[go: up one dir, main page]

CN108555550A - The preparation process of Determination of multiple metal elements mixing type piston ring - Google Patents

The preparation process of Determination of multiple metal elements mixing type piston ring Download PDF

Info

Publication number
CN108555550A
CN108555550A CN201810512879.6A CN201810512879A CN108555550A CN 108555550 A CN108555550 A CN 108555550A CN 201810512879 A CN201810512879 A CN 201810512879A CN 108555550 A CN108555550 A CN 108555550A
Authority
CN
China
Prior art keywords
weight
parts
piston ring
determination
metal elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810512879.6A
Other languages
Chinese (zh)
Inventor
何大林
林上忠
黄光伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SHANGZHONG PISTON RING CO LTD
Original Assignee
ANHUI SHANGZHONG PISTON RING CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI SHANGZHONG PISTON RING CO LTD filed Critical ANHUI SHANGZHONG PISTON RING CO LTD
Priority to CN201810512879.6A priority Critical patent/CN108555550A/en
Publication of CN108555550A publication Critical patent/CN108555550A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • B23P15/10Making specific metal objects by operations not covered by a single other subclass or a group in this subclass pistons
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/50Treatment of iron or alloys based thereon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)

Abstract

Invention broadly provides the preparation process of Determination of multiple metal elements mixing type piston ring, the piston ring is mainly mixed by iron (Fe), carbon (C), copper (Cu), niobium (Nd), aluminium (Al), rubidium (Rb), radium (Ra), silica (SiO2), manganese dioxide (MnO2) and beryllium-bronze.Reasonable design of the present invention, it is easy to process, it is mainly mixed by Determination of multiple metal elements, the structural strength of piston ring body can be effectively improved, avoid piston ring after long-term be heated, easily chipping phenomenon.

Description

The preparation process of Determination of multiple metal elements mixing type piston ring
Technical field
The invention mainly relates to the technical fields of piston ring processing, and in particular to Determination of multiple metal elements mixing type piston ring Preparation process.
Background technology
Piston ring is the becket for being embedded in inside piston groove, and piston ring is divided into two kinds:Compress ring and machine oil ring, pressure Contracting ring can be used to the burning mixture in sealing combustion room;Machine oil ring is then used for striking off machine oil extra on cylinder, piston ring Be it is a kind of have the larger metallic elastic ring for expanding outwardly deformation, it is mounted in its corresponding annular groove of section, back and forth With the piston ring of rotary motion, by the pressure difference of gas or liquid, at one of ring periphery and cylinder and ring and annular groove Sealing is formed between side.
During piston ring is used for a long time, piston ring body flexibility decrease can all occur, seriously will appear complete mistake The phenomenon of elasticity is gone, and flexibility decrease can lead to engine poor sealing, collaborate, burn oil, compression ratio (cylinder drops) influences Engine power exports.
Meanwhile existing piston ring material is relatively easy, causes the bulk strength of piston ring insufficient, in long-time high temperature item Continue working under part can so that piston ring body is more crisp, easily occurs cracking phenomena.
Invention content
Invention broadly provides the preparation processes of Determination of multiple metal elements mixing type piston ring, to solve above-mentioned background skill The technical issues of being proposed in art.
The present invention solve the technical solution that uses of above-mentioned technical problem for:Procedure of processing of the present invention is specific as follows:
Step 1:Embryo processed
First with electronic scale, according to the iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50-1.85 of 2.55-2.75 parts by weight The copper (Cu) of parts by weight, the niobium (Nd) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 weight The rubidium (Rb) of part, the dioxy of the radium (Ra) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze for changing manganese (MnO2) and 7-8 parts by weight, weighs each ingredient, is added in smelting furnace one by one by the material after weighing, Between 1000 DEG C -1500 DEG C, forging coarse-blank;
Step 2:Cooling treatment
By as cast condition blank vacuum high-pressure gas quenching stove heat to 650-700 DEG C, height is continuously used under 3 × 105Pa pressure Purity nitrogen air cooling, after cooling down completely i.e. only;
Step 3:Phosphorating treatment
Phosphorating treatment piston ring is washed with 10-12% aluminum hydroxide solutions carry out ungrease treatment first, and temperature control exists Between 50-55 DEG C, the time is 11-13 minutes, is then washed;It is washed again with 45-55%NaHSO4 solution and carries out pickling processes, temperature At 18-20 DEG C, the time is 5-8 minutes, is then washed for degree control;It is respectively 2 using volume ratio:2:1:1:A concentration of the 56% of 45 The surface prepared of the zinc oxide of HCl, 200ml/l, 4~6g/l, 1.3~1.5g/l sodium nitrate, 1.6~2g/l hydrogen peroxide and water In activator solution, temperature is controlled at 55-62 DEG C, and it is 12-15 minutes to immerse the time;
Step 4:Surface sand-blasting process
The step of piston ring excircle is activated, the activation of outer circle before being sprayed using suction-type dry blasting, sand grains type: Aluminium oxide, 20~30 mesh;Spray pressure:0.3 ± 0.05MPa, compressed air must condense drying;Jet length:35 ± 10mm, spray Sand cycle-index:2~3 times;
Working gas:Main gas:High pure nitrogen N2, purity 98%, 0.5 ± 0.05MPa of outlet pressure, flow 2000~ 2200L/H;
Auxiliary gas (I):Gas Austria Og, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 500~800L/H of flow;
Auxiliary gas (II):High-purity hydrogen H2, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 150~200L/H of flow;
Power parameter:Electric current:420~440A;Voltage:55~60V;
Geometric parameter of nozzle:Compression ratio:3~3.5, compression angle:45°;
Automatic powder feeding system:Internal powder conveying, powder feeding angle:90 °, powder feeding hole distance:9mm, 20~25g/min of powder sending quantity;
Intake method:Tangential admission;
Operating distance:Anode and cathode minimum distance:1~1.5mm;Spray distance:65~75mm;
Spraying rate:Spray gun movement speed:350mm/min, 150~250rpm of workpiece rotational frequency;
The type of cooling:It forces to cool down using compressed air;
Step 5:Piston ring excircle is cut
By the cylindricalo grinding of ring after spraying to fixed dimension and tear folder open, then this collar disintegrate at three groups of every group of length≤ 50mm is mutually bonded together due to the adhesion of outer circle coating in every ring group per loop, with CBN emery wheels by grinding wheel at Type amendment becomes the anti-contour shape of emery wheel;
Step 6:Surface spraying processing
Between 25 DEG C -35 DEG C of temperature, the piston ring that step 6 obtains is placed into ZS-811 solution, is disseminated more than 10 Minute, it further takes out, air-dries, dispel the impurity of surface adhesion, both obtain final products.
In process, each ingredient can be that can mix as follows:
Method two
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Molybdenum (Mo), the 2.35- of the technetium (Te) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The francium (Fr) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, the manganese dioxide (MnO2) of 1-2 parts by weight and 7-8 weights Measure the beryllium-bronze of part.
Method three
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Palladium (Pd), the 2.35- of the rhodium (Rh) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The barium (Ba) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, the manganese dioxide (MnO2) of 1-2 parts by weight and 7-8 weights Measure the beryllium-bronze of part.
Method four
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Yttrium (Y), the 2.35- of the zirconium (Zr) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The strontium (Sr) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, the manganese dioxide (MnO2) of 1-2 parts by weight and 7-8 weights Measure the beryllium-bronze of part.
Iron (Fe):There are good ductility, conduction, heat conductivility, has very strong ferromagnetism, belong to magnetic material.
Copper (Cu):Copper is in the metal of aubergine gloss, 8.92 grams/cc of density, 1083.4 ± 0.2 DEG C of fusing point, boiling 2567 DEG C of point, has good ductility, heat conduction and electric conductivity preferable.
Technetium (Te):4877 DEG C, tensile yield strength 1.29GPa of boiling point, 2172 DEG C, thermal conductivity 51W of fusing point, ultimate tensible strength Spend 1.51GPa.
Niobium (Nd):Niobium is greyish white non-ferrous metal, 2468 DEG C of fusing point, 4742 DEG C of boiling point, 8.57 grams/cc of density, and niobium is A kind of grey metal with gloss has paramagnetism, belongs to 5 races on the periodic table of elements, the ductility of high-purity niobium metal compared with Height, but can be hardened with the increase of impurity content.
Aluminium (Al):Silvery white light metal, there is ductility, and one layer of oxidation for preventing metal erosion can be formed in humid air Film, relative density 2.70,660 DEG C of fusing point, 2327 DEG C of of boiling point
Rubidium (Rb):It is a kind of chemical substance, the wax-like metal of silvery white of dead-soft, matter is soft and light, and chemical property is lived than potassium It sprinkles, easy ejected electron under the action of light, meets water and serve acutely, generate hydrogen and rubidium hydroxide, easily generated with oxygen effect multiple Miscellaneous oxide releases big calorimetric due to meeting water reaction, so hydrogen can be made to burn immediately, simple metal rubidium is normally stored in sealing Glass ampoule bottles in.
Radium (Ra):6.0 grams/cc of density (20 DEG C), 700 DEG C of fusing point, about 1140 DEG C of boiling point, silvery white is glossiness Soft metal.
Manganese dioxide (MnO2):Black amorphous powder or black rhomboidal crystal, dissolubility:It is insoluble in water, weak acid, weak Alkali, nitric acid, cold sulfuric acid are dissolved in concentrated hydrochloric acid and generate chlorine under heating state.
Silica (SiO2):Silica, the technical terms of chemistry, pure silica is colourless, is solid, chemical formula under room temperature For SiO2, it is not soluble in water, insoluble in acid, but it is dissolved in hydrofluoric acid and hot concentrated phosphoric acid, can and melt bases and work.
Beryllium-bronze:Contain the elements such as 1.7~2.5% berylliums and a small amount of nickel, chromium, titanium, after quenching ageing treatment, intensity pole Limit is up to 1250~1500MPa, close to the level of moderate strength steel.Plasticity is fine under as-quenched, can be processed into various Semi-finished product.Beryllium-bronze has very high hardness, elastic limit, fatigue limit and wearability, also has good corrosion resistance, heat conduction Property and electric conductivity, do not generate spark, are widely used as important elastic element, wear part and explosion-proof instrument etc. when being hit.
Molybdenum (Mo):Molybdenum fusing point is very high, and the density of molybdenum is 10.23g/cm, the about half (tungsten density 19.36g/cm) of tungsten, The coefficient of thermal expansion of molybdenum is very low, is 4.9 × 10/ DEG C at 20~100 DEG C;The pyroconductivity of molybdenum is higher, is 142.35w/ (mk), Molybdenum resistivity is relatively low:It is 5.17 × -10 Ω cm at 0 DEG C;It is 24.6 × -10 Ω cm at 800 DEG C;At 2400 DEG C for 72 ×- 10 Ω cm, molybdenum category paramagnet, the molybdenum of the 99.99% purity specific susceptibility at 25 DEG C is 0.93 × 10cm/g, the specific heat of molybdenum It is 242.8J/ (kgk) at 25 DEG C, the hardness of molybdenum is larger, and mohs hardness is 5~5.5, and molybdenum is in the heat of evaporation of boiling point 594kJ/mol;Heat of fusion is 27.6 ± 2.9kJ/mol;The heat of sublimation at 25 DEG C is 659kJ/mol.
Francium (Fr):State of matter:Solid-state has radioactivity, fusing point:300.2K (27 DEG C) boiling point:950K(677℃).
Rhodium (Rh):It is a kind of silvery white, hard metal, there is high reflectance.Rhodium metal is generally do not form oxide, Even if oxygen when heated, in an atmosphere is only absorbed in the rhodium for being heated to fusing point, but is discharged during solidification.Rhodium melts Point is higher than platinum, and density ratio platinum is low.Insoluble in most acid, it is completely insoluble in nitric acid, is slightly dissolved in chloroazotic acid rhodium.
Barium (Ba):It is silvery white non-ferrous metal, 725 DEG C of fusing point, 1600 DEG C of boiling point, 3.51 grams/cc of density has extension Property.
Zirconium (Zr):It is a kind of refractory metal, in light gray, 6.49 grams/cc of density, fusing point 1852 ± 2.001 DEG C, 4377 DEG C of boiling point.
Yttrium (Y):It is first thulium being found, is a kind of greyish black non-ferrous metal, there is ductility, with hot water energy It reacts, is soluble in diluted acid, it can special glass and alloy processed.
Strontium (Sr):It is that a kind of glossiness metallic of silvery white is soft, heat transfer conduction is easy, when being heated to fusing point in air It burns, take on a red color flame.
Compared with prior art, beneficial effects of the present invention are:Reasonable design of the present invention, it is easy to process, mainly by more Kind metallic element mixing, can effectively improve the structural strength of piston ring body, avoid piston ring after long-term be heated, easily occur broken The phenomenon that splitting.
Detailed explanation is carried out to the present invention below with reference to specific embodiment.
Specific implementation mode
With reference to embodiment, the present invention is furture elucidated, it should be understood that following specific implementation modes are only used for It the bright present invention rather than limits the scope of the invention, after having read the present invention, those skilled in the art are to of the invention The modification of various equivalent forms falls within the application range as defined in the appended claims.
Specific embodiments of the present invention are as follows:
Embodiment 1
Step 1:Embryo processed
First with electronic scale, according to the iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50-1.85 of 2.55-2.75 parts by weight The copper (Cu) of parts by weight, the niobium (Nd) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 weight The rubidium (Rb) of part, the dioxy of the radium (Ra) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze for changing manganese (MnO2) and 7-8 parts by weight, weighs each ingredient, is added in smelting furnace one by one by the material after weighing, Between 1000 DEG C -1500 DEG C, forging coarse-blank;
Step 2:Cooling treatment
By as cast condition blank vacuum high-pressure gas quenching stove heat to 650-700 DEG C, height is continuously used under 3 × 105Pa pressure Purity nitrogen air cooling, after cooling down completely i.e. only;
Step 3:Phosphorating treatment
Phosphorating treatment piston ring is washed with 10-12% aluminum hydroxide solutions carry out ungrease treatment first, and temperature control exists Between 50-55 DEG C, the time is 11-13 minutes, is then washed;It is washed again with 45-55%NaHSO4 solution and carries out pickling processes, temperature At 18-20 DEG C, the time is 5-8 minutes, is then washed for degree control;It is respectively 2 using volume ratio:2:1:1:A concentration of the 56% of 45 The surface prepared of the zinc oxide of HCl, 200ml/l, 4~6g/l, 1.3~1.5g/l sodium nitrate, 1.6~2g/l hydrogen peroxide and water In activator solution, temperature is controlled at 55-62 DEG C, and it is 12-15 minutes to immerse the time;
Step 4:Surface sand-blasting process
The step of piston ring excircle is activated, the activation of outer circle before being sprayed using suction-type dry blasting, sand grains type: Aluminium oxide, 20~30 mesh;Spray pressure:0.3 ± 0.05MPa, compressed air must condense drying;Jet length:35 ± 10mm, spray Sand cycle-index:2~3 times;
Working gas:Main gas:High pure nitrogen N2, purity 98%, 0.5 ± 0.05MPa of outlet pressure, flow 2000~ 2200L/H;
Auxiliary gas (I):Gas Austria Og, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 500~800L/H of flow;
Auxiliary gas (II):High-purity hydrogen H2, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 150~200L/H of flow;
Power parameter:Electric current:420~440A;Voltage:55~60V;
Geometric parameter of nozzle:Compression ratio:3~3.5, compression angle:45°;
Automatic powder feeding system:Internal powder conveying, powder feeding angle:90 °, powder feeding hole distance:9mm, 20~25g/min of powder sending quantity;
Intake method:Tangential admission;
Operating distance:Anode and cathode minimum distance:1~1.5mm;Spray distance:65~75mm;
Spraying rate:Spray gun movement speed:350mm/min, 150~250rpm of workpiece rotational frequency;
The type of cooling:It forces to cool down using compressed air;
Step 5:Piston ring excircle is cut
By the cylindricalo grinding of ring after spraying to fixed dimension and tear folder open, then this collar disintegrate at three groups of every group of length≤ 50mm is mutually bonded together due to the adhesion of outer circle coating in every ring group per loop, with CBN emery wheels by grinding wheel at Type amendment becomes the anti-contour shape of emery wheel;
Step 6:Surface spraying processing
Between 25 DEG C -35 DEG C of temperature, the piston ring that step 6 obtains is placed into ZS-811 solution, is disseminated more than 10 Minute, it further takes out, air-dries, dispel the impurity of surface adhesion, both obtain final products.
Embodiment 2
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Molybdenum (Mo), the 2.35- of the technetium (Te) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The francium (Fr) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, the manganese dioxide (MnO2) of 1-2 parts by weight and 7-8 weights Measure the beryllium-bronze of part.
Embodiment 3
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Palladium (Pd), the 2.35- of the rhodium (Rh) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The manganese dioxide (MnO2) and 7-8 of the barium (Ba) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight 0 The beryllium-bronze of parts by weight.
Embodiment 4
The iron (Fe) of 60-80 parts by weight, the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 parts by weight copper (Cu), Yttrium (Y), the 2.35- of the zirconium (Zr) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The strontium (Sr) of 2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, the manganese dioxide (MnO2) of 1-2 parts by weight and 7-8 weights Measure the beryllium-bronze of part.
The experiment of piston ring structure intensity
Piston ring is placed in stove at different temperatures and is carried out after scorching a period of time, pressure inspection is being placed into It surveys on device, is detected, realize the quality versus of existing piston ring and piston ring made from the invention;
During the experiment, 25, existing piston ring is first taken out, is divided into five groups;In the piston for obtaining each embodiment Ring takes out five respectively, and five big groups are divided into existing piston ring, will be in the existing piston ring and embodiment in each big group Piston ring be divided into five groups, each group is respectively placed in the stove of different temperatures, the identical time is scorched, will processed Piston ring after roasting takes out, and is detected by pressure detector, obtains following experimental result;
In first big group, the piston ring compression strength after being calcined under different temperatures
In second largest group, the piston ring compression strength after being calcined under different temperatures
In the third-largest group, the piston ring compression strength after being calcined under different temperatures
In the fourth-largest group, the piston ring compression strength after being calcined under different temperatures
Compare the inspection result of above-mentioned multiple embodiments, you can learn, the piston ring obtained using this experimental method is being passed through After crossing high-temperature calcination, the structural strength on surface is significantly greater than the surface texture intensity of existing piston ring.
Certain embodiment of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Cannot the limitation to the scope of the claims of the present invention therefore be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (7)

1. the preparation process of Determination of multiple metal elements mixing type piston ring, which is characterized in that the piston ring mainly by iron (Fe), Carbon (C), copper (Cu), niobium (Nd), aluminium (Al), rubidium (Rb), radium (Ra), silica (SiO2), manganese dioxide (MnO2) and beryllium are green Copper is mixed.
2. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 1, which is characterized in that the work Each component content in plug ring can be as follows:The iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50- of 2.55-2.75 parts by weight Aluminium (Al), the 2.25-2.50 of the copper (Cu) of 1.85 parts by weight, the niobium (Nd) of 2.15-2.45 parts by weight, 2.15-2.32 parts by weight The rubidium (Rb) of parts by weight, the radium (Ra) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze of manganese dioxide (MnO2) and 7-8 parts by weight.
3. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 2, which is characterized in that the work The specific procedure of processing of plug ring is as follows:
Step 1:Embryo processed
First with electronic scale, according to the iron (Fe), the carbon (C) of 2.55-2.75 parts by weight, 1.50-1.85 weight of 60-80 parts by weight Part copper (Cu), the niobiums (Nd) of 2.15-2.45 parts by weight, the aluminium (Al) of 2.15-2.32 parts by weight, 2.25-2.50 parts by weight The manganese dioxide of rubidium (Rb), the radium (Ra) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight (MnO2) and the beryllium-bronze of 7-8 parts by weight, each ingredient is weighed, is added in smelting furnace one by one by the material after weighing, Between 1000 DEG C -1500 DEG C, forging coarse-blank;
Step 2:Cooling treatment
By as cast condition blank vacuum high-pressure gas quenching stove heat to 650-700 DEG C, High Purity Nitrogen is continuously used under 3 × 105Pa pressure Air cooling, after cooling down completely i.e. only;
Step 3:Phosphorating treatment
Phosphorating treatment piston ring is washed with 10-12% aluminum hydroxide solutions carry out ungrease treatment first, and temperature is controlled in 50-55 Between DEG C, the time is 11-13 minutes, is then washed;It is washed again with 45-55%NaHSO4 solution and carries out pickling processes, temperature control For system at 18-20 DEG C, the time is 5-8 minutes, is then washed;It is respectively 2 using volume ratio:2:1:1:A concentration of the 56% of 45 It lives on the surface that zinc oxide, 4~6g/l, 1.3~1.5g/l sodium nitrate, 1.6~2g/l hydrogen peroxide and the water of HCl, 200ml/l are prepared Property agent solution in, temperature control at 55-62 DEG C, immerse the time be 12-15 minutes;
Step 4:Surface sand-blasting process
The step of piston ring excircle is activated, the activation of outer circle before being sprayed using suction-type dry blasting, sand grains type:Oxidation Aluminium, 20~30 mesh;Spray pressure:0.3 ± 0.05MPa, compressed air must condense drying;Jet length:35 ± 10mm, sandblasting follow Ring number:2~3 times;
Step 5:Piston ring excircle is cut
By the cylindricalo grinding of ring after spraying to fixed dimension and tear folder open, then this collar is disintegrated into three groups of every group of length≤50mm, It is mutually bonded together due to the adhesion of outer circle coating per loop in per ring group, is corrected abrasive wheel forming with CBN emery wheels As the anti-contour shape of emery wheel;
Step 6:Surface spraying processing
Between 25 DEG C -35 DEG C of temperature, the piston ring that step 6 obtains is placed into ZS-811 solution, is disseminated more than 10 points Clock further takes out, and air-dries, dispels the impurity of surface adhesion, both obtains final products.
4. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 3, which is characterized in that the step In rapid four, specific workflow is as follows:Working gas:Main gas:High pure nitrogen N2, purity 98%, outlet pressure 0.5 ± 0.05MPa, 2000~2200L/H of flow;
Auxiliary gas (I):Gas Austria Og, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 500~800L/H of flow;
Auxiliary gas (II):High-purity hydrogen H2, purity 99.99%, 0.5 ± 0.05MPa of outlet pressure, 150~200L/H of flow;
Power parameter:Electric current:420~440A;Voltage:55~60V;
Geometric parameter of nozzle:Compression ratio:3~3.5, compression angle:45°;
Automatic powder feeding system:Internal powder conveying, powder feeding angle:90 °, powder feeding hole distance:9mm, 20~25g/min of powder sending quantity;
Intake method:Tangential admission;
Operating distance:Anode and cathode minimum distance:1~1.5mm;Spray distance:65~75mm;
Spraying rate:Spray gun movement speed:350mm/min, 150~250rpm of workpiece rotational frequency;
The type of cooling:It forces to cool down using compressed air.
5. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 2, which is characterized in that the work Each component content in plug ring can be as follows:The iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50- of 2.55-2.75 parts by weight Aluminium (Al), the 2.25-2.50 of the copper (Cu) of 1.85 parts by weight, the technetium (Te) of 2.15-2.45 parts by weight, 2.15-2.32 parts by weight The molybdenum (Mo) of parts by weight, the francium (Fr) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze of manganese dioxide (MnO2) and 7-8 parts by weight.
6. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 2, which is characterized in that the work Each component content in plug ring can be as follows:The iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50- of 2.55-2.75 parts by weight Aluminium (Al), the 2.25-2.50 of the copper (Cu) of 1.85 parts by weight, the rhodium (Rh) of 2.15-2.45 parts by weight, 2.15-2.32 parts by weight The palladium (Pd) of parts by weight, the barium (Ba) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze of manganese dioxide (MnO2) and 7-8 parts by weight.
7. the preparation process of Determination of multiple metal elements mixing type piston ring according to claim 2, which is characterized in that the work Each component content in plug ring can be as follows:The iron (Fe) of 60-80 parts by weight, carbon (C), the 1.50- of 2.55-2.75 parts by weight Aluminium (Al), the 2.25-2.50 of the copper (Cu) of 1.85 parts by weight, the zirconium (Zr) of 2.15-2.45 parts by weight, 2.15-2.32 parts by weight The two of the yttrium (Y) of parts by weight, the strontium (Sr) of 2.35-2.85 parts by weight, the silica (SiO2) of 2-3 parts by weight, 1-2 parts by weight The beryllium-bronze of manganese oxide (MnO2) and 7-8 parts by weight.
CN201810512879.6A 2018-05-25 2018-05-25 The preparation process of Determination of multiple metal elements mixing type piston ring Pending CN108555550A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810512879.6A CN108555550A (en) 2018-05-25 2018-05-25 The preparation process of Determination of multiple metal elements mixing type piston ring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810512879.6A CN108555550A (en) 2018-05-25 2018-05-25 The preparation process of Determination of multiple metal elements mixing type piston ring

Publications (1)

Publication Number Publication Date
CN108555550A true CN108555550A (en) 2018-09-21

Family

ID=63540063

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810512879.6A Pending CN108555550A (en) 2018-05-25 2018-05-25 The preparation process of Determination of multiple metal elements mixing type piston ring

Country Status (1)

Country Link
CN (1) CN108555550A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343745A (en) * 2008-08-18 2009-01-14 南京飞燕活塞环股份有限公司 Piston ring inner lining spring black parkerizing method
US20110212340A1 (en) * 2010-02-26 2011-09-01 Caterpillar Inc. Reduced ferrite steel liner
CN102286702A (en) * 2011-08-15 2011-12-21 奥美合金材料科技(北京)有限公司 Iron-based powder and parts prepared from same
CN102776465A (en) * 2012-08-06 2012-11-14 南京飞燕活塞环股份有限公司 Method for applying amorphous nano materials to excircle of piston ring
CN104962839A (en) * 2015-05-22 2015-10-07 南京飞燕活塞环股份有限公司 Piston ring material high in wear resistance, fracture resistance, and hardness
CN105420591A (en) * 2015-11-03 2016-03-23 合肥海源机械有限公司 Machining method of abrasion-resistant automobile piston ring
CN106521344A (en) * 2016-12-14 2017-03-22 苏州富艾姆工业设备有限公司 Machining process of wear resisting piston rod for valve

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343745A (en) * 2008-08-18 2009-01-14 南京飞燕活塞环股份有限公司 Piston ring inner lining spring black parkerizing method
US20110212340A1 (en) * 2010-02-26 2011-09-01 Caterpillar Inc. Reduced ferrite steel liner
CN102286702A (en) * 2011-08-15 2011-12-21 奥美合金材料科技(北京)有限公司 Iron-based powder and parts prepared from same
CN102776465A (en) * 2012-08-06 2012-11-14 南京飞燕活塞环股份有限公司 Method for applying amorphous nano materials to excircle of piston ring
CN104962839A (en) * 2015-05-22 2015-10-07 南京飞燕活塞环股份有限公司 Piston ring material high in wear resistance, fracture resistance, and hardness
CN105420591A (en) * 2015-11-03 2016-03-23 合肥海源机械有限公司 Machining method of abrasion-resistant automobile piston ring
CN106521344A (en) * 2016-12-14 2017-03-22 苏州富艾姆工业设备有限公司 Machining process of wear resisting piston rod for valve

Similar Documents

Publication Publication Date Title
CN113683430B (en) Oxide high-entropy ceramic with defect fluorite structure and preparation method of anti-ablation coating thereof
CN104480462B (en) Iron-based amorphous coating and laser preparation method thereof
CN104789906A (en) Wear-resistant metal coating for hydraulic cylinder and preparation method of wear-resistant metal coating
CN104877397A (en) High-temperature protective coating for steel billets and applications thereof
CN110872713B (en) Y/Y2O3Cold spraying preparation method of metal ceramic protective coating
CN101418815A (en) Method for enhancing wear resistant and corrosion resistant performance of over current component of water pump
CN102091788B (en) Method for industrially producing iron-based dispersion-strengthened material
CN115466114A (en) A high-toughness and long-life ultra-high temperature thermal barrier coating material and its preparation method and application
CN108624839A (en) A kind of preparation method of stainless steel aluminized coating
CN104805356A (en) Metal coating for hydraulic cylinder and preparation method of metal coating
CN104211062A (en) Preparation method of non-oxide eutectic ceramic amorphous powder via reaction spraying
CN103103471B (en) Preparation method of metal ceramic coating
CN108555550A (en) The preparation process of Determination of multiple metal elements mixing type piston ring
WO2021103843A1 (en) Laser cladding and welding high-entropy alloy alcocrfeni/27simn steel composite layer and preparation method therefor
CN109487195B (en) Ultra-limit iron alloy and preparation method thereof
CN104694017B (en) Preparation method of polishing powder for polishing of silicon nitride ceramics
CN101704677A (en) Method for synthesizing and preparing titanium diboride ceramic micropowder by using a high-energy ball-milling alloying method
CN104862686A (en) Corrosion resistant coating layer for surface of hydraulic cylinder and preparation method thereof
CN111962004B (en) Composite ceramic powder for prolonging service life of stainless steel in strong corrosive gas environment and preparation method thereof
CN101654377A (en) Surface coating for furnace roller of continuous annealing furnace and after-treatment method thereof
CN103964691B (en) A kind of fluorescent glass stupalith and preparation method thereof
CN103708429A (en) Preparation method of nano vanadium nitride/chromium nitride composite powder
CN102659448A (en) Zirconia special foam ceramic filter and preparation method thereof
CN108914041B (en) A kind of high temperature resistant hydrochloric acid corrosion resistant synthesis furnace composite material and preparation method thereof
CN103700518B (en) A kind of low-voltage electrical apparatus electrical contact material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180921