CN1076582C - High-efficiency bisultap powder and its preparation - Google Patents
High-efficiency bisultap powder and its preparation Download PDFInfo
- Publication number
- CN1076582C CN1076582C CN99114511A CN99114511A CN1076582C CN 1076582 C CN1076582 C CN 1076582C CN 99114511 A CN99114511 A CN 99114511A CN 99114511 A CN99114511 A CN 99114511A CN 1076582 C CN1076582 C CN 1076582C
- Authority
- CN
- China
- Prior art keywords
- powder
- content
- bisultap
- duple
- insecticidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000843 powder Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 title claims description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 31
- 238000001035 drying Methods 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 21
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011780 sodium chloride Substances 0.000 claims abstract description 15
- 239000001294 propane Substances 0.000 claims abstract description 11
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract description 10
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 9
- 230000036571 hydration Effects 0.000 claims description 6
- 238000006703 hydration reaction Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000001103 potassium chloride Substances 0.000 claims description 5
- 235000011164 potassium chloride Nutrition 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 4
- 238000000889 atomisation Methods 0.000 claims description 4
- 238000007602 hot air drying Methods 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 abstract description 14
- 241000209094 Oryza Species 0.000 abstract description 7
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 7
- 235000009566 rice Nutrition 0.000 abstract description 7
- 241000238631 Hexapoda Species 0.000 abstract description 6
- 241000426497 Chilo suppressalis Species 0.000 abstract description 3
- 241001622642 Parnara bada Species 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 2
- 241000098289 Cnaphalocrocis medinalis Species 0.000 abstract 1
- 241001249129 Scirpophaga incertulas Species 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 241000255901 Tortricidae Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 235000011868 grain product Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 210000004894 snout Anatomy 0.000 description 2
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 231100000566 intoxication Toxicity 0.000 description 1
- 230000035987 intoxication Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a high-efficiency insecticidal duple powder and a preparation method thereof, particularly to a paddy rice field pesticide improved by an insecticidal duple aqueous agent in the form of powder and a preparation method thereof. The present invention is especially suitable for preventing and eliminating various injurious insects in paddy rice fields, such as yellow rice borers, striped rice borers, purplish rice borers, rice plant skippers, rice leaf folders, etc. The high-efficiency insecticidal duple powder is prepared from an insecticidal duple aqueous agent through drying, wherein the effective component is hydrated dimethylamino-1, 3-disodium thiosulfate propane, and the rest components are sodium chloride, sodium thiosulfate, water and a filling material. The preparation method of the insecticidal duple powder comprises: proportionally mixing the insecticidal duple aqueous agent with the filling material; filling the mixture in a spraying nozzle in a dry chamber by a pump; atomizing the mixture, and then heating the mixture by hot air for vaporizing and drying the mixture so as to obtain the high-efficiency insecticidal duple powder.
Description
What bisultap powder of the present invention and preparation method thereof related to is a kind of paddy field insecticide, through improved pulvis and manufacture method thereof, be particularly useful for preventing and kill off various pests such as paddy field paddy stem borer, striped rice borer, pink rice borer, rice plant skipper, leaf-roller by dimehypo water solution.
Existing paddy field insecticide variety is more, but great majority are to belong to aqua and emulsion, and also having only a few is to belong to hypertoxic class agricultural chemicals, medication is careless a little, and people and animals are easy to generate intoxication accident, and we are processed into the former medicine of desinsection list at the eighties research dimehypo water solution, to reduce survival dose, increase insecticidal effect, shortcoming is that dimehypo water solution still has a certain amount of ratio, the packing charges of dimehypo water solution is big, should not transport for long-distance, not storage endurance, degraded easily, consumption is big, and insecticidal effect is poor.
The objective of the invention is provides a kind of bisultap powder and preparation method thereof at above-mentioned weak point, adopt new technology dimehypo water solution is made bisultap powder, improve effective content, thereby reduced the dimehypo water solution packing charges, overcome the big difficulty of freight volume, be the insecticidal activity height, a kind of new type disinsection pulvis that effective, application process is easy, have greater activity.
Bisultap powder and preparation method thereof takes following scheme to realize: contain the effective ingredient dimehypo in the dimehypo water solution, chemical name is the two thiosulfonic acid sodium base propane C of dimethylamino-1,3-
5H
11NO
6S
4Na
2, all the other compositions are sodium chloride nacl, thiosulfonic acid sodium Na
2S
2O
3, water.Bisultap powder adopts the dimehypo water solution drying to make.Active ingredient hydration dimethylamino-1, the two thiosulfonic acid sodium base propane of 3-are 40～60% (percentage by weights) in the bisultap powder, all the other composition sodium chloride contents are 15～25% (percentage by weights), sodium thiosulfate content is 6～10% (percentage by weights), water content is 1～5% (percentage by weight), and filer content is 8～20% (percentage by weights).Filler is one or more the mixture in kaolin, white carbon, potassium chloride, sodium bicarbonate, the sodium chloride.
Bisultap powder preparation method: dimehypo water solution, filler are mixed stirring by being pumped to the nozzle that is located in the Pressuresprayingdrier drying room by the proportioning weighing,,, make bisultap powder through the hot air evaporation drying with the feed liquid atomizing.
Bisultap powder is compared with the dimehypo water solution that tradition is used, and good disinsection effect can be prevented and treated paddy rice important pests such as paddy rice paddy stem borer, striped rice borer, rice plant skipper and rice leaf roller effectively, and is easy to use, and peasant household is easy to grasp and accepts.Test through indoor and outdoor, comprehensive safety, drug effect, factors such as usage amount show, the optimum content of dimehypo is 40～60% in the bisultap powder, through Jiangsu, plant protection such as Jiangxi and agricultural chemicals identify that administrative department carries out the field control effectiveness test comparation and assessment, product insecticidal activity height of the present invention, under every mu of prerequisite with bisultap powder 60～100g, to leaf-roller, the integrated control effect of snout moth's larva is 70.5～100%, be 87～100% wherein to the control efficiency of leaf-roller medication after 2 days, the control efficiency of medication after 5 days is 79.1～96.5%, the control efficiency of medication after 10 days is 71.2～99.24%, control efficiency to snout moth's larva also reaches 70.51～100%, apparently higher than dimehypo water solution.Bisultap powder adopts the dimehypo water solution drying to make, its preparation method simple and reliable process, easy to prepare, cost is low.Because bisultap powder is made in the dimehypo water solution change, improved the dimehypo effective component content, thereby reduced packing charges, overcome the big difficulty of freight volume, and have efficient, low toxicity, long characteristics of lasting period, through outdoor test, the insect of phosphorus wing order there is special efficacy, insecticidal effect reaches about 95%.
The invention will be further described below with reference to embodiment.
Embodiment 1, preparation bisultap powder 100kg
Bisultap powder adopts the dimehypo water solution drying to make.Weighing dimehypo water solution 115kg, effective ingredient dimethylamino-1 wherein, the two thiosulfonic acid sodium base propane content of 3-are 34.8%, all the other composition sodium chloride contents are 21.7%, sodium thiosulfate content is 13%, water content is 30.5%, filler white carbon 15kg will be added in 115 kilograms of the dimehypo water solutions, mix, by the nozzle that is pumped to press atomization granulating and drying machine drying room, feed liquid is atomized, the surface area of drop is increased greatly, and meeting with hot-air to make moisture content evaporate rapidly, and drying becomes grain products in the extremely short time, promptly make bisultap powder 100kg, the spray-dried 30kg moisture content that evaporates, effective ingredient hydration dimethylamino-1 in the made bisultap powder, the two thiosulfonic acid sodium base propane of 3-are 40%, and sodium chloride content is 25%, the thiosulfonic acid sodium content is 15%, water content is 5%, is 15% from content of carbon black, and above percentage is weight percentage.Filler in the present embodiment can also be one or more the mixture in white carbon and potassium chloride, sodium bicarbonate, the sodium chloride.
Embodiment 2, preparation bisultap powder 100kg
Bisultap powder adopts the dimehypo water solution drying to make.Weighing dimehypo water solution 120kg, effective ingredient dimethylamino-1 wherein, the two thiosulfonic acid sodium base propane content of 3-are 50%, all the other composition sodium chloride contents are 13.33%, sodium thiosulfate content is 10.83%, water content is 25.84%, filler kaolin 10kg will be added in the dimehypo water solution 120 kg, mix, by the nozzle that is pumped to press atomization granulating and drying machine drying room, feed liquid is atomized, the surface area of drop is increased greatly, and meeting with hot-air to make moisture content evaporate rapidly, and drying becomes grain products in the extremely short time, promptly make bisultap powder 100kg, the spray-dried 30kg moisture content that evaporates, effective ingredient hydration dimethylamino-1 in the made bisultap powder, the two thiosulfonic acid sodium base propane of 3-are 60%, and sodium chloride content is 16%, sodium thiosulfate content is 13%, water content is 1%, and kaolin content is 10%, and above percentage is weight percentage.Filler in the present embodiment can also be the mixture of kaolin and white carbon.
Embodiment 3, preparation bisultap powder 100kg
Bisultap powder adopts the dimehypo water solution drying to make.Weighing dimehypo water solution 110kg, dimehypo effective ingredient dimethylamino-1 wherein, 3-dual-propane sodium thiosulfate content is 45.45%, all the other composition sodium chloride contents are 18.18%, sodium thiosulfate content is 5%, water content is 31.37%, filler potassium chloride 20kg will be added in 110 kilograms of the dimehypo water solutions, mix, by the nozzle that is pumped to press atomization granulating and drying machine drying room, feed liquid is atomized, the surface area of drop is increased greatly, and meeting with hot-air to make moisture content evaporate rapidly, and drying becomes grain products in the extremely short time, promptly make bisultap powder 100kg, the spray-dried 30kg moisture content that evaporates, effective ingredient hydration dimethylamino-1 in the made bisultap powder, the two thiosulfonic acid sodium base propane of 3-are 50%, and sodium chloride content is 20%, sodium thiosulfate content is 6%, water content is 4%, and the filler KCE content is 20%, and above percentage is weight percentage.Filler in the present embodiment can also be the mixture of potassium chloride, sodium bicarbonate, sodium chloride or wherein a kind of.
Though relatively two kinds of formulation insecticidal mechanisms are identical for bisultap powder of the present invention and dimehypo water solution, but bisultap powder has improved effective content, thereby eliminated the defective of dimehypo water solution, prove from field test results, insect to the paddy field phosphorus wing order has broad-spectrum insecticidal activity, and can obtain good control efficiency, dosage is also long than aqua minimizing and lasting period, control paddy field insect is played positive role, and security performance is good, be used for the control of rice at whole growth periods insect, its excellent characteristic also can show from the administration time broad (to advanced age insect remarkable prevention effect is also arranged), and it is with low cost, using conveniently, is the desirable desinsection formulation of paddy field pest control.
Claims (3)
1, a kind of bisultap powder, it is characterized in that adopting dimehypo water solution, drying is made, effective ingredient hydration dimethylamino-1, the two thiosulfonic acid sodium base propane content of 3-are 40～60% in the bisultap powder, all the other composition sodium chloride contents are 15～25%, and sodium thiosulfate content is 6～10%, and water content is 1～5%, filer content is 8～20%, and above-mentioned component content all is weight percentage.
2, bisultap powder according to claim 1 is characterized in that filler is one or more the mixture in kaolin, white carbon, potassium chloride, sodium bicarbonate, the sodium chloride.
3, a kind of bisultap powder preparation method, it is characterized in that dimehypo water solution, filler are mixed by the proportioning weighing, by the nozzle that is pumped to press atomization granulating and drying machine drying room, feed liquid is atomized, through the hot air drying, make bisultap powder, effective ingredient hydration dimethylamino-1, the two thiosulfonic acid sodium base propane content of 3-are 40～60% in the bisultap powder, all the other composition sodium chloride contents are 15～25%, sodium thiosulfate content is 6～10%, water content is 1～5%, and filer content is 8～20%, and above-mentioned component content all is weight percentage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114511A CN1076582C (en) | 1999-10-27 | 1999-10-27 | High-efficiency bisultap powder and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99114511A CN1076582C (en) | 1999-10-27 | 1999-10-27 | High-efficiency bisultap powder and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1249900A CN1249900A (en) | 2000-04-12 |
| CN1076582C true CN1076582C (en) | 2001-12-26 |
Family
ID=5277585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99114511A Expired - Fee Related CN1076582C (en) | 1999-10-27 | 1999-10-27 | High-efficiency bisultap powder and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1076582C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102992899B (en) * | 2012-11-29 | 2014-11-05 | 叶长东 | Insecticide-fertilizer composition containing bisultap and humic acid |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046837A (en) * | 1989-05-05 | 1990-11-14 | 余姚农药厂 | The manufacture method of dual-utility wei pesticide |
| CN1067353A (en) * | 1992-06-30 | 1992-12-30 | 连佐复 | Method for producing agricultural insecticide big granular " Shachongshuang " |
-
1999
- 1999-10-27 CN CN99114511A patent/CN1076582C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046837A (en) * | 1989-05-05 | 1990-11-14 | 余姚农药厂 | The manufacture method of dual-utility wei pesticide |
| CN1067353A (en) * | 1992-06-30 | 1992-12-30 | 连佐复 | Method for producing agricultural insecticide big granular " Shachongshuang " |
Non-Patent Citations (1)
| Title |
|---|
| 新编农药手册第1版 1989.10.1 农业药检所 农业出版社 * |
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| Publication number | Publication date |
|---|---|
| CN1249900A (en) | 2000-04-12 |
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