CN107334666A - A kind of hair dye containing walnut green husk pigment and preparation method thereof - Google Patents
A kind of hair dye containing walnut green husk pigment and preparation method thereof Download PDFInfo
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- 235000009496 Juglans regia Nutrition 0.000 title claims abstract description 47
- 235000020234 walnut Nutrition 0.000 title claims abstract description 47
- 239000000049 pigment Substances 0.000 title claims abstract description 34
- 239000000118 hair dye Substances 0.000 title claims abstract description 31
- 239000010903 husk Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title description 5
- 240000007049 Juglans regia Species 0.000 title 1
- 241000758789 Juglans Species 0.000 claims abstract description 46
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000284 extract Substances 0.000 claims abstract description 21
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 12
- 241001300674 Plukenetia volubilis Species 0.000 claims abstract 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract 4
- 229940082500 cetostearyl alcohol Drugs 0.000 claims abstract 3
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims abstract 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 45
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 30
- 244000307697 Agrimonia eupatoria Species 0.000 claims description 20
- 235000000125 common agrimony Nutrition 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 17
- 229940081733 cetearyl alcohol Drugs 0.000 claims description 13
- 238000000605 extraction Methods 0.000 claims description 10
- 238000002481 ethanol extraction Methods 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 5
- 238000007689 inspection Methods 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims 12
- 239000008346 aqueous phase Substances 0.000 claims 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000012141 concentrate Substances 0.000 claims 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 229940084106 spermaceti Drugs 0.000 claims 1
- 239000012177 spermaceti Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 210000004761 scalp Anatomy 0.000 abstract description 7
- 230000002045 lasting effect Effects 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 27
- 238000002791 soaking Methods 0.000 description 12
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 9
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 9
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 9
- 235000013399 edible fruits Nutrition 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 6
- ICIDSZQHPUZUHC-UHFFFAOYSA-N 2-octadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCO ICIDSZQHPUZUHC-UHFFFAOYSA-N 0.000 description 4
- 229940100458 steareth-21 Drugs 0.000 description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- 240000004160 Capsicum annuum Species 0.000 description 3
- 235000002567 Capsicum annuum Nutrition 0.000 description 3
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- ILCOCZBHMDEIAI-UHFFFAOYSA-N 2-(2-octadecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCOCCO ILCOCZBHMDEIAI-UHFFFAOYSA-N 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 229940112261 ceteareth-2 Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229940098760 steareth-2 Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
Description
技术领域technical field
本发明属于日化用品技术领域，特别涉及一种含有核桃青皮色素的染发剂及其制备方法。The invention belongs to the technical field of daily chemical products, in particular to a hair dye containing walnut green peel pigment and a preparation method thereof.
背景技术Background technique
核桃青皮，中药材名为青龙衣，为核桃外部的一层厚厚绿色果皮，气微，味微苦。我国年产核桃青皮45万吨左右，每年用于药用的核桃青皮仅有少部分，绝大部分的核桃青皮都作为废弃物而造成浪费。Walnut green peel, the Chinese medicinal material is called Qinglongyi, which is a thick green peel on the outside of the walnut. It has a slight smell and a slightly bitter taste. my country's annual output of walnut green peel is about 450,000 tons, and the walnut green peel used for medicinal purposes is only a small part every year, and most of the walnut green peel is used as waste and caused waste.
随着人民生活水平的提高，将头发通过染发剂改变为各自喜爱的颜色，以达到独特的效果，成为了现代人自我表现和追求个性的点缀。现有的染发剂中，保护天然植物类的和人工合成类的；天然植物类的效果不好，人工合成类效果好，但容易导致染发中毒，危害人体健康安全。With the improvement of people's living standards, it has become an embellishment for modern people to express themselves and pursue individuality by changing their hair into their favorite colors through hair dyes to achieve unique effects. Among the existing hair dyes, natural plant-based and synthetic-based ones are used; natural plant-based ones have poor effects, while artificial-synthetic ones have good effects, but they are likely to cause hair dyeing poisoning and endanger human health and safety.
发明内容Contents of the invention
本发明提出了一种效果好的含有核桃青皮色素的染发剂。The invention provides a hair dye with good effect containing walnut green peel pigment.
本发明的技术方案是这样实现的：Technical scheme of the present invention is realized like this:
一种含有核桃青皮色素的染发剂，包括A相、B相和C相；A hair dye containing walnut green peel pigment, including phase A, phase B and phase C;
所述A相包括水、丙二醇和EDTA二钠；The A phase includes water, propylene glycol and disodium EDTA;
所述B相包括鲸蜡硬脂醇、硬脂醇聚醚-21、硬脂醇聚醚-2、核桃青皮色素、美藤果油和仙鹤草提取物；The B phase includes cetearyl alcohol, steareth-21, steareth-2, walnut green bark pigment, cane oil and Agrimony extract;
所述C相包括过氧化氢和磷酸。The C phase includes hydrogen peroxide and phosphoric acid.
本发明中，采用核桃青皮色素、美藤果油和仙鹤草提取物能滋养头皮，用后头发柔软，易梳，富有光泽，修复损伤头发；再配以其它原料一起共同作用，能使效果持久，不易腿色，头发不会出现分叉枯燥的现象。In the present invention, the use of walnut green bark pigment, cane fruit oil and Agrimony extract can nourish the scalp, make the hair soft, easy to comb, rich in luster, and repair damaged hair; together with other raw materials, it can make the effect lasting , not easy to leg color, the hair will not appear bifurcation and boring phenomenon.
作为优选，按重量百分比，所述染发剂由以下原料制成：1％～5％丙二醇、5％～10％EDTA二钠、10％～15％鲸蜡硬脂醇、1％～5％鲸蜡硬脂醇聚醚-21、1％～5％鲸蜡硬脂醇聚醚-2、1％～3％核桃青皮色素、0.5％～1％美藤果油、0.5％～1％仙鹤草提取物、0.1％～0.5％过氧化氢、0.1％～0.5％磷酸和余量的水，以上重量百分数均以染发剂的总重量为基准并且各原料的重量百分数之和为100％计。As a preference, the hair dye is made from the following raw materials in percentage by weight: 1% to 5% propylene glycol, 5% to 10% disodium EDTA, 10% to 15% cetearyl alcohol, 1% to 5% cetyl Waxsteareth-21, 1%～5% ceteareth-2, 1%～3% walnut green bark pigment, 0.5%～1% cane fruit oil, 0.5%～1% Agrimony extract, 0.1%-0.5% hydrogen peroxide, 0.1%-0.5% phosphoric acid and the rest of water, the above weight percentages are based on the total weight of the hair dye and the sum of the weight percentages of each raw material is 100%.
作为优选，按重量百分比，所述染发剂由以下原料制成：3％丙二醇、7％EDTA二钠、12％鲸蜡硬脂醇、3％鲸蜡硬脂醇聚醚-21、2％鲸蜡硬脂醇聚醚-2、2％核桃青皮色素、0.8％美藤果油、0.6％仙鹤草提取物、0.3％过氧化氢、0.2％磷酸和余量的水，以上重量百分数均以染发剂的总重量为基准并且各原料的重量百分数之和为100％计。As a preference, by weight percentage, the hair dye is made of the following raw materials: 3% propylene glycol, 7% disodium EDTA, 12% cetearyl alcohol, 3% ceteareth-21, 2% whale Waxsteareth-2, 2% walnut green bark pigment, 0.8% cane fruit oil, 0.6% Agrimony extract, 0.3% hydrogen peroxide, 0.2% phosphoric acid and the rest of the water, the above weight percentages are hair dyeing The total weight of the agent is the basis and the sum of the weight percentages of each raw material is 100%.
作为优选，所述核桃青皮色素是将核桃青皮用盐酸水溶液浸泡，去除浸泡液，加入乙醇提取，过滤，浓缩，干燥，即得。Preferably, the walnut green peel pigment is obtained by soaking walnut green peel with aqueous hydrochloric acid solution, removing the soaking solution, adding ethanol for extraction, filtering, concentrating, and drying.
作为优选，所述盐酸水溶液为质量百分比浓度0.5％～1％的盐酸；所述浸泡的时间为1～3小时；所述乙醇为质量百分比浓度的70％～95％的乙醇水溶液；所述乙醇提取采用浸提的方式来进行，乙醇的加入量是所述核桃青皮重量的3～5倍重量，所述乙醇提取的次数为1～5次。Preferably, the hydrochloric acid aqueous solution is hydrochloric acid with a mass percentage concentration of 0.5% to 1%; the soaking time is 1 to 3 hours; the ethanol is an ethanol aqueous solution with a mass percentage concentration of 70% to 95%; the ethanol The extraction is carried out by leaching, the amount of ethanol added is 3 to 5 times the weight of the walnut green husk, and the number of ethanol extractions is 1 to 5 times.
作为优选，所述仙鹤草提取物是将仙鹤草用乙醇提取，过滤，浓缩，干燥，即得。Preferably, the Agrimony extract is obtained by extracting Agrimony with ethanol, filtering, concentrating, and drying.
一种制备所述染发剂的方法，包括以下步骤：A method for preparing the hair dye, comprising the steps of:
(1)按配比，称取各原料备用；(1) according to proportioning, take each raw material for subsequent use;
(2)在水相缸中加入A相，加热至75℃～80℃，搅拌至完全溶解，作为水相；(2) Add phase A into the water phase tank, heat to 75°C-80°C, stir until completely dissolved, and use it as the water phase;
(3)在油相缸中加入B相，加热至75℃～80℃，搅拌至完全溶解，作为油相；(3) Add phase B into the oil phase tank, heat to 75°C-80°C, stir until completely dissolved, and use it as the oil phase;
(4)将所述水相和油相分别置于反应缸中，均质；(4) The water phase and the oil phase are respectively placed in the reaction tank, homogeneous;
(5)搅拌、冷却降温至40℃～45℃，加入C相，搅拌均匀；(5) Stir and cool down to 40°C to 45°C, add phase C, and stir evenly;
(6)质检，灌装，包装。(6) Quality inspection, filling and packaging.
与现有技术相比，本发明的有益效果是：Compared with prior art, the beneficial effect of the present invention is:
本发明通过核桃青皮色素等制成的染发剂性能温和，不刺激头皮且能滋养头皮，用后头发柔软，易梳，富有光泽，且效果持久，不易腿色，不会出现分叉枯燥的现象，还能使头发得到一定程度的修复。The hair dye made from the walnut green peel pigment of the present invention has mild performance, does not irritate the scalp and can nourish the scalp. After use, the hair is soft, easy to comb, full of luster, and the effect is long-lasting, not easy to color legs, and will not appear bifurcation and dull phenomenon , but also repair the hair to a certain extent.
具体实施方式detailed description
下面对本发明中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明的其中的几个实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。The technical solutions in the present invention are clearly and completely described below, obviously, the described embodiments are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
实施例1Example 1
一种含有核桃青皮色素的染发剂，包括A相、B相和C相；A相包括水、丙二醇和EDTA二钠；B相包括鲸蜡硬脂醇、硬脂醇聚醚-21、硬脂醇聚醚-2、核桃青皮色素、美藤果油和仙鹤草提取物；C相包括过氧化氢和磷酸。A hair dye containing walnut green peel pigment, comprising phase A, phase B and phase C; phase A comprising water, propylene glycol and disodium EDTA; phase B comprising cetearyl alcohol, steareth-21, stearin Glyth-2, walnut green bark pigment, cayenne fruit oil and agrimony extract; Phase C includes hydrogen peroxide and phosphoric acid.
其制备方法如下：Its preparation method is as follows:
(1)按重量百分比，称取以下原料备用：3％丙二醇、7％EDTA二钠、12％鲸蜡硬脂醇、3％鲸蜡硬脂醇聚醚-21、2％鲸蜡硬脂醇聚醚-2、2％核桃青皮色素、0.8％美藤果油、0.6％仙鹤草提取物、0.3％过氧化氢、0.2％磷酸和余量的水，以上重量百分数均以染发剂的总重量为基准并且各原料的重量百分数之和为100％计。(1) By weight percentage, take the following raw materials for subsequent use: 3% propylene glycol, 7% disodium EDTA, 12% cetearyl alcohol, 3% ceteareth-21, 2% cetearyl alcohol Polyether-2, 2% walnut green bark pigment, 0.8% cane fruit oil, 0.6% Agrimony extract, 0.3% hydrogen peroxide, 0.2% phosphoric acid and the rest of the water, the above weight percentages are based on the total weight of the hair dye as a benchmark and the sum of the weight percentages of each raw material is 100%.
其中，核桃青皮色素是将核桃青皮用盐酸水溶液浸泡，去除浸泡液，加入乙醇提取，过滤，浓缩，干燥，即得。盐酸水溶液为质量百分比浓度0.7％的盐酸；浸泡的时间为2小时；乙醇为质量百分比浓度的90％的乙醇水溶液；乙醇提取采用浸提的方式来进行，乙醇的加入量是所述核桃青皮重量的4倍重量，乙醇提取的次数为3次。Wherein, walnut green peel pigment is obtained by soaking walnut green peel with hydrochloric acid aqueous solution, removing the soaking liquid, adding ethanol for extraction, filtering, concentrating and drying. The aqueous hydrochloric acid solution is hydrochloric acid with a concentration of 0.7% by mass percentage; the soaking time is 2 hours; the ethanol is an aqueous ethanol solution with a concentration of 90% by mass percentage; 4 times the weight, and the number of times of ethanol extraction is 3 times.
仙鹤草提取物是将仙鹤草用质量百分比浓度的90％的乙醇回流提取3次，每次提取的时间为2小时，合并提取液，过滤，浓缩，干燥，即得。The Agrimony extract is obtained by refluxing the Agrimony with 90% ethanol in mass percent concentration for 3 times, each extraction time is 2 hours, combining the extracts, filtering, concentrating, and drying.
(2)在水相缸中加入A相，加热至78℃，搅拌至完全溶解，作为水相；(2) Add phase A into the water phase tank, heat to 78°C, stir until completely dissolved, and use it as the water phase;
(3)在油相缸中加入B相，加热至78℃，搅拌至完全溶解，作为油相；(3) Add phase B into the oil phase tank, heat to 78°C, stir until completely dissolved, and use it as the oil phase;
(4)将所述水相和油相分别置于反应缸中，均质；(4) The water phase and the oil phase are respectively placed in the reaction tank, homogeneous;
(5)搅拌、冷却降温至42℃，加入C相，搅拌均匀；(5) Stir, cool down to 42°C, add phase C, and stir evenly;
(6)质检，灌装，包装。(6) Quality inspection, filling and packaging.
实施例2Example 2
一种含有核桃青皮色素的染发剂，包括A相、B相和C相；A相包括水、丙二醇和EDTA二钠；B相包括鲸蜡硬脂醇、硬脂醇聚醚-21、硬脂醇聚醚-2、核桃青皮色素、美藤果油和仙鹤草提取物；C相包括过氧化氢和磷酸。A hair dye containing walnut green peel pigment, comprising phase A, phase B and phase C; phase A comprising water, propylene glycol and disodium EDTA; phase B comprising cetearyl alcohol, steareth-21, stearin Glyth-2, walnut green bark pigment, cayenne fruit oil and agrimony extract; Phase C includes hydrogen peroxide and phosphoric acid.
其制备方法如下：Its preparation method is as follows:
(1)按重量百分比，称取以下原料备用：5％丙二醇、10％EDTA二钠、15％鲸蜡硬脂醇、5％鲸蜡硬脂醇聚醚-21、5％鲸蜡硬脂醇聚醚-2、3％核桃青皮色素、1％美藤果油、1％仙鹤草提取物、0.5％过氧化氢、0.5％磷酸和余量的水，以上重量百分数均以染发剂的总重量为基准并且各原料的重量百分数之和为100％计。(1) By weight percentage, take the following raw materials for subsequent use: 5% propylene glycol, 10% disodium EDTA, 15% cetearyl alcohol, 5% ceteareth-21, 5% cetearyl alcohol Polyether-2, 3% walnut green bark pigment, 1% cane fruit oil, 1% Agrimony extract, 0.5% hydrogen peroxide, 0.5% phosphoric acid and the rest of the water, the above weight percentages are based on the total weight of the hair dye as a benchmark and the sum of the weight percentages of each raw material is 100%.
其中，核桃青皮色素是将核桃青皮用盐酸水溶液浸泡，去除浸泡液，加入乙醇提取，过滤，浓缩，干燥，即得。盐酸水溶液为质量百分比浓度1％的盐酸；浸泡的时间为3小时；乙醇为质量百分比浓度的95％的乙醇水溶液；乙醇提取采用浸提的方式来进行，乙醇的加入量是所述核桃青皮重量的5倍重量，乙醇提取的次数为5次。Wherein, walnut green peel pigment is obtained by soaking walnut green peel with hydrochloric acid aqueous solution, removing the soaking liquid, adding ethanol for extraction, filtering, concentrating and drying. The aqueous hydrochloric acid solution is hydrochloric acid with a concentration of 1% by mass percentage; the soaking time is 3 hours; the ethanol is an aqueous ethanol solution with a concentration of 95% by mass percentage; 5 times the weight, the number of times of ethanol extraction is 5 times.
仙鹤草提取物是将仙鹤草用质量百分比浓度的95％的乙醇回流提取3次，每次提取的时间为2小时，合并提取液，过滤，浓缩，干燥，即得。The Agrimony extract is obtained by refluxing the Agrimony with 95% ethanol in mass percentage concentration for 3 times, each extraction time is 2 hours, combining the extracts, filtering, concentrating, and drying.
(2)在水相缸中加入A相，加热至80℃，搅拌至完全溶解，作为水相；(2) Add phase A into the water phase tank, heat to 80°C, stir until completely dissolved, and use it as the water phase;
(3)在油相缸中加入B相，加热至80℃，搅拌至完全溶解，作为油相；(3) Add phase B into the oil phase tank, heat to 80°C, stir until completely dissolved, and use it as the oil phase;
(4)将所述水相和油相分别置于反应缸中，均质；(4) The water phase and the oil phase are respectively placed in the reaction tank, homogeneous;
(5)搅拌、冷却降温至45℃，加入C相，搅拌均匀；(5) Stir, cool down to 45°C, add phase C, and stir evenly;
(6)质检，灌装，包装。(6) Quality inspection, filling and packaging.
实施例3Example 3
一种含有核桃青皮色素的染发剂，包括A相、B相和C相；A相包括水、丙二醇和EDTA二钠；B相包括鲸蜡硬脂醇、硬脂醇聚醚-21、硬脂醇聚醚-2、核桃青皮色素、美藤果油和仙鹤草提取物；C相包括过氧化氢和磷酸。A hair dye containing walnut green peel pigment, comprising phase A, phase B and phase C; phase A comprising water, propylene glycol and disodium EDTA; phase B comprising cetearyl alcohol, steareth-21, stearin Glyth-2, walnut green bark pigment, cayenne fruit oil and agrimony extract; Phase C includes hydrogen peroxide and phosphoric acid.
其制备方法如下：Its preparation method is as follows:
(1)按重量百分比，称取以下原料备用：1％丙二醇、5％EDTA二钠、10％鲸蜡硬脂醇、1％鲸蜡硬脂醇聚醚-21、1％鲸蜡硬脂醇聚醚-2、1％核桃青皮色素、0.5％美藤果油、0.5％仙鹤草提取物、0.1％过氧化氢、0.1％磷酸和余量的水，以上重量百分数均以染发剂的总重量为基准并且各原料的重量百分数之和为100％计。(1) By weight percentage, take the following raw materials for subsequent use: 1% propylene glycol, 5% disodium EDTA, 10% cetearyl alcohol, 1% ceteareth-21, 1% cetearyl alcohol Polyether-2, 1% walnut green bark pigment, 0.5% cane fruit oil, 0.5% Agrimony extract, 0.1% hydrogen peroxide, 0.1% phosphoric acid and the rest of the water, the above weight percentages are based on the total weight of the hair dye as a benchmark and the sum of the weight percentages of each raw material is 100%.
其中，核桃青皮色素是将核桃青皮用盐酸水溶液浸泡，去除浸泡液，加入乙醇提取，过滤，浓缩，干燥，即得。盐酸水溶液为质量百分比浓度0.5％的盐酸；浸泡的时间为1小时；乙醇为质量百分比浓度的70％的乙醇水溶液；乙醇提取采用浸提的方式来进行，乙醇的加入量是所述核桃青皮重量的3倍重量，乙醇提取的次数为1次。Wherein, walnut green peel pigment is obtained by soaking walnut green peel with hydrochloric acid aqueous solution, removing the soaking liquid, adding ethanol for extraction, filtering, concentrating and drying. The aqueous hydrochloric acid solution is hydrochloric acid with a mass percentage concentration of 0.5%; the soaking time is 1 hour; the ethanol is a 70% ethanol aqueous solution with a mass percentage concentration; the ethanol extraction is carried out by leaching, and the addition of ethanol is the weight of the green walnut 3 times the weight, the number of times of ethanol extraction is 1 time.
仙鹤草提取物是将仙鹤草用质量百分比浓度的70％的乙醇回流提取3次，每次提取的时间为2小时，合并提取液，过滤，浓缩，干燥，即得。The Agrimony extract is obtained by refluxing the Agrimony with 70% ethanol in mass percentage concentration for 3 times, each extraction time is 2 hours, combining the extracts, filtering, concentrating, and drying.
(2)在水相缸中加入A相，加热至75℃，搅拌至完全溶解，作为水相；(2) Add phase A into the water phase tank, heat to 75°C, stir until completely dissolved, and use it as the water phase;
(3)在油相缸中加入B相，加热至75℃，搅拌至完全溶解，作为油相；(3) Add phase B into the oil phase tank, heat to 75°C, stir until completely dissolved, and use it as the oil phase;
(4)将所述水相和油相分别置于反应缸中，均质；(4) The water phase and the oil phase are respectively placed in the reaction tank, homogeneous;
(5)搅拌、冷却降温至40℃，加入C相，搅拌均匀；(5) Stir, cool down to 40°C, add phase C, and stir evenly;
(6)质检，灌装，包装。(6) Quality inspection, filling and packaging.
上述实施例所得产品，随机抽取100人进行试用，发现所得染发剂性能温和，不刺激头皮且能滋养头皮，用后头发柔软，易梳，富有光泽，且效果持久，不易腿色，不会出现分叉枯燥的现象，还能使头发得到一定程度的修复。100 people were randomly selected for trial use of the products obtained in the above examples. It was found that the obtained hair dye has mild properties, does not irritate the scalp and can nourish the scalp. The phenomenon of bifurcation and dryness can also repair the hair to a certain extent.
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the scope of the present invention. within the scope of protection.
Claims (7)
- A kind of 1. hair dye containing walnut green husk pigment, it is characterised in that：Including A phases, B phases and C phases；The A phases include water, propane diols and EDETATE SODIUM；The B phases include cetostearyl alcohol, stereth -21, stereth -2, walnut green husk pigment, oil and fat of sacha inchi and Herba Agrimoniae extract；The C phases include hydrogen peroxide and phosphoric acid.
- A kind of 2. hair dye containing walnut green husk pigment according to claim 1, it is characterised in that：Percentage by weight Than the hair dye is made up of following raw material：1%~5% propane diols, 5%~10%EDTA disodiums, 10%~15% spermaceti are hard Lipidol, 1%~5% ceteareth -21,1%~5% ceteareth -2,1%~3% walnut green husk pigment, 0.5%~1% oil and fat of sacha inchi, 0.5%~1% Herba Agrimoniae extract, 0.1%~0.5% hydrogen peroxide, 0.1%~0.5% phosphorus Acid and surplus water, above percetage by weight on the basis of the gross weight of hair dye and each raw material percetage by weight sum For 100% meter.
- A kind of 3. hair dye containing walnut green husk pigment according to claim 2, it is characterised in that：Percentage by weight Than the hair dye is made up of following raw material：3% propane diols, 7%EDTA disodiums, 12% cetostearyl alcohol, 3% cetearyl alcohol Alcohol polyethers -21,2% ceteareth -2,2% walnut green husk pigment, 0.8% oil and fat of sacha inchi, the extraction of 0.6% hairyvein agrimony Thing, 0.3% hydrogen peroxide, the water of 0.2% phosphoric acid and surplus, above percetage by weight on the basis of the gross weight of hair dye simultaneously And the percetage by weight sum of each raw material is 100% meter.
- A kind of 4. hair dye containing walnut green husk pigment according to claim any one of 1-3, it is characterised in that：It is described Walnut green husk pigment is to soak green peel of walnut with aqueous hydrochloric acid solution, removes soak, adds ethanol extraction, filters, concentrate, does It is dry, produce.
- A kind of 5. hair dye containing walnut green husk pigment according to claim 4, it is characterised in that：The hydrochloric acid is water-soluble Liquid is the hydrochloric acid of mass percent concentration 0.5%~1%；The time of the immersion is 1~3 hour；The ethanol is quality hundred Divide 70%~95% ethanol water of specific concentration；The ethanol extraction is carried out by the way of extraction, the addition of ethanol Amount is 3~5 times of weight of the green peel of walnut weight, and the number of the ethanol extraction is 1~5 time.
- A kind of 6. hair dye containing walnut green husk pigment according to claim any one of 1-3, it is characterised in that：It is described Herba Agrimoniae extract is to extract hairyvein agrimony with ethanol, is filtered, and is concentrated, and dries, produces.
- A kind of 7. method for preparing any one of the claim 1-6 hair dyes, it is characterised in that：Comprise the following steps：(1) by proportioning, each raw material for standby is weighed；(2) A phases are added in aqueous phase cylinder, are heated to 75 DEG C~80 DEG C, are stirred to being completely dissolved, as aqueous phase；(3) B phases are added in oil phase cylinder, are heated to 75 DEG C~80 DEG C, are stirred to being completely dissolved, as oil phase；(4) aqueous phase and oil phase are respectively placed in reaction cylinder, homogeneous；(5) stir, cool to 40 DEG C~45 DEG C, add C phases, stir；(6) quality inspection, filling, packaging.
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