CN108042379A - Graphene is modified hair dye - Google Patents
Graphene is modified hair dye Download PDFInfo
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- CN108042379A CN108042379A CN201711395380.3A CN201711395380A CN108042379A CN 108042379 A CN108042379 A CN 108042379A CN 201711395380 A CN201711395380 A CN 201711395380A CN 108042379 A CN108042379 A CN 108042379A
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- graphene
- modified
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- hair dye
- hair
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- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 70
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000000118 hair dye Substances 0.000 title claims abstract description 39
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000003086 colorant Substances 0.000 claims abstract description 26
- 229940074391 gallic acid Drugs 0.000 claims abstract description 21
- 235000004515 gallic acid Nutrition 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012153 distilled water Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000006184 cosolvent Substances 0.000 claims abstract description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 230000000740 bleeding effect Effects 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- -1 graphite Alkene Chemical class 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 108010076876 Keratins Proteins 0.000 claims description 2
- 102000011782 Keratins Human genes 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- 240000003152 Rhus chinensis Species 0.000 claims description 2
- 235000014220 Rhus chinensis Nutrition 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 2
- 229960002089 ferrous chloride Drugs 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 238000009738 saturating Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 210000004209 hair Anatomy 0.000 abstract description 43
- 239000000975 dye Substances 0.000 abstract description 13
- 238000004043 dyeing Methods 0.000 abstract description 11
- 238000004040 coloring Methods 0.000 abstract description 10
- 238000000554 physical therapy Methods 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 14
- 241000196324 Embryophyta Species 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 3
- 210000003780 hair follicle Anatomy 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 201000011510 cancer Diseases 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 210000003128 head Anatomy 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical class OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 241000372906 Vahlodea Species 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 230000003833 cell viability Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000003370 grooming effect Effects 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 239000012676 herbal extract Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000001024 permanent hair color Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 230000002792 vascular Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0613—Apparatus adapted for a specific treatment
- A61N5/0616—Skin treatment other than tanning
- A61N5/0617—Hair treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N5/0613—Apparatus adapted for a specific treatment
- A61N5/0625—Warming the body, e.g. hyperthermia treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N5/00—Radiation therapy
- A61N5/06—Radiation therapy using light
- A61N2005/0658—Radiation therapy using light characterised by the wavelength of light used
- A61N2005/0659—Radiation therapy using light characterised by the wavelength of light used infrared
- A61N2005/066—Radiation therapy using light characterised by the wavelength of light used infrared far infrared
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Radiology & Medical Imaging (AREA)
- Pathology (AREA)
- Biophysics (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The present invention relates to a kind of graphenes to be modified hair dye, including coloring agent and color developing agent；The coloring agent includes each component of following mass fraction：Graphene is modified 5.0~15.0 parts of gallic acid, 10.0~15.0 parts of auxiliary agent, 15.0~25.0 parts of cosolvent, 50.0~60.0 parts of distilled water.The present invention is modified by the graphene to gallic acid so that hair dye, due to reason existing for graphene, plays an important role of far-infrared physiotherapy hair care after hair dyeing.And by the modified gallic acid of graphene, graphene microchip can also be carried by being connected in the coloring agent of graphene microchip and the dye molecule of color developing agent reaction generation, what the graphene microchip of appropriate particle size size can consolidate is stuck in hair scale piece, is not easy to come off from hair, extends coloring.
Description
Technical field
The present invention relates to natural plant hair dye technical fields, specifically, are related to a kind of graphene and are modified hair dye.
Background technology
At present, hair is dyed the multiple colors such as black, brown, brown by more and more people using commercially available hair dye.
Wherein most commonly used dark hair hair dye with color and luster depth, strong coloring force, dye it is black fast the characteristics of and for a long time used by people.So
And the hair dye sold on Vehicles Collected from Market mostly contains p-phenylenediamine and diphenol compounds, there are toxicity, sensitization, causes
It is carcinous.And oxidative hair dyes with the most use contain more than 20 plants chemical composition, wherein nine kinds can cause cell mutation, if for a long time
It is a large amount of to use, and do not pay attention to cleaning, cancer may be caused.Natural plant dye increasingly receives people with its unique security feature
Attention, become the development trend in hair dye market, but the nursing effect and final hair dyeing of natural plants in hair dye
Effect is all also barely satisfactory.
Number of patent application 201310709263.5 discloses a kind of health type herbaceous plant hair dyeing in 103735453 B of CN
The preparation method of agent is used as hair dye using various herbal extracts in the invention, is good for although not containing harmful to human
The chemical hair dye ingredient of health has conditioning hair care using the fruit extract in kind such as ginger, black hair grass, black soya bean, Semen sesami nigrum
Effect, but since the principle of colouring is dyed using the bigger herbaceous plant pigment molecular of molecular weight, so cause
The penetration of vegetable colour molecule is not strong enough, and coloring unobvious improve colouring difficulty.Number of patent application
A kind of preparation method of gallic acid hair dyes is disclosed in 101869536 B of 201010207891.X, CN, is adopted in the invention
It is black so as to reach the dye of human hair with the chromogenic reaction of the gallic acid extracted in herbaceous plant and metal ferrous salt, there is color and luster
The advantages that black fast, raw material of depth, strong coloring force, dye is easy to get, is nontoxic, but this kind of hair dye only has the performance of hair dyeing, no
Possess corresponding care benefits, be unable to reach the function of hair care and nourishing.
The content of the invention
The defects of for the prior art, the object of the present invention is to provide a kind of graphene non-woven fabrics preparation method and should
With.
The purpose of the present invention is what is be achieved through the following technical solutions：
The present invention provides a kind of graphenes to be modified hair dye, including coloring agent and color developing agent；The coloring agent include with
The each component of lower mass fraction：Graphene is modified 5.0~15.0 parts of gallic acid, 10.0~15.0 parts of auxiliary agent, cosolvent 15.0
~25.0 parts, 50.0~60.0 parts of distilled water.
Preferably, the graphene is modified in gallic acid, the weight percent of graphene and gallic acid for 5.0~
15.0%：80.0~95.0%.
Preferably, the graphene is redox graphene.
Preferably, the grain size of the graphene is 0.5 μm -5 μm.If grain size is too low, when being had hair dyed, graphene is micro-
What piece can not be stablized is stuck in the gap of hair scale piece so that hair and the dyestuff combination power in graphene microchip is not strong, easily falls
Color；If graphene microchip grain size is excessive, bleeding agent is not easily accessible when opening hair scale piece in the gap of hair scale piece so that dye
Material floats over hair surface, can still cause the phenomenon that easily fades.
Preferably, the graphene is modified gallic acid and is prepared using following methods：By graphene dispersion in aqueous solution,
Add gallic acid, temperature for be stirred to react at 50~80 DEG C 6~8 it is small when, gained reaction product is evaporated recrystallization
Gallic acid is modified up to the graphene.If reaction temperature is too low, reaction speed can be caused slow, reaction is incomplete, does not partly have
Gallate-based can not be attached in graphene microchip, and when hair dyeing can cause coloring agent insufficient, effect unobvious of painting；If temperature mistake
Height, reaction speed is fast, easily leads to gallic acid and is unevenly distributed in graphene microchip so that dyeing when distribution of color not
Uniformly.
Preferably, the color developing agent includes each component of following mass fraction：5.0~15.0 parts of metal ferrous salt, auxiliary agent
10.0~15.0 parts, 15.0~25.0 parts of cosolvent, 50.0~60.0 parts of distilled water.
Preferably, the auxiliary agent includes at least one in thickener, bleeding agent, basifier, surfactant, conditioner
Kind；The thickener is sodium cellulose glycolate, Sodium Polyacrylate, xanthans, gelatin, guar gum, arabia gum and hydroxyl
One or more kinds of combinations in methylcellulose；Bleeding agent is the mixing of one or both of aqueous azone and alkaline histidine
Object；Basifier is one or both of ethanolamine, ammonium hydroxide, sodium hydroxide combination of the above；Surfactant is silicone oil, single tristearin
One or both of acid glyceride, lauryl sulfate and sodium sulfate of polyethenoxy ether of fatty alcohol combination of the above；Conditioner
For one or both of water-soluble lanolin and hydrolysis of keratin composition.
Preferably, the auxiliary agent includes each component of following mass fraction：10.0~20.0 parts of thickener, bleeding agent 1.0
~10.0,30.0~50.0 parts of basifier, 25.0~40.0 parts of surfactant, 1.0~8.0 parts of conditioner.
Preferably, the cosolvent is combination more than one or both of ethylene glycol, ethyl alcohol, isopropanol.
Preferably, the metal ferrous salt is ferrous sulfate, one kind in ferrous chloride or its combination.
Preferably, the mass ratio of the coloring agent and color developing agent is 1:1.
It is highly preferred that it is 1.1 that the graphene, which is modified gallic acid and the mass ratio of metal ferrous salt,:1, coloring agent is slightly
It is excessive, convenient for fully with color developing agent metal ferrous iron reactant salt so that metal ferrous salt noresidue.
The preparation method that the graphene is modified hair dye comprises the following steps：
The preparation of coloring agent A：(1) graphene is modified gallic acid, thickener, bleeding agent, surfactant, conditioner
Mixing is stirred evenly under the action of solubilizer according to proportioning；(2) basifier and distilled water are utilized by the mixture in step (1)
PH modulation 8~9 can be prepared by coloring agent A.
The preparation of color developing agent B：(1) by metal ferrous salt, thickener, bleeding agent, surfactant, conditioner according to proportioning
Mixing is stirred evenly under the action of solubilizer；(2) the mixture PH tune that will be prepared using basifier and distilled water in step (1)
System 8~9 can be prepared by color developing agent B.
The application method that the graphene is modified hair dye is：First by Hair grooming water logging wash clean, with towel head
Moisture on hair makes hair keep semi-moist state, is then equably coated on hair coloring agent A, head is encased with preservative film
Hair (most handy heating cap heating hair), is kept for 30~40 minutes, then color developing agent B is uniformly applied on hair, uses preservative film
Hair (most handy heating cap heating hair) is encased, entire hair dye is completed in holding 30~be eluted with water after forty minutes.
Dyeing colouring principle is：Coloring agent A is applied on hair, and the hair scale piece of hair is opened under the action of bleeding agent,
Graphene is helped to be modified gallic acid to enter inside hair；Color developing agent B is being applied on hair again at this time, is being contained in color developing agent
Metal ferrous salt in ferrous ion showed with the complex compound of three-fold coordination can be formed into the gallic acid inside hair
Black.And then the effect of colouring.
Compared with prior art, the present invention has following advantageous effect：
The hair dye dyeing raw material prepared in the present invention is gallic acid and metal ferrous salt, does not contain the causes such as p-phenylenediamine
Cancer class aniline dyes avoids p-phenylenediamine, benzenediol, strong oxidizer peroxide in conventional oxidation permanent hairdye system
Change the Health cost of the chemical harmful substances confrontation hairs such as hydrogen and scalp tissue；Simultaneously because use gallic acid small molecule and Asia
The reaction of iron ion is used as dyeing raw material, and compared to plant macromolecular dyestuff is directly used, dye molecule is easier into hair
Secured multiple of painting convenient for increasing coloring, is improved in inside；In addition when preparing coloring agent, the stone to gallic acid is passed through
Black alkene is modified so that hair dye, due to reason existing for graphene, plays an important role of far-infrared physiotherapy hair care after hair dyeing.Its
Hair care physical therapy mechanism be：Graphene radiation far-infrared engergy makes intracellular water generate resonance, resonant transforming for thermal energy, can be with
Promote fine vascular expansion, improve hair follicle pipeline microcirculation, increase hair follicle pipeline secretory volume, promote harmful substance from hair follicle pipeline
In be decomposed, excrete, improve cell viability, reach hair care physiotheraping effect.
In addition, the specific surface area for the dye molecule that simple gallic acid is generated with metal ferrous salt after chromogenic reaction
It is small, increase of the dye molecule in hair scale piece with the number of shampoo is filled in, dye molecule can extract out from hair scale piece, so as to take off
Color；By the modified gallic acid of graphene, the coloring agent of graphene microchip and the dyeing of color developing agent reaction generation are connected with
Also graphene microchip can be carried on molecule, what the graphene microchip of appropriate particle size size can consolidate is stuck in hair scale piece, is not easy
It comes off from hair, extends coloring.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1-5
Embodiment 1-5 provides a kind of graphene and is modified hair dye and preparation method thereof, and the graphene hair dye includes
Coloring agent and color developing agent, each component and content of the coloring agent and color developing agent are as shown in table 1.The coloring agent and color developing agent
Preparation method is as follows：
The preparation method of coloring agent A：(1) first prepare graphene and be modified gallic acid；(2) graphene is modified nutgall
Acid, thickener, bleeding agent, surfactant, conditioner stir evenly mixing according to proportioning under the action of solubilizer；(3) it is sharp
The PH modulation 8~9 of the mixture in step (2) be can be prepared by into coloring agent A with basifier and distilled water.Wherein graphene is modified
The preparation method of gallic acid is：It will add after redox graphene (grain size is 0.5~5 μm) in deionized water ultrasonic disperse
Enter gallic acid, temperature for be stirred to react at 50~80 DEG C 6~8 it is small when, then reaction product is subjected to distillation removal solvent, system
Gallic acid is modified for graphene is gone out.
The preparation method of color developing agent B：(1) by metal ferrous salt, thickener, bleeding agent, surfactant, conditioner according to
Proportioning stirs evenly mixing under the action of solubilizer；(2) mixture that will be prepared using basifier and distilled water in step (1)
PH modulation 8~9 can be prepared by color developing agent B.
Table 1
Comparative example 1-3
Comparative example 1-3 provides a kind of graphene and is modified hair dye and preparation method thereof, and the graphene hair dye includes
Coloring agent and color developing agent, each component and content of the coloring agent and color developing agent are as shown in table 1.The coloring agent and color developing agent
Preparation method is identical with embodiment.
Comparative example 4
It provides a kind of graphene and is modified hair dye and preparation method thereof, each component and content of the graphene hair dye
Shown in embodiment 1, it the difference is that only:It is to use non-redox that graphene described in this comparative example, which is modified gallic acid,
Graphene be modified.
Performance test
Graphene prepared by each embodiment and comparative example is modified hair dye to be tested for the property, test method is：Sense organ
Test.The results are shown in Table 1.
Table 1
There are many concrete application approach of the present invention, and the above is only the preferred embodiment of the present invention.More than it should be pointed out that
Embodiment is merely to illustrate the present invention, and the protection domain being not intended to limit the invention.For the common skill of the art
For art personnel, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as this hair
Bright protection domain.
Claims (10)
1. a kind of graphene is modified hair dye, which is characterized in that including coloring agent and color developing agent；The coloring agent includes following matter
Measure each component of number：Graphene 5.0~15.0 parts of gallic acid of modification, 10.0~15.0 parts of auxiliary agent, cosolvent 15.0~
25.0 parts, 50.0~60.0 parts of distilled water.
2. graphene according to claim 1 is modified hair dye, which is characterized in that the graphene is modified gallic acid
In, the weight percent of graphene and gallic acid is 5.0~15.0%：80.0~95.0%.
3. graphene according to claim 2 is modified hair dye, which is characterized in that the graphene is redox graphite
Alkene.
4. the graphene according to Claims 2 or 3 is modified hair dye, which is characterized in that the grain size of the graphene is 0.5
μm-5μm。
5. the graphene according to Claims 2 or 3 is modified hair dye, which is characterized in that the graphene is modified nutgall
Acid is prepared using following methods：By graphene dispersion in aqueous solution, gallic acid is added, is stirred in the case where temperature is 50~80 DEG C
Mix reaction 6~8 it is small when, gained reaction product be evaporated recrystallizes up to the graphene be modified gallic acid.
6. graphene according to claim 1 is modified hair dye, which is characterized in that the color developing agent includes following mass parts
Several each components：5.0~15.0 parts of metal ferrous salt, 10.0~15.0 parts of auxiliary agent, 15.0~25.0 parts of cosolvent, distilled water
50.0~60.0 parts.
7. graphene is modified hair dye according to claim 1 or 5, which is characterized in that the auxiliary agent includes thickener, oozes
At least one of saturating agent, basifier, surfactant, conditioner；The thickener is sodium cellulose glycolate, polyacrylic acid
One or more kinds of combinations in sodium, xanthans, gelatin, guar gum, arabia gum and hydroxymethyl cellulose；Bleeding agent is
One or both of aqueous azone and alkaline histidine mixture；Basifier is ethanolamine, one kind in ammonium hydroxide, sodium hydroxide
Or two or more combinations；Surfactant is silicone oil, glycerin monostearate, lauryl sulfate and aliphatic alcohol polyethenoxy
One or both of ether sodium sulfate combination of the above；Conditioner is water-soluble one or both of lanolin and hydrolysis of keratin
Composition.
8. graphene is modified hair dye according to claim 1 or 5, which is characterized in that the cosolvent is ethylene glycol, second
Combination more than one or both of alcohol, isopropanol.
9. graphene according to claim 5 is modified hair dye, which is characterized in that the metal ferrous salt is sub- for sulfuric acid
One kind or its combination in iron, ferrous chloride.
10. graphene according to claim 1 is modified hair dye, which is characterized in that the matter of the coloring agent and color developing agent
Amount is than being 1:1.
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| CN108814997A (en) * | 2018-08-24 | 2018-11-16 | 福建拓烯新材料科技有限公司 | The preparation method and graphene hair dye of graphene hair dye |
| CN108852902A (en) * | 2018-08-24 | 2018-11-23 | 福州峰禧知识产权服务有限公司 | A kind of preparation method and graphene hair dye of graphene hair dye |
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| CN113398009A (en) * | 2021-05-26 | 2021-09-17 | 马宋 | Natural plant hair dye capable of filtering extract and preparation method thereof |
| CN113425609A (en) * | 2021-07-30 | 2021-09-24 | 上海舒尔雅日化有限公司 | Polysilazane graphene hair dye and preparation method and use method thereof |
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| CN108814997A (en) * | 2018-08-24 | 2018-11-16 | 福建拓烯新材料科技有限公司 | The preparation method and graphene hair dye of graphene hair dye |
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| CN108814998B (en) * | 2018-08-24 | 2019-12-03 | 福建拓烯新材料科技有限公司 | A kind of preparation method of hair dye based on graphene |
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| CN110638669A (en) * | 2019-10-16 | 2020-01-03 | 商丘师范学院 | A kind of preparation method of graphene hair dye and graphene hair dye |
| CN110638669B (en) * | 2019-10-16 | 2022-03-22 | 商丘师范学院 | A kind of preparation method of graphene hair dye and graphene hair dye |
| CN113398009A (en) * | 2021-05-26 | 2021-09-17 | 马宋 | Natural plant hair dye capable of filtering extract and preparation method thereof |
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