CN107253799A - A kind of experimental rig and its test method for handling the heavy metal-polluted waters such as lead, nickel, arsenic - Google Patents
A kind of experimental rig and its test method for handling the heavy metal-polluted waters such as lead, nickel, arsenic Download PDFInfo
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- CN107253799A CN107253799A CN201710389878.2A CN201710389878A CN107253799A CN 107253799 A CN107253799 A CN 107253799A CN 201710389878 A CN201710389878 A CN 201710389878A CN 107253799 A CN107253799 A CN 107253799A
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910052785 arsenic Inorganic materials 0.000 title claims abstract description 21
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 21
- 238000010998 test method Methods 0.000 title abstract description 6
- 239000003643 water by type Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 238000001179 sorption measurement Methods 0.000 claims abstract description 41
- 239000004568 cement Substances 0.000 claims abstract description 31
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 28
- 239000002689 soil Substances 0.000 claims abstract description 18
- 238000000746 purification Methods 0.000 claims abstract description 13
- 239000011521 glass Substances 0.000 claims abstract description 6
- 239000003292 glue Substances 0.000 claims abstract description 6
- 241000196324 Embryophyta Species 0.000 claims description 10
- 241000234479 Narcissus Species 0.000 claims description 3
- 235000014676 Phragmites communis Nutrition 0.000 claims description 3
- 239000011083 cement mortar Substances 0.000 claims description 3
- 244000089486 Phragmites australis subsp australis Species 0.000 claims 1
- 239000010865 sewage Substances 0.000 abstract description 14
- 239000003673 groundwater Substances 0.000 abstract description 6
- 238000009434 installation Methods 0.000 abstract 1
- 239000008213 purified water Substances 0.000 description 4
- 244000273256 Phragmites communis Species 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/103—Arsenic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
- C02F3/327—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae characterised by animals and plants
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
本发明公开了一种处理铅、镍、砷等重金属污染水体的试验装置及其试验方法,该装置分为三个部分,第一部分为试验装置,包括矩形水渠、水阀、水泥围墙;第二部分为吸附装置,包括大型过滤板、吸附板、小型过滤板;第三部分为净化装置,包括人工湿地、生态草地。以上三个部分结合紧密、共同工作。试验时首先将过滤板和吸附板利用玻璃胶固定在矩形水渠内壁,然后将土壤填筑在水泥围墙内,在土壤上分别设置人工湿地和生态草地,充分利用植物对铅、镍、砷等重金属的吸附能力提高本发明的净化效果,设置完成后将污水从远离水阀的一端引入水渠中,最后打开水阀,使污水在装置中的流速缓慢。经过本装置处理后的水体,其清除重金属的效果可达99.8%,水体质量达到了国家地下水质量标准。
The invention discloses a test device and a test method for treating water polluted by heavy metals such as lead, nickel and arsenic. The device is divided into three parts. The first part is a test device, which includes a rectangular water channel, a water valve and a cement enclosure; the second part is a test device. Part is adsorption device, including large filter plate, adsorption plate, and small filter plate; the third part is purification device, including artificial wetland and ecological grassland. The above three parts are closely integrated and work together. During the test, the filter plate and the adsorption plate were first fixed on the inner wall of the rectangular water channel with glass glue, and then the soil was filled in the cement enclosure, and artificial wetlands and ecological grasslands were set up on the soil to make full use of the plants’ resistance to heavy metals such as lead, nickel, and arsenic. The adsorption ability of the present invention improves the purification effect of the present invention. After the installation is completed, the sewage is introduced into the canal from the end far away from the water valve, and finally the water valve is opened to slow down the flow rate of the sewage in the device. The water body treated by the device can remove heavy metals up to 99.8%, and the water quality has reached the national groundwater quality standard.
Description
技术领域technical field
本发明涉及一种处理铅、镍、砷等重金属污染水体的试验装置。该装置可以处理被铅、镍、砷等重金属污染的水体,同时其清除重金属的效果可达99.8%,水体质量可达到国家地下水质量标准。此发明还涉及该试验装置的使用方法。The invention relates to a test device for treating water bodies polluted by heavy metals such as lead, nickel and arsenic. The device can treat water polluted by heavy metals such as lead, nickel, arsenic, etc., and the effect of removing heavy metals can reach 99.8%, and the water quality can meet the national groundwater quality standard. The invention also relates to the method of use of the test device.
背景技术Background technique
土壤是人类赖以生存的主要资源之一。而随着城市现代化的迅速发展,矿床过度开采和冶炼等导致大量污染物流入土壤,使其铅、镍、砷等重金属污染日益严重。土壤中的重金属通过植物吸收进入植物体内,还可能通过河流径流污染地下水和地表水,最终通过食物链或直接接触等途径危害人体健康。Soil is one of the main resources for human survival. With the rapid development of urban modernization, over-exploitation and smelting of ore deposits have caused a large amount of pollutants to flow into the soil, causing heavy metal pollution such as lead, nickel, and arsenic to become increasingly serious. Heavy metals in the soil are absorbed into plants through plants, and may also pollute groundwater and surface water through river runoff, and eventually endanger human health through food chains or direct contact.
现有对铅、镍、砷等重金属污染的水体净化装置所能处理的污水量很少,试验方法大都是针对单一重金属污染的水体进行净化,并没有很好的利用植物对重金属的吸附能力,更不能达到很高的净化效果。因此设计了一种能处理大量铅、镍、砷等重金属污染水体的试验装置,该装置利用植物对重金属有较好吸附能力的特点提高了净化效果,净化后的水质可达到国家地下水标准。Existing water purification devices polluted by heavy metals such as lead, nickel, and arsenic can handle very little sewage. Most of the test methods are for purifying water polluted by a single heavy metal, and do not make good use of the adsorption capacity of plants for heavy metals. More can not achieve very high purification effect. Therefore, a test device that can deal with a large amount of lead, nickel, arsenic and other heavy metal-contaminated water bodies was designed. This device improves the purification effect by utilizing the characteristics of plants with good adsorption capacity for heavy metals. The purified water quality can meet the national groundwater standard.
发明内容Contents of the invention
本发明要解决的问题是设计一种能处理大量铅、镍、砷等重金属污染水体的试验装置,并且利用植物对重金属有较好吸附能力的特点提高本发明的净化效果,使净化后的水质能达到国家地下水标准。The problem to be solved in the present invention is to design a test device that can handle a large amount of lead, nickel, arsenic and other heavy metals polluted water bodies, and utilize the characteristics that plants have better adsorption capacity for heavy metals to improve the purification effect of the present invention, so that the water quality after purification It can meet the national groundwater standard.
为了解决上述技术问题,本发明提供一种处理铅、镍、砷等重金属污染水体的试验装置,该装置分为三个部分,第一部分为试验装置,包括矩形水渠、水阀、水泥围墙;第二部分为吸附装置,包括大型过滤板、吸附板、小型过滤板;第三部分为净化装置,包括人工湿地、生态草地。In order to solve the above technical problems, the present invention provides a test device for treating heavy metal polluted water bodies such as lead, nickel, arsenic, etc. The device is divided into three parts, the first part is a test device, including a rectangular water channel, a water valve, and a cement wall; the second part is a test device. The second part is the adsorption device, including large filter plates, adsorption plates, and small filter plates; the third part is the purification device, including artificial wetlands and ecological grasslands.
所述处理铅、镍、砷等重金属污染水体的试验装置整体布局是:在矩形水渠的中间设有两堵水泥围墙,所述水泥围墙中填满土壤;在所述土壤的一半区域设置生态水沟,另一半区域设置人工湿地;在所述两堵水泥围墙上放置小型过滤板;在所述水泥围墙外分别放置两倒吸附板和大型过滤板;所述的水渠底部设有水阀。The overall layout of the test device for treating heavy metal-contaminated water bodies such as lead, nickel, and arsenic is as follows: two cement walls are arranged in the middle of the rectangular water channel, and the cement walls are filled with soil; half of the soil area is provided with ecological water. ditch, and artificial wetlands are set in the other half of the area; small filter plates are placed on the two cement walls; two inverted adsorption plates and a large filter plate are placed outside the cement walls; water valves are provided at the bottom of the canal.
所述矩形水渠由水泥砌块砌筑,并用水泥砂浆抹平,该水渠长边2200mm,短边500mm,高度50mm,壁厚为50mm;在所述矩形水渠中间500mm的位置分别设有两堵高度为250mm、宽度为500mm、厚度为50mm的水泥围墙;在所述矩形水渠底部设有直径为5mm的水阀。The rectangular canal is built by cement blocks and smoothed with cement mortar. The long side of the canal is 2200mm, the short side is 500mm, the height is 50mm, and the wall thickness is 50mm; two blocks of height are respectively arranged at the position of 500mm in the middle of the rectangular canal. 250mm in width, 500mm in width, and 50mm in thickness; a water valve with a diameter of 5mm is provided at the bottom of the rectangular water channel.
所述水泥围墙中填满土壤,并划分为两个区域分别设置500mm×500mm的生态水沟和500mm×500mm的人工湿地;所述生态水沟中种植水仙,在人工湿地中种植芦苇,利用植物对重金属的吸附能力提高装置净化效果。The cement wall is filled with soil, and divided into two areas to set up an ecological ditch of 500mm×500mm and an artificial wetland of 500mm×500mm; plant narcissus in the ecological ditch, plant reeds in the artificial wetland, and use plant The adsorption capacity of heavy metals improves the purification effect of the device.
靠近生态水沟的水泥围墙上设有高度为250mm、宽度为500mm、厚度为20mm的小型过滤板,距离小型过滤板50mm处设置两道高度500mm、宽度500mm、厚度150mm相距50mm的吸附板,高度500mm、宽度500mm、厚度20mm的大型过滤板与吸附板紧靠。A small filter plate with a height of 250mm, a width of 500mm, and a thickness of 20mm is installed on the cement wall near the ecological ditch, and two adsorption plates with a height of 500mm, a width of 500mm, and a thickness of 150mm are installed at a distance of 50mm from the small filter plate. A large filter plate of 500mm, width 500mm, and thickness 20mm is in close contact with the adsorption plate.
靠近人工湿地的水泥围墙上设有小型过滤板,所述小型过滤板与一道吸附板相连,另一道吸附板50mm处设有大型过滤板,两道吸附板相距50mm;所有大型过滤板、吸附板和小型过滤板均用玻璃胶与矩形水渠内壁粘接,保证装置各部分不漏水。A small filter plate is provided on the cement wall near the artificial wetland, and the small filter plate is connected with one adsorption plate, and a large filter plate is installed at 50 mm from the other adsorption plate, and the distance between the two adsorption plates is 50 mm; all large filter plates, adsorption plates Both the filter plate and the small filter plate are bonded to the inner wall of the rectangular water channel with glass glue to ensure that all parts of the device are watertight.
本发明提供一种处理铅、镍、砷等重金属污染水体的试验装置及其试验方法,试验步骤如下:The invention provides a test device and test method for treating heavy metal polluted water bodies such as lead, nickel, arsenic, etc. The test steps are as follows:
步骤一、检查装置各部分是否完整可用,利用玻璃胶将过滤板和吸附板与矩形水渠内壁粘接;Step 1. Check whether each part of the device is complete and usable, and use glass glue to bond the filter plate and adsorption plate to the inner wall of the rectangular water channel;
步骤二、将土壤填筑在水泥围墙内,在土壤上分别设置人工湿地和生态草地,并准备好试验所需的污水;Step 2. Fill the soil in the cement wall, set up artificial wetland and ecological grassland on the soil, and prepare the sewage required for the test;
步骤三、关闭水阀,将污水从远离水阀的一端缓慢倒入水渠中,使污水依次经过大型过滤板、吸附板、小型过滤板、生态草地、人工湿地、小型过滤板、吸附板、大型过滤板,水质逐渐得到净化;Step 3. Close the water valve, slowly pour the sewage into the ditch from the end far away from the water valve, so that the sewage passes through the large filter plate, adsorption plate, small filter plate, ecological grassland, artificial wetland, small filter plate, adsorption plate, large Filter plate, the water quality is gradually purified;
步骤四、当水填满整个水渠时,停止倒水,将水阀打开,使净化后的水从水阀中缓慢流出;Step 4. When the water fills the entire ditch, stop pouring water and open the water valve to allow the purified water to flow out slowly from the water valve;
步骤五、水渠中的污水全部从水阀中排出后,重复步骤三到步骤四,直到所有的污水全部处理完毕即可停止试验。Step 5. After all the sewage in the canal is discharged from the water valve, repeat steps 3 to 4 until all the sewage is completely treated and the test can be stopped.
采用上述技术方案的处理铅、镍、砷等重金属污染水体的试验装置及其试验方法,本发明的创新之处在于:同时设置了生态草地和人工湿地,充分利用植物对重金属的吸附能力提高装置的净化效果,净化后的水质可达到国家地下水标准。Adopt the test device and test method of the heavy metal polluted water body such as lead, nickel, arsenic of the above-mentioned technical scheme, the innovation of the present invention is: set up ecological grassland and artificial wetland at the same time, make full use of plant to the adsorption capacity improvement device of heavy metal The purification effect, the purified water quality can meet the national groundwater standard.
本发明试验装置构造简单,成本低廉,拆装方便,可以反复利用。该装置可以处理大量铅、镍、砷等重金属污染的水体,同时通过多层过滤和吸附提高装置的净化效果。装置底部的水阀有效控制了试验时污水液面的高度。The test device of the invention has the advantages of simple structure, low cost, convenient assembly and disassembly, and can be used repeatedly. The device can treat water polluted by a large amount of lead, nickel, arsenic and other heavy metals, and at the same time improve the purification effect of the device through multi-layer filtration and adsorption. The water valve at the bottom of the device effectively controls the height of the sewage liquid level during the test.
附图说明Description of drawings
图1是本发明整体图Fig. 1 is an overall view of the present invention
图2是本发明整体俯视图Fig. 2 is the overall plan view of the present invention
图3是本发明整体剖面图Fig. 3 is an overall sectional view of the present invention
具体实施方式detailed description
下面结合附图,说明一种处理铅、镍、砷等重金属污染水体的试验装置具体实施方式。A specific embodiment of a test device for treating heavy metal-polluted water bodies such as lead, nickel, and arsenic will be described below in conjunction with the accompanying drawings.
如图1该装置的整体剖面图:在矩形水渠(1)的中间设有两堵水泥围墙(5),所述水泥围墙(5)中填满土壤(6);在所述土壤(6)的一半区域设置生态水沟(7),另一半区域设置人工湿地(8);在所述两堵水泥围墙(6)上放置小型过滤板(3);在所述水泥围墙(6)外对称放置两倒吸附板(4)和大型过滤板(2);所述的水渠(1)底部设有水阀(9)。The overall sectional view of the device as shown in Figure 1: two cement walls (5) are arranged in the middle of the rectangular water channel (1), and soil (6) is filled in the cement wall (5); in the soil (6) Ecological ditches (7) are set in half of the area, and artificial wetlands (8) are set in the other half; small filter plates (3) are placed on the two cement walls (6); symmetrically outside the cement walls (6) Two inverted adsorption plates (4) and a large filter plate (2) are placed; a water valve (9) is provided at the bottom of the water channel (1).
如图2该装置的整体俯视图:矩形水渠(1)由水泥砌块砌筑,并用水泥砂浆抹平,该水渠(1)长边2200mm,短边500mm,高度50mm,壁厚为50mm;在所述矩形水渠(1)中间500mm的位置分别设有两堵高度为250mm、宽度为500mm、厚度为50mm的水泥围墙(5);在所述矩形水渠(1)底部设有直径为5mm的水阀(9)。The overall top view of the device is shown in Figure 2: the rectangular water channel (1) is built by cement blocks and smoothed with cement mortar. The long side of the water channel (1) is 2200mm, the short side is 500mm, the height is 50mm, and the wall thickness is 50mm; Two cement walls (5) with a height of 250 mm, a width of 500 mm, and a thickness of 50 mm are installed at the middle 500 mm of the rectangular water channel (1); a water valve with a diameter of 5 mm is provided at the bottom of the rectangular water channel (1) (9).
如图1该装置的整体剖面图:所述水泥围墙(5)中填满土壤(6),并划分为两个区域分别设置500mm×500mm的生态水沟(7)和500mm×500mm的人工湿地(8);所述生态水沟(7)中种植水仙,在人工湿地(8)中种植芦苇,利用植物对重金属的吸附能力提高装置净化效果。As shown in Figure 1, the overall section view of the device: the cement wall (5) is filled with soil (6), and is divided into two areas to set up an ecological ditch (7) of 500mm×500mm and an artificial wetland of 500mm×500mm (8); Narcissus is planted in the ecological ditch (7), reeds are planted in the artificial wetland (8), and the purification effect of the device is improved by utilizing the adsorption capacity of the plants to heavy metals.
如图1该装置的整体剖面图:靠近生态水沟(7)的水泥围墙(5)上设有高度为250mm、宽度为500mm、厚度为20mm的小型过滤板(3),距离小型过滤板(3)50mm处设置两道高度500mm、宽度500mm、厚度150mm相距50mm的吸附板(4),高度500mm、宽度500mm、厚度20mm的大型过滤板(2)与吸附板(4)紧靠。The overall profile of the device as shown in Figure 1: a small filter plate (3) with a height of 250mm, a width of 500mm, and a thickness of 20mm is provided on the cement wall (5) near the ecological ditch (7), and the distance from the small filter plate ( 3) Two adsorption plates (4) with a height of 500 mm, a width of 500 mm, and a thickness of 150 mm are arranged at a distance of 50 mm at 50 mm, and a large filter plate (2) with a height of 500 mm, a width of 500 mm, and a thickness of 20 mm is close to the adsorption plate (4).
如图1该装置的整体剖面图:靠近人工湿地(8)的水泥围墙(5)上设有小型过滤板(3),所述小型过滤板(3)与一道吸附板(4)相连,另一道吸附板(4)50mm处设有大型过滤板(2),两道吸附板(4)相距50mm;所有大型过滤板(2)、吸附板(4)和小型过滤板(3)均用玻璃胶与矩形水渠(1)内壁粘接,保证装置各部分不漏水。As shown in Figure 1, the overall sectional view of the device: a small filter plate (3) is provided on the cement wall (5) close to the artificial wetland (8), and the small filter plate (3) is connected with an adsorption plate (4), and another There is a large filter plate (2) at 50 mm from one adsorption plate (4), and the distance between the two adsorption plates (4) is 50 mm; all large filter plates (2), adsorption plates (4) and small filter plates (3) are made of glass The glue is bonded to the inner wall of the rectangular water channel (1) to ensure that all parts of the device are watertight.
本发明提供一种处理铅、镍、砷等重金属污染水体的试验装置及其试验方法,试验步骤如下:The invention provides a test device and test method for treating heavy metal polluted water bodies such as lead, nickel, arsenic, etc. The test steps are as follows:
步骤一、检查装置各部分是否完整可用,利用玻璃胶将过滤板和吸附板与矩形水渠内壁粘接;Step 1. Check whether each part of the device is complete and usable, and use glass glue to bond the filter plate and adsorption plate to the inner wall of the rectangular water channel;
步骤二、将土壤填筑在水泥围墙内,在土壤上分别设置人工湿地和生态草地,并准备好试验所需的污水;Step 2. Fill the soil in the cement wall, set up artificial wetland and ecological grassland on the soil, and prepare the sewage required for the test;
步骤三、关闭水阀,将污水从远离水阀的一端缓慢倒入水渠中,使污水依次经过大型过滤板、吸附板、小型过滤板、生态草地、人工湿地、小型过滤板、吸附板、大型过滤板,水质逐渐得到净化;Step 3. Close the water valve, slowly pour the sewage into the ditch from the end far away from the water valve, so that the sewage passes through the large filter plate, adsorption plate, small filter plate, ecological grassland, artificial wetland, small filter plate, adsorption plate, large Filter plate, the water quality is gradually purified;
步骤四、当水填满整个水渠时,停止倒水,将水阀打开,使净化后的水从水阀中缓慢流出;Step 4. When the water fills the entire ditch, stop pouring water and open the water valve to allow the purified water to flow out slowly from the water valve;
步骤五、水渠中的污水全部从水阀中排出后,重复步骤三到步骤四,直到所有的污水全部处理完毕即可停止试验。Step 5. After all the sewage in the canal is discharged from the water valve, repeat steps 3 to 4 until all the sewage is completely treated and the test can be stopped.
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