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CN107988603B - Device and method for protecting cable from corrosion by using externally applied current of rainwater conduction - Google Patents

Device and method for protecting cable from corrosion by using externally applied current of rainwater conduction Download PDF

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CN107988603B
CN107988603B CN201711401388.6A CN201711401388A CN107988603B CN 107988603 B CN107988603 B CN 107988603B CN 201711401388 A CN201711401388 A CN 201711401388A CN 107988603 B CN107988603 B CN 107988603B
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cable
auxiliary anode
corrosion
potentiostat
applied current
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CN107988603A (en
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李胜利
胡鹏越
姜楠
赵湘育
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Zhengzhou University
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/06Constructional parts, or assemblies of cathodic-protection apparatus
    • C23F13/08Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
    • C23F13/20Conducting electric current to electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/14Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

The invention discloses an impressed current protection cable corrosion protection device utilizing rainwater conduction, which comprises a cable and an auxiliary anode arranged on an insulating sheath at the outer side of the cable; the end part of the cable is provided with a cathode access point and an impressed current protection device; the impressed current protection device comprises a reference electrode, a direct current power supply and a potentiostat, wherein the reference electrode is arranged on an insulating sheath at the outer side of the cable and is insulated from the cable; one end of the direct current power supply is connected with the auxiliary anode through a potentiostat, and the other end of the direct current power supply is connected to the cathode access point through the potentiostat. The invention can strengthen the inhibition of corrosion of the bridge cable in rainfall weather, lighten the influence of corrosion on the service life of the bridge cable, greatly improve the service life of the current cable, and simultaneously, the system is in an open circuit state when no rainfall exists, and no current passes through to save electric energy.

Description

利用雨水导电的外加电流保护缆索防腐蚀装置及方法Anti-corrosion device and method for using rainwater to conduct external current protection cable

技术领域technical field

本发明主要涉及大跨桥梁施工与维护领域,尤其涉及一种利用雨水导电的外加电流保护缆索防腐蚀装置及方法。The invention mainly relates to the field of construction and maintenance of long-span bridges, in particular to an anti-corrosion device and method for an applied current protection cable using rainwater conduction.

背景技术Background technique

社会快速发展,大跨桥梁作为现代交通的重要组成部分发挥着越来越重要的作用。悬索桥、斜拉桥和吊杆拱桥等索桥在大跨桥梁中占有相当大的比例,是跨越大江、海峡桥梁项目主要的桥型,有时甚至是唯一合理的桥型。桥梁缆索作为悬索桥或斜拉桥上的主要承重构件,其可靠性、耐久性直接关系到桥梁整体的结构安全。例如现有桥梁吊索的设计使用年限为20年,而吊索的实际使用年限则很少超过20年;与桥梁的设计使用年限100年相差甚远。桥梁缆索损坏的根本原因主要是应力腐蚀与腐蚀疲劳。从桥梁缆索失效的机制来看,主要是由于大气雨水腐蚀和外界荷载的共同作用引起的,即应力腐蚀、腐蚀疲劳耦合作用下引起的损坏,成为整个缆索的薄弱环节,严重时将影响桥梁承载力。由于腐蚀是偶然性的,应力腐蚀、腐蚀疲劳的耦合作用引起的缆索承载能力的损失通过分析的方法很难确定,因此造成对于桥梁缆索使用寿命预测不准确。而缆索护套开裂、破损部位往往腐蚀最为严重,护套一旦失效,缆索钢丝便会遭到不同程度的腐蚀破坏,严重的甚至导致断丝、断索等情况产生,直接影响桥梁的结构安全性。降雨天气时,由于大气中的雨水和氧气的共同作用,此种现象更为严重,造成较大的经济损失。With the rapid development of society, long-span bridges are playing an increasingly important role as an important part of modern transportation. Suspension bridges, cable-stayed bridges and hanger arch bridges account for a considerable proportion of long-span bridges, and are the main types of bridges spanning large rivers and straits, and sometimes even the only reasonable bridge type. Bridge cables are the main load-bearing components of suspension bridges or cable-stayed bridges, and their reliability and durability are directly related to the overall structural safety of the bridge. For example, the design service life of existing bridge slings is 20 years, but the actual service life of slings is rarely more than 20 years; it is far from the design service life of bridges of 100 years. The root causes of bridge cable damage are mainly stress corrosion and corrosion fatigue. From the point of view of the failure mechanism of bridge cables, it is mainly caused by the joint action of atmospheric rainwater corrosion and external loads, that is, the damage caused by the coupling action of stress corrosion and corrosion fatigue, which becomes the weak link of the entire cable, and will affect the load bearing capacity of the bridge in severe cases. force. Since corrosion is accidental, the loss of cable bearing capacity caused by the coupling effect of stress corrosion and corrosion fatigue is difficult to determine through analytical methods, thus resulting in inaccurate prediction of the service life of bridge cables. The cracked and damaged parts of the cable sheath are often the most severely corroded. Once the sheath fails, the cable steel wire will be corroded to varying degrees, and even lead to broken wires and broken cables, which directly affect the structural safety of the bridge. . In rainy weather, due to the joint action of rainwater and oxygen in the atmosphere, this phenomenon is more serious and causes greater economic losses.

发明内容Contents of the invention

为了解决上述问题,本发明提供了一种利用雨水导电的外加电流保护缆索防腐蚀方法,能够增强在降雨天气对桥梁缆索腐蚀的抑制,减轻腐蚀对桥梁缆索使用寿命的影响,可以大幅提高目前缆索的使用寿命,同时在未降雨时系统处于断路状态,没有电流通过节约电能。In order to solve the above problems, the present invention provides an applied current protection cable anti-corrosion method using rainwater to conduct electricity, which can enhance the inhibition of bridge cable corrosion in rainy weather, reduce the impact of corrosion on the service life of bridge cables, and can greatly improve the current cable performance. At the same time, the system is in an open circuit state when there is no rainfall, and no current passes through to save electric energy.

本发明采用的技术方案为:一种利用雨水导电的外加电流保护缆索防腐蚀装置,包括缆索和安装在缆索外侧绝缘护套上的辅助阳极;所述的缆索的端部上设有阴极接入点和外加电流保护装置;所述的外加电流保护装置包括参比电极、直流电源和恒电位仪,所述的参比电极安装在缆索外侧的绝缘护套上并与缆索绝缘;所述的直流电源的一端通过恒电位仪与辅助阳极连接,另一端通过恒电位仪连接在阴极接入点上。The technical solution adopted in the present invention is: an applied current protection cable anti-corrosion device that uses rainwater to conduct electricity, including a cable and an auxiliary anode installed on the outer insulating sheath of the cable; the end of the cable is provided with a cathode connection point and applied current protection device; the applied current protection device includes a reference electrode, a DC power supply and a potentiostat, and the reference electrode is installed on the insulating sheath outside the cable and insulated from the cable; the DC One end of the power supply is connected to the auxiliary anode through a potentiostat, and the other end is connected to the cathode access point through a potentiostat.

进一步,所述的阴极接入点设置在与辅助阳极相对的缆索端部。Further, the cathode access point is set at the end of the cable opposite to the auxiliary anode.

进一步,所述的辅助阳极是由混合氧化物、硅铁或铅材料制成。Further, the auxiliary anode is made of mixed oxide, ferrosilicon or lead material.

进一步,所述的参比电极由硫酸亚汞电极或甘汞电极制成。Further, the reference electrode is made of a mercurous sulfate electrode or a calomel electrode.

本发明还公开了一种利用雨水导电的外加电流保护缆索防腐蚀方法,该方法包括以下步骤:The invention also discloses a corrosion-resistant method for protecting cables by using rainwater to conduct electricity with an applied current. The method includes the following steps:

第一步,根据缆索护套的开裂破损状况在缆索上选择几点,在点位上设置辅助阳极,辅助阳极与缆索绝缘设置;The first step is to select some points on the cable according to the cracking and damage condition of the cable sheath, and set the auxiliary anode on the point, and the auxiliary anode is insulated from the cable;

第二步,在缆索上合适位置设置阴极接入点;The second step is to set the cathode access point at a suitable position on the cable;

第三步,在缆索护套的损坏位置选择一点或几点,在点位处设置参比电极;The third step is to select one or several points at the damaged position of the cable sheath, and set a reference electrode at the point;

第四步,在缆索底部选择合适位置设置恒电位仪;The fourth step is to select a suitable position at the bottom of the cable to set up the potentiostat;

第五步,将恒电位仪与辅助阳极、阴极接入点、参比电极用电线连接;The fifth step is to connect the potentiostat with auxiliary anode, cathode access point and reference electrode with wires;

第六步,当有降雨时,降雨雨水作为电解质溶液连通辅助阳极与缆索,使之形成导电回路,使缆索产生阴极极化,抑制缆索锈蚀。In the sixth step, when there is rainfall, the rainfall rainwater is used as an electrolyte solution to connect the auxiliary anode and the cable to form a conductive circuit, which causes the cable to generate cathodic polarization and inhibits the cable from rusting.

本发明产生的有益效果是:本发明利用降雨雨水形成导电回路,该导电回路在缆索破损部位的缆索上产生了阴极极化,增强了对桥梁缆索腐蚀的抑制,同时未降雨时没有电流通过,节约电能,减轻腐蚀对缆索使用寿命的影响,可以大幅提高目前缆索的使用寿命。The beneficial effects produced by the present invention are: the present invention utilizes rainfall and rainwater to form a conductive circuit, and the conductive circuit produces cathodic polarization on the cable at the damaged part of the cable, which enhances the inhibition of bridge cable corrosion, and at the same time, no current passes through when there is no rain, Saving electric energy and reducing the impact of corrosion on the service life of the cable can greatly increase the service life of the current cable.

附图说明Description of drawings

图1是本发明实施例的用于缆索的防腐蚀的外加电流保护装置的构造示意图;Fig. 1 is the structure schematic diagram of the applied current protection device for the anti-corrosion of cable of the embodiment of the present invention;

图2是本发明实施例的缆索结构横断面示意图;Fig. 2 is a schematic cross-sectional view of a cable structure of an embodiment of the present invention;

图3是本发明实施例的缆索结构纵断面示意图;Fig. 3 is a schematic diagram of a longitudinal section of a cable structure of an embodiment of the present invention;

图4是本发明实施例的用于缆索的防腐蚀的外加电流保护装置的连接结构图。Fig. 4 is a connection structure diagram of an applied current protection device for anti-corrosion cables according to an embodiment of the present invention.

图中:1、缆索,2、绝缘护套,3、辅助阳极,4、阴极接入点,5、直流电源,6、护套破损部位,7、参比电极,8、恒电位仪,9、电压表,10、雨水。In the figure: 1. Cable, 2. Insulation sheath, 3. Auxiliary anode, 4. Cathode access point, 5. DC power supply, 6. Damaged part of sheath, 7. Reference electrode, 8. Potentiostat, 9 , Voltmeter, 10, Rainwater.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

本发明公开了一种利用雨水导电的外加电流保护缆索防腐蚀装置,包括缆索1和包覆在缆索1外侧的绝缘护套2,如图2所示。在绝缘护套2上均匀分布有多块辅助阳极3,在缆索1上设置阴极接入点4,所述的辅助阳极3根据缆索绝缘护套2的开裂破损情况、缆索的尺寸、缆索的锈蚀状况、辅助阳极的型号等实际情况进行布置。参比电极7设置在缆索的绝缘护套2外侧并与其接触,保证其在无雨水时与缆索1绝缘。The invention discloses an applied current protection cable anti-corrosion device utilizing rainwater conduction, comprising a cable 1 and an insulating sheath 2 covering the outside of the cable 1, as shown in FIG. 2 . A plurality of auxiliary anodes 3 are evenly distributed on the insulating sheath 2, and a cathode access point 4 is set on the cable 1. The auxiliary anode 3 is based on the cracking and damage of the cable insulating sheath 2, the size of the cable, and the corrosion of the cable. The actual conditions such as the condition and the model of the auxiliary anode are arranged. The reference electrode 7 is arranged on the outside of the insulating sheath 2 of the cable and is in contact with it to ensure that it is insulated from the cable 1 when there is no rain.

如图1所示,本发明中的直流电源5用于提供持续、稳定电压或电流,直流电源5的一端通过恒电位仪8分别与所述多个辅助阳极3相连接,其相对的另一端通过恒电位仪8连接在所述阴极接入点4上。其中恒电位仪8的正极连接辅助阳极3,恒电位仪8的负极连接阴极接入点4。在缆索1上连接有电压表9,电压表9在降雨天气可以实时的监测参比电极处缆索的电位,对比监测到的电位指与保护标准的电位值,控制恒电位仪的输出电压使缆索处于被保护状态。恒电位仪8的输出电流、输出电压可以根据使用条件、被保护缆索结构所需的电流和保护系统回路的电阻进行计算确定。As shown in Figure 1, the DC power supply 5 in the present invention is used to provide continuous, stable voltage or current, and one end of the DC power supply 5 is respectively connected with the plurality of auxiliary anodes 3 through a potentiostat 8, and its opposite end It is connected to the cathode access point 4 through a potentiostat 8 . The positive pole of the potentiostat 8 is connected to the auxiliary anode 3 , and the negative pole of the potentiostat 8 is connected to the cathode access point 4 . A voltmeter 9 is connected to the cable 1, and the voltmeter 9 can monitor the potential of the cable at the reference electrode in real time in rainy weather, compare the monitored potential index with the potential value of the protection standard, and control the output voltage of the potentiostat to make the cable is protected. The output current and output voltage of the potentiostat 8 can be calculated and determined according to the conditions of use, the current required by the protected cable structure and the resistance of the protection system loop.

如图3所示,辅助阳极3布置在绝缘护套2的外侧,在外接直流电源5的作用下,为辅助阳极3提供电子,同时,通过降雨雨水10导电,与缆索1的阴极接入点4间形成导电回路,使缆索1上的阴极接入点4发生阴极极化,从而起到抑制锈蚀的作用。辅助阳极3可以采用铂片、镀铂钛、铸铁、石墨或铅银合金等。辅助阳极3具有电化学惰性,阳极极化率低,损耗少等特性。As shown in Figure 3, the auxiliary anode 3 is arranged on the outside of the insulating sheath 2, and under the action of the external DC power supply 5, it provides electrons for the auxiliary anode 3, and at the same time conducts electricity through the rainfall 10, and connects with the cathode connection point of the cable 1 4 to form a conductive loop, so that the cathodic connection point 4 on the cable 1 is cathodically polarized, thereby inhibiting corrosion. The auxiliary anode 3 can be made of platinum sheet, platinized titanium, cast iron, graphite or lead-silver alloy. The auxiliary anode 3 has the characteristics of electrochemical inertness, low anode polarizability, and less loss.

当降雨时,由于直流电源5可通过恒电位仪8对缆索1暴露在大气中的部分和辅助阳极3施加一定的直流电流,辅助阳极3的表面将发生电化学反应,使其能够不断的向缆索1的阴极接入点4提供电子,从而使缆索1产生阴极极化。当缆索1的阴极接入点4的电位负于某一点位值时,腐蚀的阳极溶解过程就会受到抑制,进而实现对桥梁缆索锈蚀的抑制,可以大幅提高目前缆索的使用寿命,去除了降雨天气下锈蚀对缆索使用寿命的影响,当没有降雨时,系统处于断路状态,电路中没有电流通过节约电能,经济效益和社会效益显著。When it rains, since the DC power supply 5 can apply a certain DC current to the part of the cable 1 exposed to the atmosphere and the auxiliary anode 3 through the potentiostat 8, an electrochemical reaction will occur on the surface of the auxiliary anode 3, so that it can continuously flow to the cable 1. The cathodic access point 4 of the cable 1 supplies electrons, thereby causing cathodic polarization of the cable 1 . When the potential of the cathode connection point 4 of the cable 1 is negative to a certain point value, the anodic dissolution process of corrosion will be inhibited, and then the corrosion of the bridge cable will be inhibited, which can greatly improve the service life of the current cable and eliminate the rainfall. The impact of corrosion on the service life of the cable in weather, when there is no rainfall, the system is in an open circuit state, and there is no current in the circuit to save electric energy, and the economic and social benefits are remarkable.

本发明在具体实施时,可以同时对多个缆索1实施保护,图1中的恒电位仪可以并联多根缆索1,对其施加外加电流保护。When the present invention is implemented, multiple cables 1 can be simultaneously protected, and the potentiostat in FIG. 1 can be connected in parallel with multiple cables 1 to apply external current protection to them.

在本说明书的描述中,参考术语“一个实施例”、“一部分实施例”、“示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料、数量或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且,描述的具体特征、结构、材料、数量或者特点可以在任何的一个或者多个实施例或示例中以合适的方式结合。此外,本领域的技术人员可以将本说明书中描述的不同实施例或示例进行结合和组合。In the description of this specification, descriptions referring to the terms "one embodiment", "a part of embodiments", "example" and the like mean that specific features, structures, materials, quantities or characteristics described in conjunction with the embodiment or example are included in this specification. In at least one embodiment or example of the invention. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials, quantities or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples described in this specification.

尽管上面已经示出和描述了本发明的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本发明的限制,本领域的普通技术人员在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。Although the embodiments of the present invention have been shown and described above, it can be understood that the above embodiments are exemplary and should not be construed as limiting the present invention, those skilled in the art can make the above-mentioned The embodiments are subject to changes, modifications, substitutions and variations.

Claims (5)

1.一种利用雨水导电的外加电流保护缆索防腐蚀装置,其特征在于:包括缆索和安装在缆索外侧绝缘护套上的辅助阳极;所述的缆索的端部上设有阴极接入点和外加电流保护装置;所述的外加电流保护装置包括参比电极、直流电源和恒电位仪,所述的参比电极安装在缆索外侧的绝缘护套上并与缆索绝缘;所述的直流电源的一端通过恒电位仪与辅助阳极连接,另一端通过恒电位仪连接在阴极接入点上。1. An applied current protection cable anti-corrosion device utilizing rainwater conduction is characterized in that: it comprises a cable and an auxiliary anode installed on the cable outer insulating sheath; the end of the cable is provided with a cathode access point and Applied current protection device; the described applied current protection device comprises a reference electrode, a DC power supply and a potentiostat, and the described reference electrode is installed on the insulating sheath outside the cable and insulated from the cable; the DC power supply One end is connected to the auxiliary anode through a potentiostat, and the other end is connected to the cathode access point through a potentiostat. 2.根据权利要求1所述的一种利用雨水导电的外加电流保护缆索防腐蚀装置,所述的阴极接入点设置在与辅助阳极相对的缆索端部。2. The anti-corrosion device for applied current protection cables using rainwater conduction according to claim 1, wherein the cathode access point is arranged at the end of the cable opposite to the auxiliary anode. 3.根据权利要求1所述的一种利用雨水导电的外加电流保护缆索防腐蚀装置,所述的辅助阳极是由混合氧化物、硅铁或铅材料制成。3. The anti-corrosion device for applied current protection cables utilizing rainwater conduction according to claim 1, wherein said auxiliary anode is made of mixed oxide, ferrosilicon or lead material. 4.根据权利要求1所述的一种利用雨水导电的外加电流保护缆索防腐蚀装置,所述的参比电极由硫酸亚汞电极或甘汞电极制成。4. The anticorrosion device for applied current protection cables utilizing rainwater conduction according to claim 1, wherein the reference electrode is made of a mercury sulfate electrode or a calomel electrode. 5.一种利用雨水导电的外加电流保护缆索防腐蚀方法,其特征在于:包括以下步骤:5. An applied current protection cable anti-corrosion method utilizing rainwater conduction, is characterized in that: comprises the following steps: 第一步,根据缆索护套的开裂破损状况在缆索上选择几点,在点位上设置辅助阳极,辅助阳极与缆索绝缘设置;The first step is to select some points on the cable according to the cracking and damage condition of the cable sheath, and set the auxiliary anode on the point, and the auxiliary anode is insulated from the cable; 第二步,在缆索上合适位置设置阴极接入点;The second step is to set the cathode access point at a suitable position on the cable; 第三步,在缆索护套的损坏位置选择一点或几点,在点位处设置参比电极;The third step is to select one or several points at the damaged position of the cable sheath, and set a reference electrode at the point; 第四步,在缆索底部选择合适位置设置恒电位仪;The fourth step is to select a suitable position at the bottom of the cable to set up the potentiostat; 第五步,将恒电位仪与辅助阳极、阴极接入点、参比电极用电线连接;The fifth step is to connect the potentiostat with auxiliary anode, cathode access point and reference electrode with wires; 第六步,当有降雨时,降雨雨水作为电解质溶液连通辅助阳极与缆索,使之形成导电回路,使缆索产生阴极极化,抑制缆索锈蚀。In the sixth step, when there is rainfall, the rainfall rainwater is used as an electrolyte solution to connect the auxiliary anode and the cable to form a conductive circuit, which causes the cable to generate cathodic polarization and inhibits the cable from rusting.
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CN111593354B (en) * 2020-05-27 2022-05-10 重庆交通大学 A method, system and device for cathodic protection of bridge cable with impressed current
CN113237912A (en) * 2021-04-21 2021-08-10 国网江苏省电力有限公司检修分公司 Detection C4F7N/CO2/O2Anti-oxidation test device for compatibility of gas and solid material
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