CN108059578A - A kind of luminous energy biology carbon source fertilizer and preparation method thereof - Google Patents
A kind of luminous energy biology carbon source fertilizer and preparation method thereof Download PDFInfo
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- CN108059578A CN108059578A CN201810165040.XA CN201810165040A CN108059578A CN 108059578 A CN108059578 A CN 108059578A CN 201810165040 A CN201810165040 A CN 201810165040A CN 108059578 A CN108059578 A CN 108059578A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 87
- 239000003337 fertilizer Substances 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000003895 organic fertilizer Substances 0.000 claims abstract description 24
- 238000003763 carbonization Methods 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000010902 straw Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- 150000001413 amino acids Chemical class 0.000 claims description 16
- 239000011573 trace mineral Substances 0.000 claims description 16
- 235000013619 trace mineral Nutrition 0.000 claims description 16
- 239000011701 zinc Substances 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- 240000008042 Zea mays Species 0.000 claims description 15
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 11
- 235000013339 cereals Nutrition 0.000 claims description 11
- 238000005469 granulation Methods 0.000 claims description 11
- 230000003179 granulation Effects 0.000 claims description 11
- 235000009973 maize Nutrition 0.000 claims description 11
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000005696 Diammonium phosphate Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- DBJUEJCZPKMDPA-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O DBJUEJCZPKMDPA-UHFFFAOYSA-N 0.000 claims description 10
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 10
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 10
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000003610 charcoal Substances 0.000 claims description 6
- 238000012216 screening Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000002509 fulvic acid Substances 0.000 claims description 5
- 229940095100 fulvic acid Drugs 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 244000144972 livestock Species 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003415 peat Substances 0.000 claims description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 5
- 235000011151 potassium sulphates Nutrition 0.000 claims description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- 230000000536 complexating effect Effects 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 37
- 230000000694 effects Effects 0.000 abstract description 8
- 230000035558 fertility Effects 0.000 abstract description 8
- 235000015097 nutrients Nutrition 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 230000012010 growth Effects 0.000 abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000002028 Biomass Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 4
- 235000005822 corn Nutrition 0.000 description 4
- UOXSXMSTSYWNMH-UHFFFAOYSA-L zinc;2-aminoacetate Chemical compound [Zn+2].NCC([O-])=O.NCC([O-])=O UOXSXMSTSYWNMH-UHFFFAOYSA-L 0.000 description 4
- 210000003608 fece Anatomy 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000012271 agricultural production Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003738 black carbon Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000003971 tillage Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004016 soil organic matter Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of luminous energy biology carbon source fertilizer and preparation method thereof, are as made from the raw material of following parts by weight：30 50 parts of biological carbon, 80 100 parts of inorganic fertilizer, 160 180 parts of organic fertilizer, micro- 24 parts, 35 parts of building component.Each raw material synergistic effect, meets the needs of crop in the present invention, and reduces the soil weight, improves the absorption and holding of soil nutrient ion, improves soil microenvironment.Wherein, raw material-maize straw of biological carbon is of low cost, it derives from a wealth of sources, the biological carbon carbonization effect of preparation is good, carbon content is higher than 25%, make it have increases the soil organism, absorbs heavy metal, improvement soil, increases fertility, the effect of enhancing edaphon growth well, so as to improve the soil texture and Drafting Ability.
Description
Technical field
The invention belongs to technical field of fertilizers, and in particular to a kind of luminous energy biology carbon source fertilizer and preparation method thereof.
Background technology
Fertilizer amount remains high in China's agricultural production, except the original productivity of soil cannot improve, middle-and-low-yielding fields ratio
Outside the odjective causes such as example rise, multiple crop index height, low chemical fertilizer utilization ratio is one of the main reasons for this.China's agricultural production fertilising kind
Class, dose and proportioning etc. all have a great impact to cereal crops or yield of commercial crops and quality.Traditional fertilizer is especially
Although it is that compound organic and inorganic fertilizer plays good effect, traditional fertilizer existence component in terms of crop yield is improved
It is unreasonable with nutrient formula, soil fertility can hardly be recovered, improve soil texture or even can also generate side effect, cause soil
Earth is hardened etc..In addition, continuing, largely putting into the huge waste for causing resource for chemical fertilizer, adds social sustainable development
Cost.Therefore, it is the effective measures for reducing chemical fertilizer input to improve utilization rate of fertilizer.
Biological carbon is that biomass has height fragrance compound under anoxic or anaerobic condition through one kind obtained by carbonization pyrolysis
Matter, the country put it into Biochar, and common description also has biological carbon, biological carbon and biomass char.Generally, it is considered that belong to black
Carbon (blackcarbon), abbreviation BC scopes, the main distinction are that BC includes the micro- carbonization of biomass to the whole of burning generation black smoke particle
A process.The soil organism (SOM) is the important indicator of soil fertility and the main carbon of terrestrial ecosystems remit source it
One.Numerous studies show that the application of biomass carbon can improve soil fertility, increase crop yield, and applying biomass carbon can increase fertilizer
Soil improves SOM, withholds soil nutrient, depends primarily upon biomass carbon dosage and stability, specific surface area and porosity promote
Biomass carbon adsorbs SOM, and the small organic molecule of catalytic activity polymerize to form SOM, promotes the formation of soil agreegate.In addition, its
Biological stability can promote the formation of agron, construct soil fertility, and biomass carbon can effectively adjust soil N, P, K in addition
The cycling of nutrients is waited, improves soil water-reataining fertilizer-keeping ability.Britain's environmental protection great master's James's Lovelock claims, and biological carbon is
Mitigate unique hope of Disastrous climate variation.Researcher represents that biological carbon can also improve agricultural productivity, reduce close to carbon
Collect the demand of fertilizer.
The content of the invention
The present invention provides one kind to make full use of biological carbon, and nutrient needed for fair supply plant growth improves soil texture,
Improve the luminous energy biology carbon source fertilizer of utilization rate of fertilizer.
The present invention also provides the preparation methods of the luminous energy biology carbon source fertilizer.
The technical solution adopted by the present invention is as follows：
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：30-50 parts of biological carbon, inorganic fertilizer
80-100 parts of material, 160-180 parts of organic fertilizer, 2-4 parts of trace element, 3-5 parts of building component；
The biological carbon is prepared by maize straw, made from being carbonized, crushing and sieve；
The inorganic fertilizer is according to 1 by urea, Diammonium phosphate (DAP) and potassium sulfate：0.2-0.4：The weight ratio system of 0.3-0.5
；
The organic fertilizer is according to 1 by fermented livestock excrement, fulvic acid and peat：0.2：The weight ratio system of 0.4-0.6
.
Described, building component is according to 1 by zinc ion-porphyrin nano complex compound and nano-titanium dioxide:The weight of 3-5
Than obtained.
Described, zinc ion-porphyrin nano complex compound is as made from following methods：By 10ml acetic acid zinc solutions with
The acetum of tetra- pyridylporphyrins of 1.5ml0.05mmol/L is added in reaction bulb together, and 20-30 DEG C is stirred to react 10-20h,
Obtain zinc ion-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 0.5-1.5mol/L.
Described, the grain size of nano-titanium dioxide is 20-40nm.
Described, trace element is by zinc-amino acid chelate：Chelating amino acids manganese：Amino acid chelated iron：Chelating amino acids
Boron is according to 1：0.4：0.7：0.8 weight ratio composition.
A kind of preparation method of luminous energy biology carbon source fertilizer, is as made from following steps：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 600-700 DEG C of carbonization 3h, carbonization is naturally cold after finishing
But to room temperature, crushed after drying, cross 40 mesh sieves, obtain biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while in rotary drum granulator
In plus steam, make its reunion granulating, dry, be cooled to less than 40 DEG C, screening, obtained luminous energy biology carbon source fertilizer.
Described, the temperature of granulation is 50-55 DEG C, time 3-5min；The temperature of the drying is 80-90 DEG C, the time
For 20-30min.
Described, the grain size of luminous energy biology carbon source fertilizer is 3-4mm.
Beneficial effects of the present invention：Each raw material synergistic effect, meets the needs of crop in the present invention, and reduces soil appearance
Weight improves the absorption and holding of soil nutrient ion, improves soil microenvironment.Wherein, raw material-corn stalk of biological carbon
Stalk is of low cost, derives from a wealth of sources, and the biological carbon carbonization effect of preparation is good, and carbon content is higher than 25%, makes it have good increase
The soil organism absorbs heavy metal, improvement soil, increases fertility, the effect of enhancing edaphon growth, so as to improve soil
Quality and Drafting Ability.Biological carbon and organic fertilizer cooperate, and realize acid-base balance, Nutrient absorption and viscosity absorption, significantly
Enhance improved effect of the biological carbon to soil, while increase soil gap, be conducive to water tariff collection and air circulation, play water conservation
The effect of fertilizer conservation.Building component acts synergistically with biological carbon, significantly improves the absorption property of biological carbon, is the life of edaphon
It deposits offer to inhabit and living environment, increases the growth and breeding of edaphon；Biological carbon can promote building component to luminous energy
It absorbs and utilizes, and then adsorb heavy metal, Pesticide-Polluted Soil of degrading improves soil, increases the effect of fertility.Inorganic fertilizer
Material can provide quickly and effectively short-term fertility supply for plant.Biological carbon and trace element are engaged, and improve crop to micro member
Element absorbs.
Specific embodiment
Following embodiment facilitates a better understanding of the present invention, but does not limit the present invention.Experiment in following embodiments
Method is conventional method unless otherwise specified.
Embodiment 1
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：40 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, micro- 3 parts, 4 parts of building component；
The biological carbon is prepared by maize straw, made from being carbonized, crushing and sieve；
The inorganic fertilizer is according to 1 by urea, Diammonium phosphate (DAP) and potassium sulfate：0.3：Made from 0.4 weight ratio；
The organic fertilizer is according to 1 by fermented livestock excrement, fulvic acid and peat：0.2：Made from 0.5 weight ratio.
Described, building component is according to 1 by zinc ion-porphyrin nano complex compound and nano-titanium dioxide:4 weight ratio
It is obtained.
Described, zinc ion-porphyrin nano complex compound is as made from following methods：By 10ml acetic acid zinc solutions with
The acetum of tetra- pyridylporphyrins of 1.5ml0.05mmol/L is added in reaction bulb together, and 25 DEG C are stirred to react 15h, obtain zinc from
Son-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 1mol/L.
Described, the grain size of nano-titanium dioxide is 20-40nm.
Described, trace element is by zinc-amino acid chelate：Chelating amino acids manganese：Amino acid chelated iron：Chelating amino acids
Boron is according to 1：0.4：0.7：0.8 weight ratio composition.
A kind of preparation method of luminous energy biology carbon source fertilizer, is as made from following steps：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 650 DEG C of carbonization 3h, is naturally cooled to after the completion of carbonization
Room temperature crushes after drying, crosses 40 mesh sieves, obtains biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while in rotary drum granulator
In plus steam, make its reunion granulating, dry, be cooled to less than 40 DEG C, screening, obtained luminous energy biology carbon source fertilizer.
Described, the temperature of granulation is 53 DEG C, time 4min；The temperature of the drying is 85 DEG C, time 25min.
Described, the grain size of luminous energy biology carbon source fertilizer is 3-4mm.
Embodiment 2
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：30 parts of biological carbon, inorganic fertilizer
100 parts, 160 parts of organic fertilizer, micro- 4 parts, 3 parts of building component；
The biological carbon is prepared by maize straw, made from being carbonized, crushing and sieve；
The inorganic fertilizer is according to 1 by urea, Diammonium phosphate (DAP) and potassium sulfate：0.2：Made from 0.5 weight ratio；
The organic fertilizer is according to 1 by fermented livestock excrement, fulvic acid and peat：0.2：Made from 0.4 weight ratio.
Described, building component is according to 1 by zinc ion-porphyrin nano complex compound and nano-titanium dioxide:5 weight ratio
It is obtained.
Described, zinc ion-porphyrin nano complex compound is as made from following methods：By 10ml acetic acid zinc solutions with
The acetum of tetra- pyridylporphyrins of 1.5ml0.05mmol/L is added in reaction bulb together, and 20 DEG C are stirred to react 20h, obtain zinc from
Son-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 0.5mol/L.
Described, the grain size of nano-titanium dioxide is 20-40nm.
Described, trace element is by zinc-amino acid chelate：Chelating amino acids manganese：Amino acid chelated iron：Chelating amino acids
Boron is according to 1：0.4：0.7：0.8 weight ratio composition.
A kind of preparation method of luminous energy biology carbon source fertilizer, is as made from following steps：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 600 DEG C of carbonization 3h, is naturally cooled to after the completion of carbonization
Room temperature crushes after drying, crosses 40 mesh sieves, obtains biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while in rotary drum granulator
In plus steam, make its reunion granulating, dry, be cooled to less than 40 DEG C, screening, obtained luminous energy biology carbon source fertilizer.
Described, the temperature of granulation is 55 DEG C, time 3min；The temperature of the drying is 90 DEG C, time 20min.
Described, the grain size of luminous energy biology carbon source fertilizer is 3-4mm.
Embodiment 3
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：50 parts of biological carbon, inorganic fertilizer 80
Part, 180 parts of organic fertilizer, micro- 2 parts, 5 parts of building component；
The biological carbon is prepared by maize straw, made from being carbonized, crushing and sieve；
The inorganic fertilizer is according to 1 by urea, Diammonium phosphate (DAP) and potassium sulfate：0.4：Made from 0.3 weight ratio；
The organic fertilizer is according to 1 by fermented livestock excrement, fulvic acid and peat：0.2：Made from 0.6 weight ratio.
Described, building component is according to 1 by zinc ion-porphyrin nano complex compound and nano-titanium dioxide:3 weight ratio
It is obtained.
Described, zinc ion-porphyrin nano complex compound is as made from following methods：By 10ml acetic acid zinc solutions with
The acetum of tetra- pyridylporphyrins of 1.5ml0.05mmol/L is added in reaction bulb together, and 30 DEG C are stirred to react 10h, obtain zinc from
Son-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 1.5mol/L.
Described, the grain size of nano-titanium dioxide is 20-40nm.
Described, trace element is by zinc-amino acid chelate：Chelating amino acids manganese：Amino acid chelated iron：Chelating amino acids
Boron is according to 1：0.4：0.7：0.8 weight ratio composition.
A kind of preparation method of luminous energy biology carbon source fertilizer, is as made from following steps：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 700 DEG C of carbonization 3h, is naturally cooled to after the completion of carbonization
Room temperature crushes after drying, crosses 40 mesh sieves, obtains biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while in rotary drum granulator
In plus steam, make its reunion granulating, dry, be cooled to less than 40 DEG C, screening, obtained luminous energy biology carbon source fertilizer.
Described, the temperature of granulation is 50 DEG C, time 5min；The temperature of the drying is 80 DEG C, time 30min.
Described, the grain size of luminous energy biology carbon source fertilizer is 3-4mm.
Comparative example 1
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：40 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, micro- 3 parts, zinc ion -4 parts of porphyrin nano complex compound；
Remaining is the same as embodiment 1.
Comparative example 2
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：40 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, micro- 3 parts, 4 parts of nano-titanium dioxide；
Remaining is the same as embodiment 1.
Comparative example 3
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：40 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, 3 parts of trace element；
Remaining is the same as embodiment 1.
Comparative example 4
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：40 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, micro- 3 parts, 4 parts of building component；
A kind of preparation method of luminous energy biology carbon source fertilizer, is as made from following steps：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 750-800 DEG C of carbonization 3h, carbonization is naturally cold after finishing
But to room temperature, crushed after drying, cross 40 mesh sieves, obtain biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while in rotary drum granulator
In plus steam, make its reunion granulating, dry, be cooled to less than 40 DEG C, screening, obtained luminous energy biology carbon source fertilizer.
Remaining is the same as embodiment 1.
Comparative example 5
A kind of luminous energy biology carbon source fertilizer, is as made from the raw material of following parts by weight：20 parts of biological carbon, inorganic fertilizer 90
Part, 170 parts of organic fertilizer, micro- 3 parts, 4 parts of building component；
Remaining is the same as embodiment 1.
Corn manure trial
Experimental cultivar：Lay agriculture 14.
Test site：Tangshan, Hebei Province.
Test period：In October, 2016 is in September, 2017.
Control group：Commercially available composite fertilizer (N-P-K=15-30-30), the production of Tangshan chemical fertilizer limited company
Experimental group 1-3：Fertilizer made from embodiment 1-3.
Experimental group 4-8：Fertilizer made from comparative example 1-5.
Processing mode：It carries out, uniformly spreads fertilizer over the fields fertilizer in soil surface before soil rotary tillage, then rotary tillage enters prior to seeding
Soil, per acre using 30 kilograms, field management is identical.Manure trial the results are shown in Table 1, and the influence to corn interior quality the results are shown in Table
2。
1 corn manure trial result of table
Influence result of the table 2 to corn interior quality
The soil organic matter content for showing experimental group 1-3 by soil physico-chemical index test increases, and soil texture is loose,
Crumb structure and porosity increase, while soil potassium element, trace element, soil quantity of useful microbe increased, favorably
In crops normal growth and development, yield and quality significantly improves.
The above is only the preferred embodiment of the present invention, it should be pointed out that：For the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (9)
1. a kind of luminous energy biology carbon source fertilizer, which is characterized in that be as made from the raw material of following parts by weight：Biological carbon 30-50
Part, 80-100 parts of inorganic fertilizer, 160-180 parts of organic fertilizer, 2-4 parts of trace element, 3-5 parts of building component；
The biological carbon is prepared by maize straw, made from being carbonized, crushing and sieve；
The inorganic fertilizer is according to 1 by urea, Diammonium phosphate (DAP) and potassium sulfate：0.2-0.4：Made from the weight ratio of 0.3-0.5；
The organic fertilizer is according to 1 by fermented livestock excrement, fulvic acid and peat：0.2：Made from the weight ratio of 0.4-0.6.
2. luminous energy biology carbon source fertilizer according to claim 1, which is characterized in that the building component is by zinc ion-porphin
Quinoline complexing nano object and nano-titanium dioxide are according to 1:Made from the weight ratio of 3-5.
3. luminous energy biology carbon source fertilizer according to claim 2, which is characterized in that the zinc ion-porphyrin nano complex compound
As made from following methods：10ml acetic acid zinc solutions are added together with the acetum of tetra- pyridylporphyrins of 1.5ml 0.05mmol/L
Enter into reaction bulb, 20-30 DEG C is stirred to react 10-20h, obtains zinc ion-porphyrin nano complex compound.
4. luminous energy biology carbon source fertilizer according to claim 3, which is characterized in that the concentration of the acetic acid zinc solution is 0.5-
1.5mol/L。
5. luminous energy biology carbon source fertilizer according to claim 2, which is characterized in that the grain size of the nano-titanium dioxide is
20-40nm。
6. luminous energy biology carbon source fertilizer according to claim 1, which is characterized in that the trace element is by chelating amino acids
Zinc：Chelating amino acids manganese：Amino acid chelated iron：Chelating amino acids boron is according to 1：0.4：0.7：0.8 weight ratio composition.
7. a kind of preparation method of luminous energy biology carbon source fertilizer any one of claim 1-6, which is characterized in that be by with
Made from lower step：
1) maize straw is sent into vacuum type carbonization kiln, is warming up to 600-700 DEG C of carbonization 3h, is naturally cooled to after the completion of carbonization
Room temperature crushes after drying, crosses 40 mesh sieves, obtains biological carbon；
2) inorganic fertilizer, organic fertilizer are smashed it through into 30 mesh sieves, adds in trace element, be uniformly mixed, obtain powder；
3) charcoal, powder and building component are uniformly mixed, are placed in rotary drum granulator granulation, while add in rotary drum granulator
Steam makes its reunion granulating, drying, is cooled to less than 40 DEG C, and luminous energy biology carbon source fertilizer is made in screening.
8. the preparation method of luminous energy biology carbon source fertilizer according to claim 7, which is characterized in that the temperature of the granulation is
50-55 DEG C, time 3-5min；The temperature of the drying is 80-90 DEG C, time 20-30min.
9. the preparation method of luminous energy biology carbon source fertilizer according to claim 7, which is characterized in that the luminous energy biology carbon source
The grain size of fertilizer is 3-4mm.
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| CN109321255A (en) * | 2018-11-05 | 2019-02-12 | 塔里木大学 | Composition for improving heavily saline-alkali land |
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Application publication date: 20180522 |