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CN108372342A - A kind of increasing material manufacturing method of high-strength alusil alloy - Google Patents

A kind of increasing material manufacturing method of high-strength alusil alloy Download PDF

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Publication number
CN108372342A
CN108372342A CN201810142109.7A CN201810142109A CN108372342A CN 108372342 A CN108372342 A CN 108372342A CN 201810142109 A CN201810142109 A CN 201810142109A CN 108372342 A CN108372342 A CN 108372342A
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strength
increasing material
material manufacturing
alusil alloy
welding
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卢秉恒
方学伟
张丽娟
姚云飞
王缪乾
赵纪元
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Xian Jiaotong University
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Xian Jiaotong University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/04Welding for other purposes than joining, e.g. built-up welding
    • B23K9/044Built-up welding on three-dimensional surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/28Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/286Al as the principal constituent
    • B23K35/288Al as the principal constituent with Sn or Zn
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/16Arc welding or cutting making use of shielding gas
    • B23K9/173Arc welding or cutting making use of shielding gas and of a consumable electrode
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/235Preliminary treatment

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Arc Welding In General (AREA)

Abstract

本发明公开一种高强铝硅合金的增材制造方法,包括以下步骤:A.基板清洗;B.CMT增材制造:采用带有惰性气体保护的CMT焊机及焊接机器人,进行单道焊接;C.层间锤击:每焊完一道就用锤击装置进行锤击,直至大于或等于设定变形量;D.循环B、C步骤,直至完成高强铝硅合金的增材制造。本发明主要利用CMT这一制备工艺,加上在线锤击强化装置,使得锤击后的焊件气孔减少,柱状晶破碎,择优取向消失,抗拉强度达到了180MPa,延伸率超过25%。The invention discloses a high-strength aluminum-silicon alloy additive manufacturing method, comprising the following steps: A. substrate cleaning; B. CMT additive manufacturing: using a CMT welding machine and a welding robot with inert gas protection to perform single-pass welding; C. Hammering between layers: Hammering with a hammering device after each weld is completed, until it is greater than or equal to the set deformation; D. Repeat steps B and C until the additive manufacturing of high-strength aluminum-silicon alloy is completed. The present invention mainly utilizes the preparation technology of CMT, together with an online hammer strengthening device, so that the pores of the weldment after hammering are reduced, the columnar crystals are broken, and the preferred orientation disappears, the tensile strength reaches 180MPa, and the elongation exceeds 25%.

Description

一种高强铝硅合金的增材制造方法A kind of additive manufacturing method of high-strength aluminum-silicon alloy

技术领域technical field

本发明属于增材制造技术领域,特别涉及基一种高强铝硅合金的增材制造方法。The invention belongs to the technical field of additive manufacturing, in particular to an additive manufacturing method based on a high-strength aluminum-silicon alloy.

背景技术Background technique

增材制造方法不同于传统的等材或减材制造技术,它可以直接成形复杂的结构件,且成形过程中无需模具,其生产效率不受工件复杂度的影响,而电弧增材制造技术成形效率高,可达到Kg/h,非常适合于高效增材制造领域。The additive manufacturing method is different from the traditional equal material or subtractive manufacturing technology. It can directly form complex structural parts, and no mold is needed during the forming process. Its production efficiency is not affected by the complexity of the workpiece, while the electric arc additive manufacturing technology forms High efficiency, up to Kg/h, very suitable for high-efficiency additive manufacturing.

CMT(冷金属过渡技术)是电弧增材制造技术中的一种,是一种制造形式灵活,成本相对较低,成形效率高、热输入量较小的增材制造技术,通过机器人或机床的精确控制,可以实现复杂结构件的快速成形。CMT (Cold Metal Transition Technology) is a kind of arc additive manufacturing technology. It is an additive manufacturing technology with flexible manufacturing form, relatively low cost, high forming efficiency and small heat input. Precise control can realize rapid prototyping of complex structural parts.

铝合金因其质量轻、塑韧性好的综合性能被广泛的应用于航天航空,其在国民经济中占有重要的地位。为了提高铝合金的强度,在工业纯铝中加入了Si、Mg、Cu等合金元素,铝合金的强化相包括:CuAl2、Mg2Si、Al2CuMg等,这些强化相在铝中有较大溶解度,且随着温度下降而显著减小。因此需要进行后续的热处理强化,对于大型结构件来说,一方面成本较高,很难找到合适的热处理装置,且处理后会有一定的变形度,另一方面由于加入合金元素后成本会变高。Aluminum alloy is widely used in aerospace because of its light weight, good plasticity and toughness, and it occupies an important position in the national economy. In order to improve the strength of aluminum alloy, Si, Mg, Cu and other alloying elements are added to industrial pure aluminum. The strengthening phase of aluminum alloy includes: CuAl 2 , Mg 2 Si, Al 2 CuMg, etc. These strengthening phases are relatively rare in aluminum. High solubility, which decreases significantly with decreasing temperature. Therefore, follow-up heat treatment strengthening is required. For large structural parts, on the one hand, the cost is high, it is difficult to find a suitable heat treatment device, and there will be a certain degree of deformation after treatment. On the other hand, the cost will change after adding alloy elements. high.

增材制造过程是逐层打印,不同与传统的减材或等材制造,由于温度梯度的关系,制备的材料均有一定的织构,致使材料呈各向异性,限制了在某些场合的应用。The process of additive manufacturing is layer-by-layer printing, which is different from traditional subtractive or equal-material manufacturing. Due to the temperature gradient, the prepared materials have a certain texture, resulting in anisotropic materials, which limits the use of materials in some occasions. application.

发明内容Contents of the invention

本发明的目的在于提供一种高强铝硅合金的增材制造方法,以解决现有技术中存在的一下技术问题:(1)增材制造金属材料具备各向异性的特点,限制了其应用;(2)传统的铸造制备铝合金的方法在增加强化元素Si、Cu或Mg,提高铝合金强度时,成本较高且热处理工艺复杂。本发明方法可使增材制造铝硅合金强度提高,择优取向致使的各向异性消失。The purpose of the present invention is to provide a method for additive manufacturing of high-strength aluminum-silicon alloys to solve the following technical problems in the prior art: (1) The metal material for additive manufacturing has the characteristics of anisotropy, which limits its application; (2) The traditional casting method for preparing aluminum alloys requires high cost and complex heat treatment process when adding strengthening elements Si, Cu or Mg to improve the strength of aluminum alloys. The method of the invention can improve the strength of the aluminum-silicon alloy manufactured by additive manufacturing, and the anisotropy caused by the preferred orientation disappears.

为了实现上述目的,本发明采用如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:

一种高强铝硅合金的增材制造方法,包括以下步骤:A method for additive manufacturing of high-strength aluminum-silicon alloys, comprising the following steps:

A.基板清洗;A. Substrate cleaning;

B.CMT增材制造:采用带有惰性气体保护的CMT焊机及焊接机器人,进行单道焊接;B. CMT additive manufacturing: use CMT welding machine and welding robot with inert gas protection for single-pass welding;

C.层间锤击:每焊完一道就用锤击装置进行锤击,直至大于或等于设定变形量;C. Hammering between layers: Hammering with a hammering device after each weld is completed, until it is greater than or equal to the set deformation amount;

D.循环B、C步骤,直至完成高强铝硅合金的增材制造。D. Repeat steps B and C until the additive manufacturing of high-strength aluminum-silicon alloy is completed.

进一步的,步骤A中将成分与增材制造原料相同的平整基板用丙酮和酒精进行清洗至干净。Further, in step A, the flat substrate with the same composition as the additive manufacturing raw material is cleaned with acetone and alcohol until clean.

进一步的,单道焊接所用金属丝材为4043铝硅合金,该金属丝材组成质量百分数为Si:4.5~6.0%,Fe:0.8%,Cu:0.30%,Mn:0.05%,Mg:0.05%,Zn:0.10%,Ti:0.20%,余量为铝。Further, the metal wire used for single-pass welding is 4043 aluminum-silicon alloy, and the weight percentage of the metal wire is Si: 4.5-6.0%, Fe: 0.8%, Cu: 0.30%, Mn: 0.05%, Mg: 0.05% , Zn: 0.10%, Ti: 0.20%, and the balance is aluminum.

进一步的,金属丝材的直径为0.8至1.6mm。Further, the diameter of the metal wire is 0.8 to 1.6mm.

进一步的,单道焊接时,金属丝材以3至7m/min的速度供给给CMT激励部件,以300至700mm/min的速度沿工件扫描执行CMT增材制造程序。Further, during single-pass welding, the metal wire is fed to the CMT excitation component at a speed of 3 to 7m/min, and the CMT additive manufacturing program is executed by scanning along the workpiece at a speed of 300 to 700mm/min.

进一步的,所述设定变形量为50%。Further, the set deformation amount is 50%.

进一步的,步骤B中单道焊接时,焊接速度300~700mm/min,焊接电流100A。Further, during single pass welding in step B, the welding speed is 300-700mm/min, and the welding current is 100A.

进一步的,步骤D最终获得高强铝硅合金的抗拉强度大于或等于180Mpa,维氏硬度大于或等于62HV。Further, step D finally obtains a high-strength aluminum-silicon alloy with a tensile strength greater than or equal to 180Mpa and a Vickers hardness greater than or equal to 62HV.

进一步的,步骤D最终获得高强铝硅合金延伸率超过25%。Further, step D finally obtains the high-strength aluminum-silicon alloy with an elongation rate exceeding 25%.

相对于现有技术,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

a.本发明主要利用CMT这一新的制备方法,可实现铝合金毛坯件快速成形制造,达到快速灵活地制造出具有特殊形状的零件,且具有方法简单、成本低廉、生产灵活的特点。a. The present invention mainly utilizes the new preparation method of CMT, which can realize the rapid prototyping of aluminum alloy blanks, achieve fast and flexible manufacture of parts with special shapes, and has the characteristics of simple method, low cost and flexible production.

b.该方法制备的铝硅合金可以使Si相呈现出细小的等轴晶,消除了直接焊接得到的粗大树枝晶组织。b. The aluminum-silicon alloy prepared by this method can make the Si phase present fine equiaxed crystals, eliminating the coarse dendrite structure obtained by direct welding.

c.利用该方法可得到抗拉强度180MPa左右,延伸率超过25%的铝硅合金。c. Using this method, an aluminum-silicon alloy with a tensile strength of about 180 MPa and an elongation of more than 25% can be obtained.

附图说明Description of drawings

图1为锤击前后的铝硅合金气孔对比图;其中图1(a)为锤击前视图,图1(b)为锤击后视图;Figure 1 is a comparison diagram of aluminum-silicon alloy pores before and after hammering; Figure 1(a) is a front view of hammering, and Figure 1(b) is a rear view of hammering;

图2为CMT焊后的铝硅合金纵向组织及锤击后的组织对比图;其中,图2(a)为锤击前铝硅合金纵向组织;图2(b)为锤击后铝硅合金纵向组织。Figure 2 is a comparative diagram of the longitudinal structure of Al-Si alloy after CMT welding and the structure after hammering; among them, Figure 2(a) is the longitudinal structure of Al-Si alloy before hammering; Figure 2(b) is the Al-Si alloy after hammering vertical organization.

具体实施方式Detailed ways

下面结合附图和实施例对本发明做详细说明,所述是对本发明的解释,而非限制。The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments, which are explanations of the present invention rather than limitations.

实施例Example

一种高强铝硅合金的增材制造方法,焊接原材料为直径0.8~1.6mm的铝合金焊丝。具体工艺流程如下:An additive manufacturing method for high-strength aluminum-silicon alloy, the welding raw material is aluminum alloy welding wire with a diameter of 0.8-1.6 mm. The specific process is as follows:

A.先将与焊丝成分相同的铝合金基板用丙酮、酒精依次清洗干净;A. First clean the aluminum alloy substrate with the same composition as the welding wire with acetone and alcohol in sequence;

B.装好焊丝,打开Ar保护气体,检查送丝、冷却系统无故障;焊丝为4043铝硅合金,该金属丝材组成质量百分数为Si:4.5~6.0%,Fe:0.8%,Cu:0.30%,Mn:0.05%,Mg:0.05%,Zn:0.10%,Ti:0.20%,余量为铝;B. Install the welding wire, turn on the Ar shielding gas, and check that the wire feeding and cooling systems are not faulty; the welding wire is 4043 aluminum-silicon alloy, and the mass percentage of the metal wire is Si: 4.5-6.0%, Fe: 0.8%, Cu: 0.30 %, Mn: 0.05%, Mg: 0.05%, Zn: 0.10%, Ti: 0.20%, the balance is aluminum;

C.经过步骤B后,用CMT设备按照相应的参数焊接:C. After step B, use CMT equipment to weld according to the corresponding parameters:

a.设定TCP点,编写相应的焊接程序;a. Set the TCP point and write the corresponding welding program;

b.焊接工艺参数为:焊接速度300~700mm/min,焊接电流100A左右,每道等待时间为10s左右。单道焊接时,金属丝材以3至7m/min的速度供给给CMT激励部件,以300至700mm/min的速度沿工件扫描执行CMT增材焊接程序。b. Welding process parameters are: welding speed 300-700mm/min, welding current about 100A, and waiting time for each pass is about 10s. During single-pass welding, the metal wire is fed to the CMT excitation component at a speed of 3 to 7m/min, and the CMT additive welding program is executed by scanning along the workpiece at a speed of 300 to 700mm/min.

D.锤击:利用气锤强化装置,将焊后单道试样进行反复锤击,直至变形量超过50%。D. Hammering: Use the air hammer strengthening device to repeatedly hammer the single-pass sample after welding until the deformation exceeds 50%.

E.重复C、D步骤,直到得到所需高度的试样。E. Repeat steps C and D until the desired height of the sample is obtained.

由图1可以看出,锤击后的铝硅合金焊件气孔明显减少,有利于材料的疲劳寿命的提升。It can be seen from Figure 1 that the porosity of the aluminum-silicon alloy weldment after hammering is significantly reduced, which is beneficial to the improvement of the fatigue life of the material.

由图2可以看出锤击后的铝硅合金焊件纵向柱状晶破碎,晶粒明显细化且由于柱状晶的变形、破碎,消除了增材制造焊件有明显择优取向的问题。It can be seen from Figure 2 that the longitudinal columnar grains of the aluminum-silicon alloy weldment after hammering are broken, and the grains are obviously refined. Due to the deformation and breakage of the columnar grains, the problem of obvious preferred orientation of the additive manufacturing weldment is eliminated.

锤击装置可以为气锤、电磁锤、液压锤或其它能使得铝硅合金产生变形的锤击装置。The hammering device may be an air hammer, electromagnetic hammer, hydraulic hammer or other hammering devices capable of deforming the aluminum-silicon alloy.

单道焊接完成后,待成型焊道降至能够锤击的温度后,将锤头中心与焊道中心调整至重合,按照既定路径进行逐层锤击;变形量控制在50%或以上;达到设定变形量后重复焊接锤击的过程直至达到预定厚度。After the single-pass welding is completed, after the formed weld bead drops to the temperature that can be hammered, adjust the center of the hammer head to coincide with the center of the weld bead, and perform hammering layer by layer according to the established path; the deformation is controlled at 50% or above; After setting the amount of deformation, repeat the process of welding and hammering until the predetermined thickness is reached.

从表1可以看出锤击后的铝硅焊件抗拉强度明显提升,证明在线锤击强化为提高铝硅合金强度的一种有效手段:It can be seen from Table 1 that the tensile strength of the aluminum-silicon weldment after hammering is significantly improved, which proves that online hammering strengthening is an effective means to improve the strength of aluminum-silicon alloys:

表1 锤击前后铝硅合金强度对比Table 1 Strength comparison of Al-Si alloy before and after hammering

试样sample 原始铝硅合金焊件Raw Al-Si Alloy Weldments 锤击后铝硅合金焊件Al-Si alloy weldment after hammering 抗拉强度(MPa)Tensile strength (MPa) 153MPa153 MPa 180MPa180MPa 维氏硬度(HV)Vickers Hardness (HV) 43HV43HV 62HV62HV

Claims (9)

1. a kind of increasing material manufacturing method of high-strength alusil alloy, which is characterized in that include the following steps:
A. base-plate cleaning;
B.CMT increasing material manufacturings:Using CMT welding machines and welding robot with inert gas shielding, single track welding is carried out;
C. interlayer hammers:It is often soldered and is just hammered together with hammering device, until more than or equal to setting deflection;
D. B, step C are recycled, until completing the increasing material manufacturing of high-strength alusil alloy.
2. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that will in step A Ingredient planarizing substrate acetone identical with increasing material manufacturing raw material and alcohol are cleaned to clean.
3. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that single track welds institute It is 4043 alusil alloys with metal wire material, it is Si which, which forms mass percent,:4.5~6.0%, Fe:0.8%, Cu: 0.30%, Mn:0.05%, Mg:0.05%, Zn:0.10%, Ti:0.20%, surplus is aluminium.
4. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 2, which is characterized in that metal wire material A diameter of 0.8 to 1.6mm.
5. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that single track welds When, metal wire material is supplied to CMT driver units with 3 to 7m/min speed, is swept along workpiece with 300 to 700mm/min speed It retouches and executes CMT increasing material manufacturing programs.
6. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that the setting becomes Shape amount is 50%.
7. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that single in step B When road welds, 300~700mm/min of speed of welding, welding current 100A.
8. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that step D is final The tensile strength for obtaining high-strength alusil alloy is greater than or equal to 180Mpa, and Vickers hardness is greater than or equal to 62HV.
9. a kind of increasing material manufacturing method of high-strength alusil alloy according to claim 1, which is characterized in that step D is final It is more than 25% to obtain high-strength alusil alloy elongation percentage.
CN201810142109.7A 2018-02-11 2018-02-11 A kind of increasing material manufacturing method of high-strength alusil alloy Pending CN108372342A (en)

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