CN107296051A - A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and tiadinil - Google Patents
A kind of bactericidal composition and its application of the pyrrole bacterium ketone of benzene containing amine and tiadinil Download PDFInfo
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- CN107296051A CN107296051A CN201710540727.2A CN201710540727A CN107296051A CN 107296051 A CN107296051 A CN 107296051A CN 201710540727 A CN201710540727 A CN 201710540727A CN 107296051 A CN107296051 A CN 107296051A
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- China
- Prior art keywords
- tiadinil
- pyrrole bacterium
- bacterium ketone
- bactericidal composition
- benzene pyrrole
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- 241000894006 Bacteria Species 0.000 title claims abstract description 84
- 150000001412 amines Chemical class 0.000 title claims abstract description 84
- 150000002576 ketones Chemical class 0.000 title claims abstract description 77
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 15
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title claims abstract description 9
- REEJOFMTJPOBAY-UHFFFAOYSA-N benzene;1h-pyrrole Chemical compound C=1C=CNC=1.C1=CC=CC=C1 REEJOFMTJPOBAY-UHFFFAOYSA-N 0.000 claims abstract description 75
- 230000000694 effects Effects 0.000 claims abstract description 16
- 208000031888 Mycoses Diseases 0.000 claims abstract description 11
- 239000003814 drug Substances 0.000 claims abstract description 9
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 7
- 241001530056 Athelia rolfsii Species 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 8
- 239000004563 wettable powder Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000009472 formulation Methods 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 239000003905 agrochemical Substances 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 10
- 201000010099 disease Diseases 0.000 abstract description 9
- 230000002265 prevention Effects 0.000 abstract description 9
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 235000013339 cereals Nutrition 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 235000013311 vegetables Nutrition 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- 230000003111 delayed effect Effects 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 29
- 238000000034 method Methods 0.000 description 18
- 239000003921 oil Substances 0.000 description 13
- 239000004615 ingredient Substances 0.000 description 12
- 239000002994 raw material Substances 0.000 description 11
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 10
- -1 diffusant Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000004530 micro-emulsion Substances 0.000 description 9
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 231100000419 toxicity Toxicity 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 210000000481 breast Anatomy 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 241001272567 Hominoidea Species 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000546 pharmaceutical excipient Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229930192474 thiophene Natural products 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 241000813090 Rhizoctonia solani Species 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005779 Fenpyrazamine Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000008686 ergosterol biosynthesis Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- UTOHZQYBSYOOGC-UHFFFAOYSA-N fenpyrazamine Chemical compound O=C1N(C(C)C)N(C(=O)SCC=C)C(N)=C1C1=CC=CC=C1C UTOHZQYBSYOOGC-UHFFFAOYSA-N 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses bactericidal composition and its application of a kind of pyrrole bacterium ketone of benzene containing amine and tiadinil.The bactericidal composition is using amine benzene pyrrole bacterium ketone and tiadinil as principle active component, and wherein the mass ratio of amine benzene pyrrole bacterium ketone and tiadinil is 1~70：1~50.The bactericidal composition can be applied to preventing and treating Cereal, fruit tree, vegetable disease, it is particularly useful for preventing and treating the fungal diseases such as anthracnose, downy mildew, gray mold, banded sclerotial blight, false smut, with higher synergistic function, overcome and delayed the resistance to the action of a drug of germ, sterilization speed is fast, lasting period length, reduce application cost, and prevention effect is substantially better than its single dose and used.
Description
Technical field：
The present invention relates to a kind of bactericidal composition and application thereof, especially one kind is based on amine benzene pyrrole bacterium ketone and tiadinil
Want bactericidal composition and its application of active component.
Background technology
Amine benzene pyrrole bacterium ketone (fenpyrazamine) is the heterocyclic fungicide based on pyridine, molecular formula：C17H21N3O2S,
Chemical name：1- [(2- acrylic sulfenyl) formoxyl] -2- isopropyls -4- (2- aminomethyl phenyls) -5- amino -1H- pyrazoles -3-
Ketone.
By the pathogen for the mechanism of action for suppressing ergosterol biosynthesis pathway, show to mycelial growth and spore
Sprout the inhibitory action with pollen tube growth.Gray mold mainly is prevented and treated, for cucumber, grape, citrus, potato, capsicum, eggplant
Son, ornamental plant etc..
Tiadinil (Tiadinil), molecular formula：C11H10ClN3OS, chemical name：Chloro- 4,4'- dimethyl -1,2 of 3'-,
3- thiadiazoles -5- formailides.Structural formula：
Tiadinil is a kind of novel systemic fungicide, is transmitted to other positions rapidly by root absorption.This medicine
Inhibitory activity of the agent to germ in itself is poor, by preventing the neighbouring healthy cell of germ mycelia intrusion, and generation can be induced disease-resistant
Gene.Lasting period is long, has preferable prevention effect to leaf blast disease and fringe rice blast, to powdery mildew, rust, late blight or epidemic disease
Disease, downy mildew also have certain prevention effect.
The difficulty of prevention and cure of current phytopathogen is increasing, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity are increased, and difficulty is increased in preventing and treating；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention be provide that a kind of applied widely, cost is low for above-mentioned technical problem, effect is good contains amine
The plant bactericidal composition of benzene pyrrole bacterium ketone and tiadinil.
Cause answering on fungal disease in preventing and treating plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With the especially purposes on the fungal diseases such as anthracnose, downy mildew, gray mold, banded sclerotial blight, false smut are prevented and treated.
The purpose of the present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition of the pyrrole bacterium ketone of benzene containing amine and tiadinil, the bactericidal composition is with amine benzene pyrrole bacterium ketone and thiophene acyl
Bacterium amine is principle active component, and wherein the mass ratio of amine benzene pyrrole bacterium ketone and tiadinil is 1~70：1~50, wherein Bactericidal composite
Effective ingredient is present in composition with enhancing effective amount in thing.
Described bactericidal composition, the mass ratio of wherein amine benzene pyrrole bacterium ketone and tiadinil is preferably 1~50：1~50, enter
One step is preferably 1~10：1~6.
In other more preferably technical scheme：The mass ratio of amine benzene pyrrole bacterium ketone and tiadinil is 80：1、70：1、50：
1、30：1、20：1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1:60 or 1:70.
In the compositions of the present invention, accounted for both amine benzene pyrrole bacterium ketone and tiadinil the weight/mass percentage composition of composition for 2~
80%.It is preferred that 10~40%.
Described bactericidal composition, wherein using amine benzene pyrrole bacterium ketone and tiadinil as principle active component and known auxiliary agent
Any one formulation allowed on agricultural chemicals is re-dubbed with excipient.These known auxiliary agents, excipients have dispersant, diffusant,
Defoamer, wetting agent, disintegrant etc., can use calcium dodecyl benzene sulfonate, APES, benzylphenol polyoxy second
Alkene ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid
Ethylene oxide adduct, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE,
TWEEN Series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphorous acid
One or more of salt, lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. are combined, excipient
Including cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and
Other auxiliary materials can be with alone or be used in combination.
Described bactericidal composition, its formulation is missible oil, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
Application of the above-mentioned bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Application has remarkable result in terms of class, fruit tree, vegetable crop disease.
Above-mentioned application, described fungal diseases of plants is in anthracnose, downy mildew, gray mold, banded sclerotial blight, false smut
It is at least one.
The characteristics of bactericidal composition of the present invention：
1st, the amine benzene pyrrole bacterium ketone and tiadinil used in the present invention, the mechanism of action is different, mutual mixture will not produce it is low touch,
Can Synergistic, reduce dosage, reduce cost.
2nd, present composition scope of application increase, it is adaptable to prevent and treat Cereal, fruit tree, the refractory fungal disease of vegetables,
Particularly preventing and treating anthracnose, downy mildew, gray mold, banded sclerotial blight, false smut etc. has significant effect.Bactericidal composition of the present invention
There is good prevention effect to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease；And suppress insect or fungi to list
The drug-fast generation of one preparation (amine benzene pyrrole bacterium ketone and tiadinil are any).Bactericidal composition of the present invention can produce higher association
Same synergistic effect, and the consumption of the amount ratio independent reactive compound of the mixture substantially reduces, i.e. and the activity of mixture is big
In the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as anthracnose, downy mildew, gray mold, banded sclerotial blight, false smut have obvious synergistic function, overcome and have delayed anti-
The property of medicine, expands preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating recruitment, drug cost are reduced；(3) alternative routine and easily
Produce the agricultural chemicals of resistance；(4) compared with single dose, production and use cost reduction；(5) the drug-fast generation of fungi is suppressed, it is imitated
Fruit uses apparently higher than its single dose.
Embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method is used indoors, determines EC of the different agents to bacterial strain50Value, using co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, circular is as follows：
A certain single dose (generally selects EC as standard agent using in mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, and CTC exists when being less than 80 for antagonism, CTC
It is summation action between 80-120.
According to active ingredient amine benzene pyrrole bacterium ketone (A)：Tiadinil (B) quality proportioning is：80:1、70：1、50：1、30：1、
20：1、10：1、5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50、1:60、1:70 are tested, and are surveyed
Determine its co-toxicity coefficient to Rhizoctonia solani Kuhn (Thanatephorus cucumeris (Frank) Donk.).
Table 1：Indoor biometricses result of the amine benzene pyrrole bacterium ketone+tiadinil different ratio to rice sheath blight disease
Field control effectiveness test：
Rice sheath blight disease experiment is prevented and treated with pesticidal preparations made from above-described embodiment.
1st, test process：This test medicine consumption sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the amine benzene pyrrole bacterium ketone SC of agricultural chemicals single dose 30% and 6% tiadinil GR and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：(every takes 5M for 5 points of grab sample in test process area2), carry out the state of an illness point according to national field test relevant criterion
Level, calculates preventive effect.Result of the test is shown in Table 2：
The field test effect of table 2
Shown by indoor biometricses and field efficacy result, amine benzene pyrrole bacterium ketone has obvious association with tiadinil composition
Same synergistic effect, the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has in agricultural application and applies valency
Value.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% amine benzene pyrrole bacterium ketone tiadinil wettable powder (1:2)
By amine benzene pyrrole bacterium ketone 5g, tiadinil 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, expansion
Powder NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures and carry out air-flow crushing, and being made has
Effect Ingredient percent is 15% amine benzene pyrrole bacterium ketone tiadinil wettable powder.
Embodiment 2：15% amine benzene pyrrole bacterium ketone tiadinil wettable powder (1:4)
It is high by amine benzene pyrrole bacterium ketone 3g, tiadinil 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 15% amine benzene pyrrole bacterium ketone thiophene acyl bacterium that active ingredient mass percent, which is made,
Amine wettable powder.
Embodiment 3：14% amine benzene pyrrole bacterium ketone tiadinil wettable powder (1:6)
It is high by amine benzene pyrrole bacterium ketone 2g, tiadinil 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g
Ridge soil adds to 100g mixtures and carries out air-flow crushing, and it is 14% amine benzene pyrrole bacterium ketone thiophene acyl bacterium that active ingredient mass percent, which is made,
Amine wettable powder.
Embodiment 4：20% amine benzene pyrrole bacterium ketone tiadinil suspending agent (1:1)
Weigh 10g amine benzene pyrrole bacterium ketone, 10g tiadinils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate
4g, xanthans 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, 100g is complemented to water, in the work of sand mill
Effective Ingredient percent is made under for 20% amine benzene pyrrole bacterium ketone tiadinil suspending agent.
Embodiment 5：55% amine benzene pyrrole bacterium ketone tiadinil aqueous emulsion (1:10)
Weigh 5g amine benzene pyrrole bacterium ketone, 50g tiadinils, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared into aqueous emulsion is thrown
Enter the mixing of mixing kettle high speed, effective Ingredient percent is made for 55% amine benzene pyrrole bacterium ketone tiadinil aqueous emulsion.
Embodiment 6：42% amine benzene pyrrole bacterium ketone tiadinil missible oil (1:20)
Weigh 2g amine benzene pyrrole bacterium ketone, 40g tiadinils, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, active ingredient is made
Mass percent is 42% amine benzene pyrrole bacterium ketone tiadinil missible oil.
Embodiment 7：70% amine benzene pyrrole bacterium ketone tiadinil missible oil (2.5:1)
Weigh 50g amine benzene pyrrole bacterium ketone, 20g tiadinils, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether
2g, castor oil polyoxyethylene ether 2g, 150# solvent naphtha to 100g.The method that above raw material is routinely prepared into missible oil puts into mixing
Mixed in kettle, effective Ingredient percent is made for 70% amine benzene pyrrole bacterium ketone tiadinil missible oil.
Embodiment 8：18% amine benzene pyrrole bacterium ketone tiadinil water dispersion granule (5：1)
Weigh 15g amine benzene pyrrole bacterium ketone, 3g tiadinils, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and above raw material is formed with imitating into sub-prime by water dispersible granular agent method
Amount percentage is 18% amine benzene pyrrole bacterium ketone tiadinil water dispersion granule.
Embodiment 9：11% amine benzene pyrrole bacterium ketone tiadinil missible oil (10:1)
Weigh 10g amine benzene pyrrole bacterium ketone, 1g tiadinils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, active ingredient is made
Mass percent is 11% amine benzene pyrrole bacterium ketone tiadinil missible oil.
Embodiment 10：31.5% amine benzene pyrrole bacterium ketone tiadinil microemulsion (20:1)
Weigh 30g amine benzene pyrrole bacterium ketone, 1.5g tiadinils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether
Phosphate 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely matched somebody with somebody
Mixed in the method input mixing kettle of microemulsion processed, effective Ingredient percent is made for 31.5% amine benzene pyrrole bacterium ketone thiophene acyl
Bacterium amine microemulsion.
Embodiment 11：31% amine benzene pyrrole bacterium ketone tiadinil missible oil (30:1)
Weigh 30g amine benzene pyrrole bacterium ketone, 1g tiadinils, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
150# solvent naphthas are to 100g.Mixed in the method input mixing kettle that above raw material is routinely prepared to missible oil, active ingredient is made
Mass percent is 31% amine benzene pyrrole bacterium ketone tiadinil missible oil.
Embodiment 12：51% amine benzene pyrrole bacterium ketone tiadinil suspending agent (50:1)
50g amine benzene pyrrole bacterium ketone, 1g tiadinils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% amine benzene pyrrole bacterium ketone tiadinil suspending agent.
Embodiment 13：32% amine benzene pyrrole bacterium ketone tiadinil microemulsion (1:15)
Weigh 2g amine benzene pyrrole bacterium ketone, 30g tiadinils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mixed in the method input mixing kettle of microemulsion, effective Ingredient percent is made for 32% amine benzene pyrrole bacterium ketone tiadinil
Microemulsion.
Embodiment 14：6% amine benzene pyrrole bacterium ketone tiadinil aqueous emulsion (1:5)
Weigh 1g amine benzene pyrrole bacterium ketone, 5g tiadinils, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl
Phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.Above raw material is routinely prepared to the method input of aqueous emulsion
Mixing kettle high speed is mixed, and effective Ingredient percent is made for 6% amine benzene pyrrole bacterium ketone tiadinil aqueous emulsion.
Embodiment 15：62% amine benzene pyrrole bacterium ketone tiadinil microemulsion (1:30)
Weigh 2g amine benzene pyrrole bacterium ketone, 60g tiadinils, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g add water to 100g.Above raw material is routinely prepared
Mixed in the method input mixing kettle of microemulsion, effective Ingredient percent is made for 62% amine benzene pyrrole bacterium ketone tiadinil
Microemulsion.
Embodiment 16：51% amine benzene pyrrole bacterium ketone tiadinil suspending agent (1:50)
1g amine benzene pyrrole bacterium ketone, 50g tiadinils, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed,
Xanthans 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
Effective Ingredient percent is made for 51% amine benzene pyrrole bacterium ketone tiadinil suspending agent.
Embodiment 17：7% amine benzene pyrrole bacterium ketone tiadinil water dispersion granule (1：2.5)
2g amine benzene pyrrole bacterium ketone, 5g tiadinils are weighed, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g gather
Vinyl alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, and above raw material is formed with by water dispersible granular agent method
Effect Ingredient percent is 7% amine benzene pyrrole bacterium ketone tiadinil water dispersion granule.
Claims (9)
1. the bactericidal composition of a kind of pyrrole bacterium ketone of benzene containing amine and tiadinil, it is characterised in that the bactericidal composition is with amine benzene pyrrole bacterium
Ketone and tiadinil are principle active component, and wherein the mass ratio of amine benzene pyrrole bacterium ketone and tiadinil is 1~70：1~50.
2. bactericidal composition according to claim 1, it is characterised in that the quality of the amine benzene pyrrole bacterium ketone and tiadinil
Than for 1~50：1~50.
3. bactericidal composition according to claim 2, it is characterised in that the quality of the amine benzene pyrrole bacterium ketone and tiadinil
Than for 1~10：1~6.
4. bactericidal composition according to claim 1, it is characterised in that both described amine benzene pyrrole bacterium ketone and tiadinil
The weight/mass percentage composition for accounting for composition is 2-80%.
5. bactericidal composition according to claim 4, it is characterised in that both described amine benzene pyrrole bacterium ketone and tiadinil
The weight/mass percentage composition for accounting for composition is 10-40%.
6. bactericidal composition according to claim 1, it is characterised in that using amine benzene pyrrole bacterium ketone and tiadinil mainly to have
Effect composition and insecticides adjuvant are configured to any one formulation allowed on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Wettable powder or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is anthracnose, downy mildew, ash
At least one of mildew, banded sclerotial blight, false smut.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101473829A (en) * | 2008-12-18 | 2009-07-08 | 孙家隆 | Bactericide agent composition containing tiadinil and flutolanil |
| CN102105060A (en) * | 2008-06-05 | 2011-06-22 | 巴斯夫欧洲公司 | Synergistic fungicidal mixtures |
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2017
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102105060A (en) * | 2008-06-05 | 2011-06-22 | 巴斯夫欧洲公司 | Synergistic fungicidal mixtures |
| CN101473829A (en) * | 2008-12-18 | 2009-07-08 | 孙家隆 | Bactericide agent composition containing tiadinil and flutolanil |
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