CN107936651A - A kind of sandals for woman vamp coating composition - Google Patents
A kind of sandals for woman vamp coating composition Download PDFInfo
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- CN107936651A CN107936651A CN201711359082.9A CN201711359082A CN107936651A CN 107936651 A CN107936651 A CN 107936651A CN 201711359082 A CN201711359082 A CN 201711359082A CN 107936651 A CN107936651 A CN 107936651A
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- China
- Prior art keywords
- sandals
- woman
- coating composition
- fungicide
- dispersant
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- 239000008199 coating composition Substances 0.000 title claims abstract description 27
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 29
- 239000000417 fungicide Substances 0.000 claims abstract description 29
- 239000002270 dispersing agent Substances 0.000 claims abstract description 28
- 239000013530 defoamer Substances 0.000 claims abstract description 27
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 25
- 239000002562 thickening agent Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000012153 distilled water Substances 0.000 claims abstract description 15
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 15
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims abstract description 14
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 14
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004816 latex Substances 0.000 claims abstract description 14
- 229920000126 latex Polymers 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 16
- 239000010439 graphite Substances 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 13
- 150000002148 esters Chemical class 0.000 claims description 13
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 3
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- UWIULCYKVGIOPW-UHFFFAOYSA-N Glycolone Natural products CCOC1=C(CC=CC)C(=O)N(C)c2c(O)cccc12 UWIULCYKVGIOPW-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
- 229940043237 diethanolamine Drugs 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 229910021389 graphene Inorganic materials 0.000 abstract description 11
- 230000000845 anti-microbial effect Effects 0.000 abstract description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract description 2
- 239000004005 microsphere Substances 0.000 abstract description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 229920000767 polyaniline Polymers 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 13
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- -1 diethyl Hydramine Chemical compound 0.000 description 11
- 239000001913 cellulose Substances 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000003981 vehicle Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- WXQDFOGZIYLEGP-UHFFFAOYSA-N C(C(C)C)#N.C(C(C)C)#N.[N] Chemical compound C(C(C)C)#N.C(C(C)C)#N.[N] WXQDFOGZIYLEGP-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- YWNYZQTZOONLGU-UHFFFAOYSA-N C(CC)Cl.[O] Chemical compound C(CC)Cl.[O] YWNYZQTZOONLGU-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 229950007687 macrogol ester Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention provides a kind of sandals for woman vamp coating composition, it is characterised in that includes the component of following parts by weight：Ethylene vinyl acetate latex 16 24, polyacrylamide 19 35, N-N-dimethylformamide 13 21, azodiisobutyronitrile 9 14, methyl methacrylate 8 17, dispersant 59, thickener 28, fungicide 23 57, defoamer 13, pH adjusting agent 4 11, epoxychloropropane 59 73, polyaniline graphene hollow microspheres 16 28, distilled water 33 56.The present invention can significantly improve article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, used suitable for large-scale promotion.
Description
Technical field
The present invention relates to footwear applications technical field of coatings, and in particular to a kind of coating for footwear.
Background technology
Coating composition is used in numerous industry.These industry can include, but not limited to land transport vehicle for example
Car, truck, sport vehicle, motorcycle；Marine equipment such as ship, ship and submarine；Aircraft such as aircraft
And helicopter；Industrial such as business equipment and structure, including wall and roof；Build such as Construction traffic and structure, bag
Include wall and roof, military such as military vehicle, such as tank and brave horse transport vehicle, and military structure body, including wall and roof,
Such as caisson and battery case etc..
In these industry, coating for example protects various parts from because of corrosion, wear, impact, change for numerous purposes
Damage caused by product, ultraviolet light, flame and heat and other environmental exposures, and for their components deposited thereon well
Assign shellproof and explosion-proof buffering performance (balllistic and blast mitigation properties).Therefore,
Huge effort is taken to develop the coating composition for having and improving performance.
Coating usually can be used for footwear industry.Footwear (footwear) generally fall into two parts, vamp and sole.
Vamp is the part for being designed as cosily encapsulating foot of footwear, and the attachment that is designed as providing that sole is footwear rubs
Wipe power (traction), protection, damping and/or the part on endurable surface.
Vamp is typically made of many different components, these components are usually made from a variety of materials.The material
Including, such as natural leather, synthetic leather, vinyl material and fabric such as nylon；Other fabrics can also be used.Even in
During the normal use of footwear, many upper members, particularly " toe-cap " may experience loss and/or abrasions.
Similarly, sole generally includes the different components being made from a different material.Midsole typically by foam for example
Ethylene vinyl acetate (EVA) foam or polyurethane such as TPU foams are made.These materials application load, for example exist
By elastic compression under foot and the power of leg generation during body movement.Many footwear, particularly sport footwear are included in another shoes department part example
Filling damping element or bladder in such as midsole, footwear outer bottom.The bladder can be by that can show resistance to compression
To provide expandable insert made of the polymeric material of additional cushioning effect for footwear wearer.These bladders can use-case
As plasma, water or other fluids such as air or nitrogen are filled.Footwear outer bottom is usually by synthesizing and/or natural rubber, such as
Silica-filled rubber composition is made.During the normal use of footwear, footwear outer bottom may also undergo loss and/or
Abrasion.
Therefore, it is intended that article of footwear to being lost, wearing and improved resistance, durability and the antibiotic property of other damages
Energy.
The content of the invention
In view of this, the present invention provides a kind of new sandals for woman vamp coating composition, and the present invention can significantly improve
Article of footwear to being lost, wearing and the resistance of other damages, durability and anti-microbial property, make suitable for large-scale promotion
With.
The technical scheme is that：A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Second
Alkene-vinyl acetate latex 16-24, polyacrylamide 19-35, N-N-dimethylformamide 13-21, azodiisobutyronitrile
9-14, methyl methacrylate 8-17, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH are adjusted
Agent 4-11, epoxychloropropane 59-73, polyaniline-graphite alkene tiny balloon 16-28, distilled water 33-56.
Further, the sandals for woman vamp coating composition includes the component of following parts by weight：Ethane-acetic acid ethyenyl
Ester gum breast 19-22, polyacrylamide 24-31, N-N-dimethylformamide 15-19, azodiisobutyronitrile 10-12, methyl-prop
E pioic acid methyl ester 11-15, dispersant 6-7, thickener 4-7, fungicide 31-46, defoamer 2-3, pH adjusting agent 5-9, ring
Oxygen chloropropane 63-70, polyaniline-graphite alkene tiny balloon 21-25, distilled water 39-45.
Further, the sandals for woman vamp coating composition includes the component of following parts by weight：Ethane-acetic acid ethyenyl
Ester gum breast 21, polyacrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, methyl methacrylate 13,
Dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, epoxychloropropane 67, polyaniline-graphite alkene are empty
Heart microballoon 23, distilled water 42.
Further, the fungicide is graphene oxide.Particularly, fungicide of the invention mix enter polyaniline-
Adsorbed in graphene hollow microspheres, form slowly releasing effect, long-acting antibacterial layer is formed in coating surface.
Further, the coalescents are propane diols, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dipropyl
One kind in glycol dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol butyl ether.
Further, the dispersant is lauryl sodium sulfate, methyl anyl alcohol, polyacrylamide, guar gum, aliphatic acid
One kind in macrogol ester.The poly- diethanol that the dispersant is the poly- diethanol that molecular weight is 5000 and molecular weight is 4000
4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, polyacrylamide, N-N-dimethylformamide, idol
Shaken up after nitrogen bis-isobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.Rear solution will be shaken up and be heated to 40-
50 DEG C, and 60-90min is stirred with 60r/min, obtain mixed solution；S2. polyimides tiny balloon is mixed with fungicide；
S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with the scattered of 4000-5500r/min
Rate Dispersion 20-40min.
Compounded by the synergistic of each component of the present invention, the present invention can significantly improve article of footwear to being lost, wear and
Resistance, durability and the anti-microbial property of other damages, use suitable for large-scale promotion.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, it is clear that described reality
It is only part of the embodiment of the present invention to apply example, instead of all the embodiments.
Embodiment 1
The present embodiment provides a kind of sandals for woman vamp coating composition, the sandals for woman vamp coating composition includes following weight
The component of number：Ethane-acetic acid ethyenyl ester latex 21, polyacrylamide 27, N-N-dimethylformamide 17, two isobutyl of azo
Nitrile 11, methyl methacrylate 13, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, epoxy
Chloropropane 67, polyaniline-graphite alkene tiny balloon 23, distilled water 42.
Further, the fungicide is graphene oxide.
Particularly, fungicide of the invention is mixed to enter in polyaniline-graphite alkene tiny balloon and adsorbed, and forms sustained release effect
Should, long-acting antibacterial layer is formed in coating surface.
Further, the coalescents are propandiol butyl ether.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
The preparation method of coating of the present invention is：S1. by butyl acrylate, polyacrylamide, N-N-dimethylformamide, idol
Shaken up after nitrogen bis-isobutyronitrile, mannitol dissolving, wherein acrylic monomers uses after newly steaming.Rear solution will be shaken up and be heated to 40-
50 DEG C, and 60-90min is stirred with 60r/min, obtain mixed solution；S2. polyimides tiny balloon is mixed with fungicide；
S3. remaining component of the component in S1 and S2 and coating is mixed according to mass fraction, with the scattered of 4000-5500r/min
Rate Dispersion 20-40min.
Embodiment 2
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 21, gather
Acrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, increasing
Thick dose 5, fungicide 39, defoamer 2, pH adjusting agent 8, epoxychloropropane 67, polyaniline-graphite alkene tiny balloon 23, steam
Distilled water 42.
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is the poly- diethanol that molecular weight is 5000 and the poly- diethanol that molecular weight is 4000
4:The mixture of 5 mass ratioes, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 3
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：The sandals for woman vamp coating composition
Include the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 19, polyacrylamide 24, N-N-dimethylformamide
15th, azodiisobutyronitrile 10, methyl methacrylate 11, dispersant 6, thickener 4, fungicide 31, defoamer 2, pH
Conditioning agent 5, epoxychloropropane 63, polyaniline-graphite alkene tiny balloon 21, distilled water 39.
Further, the fungicide is graphene oxide.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is lauryl sodium sulfate, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 4
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 24, gather
Acrylamide 35, N-N-dimethylformamide 21, azodiisobutyronitrile 14, methyl methacrylate 17, dispersant 9, increasing
Thick dose 8, fungicide 57, defoamer 3, pH adjusting agent 11, epoxychloropropane 73, polyaniline-graphite alkene tiny balloon 28,
Distilled water 56.
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 5
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 22, gather
Acrylamide 31, N-N-dimethylformamide 19, azodiisobutyronitrile 12, methyl methacrylate 15, dispersant 7, increasing
Thick dose 7, fungicide 46, defoamer 3, pH adjusting agent 9, epoxychloropropane 70, polyaniline-graphite alkene tiny balloon 25, steam
Distilled water 45.
Further, the fungicide is graphene oxide.
Further, the coalescents are ethylene glycol monobutyl ether.
Further, the dispersant is polyacrylamide, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Embodiment 6
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 16, gather
Acrylamide 19, N-N-dimethylformamide 13, azodiisobutyronitrile 9, methyl methacrylate 8, dispersant 5, thickening
Agent 2, fungicide 23, defoamer 1, pH adjusting agent 4, epoxychloropropane 59, polyaniline-graphite alkene tiny balloon 16, distillation
Water 33.
Further, the fungicide is graphene oxide.
Further, the coalescents are dimethyl ether.
Further, the dispersant is guar gum, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 1
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 21, gather
Acrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, increasing
Thick dose 5, defoamer 2, pH adjusting agent 8, epoxychloropropane 67, polyaniline-graphite alkene tiny balloon 23, distilled water 42.
Further, the coalescents are diethylene glycol monoethyl ether.
Further, the dispersant is fatty acid polyethylene glycol ester, can reach more preferable dispersion effect.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 2
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 21, gather
Acrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, increasing
Thick dose 5, fungicide 39, defoamer 2, pH adjusting agent 8, epoxychloropropane 67, distilled water 42.
Further, the fungicide is graphene oxide.
Further, the coalescents are tripropylene glycol butyl ether.
Further, the dispersant is polyacrylamide.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Comparative example 3
A kind of sandals for woman vamp coating composition, includes the component of following parts by weight：Ethane-acetic acid ethyenyl ester latex 21, gather
Acrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, methyl methacrylate 13, dispersant 6, increasing
Thick dose 5, fungicide 39, defoamer 2, pH adjusting agent 8, polyaniline-graphite alkene tiny balloon 23, distilled water 42.
Further, the fungicide is graphene oxide.
Further, the coalescents are propane diols.
Further, the dispersant is methyl anyl alcohol.
Further, the thickener is hydroxyethyl ether cellulose, and defoamer is tributyl phosphate, and pH adjusting agent is diethyl
Hydramine.
Coating property is tested
Salt spray resistance
Coating in embodiment and comparative example is coated on wooden test piece respectively and in aluminium alloy test piece, aluminium alloy test piece is selected
6063.After paint spraying, tested when standing 48 is small after film forming is fully cured in coating.Adhesive force survey is carried out to above-mentioned coating
Examination, neutral salt spray test, test method according to《GB/T 1720-1979 paint film adhesion determination methods》、《GB/T 10125-2012
Artificial atmosphere corrosion test salt spray test》Carry out；Anti-microbial property test is carried out according to GB/T 21866-2008, test result is such as
Following table.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can pass through this
Field any prior art is realized.
Claims (7)
1. a kind of sandals for woman vamp coating composition, it is characterised in that include the component of following parts by weight：Ethylene-acetate second
Enester latex 16-24, polyacrylamide 19-35, N-N-dimethylformamide 13-21, azodiisobutyronitrile 9-14, methyl
Methyl acrylate 8-17, dispersant 5-9, thickener 2-8, fungicide 23-57, defoamer 1-3, pH adjusting agent 4-11,
Epoxychloropropane 59-73, polyaniline-graphite alkene tiny balloon 16-28, distilled water 33-56.
2. sandals for woman vamp coating composition according to claim 1, it is characterised in that include the group of following parts by weight
Point：Ethane-acetic acid ethyenyl ester latex 19-22, polyacrylamide 24-31, N-N-dimethylformamide 15-19, azo two are different
Butyronitrile 10-12, methyl methacrylate 11-15, dispersant 6-7, thickener 4-7, fungicide 31-46, defoamer 2-
3rd, pH adjusting agent 5-9, epoxychloropropane 63-70, polyaniline-graphite alkene tiny balloon 21-25, distilled water 39-45.
3. sandals for woman vamp coating composition according to claim 1, it is characterised in that include the group of following parts by weight
Point：Ethane-acetic acid ethyenyl ester latex 21, polyacrylamide 27, N-N-dimethylformamide 17, azodiisobutyronitrile 11, first
Base methyl acrylate 13, dispersant 6, thickener 5, fungicide 39, defoamer 2, pH adjusting agent 8, epoxychloropropane 67,
Polyaniline-graphite alkene tiny balloon 23, distilled water 42.
4. sandals for woman vamp coating composition according to claim 1, it is characterised in that the fungicide is graphite oxide
Alkene.
5. sandals for woman vamp coating composition according to claim 1, it is characterised in that the coalescents are the third two
Alcohol, methoxybutanol, ethylene glycol monobutyl ether, propandiol butyl ether, dimethyl ether, diethylene glycol monoethyl ether, tripropylene glycol
One kind in butyl ether.
6. sandals for woman vamp coating composition according to claim 1, it is characterised in that the dispersant is dodecyl
One kind in sodium sulphate, methyl anyl alcohol, polyacrylamide, guar gum, fatty acid polyethylene glycol ester.
7. sandals for woman vamp coating composition according to claim 1, it is characterised in that the thickener is fine for ethoxy
The plain ether of dimension, defoamer is tributyl phosphate, and pH adjusting agent is diethanol amine.
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Application publication date: 20180420 |