-gathering sound-absorbing device of the present invention, the sand-gathering sound-absorbing device may also include silica sol, and the addition amount of the silica sol is 2- 5%, preferably 3-4%. By using silica sol, the sand gathering sound-absorbing device can have the effect of preventing penetration. After the silica sol is dried, it can form a hydrophobic film to fill the pores between it and the sand particles, so that the sand-accumulating sound-absorbing device can further have the effect of preventing penetration.
<第二实施方式><Second Embodiment>
本发明的第二实施方式提供一种根据本发明所述的聚砂吸声装置的制备方法,采用模压的方法制备所述聚砂吸声装置。所述模压是将本发明的聚砂组合物放置于模具内借助加热、加压而成型,从而制备得到聚砂吸声装置。The second embodiment of the present invention provides a method for preparing the sand-accumulating sound-absorbing device according to the present invention, and the sand-accumulating sound-absorbing device is prepared by molding. The molding is to place the sand-accumulating composition of the present invention in a mold and shape it by heating and pressing, so as to prepare a sand-accumulating sound-absorbing device.
根据本发明的制备方法,包括以下步骤:The preparation method according to the present invention comprises the following steps:
预热步骤:将模具预热后,进行合模;Preheating step: After preheating the mold, close the mold;
注砂步骤:向模具中注入聚砂组合物;Sand injection step: inject the sand-accumulating composition into the mould;
热压步骤:将注入聚砂组合物后的模具进行热压,获得聚砂吸声装置。Hot-pressing step: hot-press the mold injected with the sand-accumulating composition to obtain a sand-accumulating sound-absorbing device.
本发明中,将模具预热至100-180℃,优选120-150℃。热压的压力为5-8公斤,优选为6-7公斤,温度为100-180℃,优选为120-150℃。另外,可以根据聚砂吸声装置的厚度确定热压的时间。在本发明中,聚砂吸声装置的厚度可以是5-50mm,热压的时间可以为10-60s,优选15-25s。In the present invention, the mold is preheated to 100-180°C, preferably 120-150°C. The pressure of hot pressing is 5-8 kg, preferably 6-7 kg, and the temperature is 100-180°C, preferably 120-150°C. In addition, the time of hot pressing can be determined according to the thickness of the sand-accumulating sound-absorbing device. In the present invention, the thickness of the sand-accumulating sound-absorbing device may be 5-50mm, and the hot pressing time may be 10-60s, preferably 15-25s.
本发明中,合模的含义是将模具的下模调整到与上模结合位置。In the present invention, the meaning of mold closing is to adjust the lower mold of the mold to the joint position with the upper mold.
结合本发明的制备方法,本发明的聚砂吸声装置的形状可以是地砖形状、板状、片状,与其它装置形成复合状等。Combined with the preparation method of the present invention, the shape of the sand-accumulating sound-absorbing device of the present invention can be a floor tile shape, a plate shape, a sheet shape, and a composite shape with other devices.
根据本发明的制备方法,所述预热步骤和所述注砂步骤之间,还包括将所述聚砂组合物与硅溶胶混合的步骤。根据本发明的制备方法,所述聚砂组合物的制备方法包括将所述聚砂组合物的各组分混合的步骤。According to the preparation method of the present invention, between the preheating step and the sand injection step, a step of mixing the sand gathering composition with silica sol is also included. According to the preparation method of the present invention, the preparation method of the sand gathering composition includes the step of mixing the components of the sand gathering composition.
具体地,根据本发明的制备方法,所述聚砂组合物的制备方法包括以下步骤:Specifically, according to the preparation method of the present invention, the preparation method of the sand gathering composition comprises the following steps:
步骤1,将基材预热后与粘结剂混合,得到包覆砂粒。优选地,预热温度可以是100-180℃,优选可以是120-150℃;在高温下,粘结剂熔化后粘结在基材上并包覆在基材的表面,一般而言,进行包覆混合搅拌的时间为30-50s。Step 1, preheating the base material and mixing it with the binder to obtain coated sand grains. Preferably, the preheating temperature can be 100-180°C, preferably 120-150°C; at high temperature, the adhesive is melted and bonded to the substrate and coated on the surface of the substrate. The coating mixing time is 30-50s.
优选地,在含有硅烷时,在将基材预热后先与硅烷进行混合,然后再与粘结剂、任选存在地石墨混合,得到包覆砂粒。更优选地,将基材预热后与硅烷混合的时间为3-10s,优选为4-6s。Preferably, when silane is present, it is mixed with the silane after preheating of the substrate, and then with the binder, optionally graphite, to obtain coated sand grains. More preferably, the time for mixing the substrate with the silane after preheating is 3-10s, preferably 4-6s.
优选地,在含有石墨时,可以在基材预热后,且与粘结剂混合后,在50-70s,优选55-60s时,加入石墨。Preferably, when graphite is included, the graphite can be added at 50-70s, preferably 55-60s, after the substrate is preheated and mixed with the binder.
步骤2,将固化剂的水溶液与包覆砂粒混合,由此产生的水蒸发使砂子迅速冷却(大约45-70秒),冷却至常温,得到冷却的包覆砂粒;该通过固化剂的水溶液与包覆砂粒的混合,还可以防止粘结剂和固化剂在混砂机中发生化学反应。优选地,固化剂的水溶液中,固化剂的质量浓度为20-30wt%。Step 2, mixing the aqueous solution of the curing agent with the coated sand, the resulting water evaporates to rapidly cool the sand (about 45-70 seconds), and cool to normal temperature to obtain cooled coated sand; The mixing of coated sand grains also prevents the chemical reaction of the binder and curing agent in the sand mixer. Preferably, in the aqueous solution of the curing agent, the mass concentration of the curing agent is 20-30 wt%.
步骤3,将所述冷却的包覆砂粒和润滑剂混合,得到聚砂组合物。优选地,混合的时间为5-15s,更优选为8-10s。一般而言,这一步骤在混砂机卸料之前加入的,可以提高聚砂组合物的流动性能。Step 3, mixing the cooled coated sand and lubricant to obtain a sand gathering composition. Preferably, the mixing time is 5-15s, more preferably 8-10s. Generally speaking, this step is added before the discharge of the sand mixer, which can improve the flow performance of the sand gathering composition.
步骤4,在覆膜过程完成时,将聚砂组合物在温度为60-80℃时转移到一震动筛上,聚砂组合物过筛至沸腾冷却槽上,以便继续降温到20-30℃,从而保证聚砂组合物具有更好的存放性能。Step 4, when the film coating process is completed, transfer the sand gathering composition to a vibrating sieve at a temperature of 60-80°C, and sieve the sand gathering composition to the boiling cooling tank to continue cooling down to 20-30°C , so as to ensure that the sand gathering composition has better storage performance.
另外,在本发明中,也可以先将固化剂的水溶液与润滑剂混合,然后再与包覆砂粒混合,其余与上述聚砂组合物的制备方法相同。In addition, in the present invention, the aqueous solution of the curing agent can also be mixed with the lubricant first, and then mixed with the coated sand particles, and the rest is the same as the preparation method of the above-mentioned sand gathering composition.
实施例Example
下面将结合实施例对本发明的实施方案进行详细描述,但是本领域技术人员将会理解,下列实施例仅用于说明本发明,而不应视为限定本发明的范围。实施例中未注明具体条件者,按照常规条件或制造商建议的条件进行。所用试剂或仪器未注明生产厂商者,均为可以通过市购获得的常规产品。Embodiments of the present invention will be described in detail below in conjunction with examples, but those skilled in the art will understand that the following examples are only used to illustrate the present invention, and should not be considered as limiting the scope of the present invention. Those who do not indicate the specific conditions in the examples are carried out according to the conventional conditions or the conditions suggested by the manufacturer. The reagents or instruments used were not indicated by the manufacturer, and they were all commercially available conventional products.
实施例1-6Examples 1-6
按照下表1的配方比例,以所述基材的质量百分比计,并按照下述制备方法制备得到聚砂组合物,其中,基材的平均粒径为50-60目。According to the formula ratio in Table 1 below, the mass percentage of the base material is used to prepare the sand gathering composition according to the following preparation method, wherein the average particle size of the base material is 50-60 mesh.
聚砂组合物的制备方法包括以下步骤:The preparation method of poly-sand composition comprises the following steps:
步骤1,将基材预热至130±5℃后与粘结剂混合搅拌,得到包覆砂粒;进行包覆混合搅拌的时间为40s。Step 1. Preheat the base material to 130±5°C and then mix and stir with the binder to obtain coated sand grains; the time for coating, mixing and stirring is 40s.
在含有硅烷时,在将基材预热后先与硅烷混合后5s,然后再与粘结剂混合,得到包覆砂粒。When silane is contained, after the substrate is preheated, it is mixed with silane for 5 seconds, and then mixed with the binder to obtain coated sand grains.
在含有石墨时,在基材预热后,且与粘结剂混合后,在55-60s时,加入石墨。When graphite is included, add graphite at 55-60 seconds after the substrate is preheated and mixed with the binder.
步骤2,将固化剂的水溶液与包覆砂粒混合,由此产生的水蒸发使砂子迅速冷却(55±5秒),冷却至常温,得到冷却的包覆砂粒;其中,固化剂的水溶液中,固化剂的质量浓度为25wt%。Step 2, mixing the aqueous solution of the curing agent with the coated sand, the resulting water evaporates to rapidly cool the sand (55 ± 5 seconds), and cool to normal temperature to obtain cooled coated sand; wherein, in the aqueous solution of the curing agent, The mass concentration of the curing agent is 25wt%.
步骤3,将所述冷却的包覆砂粒和润滑剂混合,得到聚砂组合物1-6。优选地,混合的时间为8-10s。Step 3, mixing the cooled coated sand grains with a lubricant to obtain sand gathering compositions 1-6. Preferably, the mixing time is 8-10s.
步骤4,在覆膜过程完成时,将聚砂组合物在温度为70℃时转移到一震动筛上,聚砂组合物过筛至沸腾冷却槽上,继续降温到25℃。Step 4, when the film covering process is completed, transfer the sand gathering composition to a vibrating sieve at a temperature of 70°C, sieve the sand gathering composition onto a boiling cooling tank, and continue cooling down to 25°C.
表1Table 1
然后按照下述制备方法,采用上述实施例1-6的聚砂组合物1-6,制备得到聚砂吸声装置1-6。Then, according to the following preparation method, the sand-accumulating sound-absorbing device 1-6 was prepared by using the above-mentioned sand-accumulating composition 1-6 of Examples 1-6.
聚砂吸声装置的制备方法为:The preparation method of the polysand sound-absorbing device is as follows:
预热步骤:将模具预热至150℃后,并进行合模,然后恒温开始生产。Preheating step: preheat the mold to 150°C, close the mold, and then start production at a constant temperature.
注砂步骤:向模具中注入聚砂组合物。在实施例中,可以将注砂板压下,利用注砂柱通过注砂口向模具中注入聚砂组合物。任选地,加入硅溶胶,并搅拌均匀。其中,以所述基材的质量百分比计,硅溶胶的加入量如下表2所示。Sand injection step: inject the sand-accumulating composition into the mold. In an embodiment, the sand injection plate can be pressed down, and the sand gathering composition can be injected into the mold through the sand injection port through the sand injection column. Optionally, add silica sol and mix well. Wherein, based on the mass percentage of the base material, the amount of silica sol added is shown in Table 2 below.
热压步骤:将注入聚砂组合物后的模具进行热压,获得聚砂吸声装置1-6。在实施例中,制备所得到的聚砂吸声装置的厚度为8mm,热压时间为20s,热压压力为7公斤,热压温度为150℃。Hot-pressing step: hot-press the mold injected with the sand-accumulating composition to obtain the sand-accumulating sound-absorbing device 1-6. In the embodiment, the thickness of the prepared sand-polyacoustic sound-absorbing device is 8 mm, the hot-pressing time is 20 s, the hot-pressing pressure is 7 kg, and the hot-pressing temperature is 150° C.
表2Table 2
聚砂吸声装置1-6的性能测试Performance Test of Polysand Acoustic Absorbing Device 1-6
对制备得到的聚砂吸声装置裁剪,得到300mm×600mm×8mm的聚砂吸声装置进行性能测试,结果如表3所示。The prepared sand-accumulating sound-absorbing device was cut to obtain a 300mm×600mm×8mm sand-accumulating sound-absorbing device for performance testing, and the results are shown in Table 3.
1、渗透性能测试1. Penetration performance test
在聚砂吸声装置上选好测点,用扫帚和细钢丝刷将测点上的灰土杂物清除干净。将清洁后的聚砂吸声装置用粉笔按测试仪器底座大小划好圆圈记号;并沿底座大小在聚砂吸声装置抹一圈密封材料,使密封材料嵌满缝隙且牢固地粘结在聚砂吸声装置上。将组合好的渗水试验仪底座用力压在聚砂吸声装置密封材料圈上,再加上压重铁圈压住仪器底座,以防止水从底座与聚砂吸声装置间流出。关闭细管下方的开关,向仪器的上方量筒中注入掺有少量红墨水的清洁水,直到量筒上端的溢水孔溢水为止(总量为600ml)。迅速将开关全部打开,水开始从细管下部流出,立即开动秒表,每间隔60s,读记仪器管的刻度一次,进行3次。Select the measuring point on the polysand sound-absorbing device, and use a broom and a fine wire brush to remove the dust and debris on the measuring point. Use chalk to draw a circle mark on the cleaned sand-polyacoustic device according to the size of the test instrument base; and apply a circle of sealing material on the polysand-absorbent device along the size of the base, so that the sealing material is embedded in the gap and firmly bonded to the polyacoustic sound-absorbing device. Sand on the sound-absorbing device. Press the base of the assembled water seepage tester firmly on the sealing material ring of the sand-accumulating sound-absorbing device, and press the weight iron ring to press the instrument base to prevent water from flowing out from between the base and the sand-accumulating sound-absorbing device. Turn off the switch below the thin tube, and inject clean water mixed with a small amount of red ink into the upper measuring cylinder of the instrument until the overflow hole at the upper end of the measuring cylinder overflows (the total amount is 600ml). Quickly turn on all the switches, water starts to flow out from the lower part of the thin tube, start the stopwatch immediately, and read the scale of the instrument tube once every 60 seconds, and perform 3 times.
2、降噪系数测试2. Noise reduction coefficient test
将制备得到聚砂吸声装置置于混响室中进行测试,其中,聚砂吸声装置的后空腔100mm2,在所述聚砂吸声装置的后空腔中设置一层50mm厚的64k玻璃棉,取多块聚砂吸声装置,复合为2.4m×4.2m×8mm(表面积为10.08m2)的聚砂吸声板,然后按照GB/T16731-1997测定其降噪系数。Place the prepared sand-accumulating sound-absorbing device in a reverberation chamber for testing, wherein the rear cavity of the sand-accumulating sound-absorbing device is 100 mm 2 , and a layer of 50 mm thick 64k glass wool, take several pieces of poly-sand sound-absorbing devices, composite them into a poly-sand sound-absorbing panel of 2.4m×4.2m×8mm (surface area: 10.08m 2 ), and then measure its noise reduction coefficient according to GB/T16731-1997.
3、抗折强度测试3. Flexural strength test
取聚砂吸声装置,将其裁剪为10mm×120mm×8mm利用万能材料试验机测试其抗折强度。Take the polysand sound-absorbing device, cut it into 10mm×120mm×8mm, and test its flexural strength with a universal material testing machine.
4、防火性能测试4. Fire performance test
按照国家标准GB8624-2007进行测试。Test according to the national standard GB8624-2007.
表3table 3
由表1可以看出,本申请的实施例1-5的聚砂吸声装置具备优异的防渗透性能,降噪系数大,抗折强度高,并且具有优异的防火性能。It can be seen from Table 1 that the sand-accumulating sound-absorbing devices of Examples 1-5 of the present application have excellent anti-penetration performance, large noise reduction coefficient, high flexural strength, and excellent fireproof performance.
对比例1-5Comparative example 1-5
按照下表4中的配方比例,以所述基材的质量百分比计,并按照实施例1-6的制备方法制备得到聚砂组合物A-E,其中,基材的平均粒径为50-60目。According to the formula ratio in the following table 4, based on the mass percentage of the base material, and according to the preparation method of Example 1-6, the sand gathering composition A-E is prepared, wherein the average particle size of the base material is 50-60 mesh .
表4Table 4
然后按照实施例1-6的制备方法,制备得到相应的对比例1-5的聚砂吸声装置A-E。其中,以所述基材的质量百分比计,硅溶胶的加入量如下表5所示。Then, according to the preparation methods of Examples 1-6, the corresponding sand-gathering and sound-absorbing devices A-E of Comparative Examples 1-5 were prepared. Wherein, in terms of the mass percentage of the substrate, the amount of silica sol added is shown in Table 5 below.
表5table 5
聚砂吸声装置A-E的性能测试Performance test of polysand sound absorbing device A-E
对制备得到的聚砂吸声装置A-E裁剪,得到300mm×600mm×8mm的聚砂吸声装置进行上述与实施例1-6的聚砂吸声装置1-6相同的性能测试,结果如下表6所示。The prepared sand-gathering sound-absorbing device A-E was cut to obtain a 300mm×600mm×8mm sand-gathering sound-absorbing device, and the same performance test as the above-mentioned sand-gathering sound-absorbing device 1-6 in Examples 1-6 was performed, and the results are shown in Table 6 shown.
表6Table 6
由表6可以看出,对比例1中,仅加入0.1%的粘结剂和0.01%的固化剂,其制备得到的聚砂吸声装置A的防渗透性能差,抗折强度低。对比例2中,加入了6%的粘结剂和0.6%的固化剂,其制备得到的聚砂吸声装置B的降噪系数低,吸声性能差。对比例3中仅加入0.5%的粘结剂,其制备得到的聚砂吸声装置C的防渗透性能差。对比例4中加入8%的粘结剂和0.04%的固化剂,其制备得到的聚砂吸声装置D的降噪系数低,吸声性能差。对比例5中加入了4%的环氧树脂作为粘结剂,并加入0.1%的润滑剂,所制备得到的聚砂吸声装置E的防渗透性能差,且防火性能仅能达到B1级。It can be seen from Table 6 that in Comparative Example 1, only 0.1% of binder and 0.01% of curing agent are added, and the prepared sand-acoustic device A has poor anti-permeability and low flexural strength. In comparative example 2, 6% of binder and 0.6% of curing agent were added, and the prepared sand-accumulating sound-absorbing device B had a low noise reduction coefficient and poor sound-absorbing performance. In Comparative Example 3, only 0.5% of binder was added, and the anti-permeability of the sand-accumulating sound-absorbing device C prepared by it was poor. In Comparative Example 4, 8% of binder and 0.04% of curing agent were added, and the sand-accumulating sound-absorbing device D prepared by it had a low noise reduction coefficient and poor sound-absorbing performance. In Comparative Example 5, 4% epoxy resin was added as a binder and 0.1% lubricant was added. The prepared sand-accumulating sound-absorbing device E had poor anti-penetration performance, and its fireproof performance could only reach B1 level.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应以所述权利要求的保护范围为准。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Anyone skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present invention. Should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be determined by the protection scope of the claims.
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| CN111620596A (en) * | 2020-06-19 | 2020-09-04 | 成都祥瑞尚科技有限公司 | Curing agent system for sand-gathering sound absorption and insulation board, sand-gathering sound absorption and insulation board and preparation method thereof |
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