CN107936856A - A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof - Google Patents
A kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof Download PDFInfo
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- CN107936856A CN107936856A CN201711235984.1A CN201711235984A CN107936856A CN 107936856 A CN107936856 A CN 107936856A CN 201711235984 A CN201711235984 A CN 201711235984A CN 107936856 A CN107936856 A CN 107936856A
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- 230000001070 adhesive effect Effects 0.000 title claims abstract description 49
- 239000000853 adhesive Substances 0.000 title claims abstract description 48
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229920002472 Starch Polymers 0.000 claims abstract description 33
- 239000002994 raw material Substances 0.000 claims abstract description 29
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 28
- 230000008719 thickening Effects 0.000 claims abstract description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 25
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 25
- 235000019890 Amylum Nutrition 0.000 claims abstract description 22
- 239000000945 filler Substances 0.000 claims abstract description 22
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 21
- 239000013530 defoamer Substances 0.000 claims abstract description 21
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 239000003999 initiator Substances 0.000 claims abstract description 21
- 239000007822 coupling agent Substances 0.000 claims abstract description 16
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 16
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 16
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 94
- 241000196324 Embryophyta Species 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 240000003183 Manihot esculenta Species 0.000 claims description 12
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- 239000008107 starch Substances 0.000 claims description 11
- 235000019698 starch Nutrition 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 229920002261 Corn starch Polymers 0.000 claims description 6
- 241000209140 Triticum Species 0.000 claims description 6
- 235000021307 Triticum Nutrition 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 235000005822 corn Nutrition 0.000 claims description 6
- 239000008120 corn starch Substances 0.000 claims description 6
- 229940099112 cornstarch Drugs 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- -1 polypropylene glycerol Polymers 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000010455 vermiculite Substances 0.000 claims description 6
- 229910052902 vermiculite Inorganic materials 0.000 claims description 6
- 235000019354 vermiculite Nutrition 0.000 claims description 6
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 5
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 5
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 5
- LQPUCRPHHIWEMI-UHFFFAOYSA-N C(CCCCCCCCCCC)C(C#N)(C)N.[Na] Chemical compound C(CCCCCCCCCCC)C(C#N)(C)N.[Na] LQPUCRPHHIWEMI-UHFFFAOYSA-N 0.000 claims description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical group CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical group CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 5
- 235000011151 potassium sulphates Nutrition 0.000 claims description 5
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 5
- 229940117958 vinyl acetate Drugs 0.000 claims description 5
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 8
- 241000894006 Bacteria Species 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 4
- 239000003292 glue Substances 0.000 description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 1
- 244000275012 Sesbania cannabina Species 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002543 antimycotic Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of antibacterial high-performance environment-friendly adhesive and preparation method thereof, include the raw material of following parts by weight：25 35 parts of epoxy resin, 24 parts of hardness regulator, 15 20 parts of polyvinyl alcohol, 15 25 parts of polyvinyl acetate, 46 parts of calcium carbonate, 17 21 parts of filler of thickening, 0.3 0.7 parts of bacteriostatic agent, 68 parts of propane diols, 48 parts of emulsifying agent, 23 parts of defoamer, 0.7 1.1 parts of initiator, 57 parts of coupling agent, 10 18 parts of plant amylum, 12 parts of curing accelerator.Its adhesion strength of the invention is high, curing rate is fast, ageing-resistant performance is good, has the advantages that to inhibit bacteria growth, is not easy mouldy, formaldehydeless, safety and environmental protection, period of storage length, low temperature not gel；The raw material components of the present invention are safe and reliable at the same time, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, has higher practical value and good application prospect.
Description
Technical field
The present invention relates to building material technical field, and in particular to a kind of antibacterial high-performance environment-friendly adhesive and its preparation side
Method.
Background technology
Of the same race and xenogenesis construction material can be preferably bonded together by architecture adhesion agent, substitute the works such as original nail, riveting, weldering
Skill, high degree save resource, improve speed of application, reduce project cost etc..In recent years, the increment of architecture adhesion agent
Amplitude considerably beyond other products, its application range also by the application extensions such as the reinforcing, reinforcement, antidetonation of single existing building to
The every field such as road, bridge, subway, culvert, tunnel, dykes and dams, or even newly-built every High speed railway project also largely use
Building structure glue sticking, and with advances in technology, adhesive changes to featuresization, such as heat-resisting, low temperature resistant, insulation,
Expediting setting type, environmental type etc..
On the one hand in order to reach environment protecting, there is the building adhesive that synthesis is gradually replaced using natural plant,
Such as guar gum and sesbania gum.Natural plant generally requires etherification modified or non-ionic hydroxypropyl changes using cationic
Property after, its caking property and it is water-soluble can just greatly improve, but its water resistance is poor, if be chronically exposed in air easily by
Tide, corrosion, and easily come off, there is crack, seriously affected construction quality.
On the other hand with the demand to decorations personalization, family DIY operations are gradually risen, build nail-free glue with
Gradually widely used by people by means of its is easy for construction, the advantages of beautiful is bonded without nail.Chinese Enterprises are also developed in recent years
Several moneys building nail-free glue products, but the kind developed also is only limitted to non-environmental protection product, contain a large amount of hazardous solvents.While by
Moister in the use environment of some glue, bacterium is more, very easy mouldy, and environmental protection, pursuit are increasingly pursued in people
Perfect today, exploitation one kind can improve architectural construction technology, avoid mouldy aging and influence the environment protection architecture of construction effect
Glue is very important.
The content of the invention
The defects of for the prior art, the object of the present invention is to provide a kind of antibacterial high-performance environment-friendly adhesive, this is antibacterial
Its adhesion strength of high-performance environment-friendly adhesive is high, curing rate is fast, ageing-resistant performance is good, has and inhibits bacteria growth, is not easy
Mouldy, formaldehydeless, safety and environmental protection, period of storage are long, low temperature not gel the advantages of；The raw material components of the present invention safely may be used at the same time
Lean on, it is environmentally safe, and raw material is easy to get, cost is relatively low, and technique is concise, before having higher practical value and good application
Scape.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of antibacterial high-performance environment-friendly adhesive, include the raw material of following parts by weight：
25-35 parts of epoxy resin, 2-4 parts of hardness regulator, 15-20 parts of polyvinyl alcohol, 15-25 parts of polyvinyl acetate, carbonic acid
4-6 parts of calcium, thickening 17-21 parts of filler, 0.3-0.7 parts of bacteriostatic agent, 6-8 parts of propane diols, 4-8 parts of emulsifying agent, 2-3 parts of defoamer,
0.7-1.1 parts of initiator, 5-7 parts of coupling agent, 10-18 parts of plant amylum, 1-2 parts of curing accelerator.
Preferably, the antibacterial high-performance environment-friendly adhesive includes the raw material of following parts by weight：
30 parts of epoxy resin, 3 parts of hardness regulator, 18 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 5 parts of calcium carbonate, thickening are filled out
19 parts of material, 0.5 part of bacteriostatic agent, 7 parts of propane diols, 6 parts of emulsifying agent, 2.5 parts of defoamer, 0.9 part of initiator, 6 parts of coupling agent, plant
14 parts of starch, 1.5 parts of curing accelerator.
Preferably, the hardness regulator is methyl acetate, butyl acrylate, vinylacetate weight ratio 2:1:1 composition
Mixture.
Preferably, the thickening filler is vermiculite powder, talcum powder, silica flour according to weight ratio 1:3:The mixing of 2 compositions
Thing, the specification of the thickening filler was 300 mesh.
Preferably, the bacteriostatic agent it is nano oxidized for nano-titanium dioxide, nano zine oxide and Kathon CG according to weight ratio 2:
2:The mixture of 3 compositions.
Preferably, the emulsifying agent includes the raw material of following parts by weight：1-2 parts of octyl phenol polyoxyethylene ether, octadecanol
3-5 parts of polyoxyethylene ether, 1-3 parts of lauryl sodium sulfate, 2-4 parts of sodium dodecyl aminopropionitrile；
The defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio 2:1:2 compositions
Mixture；
The initiator is ammonium sulfate and potassium sulfate according to weight ratio 2:The mixture of 1 composition.
Preferably, the plant amylum is cornstarch, tapioca, wheaten starch according to weight ratio 4:3:1 composition
Mixture；
The preparation method of the plant amylum is：By weight corn, cassava, wheat cleaning, it is added into high speed disintegrator
It is pulverized and mixed, crosses 150 mesh sieves, add suitable water and decocted 50 minutes under 1.5 atmospheric pressure, then gains are spray-dried
.
Preferably, the curing accelerator is cobalt naphthenate, cobalt iso-octoate, methyl ethyl ketone peroxide according to weight ratio 2:2:5
The mixture of composition.
The present invention also provides a kind of preparation method of antibacterial high-performance environment-friendly adhesive, comprise the following steps：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed 300-400
R/min, stirs 25-35 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight are added in homogenizer, and in 40-50 DEG C of temperature, stirring turns
Speed is 200-300 r/min, stirs 10-20 minutes, adds propane diols, continues stirring and sees for 5-9 minutes, obtains mixture B；
Step 4, adds the deionized water of 10-16 times of polyvinyl alcohol and its weight, is then heated up to 92-96 in a kettle
DEG C boil 25-35 minutes, be completely dissolved polyvinyl alcohol, be cooled to 70-76 DEG C, add epoxy resin, insulated and stirred 15-25
Minute, 55-60 DEG C is cooled to, adds polyvinyl acetate, initiator, defoamer, insulated and stirred 40-60 minutes, stirring turns
Fast 300-400r/min, then 30-40 DEG C is cooled to, sequentially add the mixture A of step 2 preparation, mixture prepared by step 3
B, emulsifying agent, hardness regulator, curing accelerator, when continuation insulated and stirred 1-2 is small, speed of agitator 400-600r/min is natural
It is cold to remove the rear antibacterial high-performance environment-friendly adhesive up to the present invention.
Preferably, the preparation process of the antibacterial high-performance environment-friendly adhesive is：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed is 350 r/
Min, stirs 30 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight is added in homogenizer, in temperature 45 C, speed of agitator
For 250r/min, stir 15 minutes, add propane diols, continue stirring and see for 7 minutes, obtain mixture B；
Step 4, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle
30 minutes, polyvinyl alcohol is completely dissolved, is cooled to 73 DEG C, add epoxy resin, insulated and stirred 20 minutes, is cooled to 57
DEG C, polyvinyl acetate, initiator, defoamer, insulated and stirred 50 minutes, speed of agitator 350r/min are added, then be cooled to
35 DEG C, sequentially add the mixture A of step 2 preparation, mixture B prepared by step 3, emulsifying agent, hardness regulator, curing rush
Into agent, when continuation insulated and stirred 1.5 is small, speed of agitator 500r/min is naturally cold to remove the rear antibacterial high-performance ring up to the present invention
Protect adhesive.
Compared with prior art, the present invention has following beneficial effect：
（1）A kind of antibacterial high-performance environment-friendly adhesive of the present invention is main using epoxy resin, polyvinyl alcohol, polyvinyl acetate
Raw material, by stirring fusion reaction, its caking property is preferable, and auxiliary with the addition of plant amylum and further enhance its bonding strength,
The auxiliary agent of addition make it that being firmly bonded for adhesive is reliable, and bin stability is preferable, water-fast weather-proof not shrink.
（2）A kind of plant amylum of antibacterial high-performance environment-friendly adhesive addition of the present invention is mainly cornstarch, cassava
What starch and wheaten starch obtained after extraction polymerize, on the one hand its can effectively reduce the usage amount of polyvinyl alcohol it is nontoxic,
Formaldehydeless pollution, harmless, good environmental protection, another aspect corn, cassava and a few person's plant polyoses of wheat and starch contain
Amount is higher, it is good with bond effect prepared by polyvinyl alcohol, and anti-slipping property is excellent, and performance is stablized.
（3）Calcium carbonate, hardness regulator and the coupling agent of a kind of antibacterial high-performance environment-friendly adhesive addition of the present invention, it is several
Person's compound action can have a thixotropic property, and sizing is convenient and glue will not trickle along facade, can allow building decoration
Become smooth seamless, while the bacteriostatic agent added also has the effect of preferable antimycotic antiseptic, improves the self-cleaning performance of product.
（4）A kind of ceramic tile of the present invention bonds the thickening filler of agent addition, predominantly vermiculite powder, talcum with high-efficiency environment friendly
Powder, silica flour, its granularity is smaller, can effectively with other materials be crosslinked, formed densification paste elastomer, from thermal expansion,
The infringement of freezing up, so that preparing the weatherability that adhesive reaches excellent, on the other hand the filler of addition can be absorbed in air
Pollutant, haveed the function that it is preferable purification air.
（5）A kind of curing accelerator of antibacterial high-performance environment-friendly adhesive addition of the present invention, can improve adhesive
Solidification rate, emulsifying agent, defoamer and the initiator compound action of addition can improve the high and low temperature resistance of adhesive, make
Obtain the mechanical index such as fracture strength, impact strength, peel strength, elongation of stretching after adhesive plastic to significantly improve, sagging
Performance and adhesive property greatly improve.
（6）A kind of antibacterial high-performance environment-friendly adhesive of the present invention, its adhesion strength is high, curing rate is fast, resistance to ag(e)ing
Can be good, have the advantages that to inhibit bacteria growth, be not easy mouldy, formaldehydeless, safety and environmental protection, period of storage length, low temperature not gel；
The raw material components of the present invention are safe and reliable at the same time, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, have compared with
High practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical solution in the embodiment of the present invention is clearly and completely described, is shown
So, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based on the reality in the present invention
Apply example, those of ordinary skill in the art's all other embodiments obtained without making creative work, all belong to
In the scope of protection of the invention.
Embodiment 1.
A kind of antibacterial high-performance environment-friendly adhesive of the present embodiment, includes the raw material of following parts by weight：
25 parts of epoxy resin, 2 parts of hardness regulator, 15 parts of polyvinyl alcohol, 15 parts of polyvinyl acetate, 4 parts of calcium carbonate, thickening are filled out
17 parts of material, 0.3 part of bacteriostatic agent, 6 parts of propane diols, 4 parts of emulsifying agent, 2 parts of defoamer, 0.7 part of initiator, 5 parts of coupling agent, plant are formed sediment
10 parts of powder, 1 part of curing accelerator.
Hardness regulator in the present embodiment is methyl acetate, butyl acrylate, vinylacetate weight ratio 2:1:1 composition
Mixture.
Thickening filler in the present embodiment is vermiculite powder, talcum powder, silica flour are according to weight ratio 1:3:The mixing of 2 compositions
Thing, the specification of the thickening filler was 300 mesh.
It is nano-titanium dioxide, nano zine oxide and Kathon CG according to weight ratio 2 that bacteriostatic agent in the present embodiment is nano oxidized:
2:The mixture of 3 compositions.
Emulsifying agent in the present embodiment includes the raw material of following parts by weight：1 part of octyl phenol polyoxyethylene ether, octadecanol gather
3 parts of ethylene oxide ether, 1 part of lauryl sodium sulfate, 2 parts of sodium dodecyl aminopropionitrile；
The defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio 2:1:2 compositions
Mixture；
The initiator is ammonium sulfate and potassium sulfate according to weight ratio 2:The mixture of 1 composition.
Plant amylum in the present embodiment is cornstarch, tapioca, wheaten starch are according to weight ratio 4:3:1 composition
Mixture；
The preparation method of the plant amylum is：By weight corn, cassava, wheat cleaning, it is added into high speed disintegrator
It is pulverized and mixed, crosses 150 mesh sieves, add suitable water and decocted 50 minutes under 1.5 atmospheric pressure, then gains are spray-dried
.
Curing accelerator in the present embodiment is cobalt naphthenate, cobalt iso-octoate, methyl ethyl ketone peroxide are according to weight ratio 2:2:5
The mixture of composition.
A kind of preparation method of antibacterial high-performance environment-friendly adhesive of the present embodiment, comprises the following steps：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed is 300 r/
Min, stirs 25 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight is added in homogenizer, in 40 DEG C of temperature, speed of agitator
For 200r/min, stir 10 minutes, add propane diols, continue stirring and see for 5 minutes, obtain mixture B；
Step 4, adds the deionized water of 10 times of polyvinyl alcohol and its weight, is then heated up to 92 DEG C and boils in a kettle
25 minutes, polyvinyl alcohol is completely dissolved, is cooled to 70 DEG C, add epoxy resin, insulated and stirred 15 minutes, is cooled to 55
DEG C, polyvinyl acetate, initiator, defoamer, insulated and stirred 40 minutes, speed of agitator 300r/min are added, then be cooled to
30 DEG C, sequentially add the mixture A of step 2 preparation, mixture B prepared by step 3, emulsifying agent, hardness regulator, curing rush
Into agent, when continuation insulated and stirred 1 is small, speed of agitator 400r/min is naturally cold to remove the rear antibacterial high-performance environment-friendly up to the present invention
Adhesive.
Embodiment 2.
A kind of antibacterial high-performance environment-friendly adhesive of the present embodiment, includes the raw material of following parts by weight：
35 parts of epoxy resin, 4 parts of hardness regulator, 20 parts of polyvinyl alcohol, 25 parts of polyvinyl acetate, 6 parts of calcium carbonate, thickening are filled out
21 parts of material, 0.7 part of bacteriostatic agent, 8 parts of propane diols, 8 parts of emulsifying agent, 3 parts of defoamer, 1.1 parts of initiator, 7 parts of coupling agent, plant are formed sediment
18 parts of powder, 2 parts of curing accelerator.
Hardness regulator in the present embodiment is methyl acetate, butyl acrylate, vinylacetate weight ratio 2:1:1 composition
Mixture.
Thickening filler in the present embodiment is vermiculite powder, talcum powder, silica flour are according to weight ratio 1:3:The mixing of 2 compositions
Thing, the specification of the thickening filler was 300 mesh.
It is nano-titanium dioxide, nano zine oxide and Kathon CG according to weight ratio 2 that bacteriostatic agent in the present embodiment is nano oxidized:
2:The mixture of 3 compositions.
Emulsifying agent in the present embodiment includes the raw material of following parts by weight：2 parts of octyl phenol polyoxyethylene ether, octadecanol gather
5 parts of ethylene oxide ether, 3 parts of lauryl sodium sulfate, 4 parts of sodium dodecyl aminopropionitrile；
The defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio 2:1:2 compositions
Mixture；
The initiator is ammonium sulfate and potassium sulfate according to weight ratio 2:The mixture of 1 composition.
Plant amylum in the present embodiment is cornstarch, tapioca, wheaten starch are according to weight ratio 4:3:1 composition
Mixture；
The preparation method of the plant amylum is：By weight corn, cassava, wheat cleaning, it is added into high speed disintegrator
It is pulverized and mixed, crosses 150 mesh sieves, add suitable water and decocted 50 minutes under 1.5 atmospheric pressure, then gains are spray-dried
.
Curing accelerator in the present embodiment is cobalt naphthenate, cobalt iso-octoate, methyl ethyl ketone peroxide are according to weight ratio 2:2:5
The mixture of composition.
A kind of preparation method of antibacterial high-performance environment-friendly adhesive of the present embodiment, comprises the following steps：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed is 400 r/
Min, stirs 35 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight is added in homogenizer, in temperature 50 C, speed of agitator
For 300 r/min, stir 20 minutes, add propane diols, continue stirring and see for 9 minutes, obtain mixture B；
Step 4, adds the deionized water of 16 times of polyvinyl alcohol and its weight, is then heated up to 96 DEG C and boils in a kettle
35 minutes, polyvinyl alcohol is completely dissolved, is cooled to 76 DEG C, add epoxy resin, insulated and stirred 25 minutes, is cooled to 60
DEG C, polyvinyl acetate, initiator, defoamer, insulated and stirred 60 minutes, speed of agitator 400r/min are added, then be cooled to
40 DEG C, sequentially add the mixture A of step 2 preparation, mixture B prepared by step 3, emulsifying agent, hardness regulator, curing rush
Into agent, when continuation insulated and stirred 2 is small, speed of agitator 600r/min is naturally cold to remove the rear antibacterial high-performance environment-friendly up to the present invention
Adhesive.
Embodiment 3.
A kind of antibacterial high-performance environment-friendly adhesive of the present embodiment, includes the raw material of following parts by weight：
30 parts of epoxy resin, 3 parts of hardness regulator, 18 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 5 parts of calcium carbonate, thickening are filled out
19 parts of material, 0.5 part of bacteriostatic agent, 7 parts of propane diols, 6 parts of emulsifying agent, 2.5 parts of defoamer, 0.9 part of initiator, 6 parts of coupling agent, plant
14 parts of starch, 1.5 parts of curing accelerator.
Hardness regulator in the present embodiment is methyl acetate, butyl acrylate, vinylacetate weight ratio 2:1:1 composition
Mixture.
Thickening filler in the present embodiment is vermiculite powder, talcum powder, silica flour are according to weight ratio 1:3:The mixing of 2 compositions
Thing, the specification of the thickening filler was 300 mesh.
It is nano-titanium dioxide, nano zine oxide and Kathon CG according to weight ratio 2 that bacteriostatic agent in the present embodiment is nano oxidized:
2:The mixture of 3 compositions.
Emulsifying agent in the present embodiment includes the raw material of following parts by weight：1 part of octyl phenol polyoxyethylene ether, octadecanol gather
4 parts of ethylene oxide ether, 2 parts of lauryl sodium sulfate, 3 parts of sodium dodecyl aminopropionitrile；
The defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio 2:1:2 compositions
Mixture；
The initiator is ammonium sulfate and potassium sulfate according to weight ratio 2:The mixture of 1 composition.
Plant amylum in the present embodiment is cornstarch, tapioca, wheaten starch are according to weight ratio 4:3:1 composition
Mixture；
The preparation method of the plant amylum is：By weight corn, cassava, wheat cleaning, it is added into high speed disintegrator
It is pulverized and mixed, crosses 150 mesh sieves, add suitable water and decocted 50 minutes under 1.5 atmospheric pressure, then gains are spray-dried
.
Curing accelerator in the present embodiment is cobalt naphthenate, cobalt iso-octoate, methyl ethyl ketone peroxide are according to weight ratio 2:2:5
The mixture of composition.
A kind of preparation method of antibacterial high-performance environment-friendly adhesive of the present embodiment, comprises the following steps：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed is 350 r/
Min, stirs 30 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight is added in homogenizer, in temperature 45 C, speed of agitator
For 250r/min, stir 15 minutes, add propane diols, continue stirring and see for 7 minutes, obtain mixture B；
Step 4, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle
30 minutes, polyvinyl alcohol is completely dissolved, is cooled to 73 DEG C, add epoxy resin, insulated and stirred 20 minutes, is cooled to 57
DEG C, polyvinyl acetate, initiator, defoamer, insulated and stirred 50 minutes, speed of agitator 350r/min are added, then be cooled to
35 DEG C, sequentially add the mixture A of step 2 preparation, mixture B prepared by step 3, emulsifying agent, hardness regulator, curing rush
Into agent, when continuation insulated and stirred 1.5 is small, speed of agitator 500r/min is naturally cold to remove the rear antibacterial high-performance ring up to the present invention
Protect adhesive.
The performance test results of antibacterial high-performance environment-friendly adhesive prepared by various embodiments above are as follows：
| Tensile strength MPa | Tearing strength MPa | Heat resistance（120 DEG C, bubble-free time h） | Elongation at break % | |
| Embodiment 1 | 32 | 4.3 | 4.8 | 169 |
| Embodiment 2 | 35 | 4.3 | 5.1 | 162 |
| Embodiment 3 | 33 | 4.2 | 4.7 | 166 |
| Standard requirement | 21 | 3.7 | 2.3 | 137 |
A kind of antibacterial its adhesion strength of high-performance environment-friendly adhesive height of the present invention, curing rate is fast, ageing-resistant performance is good, tool
Inhibit bacteria growth, be not easy mouldy, formaldehydeless, safety and environmental protection, period of storage be long, low temperature not gel the advantages of；This hair at the same time
Bright raw material components are safe and reliable, environmentally safe, and raw material is easy to get, and cost is relatively low, and technique is concise, has higher practicality
Value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (10)
1. a kind of antibacterial high-performance environment-friendly adhesive, it is characterised in that include the raw material of following parts by weight：
25-35 parts of epoxy resin, 2-4 parts of hardness regulator, 15-20 parts of polyvinyl alcohol, 15-25 parts of polyvinyl acetate, carbonic acid
4-6 parts of calcium, thickening 17-21 parts of filler, 0.3-0.7 parts of bacteriostatic agent, 6-8 parts of propane diols, 4-8 parts of emulsifying agent, 2-3 parts of defoamer,
0.7-1.1 parts of initiator, 5-7 parts of coupling agent, 10-18 parts of plant amylum, 1-2 parts of curing accelerator.
A kind of 2. antibacterial high-performance environment-friendly adhesive according to claim 1, it is characterised in that the antibacterial high-performance ring
Protecting adhesive includes the raw material of following parts by weight：
30 parts of epoxy resin, 3 parts of hardness regulator, 18 parts of polyvinyl alcohol, 20 parts of polyvinyl acetate, 5 parts of calcium carbonate, thickening are filled out
19 parts of material, 0.5 part of bacteriostatic agent, 7 parts of propane diols, 6 parts of emulsifying agent, 2.5 parts of defoamer, 0.9 part of initiator, 6 parts of coupling agent, plant
14 parts of starch, 1.5 parts of curing accelerator.
3. a kind of antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that the hardness is adjusted
Agent is methyl acetate, butyl acrylate, vinylacetate weight ratio 2:1:The mixture of 1 composition.
A kind of 4. antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that the thickening filler
It is vermiculite powder, talcum powder, silica flour according to weight ratio 1:3:The mixture of 2 compositions, the specification of the thickening filler was 300
Mesh.
5. a kind of antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that the bacteriostatic agent is received
Rice is oxidized to nano-titanium dioxide, nano zine oxide and Kathon CG according to weight ratio 2:2:The mixture of 3 compositions.
A kind of 6. antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that the emulsifying agent bag
Include the raw material of following parts by weight：1-2 parts of octyl phenol polyoxyethylene ether, 3-5 parts of octadecanol polyoxyethylene ether, dodecyl sulphate
1-3 parts of sodium, 2-4 parts of sodium dodecyl aminopropionitrile；
The defoamer is silicone emulsion, polypropylene glycerol aether and dimethyl silicone polymer according to weight ratio 2:1:2 compositions
Mixture；
The initiator is ammonium sulfate and potassium sulfate according to weight ratio 2:The mixture of 1 composition.
A kind of 7. antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that the plant amylum
It is cornstarch, tapioca, wheaten starch according to weight ratio 4:3:The mixture of 1 composition；
The preparation method of the plant amylum is：By weight corn, cassava, wheat cleaning, it is added into high speed disintegrator
It is pulverized and mixed, crosses 150 mesh sieves, add suitable water and decocted 50 minutes under 1.5 atmospheric pressure, then gains are spray-dried
.
8. a kind of antibacterial high-performance environment-friendly adhesive according to claim 1 or 2, it is characterised in that described cure promotes
Agent is cobalt naphthenate, cobalt iso-octoate, methyl ethyl ketone peroxide are according to weight ratio 2:2:The mixture of 5 compositions.
A kind of 9. method for preparing antibacterial high-performance environment-friendly adhesive as claimed in claim 1 or 2, it is characterised in that including
Following steps：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed 300-400
R/min, stirs 25-35 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight are added in homogenizer, and in 40-50 DEG C of temperature, stirring turns
Speed is 200-300 r/min, stirs 10-20 minutes, adds propane diols, continues stirring and sees for 5-9 minutes, obtains mixture B；
Step 4, adds the deionized water of 10-16 times of polyvinyl alcohol and its weight, is then heated up to 92-96 in a kettle
DEG C boil 25-35 minutes, be completely dissolved polyvinyl alcohol, be cooled to 70-76 DEG C, add epoxy resin, insulated and stirred 15-25
Minute, 55-60 DEG C is cooled to, adds polyvinyl acetate, initiator, defoamer, insulated and stirred 40-60 minutes, stirring turns
Fast 300-400r/min, then 30-40 DEG C is cooled to, sequentially add the mixture A of step 2 preparation, mixture prepared by step 3
B, emulsifying agent, hardness regulator, curing accelerator, when continuation insulated and stirred 1-2 is small, speed of agitator 400-600r/min is natural
It is cold to remove the rear antibacterial high-performance environment-friendly adhesive up to the present invention.
10. the preparation method of a kind of antibacterial high-performance environment-friendly adhesive according to claim 9, it is characterised in that described
Step is：
Step 1, weighs prepare each component raw material on request；
Step 2, coupling agent, thickening filler, bacteriostatic agent, calcium carbonate are mixed and added in homogenizer, rotating speed is 350 r/
Min, stirs 30 minutes, obtains mixture A；
Step 3, the water that plant amylum is mixed to 3-5 times of its weight is added in homogenizer, in temperature 45 C, speed of agitator
For 250r/min, stir 15 minutes, add propane diols, continue stirring and see for 7 minutes, obtain mixture B；
Step 4, adds the deionized water of 13 times of polyvinyl alcohol and its weight, is then heated up to 94 DEG C and boils in a kettle
30 minutes, polyvinyl alcohol is completely dissolved, is cooled to 73 DEG C, add epoxy resin, insulated and stirred 20 minutes, is cooled to 57
DEG C, polyvinyl acetate, initiator, defoamer, insulated and stirred 50 minutes, speed of agitator 350r/min are added, then be cooled to
35 DEG C, sequentially add the mixture A of step 2 preparation, mixture B prepared by step 3, emulsifying agent, hardness regulator, curing rush
Into agent, when continuation insulated and stirred 1.5 is small, speed of agitator 500r/min is naturally cold to remove the rear antibacterial high-performance ring up to the present invention
Protect adhesive.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108485541A (en) * | 2018-05-04 | 2018-09-04 | 合肥市旺友门窗有限公司 | A kind of decorative wall paper stickup environmentally friendly corrosion resistant adhesive and preparation method thereof |
| CN108610993A (en) * | 2018-04-25 | 2018-10-02 | 合肥欧克斯新型建材有限公司 | A kind of timber floor special-purpose adhesive and preparation method thereof |
| CN108707441A (en) * | 2018-06-22 | 2018-10-26 | 郑州工程技术学院 | A kind of binder of waterproof anti-corrosion and preparation method thereof |
| CN109140101A (en) * | 2018-10-18 | 2019-01-04 | 中国化学工程第六建设有限公司 | Glass reinforced plastic pipe pipe fitting method |
| CN110734730A (en) * | 2018-07-20 | 2020-01-31 | 东莞市博君来胶粘材料科技有限公司 | A kind of silane-modified polyether two-component sealant and preparation method thereof |
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| CN112480850A (en) * | 2020-12-19 | 2021-03-12 | 重庆禄成建筑工程有限公司 | Environment-friendly high-strength adhesive |
| CN114506573A (en) * | 2022-01-04 | 2022-05-17 | 广东赞誉防霉科技有限公司 | Mildew-proof tablet and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107189718A (en) * | 2017-07-07 | 2017-09-22 | 滁州隆扬农业科技有限公司 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
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2017
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107189718A (en) * | 2017-07-07 | 2017-09-22 | 滁州隆扬农业科技有限公司 | A kind of environmentally friendly nail-free glue for building and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108610993A (en) * | 2018-04-25 | 2018-10-02 | 合肥欧克斯新型建材有限公司 | A kind of timber floor special-purpose adhesive and preparation method thereof |
| CN108485541A (en) * | 2018-05-04 | 2018-09-04 | 合肥市旺友门窗有限公司 | A kind of decorative wall paper stickup environmentally friendly corrosion resistant adhesive and preparation method thereof |
| CN108707441A (en) * | 2018-06-22 | 2018-10-26 | 郑州工程技术学院 | A kind of binder of waterproof anti-corrosion and preparation method thereof |
| CN110734730A (en) * | 2018-07-20 | 2020-01-31 | 东莞市博君来胶粘材料科技有限公司 | A kind of silane-modified polyether two-component sealant and preparation method thereof |
| CN109140101A (en) * | 2018-10-18 | 2019-01-04 | 中国化学工程第六建设有限公司 | Glass reinforced plastic pipe pipe fitting method |
| CN110999790A (en) * | 2019-12-26 | 2020-04-14 | 云南师范大学 | A kind of method and subculture method for simultaneously inhibiting bacteria and prolonging subculture time of potato tissue culture seedlings |
| CN112480850A (en) * | 2020-12-19 | 2021-03-12 | 重庆禄成建筑工程有限公司 | Environment-friendly high-strength adhesive |
| CN114506573A (en) * | 2022-01-04 | 2022-05-17 | 广东赞誉防霉科技有限公司 | Mildew-proof tablet and application thereof |
| CN114506573B (en) * | 2022-01-04 | 2023-10-31 | 广东赞誉防霉科技有限公司 | Mildew-proof tablet and application thereof |
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Application publication date: 20180420 |